Готові списки джерел за темами / Organic-inorganic Hybrid Mesoporous Materials

Добірка наукової літератури з теми "Organic-inorganic Hybrid Mesoporous Materials"

Автор: Grafiati
Опубліковано: 7 вересня 2023

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Статті в журналах з теми "Organic-inorganic Hybrid Mesoporous Materials"

1

Kickelbick, Guido. "Hybrid Inorganic–Organic Mesoporous Materials." Angewandte Chemie International Edition 43, no. 24 (June 14, 2004): 3102–4. http://dx.doi.org/10.1002/anie.200301751.

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2

Hoffmann, Frank, Maximilian Cornelius, Jürgen Morell, and Michael Fröba. "Silica-Based Mesoporous Organic–Inorganic Hybrid Materials." Angewandte Chemie International Edition 45, no. 20 (May 12, 2006): 3216–51. http://dx.doi.org/10.1002/anie.200503075.

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3

Li, Ying, Jie Lin Wang, Wei Chain, Xia Wang, Hua Ti Li, and Shuang He Liu. "Luminescent Hybrids of Eu3+ Complexes Covalently Bonded with Mesoporous Silica and PMAA." Advanced Materials Research 749 (August 2013): 82–86. http://dx.doi.org/10.4028/www.scientific.net/amr.749.82.

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Binary organic-inorganic mesoporous hybrid materials were prepared by covalntly grafting Lanthanide (III) (Eu) trifluoroacetylaceton (TAA) complexes to the ordered meosoporous silica SBA-15 via hydrothermal method and hydrolysis and co-polycondensation method with the surfactant P123 and TEOS. Besides, Novel ternary lanthanide (III) (Eu) organic-inorganic-polymeric mesoporous hybrid materials have been synthesized as well through the introduction of the organic polymer PMAA to the binary system with covalent bond. We investigated the thermal stability and luminescence properties of hybrids and found that the ternary hybrid materials exhibit better thermal stability and stronger emission intensity. Furthermore, compared with the binary mesoporous material Eu (TAA-SBA-15)3, the ternary mesoporous material Eu (TAA-SBA-15)3PMMA exhibits the characteristic emission of the Eu3+ ion with a higher luminescence Intensity, suggesting that the introduction of polymer PMMA into the mesoporous matrix is of benefit for the sensitization of Eu3+ luminescence, by replacing H2O groups that can quench the luminescence of Eu3+ ion.
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4

Bendrea, Anca-Dana, Ana-Maria Catargiu, and Mircea Grigoras. "Hybrid Organic-Inorganic Composite Materials for Application in Chemical Sensors." Chemistry Journal of Moldova 4, no. 2 (December 2009): 100–104. http://dx.doi.org/10.19261/cjm.2009.04(2).03.

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Mesoporous SBA-15/conducting polymers composites, type SBA- polithiophene, SBA-polyaniline, respectively were synthesized and their physical properties were investigated. Polymers molecules were synthesized by chemical oxidative polymerization inside the pores of the mesoporous material by a post-synthesis process. The obtained materials were characterized by X-ray diffraction, scanning electron microscopy, thermal analysis and infrared spectroscopy.
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5

Wang, Lina, Tao Qi, and Yi Zhang. "Novel organic–inorganic hybrid mesoporous materials for boron adsorption." Colloids and Surfaces A: Physicochemical and Engineering Aspects 275, no. 1-3 (March 2006): 73–78. http://dx.doi.org/10.1016/j.colsurfa.2005.06.075.

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6

Nakanishi, Kazuki, and Kazuyoshi Kanamori. "Phase Separation in Sol-Gel Systems of Organic-Inorganic Hybrids." Advances in Science and Technology 45 (October 2006): 759–68. http://dx.doi.org/10.4028/www.scientific.net/ast.45.759.

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Organic-inorganic hybrid monoliths with well-defined macropores and/or mesopores have been synthesized by a sol-gel process accompanied by polymerization-induced phase separation. Using aklyltrialkoxysilanes and alkylene-bridged alkoxysilanes, two different categories of organo-siloxane networks have been characterized in view of macroporoisity based on phase separation as well as mesoporosity based on supramolecular templating by surfactants. The alkyl-terminated polysiloxane network exhibited substantial surface hydrophobicity together with the mechanical flexibility. On the other hand, the alkylene-bridged network behaved much more similarly to those prepared from tetraalkoxysilanes with regard to surface hydrophilicity, mechanical rigidness and mesopore-forming ability. Supramolecular templating of mesopores embedded in the gel skeletons comprising well-defined macroporous network has proven to give wide variety of hierarchically designed macro-mesoporous organic-inorganic hybrid materials.
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7

Díaz, Urbano, Mercedes Boronat, and Avelino Corma. "Hybrid organic–inorganic structured materials as single-site heterogeneous catalysts." Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 468, no. 2143 (March 14, 2012): 1927–54. http://dx.doi.org/10.1098/rspa.2012.0066.

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Catalyst selectivity is associated with well-defined homogeneous active sites. Transition metal complexes and organocatalysts are highly active and selective in the homogeneous phase, and their heterogenization by incorporating them into inorganic solid materials allows combining their excellent catalytic activity with improved separation, recovering and recycling properties. In this article, we present the structural characteristics and catalytic properties of hybrid organic–inorganic materials in which the molecular catalysts are part of the inorganic structure, emphasizing the possibilities of periodic mesoporous hybrid materials and coordination polymers as single-site solid catalysts.
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8

Lu, Yunfeng. "Surfactant-Templated Mesoporous Materials: From Inorganic to Hybrid to Organic." Angewandte Chemie International Edition 45, no. 46 (November 27, 2006): 7664–67. http://dx.doi.org/10.1002/anie.200602489.

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9

Zhu, Yun-Pei, Tie-Zhen Ren, and Zhong-Yong Yuan. "Mesoporous non-siliceous inorganic–organic hybrids: a promising platform for designing multifunctional materials." New J. Chem. 38, no. 5 (2014): 1905–22. http://dx.doi.org/10.1039/c3nj01139a.

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Анотація:
An overview of the recent progress in the designed synthesis, modification and multifunctional applications of mesoporous non-siliceous inorganic–organic hybrid materials including metal phosphonates, carboxylates and sulfonates is presented.
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10

Ye, Ranfeng, Min Ni, Hao Chen, and Shengqing Li. "Synthesis of mesoporous nickel–titanium-trimesic acid inorganic–organic hybrid composite in ionic liquid microemulsions for adsorption of rhodamine B from aqueous solution." Materials Express 10, no. 2 (February 1, 2020): 251–57. http://dx.doi.org/10.1166/mex.2020.1639.

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Анотація:
For the first time, mesoporous nickel–titanium-trimesic acid (NTT) inorganic–organic hybrid composite was synthesized in water-in-[Bmim]PF6 ionic liquid microemulsions using the trimesic acid (BTC) as the linker. The synthesized NTT was characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) analysis, powder X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR) methods, etc. Then, the isotherm and kinetic of adsorption were studied. The experimental data were well fitted with isotherm models of Langmuir and Freundlich (IMLF) at 298 K and 308 K and better fitted with the isotherm model of Langmuir (IML) at 318 K with the adsorption capacity of 662.212 μmol/g (maximum). The adsorption of rhodamine B (RhB) on NTT can be described by pseudo-second-order (PSO) kinetic model. This proposed method for synthesis of mesoporous NTT inorganic–organic hybrid composite is facile, environment-friendly and operated at room temperature, which could be applied to synthesis of other mesoporous inorganic–organic hybrid composites.
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Більше джерел

Дисертації з теми "Organic-inorganic Hybrid Mesoporous Materials"

1

Ghosh, A. "Synthesis, characterization and catalytic activities of organic-inorganic hybrid mesoporous materials." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2004. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2409.

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Erigoni, Andrea. "Organic-Inorganic Hybrid Catalysts for Chemical Processes of Industrial Interest." Doctoral thesis, Universitat Politècnica de València, 2021. http://hdl.handle.net/10251/165238.

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Анотація:
[ES] El trabajo de investigación descrito en la presente Tesis Doctoral ha sido desarrollado en el marco del proyecto europeo MULTI2HYCAT (grant agreement N. 720783) y se ha centrado en la síntesis y caracterización de materiales mono- y multi-funcionales que presentan sitios catalíticos ácidos, básicos o redox. Diferentes líneas de investigación han sido desarrolladas en paralelo para obtener distintos materiales híbridos que serán empleados en diferentes procesos catalíticos, en línea con las necesidades de los socios industriales del proyecto. Debido a la naturaleza colaborativa del proyecto, cada miembro académico se ha en-centrado en un aspecto del desarrollo de los materiales. Es por ello que el Instituto de Tecnología Química (ITQ-CSIC), donde se ha llevado a cabo esta Tesis Doctoral, se ha centrado en la síntesis de los catalizadores híbridos. Por ello, parte de la caracterización descrita en el Capítulo 3 se ha llevado a cabo en la Università del Piemonte Orientale (IT), durante una estancia de un mes. Ademas, algúnos resultados catalíticos descritos en los Capítulos 3 y 5 han sido obtenidos por la University of Southampton (UK). En el Capítulo 3, se ha descrito la síntesis de dos catalizadores heterogéneos híbridos que presentan moléculas de ácido aril-sulfónico en su composición. En uno de ellos, el anillo aromático presentará átomos de flúor en posición 2, 3, 5, 6. Se han llevado a cabo dos estrategias de síntesis multi-etapas, a través de la síntesis de los precursores alkoxi-silanos, a través de procesos de condensación junto a un precursor de sílice (en ausencia de agentes directores de estructura, a pH neutro y temperaturas bajas) y de una reacción de tethering. Los materiales híbridos han sido caracterizados a través de dife-rentes técnicas. Las propiedades texturales, la estabilidad térmica y la composición química de los catalizadores ha sido estudiada. Además, moléculas sondas han sido adsorbidas en los materiales hibridos y las interacciones entre ellos han sido estudiadas a través de espectroscopias FTIR y RMN multi-nuclear. El catalizador hibrido en que el anillo aromático estaba fluorado resultó ser el más activo catalíticamente en la reac-ción de formación de acetal entre benzaldehído y etilenglicol. Una versión de los hí-bridos en que la superficie había sido pasivada con grupos metilos también fue obteni-da. Las propiedades de los materiales híbridos pasivados fueron comparadas, para po-der estudiar el efecto de la polaridad de la superficie del soporte sobre la actividad catalítica. En el Capítulo 4 se describe la síntesis de órgano-catalizadores híbridos obtenidos por anclaje de precursores de silicio funcionalizados con grupos básicos sobre un soporte del tipo MCM-41. Los catalizadores han sido caracterizados y empleados en diferentes reacciones de formación de enlaces C-C, como la condensación de Knoevenagel y la adición de Michael. Los catalizadores híbridos han sido empleados en la condensación entre furfural y metil isobutil cetona. El catalizador más activo ha sido seleccionado para ser funcionalizado posteriormente con nanoparticulas de paladio y empleado en un proceso catalítico en cascada. Mecanismos de reacción han sido pro-puesto para cada proceso catalítico. El efecto beneficioso debido a la presencia de los grupos silanoles en la superficie del soporte también fue analizado. En el Capítulo 5, la síntesis de catalizadores híbridos multi-funcionales fue descrita. Basándose en los resultados obtenidos en el Capítulo 4, se ha preparado un catalizador que presente grupos aminopropil- y nanopartículas de paladio. Las propiedades estructurales y texturales han sido estudiadas. Además, a través de la microscopia electrónica de transmisión, la distribución dimensional de las nanoparticulas ha sido estimada, resultando en un tamaño medio equivalente a la dimensión de los canales mesoporosos del soporte, MCM-4
[CA] El treball de recerca descrit en aquesta tesi doctoral es va desenvolupar en el marc del projecte europeu MULTI2HYCAT (grant agreement N. 720783) i se centra en la sínte-si i la caracterització de catalitzadors híbrids mono i multifuncionals amb àcid, base o redox actius llocs. S'han desenvolupat diverses línies d'investigació en paral·lel per dissenyar múltiples catalitzadors híbrids per a diferents processos catalítics, basant-se en les necessitats dels socis industrials. A causa del caràcter col·laboratiu del projecte, cada soci acadèmic es va centrar princi-palment en un aspecte de tot el procés. Institut de Tecnologia Química (ITQ-CSIC), on es va desenvolupar aquesta tesi, està principalment centrat en el disseny i síntesi de catalitzadors híbrids. Per això, part dels resultats de caracterització reportats al Capítol 3 s'han dut a terme a la Università del Piemonte Orientale (IT), durant una estada d'un mes. Alguns dels resultats catalítics reportats al Capítol 3 i al Capítol 5 han estat reali-tzats per la Universitat de Southampton (Regne Unit). En el Capítol 3, s'ha descrit la síntesi de dos catalitzadors heterogenis híbrids que pre-senten molècules d'àcid aril-sulfònic en la composició. En un d'ells, l'anell aromàtic presentarà àtoms de fluor en posició 2, 3, 5, 6. S'han dut a terme dues estratègies de síntesi multi-etapes, a través de la síntesi dels precursors alkoxi-silans, mitjançant pro-cessos de condensació al costat d'un precursor de sílice (en absència d'agents directors d'estructura, a pH neutre i temperatures baixes) i d'una reacció de tethering. Els mate-rials híbrids han estat caracteritzats mitjançant diferents tècniques. Les propietats texturals, l'estabilitat tèrmica i la composició química dels catalitzadors ha sigut estudiada. A més, molècules sondes han estat adsorbides en els materials híbrids i les interaccions entre ells han estat estudiades mitjançant espectroscòpies FTIR i RMN multi-nuclear. El catalitzador híbrid en que l'anell aromàtic estava fluorat va resultar ser el més actiu catalíticament en la reacció de formació d'acetal entre benzaldehid i etilenglicol. Una versió dels híbrids en que la superfície havia estat pasivada amb grups metilos també va ser obtinguda. Les propietats dels materials híbrids passivats van ser comparades, per poder estudiar l'efecte de la polaritat de la superfície del suport sobre l'activitat catalítica. En el Capítol 4 es descriu la síntesi d'organo-catalitzadors híbrids obtinguts per ancoratge de precursors de silici funcionalitzats amb grups bàsics sobre un suport del tipus MCM-41. Els catalitzadors han estat caracteritzats i empleats en diferents reaccions de formació d'enllaços C-C, com la condensació de Knoevenagel i l'addició de Michael. Finalment, els catalitzadors híbrids han estat emprats en la condensació entre furfural i metil isobutil cetona. El catalitzador més actiu ha estat seleccionat per a ser funcionalitzat posteriorment amb nanoparticules de pal·ladi i emprat en un procés catalític en cascada. Mecanismes de reacció han estat proposat per a cada procés catalític. L'efecte beneficiós a causa de la presència dels grups silanols en la superfície de suport també va ser analitzat. En el Capítol 5, la síntesi de catalitzadors híbrids multi-funcionals va ser descrita. Basant-se en els resultats obtinguts en el Capítol 4, s'ha preparat un catalitzador que presenti grups aminopropil- i nanopartícules de palladi. Les propietats estructurals i texturals han estat estudiades. A més, a través de la microscòpia electrònica de trans-missió, la distribució dimensional de les nanoparticulas ha estat estimada, resultant en una grandària mitjana equivalent a la dimensió dels canals mesoporosos del suport, MCM-41. El material ha estat emprat com a catalitzador multi-funcional.
[EN] The research work described in this Doctoral Thesis was developed within the frame of the MULTI2HYCAT European Project (grant agreement N. 720783) and it is focused on the synthesis and characterization of mono- and multi-functional hybrid catalysts featuring acid, base or redox active sites. Several research lines have been developed in parallel to design multiple hybrid catalysts for different catalytic processes, building upon the needs of the industrial partners. Due to the collaborative nature of the project, each academic partners mainly focused on one aspect of the whole process. Instituto de Tecnología Química (ITQ-CSIC), where this Thesis was developed, mostly focused on the design and synthesis of the hybrid catalysts. For that, part of the characterization results reported in Chapter 3 have been carried out at Università del Piemonte Orientale (IT), during a one month stay. Some of the catalytic results reported in Chapter 3 and Chapter 5 have been car-ried out by the University of Southampton (UK). In Chapter 3 the synthesis of two different heterogeneous hybrid catalysts carrying aryl-sulfonic moieties, in which the aromatic ring was either fluorinated or not, is re-ported. Two multi-step synthetic approaches were developed, involving the synthesis of the silyl-derivative precursor, template-free one-pot co-condensation (at low tem-perature and neutral pH) and tethering reaction. A multi-technique approach was im-plemented to characterize the hybrid catalysts. Textural properties, thermal stability and chemical makeup of the materials were studied. Moreover, probe molecules were adsorbed onto the hybrids and the interaction were studied with multi-nuclear NMR and FTIR spectroscopies. The catalytic activity of the two hybrids showed superior performances for the fluoro-aryl-sulfonic acid, compared to the non-fluorinated mate-rial, in the acetal formation between benzaldehyde and ethylene glycol. Silanol-capped versions of the hybrids have also been prepared and their properties have been com-pared with those of hydrophilic hybrids, to study the effect of the polarity of the sur-face on the overall catalytic activity of the hybrids. In Chapter 4, the synthesis of hybrid mesoporous organocatalysts, obtained by graft-ing of commercial and custom-made silyl-derivatives onto MCM-41 supports, is re-ported. The hybrid catalysts were characterized and tested for different reactions in-volving C-C bond formation, such as Knoevenagel condensations and Michael addi-tion. Finally, the catalysts were tested in the condensation between furfural and methyl isobutyl ketone and the most performing catalyst was selected for the synthesis of a multi-functional hybrid. Reaction mechanisms have been proposed and the beneficial effect of the surface silanol groups on the catalytic activity was demonstrated. In Chapter 5, the synthesis of hybrid multi-functional catalysts is reported. Building upon the results reported in Chapter 4, a hybrid catalyst featuring aminopropyl moie-ties and palladium nanoparticles was developed. Structural and textural properties of the catalysts were accessed. Moreover, transmission electron microscopy showed a narrow nanoparticles distribution, centered a value equivalent to the size of the meso-porous channels of the support. The catalyst was tested in a tandem process involving the aldol condensation between furfural and methyl isobutyl ketone followed by hy-drogenation of the aldol adduct. The influence of several variables on the activity of the multi-functional catalyst was explored, with the scope of paving the way for more thorough studies to be carried out in flow regime. Lastly, proof-of-concept syntheses of multi-functional hybrid catalysts featuring base sites and supported metal complex are reported.
The research work described in this Doctoral Thesis was developed within the frame of the MULTI2HYCAT European Project (grant agreement N. 720783). I would like to thank la Caixa foundation for my PhD scholarship.
Erigoni, A. (2021). Organic-Inorganic Hybrid Catalysts for Chemical Processes of Industrial Interest [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/165238
TESIS
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3

Ahmad, Sana. "Preparation and characterization of cyclopentadienyltitanium-based organic-inorganic hybrid materials." Thesis, Bordeaux 1, 2010. http://www.theses.fr/2010BOR14066/document.

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Ce mémoire rapporte la préparation et l'étude de matériaux hybrides organiques-inorganiques à base de titane où les deux réseaux sont liés par des liaisons titane-carbone stables. Différents précurseurs dans lesquels deux groupes cyclopentadienyltitane sont reliés par des espaceurs variés ont été préparés. Ces espaceurs comprennent des groupes aromatiques et hétéroaromatiques linéaires ainsi que des groupes aromatiques disubstitués par des chaînes alkyle. Ces complexes dimétalliques, où le titane est aussi lié à trois groupes labiles, ont été ensuite hydrolysés dans les conditions du procédé sol-gel pour conduire à des hybrides de classe II. Le réseau organique y est lié au réseau inorganique par des liaisons stables titane-carbone. Ces matériaux sont organisés et leur mode d'organisation dépend de la nature de l'espaceur reliant les groupes cyclopentadienyle. Les espaceurs linéaires conduisent à des matériaux à structure en escalier dans lesquels les ligands sont associés par des liaisons p. La longueur des espaceurs n'a pas d'effet sur cette organisation. Par contre, les matériaux à espaceurs substitués latéralement sont organisés par les chaînes alkyle. La calcination de ces matériaux hybrides sous oxygène conduit à la formation de dioxyde de titane nanoporeux sous forme d'anatase dont la cristallinité et la surface spécifique dépendent de la température de calcination. D'une façon similaire des films de dioxyde de titane de même type sont obtenus par la calcination de films minces d'hybrides préparés par spin-coating
This work aimed to the preparation of titanium-based organic-inorganic hybrid materials where both networks are linked through stable titanium-carbon bonds. The preparation of various di(cyclopentadienyltitanium) precursors in which various organic groups serve as a bridge between the two cyclopentadienyl groups while each titanium atom is equipped with three hydrolysable groups was first achieved. Then, these complexes were hydrolyzed in a sol-gel process that led to new self-assembled titanium-based class II hybrid materials in which the inorganic network is connected to the organic network through stable titanium-carbon bonds. The mode of organization of the nanostructures depends on the spacer bridging the cyclopentadienyl groups. Linear aromatic spacers led to materials having a stair-like structure in which the organic ligands are arranged via p-stacking. The length of the spacer has a little effect on the organization of the nanostructures. The structure of the materials obtained with spacers endowed with long lateral chains is governed by the side chains. The calcination of these materials under oxygen led to the formation of nanoporous anatase titanium dioxide the crystallinity and surface area of which depend on the calcination temperature. Similarly titanium dioxide thin films were prepared by the calcination of hybrid thin films prepared by spin coating
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4

Comes, Navarro María. "Hybrid inorganic-organic materials for the optical recognition of neutral and anionic species." Doctoral thesis, Universitat Politècnica de València, 2016. http://hdl.handle.net/10251/62153.

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[EN] The doctoral thesis presented under the title "Hybrid inorganic-organic materials for the optical recognition of neutral and anionic species" has had as its main objective the synthesis and characterization of organic-inorganic hybrid materials based on the combination of the principles of Supramolecular Chemistry and Materials Science. Recent studies confirm that cooperation between these two areas of Chemistry allow the simulation of what natural living beings have been doing for millions of years in a natural way. At cellular level, many vital functions are related to the ability of a particular receptor to recognize a particular species, giving a specific answer. But what is more interesting is that in living organisms, most of these systems do not exist as dissolved molecules, but are bounded to a (bio)organic skeleton with more or less flexibility. When we imitated these systems bearing in mind the supramolecular and analytical chemistry, we find that we need a sensory molecule able to join with the specie that we want to detect and at the same time, this union must produce a change in its physico-chemical properties giving as a result a signal. But moreover, if we take advantatge of the fact that siliceous nanostructured materials present a high physical and chemical stability and that they have cavities where the sensor system can be incorporated into, we have the synthetic hybrid organic-inorganic combination similar to the natural one. In order to develop this idea, we have used sensor systems widely studied in molecular recognition processes in aqueous media and we have applied them to the inorganic-organic hydrid materials. Therefore, the present work thesis has been structured in two parts: on the one hand, the synthesis and characterization of the functionalized inorganic porous solid materials by the study and detection of amines using the "chemodosimeter" approach. On the other hand, we have made the synthesis and characterization of the organic functionalized inorganic porous solid materials for the study and detection of anionic species through the displacement assays approach.
[ES] La tesis doctoral que se presenta bajo el título "Hybrid inorganic-organic materials for the optical recognition of neutral and anionic species" ha tenido como objetivo principal la síntesis y caracterización de materiales híbridos orgánico-inorgànicos basados en la combinación de los principios de la Química Supramolecular y la Ciencia de los Materiales. Recientes estudios corroboran que la cooperación entre estas dos áreas de la Química permite simular lo que ya hace millones de años realizan de forma natural los organismos vivos. A nivel celular, muchas de las funciones vitales están relacionadas con la habilidad de un receptor concreto para reconocer una determinada especie, dando una respuesta específica. Pero lo que resulta más interesante, es que en los organismos vivos, la mayoría de estos sistemas no existen en forma de moléculas disueltas, sino que están unidos con mayor o menor flexibilidad a un esqueleto bio(in)orgánico. Cuando imitamos estos sistemas teniendo en cuenta la química supramolecular y analítica, nos encontramos que necesitamos de una molécula indicadora que sea capaz de unirse a la especie que queremos detectar y que a su vez, esta unión produzca un cambio en las propiedades físico-químicas de la entidad para producir una señal. Pero además, si aprovechamos el hecho de que los materiales silíceos nanoestructurados presentan una alta estabilidad física y química y que proporcionan cavidades donde alojar al sistema sensor, tenemos la combinación híbrida orgánico-inorgánico sintética similar a la natural. Con el objetivo de desarrollar esta idea, hemos utilizado sistemas sensores ampliamente estudiados en procedimientos de reconocimiento molecular en disolución acuosa y los hemos aplicado a los materiales híbridos orgánico-inorgànicos. De esta manera, el trabajo de tesis se ha estructurado en dos partes: por una parte, la síntesis y caracterización de materiales sólidos inorgánicos porosos funcionalizados para el estudio y detección de aminas utilizando el procedimiento de "dosímetro químico", y en una segunda parte, se ha llevado a cabo la síntesis y caracterización de sólidos inorgánicos porosos funcionalizados para el estudio y detección de especies aniónicas mediante el procedimiento de "ensayos por desplazamiento".
[CA] La tesis doctoral que es presenta sota el títol "Hybrid inorganic-organic materials for the optical recognition of neutral and anionic species" ha tingut com objectiu principal la síntesi i caracterització de materials híbrids orgànic-inorgànics basats en la combinació dels principis de la Química Supramolecular i la Ciència dels Materials. Estudis recents corroboren que la cooperació entre aquestes dues àrees de la Química permet simular el que ja fa milions d'anys realitzen de forma natural els organismes vius. A nivell cel·lular, moltes de les funcions vitals estan relacionades amb l'habilitat d'un receptor concret per a reconèixer una espècie determinada, donant una resposta específica. Però el que és més interessant, és que als organismes vius, la majoria d'aquests sistemes no existeixen en forma de molècules dissoltes, sinó que estan units amb major o menor flexibilitat a un esquelet bio(in)orgànic. Quan imitem aquests sistemes tenint en compte la química supramolecular i analítica, ens trobem que necessitem d'una molècula indicadora que sigui capaç d'unir-se a l'espècie que volem detectar i que alhora, aquesta unió produeixi un canvi en les propietats fisico-químiques de l'entitat per produir una senyal. Però a més, si aprofitem el fet que els materials silícics nanoestructurats presenten una alta estabilitat física i química i que proporcionen cavitats on es pot allotjar el sistema sensor, tenim la combinació híbrida orgànica-inorgànica sintètica semblant a la natural. Per tal de desenvolupar aquesta idea, hem utilitzat sistemes sensors ampliament estudiats en procediments de reconeixement molecular en dissolució aquosa i els hem aplicat als materials híbrids orgànic-inorgànics. Així el present treball de Tesis s'ha estructurat en dues parts: per una banda, la síntesis i caracterització de materials sòlids inorgànics porosos funcionalitzats per l'estudi i detecció d'amines utilitzant el procediment de "dosímetre químic", i en una segona part, s'ha realitzat la síntesis i caracterització de sòlids inorgànics porosos funcionalitzats per a l'estudi i detecció d'espècies aniòniques mitjançant el procediment "d'assajos per desplaçament".
Comes Navarro, M. (2016). Hybrid inorganic-organic materials for the optical recognition of neutral and anionic species [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/62153
TESIS
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Hicks, Jason Christopher. "Organic/inorganic hybrid amine and sulfonic acid tethered silica materials synthesis, characterization and application /." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2007. http://hdl.handle.net/1853/26583.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2008.
Committee Chair: Jones, Christopher; Committee Member: Koros, William; Committee Member: Lyon, Andrew; Committee Member: Nair, Sankar; Committee Member: Weck, Marcus. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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6

Sanderyd, Viktor. "Novel Hybrid Nanomaterials : Combining Mesoporous Magnesium Carbonate with Metal-Organic Frameworks." Thesis, Uppsala universitet, Nanoteknologi och funktionella material, 2018. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-355366.

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Nanotechnology as a field has the potential to answer some of the major challenges that mankind faces in regards to environmental sustainability, energy generation and health care. Though, solutions to these concerns can not necessarily rely on our current knowhow. Instead, it is reasonable to expect that humanity must adapt and learn to develop new materials and methods to overcome the adversities that we are facing. This master thesis has involved developing novel materials, serving as a small step in the continuous march towards a bright future where this is possible. More specifically, this work sought to combine mesoporous magnesium carbonate with various metal-organic frameworks to utilize the beneficial aspects from each of these constituents. The ambition was that these could be joined to render combined micro-/mesoporous core-shell structures, with high surface areas and many active sites whilst maintaining a good permeability. Numerous different synthesis routes were developed and explored in the pursuit of viable routes to design novel materials with potential future applications within for instance drug delivery, water harvesting from air and gas adsorption. Coreshell structures of the hydrophilic mesoporous magnesium carbonate covered with the hydrophobic zeolitic imidazole framework ZIF-8 was successfully synthesized for the first time, and practical studies demonstrated a dramatically enhanced water stability, which is perceived to have an impact on further research on these materials. ZIF-67 was also combined with mesoporous magnesium carbonate in a similar manner. Further, Mg-MOF-74 was grown directly from mesoporous magnesium carbonate, where the latter acted as a partially self-sacrificing template, with the aim of rendering a porous hierarchical structure with contributions from the micro- and mesoporous ranges. The outcomes of all these syntheses were characterized using several analyzing methods such as scanning electron microscopy, X-ray diffraction, energy dispersive spectroscopy and nitrogen sorption analysis.
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Ojo, Kolade Omoniyi. "Mesoporous Functionalized Materials for Post-Combustion Carbon Dioxide Capture." Digital Commons @ East Tennessee State University, 2011. https://dc.etsu.edu/etd/1378.

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Novel highly functionalized hybrid organic-inorganic materials were synthesized by polycondensation of bis[3-(trimethoxysilyl)propyl]amine in presence of cationic and anionic surfactants. Reaction media strongly affected gelation time. Thus, in basic media gelation occurred immediately while acid increased gelation time. Material structures were studied by IR spectroscopy, porosimetry, XRD, and SAXS methods. In spite of the absence of an inorganic linker, obtained bridged silsesquioxanes had mesoporous structure. A material prepared in the presence of dodecylamine as a template had higher surface area and narrow pore size distribution while the use of sodium dodecylbenzene sulfate resulted in formation of mesopores with wide size ranges. Accessibility of surface amine groups in silsesquioxanes was studied for molecules of acidic nature and different sizes: HCl, CO2 and picric acid. High contents of accessible amine groups in these materials make them prospective adsorbents for post-combustion CO2 capture.
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8

Atoini, Youssef. "New luminescent hybrid materials : synthesis and properties." Thesis, Strasbourg, 2017. http://www.theses.fr/2017STRAF004/document.

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L'objectif de cette thèse est la synthèse, la caractérisation et l'étude de complexes métalliquesluminescents, en particulier de Pt (II), leurs propriétés d'agrégation en solution, mais également dansun espace confiné ainsi qu’en surface. L'incorporation de complexes de métaux de transition dans lastructure poreuse, et ainsi que leur dépôt à la surface de nanoparticules et dans un cadre métalloorganique(MOF), par greffage post-synthétique, ont été étudiés. Sont également étudiés lacorrélation entre les propriétés de films d’une série de complexes de Pt(II) avec leur morphologie,leur mobilité électronique et la simulation de leur structure auto-assemblée par diffraction auxrayons-X. Les propriétés de luminescence de complexes amphiphiles de Pt(II) sont améliorées àl’intérieur de nanoparticules de silice mesoporeuse par la création d’un d’espace confiné. Un effetsimilaire est observé par le dépôt de complexes de Pt(II) fonctionnalisés sur une surface denanoparticules d’or. La luminescence d’un cadre organométallique a été modifiée par greffage postsynthétiquede complexes d’Ir(III) et de Pt(II)
The aim of this thesis is the synthesis, characterization and investigation of luminescent metalcomplexes, and in particular of Pt(II) compounds, their aggregation properties in solution but inconfined space as well. The incorporation of transition metal complexes in porous structure, and inparticular in a metal-organic framework (MOF), by post-synthesis grafting, have been investigated.Luminescence properties of amphiphilic Pt(II) complexes were enhanced inside mesoporous silicananoparticles by the creation of a confined space. Similar effect is observed by deposition offunctionalized Pt(II) complexes on gold nanoparticles surface. Luminescence of metal organicframework was tuned by post-synthetic grafting of Ir(III) and Pt(II) complexes
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Xing, Rong. "INVESTIGATION OF THE ASSEMBLY OF SURFACTANTS AT THE SOLID-LIQID INTERFACE FOR ADSORPTION AND MATERIALS APPLICATIONS." UKnowledge, 2007. http://uknowledge.uky.edu/gradschool_diss/510.

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This dissertation addresses two topics associated with the assembly of surfactants at the solid-liquid interface for adsorption and materials synthesis. The first is the adsorption of an anionic fluorinated surfactant, tetraethylammonium perfluorooctylsulfonate (TEA-FOS), at the solid/liquid interface. Attenuated total reflection Fourier transform infrared spectroscopy is used to study the adsorption kinetics and average orientation of surfactants at the hydroxylated germanium surface. Atomic force microscopy provides complementary images of the adsorbed layer structure on mica. The adsorption follows unusual three-stage kinetics in which the rate of adsorption starts fast, slows as the surface becomes crowded, and then (surprisingly) accelerates due to nucleation of a heterogeneous multilayer structure. These fast-slow-fast three stage adsorption kinetics are observed for a wide range of concentrations at pH 6, and the rates of the three stages are modulated by pH and salt by tuning electrostatic interactions among surfactants, counterions, and the surface. The results suggest that tetraethylammonium mediates interactions between surfactants and with negatively charged surfaces. The dichroism measurements and AFM are consistent with a mechanism in which TEA-FOS first forms an incomplete layer with chains oriented randomly or somewhat parallel to the surface, followed by formation of flattened multilayer clusters with the chains oriented somewhat normal to the substrate. The second topic is the sol-gel synthesis of mesoporous silica materials using dual surfactant templates. Studies of templating with mixed cetyltrimethylammonium bromide and octyl-beta-D-glucopyranoside surfactants shows that the ternary phase diagram of surfactants in water can be used to predict mesoporous materials structure, and that vapor-phase ammonia treatments can either stabilize the structure or induce swelling by the Maillard reaction. Studies of sol-gel reaction-induced precipitation with demixed hydrocarbon and fluorocarbon cationic surfactant micelles show a wide variety of pore structures. A number of synthesis parameters are adjusted to tune the pore structure, for instance to adjust the size and populations of bimodal mesopores. Selective swelling of the two surfactants by liphophilic and fluorophilic solvents is observed. Finally, proteinaccessible hollow spherical silica particles with mesoporous shells are reported. The methods for engineering mesoporous materials reported here have potential applications in adsorption, controlled drug delivery and for catalysis.
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Ordon, Karolina. "Functionalized semiconducting oxides based on bismuth vanadate with anchored organic dye molecules for photoactive applications." Thesis, Le Mans, 2018. http://www.theses.fr/2018LEMA1006/document.

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La recherche de nouveaux matériaux en tant que photocatalyseurs en lumière visible pour la dépollution de l’environnement (eaux, atmosphères) est un domaine de recherche très actif et suscite l’intérêt d’une large communauté scientifique en Physique, Chimie et Sciences des matériaux. Des recherches exhaustives sont actuellement menées pour améliorer l’efficacité photocatalytique de certaines classes de matériaux photoactifs connus, et pour développer la synthèse de nouveaux matériaux fonctionnels. Dans ce contexte, les semiconducteurs oxydes photoactifs à base de vanadates de bismuth (BiVO4) possédant une bande électronique au milieu du spectre visible, offrent une sérieuse alternative aux photocatalyseurs classiques efficaces (TiO2, ZnO) dont la photo-excitation requiert uniquement la fraction UV du spectre solaire. Le travail effectué dans le cadre de cette thèse est donc dédié aux matériaux à base BiVO4 sous forme d’architectures mésoporeuses ou d’assemblages hybrides associant des groupes organiques à transfert de charges.Deux contributions majeures ont été développées dont la première portant sur la réalisation expérimentale d’architectures mésoporeuses inédites, fonctionnalisées par des groupes organiques sensibilisateurs et l’étude de leurs propriétés électroniques et optiques en vue d’optimiser leurs efficacités photocatalytiques. La deuxième partie porte sur des simulations numériques de nanostructures hybrides par des approches exploitant la méthode DFT, ab-initio ou des modèles de chimie quantique. Des systèmes modèles ont été construits associant des nanoclusters (NC) et des groupes organiques (GO). Les propriétés électroniques et optiques ainsi que les caractéristiques structurelles et vibrationnelles des systèmes (NC-GO) ont été déterminées et confrontées aux données expérimentales. Les phénomènes de transfert de charges impliqués entre les groupes organiques et la structure inorganique ont été caractérisés ainsi que leur rôle dans l’efficacité des réponses photo-catalytiques des systèmes hybrides
The search for new materials as photocatalysts invisible light for the depollution of the environment (waters, atmospheres) is a very active field of research and attracts the interest of a large scientific community in Physics, Chemistry and Materials Science. Recent research developpements are conducted to improve the photocatalytic efficiency of certain classes of known photoactive materials, and to develop the synthesis of new functional materials. In this context, photoactive oxide semiconductors based on bismuth vanadate (BiVO4) having an electronic band in the middle of the visible spectrum, offer a serious alternative to efficient conventional photocatalysts (TiO2, ZnO) whose photo-excitation requires only the UV fraction of the solar spectrum.The work done in this thesis is therefore dedicated toBiVO4-based materials in the form of mesoporous architectures or hybrid assemblies associating organic groups with charge transfer processes. Two major contributions have been developed, one of which is the experimental realization of novel mesoporous architectures, functionalized by sensitizing organic groups and the study of their electronic and optical properties in order to optimize their photocatalytic efficiencies. The second part deals with numerical simulations of hybrid nanostructures using approaches as the DFT method, ab-initio or quantum chemistry codes. Model systems have been constructed associating BiVO4nanoclusters (NC) and organic groups (GO). The electronic and optical properties as well as the structural and vibrational characteristics of the systems (NC-GO) were determined and compared with the experimental data. The charge transfer phenomena involved between the organic groups and the inorganic structure were characterized as well as their role in the efficiency of photo-catalytic responses of hybrid systems
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Книги з теми "Organic-inorganic Hybrid Mesoporous Materials"

1

Zhu, Yun-Pei, and Zhong-Yong Yuan. Mesoporous Organic-Inorganic Non-Siliceous Hybrid Materials. Berlin, Heidelberg: Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-45634-7.

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2

C, Klein Lisa, ed. Organic/inorganic hybrid materials II. Warrendale, Penn: Materials Research Society, 1999.

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3

Sequeira, César A. C. Multifunctional Mesoporous Inorganic Solids. Dordrecht: Springer Netherlands, 1993.

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4

1934-, Mark James E., Lee C. Y.-C. 1947-, Biancini P. A. 1957-, and American Chemical Society. Division of Polymeric Materials: Science and Engineering., eds. Hybrid organic-inorganic composites. Washington, D.C: American Chemical Society, 1995.

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5

Grewal, Paramjit. Computational studies of inorganic-organic hybrid materials. Portsmouth: University of Portsmouth, 2004.

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6

Rurack, Knut, and Ramón Martínez-Máñez, eds. The Supramolecular Chemistry of Organic-Inorganic Hybrid Materials. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470552704.

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7

Knut, Rurack, and Martínez-Máñez Ramón, eds. The supramolecular chemistry of organic-inorganic hybrid materials. Hoboken, N.J: Wiley, 2010.

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8

1954-, Nalwa Hari Singh, ed. Handbook of organic-inorganic hybrid materials and nanocomposites. Stevenson Ranch, Calif: American Scientific Publishers, 2003.

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9

Lin, Ching-Fuh. Organic, inorganic, and hybrid solar cells: Principles and practice. Hoboken, NJ: Wiley, 2012.

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10

G, Hubert-Pfalzgraf Liliane, Najafi S. Iraj, and Society of Photo-optical Instrumentation Engineers., eds. Organic-inorganic hybrid materials for photonics: 19-20 July 1998, San Diego, California. Bellingham, Wash., USA: SPIE, 1998.

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Частини книг з теми "Organic-inorganic Hybrid Mesoporous Materials"

1

Fujita, Satoru, Mahendra P. Kapoor, and Shinji Inagaki. "Organic-Inorganic Hybrid Mesoporous Silica." In Nanohybridization of Organic-Inorganic Materials, 141–69. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-92233-9_7.

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2

Slowing, Igor I., Brian G. Trewyn, and Victor S. Y. Lin. "Nanogated Mesoporous Silica Materials." In The Supramolecular Chemistry of Organic-Inorganic Hybrid Materials, 479–502. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470552704.ch16.

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3

Hoffmann, Frank, and Michael Fröba. "Silica-Based Mesoporous Organic-Inorganic Hybrid Materials." In The Supramolecular Chemistry of Organic-Inorganic Hybrid Materials, 37–111. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470552704.ch3.

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4

Dunphy, Darren R., Bernd Smarsly, and C. Jeffrey Brinker. "Control of Morphology in Mesoporous and Mesostructured Hybrid Materials." In The Supramolecular Chemistry of Organic-Inorganic Hybrid Materials, 531–45. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470552704.ch18.

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Mitzi, David B. "Hybrid Organic-Inorganic Electronics." In Functional Hybrid Materials, 347–86. Weinheim, FRG: Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527602372.ch10.

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Sugahara, Yoshiyuki. "Organic-Inorganic Hybrid Materials." In Materials Chemistry of Ceramics, 213–33. Singapore: Springer Singapore, 2019. http://dx.doi.org/10.1007/978-981-13-9935-0_10.

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Mackenzie, J. D. "Hybrid Organic—Inorganic Materials." In ACS Symposium Series, 226–36. Washington, DC: American Chemical Society, 1995. http://dx.doi.org/10.1021/bk-1995-0585.ch017.

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Hüsing, Nicola, and Ulrich Schubert. "Porous Inorganic-Organic Hybrid Materials." In Functional Hybrid Materials, 86–121. Weinheim, FRG: Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527602372.ch4.

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Kango, Sarita, Susheel Kalia, Pankaj Thakur, Bandna Kumari, and Deepak Pathania. "Semiconductor–Polymer Hybrid Materials." In Organic-Inorganic Hybrid Nanomaterials, 283–311. Cham: Springer International Publishing, 2014. http://dx.doi.org/10.1007/12_2014_295.

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Gualandi, Chiara, Annamaria Celli, Andrea Zucchelli, and Maria Letizia Focarete. "Nanohybrid Materials by Electrospinning." In Organic-Inorganic Hybrid Nanomaterials, 87–142. Cham: Springer International Publishing, 2014. http://dx.doi.org/10.1007/12_2014_281.

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Тези доповідей конференцій з теми "Organic-inorganic Hybrid Mesoporous Materials"

1

Frunza, Ligia, Hendrik Kosslick, Andreas Schonhals, Irene Pitsch, and Stefan Frunza. "Dynamic behavior of hybrid organic-inorganic composites: liquid crystals confined in SBA-15 mesoporous materials." In International Symposium on Optical Science and Technology, edited by Iam-Choon Khoo. SPIE, 2002. http://dx.doi.org/10.1117/12.453885.

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2

Vu, Trinh, Highqueen Sarpomah, Michael Kamen, Tolessa Deksissa, and Jiajun Xu. "Nanoparticles Infused Mesoporous Material for Water Treatment Processes." In ASME 2017 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/imece2017-70475.

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In current study, a hybrid mesoporous material infused with metallic oxide nanoparticles, MCM-48 with TiO2 nanoparticles, has been developed for potential application in water treatment. Using this unique hybrid structure, it can combine the advantages of the effective pollutants removal capability of metallic oxide nanoparticles, and the strong yet high permeable structure of mesoporous material. A modified hydrothermal method has been developed to synthesize three hybrid samples with TiO2 nanoparticles of three assorted sizes (15, 50 and 300nm), and their structure have also been characterized. The synthesized samples are tested for its capability of removing organic dye and trace metals using ICP-MS. The results have shown that while all three hybrid materials have shown over 80% adsorption rate for organic dye, the sample synthesized using 300nm TiO2 nanoparticle has shown the highest adsorption rate. Similarly, the highest adsorption rate for most trace metals test here also occurs in the sample made with 300nm TiO2 nanoparticle. Coincidentally, the sample prepared with 300nm TiO2 nanoparticle has a much larger internal surface area and smaller average pore size compared to the two other samples, which may lead to the higher adsorption rate of trace metals and organic dye tested here. This study has presented a hybrid mesoporous material that can be potentially used for pollutants removal of water treatment. Future studies are still needed to fully explore this hybrid material and its capability in water treatment.
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3

Armani, Andrea M., Jinghan He, Andre Kovach, and Hyungwoo Choi. "Hybrid Organic/Inorganic Integrated Photonics." In Novel Optical Materials and Applications. Washington, D.C.: OSA, 2019. http://dx.doi.org/10.1364/noma.2019.nom2b.2.

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4

Cook, G., V. Reshetnyak, A. V. Glushchenko, M. A. Saleh, and D. R. Evans. "Nanoparticle Doped Organic-Inorganic Hybrid Photorefractives." In Photorefractive Effects, Photosensitivity, Fiber Gratings, Photonic Materials and More. Washington, D.C.: OSA, 2007. http://dx.doi.org/10.1364/pr.2007.suc3.

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5

Katayama, Junko, Shigeru Yamaki, Masahiro Mitsuyama, and Makoto Hanabata. "Organic-inorganic hybrid materials for nanoimprint lithography." In SPIE 31st International Symposium on Advanced Lithography, edited by Michael J. Lercel. SPIE, 2006. http://dx.doi.org/10.1117/12.655053.

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6

Toropov, Nikita A., Aisylu N. Kamalieva, and Tigran A. Vartanyan. "Organic-inorganic planar hybrid materials for spasers." In SPIE Optics + Optoelectronics, edited by Mario Bertolotti, Joseph W. Haus, and Alexei M. Zheltikov. SPIE, 2015. http://dx.doi.org/10.1117/12.2178660.

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7

Dinesh, M. Redemeyer, Mukesh Kumar, S. Dalela, S. K. Tripathi, Keya Dharamvir, Ranjan Kumar, and G. S. S. Saini. "3D Isostructurality of Inorganic-Organic Hybrid Materials." In INTERNATIONAL CONFERENCE ON ADVANCES IN CONDENSED AND NANO MATERIALS (ICACNM-2011). AIP, 2011. http://dx.doi.org/10.1063/1.3653692.

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8

Kamada, K., S. Kurosawa, Y. Yokota, T. Yanagida, M. Nikl, and A. Yoshikawa. "Functional possibilities of inorganic-organic hybrid scintillator." In 2013 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 2013. http://dx.doi.org/10.7567/ssdm.2013.ps-8-21.

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9

Dou, Letian. "Two-dimensional organic-inorganic hybrid perovskites (Conference Presentation)." In Oxide-based Materials and Devices X, edited by Ferechteh H. Teherani, David C. Look, and David J. Rogers. SPIE, 2019. http://dx.doi.org/10.1117/12.2516752.

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10

Sugino, Naoto, Makoto Hanabata, and Satoshi Takei. "Organic-inorganic hybrid resist materials in advanced lithography." In Nanoengineering: Fabrication, Properties, Optics, and Devices XIV, edited by Eva M. Campo, Elizabeth A. Dobisz, and Louay A. Eldada. SPIE, 2017. http://dx.doi.org/10.1117/12.2275105.

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Звіти організацій з теми "Organic-inorganic Hybrid Mesoporous Materials"

1

Lai, Peng. Mesoporous Silicia Nanowires by Space-Confined Organic-Inorganic Hybrid Self-Assembly. Office of Scientific and Technical Information (OSTI), October 2007. http://dx.doi.org/10.2172/990221.

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2

Haddad, Tim, and Shawn Phillips. Nanostructured Hybrid Organic/Inorganic Materials. Silsesquioxane Modified Plastics. Fort Belvoir, VA: Defense Technical Information Center, December 1998. http://dx.doi.org/10.21236/ada409298.

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3

Francis, Matthew. Virus-Based Scaffolds for Organic/Inorganic Hybrid Materials. Fort Belvoir, VA: Defense Technical Information Center, January 2006. http://dx.doi.org/10.21236/ada455770.

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4

Haddad, Timothy S., Russell Stapleton, Hong G. Jeon, Patrick T. Mather, and Joseph D. Lichtenhan. Nanostructured Hybrid Organic/Inorganic Materials, Silsesquioxane Modified Plastics. Fort Belvoir, VA: Defense Technical Information Center, January 1996. http://dx.doi.org/10.21236/ada386916.

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5

Bulovic, Vladimir. Integrated Vacuum Growth System for Hybrid Organic-Inorganic Materials. Fort Belvoir, VA: Defense Technical Information Center, March 2004. http://dx.doi.org/10.21236/ada422230.

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6

Phillips, Shawn H., Timothy S. Haddad, and Rusty L. Blanski. New Multi-Functional Materials Using Versatile Hybrid (Inorganic/Organic) POSS Nanotechnology. Fort Belvoir, VA: Defense Technical Information Center, April 2001. http://dx.doi.org/10.21236/ada410570.

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7

Jamison, G. M., D. A. Loy, R. S. Saunders, and T. M. Alam. LDRD final report on polyphosphaacetylenes, new hybrid conducting organic-inorganic materials. Office of Scientific and Technical Information (OSTI), June 1996. http://dx.doi.org/10.2172/270675.

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8

Bulovic, Vladimir. PECASE: Nanostructure Hybrid Organic/Inorganic Materials for Active Opto-Electronic Devices. Fort Belvoir, VA: Defense Technical Information Center, January 2011. http://dx.doi.org/10.21236/ada547102.

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