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Добірка наукової літератури з теми "Chemical approach"

Автор: Grafiati

Опубліковано: 11 березня 2023

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Статті в журналах з теми "Chemical approach"

Cortini, Massimo, and Domenico Anastasio. "Chemical banding in volcanic minerals: a statistical phenomenological approach." European Journal of Mineralogy 13, no. 3 (May 29, 2001): 571–75. http://dx.doi.org/10.1127/0935-1221/2001/0013-0571.

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Liu, Yu, Mark Mercola, and Robert J. Schwartz. "The All-Chemical Approach." Circulation Research 119, no. 4 (August 5, 2016): 505–7. http://dx.doi.org/10.1161/circresaha.116.309146.

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Bartlett, P. N. "Integrated chemical systems. A chemical approach to nanotechnology." Journal of Electroanalytical Chemistry 387, no. 1-2 (May 1995): 151. http://dx.doi.org/10.1016/0022-0728(95)90297-x.

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Zaikov, Gennady, and Marina Artsis. "Degradation of polymers in aggressive media. Kinetic approach." Chemistry & Chemical Technology 3, no. 1 (March 15, 2009): 29–40. http://dx.doi.org/10.23939/chcht03.01.029.

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The degradation of polymers in aggressive media is a complex physico-chemical process including adsorption, diffusion and the dissociation of chemically unstable bonds. The course of degradation has a number of special features, which are linked both with the specific structure of polymeric materials and with specific kinetics of reactions in solids

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Sato, H., and H. Zhang. "Atomistic Approach of Chemical Diffusion." Defect and Diffusion Forum 95-98 (January 1993): 57–74. http://dx.doi.org/10.4028/www.scientific.net/ddf.95-98.57.

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Marks, Friedrich. "Chemical Carcinogenesis The Multistage Approach." Interdisciplinary Science Reviews 14, no. 3 (September 1, 1989): 233–40. http://dx.doi.org/10.1179/030801889789797970.

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Salakhutdinov, N. F., L. N. Rogoza, and G. A. Tolstikov. "Hypercholesterolemia: Chemical Aspect of Approach." Current Medicinal Chemistry 18, no. 26 (September 1, 2011): 4076–105. http://dx.doi.org/10.2174/092986711796957248.

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Kocherginsky, Nikolai, and Martin Gruebele. "Mechanical approach to chemical transport." Proceedings of the National Academy of Sciences 113, no. 40 (September 19, 2016): 11116–21. http://dx.doi.org/10.1073/pnas.1600866113.

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Nonequilibrium thermodynamics describes the rates of transport phenomena with the aid of various thermodynamic forces, but often the phenomenological transport coefficients are not known, and the description is not easily connected with equilibrium relations. We present a simple and intuitive model to address these issues. Our model is based on Lagrangian dynamics for chemical systems with dissipation, so one may think of the model as physicochemical mechanics. Using one main equation, the model allows a systematic derivation of all transport and equilibrium equations, subject to the limitation that heat generated or absorbed in the system must be small for the model to be valid. A table with all major examples of transport and equilibrium processes described using physicochemical mechanics is given. In equilibrium, physicochemical mechanics reduces to standard thermodynamics and the Gibbs–Duhem relation, and we show that the First and Second Laws of thermodynamics are satisfied for our system plus bath model. Out of equilibrium, our model provides relationships between transport coefficients and describes system evolution in the presence of several simultaneous external fields. The model also leads to an extension of the Onsager–Casimir reciprocal relations for properties simultaneously transported by many components.

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Lee, M. Howard. "Chemical potential: Gibbs-Duhem approach." Physical Review E 53, no. 5 (May 1, 1996): 5488–90. http://dx.doi.org/10.1103/physreve.53.5488.

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Delgado, Juan Luis, Pierre-Antoine Bouit, Salvatore Filippone, MaÁngeles Herranz, and Nazario Martín. "Organic photovoltaics: a chemical approach." Chemical Communications 46, no. 27 (2010): 4853. http://dx.doi.org/10.1039/c003088k.

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Дисертації з теми "Chemical approach"

Pennington, Daniel. "Chemical facility preparedness a comprehensive approach." Thesis, Monterey, Calif. : Springfield, Va. : Naval Postgraduate School ; Available from National Technical Information Service, 2006. http://library.nps.navy.mil/uhtbin/hyperion/06Sep%5FPennington.pdf.

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Thesis (M.A. in Security Studies (Homeland Security And Defense))--Naval Postgraduate School, September 2006.
Thesis Advisor(s): Ted Lewis. "September 2006." Includes bibliographical references (p. 83-88). Also available in print.

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Aldeeb, Abdulrehman Ahmed. "Systematic approach for chemical reactivity evaluation." Diss., Texas A&M University, 2003. http://hdl.handle.net/1969.1/159.

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Under certain conditions, reactive chemicals may proceed into uncontrolled chemical reaction pathways with rapid and significant increases in temperature, pressure, and/or gas evolution. Reactive chemicals have been involved in many industrial incidents, and have harmed people, property, and the environment. Evaluation of reactive chemical hazards is critical to design and operate safer chemical plant processes. Much effort is needed for experimental techniques, mainly calorimetric analysis, to measure thermal reactivity of chemical systems. Studying all the various reaction pathways experimentally however is very expensive and time consuming. Therefore, it is essential to employ simplified screening tools and other methods to reduce the number of experiments and to identify the most energetic pathways. A systematic approach is presented for the evaluation of reactive chemical hazards. This approach is based on a combination of computational methods, correlations, and experimental thermal analysis techniques. The presented approach will help to focus the experimental work to the most hazardous reaction scenarios with a better understanding of the reactive system chemistry. Computational methods are used to predict reaction stoichiometries, thermodynamics, and kinetics, which then are used to exclude thermodynamically infeasible and non-hazardous reaction pathways. Computational methods included: (1) molecular group contribution methods, (2) computational quantum chemistry methods, and (3) correlations based on thermodynamic-energy relationships. The experimental techniques are used to evaluate the most energetic systems for more accurate thermodynamic and kinetics parameters, or to replace inadequate numerical methods. The Reactive System Screening Tool (RSST) and the Automatic Pressure Tracking Adiabatic Calorimeter (APTAC) were employed to evaluate the reactive systems experimentally. The RSST detected exothermic behavior and measured the overall liberated energy. The APTAC simulated near-adiabatic runaway scenarios for more accurate thermodynamic and kinetic parameters. The validity of this approach was investigated through the evaluation of potentially hazardous reactive systems, including decomposition of di-tert-butyl peroxide, copolymerization of styrene-acrylonitrile, and polymerization of 1,3-butadiene.

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Jensen, Stephanie Meryl, and Stephanie Meryl Jensen. "A Bioorthogonal Approach to Chemical Virology." Diss., The University of Arizona, 2016. http://hdl.handle.net/10150/621769.

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Dengue virus (DENV) is a mosquito-transmitted flavivirus that threatens approximately half of the world's population. In this dissertation, the use of bioorthogonal chemistry as a tool for researching emerging viral diseases, including DENV is explored. To this end, a bioorthogonally-modified amino acid was successfully installed within the proteome of DENV, which was used for the pull down of a known virus-protein interaction. This technology is intended to be broadly used for the determination of any virus-host interaction, through the installment of a non-perturbing modification that 1) does not hinder viral infectivity and 2) can be selectively discriminated by any complimentary probe. En route to using this technology, a new viral purification strategy was developed for DENV that reduces the overall purification time by 10 hours, and improves retention of virion infectivity. This method and a survey of other viral purification methods used with DENV is contained herein. Furthermore, a chemical scaffold that was repurposed for exploration of protein-protein crosslinking, namely for release of a reactive chemical warhead under acidic conditions, was used for the surface modification of DENV. This triazabutadiene probe was found to be activated by light. In this dissertation is reported the first time aryl diazonium ions for protein crosslinking have been generated on a protein or viral surface through UV-irradiation. The advantages and limitations of this chemistry are presented herein.

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Baldauf, Paul D. "Chemical industry security voluntary or mandatory approach?" Thesis, Monterey, Calif. : Naval Postgraduate School, 2007. http://bosun.nps.edu/uhtbin/hyperion.exe/07Mar%5FBaldauf.pdf.

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Thesis (M.A. in Security Studies (Homeland Security and Defense))--Naval Postgraduate School, March 2007.
Thesis Advisor(s): Thomas J. Mackin, Nadav Morag. "March 2007." Includes bibliographical references (p. 75-79). Also available in print.

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Alqahtani, Abdullah. "Integrated approach to chemical process flowsheet synthesis." Thesis, Loughborough University, 2008. https://dspace.lboro.ac.uk/2134/4034.

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Chemical process synthesis is an open ended step of process design as it deals with the problem of how to develop and integrate the chemical process flowsheet. Over the past four decades, very few systematic procedures have been proposed for the rigorous synthesis of complete chemical process flowsheets. Mathematical design and heuristics from experience of past processes are the two main methods usually employed in process synthesis. Most approaches for new designs use heuristics based on studying reaction and separation systems in isolation. This thesis discusses the development of a new process synthesis systematic procedure and software that integrates a knowledge based system with Aspen HYSYS process simulator, HYSYS optimizer, Aspen Icarus economic evaluator, and databases, utilising knowledge from existing industrial processes to obtain design rules. The proposed generic superstructure for the synthesis and optimization of reaction-separation-recycle systems has been validated. To account for the non-ideal behaviour of reactors, modular simulation is used and an example of the approach is illustrated for a fluidized bed reactor. Preliminary work in customizing Aspen HYSYS to simulate new unit operation has been illustrated. A Visual Basic for Application (VBA) programming code has been developed to link the integrated knowledge based system (IKBS) to Aspen HYSYS. The prototype IKBS has been applied for the selection of reactor-separator-recycle systems for ethylene oxide, ethylene glycol, acetic acid and cumene manufacturing processes as case studies. A wide range of chemical reactors and separators were considered during the selection process and then elimination occurs at different levels leading to the best alternatives being selected for simulation, optimization and economic evaluation in the second phase of the IKBS for future development. The suggested alternative reactor-separator-recycle systems by the IKBS include currently used processes in addition to novel and recommended reactors/separators in industrial research. The proposed integrated knowledge based approach to chemical process flowsheet synthesis is expected to yield a cost effective design methodology for the petrochemical industry.

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Milsted, Andrew J. "Facilitating chemical discovery : an e-science approach." Thesis, University of Southampton, 2015. https://eprints.soton.ac.uk/377591/.

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e-Science technologies and tools have been applied to the facilitating of the accumulation, validation, analysis, computation, correlation and dissemination of chemical information and its transformation into accepted chemical knowledge. In this work a number of approaches have been investigated to address the diffeerent issues with recording and preserving the scientific record, mainly the laboratory notebook. The electronic laboratory notebook (ELN) has the potential to replace the paper notebook with a marked-up digital record that can be searched and shared. However it is a challenge to achieve these benefits without losing the usability and flexibility of traditional paper notebooks. Therefore using a blog-based platform will be investigated to try and address the issues associated with the development of a flexible system for recording scientific research.

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Cocchi, Stefano <1984&gt. "A chemical loop approach for methanol reforming." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2012. http://amsdottorato.unibo.it/4758/1/Cocchi_Stefano_Tesi.pdf.

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Over the past few years, the switch towards renewable sources for energy production is considered as necessary for the future sustainability of the world environment. Hydrogen is one of the most promising energy vectors for the stocking of low density renewable sources such as wind, biomasses and sun. The production of hydrogen by the steam-iron process could be one of the most versatile approaches useful for the employment of different reducing bio-based fuels. The steam iron process is a two-step chemical looping reaction based (i) on the reduction of an iron-based oxide with an organic compound followed by (ii) a reoxidation of the reduced solid material by water, which lead to the production of hydrogen. The overall reaction is the water oxidation of the organic fuel (gasification or reforming processes) but the inherent separation of the two semireactions allows the production of carbon-free hydrogen. In this thesis, steam-iron cycle with methanol is proposed and three different oxides with the generic formula AFe2O4 (A=Co,Ni,Fe) are compared in order to understand how the chemical properties and the structural differences can affect the productivity of the overall process. The modifications occurred in used samples are deeply investigated by the analysis of used materials. A specific study on CoFe2O4-based process using both classical and in-situ/ex-situ analysis is reported employing many characterization techniques such as FTIR spectroscopy, TEM, XRD, XPS, BET, TPR and Mössbauer spectroscopy.

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Cocchi, Stefano <1984&gt. "A chemical loop approach for methanol reforming." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2012. http://amsdottorato.unibo.it/4758/.

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Vozniuk, Olena <1989&gt. "Chemical-Loop Approach in Bio-Alcohols Reforming." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2017. http://amsdottorato.unibo.it/7775/1/Thesis%20Olena%20Vozniuk%202017.pdf.

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The current research is focused on the study and evaluation of a new process for the hydrogen generation, named as Chemical-Loop Reforming (CLR) of Ethanol. The main principle of the CLR process is that an oxygen-storage material is first reduced by ethanol stream (T-450oC), and then re-oxidized by water (T-450oC), in order to produce hydrogen and restore the original oxidation state of a looping-material. Different M-modified spinel-type mixed oxides: TYPE I – MFe2O4 and TYPE II – M0.6Fe2.4Oy viz. modified ferrospinels (where M=Cu, Co, Mn, Mg, Ca and Cu/Co, Cu/Mn, Co/Mn), as potentially attractive ionic oxygen and electron carrier looping materials, were prepared via co-precipitation method and tested in terms of both redox properties and catalytic activity to generate hydrogen by oxidation with steam, after the reductive step carried out with ethanol. Particularly, the focus on the reactivity behavior of binary/ternary materials explained by their ability to form thermodynamically stable spinel oxides which allow us to re-obtain the initial spinel phase upon cycling and in turn increase a stability of the looping material itself. In addition, the research includes in-situ DRIFTS and in-situ XPS studies that allowed to extract information at molecular level and to follow surface changes within the reduction/re-oxidation processes during CLR process. Bulk characterizations have been done using XRD, TEM/SEM/EDX, TPR/O, Magnetic measurements and Raman/Mössbauer Spectroscopic techniques. Moreover, a modification of the conventional CLR process with an addition of the 3rd regeneration step (carried out with air) was done in order to increase the stability of the looping material and to overcome the deactivation problems, such as: a coke deposition/accumulation and an incomplete re-oxidation of M0 during the 2nd step.

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Heikkilä, Anna-Mari. "Inherent safety in process plant design : an index-based approach /." Espoo [Finland] : Technical Research Centre of Finland, 1999. http://www.vtt.fi/inf/pdf/publications/1999/P384.pdf.

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Книги з теми "Chemical approach"

Bard, Allen J. Integrated chemical systems: A chemical approach to nanotechnology. New York: Wiley, 1994.

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McNeece, Carl Aaron. Chemical dependency: A systems approach. 2nd ed. Boston: Allyn and Bacon, 1998.

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M, DiNitto Diana, ed. Chemical dependency: A systems approach. 4th ed. Boston: Allyn & Bacon, 2012.

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McNeece, Carl Aaron. Chemical dependency: A systems approach. Englewood Cliffs, N.J: Prentice Hall, 1994.

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McNeece, C. Aaron. Chemical dependency: A systems approach. Englewood Cliffs, N.J: Prentice Hall, 1994.

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R, Heineman William, ed. Chemical instrumentation: A systematic approach. 3rd ed. New York: Wiley, 1989.

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1953-, Roitberg Bernard D., and Isman Murray B, eds. Insect chemical ecology: An evolutionary approach. New York: Chapman & Hall, 1992.

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Enzyme kinetics: A modern approach. Hoboken, N.J: Wiley-Interscience, 2003.

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Process control: A practical approach. Hoboken, N.J: Wiley, 2011.

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Temkin, O. N. Chemical reaction networks: A graph-theoretical approach. Boca Raton, Fla: CRC Press, 1996.

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Частини книг з теми "Chemical approach"

Grabley, Susanne, Ralf Thiericke, and Axel Zeeck. "The Chemical Screening Approach." In Drug Discovery from Nature, 124–48. Berlin, Heidelberg: Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/978-3-642-60250-4_8.

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Nicolis, G., and C. Nicolis. "Thermodynamic Approach to Chemical Networks." In Advances in Chemical Physics, 85–95. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118959602.ch8.

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Mutaftschiev, Boyan. "Homogeneous Nucleation; the Chemical Approach." In The Atomistic Nature of Crystal Growth, 201–26. Berlin, Heidelberg: Springer Berlin Heidelberg, 2001. http://dx.doi.org/10.1007/978-3-662-04591-6_11.

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Thomas, Merin Sara, Prasanth K. S. Pillai, Sabu Thomas, and Laly A. Pothen. "Functionalization of Cellulose—Chemical Approach." In Functionalized Polymers, 139–52. Boca Raton : CRC Press, [2021]: CRC Press, 2021. http://dx.doi.org/10.1201/9780367821913-7.

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Snell, Terry W. "Review paper: Chemical ecology of rotifers." In Rotifera VIII: A Comparative Approach, 267–76. Dordrecht: Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-011-4782-8_34.

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Okazaki, Susumu. "Dynamical Approach to Vibrational Relaxation." In Advances in Chemical Physics, 191–270. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470141786.ch4.

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Harr, Thomas. "Diagnostic Approach to Drug Allergy." In Chemical Immunology and Allergy, 47–60. Basel: S. KARGER AG, 2012. http://dx.doi.org/10.1159/000335615.

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Levine, R. D. "Information Theory Approach in Chemical Dynamics." In Frontiers of Chemical Dynamics, 195–216. Dordrecht: Springer Netherlands, 1995. http://dx.doi.org/10.1007/978-94-011-0345-9_9.

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Barke, Hans-Dieter, Günther Harsch, and Siegbert Schmid. "Structure-Oriented Approach in Chemical Education." In Essentials of Chemical Education, 291–319. Berlin, Heidelberg: Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-21756-2_10.

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Zhao, Wenyi. "Telescope Approach." In Handbook for Chemical Process Research and Development, Second Edition, 493–526. 2nd ed. Boca Raton: CRC Press, 2023. http://dx.doi.org/10.1201/9781003288411-14.

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Тези доповідей конференцій з теми "Chemical approach"

Ostrzenski, Jack. "Large-scale petrochemical projects: Modern approach to execution." In Chemical Industry. IEEE, 2008. http://dx.doi.org/10.1109/pciceurope.2008.4563527.

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Viner, Boris. "Safety- Centered approach to quality of light for petrochemical facilities safety." In Chemical Industry. IEEE, 2008. http://dx.doi.org/10.1109/pciceurope.2008.4563523.

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Gabriel, Thomas, Lothar Litz, and Bernd Schrors. "Systematic approach for the SIL-proof of non-standard safety-loops." In Chemical Industry. IEEE, 2008. http://dx.doi.org/10.1109/pciceurope.2008.4563538.

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Vincent, Lena, Kalin Vetsigian, and David Baum. "A Chemical Ecosystem Selection Approach for Generating Evolvable Chemical Systems." In The 2018 Conference on Artificial Life. Cambridge, MA: MIT Press, 2018. http://dx.doi.org/10.1162/isal_a_00118.

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Egbogah, E. O., G. J. Clark, M. J. Smith, and N. Mungan. "Waterflooding: The Graded Chemical Concentration Approach." In Annual Technical Meeting. Petroleum Society of Canada, 1985. http://dx.doi.org/10.2118/85-36-5.

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Crafa, Silvia, and Luca Padovani. "The chemical approach to typestate-oriented programming." In SPLASH '15: Conference on Systems, Programming, Languages, and Applications: Software for Humanity. New York, NY, USA: ACM, 2015. http://dx.doi.org/10.1145/2814270.2814287.

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Liu, Chuangwen, Peishan Tu, Pangbo Wu, Haomo Tang, Yande Jiang, Jian Kuang, and Evangeline F. Y. Young. "An Effective Chemical Mechanical Polishing Filling Approach." In 2015 IEEE Computer Society Annual Symposium on VLSI (ISVLSI). IEEE, 2015. http://dx.doi.org/10.1109/isvlsi.2015.75.

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Zarzhitsky, D., D. F. Spears, and W. M. Spears. "Distributed robotics approach to chemical plume tracing." In 2005 IEEE/RSJ International Conference on Intelligent Robots and Systems. IEEE, 2005. http://dx.doi.org/10.1109/iros.2005.1545428.

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Mehta, Shikha. "Bio-inspired approach to solve chemical equations." In 2013 Sixth International Conference on Contemporary Computing (IC3). IEEE, 2013. http://dx.doi.org/10.1109/ic3.2013.6612240.

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Sadawi, Noureddin M., Alan P. Sexton, and Volker Sorge. "Chemical structure recognition: a rule-based approach." In IS&T/SPIE Electronic Imaging, edited by Christian Viard-Gaudin and Richard Zanibbi. SPIE, 2012. http://dx.doi.org/10.1117/12.912185.

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Звіти організацій з теми "Chemical approach"

Prasad, Paras N. Development of Bottom-Up Chemical Approaches to 3-D Negative Index Meta-Materials: Two Photon Lithographic Approach-Chiral Chemical Synthesis Approach. Fort Belvoir, VA: Defense Technical Information Center, June 2014. http://dx.doi.org/10.21236/ad1013206.

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Bernstein, Lawrence S., Frank O. Clark, Irving R. Epstein, Seth Fraden, Darren R. Link, Jordan B. Pollack, Steven Richtsmeier, and Anatol M. Zhabotinsky. A Novel Approach to Chemical Communications. Fort Belvoir, VA: Defense Technical Information Center, June 2010. http://dx.doi.org/10.21236/ada546000.

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Apt, K., and J. Markin. A systems approach to chemical weapons verification. Office of Scientific and Technical Information (OSTI), June 1990. http://dx.doi.org/10.2172/6823154.

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Sariciftci, Niyazi Serdar. CO2 Recycling: The Conversion of Renewable Energy into Chemical Fuels. AsiaChem Magazine, November 2020. http://dx.doi.org/10.51167/acm00011.

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We want to bring the idea of conversion of CO2 into synthetic fuels (CO2 recycling) into attention, as a possible approach for transportable storage of renewable energy. Recycling of CO2 by homogeneous and/or heterogeneous catalytic approaches have been investigated with increasing emphasis within the scientific community. In the last decades, especially using organic and bioorganic systems towards CO2 reduction has attracted great interest. Chemical, electrochemical, photoelectrochemical, and bioelectrochemical approaches are discussed vividly as new routes towards the conversion of CO2 into synthetic fuels and/or useful chemicals in the recent literature. Here we want to especially emphasize the new developments in bio-electrocatalysis with some recent examples.

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Onishi, Yasuo. Reactive Transport Modeling Approach and its Initial Saltcake Dilution Chemical Modeling. Office of Scientific and Technical Information (OSTI), November 2002. http://dx.doi.org/10.2172/15010065.

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DeLisa, Matthew. Engineering Metabolic Channels as a New Approach to Microbial Chemical Manufacture. Fort Belvoir, VA: Defense Technical Information Center, January 2009. http://dx.doi.org/10.21236/ada548814.

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Wong, Chun-Shang, Chen Wang, Konrad Thurmer, Josh Whaley, and Robert Kolasinski. New experimental approach to understanding the chemical reactivity of oxide surfaces. Office of Scientific and Technical Information (OSTI), September 2021. http://dx.doi.org/10.2172/1821793.

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Laurence, T. INTRACELLULAR CHEMICAL MEASUREMENTS:A GENERALIZED APPROACH WITH HIGH-SPATIAL RESOLUTION USING FUNCTIONALIZED NANOPARTICLES. Office of Scientific and Technical Information (OSTI), March 2007. http://dx.doi.org/10.2172/902606.

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Hoffmann, Roald, and John Wilkins. Simple Adsorbates on Transition Metal Surfaces: A Joint Chemical and Physical Approach. Fort Belvoir, VA: Defense Technical Information Center, February 1989. http://dx.doi.org/10.21236/ada205726.

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Gallis, Michail A., Ryan Bomar Bond, and John Robert Torczynski. Molecule-based approach for computing chemical-reaction rates in upper atmosphere hypersonic flows. Office of Scientific and Technical Information (OSTI), August 2009. http://dx.doi.org/10.2172/1023586.

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