Дисертації з теми "Transition Metal Complexes - Organic Reactions"
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Sheridan, J. B. "The reactions of transition metal hydrocarbon complexes." Thesis, University of Bristol, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.356238.
Повний текст джерелаCupertino, D. C. "Reactions of highly functionalised alkenes with some transition metal complexes." Thesis, University of Liverpool, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.370840.
Повний текст джерелаThu, Hung-yat. "Catalytic C-H bond functionalization reactions catalyzed by rhodium(III) porphyrin, palladium(II) and platinum(II) acetate complexes." View the Table of Contents & Abstract, 2006. http://sunzi.lib.hku.hk/hkuto/record/B38027872.
Повний текст джерелаFurze, John D. "A study of the substitution, carbonylation and free radical reactions of some transition metal complexes." Thesis, Kingston University, 1989. http://eprints.kingston.ac.uk/20525/.
Повний текст джерелаSaleem, al-Shaqri Layla Mohammed. "Kinetic studies of inorganic and organic peroxo complexes /." free to MU campus, to others for purchase, 2003. http://wwwlib.umi.com/cr/mo/fullcit?p3099628.
Повний текст джерелаAllen, D. L. "The reaction of carbon dioxide with tertiary-phosphine transition-metal complexes and related studies." Thesis, University of Oxford, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375231.
Повний текст джерелаOshima, Kazuyuki. "Organic Synthesis Based on Transition-Metal-Catalyzed Addition Reactions of Boron Reagents." 京都大学 (Kyoto University), 2012. http://hdl.handle.net/2433/157539.
Повний текст джерелаNuel, Didier. "Etude de la reactivite de fragments alkylidynes dans des clusters trinucleaires du fer." Toulouse 3, 1986. http://www.theses.fr/1986TOU30206.
Повний текст джерелаArliguie, Thérèse. "Complexes du ruthenium hydrures et derives de l'hydrogene moleculaire : reactions de deshydrogenation inter et intramoleculaires." Toulouse 3, 1988. http://www.theses.fr/1988TOU30111.
Повний текст джерелаHartikka, Antti. "Towards Rational Design of Asymmetric Catalyst for Organometallic and Organocatalytic Reactions." Doctoral thesis, Uppsala : University Library / Universitetsbiblioteket, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-7905.
Повний текст джерелаGOMES, DE LIMA LUIS CARLOS. "Reactions d'alcynes cyanes (monocyanoacethylene et dicyanoacethylene), vis-a-vis de complexes organometalliques du fer, du cobalt, du molybdene et du tungstene." Brest, 1986. http://www.theses.fr/1986BRES2009.
Повний текст джерелаMenu, Marie-Joëlle. "Nouveaux reactifs dans la chimie des complexes du rhodium, du chrome et du tungstene : les anions diazo rc(n::(2))**(-)." Toulouse 3, 1988. http://www.theses.fr/1988TOU30068.
Повний текст джерелаJund, Rodolphe. "Electrochimie de clusters mixtes tetrametalliques." Université Louis Pasteur (Strasbourg) (1971-2008), 1987. http://www.theses.fr/1987STR13175.
Повний текст джерелаTouma, Marwan. "Nouvelles reactions d'oligomerisation et de telomerisation selectives catalysees par des complexes cationiques du palladium." Toulouse 3, 1986. http://www.theses.fr/1986TOU30139.
Повний текст джерелаLe, Mest Yves. "Etude des propriétés électrochimiques de biporphyrines de type "face-à-face" : réactivité des dérives du cobalt vis-à-vis de l'oxygène." Brest, 1988. http://www.theses.fr/1988BRES2013.
Повний текст джерелаHenry, Marc. "Application du concept d'electronegativite aux processus d'hydrolyse et de condensation en chimie minerale." Paris 6, 1988. http://www.theses.fr/1988PA066293.
Повний текст джерелаGiraudon, Jean-Marc. "Complexes mono et dinucléaires du molybdene avec les ligands macrocycliques : synthèse, structure, réactivité et propriétés redox." Brest, 1988. http://www.theses.fr/1988BRES2019.
Повний текст джерелаAlnagi, Omar. "Reaction de la trimethylphosphine sur les sels de cobalt (ii) : synthese des complexes pentacoordonnes cox::(2)(pme::(3))::(3) (x=c1**(-), br**(-), i**(-), ncs**(-), no::(2)**(-)), reactivite vis-a-vis de petites molecules co, no et o::(2)." Toulouse 3, 1987. http://www.theses.fr/1987TOU30048.
Повний текст джерелаWeiss, Jean. "Synthese de (2) et (3)-catenands, coordinats a anneaux entrelaces." Université Louis Pasteur (Strasbourg) (1971-2008), 1986. http://www.theses.fr/1986STR13110.
Повний текст джерелаSEMRA, ASSIA. "Substitutions nucleophiles en serie arenetricarbonylchrome." Paris 6, 1987. http://www.theses.fr/1987PA066622.
Повний текст джерелаRouida, Bouchaïb. "Syntheses diastereoselectivites de complexes chiraux du molybdene et du fer carbonyle par action de derives asymetriques du phosphore." Paris 6, 1988. http://www.theses.fr/1988PA066515.
Повний текст джерелаAchi, Sabah Samira. "Nouvelle voie d'acces aux acides alpha -amines, par catalyse homogene a l'aide de complexes de metaux de transition, synthese de nouveaux complexes phosphores chiraux du tungstene pentacarbonyle." Paris 6, 1987. http://www.theses.fr/1987PA066227.
Повний текст джерелаCromer, Rémy. "Porphyrines n-substituees : modelisation de l'inhibition d'hemoproteines." Université Louis Pasteur (Strasbourg) (1971-2008), 1986. http://www.theses.fr/1986STR13015.
Повний текст джерелаEtienne, Michel. "Réactivité de complexes dinucléaires hydrure et alcénylidène ponte du fer vis-a-vis d'hydrocarbures cyanes insatures (mono et dicyanoacétylène, tétracyanoethylène)." Brest, 1988. http://www.theses.fr/1988BRES2009.
Повний текст джерелаNemra, Ghinwa. "Comportement electrochimique de nouveaux complexes a liaison pd-pd et pt-pd stabilises par des ligands bidentates ph : :(2)pch::(2)pph::(2)." Strasbourg 1, 1986. http://www.theses.fr/1986STR13055.
Повний текст джерелаMetabanzoulou, Jean-Pierre. "Mecanisme de la complexation de l'ion uo : :(2)**(2+) par des di(acyl-4 pyrazolones-5), des ethers-couronnes, des diazapolyoxamacrocycles et des ligands apparentes." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13146.
Повний текст джерелаLaurent, Pascale. "Complexes acyl, alcoxycarbonyl et alkyl tetracarbonylfer : intermédiaires dans la carbonylation catalytique d'halogénures d'alkyle." Brest, 1989. http://www.theses.fr/1989BRES2002.
Повний текст джерелаWang, Dan Li. "Reaction des metalloporphyrines reduites avec les monohalogenoalcanes et les dihalogenoalcanes vicinaux." Paris 7, 1988. http://www.theses.fr/1988PA077166.
Повний текст джерелаELKACEMI, KACEM. "Etude electrochimique de divers conducteurs organiques." Paris 6, 1986. http://www.theses.fr/1986PA066399.
Повний текст джерелаConan, Françoise. "Contribution à l'élaboration de nouveaux squelettes organiques via l'étude de la réactivité d'un groupe disulfure de carbone coordine au molybdène." Brest, 1988. http://www.theses.fr/1988BRES2017.
Повний текст джерелаNeff, Denis. "Complexes alleniques de cyclopentadienyle manganese dicarbonyle : acces aux allenes optiquement actifs, etude de photodecomplexations et syntheses de complexes difonctionnels." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13122.
Повний текст джерелаRimmelin, Jean. "Etude des relations structure-reactivite electrochimique dans quelques clusters du cobalt et du rhodium." Université Louis Pasteur (Strasbourg) (1971-2008), 1987. http://www.theses.fr/1987STR13176.
Повний текст джерелаWilson, F. I. C. "Reactions of some dinuclear transition metal complexes." Thesis, Kingston University, 1988. http://eprints.kingston.ac.uk/20522/.
Повний текст джерелаIloughmane-Gaspard, Hafida. "Ene reactivite d'alcenylsilanes et -germanes : synthese et stabilisation de metalloles du groupe 14." Toulouse 3, 1986. http://www.theses.fr/1986TOU30214.
Повний текст джерелаBen, Nasr Chérif. "Complexation du nickel (II) et des lanthanides (III) par des phosphoramides bidentes : Application à l'extraction liquide-liquide." Nancy 1, 1986. http://www.theses.fr/1986NAN10032.
Повний текст джерелаGreen, G. "Transition metal oxo-complexes as organic oxidants." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37711.
Повний текст джерелаYoung, George Hansen. "Reactions of transition-metal propargyl complexes with polynuclear metal carbonyls /." The Ohio State University, 1989. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487672631602474.
Повний текст джерелаHamilton, Charles W. Ph D. Massachusetts Institute of Technology. "Nitrene transfer reactions by late transition metal complexes." Thesis, Massachusetts Institute of Technology, 2007. http://hdl.handle.net/1721.1/38618.
Повний текст джерелаVita.
Includes bibliographical references.
This thesis presents nitrene transfer reactions that are catalyzed or mediated by late transition metal complexes. Sterically large, fluorinated supporting ligands are used to minimize potential side reactions. A new 1,10-phenanthroline ligand has been synthesized with 2,4,6-(CF3)3C6H2- groups in the 2- and 9-positions (1). A cationic copper(l) complex of 1 catalyzes nitrene transfer from N-(p-toluenesulfonylimino)phenyliodinane (PhlNTs) to the C-H bonds of 1,3-dimethoxybenzene in 63% yield. Altering the stoichiometry results in the formation of a different major product, N,N-bis(2',4'-dimethoxyphenyl)-p-toluenesulfonamide, in 33% yield. Treatment of a cationic copper(l) complex of 1 with p-nitrobenzenesulfonyl azide (NsN3) results in the formation of a rare mononuclear sulfonamido complex of copper(ll), 2. This complex is presumably formed via decomposition of a reactive sulfonimido complex of copper(lll). Although not a proficient nitrene transfer reagent to benzene, complex 2 is a precatalyst for nitrene transfer from NsN3 to benzene. Deprotonation of a palladium(ll) sulfonamido complex of 1 results in the formation of the first mononuclear sulfonimido complex of palladium,
(cont.) 3. The sulfonimido ligand is bound in a K2-N,O chelate. This complex is a proficient nitrene transfer reagent to carbon monoxide, phosphines, and ethyl vinyl ether. A rhodium(lll) hydride chloride complex containing two N-heterocyclic carbene ligands, one of which is cyclometallated, is a convenient synthetic equivalent of a rhodium(l) chloride complex. Treatment of the rhodium(Ill) hydride with acetonitrile results in reductive elimination to form a rhodium(l) chloride complex. The chloride is readily abstracted by sodium azide to form a cationic rhodium(l) complex coordinated by two molecules of acetonitrile and containing an unbound azide. Upon exposure to UV light, this molecule undergoes cyclometallation to form a cationic rhodium(lll) hydride complex. The rhodium(lll) hydride chloride complex can be treated with oxygen to form a rhodium(lll) peroxide complex. The neutral peroxide complex has poor reactivity with trimethylphosphite and t-stilbene. However, a cationic rhodium peroxide complex oxidizes trimethylphosphite and t-stilbene at elevated temperatures.
by Charles W. Hamilton.
Ph.D.
Boukhalfa, Hakim. "Complexation du fer par des ligands tripodes à base de sous-unités 8-hydroxyquinoléine et 2,2'dihydroxybiphényle : aspects thermodynamiques et cinétiques." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10250.
Повний текст джерелаWarner, P. "Asymmetric synthesis via transition metal acyl complexes." Thesis, University of Oxford, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.355823.
Повний текст джерелаQuelch, Geoffrey E. "Theoretical studies of some transition metal complexes." Thesis, University of Manchester, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.329083.
Повний текст джерелаLin, Bing. "Organometallic chemistry of transition metal polyyne complexes." Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272565.
Повний текст джерелаZweni, Pumza P. "Dendrimer-transition metal catalyzed oxidation and reduction reactions." Thesis, University of Ottawa (Canada), 2005. http://hdl.handle.net/10393/10529.
Повний текст джерелаHartstock, Frederick W. "Activation of organic molecules by transition metal complexes." Thesis, University of Ottawa (Canada), 1987. http://hdl.handle.net/10393/5306.
Повний текст джерелаGilbert, M. "Carbon-carbon coupling reactions of organotransition metal complexes." Thesis, University of Bristol, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.235314.
Повний текст джерелаYoung, Mary Jane. "Phosphate diester cleavage mediated by transition metal complexes." Thesis, McGill University, 1996. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=40473.
Повний текст джерелаCopper(II) complexes of bis(2-pyridylmethyl)amine (Cu(II)bpa), N-(2-hydroxyethyl)bis(2-pyridylmethyl)amine (Cu(II)hebpa) and N-(3-hydroxypropyl)bis(2-pyridylmethyl)amine (Cu(II)hpbpa) have been synthesized and their reactivities and mechanisms for cleaving bis(2,4-dinitrophenyl) phosphate (BDNPP) have been investigated. Cu(II)hpbpa is observed to be the most reactive (k = 7.2 $ times$ 10$ sp{-1}$ M$ sp{-1}$ s$ sp{-1}$ at 25$ sp circ$C, pH 8.8) for cleaving BDNPP followed by Cu(II)bpa (k = 2.0 $ times$ 10$ sp{-2}$ M$ sp{-1}$ s$ sp{-1}$) and Cu(II)hebpa (k = 2.0 $ times$ 10$ sp{-2}$ s$ sp{-1}$). HPLC product analyses indicated that Cu(II)hpbpa cleaves BDNPP mostly through transesterification while the complexes Cu(II)bpa and Cu(II)hebpa cleave BDNPP predominantly by hydrolysis. The differences in the mechanisms and the reactivities are explained in terms of the differences in the structures of the three copper(II) complexes.
Copper(II) complexes of 1,8-bis(1,4,7-triazacyclononyl-N-methyl)naphthalene (tntn), 1,4,7-triazacyclononane (tacn), and N-benzyl-1,4,7-triazacyclononane (btacn) have been prepared and their reactivities compared for cleaving RNA. The novel dinuclear copper(II) complex, Cu(II)$ sb2$tntn, is observed to be 200-500 fold faster per metal center than the mononuclear copper(II)complexes, Cu(II)tacn and Cu(II)btacn, for cleaving a diribonucleotide, ApA, and its cyclic phosphate intermediate, $2 sp prime3 sp prime$-cAMP. Cu(II)$ sb2$tntn (2.0 mM) reduces the half life of ApA (0.05 mM) to 50 minutes (pH 6, 50$ sp circ$C); this represents a rate acceleration of approximately 10$ sp5$ fold over the background hydroxide rate. The half life of $2 sp prime3 sp prime$-cAMP (0.05 mM) is decreased to 4 minutes in the presence of Cu(II)$ sb2$tntn (2.0 mM, pH 6, 25$ sp circ$C); this represents a rate acceleration of about 10$ sp8$ fold over the background hydroxide rate.
Zhu, Ping Yeh. "Controlled reactions of arene-transition metal complexes with nucleophiles." Case Western Reserve University School of Graduate Studies / OhioLINK, 1995. http://rave.ohiolink.edu/etdc/view?acc_num=case1058203649.
Повний текст джерелаLiang, Shengwen. "Nitrene Transfer Reactions Mediated by Transition Metal Scorpionate Complexes." Ohio University / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1339005115.
Повний текст джерелаHuang, Xin. "Theoretical studies on transition metal mediated reactions /." View abstract or full-text, 2004. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202004%20HUANG.
Повний текст джерелаHerring, A. M. "New transition metal complexes containing functionalised phosphine ligands." Thesis, University of Leeds, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383967.
Повний текст джерела