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Статті в журналах з теми "Isotope kinetic effect"
Musich, О., A. Zubko, and О. Demyanуuk. "Isotopic effect of macro- and microelements in ecosystems." Balanced nature using, no. 4 (August 18, 2020): 132–38. http://dx.doi.org/10.33730/2310-4678.4.2020.226644.
Повний текст джерелаXu, Yingkui, Dan Zhu, Xiongyao Li, and Jianzhong Liu. "Why magnesium isotope fractionation is absent from basaltic melts under thermal gradients in natural settings." Geological Magazine 157, no. 7 (November 25, 2019): 1144–48. http://dx.doi.org/10.1017/s0016756819001304.
Повний текст джерелаBinder, David A., and Robert Eliason. "Kinetic hydrogen isotope effect." Journal of Chemical Education 63, no. 6 (June 1986): 536. http://dx.doi.org/10.1021/ed063p536.
Повний текст джерелаKrinkin, David. "Anomalously large kinetic isotope effect." Open Chemistry 5, no. 4 (December 1, 2007): 1019–63. http://dx.doi.org/10.2478/s11532-007-0048-2.
Повний текст джерелаJoelsson, L. M. T., J. A. Schmidt, E. J. K. Nilsson, T. Blunier, D. W. T. Griffith, S. Ono, and M. S. Johnson. "Development of a new methane tracer: kinetic isotope effect of <sup>13</sup>CH<sub>3</sub>D + OH from 278 to 313 K." Atmospheric Chemistry and Physics Discussions 15, no. 19 (October 15, 2015): 27853–75. http://dx.doi.org/10.5194/acpd-15-27853-2015.
Повний текст джерелаRöckmann, T., S. Walter, B. Bohn, R. Wegener, H. Spahn, T. Brauers, R. Tillmann, E. Schlosser, R. Koppmann, and F. Rohrer. "Isotope effect in the formation of H<sub>2</sub> from H<sub>2</sub>CO studied at the atmospheric simulation chamber SAPHIR." Atmospheric Chemistry and Physics 10, no. 12 (June 16, 2010): 5343–57. http://dx.doi.org/10.5194/acp-10-5343-2010.
Повний текст джерелаAway, Kenneth Charles West, and Zhu-Gen Lai. "Solvent effects on SN2 transition state structure. II: The effect of ion pairing on the solvent effect on transition state structure." Canadian Journal of Chemistry 67, no. 2 (February 1, 1989): 345–49. http://dx.doi.org/10.1139/v89-056.
Повний текст джерелаMurata, Yasujiro, Shih-Ching Chuang, Fumiyuki Tanabe, Michihisa Murata, and Koichi Komatsu. "Recognition of hydrogen isotopomers by an open-cage fullerene." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 371, no. 1998 (September 13, 2013): 20110629. http://dx.doi.org/10.1098/rsta.2011.0629.
Повний текст джерелаTsai, I.-Chun, Wan-Yu Chen, Jen-Ping Chen, and Mao-Chang Liang. "Kinetic mass-transfer calculation of water isotope fractionation due to cloud microphysics in a regional meteorological model." Atmospheric Chemistry and Physics 19, no. 3 (February 8, 2019): 1753–66. http://dx.doi.org/10.5194/acp-19-1753-2019.
Повний текст джерелаUspenskaya, Elena V., Tatyana V. Pleteneva, Anton V. Syroeshkin, Ilaha V. Kazimova, Tatyana E. Elizarova, and Artem I. Odnovorov. "Role of stable hydrogen isotope variations in water for drug dissolution managing." Current Issues in Pharmacy and Medical Sciences 33, no. 2 (June 1, 2020): 94–101. http://dx.doi.org/10.2478/cipms-2020-0017.
Повний текст джерелаДисертації з теми "Isotope kinetic effect"
Lu, Siran. "Single molecule kinetic isotope effect." Thesis, University of Oxford, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.526483.
Повний текст джерелаKopec-Harding, Kamilla Rosa. "Computational studies of the kinetic isotope effect inmethylamine dehydrogenase." Thesis, University of Manchester, 2012. https://www.research.manchester.ac.uk/portal/en/theses/computational-studies-of-the-kinetic-isotope-effect-inmethylamine-dehydrogenase(b6883173-40ea-4a35-948b-c966105230cd).html.
Повний текст джерелаBurke, Erin E. "Heavy atom and hydrogen kinetic isotope effect studies on recombinant, mammalian sialyltransferases." [Gainesville, Fla.] : University of Florida, 2005. http://purl.fcla.edu/fcla/etd/UFE0011586.
Повний текст джерелаIngle, Shakti Singh. "RNA structure investigation: a deuterium kinetic isotope effect/hydroxyl radical cleavage experiment." Thesis, Boston University, 2013. https://hdl.handle.net/2144/12787.
Повний текст джерелаThe hydroxyl radical is widely used as a high-resolution footprinting agent for DNA and RNA. The hydroxyl radical abstracts a hydrogen atom from the sugar- phosphate backbone of a nucleic acid molecule, creating a sugar-based radical that eventually results in a strand break. It was shown previously that replacement of deoxyribose hydrogen atoms with deuterium results in a kinetic isotope effect (KIE) on hydroxyl radical cleavage of DNA. The KIE correlates well with the solvent accessible surface area of a deoxyribose hydrogen atom in DNA. We chose the structurally well-defmed sarcin-ricin loop (SRL) RNA molecule as a model system to extend the deuterium KIE/hydroxyl radical cleavage experiment to RNA. We observed a substantial KIE upon deuteration of the 5'-carbon of the ribose. Values ranged from 1.20 to 1.96, and depended on the position of the residue within the SRL. We found a smaller KIE upon 4'-deuteration. Values ranged from 1.05 to 1.23. Values of 5' and 4' KIEs correlate with the extent of cleavage and with the solvent accessible surface areas of ribose hydrogen atoms ofthe SRL. Gel electrophoresis of cleavage products reveals that the strand break is terminated at the 5' end by multiple chemical species. Upon 3'-radiolabeling a specifically 5'-deuterated SRL RNA molecule, we observed a KIE on the production of a cleavage product having a gel mobility different from that of a phosphate-terminated RNA strand. Reduction with sodium borohydride gave rise to an RNA fragment terminated by a 5'-hydroxyl group. These experiments are consistent with 5' hydrogen abstraction by the hydroxyl radical producing a 5'-aldehyde-terminated RNA strand that retains the nucleotide from which the hydrogen atom was abstracted. This is the first report of such a species. This chemistry has important implications for the interpretation of structural analysis experiments on RNA that rely on primer extension to synthesize eDNA copies of hydroxyl radical cleavage products. The different 5'-terminated products resulting from hydroxyl radical cleavage at a given nucleotide would yield cDNAs of two different lengths, thereby distributing the cleavage intensity over two nucleotides instead ofone and lowering the resolution ofthe experiment.
Yousefi-Shivyari, Niloofar. "Isotope ratios in source determination of formaldehyde emissions." Thesis, Virginia Tech, 2020. http://hdl.handle.net/10919/99308.
Повний текст джерелаMaster of Science
Home-interior products like cabinetry are often produced with wood composites adhesively bonded with urea-formaldehyde (UF) resin. UF resins are low cost and highly effective, but their chemical nature results in formaldehyde emission from the composite. High emissions are avoided, and the federal government has regulated and steadily reduced allowable emissions since 1985. The industry continuously improved UF technologies to meet regulations, as in 2010 when the most demanding regulations were implemented. At that time, many people were unaware that wood also generates formaldehyde; this occurs at very low levels but heating during composite manufacture causes a temporary burst of natural formaldehyde. Some wood types produce unusually high formaldehyde levels, making regulation compliance more difficult. This situation, and the desire to raise public awareness, created a major industrial goal: determine how much formaldehyde emission originates from the resin and how much originates from the wood. These formaldehyde sources can be distinguished by measuring the carbon isotope ratio, 13C/12C. This ratio changes and varies due to the kinetic isotope effect. Slight differences in 13C and 12C reactivity reveal the source as either petrochemical (synthetic formaldehyde) or plant-based (biogenic formaldehyde). This work demonstrates that achieving the industry goal is entirely feasible, and it provides the analytical foundation. The technical strategy is: 1) establish reference isotope ratios in wood and in UF resin, and 2) from the corresponding wood composite, capture formaldehyde emissions, measure the isotope ratio, and simply calculate the percentage contributions from the reference sources. However, a complication exists. When the reference sources generate formaldehyde, the respective isotope ratios change systematically in a process called isotope fractionation (another term for the kinetic isotope effect). Consequently, this effort developed methods to measure fractionation when cured UF resin and wood separately generate formaldehyde, with greater emphasis on wood. Isotope fractionation in wood revealed multiple fractionation mechanisms. This complexity presents intriguing possibilities for new perspectives on formaldehyde emission from wood and cured UF resin. In summary, this work demonstrated how source contributions to formaldehyde emissions can be determined; it established effective methods required to refine and perfect the approach, and it revealed that isotope fractionation could serve as an entirely novel tool in the materials science of wood composites.
MacMillar, Susanna. "Isotopes as Mechanism Spies : Nucleophilic Bimolecular Substitution and Monoamine Oxidase B Catalysed Amine Oxidation Probed with Heavy Atom Kinetic Isotope Effects." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis (AUU), 2006. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-7441.
Повний текст джерелаPagano, Philip Lee Jr. "Investigating fast dynamics at the tunneling ready state in formate dehydrogenase." Diss., University of Iowa, 2017. https://ir.uiowa.edu/etd/5592.
Повний текст джерелаIndurugalla, Deepani. "A kinetic isotope effect study on the acid-catalyzed hydrolysis of methyl xylopyranosides and methyl 5-thioxylopyranosides." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape10/PQDD_0021/NQ37716.pdf.
Повний текст джерелаLorenzini, Leonardo. "Effects of T3 and 3-iodothyronamine (T1AM) on cellular metabolism, and influence of serum proteins on T1AM assay." Doctoral thesis, Università di Siena, 2018. http://hdl.handle.net/11365/1046523.
Повний текст джерелаRichan, Teisha. "Conservative Tryptophan Mutations in Protein Tyrosine Phosphatase PTP1B and its Effect on Catalytic Rate and Chemical Reaction." DigitalCommons@USU, 2017. https://digitalcommons.usu.edu/etd/5584.
Повний текст джерелаКниги з теми "Isotope kinetic effect"
Wilson, Mathew John. Investigating the possibility of measuring a primary leaving group iodine kinetic isotope effect. Sudbury, Ont: Laurentian University, 1999.
Знайти повний текст джерелаJiang, Wenyi. Using kinetic isotope effects to determine the effect of ion pairing, substituents and the solvent on the structure of the Sn2 transition state. Sudbury, Ont: Laurentian University Press, 1995.
Знайти повний текст джерелаOsborne, Craig. Measuring the rate constant and secondary a-deuterium kinetic isotope effect for the SN2 reaction between para-nitrobenzyl choride and cyanide ion in 15% aqueous DMSO. Sudbury, Ont: Laurentian University, 1996.
Знайти повний текст джерелаF, Cook Paul, ed. Enzyme mechanism from isotope effects. Boca Raton: CRC Press, 1991.
Знайти повний текст джерелаE, Buncel, and Saunders William Hundley 1926-, eds. Heavy atom isotope effects. Amsterdam: Elsevier, 1992.
Знайти повний текст джерелаBruce, Cook. The Feasibility of measuring the rate constant and secondary [alpha]-deuterium kinetic isotope effect for the Sn2 reaction between sodium phenoxide and benzyl chloride at low concentrations of phenoxide ion. Sudbury, Ont: Laurentian University, 1995.
Знайти повний текст джерелаE, Buncel, and Lee C. C. 1924-, eds. Secondary and solvent isotope effects. Amsterdam: Elsevier, 1987.
Знайти повний текст джерелаBuchachenko, A. L. Magnetic isotope effect in chemistry and biochemistry. Hauppauge, NY: Nova Science Publishers, 2009.
Знайти повний текст джерелаAmnon, Kohen, and Limbach Hans-Heinrich, eds. Isotope effects in chemistry and biology. Boca Raton: Taylor & Francis, 2006.
Знайти повний текст джерелаIkeda, Glenn Kazuo. Kinetic isotope effects in the fragmentation of N1'-methyl-2-(1-hydroxybenzyl)thiamin. Ottawa: National Library of Canada, 2003.
Знайти повний текст джерелаЧастини книг з теми "Isotope kinetic effect"
Kobayashi, Kensei. "Kinetic Isotope Effect." In Encyclopedia of Astrobiology, 1337. Berlin, Heidelberg: Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-44185-5_5240.
Повний текст джерелаKobayashi, Kensei. "Kinetic Isotope Effect." In Encyclopedia of Astrobiology, 1. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-27833-4_5240-1.
Повний текст джерелаWerner, Roland A., and Marc-André Cormier. "Isotopes—Terminology, Definitions and Properties." In Stable Isotopes in Tree Rings, 253–89. Cham: Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-030-92698-4_8.
Повний текст джерелаScheer, Milton D. "A Kinetic Isotope Effect in the Thermal Dehydration of Cellobiose." In Fundamentals of Thermochemical Biomass Conversion, 89–94. Dordrecht: Springer Netherlands, 1985. http://dx.doi.org/10.1007/978-94-009-4932-4_5.
Повний текст джерелаVanoni, M. A., K. K. Wong, and J. S. Blanchard. "Kinetic isotope effect studies on yeast, spinach and human erythrocyte glutathione reductases." In Flavins and Flavoproteins 1987, edited by D. E. Edmondson and D. B. McCormick, 55–58. Berlin, Boston: De Gruyter, 1987. http://dx.doi.org/10.1515/9783110884715-010.
Повний текст джерелаShackelford, Scott A. "Mechanistic Investigations of Condensed Phase Energetic Material Decomposition Processes Using the Kinetic Deuterium Isotope Effect." In Chemistry and Physics of Energetic Materials, 413–32. Dordrecht: Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-009-2035-4_18.
Повний текст джерелаWolfsberg, Max, W. Alexander Van Hook, and Piotr Paneth. "Kinetic Isotope Effects on Chemical Reactions." In Isotope Effects, 313–42. Dordrecht: Springer Netherlands, 2009. http://dx.doi.org/10.1007/978-90-481-2265-3_10.
Повний текст джерелаBagshaw, Clive R. "Kinetic Isotope Effects." In Encyclopedia of Biophysics, 1–3. Berlin, Heidelberg: Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-642-35943-9_58-1.
Повний текст джерелаBagshaw, Clive R. "Kinetic Isotope Effects." In Encyclopedia of Biophysics, 1200–1201. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-16712-6_58.
Повний текст джерелаWolfsberg, Max, W. Alexander Van Hook, and Piotr Paneth. "Kinetic Isotope Effects Continued: Variational Transition State Theory and Tunneling." In Isotope Effects, 181–202. Dordrecht: Springer Netherlands, 2009. http://dx.doi.org/10.1007/978-90-481-2265-3_6.
Повний текст джерелаТези доповідей конференцій з теми "Isotope kinetic effect"
Jiang, Clancy Zhijian, Itay Halevy, and Nicholas Tosca. "Kinetic Isotope Effect of C in Siderite Growth at 298.15 K." In Goldschmidt2020. Geochemical Society, 2020. http://dx.doi.org/10.46427/gold2020.1191.
Повний текст джерелаOber, Douglas, Mitchio Okumura, and TzuLing Chen. "SINGLE SUBSTITUTION KINETIC ISOTOPE EFFECT MEASUREMENTS FOR CH4 + O(1D) USING CAVITY RING-DOWN SPECTROSCOPY." In 2020 International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2020. http://dx.doi.org/10.15278/isms.2020.fb09.
Повний текст джерелаJiang, Clancy Zhijian, Itay Halevy та Nicholas Tosca. "Kinetic isotope effect in siderite growth; an abiotic origin for depleted δ13C-siderite in banded iron formations." У Goldschmidt2021. France: European Association of Geochemistry, 2021. http://dx.doi.org/10.7185/gold2021.4155.
Повний текст джерелаOber, Douglas, Mitchio Okumura, THINH Bui, LINHAN SHEN, and TzuLing Chen. "SINGLE SUBSTITUTION KINETIC ISOTOPE EFFECT MEASUREMENTS FOR CH<sub>4</sub> + O(<sup>1</sup>D) USING CAVITY RING-DOWN SPECTROSCOPY." In 2021 International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2021. http://dx.doi.org/10.15278/isms.2021.wc03.
Повний текст джерелаLee, Jin-Ha, Mamoru Nishimoto, Masayuki Okuyama, Haruhide Mori, Atsuo Kimura, Doman Kim, Masao Ohguchi, and Seiya Chiba. "ALPHA-SECONDARY DEUTERIUM KINETIC ISOTOPE EFFECTS FOR HYDROLYSIS OF TREHALOSE BY TREHALASE." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.731.
Повний текст джерелаMehboob, Khurram, and Mohammad S. Aljohani. "Effect of Spray System on in Containment Fission Product Washout During In-Vessel Release Phase." In 2017 25th International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/icone25-66056.
Повний текст джерелаChew, Kathryn, Patrick Vaccaro, and Zachary Vealey. "VIBRATIONALLY-RESOLVED KINETIC ISOTOPE EFFECTS IN THE PROTON-TRANSFER DYNAMICS OF GROUND-STATE TROPOLONE." In 70th International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2015. http://dx.doi.org/10.15278/isms.2015.ti11.
Повний текст джерелаLobyshev, V. I. "PROSPECTS FOR THE USE OF ISOTOPE-MODIFIED WATER IN BIOLOGY AND MEDICINE." In NOVEL TECHNOLOGIES IN MEDICINE, BIOLOGY, PHARMACOLOGY AND ECOLOGY. Institute of information technology, 2022. http://dx.doi.org/10.47501/978-5-6044060-2-1.87-91.
Повний текст джерелаUlrich, Robert, Rachel Han, Jamie Lucarelli, Julia Campbell, Abbas Hakim, Shayleen Singh, Justin Ries, Aradhna Tripati та Robert Eagle. "Coupled Δ47–Δ48 clumped isotope analysis indicates origins of kinetic isotope effects in cultured biogenic marine carbonates". У Goldschmidt2021. France: European Association of Geochemistry, 2021. http://dx.doi.org/10.7185/gold2021.7851.
Повний текст джерелаSchwab, Lorenz, Niklas Gallati, David McLagan, Harald Biester, Stephan Kraemer, and Jan Wiederhold. "Kinetic versus Equilibrium Mercury Isotope Effects During Homogenous and Surface Catalyzed Mercury(II) Reduction by Iron(II)." In Goldschmidt2022. France: European Association of Geochemistry, 2022. http://dx.doi.org/10.46427/gold2022.11919.
Повний текст джерелаЗвіти організацій з теми "Isotope kinetic effect"
Chang, Paul. Theoretical calculations of kinetic isotope effects. Portland State University Library, January 2000. http://dx.doi.org/10.15760/etd.785.
Повний текст джерелаBrown, Gilbert M., Thomas J. Meyer, and Bruce A. Moyer. Utilization of Kinetic Isotope Effects for the Concentration of Tritium. Office of Scientific and Technical Information (OSTI), June 2000. http://dx.doi.org/10.2172/827388.
Повний текст джерелаBrown, Gilbert M., Thomas j. Meyer, and Bruce A. Moyer. Utilization of Kinetic Isotope Effects for the Concentration of Tritium. Office of Scientific and Technical Information (OSTI), June 1999. http://dx.doi.org/10.2172/827393.
Повний текст джерелаBrown, Gilbert M., and Thomas J. Meyer. UTILIZATION OF KINETIC ISOTOPE EFFECTS FOR THE CONCENTRATION OF TRITIUM. Office of Scientific and Technical Information (OSTI), December 2001. http://dx.doi.org/10.2172/827401.
Повний текст джерелаBrown, G. M., and T. J. Meyer. Utilization of kinetic isotope effects for the concentration of tritium. 1997 annual progress report. Office of Scientific and Technical Information (OSTI), September 1997. http://dx.doi.org/10.2172/13743.
Повний текст джерелаBrown, G. M., and T. J. Meyer. Utilization of kinetic isotope effects for the concentration of tritium. 1998 annual progress report. Office of Scientific and Technical Information (OSTI), June 1998. http://dx.doi.org/10.2172/13744.
Повний текст джерела