Готові списки джерел за темами / Nikolaev

Добірка наукової літератури з теми "Nikolaev"

Автор: Grafiati
Опубліковано: 30 травня 2022
Оновлено: 31 травня 2022

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Статті в журналах з теми "Nikolaev"

1

Khubaeva, Lana К. "Vladikavkaz Nikolaev School." Vestnik of North-Ossetian State University, no. 1(2021) (March 25, 2021): 50–56. http://dx.doi.org/10.29025/1994-7720-2021-1-50-56.

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The article is devoted to the Vladikavkaz city Nikolaev school, which was opened in 1874. Documents preserved in the fund of the Public Schools Directorate of the Central State Archive (CSA) of the Republic of North Ossetia-Alania indicate that the school was a male educational institution and the name of the school was named after Nikolai Ugodnik. The school was originally a four-year school, later, in 1897, it was transformed into a six-year school. It was subordinate to the Ministry of Public Education and the Directorate of public schools in the Terek region. On November 3, 1895, the Society for Aid to the Poorest Students of the Vladikavkaz Nikolaev School was officially registered at the school. The fact of the creation of such a Society testifies to the fact that the school was not intended exclusively for children of privileged classes. The October Revolution made great changes in the educational system established by this period. Many schools have ceased to function. The same fate befell the Nikolaev School, but not immediately. The educational institution managed to prepare several generations of graduates who continued their education in higher educational institutions before and post-revolutionary Russia. The Nikolaev school entered the history of Vladikavkaz as a source of enlightenment, thanks to which dozens of young people who did not live not only in Vladikavkaz, but also those who entered here from remote areas of the region received education. The school existed until 1921, having survived two Russian revolutions and the period of the First World War.
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2

Ananiev, Vitaly G. "A. S. Nikolaev in the Institute of Out-of-School Education and His ‘Museum of Archival Work’ Project." Herald of an archivist, no. 4 (2018): 1254–65. http://dx.doi.org/10.28995/2073-0101-2018-4-1254-1265.

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The article is devoted to the work Alexander S. Nikolaev (1877 – 1934) in the Petrograd Institute of Out-of-School Education in late 1910s – early 1920s. His teaching activities at the Institute and the place of archival issues in the program of its museum department have been studied on the basis of archival documents. The Institute initially focused on training of instructors and employees of cultural institutions, school teachers for adults and universities professors. The Institute had a museum section (department – faculty), on the basis of which several exemplary workshops for creating of manuals and their mastering were to be organized. That is the context in which A. S. Nikolaev’s projects of archival museum creation should be studied. One of such projects worked out by Nikolaev at that time has gone unnoticed until its publication in the Appendix. The connection of this project with the development level of museum affairs of the period is shown. Nikolaev's aspiration to show evolution of archiving and to follow fond formation stage by stage and his use of photographic and graphic materials are also noted. Moreover, it is the first assessment of the work of the Institute as one of the centers for teaching archiving in late 1910s – early 1920s.Training at the museum department of the Institute included a number of courses in both archiving and preservation of documentary monuments. This was due not only to the traditional proximity of archiving and museum work, but also to the circumstances of the first post-revolutionary years. Many museums (located in palaces and mansions of nobility) acquired valuable archival collections. They looked for an opportunity to use these in their scientific activities and exhibitions. The latter was due to the emphasis put on history of daily life and introduction of sociological method in museum work.
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3

Naumov, A. G., A. S. Shprykov, D. A. Sutyagina, E. R. Kryukov, P. A. Bochkarev, and M. A. Spiridonov. "Surgeon, citizen, teacher (to the 100th anniversary of the birth of Professor I.S. Nikolaev)." Kazan medical journal 102, no. 1 (February 10, 2021): 110–14. http://dx.doi.org/10.17816/kmj2021-110.

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The article provides information about a prominent Nizhny Novgorod surgeon, the first head of the tuberculosis department of the Gorky Medical Institute named after S.M. Kirov (now Privolzhsky Research Medical University) Ivan Semenovich Nikolaev. Ivan Semyonovich Nikolaev went through the horrors of the Great Patriotic War, worked with prominent doctors of his time (L.V. Bogush, B.A. Korolev, S.S. Yudin), achieved unprecedented success in the surgical treatment of pulmonary and extrapulmonary tuberculosis, received the degree of Doctor of Medical Sciences after defending the candidate's thesis (for the first time in the history of the Gorky Medical Institute named after S.M. Kirov) due to the uniqueness and fundamental nature of the scientific materials presented. Professor Ivan Semyonovich Nikolaev successfully combined pedagogical, scientific and medical work with great organizational and social work. For many years, I.S. Nikolaev was a member of the board of the All-Union and All-Russian Society of Phthisiologists, for more than 20 years he was the Chairman of the Board of the Gorky Scientific Medical Society of Phthisiologists, a member of the editorial board of the journal Problems of Tuberculosis. Many times Ivan Semyonovich Nikolaev represented the Nizhny Novgorod phthisiology and medical institute at the All-Union and All-Russian congresses and conferences of phthisiologists was a member of their presidiums. In 1988, Ivan Semyonovich Nikolaev, due to his age, left the position of head of the tuberculosis department and worked as a consultant professor for several years, and then retired. In recent years, he lived in his native village Paustovo (Vyaznikovsky district, Vladimir region). In 1999, Ivan Semyonovich died.
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4

Николаев, Андрей Борисович. "Reflections on Tsuyoshi Hasegawa’s Review." Journal of Modern Russian History and Historiography 6, no. 1 (2013): 17–34. http://dx.doi.org/10.1163/22102388-00600004.

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This article is a response to Tsuyoshi Hasegawa’s review of Nikolaev’s 2005 book, Revolution and Power: The IV State Duma, 27 February – 3 March 1917. It recounts the history of Nikolaev’s acquaintance with Hasegawa and underscores the importance of Hasegawa’s contributions to the understanding of the February Revolution. The response critically assesses Hasegawa’s interpretation of the February 1917 Revolution, especially his treatment of the role of Duma liberals and his emphasis on mass politics, but only in so far as the interpretation colors Hasegawa’s review of Nikolaev’s book. Nikolaev’s response adds new details to the history of the February Revolution, by showing how, on the evening of 27 February, the 1st Infantry Reserve Regiment joined the revolution. Nikolaev emphasizes that his main ambition is to persuade historians to take a new look at the role of the Duma liberals in February 1917.
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5

Protsyuk, Y., and A. Mazhaev. "Astronomical databases of Nikolaev Observatory." Proceedings of the International Astronomical Union 3, S248 (October 2007): 548–52. http://dx.doi.org/10.1017/s1743921308020127.

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AbstractSeveral astronomical databases were created at Nikolaev Observatory during the last years. The databases are built by using MySQL search engine and PHP scripts. They are available on NAO web-site http://www.mao.nikolaev.ua.
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6

Chernets, Liliya. "P.A. Nikolaev – President of MAPRYAL." Stephanos. Peer reviewed multilanguage scientific journal 22, no. 2 (March 30, 2017): 172–77. http://dx.doi.org/10.24249/2309-9917-2017-22-2-172.

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7

Waldschmidt, Michel. "On a paper by Nikolaev." Ramanujan Journal 57, no. 4 (February 12, 2022): 1517–18. http://dx.doi.org/10.1007/s11139-021-00406-x.

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8

Hasegawa, Tsuyoshi. "Review of A. B. Nikolaev, Revoliutsiia i vlast’: How Has Nikolaev Changed the Interpretation of the February Revolution?" Journal of Modern Russian History and Historiography 6, no. 1 (2013): 1–16. http://dx.doi.org/10.1163/22102388-00600003.

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A.B. Nikolaev’s book has not received much attention either in the West or in Russia, but it is an important book that has significantly changed our understanding the February Revolution of 1917. Nikolaev’s meticulously researched monograph, based on a wide array of new sources, challenges the previously dominant interpretation that the Provisional Committee of the State Duma (Duma Committee) was forced to seize power only to stem the tide of the insurgency from below. He argues that the Duma Committee was from its inception clear about its intention to overthrow the old regime and to create a new power to replace it even before the Petrograd Soviet was formed. The Duma Committee played a crucial role in prompting military units to take the side of the revolution, in steering the insurgents to the State Duma, in creating the Military Commission to organize insurgents to occupy strategic positions in the city, in taking over the food supply commission to feed the insurgents, in attacking and destroying the tsarist police, while preventing and suppressing potentially dangerous anarchical pogroms, and in taking control over the imperial bureaucracy. Nikolaev also raises an interesting question about the relationship between the Duma Committee, the State Duma and the Provisional Government by arguing that the Provisional Government made a hasty and cardinal mistake in cutting its relationship with the State Duma. This book is a landmark in the interpretation of the February Revolution, and especially of the role of the Duma liberals in the revolution.
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9

Ivantsov, Anatoliy. "Asteroid mass determination at Nikolaev Observatory." Planetary and Space Science 56, no. 14 (November 2008): 1857–61. http://dx.doi.org/10.1016/j.pss.2008.02.033.

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10

Komisar, Olena, and Natalia Zagorodniuk. "Bryophytes industrial area of Nikolaev city." Chornomorski Botanical Journal 8, no. 1 (March 1, 2012): 87–97. http://dx.doi.org/10.14255/2308-9628/12.81/9.

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Дисертації з теми "Nikolaev"

1

Borissov, Nikolay Nikolaev [Verfasser], and C. [Akademischer Betreuer] Weinhardt. "Automated Bidding in Computing Service Markets : Strategies, Architectures, Protocols / Nikolay Nikolaev Borissov. Betreuer: C. Weinhardt." Karlsruhe : KIT-Bibliothek, 2012. http://d-nb.info/1021726192/34.

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2

Sprenger, Julia U. [Verfasser], Viacheslav [Akademischer Betreuer] Nikolaev, and Peter [Akademischer Betreuer] Schu. "Local cAMP dynamics in the SERCA2a signalling complex / Julia U. Sprenger. Gutachter: Viacheslav Nikolaev ; Peter Schu. Betreuer: Viacheslav Nikolaev." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://d-nb.info/1061172058/34.

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Jetchev, Nikolay N. [Verfasser]. "Learning representations from motion trajectories : analysis and applications to robot planning and control / Nikolay Nikolaev Jetchev." Berlin : Freie Universität Berlin, 2012. http://d-nb.info/1027151604/34.

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4

Perera, Ruwan K. [Verfasser], Viacheslav [Akademischer Betreuer] Nikolaev, and Blanche [Akademischer Betreuer] Schwappach. "Phosphodiesterases as Crucial Regulators of Cardiomyocyte cAMP in Health and Disease / Ruwan K. Perera. Gutachter: Viacheslav Nikolaev ; Blanche Schwappach. Betreuer: Viacheslav Nikolaev." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://d-nb.info/1061172074/34.

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5

Hofmann, Sandra [Verfasser], Viacheslav [Akademischer Betreuer] [Gutachter] Nikolaev, and Stephan E. [Gutachter] Lehnart. "Einfluss der Herzinsuffizienz auf Membranstrukturen und lokale cAMP-Dynamiken der SERCA2a-Mikrodomäne / Sandra Hofmann ; Gutachter: Viacheslav Nikolaev, Stephan E. Lehnart ; Betreuer: Viacheslav Nikolaev." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://d-nb.info/1120117569/34.

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6

Geibel, Uta [Verfasser], Viacheslav O. [Akademischer Betreuer] [Gutachter] Nikolaev, Marcus [Gutachter] Niebert, and Rainer [Gutachter] Mausberg. "Entwicklung und Validierung eines neuen Schnellmessverfahrens für Adrenalin im Blutserum / Uta Geibel ; Gutachter: Viacheslav O. Nikolaev, Marcus Niebert, Rainer Mausberg ; Betreuer: Viacheslav O. Nikolaev." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2017. http://d-nb.info/114323104X/34.

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7

Bikkenin, Oskar. "Nikolai Tscherepnins Svat [Der Heiratsvermittler]." Universitätsbibliothek Leipzig, 2017. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-221319.

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Unter den Genres des russischen Musiktheaters hat die komische Oper die längste Tradition. Entstanden in den siebziger Jahren des 18. Jahrhunderts, blieb sie bis ins erste Drittel des 19. Jahrhunderts hinein die einzige professionelle musiktheatralische Gattung. Nationale Genrekennzeichen sind das Lyrische, das Phantastische und das Satirische sowie die Vermischung dieser Züge, wie man sie beispielsweise in der Mainacht von Rimski-Korsakow, in Wakula der Schmied von Tschaikowsky und in der Hochzeit von Mussorgski findet, um nur einige herausragende Beispiele des 19. Jahrhunderts zu nennen. Diese genrespezifischen Eigenschaften wurden im 20. Jahrhundert größtenteils beibehalten. Neben den bekannten Werken Igor Strawinskys, Sergei Prokofjews und Dmitri Schostakowitschs stellen die Opern Nikolai Tscherepnins in der ersten Jahrhunderthälfte einen interessanten Sonderweg dar.
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8

Nikolaev, Alexander [Verfasser]. "Determination of the η mass from the production threshold for the γp → pη reaction / Alexander Nikolaev. Mathematisch-Naturwissenschaftliche Fakultät". Bonn : Universitäts- und Landesbibliothek Bonn, 2012. http://d-nb.info/1019451874/34.

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9

Lämmle, Simon [Verfasser], Ali [Akademischer Betreuer] El-Armouche, and Viacheslav [Akademischer Betreuer] Nikolaev. "Die Rolle der Phosphodiesterase 2 im Herzen / Simon Lämmle. Gutachter: Ali El-Armouche ; Viacheslav Nikolaev. Betreuer: Ali El-Armouche." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://d-nb.info/1063154405/34.

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10

Bikkenin, Oskar. "Nikolai Tscherepnins Svat [Der Heiratsvermittler]: Möglichkeiten der komischen Oper im 20. Jahrhundert." Musikgeschichte in Mittel- und Osteuropa ; 3 (1998), S. 74-77, 1998. https://ul.qucosa.de/id/qucosa%3A15453.

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Unter den Genres des russischen Musiktheaters hat die komische Oper die längste Tradition. Entstanden in den siebziger Jahren des 18. Jahrhunderts, blieb sie bis ins erste Drittel des 19. Jahrhunderts hinein die einzige professionelle musiktheatralische Gattung. Nationale Genrekennzeichen sind das Lyrische, das Phantastische und das Satirische sowie die Vermischung dieser Züge, wie man sie beispielsweise in der Mainacht von Rimski-Korsakow, in Wakula der Schmied von Tschaikowsky und in der Hochzeit von Mussorgski findet, um nur einige herausragende Beispiele des 19. Jahrhunderts zu nennen. Diese genrespezifischen Eigenschaften wurden im 20. Jahrhundert größtenteils beibehalten. Neben den bekannten Werken Igor Strawinskys, Sergei Prokofjews und Dmitri Schostakowitschs stellen die Opern Nikolai Tscherepnins in der ersten Jahrhunderthälfte einen interessanten Sonderweg dar.
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Книги з теми "Nikolaev"

1

Ivan Nikolaev. Moskva: Russkiĭ avangard, 2008.

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2

Abukaev-Ėmgak, Vi︠a︡cheslav. Semen Nikolaev: Vashmutlanymash, statʹi︠a︡. Ĭoshkar-Ola: Respublikyse ustalyk ru̇der, 1996.

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3

Urmanova, Kamilla Nadyrovna. Alekseĭ Nikolaev: Zhiznʹ v muzyke. Moskva: Moskovskai︠a︡ gos. konservatorii︠a︡ im. P.I. Chaĭkovskogo, 2004.

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4

P, Zaĭt͡seva A., та I͡Akovlev I. I, ред. Anatoliĭ Vasilʹevich Nikolaev, 1902-1977. Moskva: "Nauka", 1992.

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5

Ustinov, I︠U︡ S. Kosmonavt no. 3 Andrii︠a︡n Nikolaev. Moskva: Geroi Otechestva, 2004.

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6

Kalchev, Kalcho. General Danail Nikolaev: Biografichen portret. Sofii︠a︡: Izd-vo na Ministerstvoto na otbranata "Sv. Georgi Pobedonoset︠s︡", 1995.

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7

Staryĭ Nikolaev: Toponimicheskiĭ slovarʹ-spravochnik. Nikolaev: Izdatelʹstvo Iriny Gudym, 2008.

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8

Peev, I͡Urdan. Generalŭt ot pekhotata Danail Nikolaev. Sofii͡a: Voennoizdatelski kompleks "Sv. Georgi Pobedonoset͡s", 1993.

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9

Umerenkov, A. Zdravstvui, gorod korabelov [Nikolaev]: Putevoditel'. Odessa: Mayak, 1986.

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10

Mangachev, Petko. D-r Nikolaĭ Nikolaev -- zhivot i delo, (1887 g.--1960 g.). Sofii︠a︡: Kolbis, 2007.

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Частини книг з теми "Nikolaev"

1

Petrov, G. M., R. T. Fedorova, and P. N. Fedorov. "The Vacuum Mires of the Transit Instrument at Nikolaev." In Astrometric Techniques, 529–31. Dordrecht: Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4676-7_66.

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2

Shornikov, O. E., A. V. Shulga, N. S. Liadovoi, S. L. Kashtalian, and P. V. Maigurov. "The Nikolaev Axial Meridian Circle: The Present and Future Status." In Inertial Coordinate System on the Sky, 88. Dordrecht: Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-009-0613-6_24.

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3

Lukanitschewa, Swetlana. "Evreinov, Nikolaj Nikolaevič." In Kindlers Literatur Lexikon (KLL), 1. Stuttgart: J.B. Metzler, 2020. http://dx.doi.org/10.1007/978-3-476-05728-0_396-1.

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4

Drews-Sylla, Gesine. "Aleškovskij, Juz: Nikolaj Nikolaevič." In Kindlers Literatur Lexikon (KLL), 1–2. Stuttgart: J.B. Metzler, 2020. http://dx.doi.org/10.1007/978-3-476-05728-0_43-1.

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Lukanitschewa, Swetlana. "Evreinov, Nikolaj Nikolaevič: Teatralizacija žizni." In Kindlers Literatur Lexikon (KLL), 1–2. Stuttgart: J.B. Metzler, 2020. http://dx.doi.org/10.1007/978-3-476-05728-0_397-1.

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6

Buckley, Mary. "Nikolai." In Soviet Social Scientists Talking, 90–96. London: Palgrave Macmillan UK, 1986. http://dx.doi.org/10.1007/978-1-349-18350-0_16.

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Diller, Axel. "Lenau, Nikolaus." In Kindlers Literatur Lexikon (KLL), 1. Stuttgart: J.B. Metzler, 2020. http://dx.doi.org/10.1007/978-3-476-05728-0_7353-1.

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8

Koopmann, Helmut. "Nikolaus Lenau." In Kindler Kompakt: Deutsche Literatur, 19. Jahrhundert, 118–22. Stuttgart: J.B. Metzler, 2015. http://dx.doi.org/10.1007/978-3-476-05521-7_14.

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Kremer, Richard. "Nikolaus Kopernikus." In Kindler Kompakt Klassiker der Naturwissenschaften, 53–55. Stuttgart: J.B. Metzler, 2016. http://dx.doi.org/10.1007/978-3-476-05529-3_8.

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10

Walker, Rachel. "Nikolaas Tinbergen." In Encyclopedia of Animal Cognition and Behavior, 1–5. Cham: Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-47829-6_488-1.

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Тези доповідей конференцій з теми "Nikolaev"

1

Pinigin, Gennadiy, Magda Stavinschi, Vasile Mioc, Cristiana Dumitrache, and Nedelia A. Popescu. "Bucharest-Nikolaev Astronomical Observatories’ Collaboration in Astronomy." In EXPLORING THE SOLAR SYSTEM AND THE UNIVERSE. AIP, 2008. http://dx.doi.org/10.1063/1.2993704.

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2

Maigurova, Nadezhda, Gennady Pinigin, Vasile Mioc, Cristiana Dumitrache, and Nedelia A. Popescu. "Results of CCD Observations of Ecliptic Zone in Nikolaev Observatory." In EXPLORING THE SOLAR SYSTEM AND THE UNIVERSE. AIP, 2008. http://dx.doi.org/10.1063/1.2993635.

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3

Parkhomov, Vladimir. "The Fate of People and Machines." In Irkutsk Historical and Economic Yearbook 2020. Baikal State University, 2020. http://dx.doi.org/10.17150/978-5-7253-3017-5.49.

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Анотація:
An attempt was made to relate to one source the fate of a man born at the Krutoy mine and who died in fascist captivity and the history of a machine whose existence ended at the mine created at the Nikolaev Ironworks, the construction director of which was Ivan Antonovich Barozzi de Els.
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4

Cocieru, Mariana. "Folclorul ca act de conservare al conștiinței naționale." In Conferința științifică națională "Sergiu Moraru: 75 de ani de la naștere". “Bogdan Petriceicua-Hasdeu” Institute of Romanian Philology, Republic of Moldova, 2021. http://dx.doi.org/10.52505/sm.75.2021.05.

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In this approach we will refer to an article-synthesis „Folklore ‒ a factor of preservation of national consciousness” signed by Sergiu Moraru with reference to the awareness of folklorists in Bessarabia of the urgent need to safeguard the elements of traditional culture of Romanians in Moldova , Ukraine (Odessa region, Chernivtsi, Nikolaev, Kirovohrad), Russian Federation (Krasnodar region) in the postwar period. We will also reflect on the development of folklore research by establishing scientific criteria for investigating and publishing field-recorded folklore materials, with the necessary parallels on the emergence of the first collections of cultural memory samples in general Romanian folklore.
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5

Nikolaev, Yu A., E. V. Demkina, I. V. Perminova, N. G. Loiko, I. A. Borzenkov, A. E. Ivanova, A. I. Konstantinov, and G. I. El-Registan. "The effect of humic substances on increasing the viability of hydrocarbon-oxidizing bacteria." In Fifth International Conference of CIS IHSS on Humic Innovative Technologies «Humic substances and living systems». CLUB PRINT ltd., 2019. http://dx.doi.org/10.36291/hit.2019.nikolaev.075.

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6

Suslov, A. Yu. "Semyon Nikolaevich Nikolaev (1880–1976): on the biography of the last deputy of the All-Russian Constituent Assembly." In Civil War in the East of Russia (November 1917 – December 1922). FUE «Publishing House SB RAS», 2019. http://dx.doi.org/10.31518/978-5-7692-1664-0-410-416.

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7

Egorov, P. M. "ON THE ISSUE OF POLICY IN THE FIELD OF FOREIGN ECONOMIC ACTIVITY OF THE REPUBLIC OF SAKHA (YAKUTIA) DURING THE PRESIDENCY OF M.E. NIKOLAEV." In Внешние связи Якутии сквозь призму времени. Институт гуманитарных исследований и проблем малочисленных народов Севера Сибирского отделения РАН, 2019. http://dx.doi.org/10.25693/epm18.11.19.

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8

Mainland, Geoffrey, and Greg Morrisett. "Nikola." In the third ACM Haskell symposium. New York, New York, USA: ACM Press, 2010. http://dx.doi.org/10.1145/1863523.1863533.

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9

Vseviov, Lev. "Bibliorraphy of Nikolay Kirpichnikov's works." In Our earth is great and plentiful. Institute for the History of Material Culture Russian Academy of Sciences, 2019. http://dx.doi.org/10.31600/978-5-907053-29-8-2019-11-13.

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10

"Assessment of Formula-Based Structural Annotation of Humic Substances by Mild Chemical Derivatization and Mass Spectrometry." In Sixth International Conference on Humic Innovative Technologies "Humic Substances and Eco-Adaptive Technologies ”(HIT – 2021). Non-Commercial Partnership "Center for Biogenic Resources "Humus Sapiens" (NP CBR "Humus Sapiens"), 2021. http://dx.doi.org/10.36291/hit.2021.mikhnevich.002.

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Анотація:
Natural organic matter (NOM) plays an important role in the environment and its chemical properties and molecular composition reflect balance between mineralization and sequestration of organic carbon. Ultrahigh resolution mass spectrometry (e.g., FTICR MS) provides essential molecular information about NOM. However, NOM molecular heterogeneity prevents application of tandem MS experiments and direct structural information is ultimately missing leaving opportunities to only ambiguous formula-based annotation. The main aim of this work was to develop a chemical workflow to reliably examine the accuracy of several FTICR MS-derived structural indices with the focus on aromaticity and O-functional groups, which greatly impact compound properties. Four NOM samples of different origin (coal, oxidized lignin, river, and permafrost thaw) were brominated by NBS in acetonitrile for 24 hrs at RT. Carboxylic groups in all samples were determined by selective deuteromethylation using CD 3OD/SOCl2 reaction and by HATU amidation with 15N labeled glycine. Carbonyl groups were reduced by NaBD4. All parent and labeled mixtures were analyzed by ESI FTCR MS. Custom python scripts were developed to treat spectra and enumerate specific structural moieties in individual components. Obtained data was used to assess reliability of exact aromaticity indices (AI)1 and aromaticity equivalents (Xc) 2. Lignin- and coal-derived samples turned out to be the most sensitive to bromination which corroborated with the model phenolic structures. On contrary, permafrost thaw, which is enriched with labile species, was mostly resistant to bromination - 22% of molecular ions were brominated. Moreover, unlike oxidized riverine sample, coal NOM included polybrominated species, which implies that reaction efficiency depends on reactivity (i.e. substituents) of aromatic fragments. Samples were characterized by drastically different bromine distributions on van Krevelen diagrams, which correlated with the distribution of non-carboxylic oxygen atoms. Further, we compared AI and Xc aromaticity indices in terms of the proportion of correctly assigned aromatics. The data on brominated molecules were in good agreement with the AI values; however, apparently AI tends to overestimate the number of non-aromatics in the sample since it describe averaged aromaticity rather than the factual presence of aromatic ring. On the other hand, Xc perfectly recognized non-aromatics. In general, a higher proportion of correctly attributed aromatics was observed for the aromaticity equivalent Xc (up to 68%), which tends to find aromatic moieties in non-aromatic molecules assigned by AI. Still, we observed a number of aromatic- and condensed aromatic-assigned compounds, which were resistant to bromination or included lesser Br-atoms than the evaluated number of aromatic rings. Reaction with NaBD4 and enumeration of labeling series revealed the presence of carbonyl groups in these species, which in case of multiple reducing could be reliably assigned to quinone – condensed non-aromatic compounds. The approach may be of great importance in biogeochemical and medicinal studies of NOM. Acknowledgements. This work was supported by the Russian Science Foundation gran No 21-47-04405. References 1. Zherebker, A., Lechtenfeld, O. J., Sarycheva, A., Kostyukevich, Y., Kharybin, O., Fedoros, E. I. and Nikolaev, E. N. Anal. Chem., 2020, 92 (13), 9032-9038; 2. Yassine, M.M., Harir, M., Dabek-Zlotorzynska, E. and Schmitt-Kopplin, P. Rapid Commun. Mass Spectrom., 2014, 28, 2445-2454.
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Звіти організацій з теми "Nikolaev"

1

Burns, L. E., G. R. C. Graham, and J. D. Barefoot. Nikolai electromagnetic and magnetic airborne geophysical survey data compilation. Alaska Division of Geological & Geophysical Surveys, January 2020. http://dx.doi.org/10.14509/30262.

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2

Yevtuch, Mykola B., Vasyl M. Fedorets, Oksana V. Klochko, Mariya P. Shyshkina, and Alla V. Dobryden. Development of the health-preserving competence of a physical education teacher on the basis of N. Bernstein's theory of movements construction using virtual reality technologies. CEUR Workshop Proceedings, July 2021. http://dx.doi.org/10.31812/123456789/4634.

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The article studies the results of the research aimed at the improvement of the methodology of develop- ment of the health-preserving competence of a Physical Education teacher in conditions of post-graduate education on the basis of Nikolai Bernstein’s theory of movement construction using virtual reality technologies. Based on the use of AR/VR technologies a software application “Virtual Model Illustrating Nikolai Bernstein’s Theory of Movement Construction” was developed. The stated model is one of the tools of the “Methodology of development of the health preserving competence of a Physical Educa- tion teacher on the basis of Nikolai Bernstein’s theory of the levels of movement construction”. The experimental study determines that the application of the virtual model within the stated methodology is an effective tool for the development of the health preserving competence of a Physical Education teacher. The application of the virtual model allows the actualization of the health preserving, conceptual, gnoseological, biomechanical, inclusive, corrective potentials of Nikolai Bernstein’s theory of movement construction. The use of the virtual model presents the ways of targeted and meaningful use of Nikolai Bernstein’s theory of the levels of movement construction by a Physical Education teacher and the improvement of physical and recreational technologies and concrete physical exercises and movement modes. Due to the application of virtual reality tools, health-preserving, preventative, corrective and developmental strategies are being formed among which the significant ones are: “Application of syner- gistic movements to adaptation to movement activity, and recreation”, “Application of spatial movements for actualization of the orientation and search activities and development of spatial thinking”, “Use of movements with a complicated algorithm for intellect development”.
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3

Yancheva, Denitsa, Stefan Tapanov, Neda Anastasova, Evelina Velcheva, Simeon Stoyanov, and Bistra Stamboliyska. Pigments and Organic Binders in the Wall Paintings of Chapel “St. Nikolay” in Rila Monastery Catholicon, Bulgaria. "Prof. Marin Drinov" Publishing House of Bulgarian Academy of Sciences, December 2019. http://dx.doi.org/10.7546/crabs.2019.11.03.

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4

Murphy, Jim. Lithographic description of skeletonized core samples from 8 holes received at the GMC (1 box, holes N1 through N8) of the INEXCO Mining Company Nikolai Project, McCarthy, Alaska that consist of core samples of the Nikolai Greenstone and the basal Chitistone Limestone. Alaska Division of Geological & Geophysical Surveys, 1996. http://dx.doi.org/10.14509/19120.

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5

Wypych, Alicja, Evan Twelker, L. L. Lande, and R. J. Newberry. Along-strike geochemical variations in the Late Triassic Nikolai magmatic system, Wrangellia, central Alaska (poster number V31D-3059): American Geophysical Union 2015 Fall Meeting, December 14-18, 2015. Alaska Division of Geological & Geophysical Surveys, December 2015. http://dx.doi.org/10.14509/29567.

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