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Автор: Grafiati

Опубліковано: 6 вересня 2023

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1

Vante, N. Alonso, W. Jaegermann, H. Tributsch, W. Hoenle, and K. Yvon. "Electrocatalysis of oxygen reduction by chalcogenides containing mixed transition metal clusters." Journal of the American Chemical Society 109, no. 11 (May 1987): 3251–57. http://dx.doi.org/10.1021/ja00245a013.

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2

Singh, Harish, Manashi Nath, and McKenzie Marley Hines. "Development of High-Performance Electrode Materials for Supercapacitor Application through Combinatorial Electrodeposition." ECS Meeting Abstracts MA2022-01, no. 3 (July 7, 2022): 492. http://dx.doi.org/10.1149/ma2022-013492mtgabs.

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Electrochemical capacitors (ECs) are promising energy storage devices that have received great attention because of their excellent electrochemical performance with high output power, short discharging time, and long-term cycle stability. Metal chalcogenides (especially selenides and tellurides) are considered to be a new class of battery-like electrode materials and have contributed to ameliorate the electrochemical performance with better electronic conductivity and chemical stability. In the current investigation, a series of mixed transition metal-based chalcogenides have been grown directly on nickel foam by electrodeposition without the addition of a binder to the electrode composite. It was observed that the supercapacitor activity was dependent on the quantity of Cu and Co in the Cu-Co-Se ternary selenide electrocatalysts. Surprisingly, Cu–Co ternary selenides exhibit superior specific capacitance in comparison to their pure parent compounds, CoSe and Cu3Se2. Among the series of Cu–Co ternary selenides, the specific capacitance achieved for Cu0.6Co0.4Se2 showed the best specific capacitance value of 2063 F/g at a current density of 1 A/g and also maintained a cyclic stability of more than 90 % at a higher current density of 10 A/g after 1000 charge-discharge cycles. Moreover, doping effects at the transition metal site are also illustrated in this work and had a positive influence on the supercapacitor activity because, it led to lattice distortion, electronic structure modification, as well as helping to tune the surface redox behavior. The observed results clearly demonstrate that the binder free metal chalcogenide-based catalysts may be used as a potential electrode material for future energy storage devices. Figure 1

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3

Bokova, Maria, Steven Dumortier, Christophe Poupin, Renaud Cousin, Mohammad Kassem, and Eugene Bychkov. "Potentiometric Chemical Sensors Based on Metal Halide Doped Chalcogenide Glasses for Sodium Detection." Sensors 22, no. 24 (December 18, 2022): 9986. http://dx.doi.org/10.3390/s22249986.

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Chalcogenide glasses are widely used as sensitive membranes in the chemical sensors for heavy metal ions detection. The lack of research work on sodium ion-selective electrodes (Na+-ISEs) based on chalcogenide glasses is due to the high hygroscopicity of alkali dopes chalcogenides. However, sodium halide doped Ga2S3-GeS2 glasses are more chemically stable in water and could be used as Na+-sensitive membranes for the ISEs. In this work we have studied the physico-chemical properties of mixed cation (AgI)x(NaI)30-x(Ga2S3)26(GeS2)44 chalcogenide glasses (where x = 0, 7.5, 15, 22.5 and 30 mol.% AgI) using density, DSC, and conductivity measurements. The mixed cation effect with shallow conductivity and glass transition temperature minimum was found for silver fraction r = Ag/(Na + Ag) ≈ 0.5. Silver addition decreases the moisture resistance of the glasses. Only (AgI)22.5(NaI)7.5(Ga2S3)26(GeS2)44 composition was suitable for chemical sensors application, contrary to the single cation sodium halide doped Ga2S3-GeS2 glasses, where 15 mol.% sodium-halide-containing vitreous alloys are stable in water solutions. The analytical parameters of (NaCl)15(Ga2S3)23(GeS2)62; (NaI)15(Ga2S3)23(GeS2)62 and (AgI)22.5(NaI)7.5(Ga2S3)26(GeS2)44 glass compositions as active membranes in Na+-ISEs were investigated, including detection limit, sensitivity, linearity, ionic selectivity (in the presence of K+, Mg2+, Ca2+, Ba2+, and Zn2+ interfering cations), reproducibility and optimal pH-range.

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4

Antonov, V. N., L. V. Bekenov, and A. N. Yaresko. "Electronic Structure of Strongly Correlated Systems." Advances in Condensed Matter Physics 2011 (2011): 1–107. http://dx.doi.org/10.1155/2011/298928.

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The article reviews the rich phenomena of metal-insulator transitions, anomalous metalicity, taking as examples iron and titanium oxides. The diverse phenomena include strong spin and orbital fluctuations, incoherence of charge dynamics, and phase transitions under control of key parameters such as band filling, bandwidth, and dimensionality. Another important phenomena presented in the article is a valence fluctuation which occur often in rare-earth compounds. We consider some Ce, Sm, Eu, Tm, and Yb compounds such as Ce, Sm and Tm monochalcogenides, Sm and Yb borides, mixed-valent and charge-ordered Sm, Eu and Yb pnictides and chalcogenides R4X3and R3X4(R = Sm, Eu, Yb; X = As, Sb, Bi), intermediate-valence YbInCu4and heavy-fermion compounds YbMCu4(M = Cu, Ag, Au, Pd). Issues addressed include the nature of the electronic ground states, the metal-insulator transition, the electronic and magnetic structures. The discussion includes key experiments, such as optical and magneto-optical spectroscopic measurements, x-ray photoemission and x-ray absorption, bremsstrahlung isochromat spectroscopy measurements as well as x-ray magnetic circular dichroism.

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5

Boubeche, Mebrouka, Ningning Wang, Jianping Sun, Pengtao Yang, Lingyong Zeng, Shaojuan Luo, Yiyi He, et al. "Superconducting dome associated with the suppression and re-emergence of charge density wave states upon sulfur substitution in CuIr₂Te₄ chalcogenides." Journal of Physics: Condensed Matter 34, no. 20 (March 24, 2022): 205602. http://dx.doi.org/10.1088/1361-648x/ac594c.

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Abstract We report the path from the charge density wave (CDW)-bearing superconductor CuIr2Te4 to the metal insulator transition (MIT)-bearing compound CuIr2S4 by chemical alloying with the gradual substitution of S for Te. The evolution of structural and physical properties of the CuIr2Te4−x S x (0 ⩽ x ⩽ 4) polycrystalline system is systemically examined. The x-ray diffraction (XRD) results imply CuIr2Te4−x S x (0 ⩽ x ⩽ 0.5) crystallizes in a NiAs defected trigonal structure, whereas it adapts to the cubic spinel structure for 3.6 ⩽ x ⩽ 4 and it is a mixed phase in the doping range of 0.5 < x < 3.6. Unexpectedly, the resistivity and magnetization measurements reveal that small-concentration S substitution for Te can suppress the CDW transition, but it reappears around x = 0.2, and the CDW transition temperature enhances clearly as x augments for 0.2 ⩽ x ⩽ 0.5. Besides, the superconducting critical temperature (T c) first increases with S doping content and then decreases after reaching a maximum T c = 2.82 K for CuIr2Te3.85S0.15. MIT order has been observed in the spinel region (3.6 ⩽ x ⩽ 4) associated with T MI increasing with x increasing. Finally, the rich electronic phase diagram of temperature versus x for this CuIr2Te4−x S x system is assembled, where the superconducting dome is associated with the suppression and re-emergence of CDW as well as MIT states at the end upon sulfur substitution in the CuIr2Te4−x S x chalcogenides.

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6

Sedhain, Ram Prasad, and Gopi Chandra Kaphle. "STRUCTURAL AND ELECTRONIC PROPERTIES OF TRANSITION METAL DI-CHALCOGENIDES (MX2) M=(Mo, W) AND X=(S, Se) IN BULK STATE: A FIRST-PRINCIPLES STUDY." Journal of Institute of Science and Technology 22, no. 1 (July 18, 2017): 41–50. http://dx.doi.org/10.3126/jist.v22i1.17738.

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Transition metal di-chalcogenides (MX2) M=(Mo, W) and X=(S, Se) in bulk state are of great interest due to their diverse applications in the field of modern technology as well as to understand the fundamental aspect of Physics. We performed structural and electronic properties of selected systems using density functional theory implemented in Tight Binding Linear Muffin- tin Orbital (TBLMTO) approach with subsequent refinement. The structural optimization is performed through energy minimization process and lattice parameters of optimized structures for MoS2, MoSe2, WS2 and WSe2 are found to be 3.20Å, 3.34Å, 3.27Å and 3.34Å respectively, which are within the error bar less than 5% with experimental values. The band gaps for all TMDCs are found to be of indirect types with semiconducting behaviours. The values of band gap of MoS2, MoSe2, WS2 and WSe2 in bulk state are found to be 1.16eV, 108eV, 1.50eV and 1.29eV respectively which are comparable with experimental and previously calculated data. Due to the symmetric nature of up spin and down spin channels of Density of States (DOS) all the systems selected are found to be non magnetic. However it fully supports the results obtained from band structure calculations. The potential and charge distributions plots support the results. The charge density plots reveals the covalent nature of bond in (100) plane. However (110) plane shows mixed types of bonding.Journal of Institute of Science and TechnologyVolume 22, Issue 1, July 2017, page: 41-50

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7

Patil, S. M., S. R. Mane, R. M. Mane, S. S. Mali, P. S. Patil, and P. N. Bhosale. "Synthesis and X-ray photoelectron spectroscopy (XPS) and thermoelectric studies of ternary Bi2(Te0.5Se0.5)3 mixed-metal chalcogenide thin films by the arrested precipitation technique." Canadian Journal of Chemistry 89, no. 11 (November 2011): 1375–81. http://dx.doi.org/10.1139/v11-107.

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Arrested precipitation technique (APT) has been successfully employed for the deposition of Bi2(Te0.5Se0.5)3 thin films. Analytical grade bismuth nitrate complexes with triethanolamine (TEA), sodium tellurosulfite, and sodium selenosulfite were used as precursor materials. The film was obtained at 55 ± 0.5 °C in an aqueous alkaline medium (pH = 10.5 ± 0.2). As-deposited film was characterized by chemical compositional, optical, and electrical analyses. The optical absorption spectrum for the sample was recorded in the wavelength region 400–900 nm. It shows a high coefficient of absorption (α = 105 cm–1) with an allowed direct type of transition. X-ray diffraction (XRD) study of the film shows a nanocrystalline and rhombohedral structure. From scanning electron microscopy (SEM), atomic force microscopy (AFM), and energy dispersive X-ray analysis (EDAX) studies, the deposited film shows uniform morphology and good stoichiometry. X-ray photoelectron spectroscopy (XPS) was used to study the binding energy and surface oxidation of the material. Electrical conduction study shows that material is an n-type semiconductor and shows good thermoelectric figure of merit.

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8

Mitchell, Kwasi, and James A. Ibers. "Rare-Earth Transition-Metal Chalcogenides." Chemical Reviews 102, no. 6 (June 2002): 1929–52. http://dx.doi.org/10.1021/cr010319h.

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9

Varadwaj, Pradeep, Helder Marques, Arpita Varadwaj, and Koichi Yamashita. "Chalcogen···Chalcogen Bonding in Molybdenum Disulfide, Molybdenum Diselenide and Molybdenum Ditelluride Dimers as Prototypes for a Basic Understanding of the Local Interfacial Chemical Bonding Environment in 2D Layered Transition Metal Dichalcogenides." Inorganics 10, no. 1 (January 12, 2022): 11. http://dx.doi.org/10.3390/inorganics10010011.

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An attempt was made, using computational methods, to understand whether the intermolecular interactions in the dimers of molybdenum dichalcogenides MoCh2 (Ch = chalcogen, element of group 16, especially S, Se and Te) and similar mixed-chalcogenide derivatives resemble the room temperature experimentally observed interactions in the interfacial regions of molybdenites and their other mixed-chalcogen derivatives. To this end, MP2(Full)/def2-TVZPPD level electronic structure calculations on nine dimer systems, including (MoCh2)2 and (MoChCh′2)2 (Ch, Ch′ = S, Se and Te), were carried out not only to demonstrate the energetic stability of these systems in the gas phase, but also to reproduce the intermolecular geometrical properties that resemble the interfacial geometries of 2D layered MoCh2 systems reported in the crystalline phase. Among the six DFT functionals (single and double hybrids) benchmarked against MP2(full), it was found that the double hybrid functional B2PLYPD3 has some ability to reproduce the intermolecular geometries and binding energies. The intermolecular geometries and binding energies of all nine dimers are discussed, together with the charge density topological aspects of the chemical bonding interactions that emerge from the application of the quantum theory of atoms in molecules (QTAIM), the isosurface topology of the reduced density gradient noncovalent index, interaction region indicator and independent gradient model (IGM) approaches. While the electrostatic surface potential model fails to explain the origin of the S···S interaction in the (MoS2)2 dimer, we show that the intermolecular bonding interactions in all nine dimers examined are a result of hyperconjugative charge transfer delocalizations between the lone-pair on (Ch/Ch′) and/or the π-orbitals of a Mo–Ch/Ch′ bond of one monomer and the dπ* anti-bonding orbitals of the same Mo–Ch/Ch′ bond in the second monomer during dimer formation, and vice versa. The HOMO–LUMO gaps calculated with the MN12-L functional were 0.9, 1.0, and 1.1 eV for MoTe2, MoSe2 and MoS2, respectively, which match very well with the solid-state theoretical (SCAN-rVV10)/experimental band gaps of 0.75/0.88, 0.90/1.09 and 0.93/1.23 eV of the corresponding systems, respectively. We observed that the gas phase dimers examined are perhaps prototypical for a basic understanding of the interfacial/inter-layer interactions in molybdenum-based dichalcogenides and their derivatives.

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10

Huang, Yu Li, Wei Chen, and Andrew T. S. Wee. "Two‐dimensional magnetic transition metal chalcogenides." SmartMat 2, no. 2 (May 4, 2021): 139–53. http://dx.doi.org/10.1002/smm2.1031.

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11

Jung, Yeonwoong, Yu Zhou, and Judy J. Cha. "Intercalation in two-dimensional transition metal chalcogenides." Inorganic Chemistry Frontiers 3, no. 4 (2016): 452–63. http://dx.doi.org/10.1039/c5qi00242g.

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12

Baranov, N. V., N. V. Selezneva, and V. A. Kazantsev. "Magnetism and Superconductivity of Transition Metal Chalcogenides." Physics of Metals and Metallography 119, no. 13 (December 2018): 1301–4. http://dx.doi.org/10.1134/s0031918x18130215.

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13

JAEGERMANN, W., and H. TRIBUTSCH. "Interfacial properties of semiconducting transition metal chalcogenides." Progress in Surface Science 29, no. 1-2 (1988): 1–167. http://dx.doi.org/10.1016/0079-6816(88)90015-9.

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14

Mitchell, Kwasi, and James A. Ibers. "ChemInform Abstract: Rare-Earth Transition-Metal Chalcogenides." ChemInform 33, no. 34 (May 20, 2010): no. http://dx.doi.org/10.1002/chin.200234267.

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15

Singh, Harish, McKenzie Marley Hines, Shatadru Chakravarty, and Manashi Nath. "Multi-Walled Carbon Nanotube Supported Manganese Selenide As Highly Active Bifunctional OER and ORR Electrocatalyst." ECS Meeting Abstracts MA2022-01, no. 34 (July 7, 2022): 1376. http://dx.doi.org/10.1149/ma2022-01341376mtgabs.

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Transition metal selenides have attracted intensive interest as cost-effective electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) because of the continuous thrust in sustainable energy conversion. In this article a Mn-based bifunctional electrocatalyst, MnSe has been identified which shows efficient OER and ORR activity in alkaline medium. The catalytic activity could be further enhanced by using multiwalled carbon nanotubes (MWCNT) asadditives which increases the charge transfer and electronic conductivity of the catalyst composite. This MnSe@MWCNT catalyst composite exhibits a very low overpotential of 210 mV at 50 mA cm-2 when deposited on Ni foam, which outperforms state-of-the-art RuO2 as well as other oxide and Mn-based electrocatalysts. Furthermore, the composite’s facile OER kinetics was evidenced by its small Tafel slope of 54.76 mV dec–1 and low charge transfer resistance, indicating quick transport of the reactant species. The MnSe@MWCNT also exhibited efficient electrocatalytic activity for ORR with a Eonset of 0.94 V, which is among the best reported till date for chalcogenide based ORR electrocatalysts. More importantly, this MnSe-based ORR electrocatalyst exhibits high degree of methanol tolerance, showing no degradation of catalyst performance in presence of copious quantities of methanol, thereby out-performing state-of-the-art Pt electrocatalyst. The catalyst compositie also exhibited exceptional functional and compositional stability for OER and ORR after prolonged period of continuous operation in alkaline medium. The surface Raman analysis after OER revealed the retention of manganese selenide surface with evidence of Mn-oxo coordination confirming the formation of mixed anionic (oxy)selenide as the active surface for OER. Such efficient bifunctional OER and ORR activity makes this MnSe based catalyst attractive for overall electrolysis in regenerative as well as direct methanol fuel cells.

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16

Zhang, Yingxi, Liao Zhang, Tu'an Lv, Paul K. Chu, and Kaifu Huo. "Two‐Dimensional Transition Metal Chalcogenides for Alkali Metal Ions Storage." ChemSusChem 13, no. 6 (March 9, 2020): 1114–54. http://dx.doi.org/10.1002/cssc.201903245.

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17

Guo, Yan-Dong, Hong-Bo Zhang, Hong-Li Zeng, Hai-Xia Da, Xiao-Hong Yan, Wen-Yue Liu, and Xin-Yi Mou. "A progressive metal–semiconductor transition in two-faced Janus monolayer transition-metal chalcogenides." Physical Chemistry Chemical Physics 20, no. 32 (2018): 21113–18. http://dx.doi.org/10.1039/c8cp02929f.

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18

Zhou, Xiuquan, and Efrain E. Rodriguez. "Tetrahedral Transition Metal Chalcogenides as Functional Inorganic Materials." Chemistry of Materials 29, no. 14 (July 5, 2017): 5737–52. http://dx.doi.org/10.1021/acs.chemmater.7b01561.

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19

SALVADOR, P. A., T. O. MASON, M. E. HAGERMAN, and K. R. POEPPELMEIER. "ChemInform Abstract: Layered Transition Metal Oxides and Chalcogenides." ChemInform 29, no. 17 (June 23, 2010): no. http://dx.doi.org/10.1002/chin.199817275.

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20

Lin, Yang-Jie, Bin-Wen Liu, Run Ye, Xiao-Ming Jiang, Long-Qi Yang, Hui-Yi Zeng, and Guo-Cong Guo. "SrCdSnQ4 (Q = S and Se): infrared nonlinear optical chalcogenides with mixed NLO-active and synergetic distorted motifs." Journal of Materials Chemistry C 7, no. 15 (2019): 4459–65. http://dx.doi.org/10.1039/c9tc00029a.

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Two new infrared (IR) nonlinear optical (NLO) chalcogenides, SrCdSnQ₄ (Q = S and Se) (1 and 2), were obtained by mixing NLO-active metal chalcogenides and d¹⁰ metal tetrahedral motifs in an alkali metal-containing system.

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21

Mazánek, Vlastimil, Hindia Nahdi, Jan Luxa, Zdeněk Sofer, and Martin Pumera. "Electrochemistry of layered metal diborides." Nanoscale 10, no. 24 (2018): 11544–52. http://dx.doi.org/10.1039/c8nr02142b.

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22

Bronger, W., P. Müller, and D. Welz. "Magnetism of ternary alkali metal–transition metal chalcogenides with binuclear units." Physica B: Condensed Matter 276-278 (March 2000): 710–11. http://dx.doi.org/10.1016/s0921-4526(99)01814-1.

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23

Dai, Meng, and Rui Wang. "Synthesis and Applications of Nanostructured Hollow Transition Metal Chalcogenides." Small 17, no. 29 (May 20, 2021): 2006813. http://dx.doi.org/10.1002/smll.202006813.

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24

Su, Jianwei, Guiheng Liu, Lixin Liu, Jiazhen Chen, Xiaozong Hu, Yuan Li, Huiqiao Li, and Tianyou Zhai. "Recent Advances in 2D Group VB Transition Metal Chalcogenides." Small 17, no. 14 (March 10, 2021): 2005411. http://dx.doi.org/10.1002/smll.202005411.

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25

Kuznetsov, Vitalii, Andrej Fedorov, Mihail Naberukhin, Aleksandr Berdinsky, Pavel Poltarak, and Vladimir Fedorov. "Transition metal chalcogenides as sensitive elements for gas sensors." Transaction of Scientific Papers of the Novosibirsk State Technical University, no. 3-4 (April 10, 2019): 136–46. http://dx.doi.org/10.17212/2307-6879-2018-3-4-136-146.

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26

Chen, Zhijie, Wei Wei, and Bing-Jie Ni. "Transition metal chalcogenides as emerging electrocatalysts for urea electrolysis." Current Opinion in Electrochemistry 31 (February 2022): 100888. http://dx.doi.org/10.1016/j.coelec.2021.100888.

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27

Wang, Peijian, Deren Yang, and Xiaodong Pi. "Toward Wafer‐Scale Production of 2D Transition Metal Chalcogenides." Advanced Electronic Materials 7, no. 8 (May 13, 2021): 2100278. http://dx.doi.org/10.1002/aelm.202100278.

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28

Yoo, Dongwon, Minkyoung Kim, Sohee Jeong, Jeonghee Han, and Jinwoo Cheon. "Chemical Synthetic Strategy for Single-Layer Transition-Metal Chalcogenides." Journal of the American Chemical Society 136, no. 42 (October 14, 2014): 14670–73. http://dx.doi.org/10.1021/ja5079943.

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29

Bennett, J. C., and F. W. Boswell. "Charge-density wave modulations in the transition metal chalcogenides." Proceedings, annual meeting, Electron Microscopy Society of America 54 (August 11, 1996): 706–7. http://dx.doi.org/10.1017/s0424820100165999.

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Анотація:

The transition metal chalcogenides, due to the typically large covalency of the metal-chalcogenide bonds, often adopt low-dimensional structures and exhibit charge-density wave (CDW) modulations. Incommensurate (IC) or commensurate (C) modulations structures are observed as well as a rich variety of phase transitions driven by the temperature dependence of the CDW amplitude and phase. Defects of the CDW modulation, including antiphase boundaries (APB) and discommensurations (DC), are of determinate importance for the mediation of these phase transitions. The microstructural phenomena occurring in the quasi-one-dimensional chalcogenides will be surveyed with emphasis on two representative systems: the Nb1-xTaxTe4 solid solution and the MxNb3Te4 (M = In or TI) intercalation compound.The NbxTa1-xTe4 compounds are based on a tetragonal subcell with axes (a x a x c) and consist of an extended chain of metal atoms centered within an antiprismatic cage of Te atoms.

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30

Burdett, Jeremy K., and John F. Mitchell. "Electronic origin of nonstoichiometry in early-transition-metal chalcogenides." Chemistry of Materials 5, no. 10 (October 1993): 1465–73. http://dx.doi.org/10.1021/cm00034a016.

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31

Jaegermann, W., and D. Schmeisser. "Reactivity of layer type transition metal chalcogenides towards oxidation." Surface Science Letters 165, no. 1 (January 1986): A3. http://dx.doi.org/10.1016/0167-2584(86)91160-6.

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32

Jaegermann, W., and D. Schmeisser. "Reactivity of layer type transition metal chalcogenides towards oxidation." Surface Science 165, no. 1 (January 1986): 143–60. http://dx.doi.org/10.1016/0039-6028(86)90666-7.

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33

Tremel, Wolfgang, Holger Kleinke, Volkmar Derstroff, and Christian Reisner. "Transition metal chalcogenides: new views on an old topic." Journal of Alloys and Compounds 219, no. 1-2 (March 1995): 73–82. http://dx.doi.org/10.1016/0925-8388(94)05064-3.

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34

Qin, Na, Xian Du, Yangyang Lv, Lu Kang, Zhongxu Yin, Jingsong Zhou, Xu Gu, et al. "Electronic structure and spin–orbit coupling in ternary transition metal chalcogenides Cu₂TlX ₂ (X = Se, Te)." Chinese Physics B 31, no. 3 (March 1, 2022): 037101. http://dx.doi.org/10.1088/1674-1056/ac3ecd.

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Ternary transition metal chalcogenides provide a rich platform to search and study intriguing electronic properties. Using angle-resolved photoemission spectroscopy and ab initio calculation, we investigate the electronic structure of Cu2TlX 2 (X = Se, Te), ternary transition metal chalcogenides with quasi-two-dimensional crystal structure. The band dispersions near the Fermi level are mainly contributed by the Te/Se p orbitals. According to our ab-initio calculation, the electronic structure changes from a semiconductor with indirect band gap in Cu2TlSe2 to a semimetal in Cu2TlTe2, suggesting a band-gap tunability with the composition of Se and Te. By comparing ARPES experimental data with the calculated results, we identify strong modulation of the band structure by spin–orbit coupling in the compounds. Our results provide a ternary platform to study and engineer the electronic properties of transition metal chalcogenides related to large spin–orbit coupling.

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Wang, Lin-Hui, Long-Long Ren, and Yu-Feng Qin. "The Review of Hybridization of Transition Metal-Based Chalcogenides for Lithium-Ion Battery Anodes." Materials 16, no. 12 (June 18, 2023): 4448. http://dx.doi.org/10.3390/ma16124448.

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Transition metal chalcogenides as potential anodes for lithium-ion batteries have been widely investigated. For practical application, the drawbacks of low conductivity and volume expansion should be further overcome. Besides the two conventional methods of nanostructure design and the doping of carbon-based materials, the component hybridization of transition metal-based chalcogenides can effectively enhance the electrochemical performance owing to the synergetic effect. Hybridization could promote the advantages of each chalcogenide and suppress the disadvantages of each chalcogenide to some extent. In this review, we focus on the four different types of component hybridization and the excellent electrochemical performance that originated from hybridization. The exciting problems of hybridization and the possibility of studying structural hybridization were also discussed. The binary and ternary transition metal-based chalcogenides are more promising to be used as future anodes of lithium-ion batteries for their excellent electrochemical performance originating from the synergetic effect.

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Song, Ruru, Deyu Li, Yafeng Xu, Junfeng Gao, Lu Wang, and Youyong Li. "Interface engineering of heterogeneous transition metal chalcogenides for electrocatalytic hydrogen evolution." Nanoscale Advances 4, no. 3 (2022): 865–70. http://dx.doi.org/10.1039/d1na00768h.

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Zhao, Yang, Shizhong Wei, Kunming Pan, Zhili Dong, Bin Zhang, Hong-Hui Wu, Qiaobao Zhang, Junpin Lin, and Huan Pang. "Self-supporting transition metal chalcogenides on metal substrates for catalytic water splitting." Chemical Engineering Journal 421 (October 2021): 129645. http://dx.doi.org/10.1016/j.cej.2021.129645.

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Matthews, Peter D., Paul D. McNaughter, David J. Lewis, and Paul O'Brien. "Shining a light on transition metal chalcogenides for sustainable photovoltaics." Chemical Science 8, no. 6 (2017): 4177–87. http://dx.doi.org/10.1039/c7sc00642j.

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Transition metal chalcogenides are an important family of materials that have received significant interest in recent years as they have the potential for diverse applications ranging from use in electronics to industrial lubricants.

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39

Krishnamoorthy, Aravind, Minh A. Dinh, and Bilge Yildiz. "Hydrogen weakens interlayer bonding in layered transition metal sulfide Fe1+xS." Journal of Materials Chemistry A 5, no. 10 (2017): 5030–35. http://dx.doi.org/10.1039/c6ta10538f.

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40

Li, Guang-mao, Qiong Liu, Kui Wu, Zhi-hua Yang, and Shi-lie Pan. "Na2CdGe2Q6(Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses." Dalton Transactions 46, no. 9 (2017): 2778–84. http://dx.doi.org/10.1039/c7dt00087a.

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Li, Song-Lin, Kazuhito Tsukagoshi, Emanuele Orgiu, and Paolo Samorì. "Charge transport and mobility engineering in two-dimensional transition metal chalcogenide semiconductors." Chemical Society Reviews 45, no. 1 (2016): 118–51. http://dx.doi.org/10.1039/c5cs00517e.

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SEKINE, Tomoyuki. "Lattice dynamics and Raman scattering in intercalated transition-metal chalcogenides." Journal of the Spectroscopical Society of Japan 40, no. 1 (1991): 3–14. http://dx.doi.org/10.5111/bunkou.40.3.

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Rouxel, Jean. "New 1D-Materials In The Field Of Transition Metal Chalcogenides." Molecular Crystals and Liquid Crystals 121, no. 1-4 (March 1985): 1–13. http://dx.doi.org/10.1080/00268948508074823.

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44

Monceau, P., M. Renard, J. Richard, M. C. Saint-lager, and Z. Z. Wang. "Non-Linear Response of Transition Metal Tri-and Tetra-Chalcogenides." Molecular Crystals and Liquid Crystals 121, no. 1-4 (March 1985): 39–47. http://dx.doi.org/10.1080/00268948508074828.

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SUGIMOTO, Jun, and Kazuhito SHINTANI. "10113 Analysis of the electronic properties of transition metal chalcogenides." Proceedings of Conference of Kanto Branch 2015.21 (2015): _10113–1_—_10113–2_. http://dx.doi.org/10.1299/jsmekanto.2015.21._10113-1_.

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46

Powell, A. V. "Chapter 7. Intercalation compounds of low-dimensional transition metal chalcogenides." Annual Reports Section "C" (Physical Chemistry) 90 (1993): 177. http://dx.doi.org/10.1039/pc9939000177.

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47

Heine, Thomas. "Transition Metal Chalcogenides: Ultrathin Inorganic Materials with Tunable Electronic Properties." Accounts of Chemical Research 48, no. 1 (December 9, 2014): 65–72. http://dx.doi.org/10.1021/ar500277z.

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48

Yin, Wenlong, Wendong Wang, Lei Kang, Zheshuai Lin, Kai Feng, Youguo Shi, Wenyu Hao, Jiyong Yao, and Yicheng Wu. "Ln3FeGaQ7: A new series of transition-metal rare-earth chalcogenides." Journal of Solid State Chemistry 202 (June 2013): 269–75. http://dx.doi.org/10.1016/j.jssc.2013.03.029.

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49

Sarma, Saurav Chandra, and Sebastian C. Peter. "Structurally ordered transition metal-based chalcogenides for oxygen reduction reaction." Acta Crystallographica Section A Foundations and Advances 73, a2 (December 1, 2017): C1271. http://dx.doi.org/10.1107/s2053273317083036.

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50

Brec, R. "Host structure modification upon lithium intercalation in transition metal chalcogenides." Materials Science and Engineering: B 3, no. 1-2 (July 1989): 73–79. http://dx.doi.org/10.1016/0921-5107(89)90181-5.

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