Готові списки джерел за темами / Solubility of Liquids

Добірка наукової літератури з теми "Solubility of Liquids"

Автор: Grafiati
Опубліковано: 6 вересня 2023

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Статті в журналах з теми "Solubility of Liquids"

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Zafarani-Moattar, Mohammad Taghi, Hemayat Shekaari, and Elnaz Mazaher Haji Agha. "Measurement and Modeling of Solubility of Galactose in Aqueous Ionic Liquids, 1-Butyl-3-Methyl Imidazolium Bromide, 1-Hexyl-3-Methyl Imidazolium Bromide and 1-Butyl-3-Methylimidazolium Chloride at T = (298.15 And 308.15) K." Pharmaceutical Sciences 25, no. 4 (December 20, 2019): 319–30. http://dx.doi.org/10.15171/ps.2019.32.

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Background: Saccharides are considered as abundant, cheap and renewable starting materials for chemicals and fuels. Recently, ionic liquids have been used as green solvents for saccharides. The solubility values of galactose in aqueous ionic liquid solutions are not available. Thus, the main objective of this research was to determine the solubility of galactose in aqueous solutions containing ionic liquids, 1-butyl-3-methyl imidazolium bromide, [BMIm]Br, 1-butyl-3-methylimidazolium chloride [BMIm]Cl and 1-hexyl-3-methyl imidazolium bromide, [HMIm]Br at different mole fractions of ionic liquids at T = (298.15 and 308.15) K. Methods: In this study, the gravimetric method was used to measure the solubility of galactose in aqueous ionic liquids solutions. Results: The solubility values of galactose in water and aqueous ionic liquid solutions were correlated with the activity coefficient models of Wilson, NRTL, modified NRTL, NRF-NRTL, and UNIQUAC. Conclusion: It was concluded that with increasing the mole fraction of ionic liquids, the solubility values of galactose decrease and in fact all of these ionic liquids show salting-out effect on aqueous galactose solutions and this behavior is stronger in ionic liquid 1-butyl-3-methylimidazolium chloride.
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Biń, Andrzej K. "Ozone Solubility in Liquids." Ozone: Science & Engineering 28, no. 2 (May 2006): 67–75. http://dx.doi.org/10.1080/01919510600558635.

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Monder, Hila, Leo Bielenki, Hanna Dodiuk, Anna Dotan, and Samuel Kenig. "Poly (Dimethylsiloxane) Coating for Repellency of Polar and Non-Polar Liquids." Polymers 12, no. 10 (October 21, 2020): 2423. http://dx.doi.org/10.3390/polym12102423.

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The wettability of poly (dimethylsiloxane) (PDMS) coating on plasma-treated glass was studied at room temperature using polar and non-polar liquids. The wettability was investigated regarding the liquids’ surface tensions (STs), dielectric constants (DCs) and solubility parameters (SPs). For polar liquids, the contact angle (CA) and contact angle hysteresis (CAH) are controlled by the DCs and non-polar liquids by the liquids’ STs. Solubility parameter difference between the PDMS and the liquids demonstrated that non-polar liquids possessed lower CAH. An empirical model that integrates the interfacial properties of liquid/PDMS has been composed. Accordingly, the difference between the SPs of PDMS and the liquid is the decisive factor affecting CAH, followed by the differences in DCs and STs. Moreover, the interaction between the DCs and the SPs is of importance to minimize CAH. It has been concluded that CAH, and not CA, is the decisive attribute for liquid repellency of PDMS coating.
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4

Matuszek, Karolina, Ewa Pankalla, Aleksander Grymel, Piotr Latos, and Anna Chrobok. "Studies on the Solubility of Terephthalic Acid in Ionic Liquids." Molecules 25, no. 1 (December 24, 2019): 80. http://dx.doi.org/10.3390/molecules25010080.

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Low solubility of terephthalic acid in common solvents makes its industrial production very difficult and not environmentally benign. Ionic liquids are known for their extraordinary solvent properties, with capability to dissolve a wide variety of materials, from common solvents to cellulose, opening new possibilities to find more suitable solvents for terephthalic acid. This work presents studies on the solubility of terephthalic acid in ionic liquids, and demonstrates that terephthalic acid is soluble in ionic liquids, such as 1-ethyl-3-methylimidazolium diethylphosphate, 1-butyl-3-methylimidazolium acetate, and dialkylimidazolium chlorides up to four times higher than in DMSO. Additionally, the temperature effect and correlation of ionic liquid structure with solubility efficiency are discussed.
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5

Wu, Tian, Qing Huang, Wei Li, Gongxuan Chen, Xiaoling Ma, and Guoping Zeng. "Electroreduction of Copper Dichloride Powder to Copper Nanoparticles in an Ionic Liquid." Journal of Nanomaterials 2014 (2014): 1–6. http://dx.doi.org/10.1155/2014/751424.

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There were a large number of ionic liquids electrodeposition reported in the literature; but were still in the laboratory stage some problems in the practical application of electrodeposition remain such as easily reacted with moisture in the air (AlCl3ionic liquid), high cost, and corrosive (dialkylimidazolium cation andBF4−,PF6−ionic liquid). In addition to the above shortcomings, low solubility of many metal salts in ionic liquids limits the practical application. In order to solve the problem of low solubility, [Bmim]Cl could be added [Bmim]PF6, which could significantly increase the solubility of metal chlorides; this method could be commonly used in preparing metal electrochemical reduction of metal chlorides. Our study showed that adding cationic groups in hydroxyl ionic liquid could cause the good solubility of transition metal chlorides, such as CuCl2. Complexation of hydroxyl functional group and transition metal ions increased solubility, resulting in a larger deposition current density and surface electrochemical reduction of copper nanoparticles deposited on the metal Ni. The electroreduction mechanism and behavior of CuCl2in hydroxyl ionic liquid and the Cu nanoparticle formation mechanism were investigated based on a comparison between similar experiments in the ionic liquid.
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Buchowski, H., and A. Khiat. "Solubility of solids in liquids: one-parameter solubility equation." Fluid Phase Equilibria 25, no. 3 (January 1986): 273–78. http://dx.doi.org/10.1016/0378-3812(86)80003-6.

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Lei, Zhigang, Chengna Dai, and Biaohua Chen. "Gas Solubility in Ionic Liquids." Chemical Reviews 114, no. 2 (November 6, 2013): 1289–326. http://dx.doi.org/10.1021/cr300497a.

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Turner, J. C. R. "Solubility of Gases in Liquids." Chemical Engineering Science 46, no. 9 (1991): 2385. http://dx.doi.org/10.1016/0009-2509(91)85142-k.

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Manic, Marina S., and Vesna Najdanovic-Visak. "Solubility of Mixtures Containing Soybean Oil, Ionic Liquid and Methanol." Open Chemical Engineering Journal 10, no. 1 (April 8, 2016): 41–49. http://dx.doi.org/10.2174/1874123101610010041.

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This paper presents data on mutual solubility of the binary (soybean oil + ionic liquid) and ternary (soybean oil + methanol + ionic liquid) systems, where ionic liquid stands for 1-butyl-3-methylimidazolium thiocyanate [C4MIM][SCN] or 1-butyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide [C4MIM][NTf2] or 1-butyl-3-methylimidazolium dicyanamide [C4MIM][DCA] or 1-butyl-3-methylimidazolium hexafluorophosphate [C4MIM][PF6] or 1-butyl-3-methyl imida zolium hydrogensulfate [C4MIM] [HSO4] or 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [C10MIM][NTf2] or methyltrioctylammonium bis(trifluoromethylsulfonyl)imide [ALIQUAT][NTf2] or methyltrioctylammonium chloride [ALIQUAT][Cl]. Solubilities were determined by the cloud point titration method in the temperature range of 298 K to 343 K. Obtained results suggest that imidazolium based ionic liquids exhibit lower solubility in soybean oil than ionic liquids with the aliquat cation. Thus, aliquat based ionic liquids are good candidate to be used as co-solvents for biphasic (methanol + soybean oil) mixture.
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Gamsjäger, Heinz, John W. Lorimer, Mark Salomon, David G. Shaw, and Reginald P. T. Tomkins. "The IUPAC-NIST Solubility Data Series: A guide to preparation and use of compilations and evaluations (IUPAC Technical Report)." Pure and Applied Chemistry 82, no. 5 (March 22, 2010): 1137–59. http://dx.doi.org/10.1351/pac-rep-09-10-33.

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The IUPAC-NIST Solubility Data Series (SDS) is an ongoing project that provides comprehensive reviews of published data for solubilities of gases, liquids, and solids in liquids or solids. Data are compiled in a uniform format, evaluated, and, where data from independent sources agree sufficiently, recommended values are proposed. This paper is a guide to the SDS and is intended for the benefit of both those who use the SDS as a source of critically evaluated solubility data and who prepare compilations and evaluations for future volumes. A major portion of this paper presents terminology and nomenclature currently recommended by IUPAC and other international bodies and relates these to obsolete forms that appear in the older solubility literature. In addition, this paper presents a detailed guide to the criteria and procedures used in data compilation, evaluation, and presentation and considers special features of solubility in gas + liquid, liquid + liquid, and solid + liquid systems. In the past, much of this information was included in introductory sections of individual volumes of the SDS. However, to eliminate repetitive publication, this information has been collected, updated, and expanded for separate publication here.
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Дисертації з теми "Solubility of Liquids"

1

Campanell, Frank Christopher. "The Modeling of Solubility." Wright State University / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=wright1169068854.

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Asatani, Haruki. "Solubility of gases in liquids." Thesis, University of Ottawa (Canada), 1986. http://hdl.handle.net/10393/4643.

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Bernardo, Carlos Gabriel Pires Morgado. "Solubility of organic liquids in polystyrene matrices." Thesis, University of Oxford, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.419261.

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4

Wu, M. F. "The solubility of solutes in cryogenic liquids." Thesis, University of Southampton, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373935.

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Ochsner, Allison Becker. "Solubility prediction in nonideal liquid mixtures /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487260859494571.

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6

Santos, Ana Rute Duarte dos. "Study on solubility of pharmaceutical compounds in ionic liquids." Master's thesis, Faculdade de Ciências e Tecnologia, 2013. http://hdl.handle.net/10362/9660.

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Анотація:
Dissertation to obtain the degree of master in Chemical and Biochemical Engineering
The sufficient solubility of N-acetyl-L-cysteine (NAC), coumarin (COU) and 4-hydroxycoumarin (4HC) in alternative solvents obtained in this work can open new perspectives in pharmaceutical processing. Solid–liquid equilibrium (SLE) measurements have been made using a dynamic (synthetic) method. The melting point and the enthalpy of fusion of the pharmaceutical compounds were acquired using differential scanning calorimetry (DSC). The solubility of N-acetyl-L-cysteine and 4-hydroxycoumarin in trifluoromethanesulfonate ionic liquids was found to be significantly higher than in the studied bis(trifluoromethylsulfonyl)imide ionic liquids, and when compared, coumarin have the opposite behaviour. The best solvent amongst studied for this antioxidant (NAC) and anticoagulants (COU and 4HC) was discovered. The solid–liquid phase equilibrium were described using six different correlation equations which revealed relatively good description with the acceptable standard deviation temperature range. Moreover, the solubility data was used to calculate the 1-octanol/water partition coefficients and experimental partition coefficients (logP) was found to be negative in N-acetyl-L-cysteine and positive in the case of coumarin, at five temperatures with N-acetyl-L-cysteine being more hydrophilic and coumarin more hydrophobic; These results are also proof of the possibility of using these compounds as pharmaceutical products.
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Batista, Marta Luísa Salsas. "Development of a solubility parameters scale for ionic liquids." Master's thesis, Universidade de Aveiro, 2010. http://hdl.handle.net/10773/3140.

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Анотація:
Mestrado em Engenharia Química
Os biocombustíveis, como bioetanol e butanol, têm se tornado numa área de grande relevância e objecto de investigação, dadas as suas propriedades que possibilitam a substituição dos combustíveis fósseis mais comuns. No entanto, a sua produção tem um problema associado que é a formação de azeotropos sempre que o álcool se encontra na presença de água. Este problema é usualmente ultrapassado pela utilização de Distilação Extractiva, onde os Líquidos Iónicos (ILs) são usados como agentes de separação, com o intuito de quebrarem o azeotropo. Na última década, os líquidos iónicos, dadas as suas propriedades únicas, têm sido alvo de muita investigação. Entre as mais diversas características, a possibilidade de refinar as suas propriedades para uma tarefa específica, permitiu identificar a necessidade de estudar e perceber qual a relação estrutura-propriedade dos líquidos iónicos, o que levou ao recurso de modelos predictivos. Neste trabalho, o parâmetro de solubilidade de Hildebrand baseado na Teoria das Soluções Regulares, foi utilizado para estimar o parâmetro de solubilidade usando dados experimentais disponíveis para coeficientes de actividade a diluição infinita e também para viscosidade, com o objectivo de obter de uma escala de parâmetros de solubilidade para líquidos iónicos. Dos resultados obtidos, para os coeficientes de actividade a diluição infinita, foi possível observar que os líquidos iónicos possuem um carácter anfifílico (efeito camaleónico), e utilizando a viscosidade na estimação dos parâmetros de solubilidade verificou-se que, no entanto, os líquidos iónicos comportam-se predominantemente como moléculas polares. Neste trabalho, também foram medidas solubilidades para o líquido iónico hexafluorofosfato de 1-butil-3-metil-imidazólio em misturas de água e 1- propanol e ainda 1-propanol e tolueno. Este procedimento permitiu a confirmação do comportamento (efeito camaleónico) descrito anteriormente pela utilização de coeficientes de actividade a diluição infinita. Na estimação dos parâmetros de solubilidade, algumas não conformidades foram observadas. A sua causa poderá estar no facto de que o parâmetro de solubilidade de Hildebrand não detalha a polaridade da molecula ou interacções específicas que, os líquidos iónicos sendo moléculas complexas, poderá ser insuficiente para descrever o seu comportamento. Desta forma, extensões ao parâmetro de solubilidade de Hildebrand são sugeridas neste trabalho. ABSTRACT: Bioethanol and biobutanol are biofuels that nowadays are gaining significance due to their physical and chemical properties that enables the replacement of fossil fuels. Nevertheless, their production brings an inherent problem which is the formation of an azeotrope when the alcohol is in the presence of water. Extractive distillation is the process most widely used, where Ionic liquids may act as separation agent, in order to break or shift the azeotrope. For the past decade, ionic liquids, due to their unique properties, have received an increasing attention by the academic community and industry. Within their characteristics, the possibility of tune their properties allowed identifying the need to understand the relation structure-property which leaded the use of predictive models. In this work, Hildebrand solubility parameter based on Regular Solution Theory, was used to estimate solubility parameters using experimental data available for activity coefficients at infinite dilution and viscosity, aiming the establishment of a solubility parameters scale for ionic liquids. The use of activity coefficients at infinite dilution allowed observing that ionic liquids have amphiphilic (chameleonic) behaviour, and with viscosity it was observed that they act predominantly as polar molecules. In this work, it was also measured solubilities for 1-butyl-3-methylimidazolium hexafluorophosphate in mixtures of water and 1-propanol and in mixture of 1- propanol and toluene. This procedure allowed to confirm the behaviour (chameleonic effect) described by solubility parameters estimated by activity coefficients at infinite dilution. In the estimation of solubility parameters, some non-conformities were observed and which can be explained by the fact that the Hildebrand solubility parameter does not detail molecule polarity or specific interactions, and the structure of ionic liquids is clearly more complex than it is taken account. In this matter, other extensions for Hildebrand solubility parameter are suggested.
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Rebiai, R. "The solubility of water in cryogenic liquids and the related effects." Thesis, University of Southampton, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.356094.

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Tick, Geoffrey Ray. "Dissolution and enhanced solubilization of immiscible phase organic liquids in porous media : Theoretical, laboratory, and field investigations." Diss., The University of Arizona, 2003. http://etd.library.arizona.edu/etd/GetFileServlet?file=file:///data1/pdf/etd/azu_e9791_2003_398_sip1_w.pdf&type=application/pdf.

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Tomlinson, Sean R. "The solubility and secondary structure of zein in imidazolium-based ionic liquids." Diss., Kansas State University, 2013. http://hdl.handle.net/2097/15511.

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Анотація:
Doctor of Philosophy
Department of Chemical Engineering
Jennifer L. Anthony
Ionic liquids are low melting salts composed of an organic cation and an inorganic or organic anion. Ionic liquids are of interest for their wide range of applications and unique properties, such as the negligible vapor pressure of some types of ionic liquids, and the ability to modify ionic liquid properties by selection of the cation or anion. It has been hypothesized that over one million binary ionic liquids (meaning a single cation/anion pair) are possible. Due to the vast number of potential combinations, it should be possible to design ionic liquids specifically for an application of interest. One potential application is their use as protein solvents. However there is little understanding of how ionic liquids affect proteins. This research examined the solubility and secondary structure of the hydrophobic corn protein zein in seven ionic liquids and three conventional solvents as a function of temperature and solvent properties. Zein’s solubility in the solvents was measured gravimetrically from 30 to 60 degrees Celsius. Solubility was then related to solvent properties to gain an understanding of what solvent properties are important, and how to design an ionic liquid to dissolve zein. It was found that a good solvent for zein has a small molecular volume, a low polarity, and is a weak hydrogen bond acceptor. Infrared spectroscopy with curve fitting was used to examine the secondary structure of zein as a function of both solvent and temperature from 25 to 95 degrees Celsius. It was found that most of the ionic liquids change zein’s secondary structure, but those secondary structure changes were not affected by temperature. Aprotic ionic liquids increase the amount of β-turn secondary structure through non-polar interactions between the mixed aromatic-alkyl imidazolium cations and the non-polar portions of the zein. Strong hydrogen bond accepting molecules were found to increase the amount of β-turn secondary structure. It is hypothesized from this research that suitable solvents for zein will have a small molar volume, low polarity, and be poor hydrogen bond acceptors. This combination of properties will enhance zein’s solubility and limit secondary structure changes that can harm protein properties.
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Книги з теми "Solubility of Liquids"

1

Fogg, Peter G. T. Solubility of gases in liquids: A critical evaluation of gas/liquid systems in theory and practice. Chichester: J. Wiley, 1991.

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2

Meeting, American Chemical Society, and American Chemical Society. Division of Industrial and Engineering Chemistry, eds. Gas-expanded liquids and near-critical media: Green chemistry and engineering. Washington, D.C: American Chemical Society, 2009.

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3

CRC handbook of polymer-liquid interaction parameters and solubility parameters. Boca Raton: CRC Press, 1990.

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4

Jae-Jin, Shim, ed. Solubility in supercritical carbon dioxide. Boca Raton: CRC Press, 2007.

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5

Maria Celeste de Carvalho Serra. Solubilidade de gases em água e em meios de fermentação. Lisboa: Edic̨ões Colibri, 2007.

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6

Palacios, Jose Manuel. The solubility of copper in lime-saturated and calcium ferrite-saturated liquid iron oxide. Ann Arbor, MI: UMI Dissertation Services, 1991.

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7

Siwka, Jerzy. Azot w ciekłych stopach żelaza. Częstochowa: Wydawn. Politechniki Częstochowskiej, 2006.

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8

Qiu, Guang-Ming. Modification and preparation of membrane in supercritical carbon dioxide. New York: Nova Science Publishers, 2010.

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9

Mulrooney, John Leonard. An investigation of a sorption apparatus to measure the solubility and diffusivity of a liquid blowing agent in a polymer at an elevated pressure. Ottawa: National Library of Canada, 1995.

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10

1955-, Qiu Guang-Ming, ed. Modification and preparation of membrane in supercritical carbon dioxide. Hauppauge, N.Y: Nova Science Publishers, 2009.

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Частини книг з теми "Solubility of Liquids"

1

Krause, Sonja. "Solubility of Polymers in Liquids." In The Experimental Determination of Solubilities, 595–616. Chichester, UK: John Wiley & Sons, Ltd, 2004. http://dx.doi.org/10.1002/0470867833.ch15.

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Clever, H. Lawrence, and Rubin Battino. "Solubility of Gases in Liquids." In The Experimental Determination of Solubilities, 99–150. Chichester, UK: John Wiley & Sons, Ltd, 2004. http://dx.doi.org/10.1002/0470867833.ch3.

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Cohen-Adad, Roger, and Marie-Thérèse Cohen-Adad. "Solubility of Solids in Liquids." In The Experimental Determination of Solubilities, 257–314. Chichester, UK: John Wiley & Sons, Ltd, 2004. http://dx.doi.org/10.1002/0470867833.ch8.

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Szczepaniec-Cieciak, Elzbieta. "Solubility of Solids and Liquids in Cryogenic Liquids." In The Experimental Determination of Solubilities, 557–93. Chichester, UK: John Wiley & Sons, Ltd, 2004. http://dx.doi.org/10.1002/0470867833.ch14.

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Zhang, Jinming, Chenyang Liu, and Jun Zhang. "Solubility of Polymers in Ionic Liquids." In Encyclopedia of Ionic Liquids, 1–8. Singapore: Springer Nature Singapore, 2022. http://dx.doi.org/10.1007/978-981-10-6739-6_149-1.

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Zhang, Jinming, Chenyang Liu, and Jun Zhang. "Solubility of Polymers in Ionic Liquids." In Encyclopedia of Ionic Liquids, 1202–9. Singapore: Springer Nature Singapore, 2022. http://dx.doi.org/10.1007/978-981-33-4221-7_149.

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Aim, Karel, and Maurizio Fermeglia. "Solubility of Solids and Liquids in Supercritical Fluids." In The Experimental Determination of Solubilities, 491–555. Chichester, UK: John Wiley & Sons, Ltd, 2004. http://dx.doi.org/10.1002/0470867833.ch13.

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Gamsjäger, Heinz, and Erich Königsberger. "Solubility of Sparingly Soluble Ionic Solids in Liquids." In The Experimental Determination of Solubilities, 315–58. Chichester, UK: John Wiley & Sons, Ltd, 2004. http://dx.doi.org/10.1002/0470867833.ch9.

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Shiflett, Mark B., and A. Yokozeki. "Solubility of Fluorocarbons in Room Temperature Ionic Liquids." In ACS Symposium Series, 21–42. Washington DC: American Chemical Society, 2009. http://dx.doi.org/10.1021/bk-2009-1030.ch002.

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Xiao, Y., C. R. Mambote, G. A. Wierink, and A. van Sandwijk. "Solubility of A12O3 in NaCl-KCl Based Molten Salt System." In Molten Salts and Ionic Liquids, 389–95. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9780470947777.ch24.

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Тези доповідей конференцій з теми "Solubility of Liquids"

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Imani, M. T., M. Farahani, M. Kuhnke, K. Homeier, and P. Werle. "Measuring methods for solubility of gases in insulation liquids." In 2017 IEEE 19th International Conference on Dielectric Liquids (ICDL). IEEE, 2017. http://dx.doi.org/10.1109/icdl.2017.8124654.

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Asensio Delgado, Salvador, Fernando Pardo, Gabriel Zarca, and Ane Urtiaga. "Solubility differences of refrigerant gases in ionic liquids." In 14th Mediterranean Congress of Chemical Engineering (MeCCE14). Grupo Pacífico, 2020. http://dx.doi.org/10.48158/mecce-14.dg.07.06.

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Greaves, Brad, Thomas Prevost, Ed Casserly, Griffin Burk, and Ashmita Niroula. "Water Solubility of Aged Mineral Oil and Natural Ester Liquids." In 2023 IEEE 22nd International Conference on Dielectric Liquids (ICDL). IEEE, 2023. http://dx.doi.org/10.1109/icdl59152.2023.10209323.

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Perez, Daniel, Belen Garcia, Victor A. Primo, and Juan Carlo Burgos. "Analysis of Water Solubility in natural-ester based nanodielectric fluids." In 2019 IEEE 20th International Conference on Dielectric Liquids (ICDL). IEEE, 2019. http://dx.doi.org/10.1109/icdl.2019.8796556.

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Deshpande, Anirudh, Prashanta Dutta, and Soumik Banerjee. "Solubility of Oxygen in Lithium-Air Battery Electrolytes: A Molecular Dynamics Study." In ASME 2014 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/imece2014-40215.

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Ionic liquids are widely considered as potential electrolytes for lithium batteries due to their tunable electrochemical properties and extremely low vapor pressure, which makes them highly non-inflammable. However, the solubility of oxygen in ionic liquid based electrolytes is an important parameter that determines the performance of batteries. In the present study, we have employed molecular dynamics simulations to calculate the Henry’s constant and corresponding solubility values of atmospheric oxygen in N-methyl-N-propyl pyrrolidinium bis(trifluoromethanesulfonyl) imide (mppy+TFSI−) ionic liquids. After qualitatively validating the results at 323 K, we calculated the solubility of oxygen in mppy+TFSI−, as the ratio of the partial pressure of oxygen gas in the atmosphere and the Henry’s constant, at a range of temperatures that occur in realistic battery electrolytes. The solubility of oxygen increases with increasing temperature. Comparison of these solubility values with those of commonly used organic electrolytes provides valuable information regarding the feasibility of using ionic liquid electrolytes in lithium-air batteries.
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Yunus, Normawati M., Maizatul S. Shaharun, M. I. Abdul Mutalib, and T. Murugesan. "Modeling of CO2 solubility in pyridinium-based ionic liquids using UNIQUAC." In 4TH INTERNATIONAL CONFERENCE ON FUNDAMENTAL AND APPLIED SCIENCES (ICFAS2016). Author(s), 2016. http://dx.doi.org/10.1063/1.4968093.

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Sulaimon, Aliyu Adebayo, Luqman Adam Azman, Syed Ali Qasim Zohair, Bamikole Joshua Adeyemi, Azmi B. Shariff, and Wan Zaireen Nisa Yahya. "Predicting the Hydrogen Storage Potential of Ionic Liquids Using the Data Analytics Techniques." In SPE Nigeria Annual International Conference and Exhibition. SPE, 2023. http://dx.doi.org/10.2118/217176-ms.

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Abstract In recent years, hydrogen has been an attractive substitute as an energy carrier to fossil fuels, though it is difficult to store by conventional means. Ionic Liquids (ILs) are low-melting salts with varying properties of interest. Experimental investigations into the utilization of ILs as hydrogen storage mediums are still ongoing. This study aimed to predict the solubility of hydrogen in ILs using the data analytics method, whereby the correlations between the ILs’ requisite hydrogen properties and hydrogen solubility were developed and validated. The methodology involves comparing the experimental data from the literature and the simulated data from COSMO-RS software, where predictive correlations were developed using analytical software such as Python. The predictive model can be used to predict the hydrogen solubility of ILs based on the input inherent thermophysical properties of the IL before a particular IL is synthesized and tested in an actual laboratory setting.
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Petrin, Lívia, Mariana da Costa, and Rafael Dias. "An investigation of lignocellulosic biopolymers solubility in Protic Ionic Liquids aqueous solutions." In Congresso de Iniciação Científica UNICAMP. Universidade Estadual de Campinas, 2019. http://dx.doi.org/10.20396/revpibic2720192152.

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Yunus, Normawati M., M. Asif Abdul Ghani, and Ruzaimah Nik Mohamad Kamil. "Synthesis, characterization and CO2 solubility of [hmim][Tf2N] and [hmim][Ac] ionic liquids." In 3RD INTERNATIONAL CONFERENCE ON FUNDAMENTAL AND APPLIED SCIENCES (ICFAS 2014): Innovative Research in Applied Sciences for a Sustainable Future. AIP Publishing LLC, 2014. http://dx.doi.org/10.1063/1.4898480.

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Sen, Mihir, and Samuel Paolucci. "The Use of Ionic Liquids in Refrigeration." In ASME 2006 International Mechanical Engineering Congress and Exposition. ASMEDC, 2006. http://dx.doi.org/10.1115/imece2006-14712.

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Ionic liquids are salts, usually with organic cations and inorganic anions, that are liquid at room temperature. There are a wide variety of ionic liquids that can be synthesized with different properties for different applications. They are generally non-volatile, non-toxic, and non-flammable with high heat capacity, high density, high thermal and chemical stability. We propose its use as an absorbent in an absorption refrigeration cycle. The refrigerant in this case would be a gas such as carbon dioxide. The present work deals with the desirable properties of ionic liquids for this application. For example, the absorbent must have a high solubility, and the heat and mass transfer coefficients of the absorbent-refrigerant solution must be large. The viscosity of the mixture, on the other hand, should not be so large as to make its pumping difficult.
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Звіти організацій з теми "Solubility of Liquids"

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Mountain, R. D. Molecular dynamics study of the solubility of oxygen in liquid pyridine. Gaithersburg, MD: National Institute of Standards and Technology, 2003. http://dx.doi.org/10.6028/nist.ir.7075.

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HOHL, T., D. PLACE, and R. WITTMAN. STRONTIUM-90 LIQUID CONCENTRATION SOLUBILITY CORRELATION IN THE HANFORD TANK WASTE OPERATIONS SIMULATOR. Office of Scientific and Technical Information (OSTI), August 2004. http://dx.doi.org/10.2172/828017.

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Park, J. H., R. Erck, and E. T. Park. Measurement of hydrogen solubility and desorption rate in V-4Cr-4Ti and liquid lithium-calcium alloys. Office of Scientific and Technical Information (OSTI), April 1997. http://dx.doi.org/10.2172/543272.

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Looney, Brian, Holly Vermeulen, J. Dickson, Thomas White, Andrew Boggess, Thomas Peters, and Emily Fabricatore. Vapor-Liquid Partitioning of Methylmercury Compounds: Fundamental Data to Support the Savannah River Site Liquid Waste System: Henry's Law, Solubility and Vapor Pressure Determination for Representative Methylmercury Compounds. Office of Scientific and Technical Information (OSTI), June 2021. http://dx.doi.org/10.2172/1804664.

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Liaw, Shuh-Jeng. Automation of a hydrogen meter for use in coal liquefaction plant and for determination of the effect of aliphatic hydrocarbons on hydrogen solubility and mass transfer rate in coal liquid solvents. Office of Scientific and Technical Information (OSTI), January 1989. http://dx.doi.org/10.2172/5341646.

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