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Автор: Grafiati
Опубліковано: 11 березня 2023

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Статті в журналах з теми "Polymers brushes"

1

Boyes, Stephen G., Anthony M. Granville, Marina Baum, Bulent Akgun, Brian K. Mirous, and William J. Brittain. "Polymer brushes––surface immobilized polymers." Surface Science 570, no. 1-2 (October 2004): 1–12. http://dx.doi.org/10.1016/j.susc.2004.06.193.

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2

Chu, Elza, Tashnia Babar, Michael F. Bruist, and Alexander Sidorenko. "Binary Polymer Brushes of Strongly Immiscible Polymers." ACS Applied Materials & Interfaces 7, no. 23 (February 10, 2015): 12505–15. http://dx.doi.org/10.1021/am5080248.

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3

Gong, Shuting, Tianyi Wang, Jiaping Lin, and Liquan Wang. "Patterning of Polymer-Functionalized Nanoparticles with Varied Surface Mobilities of Polymers." Materials 16, no. 3 (February 1, 2023): 1254. http://dx.doi.org/10.3390/ma16031254.

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Анотація:
The polymers can be either dynamically tethered to or permanently grafted to the nanoparticle to produce polymer-functionalized nanoparticles. The surface mobility of polymer ligands with one end anchored to the nanoparticle can affect the surface pattern, but the effect remains unclear. Here, we addressed the influence of lateral polymer mobility on surface patterns by performing self-consistent field theory calculations on a modeled polymer-functionalized nanoparticle consisting of immobile and mobile brushes. The results show that except for the radius of nanoparticles and grafting density, the fraction of mobile brushes substantially influences the surface patterning of polymer-functionalized nanoparticles, including striped patterns and patchy patterns with various patches. The number of patches on a nanoparticle increases as the fraction of mobile brushes decreases, favored by the entropy of immobile brushes. Critically, we found that broken symmetry usually occurs in patchy nanoparticles, associated with the balance of enthalpic and entropic effects. The present work provides a fundamental understanding of the dependence of surface patterning on lateral polymer mobility. The work could also guide the preparation of diversified nanopatterns, especially for the asymmetric patchy nanoparticles, enabling the fundamental investigation of the interaction between polymer-functionalized nanoparticles.
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4

Yuan, Haiyang, and Guangming Liu. "Ionic effects on synthetic polymers: from solutions to brushes and gels." Soft Matter 16, no. 17 (2020): 4087–104. http://dx.doi.org/10.1039/d0sm00199f.

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5

Yin, Liying, Lin Liu, and Ning Zhang. "Brush-like polymers: design, synthesis and applications." Chemical Communications 57, no. 81 (2021): 10484–99. http://dx.doi.org/10.1039/d1cc03940g.

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Анотація:
Polymer brushes have emerged as one of the most important means of surface modification. We summarise efficient methods for the fabrication of polymer brushes. In addition, we highlight the topology and potential applications of polymer brushes.
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6

Ballauff, Matthias, Markus Biesalski, and Axel H. E. Müller. "Polymer brushes." Polymer 98 (August 2016): 387–88. http://dx.doi.org/10.1016/j.polymer.2016.06.027.

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7

Corsi, Pietro, Elia Roma, Tecla Gasperi, Fabio Bruni, and Barbara Capone. "Exploiting scaling laws for designing polymeric bottle brushes: a theoretical coarse-graining for homopolymeric branched polymers." Physical Chemistry Chemical Physics 21, no. 27 (2019): 14873–78. http://dx.doi.org/10.1039/c9cp01316d.

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8

Amoskov, Victor M., Tatiana M. Birshtein, and Victor A. Pryamitsyn. "Theory of Polymer Brushes of Liquid-Crystalline Polymers." Macromolecules 29, no. 22 (January 1996): 7240–50. http://dx.doi.org/10.1021/ma9603140.

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9

Chen, Yi-Ju, and Hsiu-Yu Yu. "Enthalpic Interactions and Solution Behaviors of Solvent-Free Polymer Brushes." Polymers 14, no. 23 (December 1, 2022): 5237. http://dx.doi.org/10.3390/polym14235237.

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Анотація:
We performed molecular dynamics simulations to characterize the role of enthalpic interaction in impacting the static and dynamic properties of solvent-free polymer brushes. The intrinsic enthalpic interaction in the simulation was introduced using different attraction strengths between distinct species. Two model systems were considered: one consisting of binary brushes of two different polymer types and the other containing a mixture of homopolymer brushes and free molecules. In the first system, we observed that, when two originally incompatible polymers were grafted to opposing surfaces, the miscibility between them was significantly enhanced. A less favorable intrinsic enthalpic interaction in the brushes resulted in a more stretched chain configuration, a lower degree of inter-brush penetration, and faster segmental relaxation. In the second system, we characterized the solvent capacity of the homopolymer brushes from variations in the energy components of the system as a function of the number of free molecules. We determined that molecular absorption was driven by the release of the entropic frustration for the grafted chains in conjunction with the chemical affinity between the solutes and polymers. The solute distribution function within the inter-wall space showed that solute–polymer mixing in the middle of the gap occurred preferentially when the enthalpic interaction was more favorable. When this was not the case, absorption was predominantly localized near the grafting surface. From the mean square displacement of the solute, we found that the brush profiles restrained the molecular diffusion perpendicular to the grafting wall; the weaker the attraction from the brush, the higher the solute mobility.
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10

Smenda, Joanna, Karol Wolski, Kamila Chajec, and Szczepan Zapotoczny. "Preparation of Homopolymer, Block Copolymer, and Patterned Brushes Bearing Thiophene and Acetylene Groups Using Microliter Volumes of Reaction Mixtures." Polymers 13, no. 24 (December 19, 2021): 4458. http://dx.doi.org/10.3390/polym13244458.

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Анотація:
The synthesis of surface-grafted polymers with variable functionality requires the careful selection of polymerization methods that also enable spatially controlled grafting, which is crucial for the fabrication of, e.g., nano (micro) sensor or nanoelectronic devices. The development of versatile, simple, economical, and eco-friendly synthetic strategies is important for scaling up the production of such polymer brushes. We have recently shown that poly (3-methylthienyl methacrylate) (PMTM) and poly (3-trimethylsilyl-2-propynyl methacrylate) (PTPM) brushes with pendant thiophene and acetylene groups, respectively, could be used for the production of ladder-like conjugated brushes that are potentially useful in the mentioned applications. However, the previously developed syntheses of such brushes required the use of high volumes of reagents, elevated temperature, or high energy UV-B light. Therefore, we present here visible light-promoted metal-free surface-initiated ATRP (metal-free SI-ATRP) that allows the economical synthesis of PMTM and PTPM brushes utilizing only microliter volumes of reaction mixtures. The versatility of this approach was shown by the formation of homopolymers but also the block copolymer conjugated brushes (PMTM and PTPM blocks in both sequences) and patterned films using TEM grids serving as photomasks. A simple reaction setup with only a monomer, solvent, commercially available organic photocatalyst, and initiator decorated substrate makes the synthesis of these complex polymer structures achievable for non-experts and ready for scaling up.
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Дисертації з теми "Polymers brushes"

1

Gunkel, Gesine. "Antibiofouling polymer brushes." Thesis, University of Cambridge, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.608096.

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2

Uğur, Gökce. "Interface Structure of Diblock Copolymer Brushes and Surface Dynamics of Homopolymer Brushes and Bilayers of Untethered Chains on Brushes." University of Akron / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=akron1311005794.

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3

Fleet, Reda Ali. "Synthesis and characterization of glycopolymer brushes." Thesis, Stellenbosch : University of Stellenbosch, 2010. http://hdl.handle.net/10019.1/5132.

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4

Wei, Yuan. "Probing Local Structure and Dynamics of Polymer Brushes with Neutron Scattering." Case Western Reserve University School of Graduate Studies / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=case1624963009022896.

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5

Sun, Liang. "Structure and Dynamics of Swollen Polymer Brushes." University of Akron / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=akron1499675793233755.

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6

Kelby, Timothy Simon. "Smart brushes on flexible substrates : probing the chemomechanical properties of stimulus-responsive polymer brushes." Thesis, University of Cambridge, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.610331.

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7

Conlin, Emma L. "Design and synthesis of liquid crystalline polymer brushes and hydrogen bonded polymers /." Available to subscribers only, 2005. http://proquest.umi.com/pqdweb?did=1079664771&sid=2&Fmt=2&clientId=1509&RQT=309&VName=PQD.

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8

Piaoran, Ye. "Synthesis of Polymers and Polymer Brushes through RAFT Polymerization via Flow Chemistry." Case Western Reserve University School of Graduate Studies / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=case1491229581133419.

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9

Tan, Khooi Yeei. "Smart surfaces using responsive polymer brushes." Thesis, University of Cambridge, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.607743.

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10

Yang, Fengyu. "Development of Polyacrylamide-Based Biomaterials in Hydrogels and Brushes." University of Akron / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=akron1555603442979042.

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Книги з теми "Polymers brushes"

1

C, Advincula Rigoberto, ed. Polymer brushes: Synthesis, characterization, applications. Weinheim: Wiley-VCH, 2004.

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2

Polymer brushes: Substrates, technologies, and properties. Boca Raton: Taylor & Francis, 2012.

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3

Azzaroni, Omar, and Igal Szleifer. Polymer and Biopolymer Brushes. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2017. http://dx.doi.org/10.1002/9781119455042.

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4

Francqui, Colloquium (4th 1998 Brussels Belgium). Conjugated oligomers, polymers, and dendrimers: From polyacetylene to DNA : proceedings of the Fourth Francqui Colloqium, 21-23 October 1998, Brussels. Paris: De Boeck Université, 1999.

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5

Vi, Thu Minh Nguyet. Factors that Affect Polymer Brush Formation. [New York, N.Y.?]: [publisher not identified], 2017.

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6

Addcon (2nd 1996 Brussels, Belgium). Addcon '96: Worldwide Additives & Polymer Modifiers Conference : book of papers from a two-day conference held at Palais des Congres, Brussels on May 21st-22nd 1996. Shawbury: Rapra Technology Ltd., 1996.

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7

Lilge, Inga. Polymer Brush Films with Varied Grafting and Cross-Linking Density via SI-ATRP. Wiesbaden: Springer Fachmedien Wiesbaden, 2017. http://dx.doi.org/10.1007/978-3-658-19595-3.

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8

Mittal, Vikas. Polymer Brushes. Taylor & Francis Group, 2018.

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9

Brittain, William J., Rigoberto C. Advincula, Kenneth C. Caster, and Jürgen Rühe. Polymer Brushes: Synthesis, Characterization and Applications. Wiley-VCH Verlag GmbH, 2005.

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10

Brittain, William J., Rigoberto C. Advincula, Kenneth C. Caster, and Jürgen Rühe. Polymer Brushes: Synthesis, Characterization and Applications. Wiley & Sons, Incorporated, John, 2006.

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Частини книг з теми "Polymers brushes"

1

Caster, Kenneth C. "Applications of Polymer Brushes and Other Surface-Attached Polymers." In Polymer Brushes, 329–70. Weinheim, FRG: Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527603824.ch17.

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2

Mori, Hideharu, and Axel H. E. Müller. "Surface-Grafted Hyperbranched Polymers." In Polymer Brushes, 167–86. Weinheim, FRG: Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527603824.ch9.

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3

Giannelis, E. P., R. Krishnamoorti, and E. Manias. "Polymer-Silicate Nanocomposites: Model Systems for Confined Polymers and Polymer Brushes." In Polymers in Confined Environments, 107–47. Berlin, Heidelberg: Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/3-540-69711-x_3.

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4

Cappella, Brunero. "Thin Polymer Films and Polymer Brushes." In Mechanical Properties of Polymers Measured through AFM Force-Distance Curves, 155–85. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-29459-9_4.

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5

Grest, Gary S. "Normal and Shear Forces Between Polymer Brushes." In Polymers in Confined Environments, 149–83. Berlin, Heidelberg: Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/3-540-69711-x_4.

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6

Zhulina, Ekaterina. "Equilibrium Structure of Ionizable Polymer Brushes." In Solvents and Self-Organization of Polymers, 227–58. Dordrecht: Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-009-0333-3_11.

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7

Orski, Sara, Gareth Sheppard, Rachelle Arnold, Joe Grubbs, and Jason Locklin. "Post-polymerization Modification of Polymer Brushes." In Functional Polymers by Post-Polymerization Modification, 353–69. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527655427.ch14.

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8

Nguyen, Chi, Prashant Deshmukh, Xiaorui Chen, Sergio Granados-Focil, and Rajeswari Kasi. "Thermoreversible Ion Gels From Side-Chain Liquid Crystalline Brushes Diblock Copolymers." In Functional Polymers, 241–63. Taylor & Francis Group, 6000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487-2742: CRC Press, 2017. http://dx.doi.org/10.1201/9781315366524-9.

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9

Pfukwa, Rueben, Lebohang Hlalele, and Bert Klumperman. "Biorelated Polymer Brushes by Surface Initiated Reversible Deactivation Radical Polymerization." In Polymers for Biomedicine, 487–524. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2017. http://dx.doi.org/10.1002/9781118967904.ch16.

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10

Murase, Yasuyuki. "Polymer Brushes." In Encyclopedia of Polymeric Nanomaterials, 1–6. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-36199-9_153-1.

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Тези доповідей конференцій з теми "Polymers brushes"

1

Chen, Long, Holger Merlitz, Su-zhen He, Chen-xu Wu, and Jens-Uwe Sommer. "Approaching charged polymer brushes." In 2011 International Conference on Remote Sensing, Environment and Transportation Engineering (RSETE). IEEE, 2011. http://dx.doi.org/10.1109/rsete.2011.5965659.

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2

Dobnikar, J., T. Curk, F. J. Martinez-Veracoechea, and D. Frenkel. "Slow colloidal dynamics in polymer brushes." In 4TH INTERNATIONAL SYMPOSIUM ON SLOW DYNAMICS IN COMPLEX SYSTEMS: Keep Going Tohoku. American Institute of Physics, 2013. http://dx.doi.org/10.1063/1.4794602.

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3

Yang, Zhiqiao. "Molecular Dynamics Simulations Of Polymer Brushes." In 2021 6th International Symposium on Computer and Information Processing Technology (ISCIPT). IEEE, 2021. http://dx.doi.org/10.1109/iscipt53667.2021.00140.

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4

Zhao, Yuejun, Tao Chen, Xiaodong Zhang, Stefan Zauscher, and Chuan-Hua Chen. "Development of an Adaptive Vapor Chamber With Thermoresponsive Polymer Coating." In ASME 2009 Second International Conference on Micro/Nanoscale Heat and Mass Transfer. ASMEDC, 2009. http://dx.doi.org/10.1115/mnhmt2009-18276.

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We propose a novel concept for an adaptive vapor chamber using a thermoresponsive polymer coating to enhance heat transfer and reduce local thermal gradients. By coating the wick structures with stimulus-responsive polymer brushes with an upper critical solution temperature (UCST), the hotter surface becomes more wettable than the colder surface. The smaller contact angle at higher temperature generates larger capillary forces and promotes stronger return flow toward the hotspots. In this paper, we present our progress toward developing the adaptive vapor chamber. We have grafted poly(2-(meth-acryloyloxy)ethyl(dimethyl(3-sulfopropyl) ammonium hydroxide) (PMEDSAH) brushes on silica wafers, and the PMEDSAH polymer coating exhibits UCST properties with stable and tunable wettability. We have captured infrared images of the evaporator with steady and transient heating, and developed a thermographic technique that can be used to test the adaptive wick functionality in a vapor chamber.
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5

Kobayashi, M., K. Mitamura, M. Terada, M. Kikuchi, D. Murakami, H. Yamaguchi, H. Arita, et al. "Applications of polymer brushes to structural nano-coatings." In 2011 IEEE Nanotechnology Materials and Devices Conference (NMDC 2011). IEEE, 2011. http://dx.doi.org/10.1109/nmdc.2011.6155315.

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6

Liu, Honglai, Yunli Xu, Xueqian Chen, and Xia Han. "Molecular Mechanism of Solvent-responsive Mixed Polymer Brushes." In 14th Asia Pacific Confederation of Chemical Engineering Congress. Singapore: Research Publishing Services, 2012. http://dx.doi.org/10.3850/978-981-07-1445-1_067.

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7

Seror, Jasmine, Nir Kampf, Alice Maroudas, and Jacob Klein. "Nanotribological Investigation of the Role of Proteoglycans in Biolubrication." In ASME 2008 9th Biennial Conference on Engineering Systems Design and Analysis. ASMEDC, 2008. http://dx.doi.org/10.1115/esda2008-59390.

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Articular joints in human body are uniquely efficient lubrication systems. While the cartilage surfaces slide past each other under physiological working conditions (pressure of tens of atmospheres and shear rates up to 106 – 107 Hz), the friction coefficient (μ) achieves extremely low values (down to 0.001) never successfully reached by mechanical prosthetic devices. Friction studies on polymer brushes attached to surfaces have recently demonstrated (17) their ability to reduce friction between the rubbing surfaces to extremely low values by means of the hydrated ions and the charges on the polymer chains. We propose that the extremely efficient lubrication observed in living joints arises from the presence of a brush-like phase of charged macromolecules at the surface of the cartilage superficial zone: hydration layers which surround the charges on the cartilage macromolecules might provide a lubricating ball-bearing-like effect as demonstrated for the synthetic polyelectrolytes (17). In this work macromolecules of the cartilage superficial zone (aggrecans) are extracted from human femoral heads and purified using well developed biochemical techniques (20). The extracted molecules are then characterized with atomic force microscope (AFM). By means of a surface force balance (SFB) normal and shear interactions between mica surfaces coated with these molecules are examined focusing on the frictional forces between such surfaces at normal stresses similar to those in human joints.
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8

Barba, Bin Jeremiah D., Patricia Nyn L. Heruela, Patrick Jay E. Cabalar, John Andrew A. Luna, Allan Christopher C. Yago, and Jordan F. Madrid. "Nanografting of Polymer Brushes on Gold Substrate by RAFT-RIGP." In IOCPS 2021. Basel Switzerland: MDPI, 2021. http://dx.doi.org/10.3390/iocps2021-11587.

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9

Fridrich, Petr, and Zbyšek Posel. "Self-Assembly of Y-Shaped Polymer Brushes with Low Poly-Dispersity." In The 3rd International Online-Conference on Nanomaterials. Basel Switzerland: MDPI, 2022. http://dx.doi.org/10.3390/materproc2022009026.

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10

Pei, Yiwen, Jadranka Travas-Sejdic, and David E. Williams. "Electrochemically switchable surfaces using polymer brush-grafted conducting polymer films." In Smart Nano-Micro Materials and Devices, edited by Saulius Juodkazis and Min Gu. SPIE, 2011. http://dx.doi.org/10.1117/12.903201.

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Звіти організацій з теми "Polymers brushes"

1

Motornov, Mikhail, Roman Sheparovych, Ihor Tokarev, Yuri Roiter, and Sergiy Minko. Nonwettable Thin Films from Hybrid Polymer Brushes can be Hydrophilic. Fort Belvoir, VA: Defense Technical Information Center, March 2007. http://dx.doi.org/10.21236/ada482327.

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2

Kurian, Mary K., Arnab Dasgupta, Mary E. Galvin, and Frederick L. Beyer. Effect of Textured Surfactant Brushes on Polymer-Layered Silicate Nanocomposite Morphology. Fort Belvoir, VA: Defense Technical Information Center, February 2004. http://dx.doi.org/10.21236/ada420985.

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3

Kuhl, Tonya Lynn, and Roland Faller. Structure-Property Relationships of Polymer Brushes in Restricted Geometries and their Utilization as Ultra-Low Lubricants. Office of Scientific and Technical Information (OSTI), September 2015. http://dx.doi.org/10.2172/1221671.

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4

Green, Peter F. Brush-Coated Nanoparticle Polymer Thin Films: structure-mechanical-optical properties. Office of Scientific and Technical Information (OSTI), August 2014. http://dx.doi.org/10.2172/1167194.

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5

Lin, Yao, Yuan Ren, and Hongwei Xia. STIR: A Pilot Study on the Bulk Properties and Morphology of Polypeptide-Grafted Brush Polymers. Fort Belvoir, VA: Defense Technical Information Center, March 2014. http://dx.doi.org/10.21236/ada614061.

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Також вас можуть зацікавити розширені добірки на тему "Polymers brushes" для конкретних типів джерел:
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Ми пропонуємо знижки на всі преміум-плани для авторів, чиї праці увійшли до тематичних добірок літератури. Зв'яжіться з нами, щоб отримати унікальний промокод!

До бібліографії