Готові списки джерел за темами / Sociology, n.e.c

Добірка наукової літератури з теми "Sociology, n.e.c"

Автор: Grafiati
Опубліковано: 10 грудня 2022
Оновлено: 28 січня 2023

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Статті в журналах з теми "Sociology, n.e.c"

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Goñi, Félix M., F.-Xabier Contreras, L.-Ruth Montes, Jesús Sot, and Alicia Alonso. "Biophysics (and sociology) of ceramides." Biochemical Society Symposia 72 (January 1, 2005): 177–88. http://dx.doi.org/10.1042/bss0720177.

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In the past decade, the long-neglected ceramides (N-acylsphingosines) have become one of the most attractive lipid molecules in molecular cell biology, because of their involvement in essential structures (stratum corneum) and processes (cell signalling). Most natural ceramides have a long (16-24 C atoms) N-acyl chain, but short N-acyl chain ceramides (two to six C atoms) also exist in Nature, apart from being extensively used in experimentation, because they can be dispersed easily in water. Long-chain ceramides are among the most hydrophobic molecules in Nature, they are totally insoluble in water and they hardly mix with phospholipids in membranes, giving rise to ceramide-enriched domains. In situ enzymic generation, or external addition, of long-chain ceramides in membranes has at least three important effects: (i) the lipid monolayer tendency to adopt a negative curvature, e.g. through a transition to an inverted hexagonal structure, is increased, (ii) bilayer permeability to aqueous solutes is notoriously enhanced, and (iii) transbilayer (flip-flop) lipid motion is promoted. Short-chain ceramides mix much better with phospholipids, promote a positive curvature in lipid monolayers, and their capacities to increase bilayer permeability or transbilayer motion are very low or non-existent.
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2

Porter, Laurellen. "Congress and Policy Change.Gerald C. Wright, Jr. , Leroy N. Rieselbach , Lawrence C. Dodd." Journal of Politics 49, no. 3 (August 1987): 892–94. http://dx.doi.org/10.2307/2131294.

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DE IPOLA, Émilio. "Vers une science du texte social." Sociologie et sociétés 2, no. 1 (September 30, 2002): 123–44. http://dx.doi.org/10.7202/001360ar.

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Résumé À partir d'une lecture critique de Métier de sociologue par P. Bourdieu, J.-C. Chamboredon et J.-C. Passeron, et de Pouvoir politique et classes sociales par N. Poulantzas, l'auteur analyse les rapports complexes entre la pratique sociologique, l'épistémologie marxiste et le matérialisme historique, ce dernier étant conçu comme science des modes de production et des formations sociales. Il s'agit de montrer la complémentarité nécessaire entre l'épistémologie et la réflexion théorique en vue de l'établissement de concepts de base visant à définir l'objet propre de la sociologie et à lui conférer ainsi son droit à l'existence théorique.
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Lampas, Nikolaos. "Book Review: Jeffrey C Alexander and Bernadette N Jaworsky, Obama Power." Political Studies Review 15, no. 3 (April 24, 2017): 494–95. http://dx.doi.org/10.1177/1478929917705075.

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5

Duvdevany, Ilana, Victor Moin, and Rivka Yahav. "The Bipolarity of Adolescents' Feelings toward Their Parents with Various Illnesses and Disabilities." Illness, Crisis & Loss 15, no. 4 (October 2007): 315–32. http://dx.doi.org/10.2190/il.15.4.c.

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The study examined feelings toward parents among Israeli Jewish adolescents with disabled parents (research group, n = 182) and non-disabled parents (control group, n = 285). It also studied the relationship between the types of parental disability (chronic heart disease, multiple sclerosis, and blindness) and the adolescents' feelings toward their parents. Bipolarity, i.e., coexistence of positive and negative feelings toward parents, was found among all participants. Nevertheless, the intensity of these feelings and a predominance of the positive feelings over the negative were higher in the research group than in the control group. The type of parental disability was significantly correlated with intensity of adolescents' feeling toward their parents. The moderator effect of adolescents' anxiety on the intensity and balance of positive and negative feelings toward parents was found in both the research and control groups. The results of this study underline the importance of examining critical dimensions of family life in cases where the parents have a disability or chronic illness.
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Celik, Secil, Yavuz Ergun, and Serap Alp. "Synthesis and Spectroscopic Studies of 3,6-Diphenyl-2,5-Dihydropyrrolo[3,4-C]Pyrrole-1,4-Dion’s N,N’-Dialkyl Derivatives." Journal of Fluorescence 19, no. 5 (April 24, 2009): 829–35. http://dx.doi.org/10.1007/s10895-009-0480-0.

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Erbas, Secil Celik, and Serap Alp. "Synthesis and Spectroscopic Studies of N,N’-dialkyl Derivatives of Antisymmetrical 2H,5H-Dihydropyrrolo[3,4-c]pyrrole-1,4-diones." Journal of Fluorescence 24, no. 2 (September 19, 2013): 329–35. http://dx.doi.org/10.1007/s10895-013-1294-7.

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Mendes, Marlon Jose Gavlik, Tânia Maria Rechia Schroeder, and Fátima Elisabeth Denari. "Violência contra pessoas com deficiência: um estudo de caso (Violence against people with disabilities: a case report)." Revista Eletrônica de Educação 14 (April 13, 2020): 3308080. http://dx.doi.org/10.14244/198271993308.

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The life of people with disabilities are marked by adverse situations, like architectural barriers, communication barriers and attitudinal barriers, This group also suffers from violent situations in their daily lifes, such as physical and verbal aggression. In the current scientific production, there is few researches that investigates the discourse of the person victim of violence, a fact that, on one hand, may characterize some ignorance of the situations experienced by these people, and, on the other hand, may result in discredit of the discourse of people with disabilities. The objective of this research was to investigate the violence experienced by people with disabilities through a case study of a young person with physical disability. The research was descriptive and had a qualitative nature, using the theoretical framework of the Sociology of disability, Violence and Stigma. Semi-structured interview was conducted, using Comprehensive Sociology as a data analysis tool. The results showed that insults and exclusions are a part of the daily life of the young, actions that can be classified as bullying. The young experience several conflicts in the school environment, having some of these conflicts resolved through the mediation of professionals. Violence against people with disabilities is a dynamic and recurring phenomenon, requiring prevention and intervention programs in the school and other researches on the theme that focuses on the victim point of view.ResumoA vida das pessoas com deficiência é marcada por situações adversas, como barreiras físicas, comunicacionais e atitudinais. Esse grupo também sofre de situações violentas em seu cotidiano, como agressões físicas e verbais. Na produção científica atual se notam poucas pesquisas que investigam o discurso da própria pessoa vítima de violência, fato esse que, de um lado, pode caracterizar desconhecimento das situações vividas por essas pessoas e, por outro, pode resultar em um descrédito em relação ao discurso das pessoas com deficiência. Nesse sentido, o objetivo desta pesquisa foi investigar as violências vividas por pessoas com deficiência por meio de um estudo de caso de um jovem com deficiência física. A pesquisa realizada foi descritiva e de natureza qualitativa, utilizando-se do referencial teórico da Sociologia da Deficiência, da Violência e do Estigma. Foi realizada entrevista a partir de um roteiro semiestruturado de questões, sendo utilizada a Sociologia Compreensiva como ferramenta de análise dos dados. Os resultados mostraram que xingamentos e exclusões fazem parte do cotidiano do jovem com deficiência, ações tais que podem, legalmente, ser tidas como bullying. O jovem vive diversos conflitos no ambiente escolar, tendo alguns desses conflitos resolvidos a partir da mediação de profissionais. A violência contra as pessoas com deficiência é um fenômeno dinâmico e recorrente, são necessários programas de prevenção e de intervenção no ambiente escolar, além de outras pesquisas sobre a temática que focalizem a perspectiva da vítima.Palavras-chave: Violência, Pessoas com deficiência, Estigma, Bullying.Keywords: Violence, Disabled Persons, Stigma, Bullying.ReferencesABRAMOVAY, M. Cotidiano das escolas: entre violências. Brasília, DF: Unesco, Observatório de Violência, Ministério da Educação 2006.AMARAL, L. A. Sobre crocodilos e avestruzes: falando de diferenças físicas, preconceitos e sua superação. In: Diferenças e preconceito na escola: alternativas teóricas e práticas. Volume 5. São Paulo: Summus, 1998. p. 11-30.ARANHA, M. S. F. Paradigmas da relação da sociedade com as pessoas com deficiência. Revista do Ministério Público do Trabalho, v. 11, n. 21, p. 160-173, 2001.BARROS, A. C. M. W.; DESLANDES, S. F.; BASTOS, O. M. A violência familiar e a criança e o adolescente com deficiências. Cadernos de Saúde Pública, v. 32, 2016.BENETTI, D. S. Efeitos de um treino de habilidades para a vida junto a adolescentes com deficiência intelectual e em situação de acolhimento. 2015. Tese (Doutorado em Educação e Ciências Humanas). Programa de Pós-Graduação em Educação Especial. Universidade Federal de São Carlos, 2015.BIANCHETTI, L. Os trabalhos e os dias dos deuses e dos homens: a mitologia como fonte para refletir sobre normalidade e deficiência. Revista Brasileira de Educação Especial, v. 7, n. 1, p. 61-75, 2001.BONI, V.; QUARESMA, S. J. Aprendendo a entrevistar: como fazer entrevistas em Ciências Sociais. Em Tese, v. 2, n. 1, p. 68-80, 2005.BORGES, L.; CAMPOS, J. A. P. P. Fatores determinantes ao ingresso de alunos com deficiência no ensino médio. Psicologia Educacional, São Paulo, n. 44, p. 79-91, jun. 2017.BOTELHO, R. G.; SOUZA, J. M. C. Bullying e educação física na escola: características, casos, conseqüências e estratégias de intervenção. Revista de Educação Física/Journal of Physical Education, v. 76, n. 139, 2007.BRANDÃO, E. C.; MATIAZI, L. D. Bullying: Violência socioeducacional – desafio permanente. Pedagogia em Ação, v. 9, n. 1, p. 17-33, 2017.BRASIL. Estatuto da Pessoa com Deficiência. Lei Brasileira de Inclusão. Lei nº 13.146, de 6 de julho de 2015. Presidência da República, Brasília/DF; 2015.CHARLOT, B. A violência na escola: como os sociólogos franceses abordam essa questão. Sociologias, Porto Alegre, n. 8, p. 432-443, 2002.CUNHA, M, J.; PINTO, P. C. Representaciones mediáticas de la deficiencia: un estudio longitudinal en la prensa. Sociologia, Problemas e Práticas, Lisboa, n. 85, p. 131-147, set. 2017.EMERICH, D. R.; ALCKMIN-CARVALHO, F.; SILVA, M. H. M. Rejeição e vitimização por pares em crianças com deficiência intelectual e transtorno do espectro autista. Revista Educação Especial, v. 30, n. 58, 2017.FERNANDES, A. P. C. S.; DENARI, F. E. Pessoa com deficiência: estigma e identidade. Revista da FAEEBA Educação e Contemporaneidade, v. 26, n. 50, p. 77-89, 2017.FOUCAULT, M. Vigiar e punir: o nascimento da prisão. Tradução R. Ramalhete. 21. ed. Petrópolis, RJ: Vozes; 1999.FRASER, M. T. D.; GONDIM, S. M. G. Da fala do outro ao texto negociado: discussões sobre a entrevista na pesquisa qualitativa. Paidéia, v. 14, n. 28, p. 139-152, 2004.GOFFMAN, E. Estigma: notas sobre a manipulação da identidade deteriorada. Rio de Janeiro: Coletivo Sabotagem, 1988.GOMES, A. E. G.; REZENDE, L. K. Reflexões sobre bullying na realidade brasileira utilizando a técnica de análise de conteúdo: revisão bibliográfica. Cadernos de Pós-Graduação em Distúrbios do Desenvolvimento, v. 11, n. 1, 2018.GUIMARÃES, A. M. A dinâmica da violência escolar: conflito e ambiguidade. Campinas, SP: Editora Autores Associados, 1996.HARLOS, F. E. Sociologia da deficiência: vozes por significados e práticas (mais) inclusivas. 2012. 201 f. Dissertação (Mestrado em Educação Especial ? Educação do Indivíduo Especial) ? Universidade Federal de São Carlos, São Carlos, 2012.MAFFESOLI, M. Dinâmica da violência. São Paulo: Editora Revista dos Tribunais, 1987.MAFFESOLI, M. Elogio da razão sensível. Petrópolis, RJ: Vozes, 1998.MAFFESOLI, M. Entre o bem e o mal. Compêndio de subversão pós-moderna. Lisboa: Instituto Piaget, 2002.MAFFESOLI, M. O conhecimento comum: introdução à sociologia compreensiva. Porto Alegre: Sulina, 2007.MAGNABOSCO, M. B.; SOUZA, L. L. Educação inclusiva e as representações dos estudantes sobre seus pares com deficiência. Psicologia Escolar e Educacional, v. 22, n. 1, p. 115-122, 2018.MAZZOTTA, M. J. S.; D'ANTINO, M. E. F. Inclusão social de pessoas com deficiências e necessidades especiais: cultura, educação e lazer. Saúde e Sociedade, v. 20, p. 377-389, 2011.MENDES, C. S. Prevenção da violência escolar: avaliação de um programa de intervenção. Revista da Escola de Enfermagem da USP, v. 45, n. 3, p. 581-588, 2011.MENDES, E. G. Breve histórico da educação especial no Brasil. Revista Educación y Pedagogía, v. 22, n. 57, maio/ago. 2010.MOREIRA, M. C. N.; BASTOS, O. M.; BASTOS, L. C.; SOARES, A. H. R.; SOUZA, W. D. S.; SANCHEZ, R. N. Violência contra crianças e adolescentes com deficiência: narrativas com conselheiros tutelares. Ciência e Saúde Coletiva, v. 19, p. 3869-3878, 2014.ORGANIZAÇÃO MUNDIAL DA SAÚDE (OMS). CIF: Classificação Internacional de Funcionalidade, Incapacidade e Saúde. Organização Mundial da Saúde. Lisboa; 2004.ORGANIZAÇÃO MUNDIAL DA SAÚDE (OMS). World report on violence and health. World Health Organization. Geneva; 2002.PAULINO, V. C.; CAIADO, K. R. M. A construção do conceito de deficiência por estudantes sem deficiência, a partir de suas histórias de vida. Educação em Foco, v. 20, n. 32, p. 35-59, 2017.SÃO PAULO. Serviço de Acolhimento Institucional para Crianças e Adolescentes. Prefeitura Municipal de São Paulo. 2017. Disponível em: <https://www.prefeitura.sp.gov.br/cidade/secretarias/assistencia_social/protecao_social_especial/index.php?p=28980>. Acesso em: 6 set. 2019.SILVA, F. R.; ASSIS, S. G. Prevenção da violência escolar: uma revisão da literatura. Educação e Pesquisa, São Paulo, v. 44. 2018.SILVA, J. L. D.; OLIVEIRA, W. A. D.; SILVA, M. A. I. D.; PEREIRA, B. O.; CECILIO, S. Estudo exploratório sobre as concepções e estratégias de intervenção de professores em face do bullying escolar. Psicologia, Sa?o Paulo, Brasil, v. 17, n. 3, p. 189-199, 2015.SIMMEL, G. A natureza sociológica do conflito. In: MORAES FILHO, E. (Org.). Simmel. São Paulo: Ática, 1983. p. 122-134.STELKO-PEREIRA, A. C.; WILLIAMS, L. C. A. Reflexões sobre o conceito de violência escolar e a busca por uma definição abrangente. Temas Psicológicos, Ribeirão Preto/SP, v. 18, n. 1, p. 45-55, 2010.STELKO-PEREIRA, A. C. Avaliação de um programa preventivo de violência escolar: planejamento, implantação e eficácia. 2012. 193 f. Tese (Doutorado em Psicologia), Universidade Federal de São Carlos, São Carlos. 2012.VIEIRA, C. M.; DENARI, F. E. Programa informativo sobre deficiência mental e inclusão: mudanças nas atitudes sociais de crianças sem deficiência. Revista Brasileira de Educação Especial, Marília/SP, v. 18, n. 2, p. 265-282, 2012.WILLIAMS, L. C. A. Sobre deficiência e violência: reflexões para uma análise de revisão de área. Revista Brasileira de Educação Especial, v. 9, n. 2, p. 141-154, 2003.YIN, R. K. Estudo de caso: planejamento e método. Porto Alegre, RS: Bookman, 2001.e3308080
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Smith, Matthew J. "R O C K S T O N E: On Race, Politics, and Public Memorials in Jamaica." Slavery & Abolition 42, no. 2 (April 3, 2021): 219–39. http://dx.doi.org/10.1080/0144039x.2021.1896186.

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Delmas, Corinne. "Dictionnaire critique de l’expertise. Santé, travail, environnement, E. Henry, C. Gilbert, J.-N. Jouzel, P. Marichalar (Eds)." Sociologie du travail 58, no. 3 (September 30, 2016): 338–40. http://dx.doi.org/10.4000/sdt.996.

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Дисертації з теми "Sociology, n.e.c"

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Ahern, J. M. "Radical hydroacylation of C-C and N-N double bonds in air." Thesis, University College London (University of London), 2011. http://discovery.ucl.ac.uk/1309819/.

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Анотація:
The formation of C-C and C-N bonds in modern organic synthesis is a key target for methodological advancement. Current methods of C-C and C-N bond formation often involve the use of expensive catalysts, or sub-stoichiometric reagents, which can lead to the generation of undesirable waste products. This thesis describes a novel and environmentally benign set of reaction conditions for the formation of C-C and C-N bonds by hydroacylation and this is promoted by mixing two reagents, an aldehyde and an electron-deficient double bond, under freely available atmospheric oxygen at room temperature Chapter 1 will provide an introduction to the thesis and mainly discusses methods for C-C bond formation, in particular, radical chemistry and hydroacylation. Chapter 2 describes the hydroacylation of vinyl sulfonates and vinyl sulfones (C-C double bonds) with aliphatic and aromatic aldehydes with a discussion and evidence for the mechanism of the transformation. Chapter 3 details the synthesis of precursors for intramolecular cyclisations and studies into aerobic intramolecular cyclisations. Chapter 4 describes the hydroacylation of vinyl phosphonates (C-C double bonds) and diazocarboxylates (N-N double bonds) with aliphatic and aromatic aldehydes bearing functional groups. In addition, the hydroacylation of diazocarboxylates with chiral aldehydes will be discussed. In conclusion, a new, facile and clean set of reaction conditions for the formation of C-C and C-N bonds has been developed via aerobic C-H activation of aldehydes providing access to unsymmetrical ketones.
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2

Qian, Xin. "Cobalt-Catalyzed C-C and C-N Coupling reactions." Phd thesis, Ecole Polytechnique X, 2013. http://pastel.archives-ouvertes.fr/pastel-00943479.

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Ce travail de these a permis le déveloippement de nouvelles reactions de couplage catalysées par des sels de cobalt(II) Le premier chapitre décrit l'allylation cobalta catalysée d'halogénures d'alkyles. La méthode est facile à mettre en œuvre, efficace avec une grande variété d'halogénures d'alkyes et des acétates ou carbonates d'allyle substitués. Les rendements vont de bons à excellents et la tolérance fonctionnelle élevée. Dans le cas d'acétates d'allyle substitués le produit linéaire est obtenu majoritairement ou exclusivement. Quelques expériences ont permis de mettre en lumière la formation d'espèce radicalaire lors du cycle catalytique. Les premiers essais pour étendre cette méthodologie aux couplages allyle-allyle et alkyle-alkyle sont également décrits. Le deuxième chapitre porte sur l'amination catalysée au cobalt d'organozinciques fonctionnalisés en utilisant des N-chloroamines. La procédure est simple et générale et demande des conditions plus douces que celles précédemment décrite, tout en tolérant un très large éventail de substrats, avec une bonne tolérance à de nombreux groupes fonctionnels. Les premiers essais pour étendre la méthodologie à la réaction entre un organozincique et une source électrophile de soufre en vue de former des liaisons C-S sont également exposés. Enfin le dernier chapitre décrit la réaction d'organozinciques engendrés par catalyse au cobalt avec une source " verte " de cyanure électrophile, N-cyano-N-phenyl-p-methyl-benzenesulfonamide (NCTS), pour conduire avec de bons rendements aux arylnitriles correspondants. Des sources analogues de CN+ ont également été testées.
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Simayi, Rena. "Synthesis and reaction chemistry of various N,N,C- and O,N,C- palladium pincer complexes." Thesis, University of Leicester, 2017. http://hdl.handle.net/2381/39392.

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In this thesis, the synthesis, characterisation and complexation chemistry of a series of related NNC and ONC pyridine based pincer ligands, together with some reaction chemistry of the metal complexes is described. The pro-ligands and the metal complexes have been characterised by a combination of multinuclear NMR spectroscopic techniques, IR spectroscopy, mass spectrometry and, for selected examples, by single crystal X-ray crystallography; remarkable spectroscopic and structural data are discussed. In Chapter 2, the synthesis and characterization of thirteen NNC and ONC pyridine based pincer ligands is described, including nine novel pincer ligands and four pyridine based pincers which have been previously reported. In Chapter 3, the palladium/platinum chemistry of NNCaryl and ONCaryl pyridine based pincer ligands is explored. Variation on the donor atoms has allowed an investigation of donor property influences on C-H activation, by giving peri-activated palladium pincer complexes for the ketimine-, aldimine-, amine- and biyridine-armed ligands and generating ortho-activated ONC palladium pincer complexes in the case of the alcohol-armed pro-ligand. Use of different palladium salts also led to different regioselective C-H activations. With the ketimine-armed naphthyl ligand (HL1ket-nap) as the example, the interconversion chemistry between the ortho- and peri-C-H activated products is also explored. In Chapter 4, sp3 C-H activation of the Et-armed ligand HL4Et with both palladium acetate and palladium chlorides has been unsuccessful, giving the N,N-coordinated bidentate species. The reaction of palladium acetate with the iPr-armed pro-ligand HL4iPr has resulted in minor amounts of C-H activated vinyl species with the major product being the non-activated palladium diacetate complex. Noticeably, upon reaction with Na2PdCl4, a mixture of the non-activated bis-chloride palladium complex and the sp3 C-H activated NNC-tridentate palladium species has been obtained, in a ratio of 1:1.5. Moreover, the sp3 C-H activation and the isolation of a rare sp3 C-H activated palladium complex have been achieved by reacting the tBu-armed pro-ligand HL4tBu with palladium acetate. The reaction of this ligand with Na2PdCl4 also resulted in the successful C-H activation of the tBu-arm to give a palladium pincer complex with a yield of 95%. Other than the NMR and FABMS analyses, the solid state X-ray structure of the latter complex confirmed the formation of the material as a rare sp3 C-H activated palladium complex. The stoichiometric reactivity of the (NNC/ONC)PdCl species towards AgBF4/AgPF6, and the subsequent ligand exchange reactions are disclosed in Chapter 5, together with the application of twelve palladium complexes as a series of promising catalysts in the allylic arylation of various allylic acetates with sodium tetraphenylborate.
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4

Huang, Xiaohua 1973. "Palladium-catalyzed C-C, C-N and C-O bond formation." Thesis, Massachusetts Institute of Technology, 2003. http://hdl.handle.net/1721.1/29639.

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Анотація:
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2003.
Vita.
Includes bibliographical references.
New methods for Pd-catalyzed cross-coupling reactions of aryl halides or arenesulfonates are described. Key to the success of these transformations is the proper choice of ligand and reaction conditions. Palladium catalysts supported by bulky, monodentate phosphine ligands with a biaryl backbone or the bidentate ligand, Xantphos, effectively promote the formation of ca-aryl carbonyl compounds. Base-sensitive functional groups are better tolerated when a weak base, such as K3PO4, is used. One of the most difficult transformations in Pd catalysis, the intermolecular C-O bond formation between primary alcohols and electron-neutral or even electron-rich aryl halides, was effectively promoted by the use of a new generation of ligands, 3-methyl-2-di-t-butylphosphinobiaryl. The one-step synthesis of ligands from cheap starting materials, as well as the mild reaction conditions employed for the coupling reactions, enables the practical use of Pd catalysis to access aryl alkyl ethers for the first time. Continuing study of Pd-catalyzed C-N bond-forming processes using biaryl monophosphine ligands led to the discovery of a structural derivative of these ligands, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl. This ligand, in combination with a Pd source, produces a catalyst system with both a greater degree of activity and of stability than those that use our previous ligands. Substrates that were not amenable to Pd catalysis previously are reexamined using this new catalyst system, and excellent results are obtained.
by Xiaohua Huang.
Ph.D.
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Cómbita, Merchán Diego Fernando. "Formación de enlaces C-C, C-N y N-N con catalizadores de óxido de cerio y de oro/óxido de cerio." Doctoral thesis, Universitat Politècnica de València, 2016. http://hdl.handle.net/10251/62780.

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[EN] Heterogeneous catalysis is one of the most important tools in the advancement of green chemistry, understood it as one that efficiently uses (preferably renewable) raw materials, eliminate waste and avoids the use of toxic and/or dangerous reagents and solvents in chemicals production and application. In this thesis we have investigated the reaction mechanisms and the nature of the active centers in C-C, C-N and N-N bond forming reactions over cerium oxide and over gold nanoparticles supported on cerium oxide heterogeneous catalysts. As C-C bond formation reaction, we had been studied Sonogashira reaction catalyzed by a heterogeneous Au/CeO2 catalyst, wherein the CeO2 nanoparticle is about 5 nm in diameter. The second part of the thesis comprises the study of C-N bonds formation during carbamoylation reaction between diaminotoluene and dimethyl carbonate, catalyzed by cerium oxide, studying the effect over the reaction of the crystal planes available for reactants adsorption. In a third part, the N-N bond formation in the reductive coupling reaction of nitrocompounds to obtain azocompounds was studied, using Au/CeO2 as heterogeneous catalyst. Also in this section we report, by first time, an active and selective heterogeneous catalyst for the Mills reaction between nitroso compounds and anilines to obtain symmetric and asymmetric azocompounds.
[ES] La catálisis heterogénea es una de las más importantes herramientas para el desarrollo de la Química Sostenible, entendida como aquella que utiliza eficientemente las materias primas (preferiblemente renovables), elimina los desechos y evita el uso de reactivos y solventes tóxicos y/o peligrosos en la manufactura y aplicación de los productos químicos. En esta tesis doctoral se han investigado los mecanismos de reacción y la naturaleza de los centros activos, en reacciones de formación de enlaces C-C, C-N, y N-N sobre catalizadores heterogéneos de óxido de cerio y de nanopartículas de oro soportadas en óxido de cerio. Como reacción de formación de enlaces C-C se ha estudiado la reacción de Sonogashira catalizada con un catalizador heterogéneo de Au/CeO2, en donde el CeO2 está en forma de nanopartículas de cerca de 5nm de diámetro. En la segunda parte de la tesis se profundiza en el estudio de la formación de enlaces C-N durante la reacción de carbamoilación del diaminotolueno con dimetilcarbonato catalizada por el óxido de cerio, estudiando el efecto que tiene sobre la reacción la naturaleza de los planos cristalinos disponibles para la adsorción de los reactivos. En una tercera parte se estudia la formación de enlaces N-N en la reacción de acoplamiento reductivo de nitrocompuestos para obtener azocompuestos en presencia de un catalizador heterogéneo de Au/CeO2. Es este mismo apartado se reporta por primera vez un catalizador heterogéneo de alta actividad y selectividad para la Reacción de Mills entre un nitrosocompuesto y una anilina para obtener azocompuestos simétricos y asimétricos.
[CAT] La catàlisi heterogènia és una de les ferramentes més importants per al desenvolupament de la Química Sostenible, entesa com aquella que utilitza eficientment les matèries pimes (preferiblement renovables), elimina els rebutjos i evita l'ús de reactius i dissolvents tòxics i/o perillosos en la manufactura i aplicació dels productes químics. En esta tesi doctoral s'han investigat els mecanismes de reacció i la natura dels centres actius, en reaccions de formació d'enllaços C-C, C-N i N-N sobre catalitzadors heterogenis d'òxid de ceri i nanopartícules d'or suportades en òxid de ceri. Com reacció de formació d'enllaços C-C s'ha estudiat la reacció de Sonogashira catalitzada amb un catalitzador heterogeni d'Au/CeO2, on el CeO2 està en forma de nanopartícules amb un diàmetre proper als 5nm. En la segona part de la tesi s'aprofundeix en l'estudi de la formació d'enllaços C-N durant la reacció de carbamilació del diaminotoluè amb dimetilcarbonat catalitzada per l'òxid de ceri, estudiant l'efecte que té sobre la reacció la natura dels plans cristal·lins disponibles per a l'adsorció dels reactius. En una tercera part s'estudia la formació d'enllaços N-N en la reacció d'acoblament reductiu de nitrocompostos per a obtenir azocompostos en presència d'un catalitzador heterogeni d'Au/CeO2. En aquest mateix apartat es reporta per primera vegada un catalitzador heterogeni d'alta activitat i selectivitat per a la Reacció de Mills entre un nitrocompost i una anilina per a obtenir azocompostos simètrics i asimètrics.
Cómbita Merchán, DF. (2016). Formación de enlaces C-C, C-N y N-N con catalizadores de óxido de cerio y de oro/óxido de cerio [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/62780
TESIS
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6

Roberts, Deborah Elizabeth. "Palladium N-neterocyclic carbene complexes as catalysts for C-N, C-Si and C-S bond formations." Thesis, University of Sussex, 2013. http://sro.sussex.ac.uk/id/eprint/45342/.

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This work is foremost a study of various palladium-bearing N-heterocyclic carbenes complexes and their catalytic potential to form C-N bonds. Both alkyl amination and aryl amination are considered. Further elucidation on the mechanism of such catalytic activity is investigated. The viability of alkyl amination using palladium complexes bearing the ligands, ITMe, 1,2,3,4- tetramethylimidazol-2-ylidene, and ICy, 1,3- bis-cyclohexylimidazol-2-ylidene, as catalysts, is investigated. This includes the synthesis of [Pd(ITMe)(neopentyl)Cl]2,[Pd(ITMe)2(neopentyl)Cl], [Pd(ITMe)(neopentyl)(tbutylamine)Cl], [Pd(ITMe)(neopentyl)(hexylamine)Cl], with successful elimination of the alkyl-amination reaction product in low yield from the latter complex. [Pd(ICy)(neopentyl)Cl]2, [Pd(ICy)2(neopentyl)Cl] are also isolated. Unsuccessful attempts were made to vary the electronic properties of the complexes by replacing the amine with a hydrazine. Work was also done on indirect alkylation using tBuLi which led to a new method for synthesis of [Pd(ItBu)2] and novel complex, [Pd(ItBu)Cl3. ItBuH] (ItBu = 1,3- bis-tertbutylimidazol-2-ylidene). Aryl amination catalysed by complexes of palladium bearing the ligand, ITMe, is considered. This includes an improved synthesis of [Pd(ITMe)2] and synthesis of [Pd(ITMe)2(anisole)Cl]. Unsuccessful attempts at the elucidation of the mechanism of [Pd(ITMe)2(anisole)] formation led to the unexpected formation of [Pd(ITMe)2(SiMe3)(Si(SiMe3)3)] and [Pd(ITMe)2(SiMe3)2]. Aryl amination with using [Pd(ITMe)2(SiMe3)2] led to two aryl amination products, 4-ortho-methoxyphenyl morpholine as well as the expected para isomer. The use of complexes [Pd(ItBu)2] and [Pd(SIPr)2] (SIPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) in C-S bond formation was explored. Addition of mesityl magnesium bromide to Pd(1,5-COD)Cl2 led to addition of mesityl substrate across 1,5-COD double bond and the addition of ITMe formed the Heck cycle intermediate [Pd(8-mesityl-1,4,5-η3 – C8H12)X2] (X=Cl, Br). Addition of 4-tolyl magnesium chloride resulting in the formation of Pd(ItBu)2(tolyl)Cl via an indirect route.
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7

Neal, Richard J. "The loosely-bound proton in ¹³N and the transfer reaction ¹¹B(¹³N,¹²C)¹²C." Thesis, University of Edinburgh, 1997. http://hdl.handle.net/1842/1783.

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The radioactive nucleus ¹³N (t½ = 10 min, Jπ = ½) contains one loosely bound proton (Sp = 1.94 MeV) which can be considered to be bound to a core of ¹²C. Taking advantage of the recent availability of beams of radioactive nuclei at Louvain-la-Neuve, Belgium, a beam of ¹³N has been used to investigate the transfer reaction ¹¹B(¹³N,¹²C)¹²C. Particle-γ coincidence data was taken, using the LEDA silicon strip array and BaF₂ modules, gating on the 15.11 MeV γ-decay from the T = 1 state in ¹²C*. Two final states, corresponding to ¹²Cgs + ¹²C*(15.11 MeV) and ¹²C*(4.44 MeV)+ ¹²C*(15.11 MeV) have been observed and angular distributions have been measured for both transitions at each of two beam energies, 29.5 MeV and 45 MeV. The results are discussed with special reference to the loosely bound nature of the valence proton in ¹³N; the transfer reaction has been modelled using a DWBA code, with the ¹³N ground state constructed as a mixture of states: a p½ proton bound to ¹²Cgs , or a p3/2 proton bound to ¹²C*₂₊ (4.44 MeV). Fits to the experimental data have been obtained using a very shallow set of optical potentials, which are found to be energy dependent. The agreement with experiment is good, with the exception of the ¹²C*(4.44)+¹²C*(15.11) transition at the lower beam energy, which is significantly underestimated by the calculations, suggesting a contribution from a different reaction mechanism.
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8

Ounaïes, Myriam. "Ensembles inévitables pour les applications holomorphes de C [exposant] n dans C [exposant] n." Toulouse 3, 1995. http://www.theses.fr/1996TOU30140.

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En une veriable complexe, l'image d'une fonction meromorphe evite au plus deux points de la sphere de rieman: c'est le theoreme de picard. De plus, grace a la theorie de nevanlinna, nous savons que chaque valeur est prise dans le disque de rayon r avec la meme frequence asymptotique sauf pour un ensemble denombrable de valeurs. En plusieurs variables, on observe un phenomene different. Il existe en effet des applications holomorphes, injectives, de c#n dans c#n dont l'image n'est pas dense dans c#n: ce sont les applications de fatou-bieberbach. Rosay et rudin ont montre qu'il existe pourtant des ensembles discrets qui doivent rencontrer l'image de toute application holomorphe non degeneree ; nous les appellerons ensembles inevitables. L. Gruman a construit explicitement une famille de tels ensembles e(a) parametres par a dans c*#n. Nous montrons que chaque ensemble e(a) est rencontre dans la boule de rayon r avec la meme frequence asymptotique pour tout a dans c*#n. Ceci constitue une sorte d'analogue a la theorie de nevanlinna en plusieurs variables
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9

Mudarra, Alonso Ángel Luis. "Coinage complexes in C-C and C-N bond-forming reactions." Doctoral thesis, Universitat Rovira i Virgili, 2020. http://hdl.handle.net/10803/670357.

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Els complexos organometàl·lics de coure, plata i or juguen un paper fonamental com espècies reactives en diverses transformacions químiques. Aquesta tesi aporta coneixement sobre el comportament d’aquests complexos en la formació d’enllaços C-C i/o C-N. En concret, estudiem: i) el mecanisme de reacció a través del qual els complexos de coure co-catalitzen un acoblament oxidant en el context de sistemes bimetàl·lics de rodi i coure; ii) el potencial de nucleòfils de plata com a agents transmetal·lants en reaccions de trifluorometilació catalitzades per pal·ladi; iii) el mecanisme de reacció de sistemes bimetàl·lics de Pd/Ag emprant un sistema model; i iv) el comportament de complexos bis(trifluorometil) cuprat, argentat i aurat com a nucleòfils. En aquesta tesi, on s´han combinat estudis experimentals i computacionals, s’ha adquirit nou coneixement sobre els processos estudiats, i s’ha contribuït al camp de la recerca química basada en el coneixement.
Los complejos organometálicos de cobre, plata y oro juegan un papel fundamental como especies reactivas en diversas transformaciones químicas. Esta tesis aporta conocimiento sobre el comportamiento de estos complejos en la formación de enlaces C-C y/o C-N. En concreto, estudiamos: i) el mecanismo de reacción por el cual complejos de cobre co-catalizan un acoplamiento oxidante en el contexto de sistemas bimetálicos de rodio y cobre; ii) el potencial de nucleófilos de plata como agentes transmetalantes en reacciones de trifluorometilación catalizadas por paladio; iii) el mecanismo de reacción de sistemas bimetálicos de Pd/Ag usando un sistema modelo; y iv) el comportamiento de complejos bis(trifluorometil) cuprato, argentato y aurato como nucleófilos. En esta tesis, donde se han combinado estudios experimentales y computacionales, se ha adquirido nuevo conocimiento sobre los procesos estudiados, y se ha contribuido al campo de la investigación química basada en el conocimiento.
Organometallic coinage metal complexes are be key reactive species for promoting a wide variety of chemical transformations. This thesis improves the understanding the behavior of these complexes in relevant C-C and/or C-N bond-forming reactions. Specifically, we have explored: i) the mechanistic intricacies of copper species as co-catalyst in the context of rhodium/copper-catalyzed oxidative coupling reactions; ii) the capability of silver nucleophiles as transmetalating agents in palladium-catalyzed trifluoromethylation reactions; iii) the reaction mechanism of Pd/Ag bimetallic reactions using a model system as probe; and, iv) the study of bis(trifluoromethyl) coinage metallates as nucleophiles. The fundamental insights gathered in this Thesis, encompassing both experimental and computational approaches, improve our understanding of the processes under study and make a contribution to the general field of knowledge-driven research in Chemistry.
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Kanuru, Vijaykumar. "Understanding surface mediated C-C and C-N bond forming reactions." Thesis, University of Cambridge, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.608956.

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Книги з теми "Sociology, n.e.c"

1

Souci, Robert D. San. N. C. Wyeth's pilgrims. San Francisco: Chronicle books, 1991.

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Weyn, Suzanne. The N-C zone. New York, NY: Macmillan McGraw-Hill, 1998.

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i, Hung Kha. Khu c tie u ai oa n: Truye n kich. [s.l.]: ♯o i Nay, 1988.

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Va n Xua n Nhi Ho . Ho n em hanh phu c: Ta p truye n. Los Alamitos, Calif: Xua n Thu, 1988.

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Anh, Phan. Con lo c ©ʻoi: Tuye n ta p truye n. Los Alamitos, Calif: Xua n Thu, 1987.

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Shubin, V. G. A N C: A view from Moscow. Bellville, South Africa: Mayibuye, 1999.

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7

Tran, Tieu. Ky u c cua con ve n. Glendale, Ca: Dai Nam, 1987.

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Binh Nguye n. Lo c. Ky tha c: Ta p truye n. Westminster, Calif: Va n Nghe, 1986.

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9

Burdick, Michael. C 'N' P. AuthorHouse, 2006.

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10

Publishing, RH Value. N C Wyeth. Random House Value Publishing, 1988.

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Частини книг з теми "Sociology, n.e.c"

1

Aggarwal, P., and M. W. P. Bebbington. "Fragments N—N, C—C, C—N." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-117-00227.

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Aggarwal, P., and M. W. P. Bebbington. "Fragment C—C—N—N—C—N." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-117-00242.

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Aggarwal, P., and M. W. P. Bebbington. "Fragment C—N—C—C—N—N." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-117-00244.

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4

Lindsley, C. W., and M. E. Layton. "Fragment N—C—N—C—C—N." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-00676.

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Lindsley, C. W., and M. E. Layton. "Fragment N—N—C—N—C—C." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-00680.

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6

Lindsley, C. W., and M. E. Layton. "Fragment C—C—N—N—C—N." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-00683.

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Lindsley, C. W., and M. E. Layton. "Fragment N—C—C—N—N—C." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-00686.

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8

von Angerer, S. "Fragment N—C—N—C—N—C." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-00796.

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9

Bohle, M. "Fragment C—N—N—C—N—N." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-00955.

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10

"N." In Dictionary of Sociology, 164–72. Routledge, 2012. http://dx.doi.org/10.4324/9780203058787-18.

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Тези доповідей конференцій з теми "Sociology, n.e.c"

1

Davis, Philip, Stewart Novick, Stephen Kukolich, Adam Daly, Kexin Li, Ian Dorell, and Lu Kang. "THE ROTATIONAL SPECTRA OF CYANOACETYLENE DIMER, H-C-C-C-N ••• H-C-C-C-N." In 71st International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2016. http://dx.doi.org/10.15278/isms.2016.wa09.

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Jenkins, Elizabeth E., and Marvin L. Marshak. "Large N[sub c]." In 10TH CONFERENCE ON THE INTERSECTIONS OF PARTICLE AND NUCLEAR PHYSICS. AIP, 2009. http://dx.doi.org/10.1063/1.3293846.

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3

Polo-Ces, Paula, Pablo Frieiro-Gomis, Fátima Lucio-Martínez, Paula Munín, Pablo Romarís, M. Pereira, and J. Vila. "Palladacycles derivates of diimines ligands [N,C,C,N]." In The 21st International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04760.

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Menga, Davide, and Tim Fellinger. "Fe-N-C electrocatalysts synthesized from Zn-N-C materials via an imprinting strategy." In Materials for Sustainable Development Conference (MAT-SUS). València: FUNDACIO DE LA COMUNITAT VALENCIANA SCITO, 2022. http://dx.doi.org/10.29363/nanoge.nfm.2022.270.

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5

Georgier, Georgi Nikolov, and Mariana Nikolova Georgiera-Grosse. "Theorem for the relation between the L1(c, n) and L2(c,ρ, n) numbers." In 2014 XXXIth URSI General Assembly and Scientific Symposium (URSI GASS). IEEE, 2014. http://dx.doi.org/10.1109/ursigass.2014.6929203.

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6

Jakes, P. "Synthesis and EPR studies of N@C[sub 60] and N@C[sub 70] radical anions." In The 14th international winterschool on electronic properties of novel materials - molecular nanostructures. AIP, 2000. http://dx.doi.org/10.1063/1.1342493.

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7

Arini, Yeni, and Siti Irene Astuti Dwiningrum. "E-Learning on the Subject of Sociology in SMA N 1 Yogyakarta." In Proceedings of the International Conference of Ethics on Business, Economics, and Social Science (ICEBESS 2018). Paris, France: Atlantis Press, 2019. http://dx.doi.org/10.2991/icebess-18.2019.5.

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8

Plank, W. "Thermal stability of the heterofullerene (C[sub 59]N)X for X=C[sub 59]N,H." In ELECTRONIC PROPERTIES OF MOLECULAR NANOSTRUCTURES: XV International Winterschool/Euroconference. AIP, 2001. http://dx.doi.org/10.1063/1.1426811.

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9

Lingyun Li, Junqing Li, Shengxian Xie, and Huishan Yu. "The implications between C-SPR and CRn (n′, n) visited." In 2012 IEEE 14th International Conference on Communication Technology (ICCT). IEEE, 2012. http://dx.doi.org/10.1109/icct.2012.6511314.

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10

Weidinger, A., B. Pietzak, M. Waiblinger, K. Lips, B. Nuber, and A. Hirsch. "Study of N@C[sub 60] and P@C[sub 60]." In The 12th international winterschool on electronic properties of novel materials: progress in molecular nanostructures. AIP, 1998. http://dx.doi.org/10.1063/1.56478.

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Звіти організацій з теми "Sociology, n.e.c"

1

Gland, J. L. Hydrogen induced C-C, C-N, and C-S bond activation on Pt and Ni surfaces. Office of Scientific and Technical Information (OSTI), December 1992. http://dx.doi.org/10.2172/10102894.

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2

Gland, J. L. Hydrogen induced C-C, C-N, and C-S bond activation on Pt and Ni surfaces. Office of Scientific and Technical Information (OSTI), January 1992. http://dx.doi.org/10.2172/6915688.

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3

Gland, J. L. Hydrogen Induced C-C, C-N, & C-S Bond Activation on Pt & Ni Surfaces. Office of Scientific and Technical Information (OSTI), July 2004. http://dx.doi.org/10.2172/830711.

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4

Gland, J. L. [Hydrogen induced C-C, C-N, and C-S bond activities on Pi and Ni surfaces]: Summary. Office of Scientific and Technical Information (OSTI), December 1994. http://dx.doi.org/10.2172/10110807.

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5

Friend, J. P. High-speed tapping for N/C machining centers. Office of Scientific and Technical Information (OSTI), November 1991. http://dx.doi.org/10.2172/6114424.

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6

Ball, J. Timothy. Running Title: C and N Allocation in Pine. Office of Scientific and Technical Information (OSTI), December 1996. http://dx.doi.org/10.2172/762784.

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7

Joyner, Rex W. Diffractive Processes in 200-GeV/c $\pi^- N \to \pi^- \pi^- \pi^+ N$ Interactions. Office of Scientific and Technical Information (OSTI), August 1987. http://dx.doi.org/10.2172/1433220.

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Karl, G., and H. J. Lipkin. Flavor symmetry in the large N{sub c} limit. Office of Scientific and Technical Information (OSTI), December 1991. http://dx.doi.org/10.2172/10107252.

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9

Karl, G., and H. J. Lipkin. Flavor symmetry in the large N sub c limit. Office of Scientific and Technical Information (OSTI), January 1991. http://dx.doi.org/10.2172/6138160.

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McGuigan, M., and C. B. Thorn. Quark-antiquark Regge trajectories in large N{sub c}QCD. Office of Scientific and Technical Information (OSTI), July 1992. http://dx.doi.org/10.2172/10155611.

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