Готові списки джерел за темами / Transition metal Chalcogenides

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Автор: Grafiati
Опубліковано: 10 грудня 2022
Оновлено: 6 вересня 2023

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Статті в журналах з теми "Transition metal Chalcogenides"

1

Wang, Lin-Hui, Long-Long Ren, and Yu-Feng Qin. "The Review of Hybridization of Transition Metal-Based Chalcogenides for Lithium-Ion Battery Anodes." Materials 16, no. 12 (June 18, 2023): 4448. http://dx.doi.org/10.3390/ma16124448.

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Анотація:
Transition metal chalcogenides as potential anodes for lithium-ion batteries have been widely investigated. For practical application, the drawbacks of low conductivity and volume expansion should be further overcome. Besides the two conventional methods of nanostructure design and the doping of carbon-based materials, the component hybridization of transition metal-based chalcogenides can effectively enhance the electrochemical performance owing to the synergetic effect. Hybridization could promote the advantages of each chalcogenide and suppress the disadvantages of each chalcogenide to some extent. In this review, we focus on the four different types of component hybridization and the excellent electrochemical performance that originated from hybridization. The exciting problems of hybridization and the possibility of studying structural hybridization were also discussed. The binary and ternary transition metal-based chalcogenides are more promising to be used as future anodes of lithium-ion batteries for their excellent electrochemical performance originating from the synergetic effect.
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2

Bennett, J. C., and F. W. Boswell. "Charge-density wave modulations in the transition metal chalcogenides." Proceedings, annual meeting, Electron Microscopy Society of America 54 (August 11, 1996): 706–7. http://dx.doi.org/10.1017/s0424820100165999.

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The transition metal chalcogenides, due to the typically large covalency of the metal-chalcogenide bonds, often adopt low-dimensional structures and exhibit charge-density wave (CDW) modulations. Incommensurate (IC) or commensurate (C) modulations structures are observed as well as a rich variety of phase transitions driven by the temperature dependence of the CDW amplitude and phase. Defects of the CDW modulation, including antiphase boundaries (APB) and discommensurations (DC), are of determinate importance for the mediation of these phase transitions. The microstructural phenomena occurring in the quasi-one-dimensional chalcogenides will be surveyed with emphasis on two representative systems: the Nb1-xTaxTe4 solid solution and the MxNb3Te4 (M = In or TI) intercalation compound.The NbxTa1-xTe4 compounds are based on a tetragonal subcell with axes (a x a x c) and consist of an extended chain of metal atoms centered within an antiprismatic cage of Te atoms.
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3

Kuznetsov, Vladimir G., Anton A. Gavrikov, Milos Krbal, Vladimir A. Trepakov, and Alexander V. Kolobov. "Amorphous As2S3 Doped with Transition Metals: An Ab Initio Study of Electronic Structure and Magnetic Properties." Nanomaterials 13, no. 5 (February 27, 2023): 896. http://dx.doi.org/10.3390/nano13050896.

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Crystalline transition-metal chalcogenides are the focus of solid state research. At the same time, very little is known about amorphous chalcogenides doped with transition metals. To close this gap, we have studied, using first principle simulations, the effect of doping the typical chalcogenide glass As2S3 with transition metals (Mo, W and V). While the undoped glass is a semiconductor with a density functional theory gap of about 1 eV, doping results in the formation of a finite density of states (semiconductor-to-metal transformation) at the Fermi level accompanied by an appearance of magnetic properties, the magnetic character depending on the nature of the dopant. Whilst the magnetic response is mainly associated with d-orbitals of the transition metal dopants, partial densities of spin-up and spin-down states associated with arsenic and sulphur also become slightly asymmetric. Our results demonstrate that chalcogenide glasses doped with transition metals may become a technologically important material.
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4

Mitchell, Kwasi, and James A. Ibers. "Rare-Earth Transition-Metal Chalcogenides." Chemical Reviews 102, no. 6 (June 2002): 1929–52. http://dx.doi.org/10.1021/cr010319h.

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5

Arulraj, Arunachalam, Praveen Kumar Murugesan, Rajkumar C, Alejandra Tello Zamorano, and Ramalinga Viswanathan Mangalaraja. "Nanoarchitectonics of Layered Metal Chalcogenides-Based Ternary Electrocatalyst for Water Splitting." Energies 16, no. 4 (February 7, 2023): 1669. http://dx.doi.org/10.3390/en16041669.

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The research on renewable energy is actively looking into electrocatalysts based on transition metal chalcogenides because nanostructured electrocatalysts support the higher intrinsic activity for both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). A major technique for facilitating the conversion of renewable and sustainable energy is electrochemical water splitting. The aim of the review is to discuss the revelations made when trying to alter the internal and external nanoarchitectures of chalcogenides-based electrocatalysts to enhance their performance. To begin, a general explanation of the water-splitting reaction is given to clarify the key factors in determining the catalytic performance of nanostructured chalcogenides-based electrocatalysts. To delve into the many ways being employed to improve the HER’s electrocatalytic performance, the general fabrication processes utilized to generate the chalcogenides-based materials are described. Similarly, to enhance the OER performance of chalcogenides-based electrocatalysts, the applied complementary techniques and the strategies involved in designing the bifunctional water-splitting electrocatalysts (HER and OER) are explained. As a conclusive remark, the challenges and future perspectives of chalcogenide-based electrocatalysts in the context of water splitting are summarized.
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6

Huang, Yu Li, Wei Chen, and Andrew T. S. Wee. "Two‐dimensional magnetic transition metal chalcogenides." SmartMat 2, no. 2 (May 4, 2021): 139–53. http://dx.doi.org/10.1002/smm2.1031.

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7

Lee, Min-Gon, SeokJae Yoo, TaeHyung Kim, and Q.-Han Park. "Large-area plasmon enhanced two-dimensional MoS2." Nanoscale 9, no. 42 (2017): 16244–48. http://dx.doi.org/10.1039/c7nr04974a.

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Two-dimensional transition metal chalcogenides (2D TMDCs) show photoluminescence (PL) enhancement as a result of the coupling between plasmon resonance of gold nanoparticles and direct band-gap transitions of 2D TMDCs.
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8

Zhang, Zhi, Yi Wang, Zelin Zhao, Weijing Song, Xiaoli Zhou, and Zejun Li. "Interlayer Chemical Modulation of Phase Transitions in Two-Dimensional Metal Chalcogenides." Molecules 28, no. 3 (January 18, 2023): 959. http://dx.doi.org/10.3390/molecules28030959.

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Two-dimensional metal chalcogenides (2D-MCs) with complex interactions are usually rich in phase transition behavior, such as superconductivity, charge density wave (CDW), and magnetic transitions, which hold great promise for the exploration of exciting physical properties and functional applications. Interlayer chemical modulation, as a renewed surface modification method, presents congenital advantages to regulate the phase transitions of 2D-MCs due to its confined space, strong guest–host interactions, and local and reversible modulation without destructing the host lattice, whereby new phenomena and functionalities can be produced. Herein, recent achievements in the interlayer chemical modulation of 2D-MCs are reviewed from the aspects of superconducting transition, CDW transition, semiconductor-to-metal transition, magnetic phase transition, and lattice transition. We systematically discuss the roles of charge transfer, spin coupling, and lattice strain on the modulation of phase transitions in the guest–host architectures of 2D-MCs established by electrochemical intercalation, solution-processed intercalation, and solid-state intercalation. New physical phenomena, new insight into the mechanism of phase transitions, and derived functional applications are presented. Finally, a prospectus of the challenges and opportunities of interlayer chemical modulation for future research is pointed out.
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9

Jung, Yeonwoong, Yu Zhou, and Judy J. Cha. "Intercalation in two-dimensional transition metal chalcogenides." Inorganic Chemistry Frontiers 3, no. 4 (2016): 452–63. http://dx.doi.org/10.1039/c5qi00242g.

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10

Baranov, N. V., N. V. Selezneva, and V. A. Kazantsev. "Magnetism and Superconductivity of Transition Metal Chalcogenides." Physics of Metals and Metallography 119, no. 13 (December 2018): 1301–4. http://dx.doi.org/10.1134/s0031918x18130215.

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Дисертації з теми "Transition metal Chalcogenides"

1

Shaw, Graham Andrew. "Solvent mediated synthesis of metal chalcogenides." Thesis, University College London (University of London), 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326065.

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2

Nahai-Williamson, Paul. "Tuning ordered states in transition metal chalcogenide systems." Thesis, University of Cambridge, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.609901.

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3

Eaglesham, D. J. "Charge density waves and their phase transitions in the transition metal chalcogenides." Thesis, University of Bristol, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375017.

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4

Pickup, David M. "The structure and characterisation of amorphous transition-metal chalcogenides." Thesis, University of Reading, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.308039.

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5

Nakanishi, Makoto. "Study of magnetic ordering of vanadium in layered transition metal chalcogenides." 京都大学 (Kyoto University), 2007. http://hdl.handle.net/2433/136959.

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6

Zhu, Bairen, and 朱柏仁. "Optical study on two dimensional transition metal dichalcogenides." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/208045.

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Atomically thin group-VI transition metal dichalcogenides (TMDC) has been emerging as a family of intrinsic 2-dimensional (2D) crystals with a sizeable bandgap in the visible and near infrared range, satisfying numerous requirements for ultimate electronics and optoelectronics. This intrinsic 2D crystal also provides a perfect platform for physics study in 2D semiconductors. The characteristic inversion symmetry breaking presented in monolayer TMDCs leads to non-zero but contrasting Berry curvatures and orbital magnetic moments at K/K’ valleys located at the corners of the first Brillouin zone. These features provide an opportunity to manipulate electrons’ additional internal degrees of freedom, namely the valley degree of freedom, making monolayer TMDC a promising candidate for the conceptual valleytronics. Besides, the strong spin-orbit interactions and the subsequent spin-valley coupling demonstrated in 2D TMDCs open potential new routes towards quantum manipulation. In this thesis, I give a brief review on the background and our progress of the physics study in 2D TMDCs (MoS2, WS2) via optical spectroscopy. Particularly, our experimental approach on the excitonic effect, valley dependent circular dichroism, and the spin-valley coupling in monolayer and bilayer TMDCs are elaborated in individual chapters.
published_or_final_version
Physics
Doctoral
Doctor of Philosophy
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7

Tsang, Ka-yi, and 曾家懿. "Two dimensional transition metal dichalcogenides grown by chemical vapor deposition." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/212604.

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An atomically thin film of semiconducting transition metal dichalcogenides (TMDCs) is emerging as a class of key materials in chemistry and physics due to their remarkable chemical and electronic properties. The TMDCs are layered materials with weak out-of-plane van der Waals (vdW) interaction and strong in-plane covalent bonding enabling scalable exfoliation into two-dimensional (2D) layers of atomic thickness. The growth techniques to prepare these 2D TMDC materials in high yield and large scale with high crystallinity have attracted intensive attention recently because of the new properties and potentials in nano-elctronic, optoelectronic, spintronic and valleytronic applications. In this thesis, I develop methods for the chemical synthesis of 2D TMDCs films. The relevant growth mechanism and material characteristics of these films are also investigated. Molybdenum disulfide (MoS2) is synthesized by using molybdenum trioxide (MoO3) and sulfur (S) powder as the precursor. The films are formed on substrate pre-treated with reduced graphene oxide as the catalyst. However, this method cannot be extended to other TMDC materials such as molybdenum diselenide (MoSe2) and tungsten diselenide (WSe2) because reduced graphene oxide (rGO) reacts with selenium to form alloy materials rather than TMDC films. At the same time, the conversion of MoO3 to MoSe2 or that of tungsten trioxide (WO3) to WSe2 without the assistance of hydrogen in the chemical reaction is not thermodynamically feasible because the oxygen in the metal oxide cannot be replaced by selenium due to lower reactivity of the latter. On the other hand, I demonstrate that MoSe2 film can be synthesized directly by using MoSe2 and Se powder. Furthermore, the method of sulfurization or selenization of pre-deposited metal film can be promising due to precise thickness/size controls. Finally, some perspectives on the engineering challenges and fabrication methods of this family of materials will be given.
published_or_final_version
Physics
Master
Master of Philosophy
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8

Walton, Richard I. "The characterisation and structure of amorphous and poorly crystalline transition-metal chalcogenides." Thesis, University of Reading, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.388467.

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9

Li, Tianyang. "Synthesis and Characterization of Atomic Scale Derivatives and Clusters of Transition Metal Chalcogenides." The Ohio State University, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=osu1460839448.

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10

WANG, MENGJIAO. "Colloidal Synthesis of Transition Metal Chalcogenides and Their Applications in Electrocatalytic Water Splitting." Doctoral thesis, Università degli studi di Genova, 2019. http://hdl.handle.net/11567/941181.

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Книги з теми "Transition metal Chalcogenides"

1

Jaegermann, W. Interfacial properties of semiconducting transition metal chalcogenides. Oxford: Pergamon, 1988.

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2

V, Borisov S., ред. Khalʹkogenidy perekhodnykh tugoplavkikh metallov: Kvaziodnomernye soedinenii͡a︡. Novosibirsk: "Nauka," Sibirskoe otd-nie, 1988.

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Частини книг з теми "Transition metal Chalcogenides"

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Fitzpatrick, Brian J. "Transition Metal Chalcogenides." In Inorganic Reactions and Methods, 237–38. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145333.ch165.

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2

Wold, Aaron, and Kirby Dwight. "Ternary Transition Metal Chalcogenides AB2X4." In Solid State Chemistry, 222–35. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1476-9_12.

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3

Kolobov, Alexander V., and Junji Tominaga. "Chalcogenides Nanoelectronics: Hype and Hope." In Two-Dimensional Transition-Metal Dichalcogenides, 529–31. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-31450-1_16.

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4

Kolobov, Alexander V., and Junji Tominaga. "Chemistry of Chalcogenides and Transition Metals." In Two-Dimensional Transition-Metal Dichalcogenides, 7–27. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-31450-1_2.

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5

Kaldis, E. "4f -Transition Metal (Rare Earth) Chalcogenides." In Inorganic Reactions and Methods, 253–55. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145203.ch157.

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6

Alonso-Vante, Nicolas. "Transition Metal Chalcogenides for Oxygen Reduction." In Lecture Notes in Energy, 417–36. London: Springer London, 2013. http://dx.doi.org/10.1007/978-1-4471-4911-8_14.

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7

Page, E. M., and D. A. Rice. "From Transition-Metal Halides with Main-Group Chalcogenides." In Inorganic Reactions and Methods, 242–43. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145180.ch158.

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8

Whangbo, M. H., D. K. Seo, and E. Canadell. "Structural and Electronic Instabilities of Transition Metal Chalcogenides." In Physics and Chemistry of Low-Dimensional Inorganic Conductors, 285–302. Boston, MA: Springer US, 1996. http://dx.doi.org/10.1007/978-1-4613-1149-2_17.

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9

Malterre, D., M. Grioni, and Y. Baer. "Photoemission Studies in Transition Metal Oxides and Chalcogenides." In Physics and Chemistry of Low-Dimensional Inorganic Conductors, 303–11. Boston, MA: Springer US, 1996. http://dx.doi.org/10.1007/978-1-4613-1149-2_18.

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10

Corbett, James M. "Transmission Electron Microscopy of CDW-Modulated Transition Metal Chalcogenides." In Physics and Chemistry of Materials with Low-Dimensional Structures, 121–51. Dordrecht: Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4603-6_4.

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Тези доповідей конференцій з теми "Transition metal Chalcogenides"

1

Sutou, Y., S. Shindo, S. Hatayama, Y. Saito, and J. Koike. "Transition Metal-Ge-Te Chalcogenides for PCRAM Material." In 2017 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 2017. http://dx.doi.org/10.7567/ssdm.2017.a-8-01.

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2

Khare, Ruchita T., Mahendra A. More, and Dattatray J. Late. "Transition metal di-chalcogenides and their nanocomposite prospective field emitters." In 2015 28th International Vacuum Nanoelectronics Conference (IVNC). IEEE, 2015. http://dx.doi.org/10.1109/ivnc.2015.7225545.

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3

Sharma, Ankit, Rutuparna Samal, C. S. Rout, and K. V. Adarsh. "Spin-Orbit Induced Crossover in Nonlinear Optical Response in Mixed Transition Metal Chalcogenides." In Frontiers in Optics. Washington, D.C.: Optica Publishing Group, 2022. http://dx.doi.org/10.1364/fio.2022.jtu4b.29.

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Анотація:
We demonstrated ultrafast nonlinear optical response in mixed-transition-metal chalcogenides. Our unprecedented results epitome the additional excitonic bands induced by the spin-orbit effect crossover the nonlinear response which can be used in optics and photonics applications.
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4

Shimizu, Hiroshi, Jiang Pu, Zheng Liu, Hong En Lim, Yusuke Nakanishi, Takahiko Endo, Kazuhiro Yanagi, Taishi Takenobu, and Yasumitsu Miyata. "High mobility and 2D electron gas in aggregates of 1D transition metal chalcogenide atomic wires." In JSAP-OSA Joint Symposia. Washington, D.C.: Optica Publishing Group, 2021. http://dx.doi.org/10.1364/jsap.2021.10a_n305_8.

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5

Mirov, S. B., V. V. Fedorov, D. V. Martyshkin, I. S. Moskalev, M. S. Mirov, O. Gafarov, A. Martinez, et al. "Mid-IR gain media based on transition metal-doped II-VI chalcogenides." In SPIE OPTO, edited by Shibin Jiang and Michel J. F. Digonnet. SPIE, 2016. http://dx.doi.org/10.1117/12.2212822.

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6

Miyata, Kentaro, Masaki Yumoto, Yasushi Kawata, Satoshi Wada, and Shinichi Imai. "Noncritically phase-matched self-difference frequency generation using transition-metal doped chalcogenides." In Nonlinear Frequency Generation and Conversion: Materials and Devices XXII, edited by Peter G. Schunemann. SPIE, 2023. http://dx.doi.org/10.1117/12.2653039.

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Roy, Sayan, Zixuan Hu, Sabre Kais, and Peter Bermel. "Tailoring Donor-Acceptor Pairs of Tungsten-based Transition Metal Di-Chalcogenides (TMDCs) for Improved Photovoltaic Current Generation." In 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC). IEEE, 2019. http://dx.doi.org/10.1109/pvsc40753.2019.8981337.

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8

Zhou, Feng, and Wei Ji. "Multi-Photon Absorption in Monolayer Transition-Metal Di-Chalcogenides and its Applications for Sub-band Multi-Photon Detection." In Conference on Lasers and Electro-Optics/Pacific Rim. Washington, D.C.: OSA, 2018. http://dx.doi.org/10.1364/cleopr.2018.th1g.3.

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9

Lei, Xunyong. "Application of Photoluminescence in the Study of Valley Polarization and Valley Coherence of Two Dimensional Transition Metal Chalcogenides." In AIAM2021: 2021 3rd International Conference on Artificial Intelligence and Advanced Manufacture. New York, NY, USA: ACM, 2021. http://dx.doi.org/10.1145/3495018.3495339.

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Bahador, S. K. "Transition metal chalcogenides and Lamellar compounds: their science & technology 36 - electrocatalysis by mocl compounds in energy conversion & storage systems." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835907.

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Звіти організацій з теми "Transition metal Chalcogenides"

1

Ibers, James A. Final Report for Grant BES ER-15522. Actinide Transition-Metal Chalcogenides and Pnictides. Office of Scientific and Technical Information (OSTI), September 2013. http://dx.doi.org/10.2172/1093586.

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2

Hopkins, Michael. Investigation of Magnetism in Transition Metal Chalcogenide Thin Films. Portland State University Library, January 2000. http://dx.doi.org/10.15760/etd.7479.

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