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Опубліковано: 28 лютого 2024

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Статті в журналах з теми "Copper(I) N-heterocyclic carbene"

1

Egbert, Jonathan D., Catherine S. J. Cazin, and Steven P. Nolan. "Copper N-heterocyclic carbene complexes in catalysis." Catalysis Science & Technology 3, no. 4 (2013): 912. http://dx.doi.org/10.1039/c2cy20816d.

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2

Trose, Michael, Fady Nahra, and Catherine S. J. Cazin. "Dinuclear N-heterocyclic carbene copper(I) complexes." Coordination Chemistry Reviews 355 (January 2018): 380–403. http://dx.doi.org/10.1016/j.ccr.2017.10.013.

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3

Frogneux, Xavier, Laura Hippolyte, Dimitri Mercier, David Portehault, Corinne Chanéac, Clément Sanchez, Philippe Marcus, François Ribot, Louis Fensterbank, and Sophie Carenco. "Direct Synthesis of N‐Heterocyclic Carbene‐Stabilized Copper Nanoparticles from an N‐Heterocyclic Carbene–Borane." Chemistry – A European Journal 25, no. 49 (August 5, 2019): 11481–85. http://dx.doi.org/10.1002/chem.201901534.

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4

Cisnetti, Federico, Pascale Lemoine, Malika El-Ghozzi, Daniel Avignant, and Arnaud Gautier. "Copper(I) thiophenolate in copper N-heterocyclic carbene preparation." Tetrahedron Letters 51, no. 40 (October 2010): 5226–29. http://dx.doi.org/10.1016/j.tetlet.2010.07.124.

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5

Furst, Marc R. L., and Catherine S. J. Cazin. "Copper N-heterocyclic carbene (NHC) complexes as carbene transfer reagents." Chemical Communications 46, no. 37 (2010): 6924. http://dx.doi.org/10.1039/c0cc02308f.

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6

Mikhaylov, Vladimir N., Igor V. Kazakov, Tatiana N. Parfeniuk, Olesya V. Khoroshilova, Manfred Scheer, Alexey Y. Timoshkin, and Irina A. Balova. "The carbene transfer to strong Lewis acids: copper is better than silver." Dalton Transactions 50, no. 8 (2021): 2872–79. http://dx.doi.org/10.1039/d1dt00235j.

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7

Zeng, Wei, Rui Qiu, En Yu Wang, and Fu Xue Chen. "Trifluoromethyl-Promoted Oxidation of Fischer N-Heterocyclic Carbene Complexes by DMSO." Advanced Materials Research 788 (September 2013): 164–67. http://dx.doi.org/10.4028/www.scientific.net/amr.788.164.

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A new protocol for trifluoromethyl-promoted oxidation of fischer-type N-Heterocyclic Carbene copper complexes has been developed by DMSO, which allows the preparation of imidazolinones from carbene complexes.
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8

Santoro, Orlando, Faïma Lazreg, Yury Minenkov, Luigi Cavallo, and Catherine S. J. Cazin. "N-heterocyclic carbene copper(i) catalysed N-methylation of amines using CO2." Dalton Transactions 44, no. 41 (2015): 18138–44. http://dx.doi.org/10.1039/c5dt03506f.

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9

She, Zhe, Mina R. Narouz, Christene A. Smith, Amy MacLean, Hans-Peter Loock, Heinz-Bernhard Kraatz, and Cathleen M. Crudden. "N-Heterocyclic carbene and thiol micropatterns enable the selective deposition and transfer of copper films." Chemical Communications 56, no. 8 (2020): 1275–78. http://dx.doi.org/10.1039/c9cc08919e.

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10

Remy-Speckmann, Ina, Birte M. Zimmermann, Mahadeb Gorai, Martin Lerch, and Johannes F. Teichert. "Mechanochemical solid state synthesis of copper(I)/NHC complexes with K3PO4." Beilstein Journal of Organic Chemistry 19 (April 14, 2023): 440–47. http://dx.doi.org/10.3762/bjoc.19.34.

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A protocol for the mechanochemical synthesis of copper(I)/N-heterocyclic carbene complexes using cheap and readily available K3PO4 as base has been developed. This method employing a ball mill is amenable to typical simple copper(I)/NHC complexes but also to a sophisticated copper(I)/N-heterocyclic carbene complex bearing a guanidine moiety. In this way, the present approach circumvents commonly employed silver(I) complexes which are associated with significant and undesired waste formation and the excessive use of solvents. The resulting bifunctional catalyst has been shown to be active in a variety of reduction/hydrogenation transformations employing dihydrogen as terminal reducing agent.
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Дисертації з теми "Copper(I) N-heterocyclic carbene"

1

Ellul, Charles. "Trimetallic N-heterocyclic carbene complexes." Thesis, University of Bath, 2011. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.538279.

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2

Sirokman, Gergely. "(N-heterocyclic-carbene)Copper(I)-catalyzed carbon-carbon bond formation using carbon dioxide." Thesis, Massachusetts Institute of Technology, 2007. http://hdl.handle.net/1721.1/39584.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2007.
Vita.
Includes bibliographical references.
This thesis presents work towards the development of a new catalytic C-C bond forming reaction. Alkynes and olefins insert into [(IPr)CuH]2 (IPr = N,N-bis-(2,6-diisopropylphenyl)-1,3-imidazol-2-ylidene) to give copper vinyl and copper alkyl complexes. These copper complexes insert CO2 into the Cu-C bond to form copper acrylate and copper carboxylate complexes. Acrylic and carboxylic acids can be isolated by hydrolysis. A catalytic cycle based on (IPr)copper(I) was developed. Alkynes undergo reductive carboxylation to give acrylic acids in moderate yields. Unexpected interactions between several components of the catalytic system led to a number of side reaction, most importantly between [(IPr)CuH]2 and the product silyl acrylate. The use of silylcarbonate salts to desylilate the product enhanced yield. In addition, silylcarbonates can also serve as a source of CO2.
by Gergely Sirokman.
Ph.D.
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3

Gallop, Christopher W. D. "N-heterocyclic carbene-palladium and -copper complexes in cross-coupling reactions." Thesis, University of Sussex, 2015. http://sro.sussex.ac.uk/id/eprint/54338/.

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Chapter 1 gives the reader a background on cross-coupling reactions, in particular palladium mediated couplings. Furthermore the importance of ligands, including phosphines and N-heterocyclic carbenes (NHC), in such cross-coupling reactions is explored. Chapter 2 provides a background to the reductive lithiation of phosphines, followed by an account of our investigation of BINAP functionalisation by means of reductive elimination.1 The reaction was examined by experimental means and through the use of density functional theory to predict 31P NMR chemical shifts. Chapter 3 provides background on the Heck reaction and selected developments over the years, with particular reference to the use of aryl chlorides in the reaction. A brief discussion of NHC based palladium complex sets the scene for our investigation of a new class of (NHC)-Pd catalysts developed by the Navarro group. Complexes of type (NHC)PdCl2(TEA) (TEA = triethylamine) have been tested for their activity in the Heck reaction, focusing on the scope of the reaction with electron-deficient aryl chlorides and electron-rich aryl bromides.2 Chapter 4 gives an account of the discovery and developments of the Sonogashira reaction. Particular attention is paid to non-classical systems such as palladium-only and copper-only protocols. Herein our investigation into the use of collaborative (NHC)-Pd and (NHC)-Cu in Sonogashira reactions is presented.3 Notable features of this system are the low catalyst loadings and the synthetically convenient conditions in which the reaction can be carried namely non-anhydrous solvents and in air. Publications: (1) Gallop, C. W. D.; Bobin, M.; Hourani, P.; Dwyer, J.; Roe, S. M.; Viseux, E. M. E. J. Org. Chem. 2013, 6522–6528. (2) Gallop, C. W. D.; Zinser, C.; Guest, D.; Navarro, O. Synlett 2014, 2225–2228. (3) Gallop, C. W. D.; Chen, M.-T.; Navarro, O. Org. Lett 2014, 3724–3727.
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4

Lazreg, Faïma. "Group 11 N-heterocyclic carbenes : synthesis, characterisation and catalytic applications." Thesis, University of St Andrews, 2015. http://hdl.handle.net/10023/7059.

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As part of a worldwide effort to develop efficient catalysts for use in organic chemistry and in the synthesis of highly valuable molecules, work performed during the course of my stay in St Andrews has focused on the design and synthesis of new group 11 metal complexes for their applications in catalysis. The aim of this work was to develop new, active and stable, easy to synthesise group 11 complexes and investigate their catalytic activity as well as to try to understand their mode of action. Two different types of complexes were explored in order to develop more active catalysts: the neutral N-Heterocyclic carbene metal complexes and the cationic derivatives. More than 20 new catalysts were developed and their reactivity studied in different catalytic reactions. New hydroxide and tert-butoxide copper(I) or silver(I) complexes were developed and compared to the common NHC metal systems. Overall, the neutral NHC-metal catalysts showed to be highly active in a broad range of applications: in the methylation of amines using CO₂ as a C1 source, in a multicomponent reaction (A³ coupling) and in dual catalysis (hydrophenoxylation). Additionally, mechanistic studies were undertaken to obtain a greater understanding of these transformations and to possibly lead to the design of new generations of catalyst. Regarding the cationic NHC metal complexes, a straightforward methodology was developed leading to a library of highly stable catalysts. Bis-NHC, mixed NHC/ phosphine as well as NHC/pyridine species were efficiently synthesised using thermal or microwave heating, in high purity and yields. In addition, the effect of the presence of two different or identical ligands on catalytic reactivity was investigated in the 3+2 cycloaddition and in the alkynylation of ketones. Insight into the catalytic cycle was obtained via mechanistic studies. These showcased the release of one ligand during the catalytic cycle and the crucial role of this ligand displacement in generating the catalytically relevant active species. The results highlight the importance of understanding the reactivity of catalyst in order to develop new and improved ones.
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5

Quezada, Carol A. "N-Heterocyclic Carbenes: From Heterocyclynes to Potential Radiopharmaceuticals." Akron, OH : University of Akron, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=akron1116249871.

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6

Lake, Benjamin Richard Morris. "Copper N-heterocyclic carbenes : novel electrochemical synthesis, stabilisation of variable oxidation states and unusual carbene reactivity." Thesis, University of Leeds, 2014. http://etheses.whiterose.ac.uk/7891/.

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This thesis concerns the synthesis, structural characterisation and reactivity of a range of novel organometallic complexes. The research primarily focuses on N-heterocyclic carbenes as ligands, and their coordination to copper cations. A novel electrochemical synthetic procedure for the synthesis of CuI-NHC complexes is described. It was found that this procedure was suitable for the synthesis of a wide range of CuI-NHC complexes, containing either bulky, non-bulky or base sensitive functional groups. Furthermore, the synthetic procedure was found to be highly selective, producing [Cu(NHC)X]- type complexes when X is a coordinating anion, and [Cu(NHC)2]X-type complexes when X is a non-coordinating anion. The structural chemistry of CuI-NHC complexes containing pendant N-allyl groups was explored, with the resultant complexes displaying an array of coordination geometries about the CuI centres. By careful modification of these ligands, the first example of a CuI -NHC complex containing a CuI-alkene interaction was observed. The coordination chemistry of NHC ligands containing pyridyl substituents, which act as ancillary donors, was investigated. CuI -NHC complexes containing these ligands were found to be catalytically competent in an Ullmann-type etherification reaction. Additionally, exposure of solutions of some of these CuI-NHC complexes to atmospheric conditions allowed the crystallographic characterisation of rare examples of CuII-NHC complexes. Finally, the rational synthesis of a range of unusual CuII-NHC complexes was performed, with the resulting complexes being structurally characterised. It was found that, under certain circumstances, oxidative decomposition of the NHC ligand within the coordination sphere of a copper centre can occur. The formation of 2-haloimidazolium and C-C coupled bis-imidazolium salts, via oxidative degradation, was investigated using a combined experimental and computational study.
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7

Charra, Valentine. "Coordination of multidentate N-heterocyclic carbene ligands to nickel." Thesis, Strasbourg, 2014. http://www.theses.fr/2014STRAF019/document.

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Le sujet de cette thèse porte sur la synthèse de ligands de type bis-NHC (carbène N-Hétérocyclique) et leur réactivité vis-À-Vis des complexes d’argent(I), de cuivre(I) et de nickel(II).Après avoir exploré les différentes méthodologies de synthèse des complexes de nickel(II) bis-NHC, le but était de tester leurs activités en catalyse d’oligomérisation de l’éthylène. Une série de nouveaux complexes d’argent(I) et de cuivre(I) fut synthétisée. Cinq voies furent testées pour la formation de complexes de nickel. Les résultats les plus probants furent obtenus par transmétallation à partir des complexes d’iodure ou de bromure d’argent(I)
The purpose of this work was the synthesis of bis-NHC (N-Heterocyclic carbene) ligands, theformation of the corresponding silver(I), copper(I) and nickel(II) complexes and the assessment ofthe catalytic activity of the bis-NHC nickel(II) complexes in ethylene oligomerization. A series of new bis-NHC silver(I) and copper(I) complexes was synthesized. Five different synthetic routes were tested for the formation of nickel(II) bis-NHC complexes. The most significant results were obtained by transmetalation from the silver(I) iodide or bromide complexes
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8

Santoro, Orlando. "Copper(I)-N-heterocyclic carbene (NHC) complexes : synthesis, characterisation and applications in synthesis and catalysis." Thesis, University of St Andrews, 2016. http://hdl.handle.net/10023/8409.

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The work described herein focuses on the synthesis and characterisation of copper(I) complexes bearing N-heterocyclic carbene (NHC) ligands, their use in catalysis as well as organometallic synthesis and related reaction mechanisms. Two classes of complexes were considered: neutral NHC-Cu(I) species and their cationic analogues. Concerning the former, initial efforts were focused on the development of a general and straightforward synthetic methodology towards complexes of the type [Cu(X)(NHC)] (X = Cl, Br, I). More than 10 NHC-Cu(I) species were synthesised in high yields under mild conditions, in air and using technical grade solvents. These complexes exhibited interesting activity in the catalytic dehydrogenation of formic acid/amine adducts proving in three times more efficiency than the copper salts previously employed in such a reaction. Hydroxide- and tert-butoxide analogues showed to be efficient catalysts in the N-methylation of amines with CO₂ as carbon source, and in the dehydrogenative coupling of silanes and carboxylic acids. Experimental and computational work were carried out in order to elucidate the mechanism of these transformations. Regarding the use of these species in organometallic synthesis, homo- and heteroleptic bis-NHC-Cu(I) complexes were employed as carbene transfer reagents to other transition metals. Aside from well-known cationic gold(I) species, two novel palladium(II) analogues were isolated and fully characterised.
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9

Shu, Tao Verfasser], Dieter [Akademischer Betreuer] [Enders, and Markus [Akademischer Betreuer] Albrecht. "N-heterocyclic carbene - and copper-catalyzed asymmetric domino reactions / Tao Shu ; Dieter Enders, Markus Albrecht." Aachen : Universitätsbibliothek der RWTH Aachen, 2018. http://d-nb.info/1171818831/34.

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Shu, Tao [Verfasser], Dieter [Akademischer Betreuer] Enders, and Markus [Akademischer Betreuer] Albrecht. "N-heterocyclic carbene - and copper-catalyzed asymmetric domino reactions / Tao Shu ; Dieter Enders, Markus Albrecht." Aachen : Universitätsbibliothek der RWTH Aachen, 2018. http://d-nb.info/1171818831/34.

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Книги з теми "Copper(I) N-heterocyclic carbene"

1

Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Hoboken, N.J: Wiley, 2009.

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Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Hoboken, N.J: Wiley, 2009.

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Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Chichester, U.K: Wiley, 2010.

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4

Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Hoboken, N.J: Wiley, 2009.

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5

Vogel, Carola S. High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes. Berlin, Heidelberg: Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-27254-7.

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6

Zou, Taotao. Anti-Cancer N-Heterocyclic Carbene Complexes of Gold(III), Gold(I) and Platinum(II). Singapore: Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-0657-9.

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7

Cazin, Catherine Suzanne Julienne. N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis. Dordrecht: Springer Science+Business Media B.V., 2011.

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8

Vogel, Carola S. High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure. Berlin, Heidelberg: Springer Berlin Heidelberg, 2012.

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9

Kühl, Olaf. Functionalised N-Heterocyclic Carbene Complexes. Wiley & Sons, Limited, John, 2010.

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10

Kuhl, Olaf, and Olaf Hl. Functionalised N-Heterocyclic Carbene Complexes. Wiley & Sons, Incorporated, John, 2010.

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Частини книг з теми "Copper(I) N-heterocyclic carbene"

1

Lazreg, Faïma, and Catherine S. J. Cazin. "NHC-Copper Complexes and their Applications." In N-Heterocyclic Carbenes, 199–242. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527671229.ch08.

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2

Lazreg, Faïma, and Catherine S. J. Cazin. "Medical Applications of NHC-Gold and -Copper Complexes." In N-Heterocyclic Carbenes, 173–98. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527671229.ch07.

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3

Díez-González, Silvia. "N-Heterocyclic Carbenes in Copper-Catalyzed Reactions." In Ideas in Chemistry and Molecular Sciences, 43–66. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2010. http://dx.doi.org/10.1002/9783527630554.ch3.

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4

Krylova, Valentina A., Peter I. Djurovich, Jacob W. Aronson, Ralf Haiges, Matthew T. Whited, and Mark E. Thompson. "Structural and Photophysical Studies of Phosphorescent Three-Coordinate Copper(I) Complexes Supported by an N-Heterocyclic Carbene Ligand." In Electrophosphorescent Materials and Devices, 755–87. New York: Jenny Stanford Publishing, 2023. http://dx.doi.org/10.1201/9781003088721-43.

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5

Fang, Xinqiang, and Yonggui Robin Chi. "N-Heterocyclic Carbene Catalysis." In Nonnitrogenous Organocatalysis, 151–83. Boca Raton, Florida : CRC Press, [2018] | Series: Organocatalysis series: CRC Press, 2017. http://dx.doi.org/10.1201/9781315371238-7.

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6

Hoyos, Mario, Daniel Guest, and Oscar Navarro. "(N-Heterocyclic Carbene)-Palladium Complexes in Catalysis." In N-Heterocyclic Carbenes, 85–110. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527671229.ch04.

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7

Wu, Linglin, Alvaro Salvador, and Reto Dorta. "Chiral MonodendateN-Heterocyclic Carbene Ligands in Asymmetric Catalysis." In N-Heterocyclic Carbenes, 39–84. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527671229.ch03.

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8

Rivera, Guillermina, and Robert H. Crabtree. "Chelate and Pincer Carbene Complexes." In N-Heterocyclic Carbenes in Synthesis, 223–39. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2006. http://dx.doi.org/10.1002/9783527609451.ch9.

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Peris, Eduardo. "Routes to N-Heterocyclic Carbene Complexes." In N-Heterocyclic Carbenes in Transition Metal Catalysis, 83–116. Berlin, Heidelberg: Springer Berlin Heidelberg, 2006. http://dx.doi.org/10.1007/978-3-540-36930-1_4.

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Jahnke, Mareike C., and F. Ekkehardt Hahn. "Chemistry of N-Heterocyclic Carbene Ligands." In Topics in Organometallic Chemistry, 95–129. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-04722-0_4.

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Тези доповідей конференцій з теми "Copper(I) N-heterocyclic carbene"

1

Su, Qingzhi, Chaoyang Chai, and Feng Zhao. "Synthesis and Photophysical Properties of Four-Coordinate N-heterocyclic Carbene Copper(Ⅰ) Complex Emitting Material with Brightly Luminescence." In 2018 7th International Conference on Energy and Environmental Protection (ICEEP 2018). Paris, France: Atlantis Press, 2018. http://dx.doi.org/10.2991/iceep-18.2018.277.

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2

Arabzadeh Nosratabad, Neda, Zhicheng Jin, Liang Du, and Hedi Mattoussi. "N-Heterocyclic carbene-stabilized gold nanoparticles and luminescent quantum dots." In Colloidal Nanoparticles for Biomedical Applications XVII, edited by Marek Osiński and Antonios G. Kanaras. SPIE, 2022. http://dx.doi.org/10.1117/12.2610485.

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3

Silbestri, Gustavo, Gabriela Fernández, María Vela Gurovic, Nelda Olivera, and Alicia Chopa. "Synthesis and Antimicrobial Activities of Gold(I) N-heterocyclic Carbene Complexes." In The 16th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2012. http://dx.doi.org/10.3390/ecsoc-16-01015.

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Mattoussi, Hedi, Neda Arabzadeh Nosratabad, Liang Du, and Zhicheng Jin. "N-Heterocyclic Carbene-stabilized QDs and Gold Nanoparticles: Effects of the Ligand Coordination." In Internet NanoGe Conference on Nanocrystals. València: Fundació Scito, 2021. http://dx.doi.org/10.29363/nanoge.incnc.2021.053.

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5

Vita, Diana E., Mercedes A. Badajoz, Marcos J. Lo Fiego, and Gustavo F. Silbestri. "Synthesis of N-Heterocyclic Carbene Gold Complexes Using 2,4,6-Trimethylphenyl Sydnone as Model Substrate †." In International Electronic Conference on Synthetic Organic Chemistry. Basel Switzerland: MDPI, 2022. http://dx.doi.org/10.3390/ecsoc-26-13674.

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6

Cingolani, Andrea, Rita Mazzoni, Valerio Zanotti, Matteo Sanviti, Laura Mazzocchetti, Tiziana Benelli, and Loris Giorgini. "Bis-amino functionalized iron N-heterocyclic carbene as epoxy resins hardener and flame behaviour modifier." In THE 9TH INTERNATIONAL CONFERENCE ON STRUCTURAL ANALYSIS OF ADVANCED MATERIALS - ICSAAM 2019. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5140308.

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7

Fernández, Sergio, Federico Franco, Josep M. Luis, and Julio Lloret-Fillol. "Unravelling the CO2 Reduction Mechanism with a Highly Active N-Heterocyclic Carbene Manganese(I) Electrocatalyst." In nanoGe Spring Meeting 2022. València: Fundació Scito, 2022. http://dx.doi.org/10.29363/nanoge.nsm.2022.343.

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8

Hussaini, Sunusi Y., Rosenani A. Haque, Mohd R. Razali, and A. M. S. Abdul Majid. "Effects of supramolecular interactions in nitrile functionalized silver(I)-N-heterocyclic carbene complexes and investigation into their enhancement of antitumor metallodrugs." In 4TH INTERNATIONAL CONFERENCE ON THE SCIENCE AND ENGINEERING OF MATERIALS: ICoSEM2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0027461.

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9

Smolen, Justin, Parth N. Shah, Jasur Tagaev, and Carolyn L. Cannon. "Determination Of An In Vitro Therapeutic Window Of N-Heterocyclic Silver Carbene Compounds That Predicts Activity In A Mouse Model Of Acute Lung Infection." In American Thoracic Society 2012 International Conference, May 18-23, 2012 • San Francisco, California. American Thoracic Society, 2012. http://dx.doi.org/10.1164/ajrccm-conference.2012.185.1_meetingabstracts.a4667.

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10

Leitans, A., N. Bulaha, and J. Lungevics. "Tribological Properties of Sputter Deposited Carbon-Copper Composite Films." In BALTTRIB 2015. Aleksandras Stulginskis University, 2015. http://dx.doi.org/10.15544/balttrib.2015.12.

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Анотація:
Carbon-copper composite coatings were deposited using high power magnetron sputtering technique. Tribological tests were performed using ball-on-disk type tribometer. Friction coefficient and wear rate were determined at 40 N load. It was found that an increase in the percentage composition of carbon in C-Cu coating, reduces the coefficient of friction value. But at higher concentrations of C coating it becomes more brittle, that reduces wear resistance.
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