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Статті в журналах з теми "Reductive reactions"
Koóš, Peter, Martin Markovič, Pavol Lopatka, and Tibor Gracza. "Recent Applications of Continuous Flow in Homogeneous Palladium Catalysis." Synthesis 52, no. 23 (August 3, 2020): 3511–29. http://dx.doi.org/10.1055/s-0040-1707212.
Повний текст джерелаNicholas, Kenneth M., and Chandrasekhar Bandari. "Deoxygenative Transition-Metal-Promoted Reductive Coupling and Cross-Coupling of Alcohols and Epoxides." Synthesis 53, no. 02 (October 7, 2020): 267–78. http://dx.doi.org/10.1055/s-0040-1707269.
Повний текст джерелаDutta, Lona, Atanu Mondal, and S. S. V. Ramasastry. "Metal‐Free Reductive Aldol Reactions." Asian Journal of Organic Chemistry 10, no. 4 (March 10, 2021): 680–91. http://dx.doi.org/10.1002/ajoc.202000693.
Повний текст джерелаPal, Sudipta, You-Yun Zhou, and Christopher Uyeda. "Catalytic Reductive Vinylidene Transfer Reactions." Journal of the American Chemical Society 139, no. 34 (August 17, 2017): 11686–89. http://dx.doi.org/10.1021/jacs.7b05901.
Повний текст джерелаLin, Ivan J. B., Hayder A. Zahalka, and Howard Alper. "Rhodium catalyzed reductive esterification reactions." Tetrahedron Letters 29, no. 15 (January 1988): 1759–62. http://dx.doi.org/10.1016/s0040-4039(00)82035-3.
Повний текст джерелаAnderson, James C., Alexander J. Blake, Paul J. Koovits, and Gregory J. Stepney. "Diastereoselective Reductive Nitro-Mannich Reactions." Journal of Organic Chemistry 77, no. 10 (May 2, 2012): 4711–24. http://dx.doi.org/10.1021/jo300535h.
Повний текст джерелаWerth, Jacob, Kristen Berger, and Christopher Uyeda. "Cobalt Catalyzed Reductive Spirocyclopropanation Reactions." Advanced Synthesis & Catalysis 362, no. 2 (November 22, 2019): 348–52. http://dx.doi.org/10.1002/adsc.201901293.
Повний текст джерелаWang, Zhipeng A., Yan-Yu Liang, and Ji-Shen Zheng. "Reductive Amination/Alkylation Reactions: The Recent Developments, Progresses, and Applications in Protein Chemical Biology Studies." Current Organic Synthesis 15, no. 6 (August 29, 2018): 755–61. http://dx.doi.org/10.2174/1570179415666180522093905.
Повний текст джерелаPaterson, Lorna A., Sandra E. Hill, John R. Mitchell, and John M. V. Blanshard. "Sulphite and oxidative—reductive depolymerization reactions." Food Chemistry 60, no. 2 (October 1997): 143–47. http://dx.doi.org/10.1016/s0308-8146(95)00253-7.
Повний текст джерелаDonohoe, Timothy J., Karl W. Ace, Paul M. Guyo, Madeleine Helliwell, and Jeffrey McKenna. "Reductive aldol reactions on aromatic heterocycles." Tetrahedron Letters 41, no. 7 (February 2000): 989–93. http://dx.doi.org/10.1016/s0040-4039(99)02224-8.
Повний текст джерелаДисертації з теми "Reductive reactions"
Rodrigo, Sanjeewa K. "Nickel Catalyzed Regioselective Reductive Coupling Reactions." University of Cincinnati / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1396532622.
Повний текст джерелаBörjesson, Carazo Marino Rolando. "Ni-Catalyzed Reductive Carboxylation Reactions with Carbon Dioxide." Doctoral thesis, Universitat Rovira i Virgili, 2020. http://hdl.handle.net/10803/670249.
Повний текст джерелаEl principal gas de efecto invernadero emitido debido al desarrollo industrial de nuestra sociedad es el dióxido de carbono. Como consecuencia, los últimos años han sido testigos del desarrollo de procesos para la fijación de CO2 en moléculas orgánicas. Aunque la utilización química del CO2 probablemente no reducirá drásticamente su concentración en la atmósfera, su bajo costo y alta disponibilidad podrían ayudar a reemplazar algunos de los procesos industriales establecidos que contribuyen al cambio climático. En particular, el grupo carboxilo está presente en una gran cantidad de productos farmacéuticos, agroquímicos o plásticos, entre otros, lo que hace que su síntesis sea un objetivo ideal para la utilización de CO2. A diferencia de las carboxilaciones tradicionales de reactivos organometálicos sensibles altamente polarizados, las reacciones de carboxilación reductora ofrecen la posibilidad de emplear electrófilos simples, que representan una formidable alternativa, conceptualidad y practicidad a un lado, para tales entidades nucleofílicas. Estos estudios de doctorado se han centrado en el desarrollo y la comprensión de reacciones de carboxilaciones reductoras nuevas, simples y prácticas para producir ácidos carboxílicos a partir de electrófilos económicos y abundantes mediante catálisis de Níquel.
The primary greenhouse gas emitted due to the industrial development of our society is carbon dioxide. As a consequence, the recent years have witnessed the development of processes for the fixation of CO2 into organic molecules. Although the chemical utilization of CO2 will most likely not dramatically reduce its concentration in the atmosphere, its low cost and high availability could potentially help replace some of the established industrial processes that contribute to climate change. In particular, the carboxylic acid motif is present on a myriad of pharmaceuticals, agrochemicals or plastics, among others, making their synthesis an ideal target for CO2 chemical utilization. Unlike traditional carboxylations of highly polarized, sensitive organometallic reagents, reductive carboxylation reactions offer the possibility to employ simple electrophiles, representing a formidable alternative, conceptuality and practicality aside, to such nuclephilic entities. These doctoral studies have focused on the development and understanding of new, simple and practical reductive carboxylations reactions to produce carboxylic acids from inexpensive and abundant electrophiles by means of Ni-catalysis.
Serrano, Robledo Eloísa Sofía. "Amide Formation via Ni-Catalyzed Reductive Coupling Reactions with Isocyanates." Doctoral thesis, Universitat Rovira i Virgili, 2018. http://hdl.handle.net/10803/586084.
Повний текст джерелаRecientemente, las reacciones de acoplamiento cruzado entre electrófilos se han posicionado como potentes alternativas a las reacciones clásicas de acoplamiento cruzado entre electrófilos orgánicos y nucleófilos organometálicos. Dichos acoplamientos reductivos ofrecen numerosas ventajas, ya que utilizan compuestos de partida simples y fácilmente asequibles que evitan la necesidad de sintetizar especies organometálicas sensibles a la humedad y al oxígeno. Debido a ello, los protocolos experimentales son prácticos y las condiciones de reacción suaves. La ubiquidad de las amidas en moléculas biológicamente activas tales como péptidos, agroquímicos y productos farmacéuticos, así como en materiales sintéticos, impulsa continuamente el desarrollo de nuevos métodos para la síntesis eficiente de amidas. La presente Tesis Doctoral, se centra en el desarrollo de nuevos acoplamientos reductivos cruzados catalizados por níquel para la síntesis de amidas, utilizando isocianatos como el sintón correspondiente a la amida. Específicamente, se presenta un nuevo protocolo para la síntesis de amidas alifáticas a partir de bromuros de alquilo primarios, secundarios y terciarios en combinación con isocianatos de arilo y alquilo. Asimismo, se incluye el desarrollo de una metodología para la hidroamidación altamente diastereoselectiva de alquinos con isocianatos para la formación de acrilamidas. Dicho protocolo utiliza bromuros de alquilo como fuentes suaves para la formación de hidruros in situ. Finalmente, se discuten resultados preliminares sobre la amidación regiodivergente, retentiva y remota, de bromuros de alquilo secundarios inactivados. Las transformaciones desarrolladas aquí constituyen nuevos métodos para la síntesis de amidas mediante la formación de enlaces C-C catalizada por metales y se caracterizan por sus condiciones suaves, su amplio alcance de reacción, su excelente regioselectividad y alta tolerancia a diversos grupos funcionales.
Recently, cross-electrophile couplings have become powerful alternatives to classical cross-coupling reactions that are based on nucleophile/electrophile regimes. Starting from readily available building blocks, reductive couplings are practical and mild protocols that circumvent the use of moisture and air-sensitive organometallic species. The ubiquity of amides in biologically relevant molecules such as peptides, agrochemicals and pharmaceuticals, as well as in polymers, continually prompts the design of novel methods for amide synthesis. This Doctoral Thesis focuses on the development of novel nickel-catalyzed reductive protocols for the synthesis of amides using isocyanates as the amide synthon. Specifically, we have discovered a novel protocol for the synthesis of aliphatic amides from primary, secondary and tertiary alkyl bromides in combination with aryl and alkyl isocyanates. A methodology for the highly diastereoselective hydroamidation of alkynes with isocyanates to afford acrylamides has been developed, with alkyl bromides used as in situ and mild hydride sources. Finally, efforts towards the regiodivergent retentive and chain-walking amidation of unactivated acyclic secondary alkyl bromides are discussed. The transformations developed herein are characterized by their mild conditions, wide substrate scope and excellent chemo- and regioselectivity, and constitute novel methods for the formation of amides via metal-catalyzed C—C bond formation.
Joensuu, Pekka Matias. "Development of catalytic stereoselective reductive aldol reactions." Thesis, University of Edinburgh, 2008. http://hdl.handle.net/1842/2576.
Повний текст джерелаGallagher, P. "The reductive decomposition of bis-diazo-alkanes." Thesis, University of Liverpool, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.381343.
Повний текст джерелаMc, Geehin Peter Kevin Mark. "Hydrogenation, hydrogenolysis and reductive fission reactions of cis dihydrodiols." Thesis, Queen's University Belfast, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252284.
Повний текст джерелаChakraborty, Satyajit. "Studies on oxidative and reductive reactions of carbocyclic compounds." Thesis, University of North Bengal, 1988. http://hdl.handle.net/123456789/709.
Повний текст джерелаFung, Chi-ming Kelvin. "Synthesis and applications of copper hydride complexes in reductive reactions." Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B36388208.
Повний текст джерелаFung, Chi-ming Kelvin, and 馮志明. "Synthesis and applications of copper hydride complexes in reductive reactions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2005. http://hub.hku.hk/bib/B36388208.
Повний текст джерелаMendiratta, Arjun. "Reductive coupling and related reactions with Mo and Ti tris- anilides." Thesis, Massachusetts Institute of Technology, 2005. http://hdl.handle.net/1721.1/32483.
Повний текст джерелаVita.
Includes bibliographical references.
Chapter 1: The capability of Mo(N[t-BulAr)₃ to act as a powerful one, two, and three electron reductant have been previously demonstrated. In this work, we show that Mo(NIt-BulAr)₃ forms a metastable adduct with the moderate [pi] acid PhCN; coordination of PhCN activates the nitrile carbon towards reaction with a variety of one-electron reagents such as dichalcogenides, nitric oxide, hydrogen atom donors, cobaltocene, and elemental phosphorus. Evidence is presented for the existence of an inner-sphere electron transfer mechanism for these reactions. Chapter 2: With the facile cleavage of N₂ by Mo(Njt-Bu]Ar)₃ already established, a Mo(NIt-Bu]Ar)₃-mediated process for the incorporation of N₂ into organic molecules is an exciting prospect; its realization depends critically on the development of methods for cleavage of the Mo-N bond formed in the early stages of the process. In this chapter, we demonstrate that appropriately-substituted Mo(IV) ketiminates (synthesized using the methods of Chapter 1) undergo [beta]-elimination to cleave the Mo-N bond and liberate PhCN. We present the kinetics of the reaction, substituent effects, and-in three cases - activation parameters. Chapter 3: Deprotonation of the titanium formate complex (ArIt-BuJN)₃TiOC(O)H with LiN(i-Pr)₂ resulted in the release of free CO and the formation of a titanium(IV) oxoanion complex, isolated as its lithium salt. Chapter 4: Previous work from these labs has shown that the unique combination of well-defined composition, steric bulk, and strong reducing ability embodied in Ti(N[t- Bu]Ar)₃ lends itself particularly well to mechanistic studies of the classical Pinacol coupling.
(cont.) As shown in Chapter 1, a similar relationship can be drawn between Mo(NIt- BulAr)₃ and reductive nitrile coupling. In this chapter we draw on this mechanistic understanding to develop three new classes of reductive cross-couplings: nitrile is coupled with pyridine to form dihydropyridines, with benzophenone to form substituted 1,4-cyclohexadienes, and with carbon dioxide to form a-iminocarboxylates.
by Arjun Mendiratta.
Ph.D.
Книги з теми "Reductive reactions"
Henderson, Richard A. The mechanisms of reactions at transition metal sites. Oxford: Oxford University Press, 1997.
Знайти повний текст джерелаUnited States. National Aeronautics and Space Administration., ed. Final report...for heterogeneous photocatalytic oxidation of atmospheric trace contaminants. [Washington, D.C: National Aeronautics and Space Administration, 1994.
Знайти повний текст джерелаUnited States. National Aeronautics and Space Administration., ed. Final report...for heterogeneous photocatalytic oxidation of atmospheric trace contaminants. [Washington, D.C: National Aeronautics and Space Administration, 1994.
Знайти повний текст джерелаW, Rees Charles, ed. Electron transfer reactions in organic chemistry. Berlin: Springer-Verlag, 1987.
Знайти повний текст джерела1946-, Isied Stephan S., ed. Electron transfer reactions: Inorganic, organometallic, and biological applications. Washington, DC: American Chemical Society, 1997.
Знайти повний текст джерелаProusek, Josef. Reakce iniciované přenosem elektronu. Praha: Academia, 1988.
Знайти повний текст джерелаHumiston, T. J. Production-scale direct oxide reduction demonstration. Edited by Santi D. J, Long J. L, Rockwell International. Rocky Flats Plant, and United States. Dept. of Energy. Albuquerque Operations Office. Golden, Colo: Rockwell International, Aerospace Operations, Rocky Flats Plant, 1989.
Знайти повний текст джерела1936-, Balzani Vincenzo, ed. Electron transfer in chemistry. Weinheim: Wiley-VCH, 2001.
Знайти повний текст джерелаOrganic redox systems: Synthesis, properties, and applications. Hoboken, New Jersey: John Wiley & Sons, 2016.
Знайти повний текст джерелаGeoghegan, Susan M. Modulating the redox propertoes of a flavoprotein; cloning, expression and site-directed mutagenesis of flavodoxin from M. elsdenii. Dublin: University College Dublin, 1997.
Знайти повний текст джерелаЧастини книг з теми "Reductive reactions"
Li, Jie Jack. "Borch reductive amination." In Name Reactions, 66–67. Cham: Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_32.
Повний текст джерелаLi, Jie Jack. "Borch reductive amination." In Name Reactions, 58–59. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_28.
Повний текст джерелаBalch, A. L. "Reductive Procedures." In Inorganic Reactions and Methods, 98–99. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch82.
Повний текст джерелаGras, J. L. "Reductive Hydrolysis." In Inorganic Reactions and Methods, 206–7. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch65.
Повний текст джерелаAtwood, David A. "Reductive Elimination Reactions." In Inorganic Reactions and Methods, 183–84. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch179.
Повний текст джерелаLi, Jie Jack. "Eschweiler–Clarke Reductive Amination." In Name Reactions, 182–85. Cham: Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_48.
Повний текст джерелаBeller, Matthias, and Xiao Feng Wu. "Reductive Carbonylations." In Transition Metal Catalyzed Carbonylation Reactions, 53–64. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-39016-6_3.
Повний текст джерелаDräger, M., and N. Kleiner. "By Reductive Processes." In Inorganic Reactions and Methods, 104–5. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145234.ch74.
Повний текст джерелаBalch, A. L. "Binuclear Reductive Elimination." In Inorganic Reactions and Methods, 95. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch76.
Повний текст джерелаLi, Jie Jack. "Clarke-Eschweiler reductive alkylation of amines." In Name Reactions, 76. Berlin, Heidelberg: Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_62.
Повний текст джерелаТези доповідей конференцій з теми "Reductive reactions"
Paz, Manuel. "The Reactions of Mitomycin C with Dithiols I. Reductive Activation." In The 14th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2010. http://dx.doi.org/10.3390/ecsoc-14-00482.
Повний текст джерелаZhang, Chun-Lin, De-Chang Liu, and Han-Ping Chen. "The Effects of Heterogeneous Reactions on the Reduction of NO in Petroleum-Coke-Fired Fluidized Beds." In 18th International Conference on Fluidized Bed Combustion. ASMEDC, 2005. http://dx.doi.org/10.1115/fbc2005-78085.
Повний текст джерелаDe Oliveira Vigier, Karine, Christophe Coutanceau, and Steve Baranton. "Electro-oxidation of glycerol and diglycerol in the presence of Pt or Pd-based electrocatalyst follows by the reductive amination of the products obtained." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/olba8004.
Повний текст джерелаManovic, Vasilije, and Borislav Grubor. "An Improved Model of Sulfur Self-Retention by Coal Ash During Coal Combustion in FBC." In 18th International Conference on Fluidized Bed Combustion. ASMEDC, 2005. http://dx.doi.org/10.1115/fbc2005-78020.
Повний текст джерелаContou-Carrere, M. N., and P. Daoutidis. "Model reduction for reaction-convection processes with fast and slow reactions." In 2003 European Control Conference (ECC). IEEE, 2003. http://dx.doi.org/10.23919/ecc.2003.7086549.
Повний текст джерелаMazumder, Sandip, and Ankan Kumar. "The In Situ Adaptive Tabulation (ISAT) Algorithm for Reacting Flow Computations With Complex Surface Chemistry." In ASME 2013 Heat Transfer Summer Conference collocated with the ASME 2013 7th International Conference on Energy Sustainability and the ASME 2013 11th International Conference on Fuel Cell Science, Engineering and Technology. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/ht2013-17694.
Повний текст джерелаBach, Fr W., Z. Babiak, T. Duda, T. Rothgardt, and G. Tegeder. "Impact of Self Propagating High Temperature Synthesis of Spraying Materials on Coatings Based on Aluminium and Metal-Oxides." In ITSC2001, edited by Christopher C. Berndt, Khiam A. Khor, and Erich F. Lugscheider. ASM International, 2001. http://dx.doi.org/10.31399/asm.cp.itsc2001p0497.
Повний текст джерелаObertelli, A. "Shell Gap Reduction In Exotic N = 17 Nuclei." In FRONTIERS IN NUCLEAR STRUCTURE, ASTROPHYSICS, AND REACTIONS - FINUSTAR. AIP, 2006. http://dx.doi.org/10.1063/1.2200921.
Повний текст джерелаKuznetsov, Vladmir V., Oleg V. Vitovsky, and Stanislav P. Kozlov. "Heat and Mass Transfer With Chemical Reactions Producing Hydrogen in Microchannels." In ASME 2011 9th International Conference on Nanochannels, Microchannels, and Minichannels. ASMEDC, 2011. http://dx.doi.org/10.1115/icnmm2011-58203.
Повний текст джерелаYASHIRO, Y., H. TAKAHASHI, N. YAMASAKI, and T. KORI. "ORGANIC COMPOUND SYNTHESIS FROM CARBON DIOXIDE BY HYDROTHERMAL REDUCTION." In Proceedings of the Seventh International Symposium on Hydrothermal Reactions. WORLD SCIENTIFIC, 2003. http://dx.doi.org/10.1142/9789812705228_0004.
Повний текст джерелаЗвіти організацій з теми "Reductive reactions"
Berry, John. Novel Homogeneous Electrocatalysts for the Nitrogen Reduction Reaction. Office of Scientific and Technical Information (OSTI), October 2020. http://dx.doi.org/10.2172/1670696.
Повний текст джерелаSchlautman, Mark A. Optimizing Metalloporphyrin-Catalyzed Reduction Reactions for In Situ Remediation of DOE Contaminants. Office of Scientific and Technical Information (OSTI), July 2013. http://dx.doi.org/10.2172/1087345.
Повний текст джерелаScott C. Brooks, Wenming Dong, Sue Carroll, Jim Fredrickson, Ken Kemner, and Shelly Kelly. Aqueous Complexation Reactions Governing the Rate and Extent of Biogeochemical U(VI) Reduction. Office of Scientific and Technical Information (OSTI), June 2006. http://dx.doi.org/10.2172/895942.
Повний текст джерелаScott C. Brooks, Wenming Dong, Sue Carroll, James K. Fredrickson, Kenneth M. Kemner, and Shelly D. Kelly. Aqueous Complexation Reactions Governing the Rate and Extent of Biogeochemical U(VI) Reduction. Office of Scientific and Technical Information (OSTI), June 2006. http://dx.doi.org/10.2172/896202.
Повний текст джерелаKemner, K. M., S. D. Kelly, Scott C. Brooks, Wenming Dong, Sue Carroll, and James K. Fredrickson. Aqueous complexation reactions governing the rate and extent of biogeochemical U(VI) reduction. Office of Scientific and Technical Information (OSTI), June 2006. http://dx.doi.org/10.2172/896239.
Повний текст джерелаNeta, P. Redox Reactions of Metalloporphyrins and their Role in Catalyzed Reduction of Carbon Dioxide. Office of Scientific and Technical Information (OSTI), September 2002. http://dx.doi.org/10.2172/836561.
Повний текст джерелаBurgos, William D., Eric E. Roden, and Gour-Tsyh Yeh. Reaction-Based Reactive Transport Modeling of Fe(III) and U(V) Reduction. Office of Scientific and Technical Information (OSTI), June 2005. http://dx.doi.org/10.2172/893413.
Повний текст джерелаLang, Mark, and Douglas Shackelford. Capitalization of Capital Gains Taxes: Evidence from Stock Price Reactions to the 1997 Rate Reduction. Cambridge, MA: National Bureau of Economic Research, January 1999. http://dx.doi.org/10.3386/w6885.
Повний текст джерелаPeng, Ciyan, Jing Chen, Sini Li, and Jianhe Li. Comparative Efficacy of Chinese Herbal Injections Combined Western medicine for Non-small cell lung cancer: A Bayesian Network Meta-Analysis of randomized controlled trials. INPLASY - International Platform of Registered Systematic Review and Meta-analysis Protocols, November 2021. http://dx.doi.org/10.37766/inplasy2021.11.0068.
Повний текст джерелаAdzic, Radoslav, and Michael Furey. Develop Novel Pt Monolayer Electrocatalysts to Facilitate Oxygen Reduction Reaction (ORR) for PEM Fuel Cells. Office of Scientific and Technical Information (OSTI), August 2013. http://dx.doi.org/10.2172/1095905.
Повний текст джерела