Добірка наукової літератури з теми "Color purity"

Structural colors have been reported instead of conventional dye- or pigment-based color filters. Color selectivity can degrade as structure-based optical resonances are accompanied by several resonance modes. In this work, we suggest a simple and effective design of the plasmonic color filter (PCF) that integrated the PCF with the one-dimensional (1D) photonic crystal (PhC). The introduced PhC creates an optical band gap and suppresses undesired peaks of the PCF caused by the high-order resonance mode. Finally, the suggested structure provides a high color purity. This study can be a guideline for technology that replaces conventional color filters.

AbstractStructural colors emerge when a particular wavelength range is filtered out from a broadband light source. It is regarded as a valuable platform for color display and digital imaging due to the benefits of environmental friendliness, higher visibility, and durability. However, current devices capable of generating colors are all based on direct transmission or reflection. Material loss, thick configuration, and the lack of tunability hinder their transition to practical applications. In this paper, a novel mechanism that generates high-purity colors by photon spin restoration on ultrashallow plasmonic grating is proposed. We fabricated the sample by interference lithography and experimentally observed full color display, tunable color logo imaging, and chromatic sensing. The unique combination of high efficiency, high-purity colors, tunable chromatic display, ultrathin structure, and friendliness for fabrication makes this design an easy way to bridge the gap between theoretical investigations and daily-life applications.

The goal of this study is to develop quantitative metrics for evaluating color tracking and gray tracking in a color medical display. Color tracking is the chromaticity consistency of the red, green, or blue shades. Gray tracking is the chromaticity consistency of the gray shades. Color tracking and gray tracking are the most important colorimetric responses of a color medical display because they directly indicate the color calibration quality and can therefore be used to compare color performance between displays. Two metrics, primary purity and gray purity, are defined to measure the color shift of the primary shades and gray shades of a color display, respectively. The area under the curves of primary purity and gray purity can then represent the quality of color tracking (C_AUC) and gray tracking (G_AUC), respectively. Fifteen displays including medical, professional-grade, consumer-grade, mobile, and special displays were tested to compare their C_AUC and G_AUC. The OLED displays have the greatest C_AUC values. The medical and professional-grade displays have the greatest combinations of C_AUC and G_AUC values. Most consumer-grade displays have lower C_AUC and G_AUC values, but some show better gray tracking than color tracking. The special displays exhibit particularly poor color and gray tracking. Using C_AUC and G_AUC together can quantitatively predict and compare color performance of different displays.

Three blue emitters via twisted donor–acceptor molecular design strategy show extremely good color purity without impairing the excellent photophysical and electrical properties. The color purity of nondoped devices can meet the blue OLED requirements of NTSC.

We propose a design of angle-insensitive and polarization-independent reflective color filters with high efficiency (>80%) based on broad resonance in a Fabry–Pérot cavity where asymmetric metal-dielectric-metal planar structures are employed. Broadband absorption properties allow the resonance in the visible range to remain nearly constant over a broad range of incident angles of up to 40° for both s- and p-polarizations. Effects of the angles of incidence and polarization state of incident light on the purity of the resulting colors are examined on the CIE 1931 chromaticity diagram. In addition, higher-order resonances of the proposed color filters and their electric field distributions are investigated for improved color purity. Lastly, the spectral properties of the proposed structures with different metallic layers are studied. The simple strategy described in this work could be adopted in a variety of research areas, such as color decoration devices, microscopy, and colorimetric sensors.

Unlike color dyes, structural colors only slightly fade during long-term usage. Here, structural colors were controllably achieved by constructing CoFeB photonic crystal layers on the surface of a nanoporous aluminum oxide (AAO) substrate by magnetron sputtering deposition. The resulting material showed a wide visible spectral response and achieved structural color control with a high resolution, high color purity, and saturation. The angle-dependent color changes of CoFeB@AAO films were further investigated by changing the incident light angle. The simulation results of the model are consistent with the experiments, which is significant in practical applications. This strategy may have great potential applications for solid structure color coatings, anti-counterfeiting and security, information storage, and electromagnetic sensors.

This paper is mainly about the high power LED temperature characteristics. With the integrating sphere, we conduct an experiment to observe and analysis the relationships of temperature and color coordinates, peak wavelength, color temperature, forward voltage, peak bandwidth, color purity, electric power. Finally we get that the temperature is the main factor to affect the color performance of white LED photoelectric, with the white LED apparent temperature rise, forward voltage, the color coordinates and color purity tends to go down. On the contrary with increasing junction temperature, the half-value wavelength and color temperature are increased accordingly.

Дисертація на здобуття наукового ступеня доктора технічних наук за спеціальністю 05.17.11 – технологія тугоплавких неметалічних матеріалів, Державний вищий навчальний заклад "Український державний хіміко-технологічний університет", Національний технічний університет "Харківський політехнічний інститут", Харків, 2020. Дисертацію присвячено розвитку наукових основ технології екологічно безпечних захисно-декоративних склоемалевих покриттів широкої колірної гами по сталі і кольоровим металам, а також принципів регулювання та прогнозування їх колірних характеристик. Внаслідок проведення дослідження за темою дисертаційної роботи одержані такі наукові результати: - науково обгрунтовано та експериментально доведено, що отримання на кольорових металах емалевих покриттів, які не вміщують Плюмбум, можливе на основі стекол системи Na₂O–BaO–B₂O₃–SiO₂; за комплексом визначених властивостей та здатності утворювати найбільш якісні покриття на мідній основі виділена область базової системи, мол.%: Na₂O – 24,2–40,5; ВаО – 5,0–10,0; B₂O₃ – 15,2–30,5; SiO₂ – 24,0–53,5, яка у зрівнянні з межами цих компонентів в відомих складах безплюмбатних емалей характеризується збільшеним в 2 рази вмістом B₂O₃ і відносно невеликим вмістом SiO₂; - встановлені основні тенденції зміни колірного тону стекол системи Na₂O–BaO–B₂O₃–SiO₂, які суттєво відрізняються за хімічним складом та забарвлені іонними барвниками, з огляду на розташування максимумів ІЧ-спектрів стекол та їх кислотно-основні властивості; останні оцінювались двома розрахунковими структурними параметрами: fSi – ступінь зв’язності кремнекисневого каркасу і Ψв – орієнтовний показник координаційного стану Бору в структурі скла. Доведено, що між колірним тоном λ та Ψв існує значний кореляційний зв'язок для стекол, забарвлених CuO r*=−0,83 і CoO r*=−0,87 та слабкий – для стекол, забарвлених K₂Cr₂O₇ – r*=0,5; - виявлені закономірності забарвлення одної скломатриці і емалевого покриття на її основі в системі R₂O–ВаО–ZnO–Al₂O₃–В₂О₃–TiO₂–SiO₂ рядом іонними барвників. Незалежно від вмісту барвників, вони надають однаковий колірний тон як стеклам, так і покриттям на основі цих стекол, а саме: CuO (1,0–3,0 мас.%) λ=489–494 нм (синьо-зелений), Fe₂O₃ (0,5–2 мас.%) λ=575–585 нм (жовтий), K₂Cr₂O₇ (0,5–2,0 мас.%) λ=570–576 нм (жовто-зелений), CoO (0,5–1,0 мас.%) λ=441–463 нм (синьо-фіолетовий), NiO (0,5–1,0 мас.%) λскла=559′–571′ нм, λпокриттів=598–629 нм (коричневий). Доказано, що за ступенем інтенсивності забарвлення стекол та покриттів на їх основі барвники розташовуються в наступній послідовності: CoO > NiO > CuO > K₂Cr₂O₇ > Fe₂O₃; - вперше встановлений механізм глушіння прозорого матричного емалевого скла в системі R₂O–ВаО–ZnO–TiO₂–Al₂O₃–В₂О₃–TiO₂–SiO₂ при введені МоО3, в результаті якого виникає явище опалесценції, а саме: за рахунок дифракції при розповсюдженні хвиль в мікронеоднорідному середовищі, в якому розмір часток молібден(VI) оксиду (0,05–0,15 мкм) менше довжини хвиль білого світла; - вперше встановлена залежність коефіцієнта дифузного відбиття емалевих покриттів від хімічного складу емалевих фрит, яка отримана обробкою експериментальної вибірки 471 складу покривних емалевих фрит методом множинного кореляційного аналізу і представлена у вигляді математичної моделі, що дозволяє розрахувати хімічний склад покривних емалей із заданим КДВ; коефіцієнт кореляції між експериментальними і розрахунковими значеннями – 0,98; - використовуючи ідею про введенні в будь-який матеріал (скло, пігмент, ситал, метал) певних компонентів в незначній кількості для модифікації його властивостей, вперше виявлено наступне: «малий додаток» Fe₂O₃ у кількості 0,25 мас.% в складі безплюмбатних емалевих стекол на основі базової системи Na₂O–BaO–B₂O₃–SiO₂ і 1 мас.% в складі безфлуористих склоемалей на основі базової системи Na₂O–B₂O₃–SiO₂ активізує процеси лікваційного розшарування скла, що дозволяє збільшити в 1,5–2,5 рази інтенсивність глушіння покриттів, а також покращити оптико-колірні характеристики пігментнозабарвлених склопокриттів, зокрема, червоного кольору. «Малий додаток» ZrO₂ у кількості до 1 мас.% в складі малофлуористої титанової емалі сприяє активному виділенню анатазу в покритті під час випалу та покращенню його оптичних характеристик; - за допомогою розробленої спеціальної комп’ютерної програми COLOUR GLASS, яка автоматично розраховує координати кольорності x y, колірний тон λ, чистоту кольору Р та наносить колірні характеристики матеріалів на графік МКО, вперше доказано, що за картиною розташування точок кольору, по-перше, можна робити прогнози відносно рівноваги, яка утворюється між іонними забарвлюючими комплексами під час варки скла, по-друге, про колористичні можливості суміши пігментів - вперше в області технологій, які потребують підвищених температур, встановлені залежності координат кольору емалевих покриттів від складу суміші пігментів у вигляді поліноміальних математичних моделей, що дозволило вирішити складну матеріалознавчу колористичну проблему знаходження співвідношення пігментів для відтворення кольору зразка із заданими колірними характеристиками. Практичне значення отриманих результатів: - розроблено склади емалевих стекол для кольорових металів, які не містять Плюмбуму – одного із самих шкідливих для навколишнього середовища елемента, запропоновано основи технології одержання виробів з їх використанням. Нові емалі широкої палітри кольорів, різного ступеню прозорості створено на основі матричної прозорої емалі. Вони характеризуються однаковим інтервалом випалу 780–820 °С, у зв’язку з чим спрощується технологія отримання художніх і ювелірних виробів. Емалі пройшли випробування та рекомендовані до впровадження у виробництво з виготовлення художніх виробів в майстерні, що знаходиться в структурі Музею українського живопису (м. Дніпро), а також на підприємстві з виготовлення ювелірних виробів, компанія "Diadema", м. Вінниця. Палітра емалевих покриттів та вироби з них представлені під час доповіді на 24 Міжнародному Конгресі емальєрів в м. Чикаго у 2018 р. Згідно міжнародного договору між ДВНЗ УДХТУ та компанією "Richemont International SA Varinor SA" м. Делемонт, Щвейцарія, виготовлено і передано замовнику емалеві стекла у вигляді порошку і емальовані мідні зразки; - створено каталог зразків кольорів, в якому представлено склооснови, кількість барвників, глушників, відновників та оптико-колірні характеристики емалевих покриттів, що не містять Плюмбум. Назву кольорів встановлювали у відповідності із назвою кольорів системи RAL. Палітра розроблених емалей ювелірного та художнього призначення включає 54 кольори: жовто-червоні, синьо-зелені, оливково-гірчичні, пастельні та коричнево-чорні; - розроблено склади малофлуористих білих і світлозабарвлених титанових емалей, безфлуористої склооснови для отримання яскравозабарвлених емалевих покриттів пігментним способом, які випробувані в виробничих умовах ТОВ «Новомосковський посуд» і рекомендовані до серійного впровадження на заводах з випуску емальованих виробів господарчо-побутового призначення. Технологічні особливості виробництва запропонованих емалей дозволяють здійснювати високотемпературні операції варки емалей на 100 °С, а випалу покриттів – на 30–50 °С нижче відомих, що в епоху тотальної економії топливно-енергетичних ресурсів дуже актуально. Малофлуористі світлозабарвлені кремова і сіро-блакитна емалі впроваджені на ТОВ "Новомосковський посуд"; - вперше для технології емалевих покриттів на сталі розроблено метод колірного моделювання, завдяки якому побудовано колірний трикутник-номограму для виробничої склооснови і пігментів жовтого, червоного, синього, за допомогою якого задається необхідний колір і розраховується необхідне співвідношення пігментів. Метод колірного моделювання є універсальним і може бути застосованим до широкого асортименту силікатних матеріалів: глазуровані покриття на керамічній основі, кольорові будівельні матеріали та інші. У вступі обґрунтовано актуальність теми дисертації, сформульовано головну мету та завдання роботи, представлено наукову новизну та практичну цінність одержаних результатів. В першому розділі наведено аналіз патентної та науково-технічної літератури, що стосується отримання екологічно безпечних емалей широкої колірної гами, сучасного стану виробництва кольорових емалей та контролю їх колірних показників, механізмів забарвлення скла та емалей і факторів, що впливають на формування кольору. У другому розділі надано основні поняття та визначення, які використовуються в роботі, а також методики дослідження фізико-хімічних властивостей і структури стекол, покриттів та їх колірні характеристики. В третьому розділі представлено дослідження з розробки екологічно безпечних емалей для міді та прогнозування їх колірних характеристик. В четвертому розділі представлено результати досліджень з розробки легкоплавкої титанової емалі, яка відповідала б вимогам діючих стандартів та випалювалась в ресурсо- та енергозберігаючих умовах виробництва та була максимально екологічно безпечною для навколишнього середовища. П'ятий розділ присвячений дослідженням з розробки складів емалевих фрит, що не вміщують Флуор, які використовуються для отримання яскравозабарвлених емалевих покриттів для виробів господарчо-побутового призначення. В шостому розділі представлені результати розробки методу колірного моделювання. Відтворити, а тим більше спрогнозувати колір із заданими колірними характеристиками – надзвичайно складна багатопланова матеріалознавча проблема, навіть якщо відома рецептура скла і покриття, режими їх варки та випалу. В сьомому розділі надано результати промислової апробації, реалізації та впровадження отриманих матеріалів.
Thesis for a Doctor of Science Degree in Specialty 05.17.11 – Refractory Non-Metallic Materials Technology, State Higher Educational Institution "Ukrainian State University of Chemical Technology", National Technical University "Kharkiv Polytechnic Institute", Kharkiv, 2019. The dissertation is devoted to creation of physicochemical bases of technology of ecologically safe protective and decorative glass-enamel coatings of wide color scale on steel and non-ferrous metals, development of principles of regulation and prediction of their color. As a result of the research on the topic of dissertation the following scientific results were obtained: - scientifically substantiated and experimentally proved that the production of lead-free enamel coatings on non-ferrous metals is possible on the basis of the Na₂O – BaO – B₂O₃ – SiO₂ glasses, by the complex of defined properties and the ability to form the highest quality coatings on a copper basis the selected region of the base system, mol %: Na₂O – 24,2–40,5; BaO – 5.0–10.0; B₂O₃ – 15.2–30.5; SiO₂ – 24,0–53,5, which in comparison with the limits of these components in known compositions of lead-free enamels, is characterized by a 2-fold increase in the content of B2O3 and a relatively small content of SiO₂; - the basic tendencies of color change of glasses of Na₂O–BaO–B₂O₃–SiO₂ system has been established, which differ significantly in chemical composition and has colored by ionic dyes, taking into account the structural features of glasses and their acid-basic properties. They has been evaluated by two calculated structural parameters: fSi is the degree of connectivity of the silica framework and Ψв is an indicative index of the coordination state of Boron in the structure of the glass. It had proved that there is a significant correlation between the colors λ and Ψv had proved for glasses colored CuO r * = - 0,83 and CoO r * = - 0,87 and weak – for glasses colored K₂Cr₂O₇, -r * = 0,5; - the patterns of coloring of one glass matrix and enamel coatings on its basis in the system R₂O–BaO–ZnO–Al₂O₃–B₂O₃–TiO₂–SiO₂ by a series of ionic dyes has been founded. Regardless of the content of the dyes, they give the same color tone to the glass and coatings based on these glasses, namely: CuO (1.0–3.0 wt%) λ = 489–494 nm (blue-green), Fe₂O₃ (0.5–2 wt%) λ = 575–585 nm (yellow), K₂Cr₂O₇ (0,5–2.0 wt%) λ = 570–576 nm (yellow-green), CoO (0.5–1.0 wt%) λ = 441–463 nm (blue-violet), NiO (0, 5-1.0 wt.%) λ glass = 559′ – 571 nm, λ coatings = 598–629 nm (brown). It has been proved that in the degree of color intensity of glasses and coatings based on them, the dyes has been arranged in the following sequence: CoO> NiO> CuO> K₂Cr₂O₇ > Fe₂O₃; - for the first time, the mechanism of silencing of transparent matrix enamel glass in R₂O–BaO–ZnO–TiO₂–Al₂O₃–B₂O₃–TiO₂–SiO₂ system with the introduction of MoO₃ has been established, which results in the phenomenon of opalescence, namely: due to diffraction at propagation of waves in micro inhomogeneous medium in which the particle size of molybdenum (VI) oxide is 0.05-0.15 μm less than the wavelength of white light; - for the first time, the dependence of the diffuse reflection coefficient (CDR) of enamel coatings on the chemical composition of enamel frits, obtained by processing the experimental sample 471 of the enamel frit composition by multiple correlation analysis, which is presented in the form of a mathematical model that allows you to calculate the chemical composition of the enamel coatings with a given CDR; the correlation coefficient between experimental and calculated values is 0.98; - using the idea of introducing into any material (glass, pigment, sitall, metal) certain components in a small amount to modify its properties, the following has been first discovered: "small addition" of Fe₂O₃ in the amount of 0.25 wt.% in the composition of lead-free enamel glasses based on the base system Na₂O–BaO–B₂O₃–SiO₂ and 1 wt.% in the composition of fluorless glass enamels based on the basic system Na₂O–B₂O₃–SiO₂ activates the processes of differentiation of the segregation-dropping structure of glass, which allows to increase the intensity of opaque coatings by 1.5–2.5 times, as well as to improve the optical-color characteristics of pigment-colored glass coatings, in particular, red. "Small addition" of ZrO₂ in the amount up to 1 wt.% in the composition of low-fluoride titanium enamel promotes the active release of anatase in the coating during firing and improving its optical characteristics; -with the help of a dedicated COLOR GLASS computer program that automatically calculates color coordinates x y, color tone λ, color purity P, and maps the color characteristics of materials to the СIE graph, it has been first demonstrated that the picture of the location of the color points, first, you can make predictions about the equilibrium that is formed between the ionic coloring complexes during the melting of glass, and secondly, about the color potential of the pigment mixture. - for the first time in the field of technologies requiring high temperatures, the dependences of the color coordinates of the enamel coatings on the composition of the pigment mixture in the form of polynomial mathematical models has been established, which made it possible to solve the complex material-coloristic problem of finding the ratio of pigments to reproduce the color of the sample with the specified color characteristics. The practical significance of the obtained results: - the compositions of enamel glasses for non-ferrous metals, which do not contain Plumbum - one of the most harmful for the environment element, had been developed; the basics of technology of obtaining products with their use had offered. New enamels of a wide range of colors with varying degrees of transparency had been created on the basis of matrix transparent enamel and they had characterized by the same firing interval of 780-820 °C, which makes the technology of obtaining artistic and jewelry easier. Enamels had been tested and recommended for implementation in the production of artistic products in the workshop, which locates in the structure of the Museum of Ukrainian Painting (Dnipro), as well as at the jewelry company, Diadema, Vinnytsia. The enamel coatings palette and their products had presented during a report at the 24th International Congress of Enamels in Chicago in 2018. According to an international agreement between the Ukrainian State University of Chemical Technology (Dnipro) and Richemont International SA Varinor SA, Delmont, Switzerland, enamel glass powder and enameled copper samples had been made and handed over to the customer; - a catalog of color samples, which presents the glass base, the number of dyes, opacifiers, reducing agents and the optic-color characteristics of enamel coatings which do not contain Plumbum, has been created. The color name was set in accordance with the color name of the RAL system. The palette of designed enamels of jewelry and artistic purpose includes transparent matrix enamel and 53 colors: yellow-red, blue-green, olive-mustard, pastel and brown-black; - a series of compositions of white and light-colored titanium enamels containing reduced amount of Fluorine, has been developed, also the composition of fluorless frites to obtain brightly colored enamel coatings pigmented way of color, which were fused and passed extensive testing in production conditions factories for the production of enameled household products, has been synthesized. Technological features of production of the enamels offered permits to carry out high-temperature operations of melting at 100oC below the known ones, and firing of coatings – by 30-50 °C, which is very relevant in the era of total saving of fuel and energy resources. Low-fluoride light-colored cream and gray-blue enamels has been introduced at "Novomoskovsk dishes"; - for the first time for the technology of enamel coatings on steel, a method of color modeling has been developed, through which a color triangle-nomogram has been constructed for the production glass base and pigments of yellow, red, blue, by which the required color is specified and the necessary ratio of pigments is calculated. The color modeling method is versatile and can be applied to a wide range of silicate materials: glazed ceramic coatings, colored building materials, and more. The introduction substantiates the relevance of the dissertation topic, formulates the main purpose and objectives of the work, presents the scientific novelty and practical value of the obtained results. The first section provides an analysis of the patent and scientific and technical literature concerning the production of environmentally safe enamels of a wide color range, the current state of production of colored enamels and the control of their color indices, the mechanisms of color of glass and enamels and factors affecting color formation. The second section provides the basic concepts and definitions used in the work, as well as methods for investigating the physicochemical properties and structure of glasses and coatings and their color characteristics. The third section presents studies on the development of environmentally safe enamels for copper and the prediction of their color characteristics. The fourth section presents the results of research on the development of fusible titanium enamel which would meet the requirements of current standards and be burned in resource- and energy-efficient production conditions and be the most environmentally safe for the environment. The fifth section is devoted to the research on the development of enamel frits that do not contain Fluorine and used to produce brightly colored enamel coatings for household products. The sixth section presents the results of the development the color modeling method. Reproduce, and even more so predict, color with predetermined color characteristics is an extremely complex multifaceted material science problem, even if glass and coating formulations, modes of melting and firing are known. In the seventh section the results of industrial testing, realization and implementation of the received materials has been presented.

Дисертація на здобуття наукового ступеня доктора технічних наук за спеціальністю 05.17.11 – технологія тугоплавких неметалічних матеріалів, Державний вищий навчальний заклад "Український державний хіміко-технологічний університет", Національний технічний університет "Харківський політехнічний інститут". Дисертацію присвячено науковим основам технології екологічно безпечних склоемалевих покриттів широкої колірної гами для сталі і кольорових металів, розробці принципів регулювання та прогнозування їх кольору. Розроблена спеціальна комп’ютерна програма COLOUR GLASS, яка за визначеними координатами кольору XYZ автоматично розташовує точки кольору на графіку МКО. Отримані емалі ювелірного та художнього призначення на основі стекол системи Na₂O–BaO–B₂O₃–SiO₂. Розроблені малофлуористі білі і світлозабарвлені титанові емалі, безфлуориста основа для пігментного способу забарвлення. Створено метод колірного моделювання, за допомогою якого можна розрахувати співвідношення пігментів для відтворення кольору зразка за заданими колірними характеристиками.
Thesis for a Doctor of Science Degree in Specialty 05.17.11 Refractory Non-Metallic Materials Technology, State Higher Educational Institution "Ukrainian State University of Chemical Technology", National Technical University "Kharkiv Polytechnic Institute". The dissertation is devoted to development of scientific bases of technology of ecologically safe protective and decorative glass-enamel coatings of wide color scale on steel and non-ferrous metals, making of principles of regulation and prediction of their color. The introduction substantiates the relevance of the dissertation topic, formulates the main purpose and objectives of the work. The first section provides an analysis of the patent and scientific and technical literature. The second section provides the basic concepts and definitions used in the work, methods for investigating the physicochemical properties and structure of glasses and coatings and their color characteristics. The third section presents studies on the development of environmentally safe enamels for copper and the prediction of their color characteristics. The fourth section presents the results of studies on the development of small fluoride titanium enamel with a firing temperature of 830 °C. The fifth section had devoted to scientific bases of technology of fluorless enamel frits for pigment method of coloring. The sixth section has devoted to the development of the color modeling method for reproducing the color of a sample with specified color characteristics. In the seventh section the results of industrial testing, implementation and implementation of the received materials has presented. As a result of the research on the topic of dissertation the following scientific results has obtained: - scientifically substantiated and experimentally proved that the production of lead-free enamel coatings on non-ferrous metals is possible on the basis of the Na₂O–BaO–B₂O₃–SiO₂ glasses, the regions of glass formation has been determined, and the regularities of changes in the properties of glasses depending on their chemical composition has been established; - the main tendencies of change of glasses color tone has established in the Na₂O–BaO–B₂O₃–SiO₂ system, which has colored by ionic dyes given the structural features of the glasses and their acid-base properties; - it has been proved that the degree of color intensity of glasses in the system R₂O –BaO – ZnO – Al₂O₃ – B₂O₃ – TiO₂ – SiO₂ and coatings based on them has been arranged in the following sequence: CoO> NiO> CuO> K₂Cr₂O₇> Fe₂O₃; - for the first time the mechanism of opacifying of transparent matrix enamel glass in the R₂O – BaO – ZnO – TiO₂ – Al₂O₃ – B₂O₃ – TiO₂ – SiO₂ system was introduced when MoO₃ has been established, namely: due to diffraction, which results in the phenomenon of opalescence; - for the first time the dependence of the diffuse reflection coefficient of enamel coatings on the chemical composition of enamel frits has been established, which is presented in the form of a mathematical model; the correlation coefficient between experimental and calculated values is 0.98; - for the first time the mechanism of opacifying of transparent matrix enamel glass in the R₂O – BaO – ZnO – TiO₂ – Al₂O₃ – B₂O₃ – TiO₂ – SiO₂ system was introduced when MoO3 has been established, namely: due to diffraction, which results in the phenomenon of opalescence; - for the first time it has been discovered that Fe₂O₃ "small additive" in the amount of 0.25 wt.% in the composition of lead-free enamel glasses on the basis of the Na₂O – BaO – B₂O₃ – SiO₂ base system and 1 wt. Fe₂O₃ in the composition of fluor-free enamel glasses on the basis of the Na₂O – B₂O₃ – SiO₂ base system activates the processes of glass removal stratification, which allows to increase 1.5-2.5 times the intensity of coating damping; - with the help of a special computer program COLOR GLASS, which automatically calculates the coordinates of the color x, y, the color tone λ, the purity of the color P and applies the color characteristics of the materials to the CIE graph, it has been proved for the first time that the chart of the location of color points can make forecasts about the equilibrium, which formed between ionic coloring complexes during glass melting; - for the first time in the field of technologies requiring high temperatures, the dependences of the color coordinates of enamel coatings on the composition of the pigment mixture in the form of polynomial mathematical models has been established, which allowed to solve the complex material-coloristic problem of finding the ratio of pigments to reproduce the color of the sample with the specified color characteristics. The practical significance of the obtained results: - the compositions of enamel art and jewelry glasses for non-ferrous metals, which do not contain Plumbum, has been developed. They are characterized by the same firing interval of 780-820 °C. A catalog of color samples has created. The palette includes fondon and 53 colors: yellow-red, blue-green, olive-mustard, pastel and brown-black; - a series of compositions of white and light-colored titanium enamels containing reduced amount of Fluorine (up to 2.5 wt.%), has been developed, also the composition of fluorless frites to obtain brightly colored enamel coatings pigmented way of color. Temperature operations of the enamel melting is 100 °C and firing of coatings is 30-50oC below the known ones.

Les développements de deux spéctromètres de saturation à ultra-haute résolution dans le domaine infrarouge, l'un dans la région spectrale 9-12 mu m et l'autre accordable de 2,3 a 3,2 mu m sont exposés en detail. La stabilisation en fréquence d'un laser à CO(2) conventionnel ou guide d'ondes au niveau de la dizaine de hertz ainsi que l'obtention d'une stabilité meilleure que 1 khz pour le laser à centres colores soulignent le role cle de ces oscillateurs dans la chaine de raccordement de fréquence de l'horloge à cesium vers le domaine visible. L'étude des interactions hyperfines est presentée dans le cas des molécules diatomiques héteronucleaires (hf) et des toupies spheriques du groupe ponctuel O(h) (sf(6)). Grace a l'enregistrement de structures hyperfines tres bien resolues, de nombreux effets ont etes mis en evidence et interpretes à l'aide du formalisme tensoriel (dans le groupe (l)o(3) x O(h)) en particulier : l'interaction de spin-vibration (bande upsilon (3) de sf(6)), les mélanges d'états de types de symétrie differents (sf(6)), les corrections ro-vibrationnelles à l'interaction de spin-rotation (hf et sf(6)), les structures superhyperfines (sf(6))

碩士
南台科技大學
電機工程系
93
Nowadays, there are some situations in the market. For example, FPDs （Flat Panel Displays） has become the trunk stream of the electrical and electronic industry markets. If TFL-LCDs and PDPs can be produced as many as possible with high efficiency, the high price will become the common price. So we can image that FPDs must become the trunk stream in the market of the electrical and electronic industry. But now, most substrates of FPDs are made of glass, so when the size of displays is bigger; the weight will become heavier, then it will burst easily. Now, we had better make the substrates of display by using the flexible materials to replace the glass, then we can reduce the cost. When it comes to the substrate whose material us flexible, now, OEDs （Organic Electroemissive Devices）is the most potential. And compared with other developed displays, organic light-emitting display has some advantages, such as high power efficiency, high brightness, fast response time, and full viewing angle. Besides, it is light, thin and having a big size of dimension. In addition, it can be flexible. Because of these advantages, organic light-emitting displays will replace those FPDs, and become more popular tendency. Since organic light-emitting devices have been developed, the substrate of organic light-emitting devices, which is made of glass is with some emissive light, including green, blue and red. The radiating efficiency of green light is the best; the other ones are minor. Besides, we can make full color organic light-emitting displays, but we can’t do anything because of the restriction of the glass. Nevertheless, we have a project to make the substrate, which is made of flexible materials. By using the radiating way of Host-Guest system, various concentrations quenching result from different guest concentration, we do the studying of parameters, And then we are able to make the fluorescent red light with better efficiency of the primary colors, RGB, and analyze the completing brightness, operating voltage, operating electric current, and outer quantum. Now, our team is able to make the green light of organic light-emitting devices whose material could be flexible. In addition, we are doing some study about the blue light. Now, in order to achieve the goal that is about the flexible organic light-emitting displays, the red light of flexible organic light-emitting device is the important point that we should develop.

博士
國立成功大學
微電子工程研究所碩博士班
99
This dissertation presents various organic light-emitting diode (OLED) structures with high efficiency and high color purity, including those with bottom-emission white light, top-emission green light, and top-emission white light. In the design of a white light device, TBADN is used as the blue host and rubrene is used as the yellow dopant. Alq3 is used as the green host, doped with C545T fluorescent material, to obtain a high-performance green light device. The carriers do not recombine effectively in the emission layer because the HOMO energy level of the blue host (TBADN) is almost the same as that of the electron transporting layer (Alq3). The emission layer is divided into two layers by another thin Alq3 layer, and a hole-blocking layer (BCP) is inserted between the emission layer and the electron transporting layer. The current efficiency of white light device was thus improved from 4.26 cd/A to 5.44 cd/A. However, the yellow emission of the device is enhanced by the small energy barrier of LUMO between BCP and rubrene, affecting the color purity of the white light device. The emission layer is divided into a doped layer and an undoped layer, and the experimental results reveal that the color purity of white light is significantly improved. The TBADN and rubrene are also used for top-emission white-OLEDs with the device structure Ag(200 nm)/NPB(40 nm)/TBADN(13 nm)/TBADN: (0.5%)rubrene (9 nm)/TBADN(11 nm)/Alq3(1 nm)/BCP(3 nm)/TBADN(30 nm) /BCP(5 nm)/Alq3(4 nm)/LiF(1 nm)Ag(20 nm)/NPB(40 nm). Since TBADN has low efficiency and the Ag film has low transparency to blue emission, three blue-emitting layers of different thickness and a hole-blocking layer are applied to enhance the blue emission in this work. The CIE coordinate of the device at 5 V indicates that it has high color purity. To fabricate a top-emission device, Ag was used as the anode and two methods of oxidation were utilized to treat the Ag surface. They were the UV-ozone method and PECVD. The work function of Ag increases with the period of exposure in UV-ozone treatment. However, such treatment also increases the sheet resistance and degrades the surface reflectance. The optimal exposure time was around 3 minutes in the experiment performed in this study. However, the performance of an OLED device that has undergone PECVD treatment is determined by the operating power and the oxidation time. The optimal conditions were 2 W for 6 minutes in the experiment herein. In the fabrication a top-emission OLED, C545T, which has high quantum efficiency, was doped into an Alq3 host and a 2nm-thick hole-blocking layer (BCP) was used deposited on the host. The LUMO of BCP is close to that of C545T and hence increasing the C545T emission and device efficiency. The current efficiency of the green-OLED is improved from 5.19 cd/A to 19.43 cd/A under a 1% doping concentration. The current efficiency of a top-emission white-OLED is improved from 0.56 cd/A to 1.08 cd/A using Ag-anode oxidation. The CIE coordinate of the device at 5 V is (0.35, 0.33), indicating the good color purity of the white-OLED.

碩士
國立中興大學
材料科學與工程學系
96
The main objective of this thesis is to study on how to improve the color-purity of LEDs, design and develop the optical filter to apply on RGB LEDs. Using measuring equipments to measure the spectrum and check the effects of improving the color-purity of LEDs. And estimating the effects on color gamut after improving the color-purity of LEDs by check the space on the CIE chromaticity coordinates. The standard color of space that had been approved by the National Television System Committee (NTSC) is used as the reference and defined as 100%. About the FWHM (Full Width Half Maximum) of Green light is too wide and there is mixed-zone between blue and green light in the RGB LEDs spectrum, we design green light narrow band-pass filter, mixed-zone band-stop filter and RGB narrow band-pass filter by optical design software. And we use the materials of TiO2 and SiO2 to make the filter film by thin film evaporation equipment. From the experiment, we have found the results as following: 1. The RGB-narrow-band-pass-filter is the best one for improving the LED color purity, and the 0.4mm-glass is the best substrate. 2. The FWHM of red, green and blue light were decreasing under 17nm in axial light measurement after RGB-narrow-band-pass-filter apply on LEDs, and the range of color gamut was increasing from 118.41% to 132.56% according to NTSC standard. 3. The limitation of this study is that the filters in our experiments can not be effective for lateral light because of the light leaking from cross-section of LED chip and the different incident angle of light.

碩士
明志科技大學
材料工程系碩士班
106
The research is based on the resonant cavity of an optical thin film process, the simple Ag/ITO/Ag cavity structure is applied to the OPV (Organic Photovoltaic) electrode so that the OPV retains the original PCE (>8%) and has good clear color transmittance (>15%), both green energy, and humanistic aesthetics. The solar light simulator is used as the light source of the photodiodes, and the self-made filter is used to detect the characteristics in the different wavelength. The filter uses a combination of an ITO-Ag multilayer thin film resonant cavity and resonance penetrating One-dimensional photonic crystal to limit the penetration peak at a half-height width of 10 nm. Apply the high-purity color of this resonant cavity combination filter to achieve accurate color discrimination of the photodiodes. In the detection of the linearity of the light intensity of the photodiodes, the self-made filter, the attenuate filter and the detection system are used to detect the short-circuit current change of the photodiodes when the light intensity changes, and the experimental rationality is theoretically calculated. Finally, compared with the experimental data in the standard measurement environment, it can be found that the self-made detection system and theoretical prediction have the same trend as the detection data in the standard environment.

This chapter explores two case studies that each illustrate an attempt to infuse feminist politics into the economically driven apparatus of book publishing: Sisterhood Is Powerful (1970) and This Bridge Called My Back: Writings by Radical Women of Color (1981). Exploring the publication history of Sisterhood Is Powerful provides a landmark case study of feminist experimentation in publishing that was inevitably fraught with controversy due to the ideological struggles of the time over economic and political “purity.” This Bridge Called My Back was published under an unusual type of contract in which contributors, rather than receiving a one-time payment at the beginning, would continue to receive payments for every ten thousand copies sold. Overall, these studies show the variety of ways in which feminists tried to get around the “taint” of publishing's relationship to the power structure in order to enact a feminist sensibility not just in the content of their writing but also in its production and dissemination.

The colour white was central to twenties aesthetics. Modernists associated it with purity, rigour, and absence of decoration: plain white privileges volume over surfaces. Modern baroque decorators used whiteness differently, to unify eclectically sourced objects. Their ‘amusing’ use of white combined multiple shades of near-white in different textures to create sophisticated effects. But, like the modernists, baroque decorators were more interested in shape than colour.

According to early-twentieth-century raciologists, the Mediterranean race, which could be found all over Europe, especially in the South, had disturbing ties to Africa and Asia and, moreover, with their vitality and appeal, could win over white women and dilute Nordic bloodlines. In their fiction, the Fitzgeralds depict the Mediterranean as a fluid site of intermixture. For F. Scott Fitzgerald, the networks that connect regional Souths to global Souths compromise the purity of the white woman and addict the white man to substances that sap his vitality. For Zelda Fitzgerald, syrupy, soggy southern climes and dishes provide a medium for white women to reject purity in favor of the stickiness that connects them to abject racialized bodies and reject mind–body dualism.

Chapter 1 documents the life path of Thomas Jefferson Brown, the son of an African-American father and Irish mother, who migrated from Arkansas to Indian Territory in the 1870s and married two African-descended women of the Creek and Seminole nations. This chapter uses Brown’s story to illustrate how some early African-American settlers initially bolstered their claims to freedom in the postemancipation era by attaching themselves to American expansion, Native Americans, and the acquisition of Indian land. This complex moment of African-American participation in the expropriation of Indian Territory was tellingly short-lived. African-American access to Indian land ended abruptly with the advent of Oklahoma statehood, Jim Crow segregation, and oil speculation. As Indian sovereignty was dissolved and notions of racial purity and “blood” acquired growing significance, “race” ultimately eclipsed “nation” as a guarantor of rights and resources. Brown’s story illuminates the construction of a new racial order in Indian Territory, and, ultimately, the limits of North American escape.

Brazil is the largest coffee producer in the world, and then there are many challenges to maintain the high quality and purity of the beans. Thus, it is important to study coffee plants, and help agronomists to detect diseases, such as rust, with resources of computer science. In this work, it is described experiments using image segmentation algorithm JSEG, which is capable to segment images in multi-scale. Using a coffee tree image database RoCoLe (Robusta Coffee Leaf Images), the JSEG algorithm is used to segment these images in four scales. It is selected typical segments in each scale and they are grouped using similarity of normalized color histograms. In this way the several scales segmentations are compared. It is concluded that the segments in scales 1 and 2, in which the colors are more homogeneous then in scales 3 and 4, are adequate to use as training samples for the detection of rust diseases.

Resumen: Realizamos un nuevo estudio de las combinaciones de colores seleccionados por Le Corbusier en los ‘claviers’ para la empresa de papeles pintados Salubra en 1931, mediante su análisis en el espacio de color Natural Color System NCS, que permite comprender las variables perceptivas de los colores (tono, negrura y cromaticidad) y sus criterios de armonía. En este artículo discutimos las gamas tonales seleccionadas y aquellas que están ausentes., e intentamos desentrañar el orden subyacente en las combinaciones de colores mediante el estudio de las similitudes y contrastes de sus tonalidades en NCS. De manera gráfica, se demuestran algunos principios de armonía como el recurso habitual de contrastar tonos fríos con cálidos, algo que difiere ligeramente del tradicional contraste de complementariedad. El trabajo completo ha sido publicado en Color Research and Application © Wiley Periodicals. Color combination criteria in Le Corbusier's Purist architecture based on Salubra claviers from 1931. DOI: 10.1002/col.21940. Abstract: We have carried out a new study of the color combinations selected by Le Corbusier in the ‘claviers’ for the Salubra wallpaper company in 1931, by analyzing them in the Natural Color System NCS, which allows us to understand the perceptive variables of colors (hue, blackness and chromaticness) as well as their combination criteria. In this paper, the selected hue ranges are discussed, and those absent ones. We aim to find out the underlying order in the color combinations by studying the similarities and contrasts of their hues in NCS. We demonstrate graphically some principles in Le Corbusier’s color preferences, such as the usual resource of contrasting cool with warm colors, something slightly different to the traditional contrast of complementary colors. The complete work has been published in Color Research and Application © Wiley Periodicals. Color combination criteria in Le Corbusier's Purist architecture based on Salubra claviers from 1931. DOI: 10.1002/col.21940. Palabras clave: color, armonía; Le Corbusier; Salubra; arquitectura; Natural Color System. Keywords: color; harmony; Le Corbusier; Salubra; architecture; Natural Color System. DOI: http://dx.doi.org/10.4995/LC2015.2015.570

The grape seed oils are characteristic by a very high content of substances. However, a lipid oxidation is the fundamental problem of the seed oils quality degradation. The important indicator for determining the specific type’s purity, stability and level of oil degradation might be its colour parameter. The aim of this study was to identify the different varieties of oils, to evaluate its development during storage and to identify changes in different pressed seed oils. The CIELAB method and NIR spectroscopy were used during the research. Its main advantages include speed, accuracy and simplicity. The use of NIR seemed to be unsuitable as it could not reliably identify different kinds of grape seed oils. Only three kinds of grape seed oils out of six were identified. Contrary, the colour values obtained, using the CIELAB method, correlated significantly with the maturity of the individual varieties. This method can help to verify the authenticity of the oil. The CIELAB method also enabled colour changes in storage. The results show that after six months of storage, the oil got browner and the L* value had decreased. After another 6 months, the shift in values was not so significant. Similarly, the values of other parameters had changed. Using the CIELAB method can be recommended for testing of larger sample sizes for future use in the evaluation of the authenticity and quality of seed oils. The CIELAB method will not replace the standard methods but it might be used for pre-selection of tested samples.

Plants adjust their growth and development in a manner optimal for the prevailing light conditions. The molecular mechanisms by which light signals are transduced and integrated with other environmental and developmental signals are an area of intense research. (Batschauer, 1999; Quail, 2002) One paradigm emerging from this work is the interconnectedness of discrete physiological responses at the biochemical level, for instance, between auxin and light signaling (Colon-Carmona et al., 2000; Schwechheimer and Deng, 2001; Tian and Reed, 1999) and between light signaling and plant pathogen interactions (Azevedo et al., 2002; Liu et al., 2002). The COP9 signalosome (CSN) protein complex has a central role in the light control of plant development. Arabidopsis mutants that lack this complex develop photomorphogenically even in the absence of light signals (reviewed in (Karniol and Chamovitz, 2000; Schwechheimer and Deng, 2001). Thus the CSN was hypothesized to be a master repressor of photomorphogenesis in darkness, and light acts to bypass or eliminate this repression. However, the CSN regulates more than just photomorphogenesis as all mutants lacking this complex die near the end of seedling development. Moreover, an essentially identical complex was subsequently discovered in animals and yeast, organisms whose development is not light responsive, exemplifying how plant science can lead the way to exciting discoveries in biomedical model species (Chamovitz and Deng, 1995; Freilich et al., 1999; Maytal-Kivity et al., 2002; Mundt et al., 1999; Seeger et al., 1998; Wei et al., 1998). Our long-term objective is to determine mechanistically how the CSN controls plant development. We previously that this complex contains eight subunits (Karniol et al., 1998; Serino et al., 1999) and that the 27 ilia subunit is encoded by the FUS5/CSN7 locus (Karniol et al., 1999). The CSN7 subunit also has a role extraneous to the COP9 signalosome, and differential kinase activity has been implicated in regulating CSN7 and the COP9 signalosome (Karniol et al., 1999). In the present research, we further analyzed CSN7, both in terms of interacting proteins and in terms of kinases that act on CSN7. Furthermore we completed our analysis of the CSN in Arabidopsis by analyzing the remaining subunits. Outline of Original Objectives and Subsequent Modifications The general goal of the proposed research was to study the CSN7 (FUS5) subunit of the COP9 signalosome. To this end we specifically intended to: 1. Identify the residues of CSN7 that are phosphorylated. 2. Monitor the phosphorylation of CSN7 under different environmental conditions and under different genetic backgrounds. 3. Generate transgenic plants with altered CSN7 phosphorylation sites. 4. Purify CSN7 kinase from cauliflower. 5. Clone the Arabidopsis cDNA encoding CSN7 kinase 6. Isolate and characterize additional CSN7 interacting proteins. 7. Characterize the interaction of CSN7 and the COP9 signalosome with the HY5-COP1 transcriptional complex. Throughout the course of the research, emphasis shifted from studying CSN7 phosphorylation (Goals 1-3), to studying the CSN7 kinase (Goal 4 and 5), an in depth analysis of CSN7 interactions (Goal 6), and the study of additional CSN subunits. Goal 7 was also abandoned as no data was found to support this interaction.