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Статті в журналах з теми "TiS3"

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Автор: Grafiati

Опубліковано: 6 вересня 2023

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1

Lai, Shengqiang, and Yongping Du. "Magnetic Behavior in TiS3 Nanoribbon." Materials 12, no. 21 (October 25, 2019): 3501. http://dx.doi.org/10.3390/ma12213501.

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The electronic structure, magnetic properties and strain response of N-a-TiS3 nanoribbons are investigated by first-principles calculations. We find that the magnetic ground state is strongly dependent on width of a-TiS3. When N equals an odd number the ground state is a ferromagnetic (FM) metal, meanwhile, when N equals an even number the ground state is an anti-ferromagnetic (AFM) metal. More interestingly, a tensile strain as large as 6% can tune the 9-a-TiS3 nanoribbon from a FM metal to a half metal. A 4% tensile strain also causes a phase transition from AFM to FM ground state for 10-a-TiS3 nanoribbon. Our findings show that N-a-TiS3 is a promising candidate for spintronic and electronic applications.

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2

Chang, H. S. W., and D. M. Schleich. "TiS2 and TiS3 thin films prepared by MOCVD." Journal of Solid State Chemistry 100, no. 1 (September 1992): 62–70. http://dx.doi.org/10.1016/0022-4596(92)90156-p.

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3

Qin, Jing-Kai, Hai-Lin Sun, Pei-Yu Huang, Yang Li, Liang Zhen, and Cheng-Yan Xu. "Synaptic plasticity realized by selective oxidation of TiS₃ nanosheet for neuromorphic devices." RSC Advances 13, no. 22 (2023): 14849–54. http://dx.doi.org/10.1039/d3ra00782k.

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In-plane memristor fabricated based on a TiS3–TiOx–TiS3 heterostructure demonstrates excellent synaptic characteristics with tunable and multiple resistance levels, which can be integrated into a neural network for high-accuracy pattern recognition.

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4

Ghasemi, Foad, Riccardo Frisenda, Eduardo Flores, Nikos Papadopoulos, Robert Biele, David Perez de Lara, Herre S. J. van der Zant, et al. "Tunable Photodetectors via In Situ Thermal Conversion of TiS3 to TiO2." Nanomaterials 10, no. 4 (April 9, 2020): 711. http://dx.doi.org/10.3390/nano10040711.

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In two-dimensional materials research, oxidation is usually considered as a common source for the degradation of electronic and optoelectronic devices or even device failure. However, in some cases a controlled oxidation can open the possibility to widely tune the band structure of 2D materials. In particular, we demonstrate the controlled oxidation of titanium trisulfide (TiS3), a layered semicon-ductor that has attracted much attention recently thanks to its quasi-1D electronic and optoelectron-ic properties and its direct bandgap of 1.1 eV. Heating TiS3 in air above 300 °C gradually converts it into TiO2, a semiconductor with a wide bandgap of 3.2 eV with applications in photo-electrochemistry and catalysis. In this work, we investigate the controlled thermal oxidation of indi-vidual TiS3 nanoribbons and its influence on the optoelectronic properties of TiS3-based photodetec-tors. We observe a step-wise change in the cut-off wavelength from its pristine value ~1000 nm to 450 nm after subjecting the TiS3 devices to subsequent thermal treatment cycles. Ab-initio and many-body calculations confirm an increase in the bandgap of titanium oxysulfide (TiO2-xSx) when in-creasing the amount of oxygen and reducing the amount of sulfur.

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5

Yao, Huizhen, and Lai Liu. "Design and Optimize the Performance of Self-Powered Photodetector Based on PbS/TiS3 Heterostructure by SCAPS-1D." Nanomaterials 12, no. 3 (January 20, 2022): 325. http://dx.doi.org/10.3390/nano12030325.

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Titanium trisulphide (TiS3) has been widely used in the field of optoelectronics owing to its superb optical and electronic characteristics. In this work, a self-powered photodetector using bulk PbS/TiS3 p-n heterojunction is numerically investigated and analyzed by a Solar Cell Capacitance Simulator in one-Dimension (SCAPS-1D) software. The energy bands, electron-holes generation or recombination rate, current density-voltage (J-V), and spectral response properties have been investigated by SCAPS-1D. To improve the performance of photodetectors, the influence of thickness, shallow acceptor or donor density, and defect density are investigated. By optimization, the optimal thickness of the TiS3 layer and PbS layer are determined to be 2.5 μm and 700 nm, respectively. The density of the superior shallow acceptor (donor) is 1015 (1022) cm−3. High quality TiS3 film is required with the defect density of about 1014 cm−3. For the PbS layer, the maximum defect density is 1017 cm−3. As a result, the photodetector based on the heterojunction with optimal parameters exhibits a good photoresponse from 300 nm to 1300 nm. Under the air mass 1.5 global tilt (AM 1.5G) illuminations, the optimal short-circuit current reaches 35.57 mA/cm2 and the open circuit voltage is about 870 mV. The responsivity (R) and a detectivity (D*) of the simulated photodetector are 0.36 A W−1 and 3.9 × 1013 Jones, respectively. The simulation result provides a promising research direction to further broaden the TiS3-based optoelectronic device.

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6

Zakharova, Olga V., Alexander A. Gusev, Dmitry S. Muratov, Alexey V. Shuklinov, Nataliya S. Strekalova, and Sergey M. Matveev. "Titanium Trisulfide Nanoribbons Affect the Downy Birch and Poplar × Aspen Hybrid in Plant Tissue Culture via the Emission of Hydrogen Sulfide." Forests 12, no. 6 (May 31, 2021): 713. http://dx.doi.org/10.3390/f12060713.

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Plant tissue culture is an important tool for accelerated vegetative reproduction of woody plants. To increase the efficiency of this method, it is necessary to search for new growth stimulators and protectors of microshoots. Two-dimensional (2D) nanomaterials are highly promising for applications in medicine and biotechnologies. We have studied the effects of TiS3 nanoribbons with the following mean dimensions: thickness less than 100 nm, length 1–10 μm and width 0.4–1 μm upon poplar × aspen hybrid and downy birch microclones in plant tissue culture. We have found the effectiveness of this particular nanomaterial as a sterilizing and stimulating agent in the initial growth stage and as a rhizogenesis-activating agent in the rooting stage. We analyzed a wide range of TiS3 concentrations in the nutrient media and identified 1.5 and 3 μg/L as optimal. However, concentration-dependent toxic effects manifesting themselves through microclones viability suppression have been discovered in the groups exposed to 6 and 15 μg/L TiS3. We have established that plant reaction to TiS3 treatment is specific for different plant species, i.e., downy birch is generally more tolerant than poplar × aspen hybrid. Here, we propose that the protective and stimulating effects of titanium trisulfide as well as its toxicity in high concentrations can be explained by the release of hydrogen sulfide as a result of aqueous hydrolysis of nanoribbons and its effect on plants. Additional studies are required in order to assess all biological effects produced by TiS3 nanoribbons at further stages of ontogenetic development and to identify the mechanisms of their action.

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7

Klepp, Kurt O. "K2TiS3, ein neues Thiotitanat(IV) mit fünffach koordiniertem Titan / K2TiS3, A New Thiotitanate(IV) with Pentacoordinate Titanium." Zeitschrift für Naturforschung B 47, no. 2 (February 1, 1992): 201–4. http://dx.doi.org/10.1515/znb-1992-0210.

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Fibrous red crystals of the new compound K2TiS3 were obtained by reacting K2S, Ti and S at 1070 K. K2TiS3 is monoclinic, space group C 2/c with a = 11.667(6) Å, b = 8.325(4) Å, c = 6.494(4) Å, β = 9 i.81(4)°, Z = 4. The crystal structure was refined to a conventional residual of 0.070. The atomic arrangement is characterized by pseudo-one-dimensional -∞-[TiS3]2− chains formed by distorted TiS5 square pyramids sharing opposite edges of their basal planes. The structure - though closely related to that of Cs2TiS3 - is of a new type.

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8

Gorlova, I. G., S. A. Nikonov, S. G. Zybtsev, V. Ya Pokrovskii, and A. N. Titov. "Temperature variation of photoconductivity in the layered quasi one-dimensional compound TiS₃: Semiconducting and unconventional behavior." Applied Physics Letters 120, no. 15 (April 11, 2022): 153102. http://dx.doi.org/10.1063/5.0082716.

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The layered quasi one-dimensional compound TiS3 is remarkable for its optical properties, especially, photoconductivity. Up to now, photoconductivity in TiS3 was studied only at room temperature. Here, we report photoconductivity, δσ, of the TiS3 whiskers in the temperature range of 5–300 K under irradiation in the near-infrared region. With a temperature decrease from room temperature down to T ∼ 100 K, δσ grows moderately, dominated by the variation of the mobility of the electrons. The estimates based on the values of δσ give the recombination time ∼3–25 μs at 300 K. The results show that above ∼100 K, TiS3 behaves as a semiconductor, where electron–hole pairs are excited across the gap, while the recombination goes through transitions of the excited electrons to a donor level with a long lifetime. Below 60 K, a drop of δσ is likely to reveal a phase transition of electrons into a collective state. Another feature in δσ( T) is seen around 17 K, resembling the temperature variation of the conductivity. This feature indicates a drop in the mobility of the electrons. While the behavior of δσ( T) is consistent with the transition of electrons into a collective state, it is strikingly different from δσ( T) of the known quasi one-dimensional conductors with charge-density waves.

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9

Zakharova, O., I. Vasyukova, D. S. Muratov, V. Korenkov, P. Baranchikov, and A. Gusev. "Concentration-dependent stimulating and toxic effects of ZrS₃ and TiS₃ nanoribbons on forest woody plants in tissue culture in vitro." IOP Conference Series: Earth and Environmental Science 875, no. 1 (October 1, 2021): 012052. http://dx.doi.org/10.1088/1755-1315/875/1/012052.

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Abstract Nanotechnology has a great potential for application in applied biotechnology. Here we demonstrate the effectiveness of synthesized by direct reaction ZrS3 and TiS3 nanoribbons as sterilizing agents, growth stimulators and activators of rhizogenesis of micro-sprouts of tree crops during clonal micropropagation. At the initiation stage at 6 and 15 μg/L ZrS3 and 3, 6 and 15 μg/L TiS3, complete sterility of shoots of brittle willow, red oak and Scots pine was noted. The maximum survival rate and seedling height at this stage was in the groups of 1.5 μg/L ZrS3 and 3 μg/L TiS3. An increase in the concentration of nanomaterials to 15 μg/L significantly reduced the viability of plants. At the proliferation stage the concentration of nanomaterials 1.5 and 3 μg/L increased the survival rate of regenerants, and at 3 μg/L with the phytohormones (benzylaminopurine, indoleacetic acid, gibberelic acid) the number of additional shoots increased. At the rooting stage ZrS3 and TiS3 at doses of 1.5 and 3 μg/L with auxin activated rhizogenesis, significantly increasing the number of seedlings with roots in comparison with the variants where only auxin were used. This effects can be associated both with the direct action of nanoribbons and with the release of hydrogen sulfide as a result of aqueous hydrolysis of nanoribbons, since H2S plays an important role in the regulation of plant physiological processes.

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10

Zakharova, Olga V., Valeria V. Belova, Peter A. Baranchikov, Anna A. Kostyakova, Dmitry S. Muratov, Gregory V. Grigoriev, Svetlana P. Chebotaryova, Denis V. Kuznetsov, and Alexander A. Gusev. "The Conditions Matter: The Toxicity of Titanium Trisulfide Nanoribbons to Bacteria E. coli Changes Dramatically Depending on the Chemical Environment and the Storage Time." International Journal of Molecular Sciences 24, no. 9 (May 5, 2023): 8299. http://dx.doi.org/10.3390/ijms24098299.

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In this work, we present an analysis of the antibacterial activity of TiS3 nanostructures in water and 0.9% NaCl solution suspensions. TiS3 nanoribbons 1–10 µm long, 100–300 nm wide, and less than 100 nm thick were produced by the direct reaction of pure titanium powder with elemental sulphur in a quartz tube sealed under vacuum. For the toxicity test of a bioluminescent strain of E. coli we used concentrations from 1 to 0.0001 g L−1 and also studied fresh suspensions and suspensions left for 24 h. The strongest toxic effect was observed in freshly prepared water solutions where the luminescence of bacteria decreased by more than 75%. When saline solution was substituted for water or when the solutions were stored for 24 h it resulted in a considerable decrease in the TiS3 antibacterial effect. The toxicity of TiS3 in water exceeded the toxicity of the reference TiO2 nanoparticles, though when saline solution was used instead of water the opposite results were observed. In addition, we did not find a relationship between the antibacterial activity of water suspensions of nanoribbons and the stability of their colloidal systems, which indicates an insignificant contribution to the toxicity of aggregation processes. In 0.9% NaCl solution suspensions, toxicity increased in proportion to the increase in the zeta potential. We suppose that the noted specificity of toxicity is associated with the emission of hydrogen sulphide molecules from the surface of nanoribbons, which, depending on the concentration, can either decrease or increase oxidative stress, which is considered the key mechanism of nanomaterial cytotoxicity. However, the exact underlying mechanisms need further investigation. Thus, we have shown an important role of the dispersion medium and the period of storage in the antibacterial activity of TiS3 nanoribbons. Our results could be used in nanotoxicological studies of other two-dimensional nanomaterials, and for the development of novel antibacterial substances and other biomedical applications of this two-dimensional material.

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11

Jiménez-Arévalo, Nuria, Eduardo Flores, Alessio Giampietri, Marco Sbroscia, Maria Grazia Betti, Carlo Mariani, José R. Ares, Isabel J. Ferrer, and Fabrice Leardini. "Borocarbonitride Layers on Titanium Dioxide Nanoribbons for Efficient Photoelectrocatalytic Water Splitting." Materials 14, no. 19 (September 23, 2021): 5490. http://dx.doi.org/10.3390/ma14195490.

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Heterostructures formed by ultrathin borocarbonitride (BCN) layers grown on TiO2 nanoribbons were investigated as photoanodes for photoelectrochemical water splitting. TiO2 nanoribbons were obtained by thermal oxidation of TiS3 samples. Then, BCN layers were successfully grown by plasma enhanced chemical vapour deposition. The structure and the chemical composition of the starting TiS3, the TiO2 nanoribbons and the TiO2-BCN heterostructures were investigated by Raman spectroscopy, X-ray diffraction and X-ray photoelectron spectroscopy. Diffuse reflectance measurements showed a change in the gap from 0.94 eV (TiS3) to 3.3 eV (TiO2) after the thermal annealing of the starting material. Morphological characterizations, such as scanning electron microscopy and optical microscopy, show that the morphology of the samples was not affected by the change in the structure and composition. The obtained TiO2-BCN heterostructures were measured in a photoelectrochemical cell, showing an enhanced density of current under dark conditions and higher photocurrents when compared with TiO2. Finally, using electrochemical impedance spectroscopy, the flat band potential was determined to be equal in both TiO2 and TiO2-BCN samples, whereas the product of the dielectric constant and the density of donors was higher for TiO2-BCN.

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12

Rohaizad, Nasuha, Carmen C. Mayorga-Martinez, Zdeněk Sofer, Richard D. Webster, and Martin Pumera. "Niobium-doped TiS2: Formation of TiS3 nanobelts and their effects in enzymatic biosensors." Biosensors and Bioelectronics 155 (May 2020): 112114. http://dx.doi.org/10.1016/j.bios.2020.112114.

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13

Kang, Jun, and Lin-Wang Wang. "Robust band gap of TiS3 nanofilms." Physical Chemistry Chemical Physics 18, no. 22 (2016): 14805–9. http://dx.doi.org/10.1039/c6cp01125j.

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14

Zhu, Hua, Hui Han, Dun Wu, Lin Wu, Wenhui Liu, Xi Tang, Junmin Xu, Changjin Zhang, and Hui Li. "Controlling hysteretic transitions in quasi-one-dimensional TiS₃ microribbons." Applied Physics Letters 121, no. 1 (July 4, 2022): 013503. http://dx.doi.org/10.1063/5.0094484.

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Understanding the occurrence of charge density wave (CDW) states in quasi-one-dimensional (quasi-1D) transition metal trichalcogenides has attracted substantial research interest. Here, we report the systematic control of hysteretic transitions in quasi-1D TiS3 microribbons by changing the thickness and the cooling rate. Two distinguished resistance hysteresis loops are observed at a high temperature of ∼290 K and a low temperature of ∼60 K, respectively. In addition, two hysteretic transitions exhibit different behaviors under the external perturbations, in which the high temperature hysteretic transition is sensitive to TiS3 microribbons thickness, while the low temperature hysteretic transition is probably related to the CDW state and is robust against external perturbations. Our findings will offer a new frontier of exploration of the hysteretic transitions in the quasi-1D transition metal trichalcogenides.

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15

Ferrer, I. J., M. D. Maciá, V. Carcelén, J. R. Ares, and C. Sánchez. "On the Photoelectrochemical Properties of TiS3 Films." Energy Procedia 22 (2012): 48–52. http://dx.doi.org/10.1016/j.egypro.2012.05.219.

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16

Яминский, И. В., А. И. Ахметова, Г. Б. Мешков та А. В. Оленин. "Сканирующая зондовая микроскопия 2D наноразмерных структур для энергонакопителей и катализаторов". NANOINDUSTRY Russia 12, № 2 (8 квітня 2019): 148–51. http://dx.doi.org/10.22184/1993-8578.2019.12.2.148.151.

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В рамках работ по модификации строения и определения физико-химических и электрофизических характеристик 2D наноразмерных структур проведено исследование их проводимости. Получены данные об электрической проводимости структур TiS3 на поверхности оксида кремния. Измерены проводимости графена и графита методом СРМ. Данные получены с помощью СЗМ ФемтоСкан.

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17

Varnum, B. C., R. W. Lim, D. A. Kujubu, S. J. Luner, S. E. Kaufman, J. S. Greenberger, J. C. Gasson, and H. R. Herschman. "Granulocyte-macrophage colony-stimulating factor and tetradecanoyl phorbol acetate induce a distinct, restricted subset of primary-response TIS genes in both proliferating and terminally differentiated myeloid cells." Molecular and Cellular Biology 9, no. 8 (August 1989): 3580–83. http://dx.doi.org/10.1128/mcb.9.8.3580-3583.1989.

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Induction of early-response genes (tetradecanoyl phorbol acetate [TPA]-induced sequences, or TIS genes; R.W. Lim, B.C. Varnum, and H.R. Herschman, Oncogene 1:263-270, 1987) by granulocyte-macrophage colony-stimulating factor (GM-CSF) and TPA was examined both in a factor-dependent murine cell line, 32D clone 3, and in mature human neutrophils. When GM-CSF-deprived 32D clone 3 cells were exposed to GM-CSF or to TPA, four TIS mRNAs (TIS7, TIS8, TIS10, and TIS11) were rapidly and transiently induced. However, neither GM-CSF nor TPA could induce accumulation of TIS1 mRNA in 32D clone 3 cells, even under superinducing conditions. Both GM-CSF and TPA also elicited rapid, transient expression of TIS8 and TIS11 mRNA in postmitotic human neutrophils. However, neither agent could induce accumulation of TIS1 mRNA in human neutrophils. TIS1 is a member of the nuclear receptor supergene family that codes for ligand-dependent transcription factors. Cell-type restriction of inducible transcription factors may contribute to developmental specification.

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18

Varnum, B. C., R. W. Lim, D. A. Kujubu, S. J. Luner, S. E. Kaufman, J. S. Greenberger, J. C. Gasson, and H. R. Herschman. "Granulocyte-macrophage colony-stimulating factor and tetradecanoyl phorbol acetate induce a distinct, restricted subset of primary-response TIS genes in both proliferating and terminally differentiated myeloid cells." Molecular and Cellular Biology 9, no. 8 (August 1989): 3580–83. http://dx.doi.org/10.1128/mcb.9.8.3580.

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Анотація:

Induction of early-response genes (tetradecanoyl phorbol acetate [TPA]-induced sequences, or TIS genes; R.W. Lim, B.C. Varnum, and H.R. Herschman, Oncogene 1:263-270, 1987) by granulocyte-macrophage colony-stimulating factor (GM-CSF) and TPA was examined both in a factor-dependent murine cell line, 32D clone 3, and in mature human neutrophils. When GM-CSF-deprived 32D clone 3 cells were exposed to GM-CSF or to TPA, four TIS mRNAs (TIS7, TIS8, TIS10, and TIS11) were rapidly and transiently induced. However, neither GM-CSF nor TPA could induce accumulation of TIS1 mRNA in 32D clone 3 cells, even under superinducing conditions. Both GM-CSF and TPA also elicited rapid, transient expression of TIS8 and TIS11 mRNA in postmitotic human neutrophils. However, neither agent could induce accumulation of TIS1 mRNA in human neutrophils. TIS1 is a member of the nuclear receptor supergene family that codes for ligand-dependent transcription factors. Cell-type restriction of inducible transcription factors may contribute to developmental specification.

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19

Bondarenko, V. I., I. N. Trunkin, I. G. Gorlova, N. B. Bolotina, and A. L. Vasiliev. "Investigating the Vacancy Structure of TiS3 Single Crystals." Bulletin of the Russian Academy of Sciences: Physics 85, no. 8 (August 2021): 858–62. http://dx.doi.org/10.3103/s1062873821080050.

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20

Lipatov, Alexey, Peter M. Wilson, Mikhail Shekhirev, Jacob D. Teeter, Ross Netusil, and Alexander Sinitskii. "Few-layered titanium trisulfide (TiS3) field-effect transistors." Nanoscale 7, no. 29 (2015): 12291–96. http://dx.doi.org/10.1039/c5nr01895a.

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21

Papadopoulos, Nikos, Riccardo Frisenda, Robert Biele, Eduardo Flores, Jose R. Ares, Carlos Sánchez, Herre S. J. van der Zant, Isabel J. Ferrer, Roberto D'Agosta, and Andres Castellanos-Gomez. "Large birefringence and linear dichroism in TiS3 nanosheets." Nanoscale 10, no. 26 (2018): 12424–29. http://dx.doi.org/10.1039/c8nr03616k.

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22

Ferrer, I. J., J. R. Ares, J. M. Clamagirand, M. Barawi, and C. Sánchez. "Optical properties of titanium trisulphide (TiS3) thin films." Thin Solid Films 535 (May 2013): 398–401. http://dx.doi.org/10.1016/j.tsf.2012.10.033.

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23

Biele, Robert, Eduardo Flores, Jose Ramón Ares, Carlos Sanchez, Isabel J. Ferrer, Gabino Rubio-Bollinger, Andres Castellanos-Gomez, and Roberto D’Agosta. "Strain-induced band gap engineering in layered TiS3." Nano Research 11, no. 1 (August 17, 2017): 225–32. http://dx.doi.org/10.1007/s12274-017-1622-3.

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24

Cui, Qiannan, Alexey Lipatov, Jamie Samantha Wilt, Matthew Z. Bellus, Xiao Cheng Zeng, Judy Wu, Alexander Sinitskii, and Hui Zhao. "Time-Resolved Measurements of Photocarrier Dynamics in TiS3 Nanoribbons." ACS Applied Materials & Interfaces 8, no. 28 (July 11, 2016): 18334–38. http://dx.doi.org/10.1021/acsami.6b04092.

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25

Gorlova, I. G., S. G. Zybtsev, V. Ya Pokrovskii, N. B. Bolotina, I. A. Verin, and A. N. Titov. "Nonlinear conductivity of quasi-one-dimensional layered compound TiS3." Physica B: Condensed Matter 407, no. 11 (June 2012): 1707–10. http://dx.doi.org/10.1016/j.physb.2012.01.012.

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26

Iyikanat, F., H. Sahin, R. T. Senger, and F. M. Peeters. "Vacancy Formation and Oxidation Characteristics of Single Layer TiS3." Journal of Physical Chemistry C 119, no. 19 (May 4, 2015): 10709–15. http://dx.doi.org/10.1021/acs.jpcc.5b01562.

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27

Guilmeau, Emmanuel, David Berthebaud, Patrick R. N. Misse, Sylvie Hébert, Oleg I. Lebedev, Daniel Chateigner, Christine Martin, and Antoine Maignan. "ZrSe3-Type Variant of TiS3: Structure and Thermoelectric Properties." Chemistry of Materials 26, no. 19 (September 17, 2014): 5585–91. http://dx.doi.org/10.1021/cm502069n.

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28

Trunkin, I. N., I. G. Gorlova, N. B. Bolotina, V. I. Bondarenko, Y. M. Chesnokov, and A. L. Vasiliev. "Defect structure of TiS3 single crystals with different resistivity." Journal of Materials Science 56, no. 3 (October 6, 2020): 2150–62. http://dx.doi.org/10.1007/s10853-020-05357-0.

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29

Patra, Abhinandan, Samadhan Kapse, Ranjit Thapa, Dattatray J. Late, and Chandra Sekhar Rout. "Quasi-one-dimensional van der Waals TiS₃ nanosheets for energy storage applications: Theoretical predications and experimental validation." Applied Physics Letters 120, no. 10 (March 7, 2022): 103102. http://dx.doi.org/10.1063/5.0080346.

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Анотація:

To cease the ever-increasing energy demand, additional enthusiastic focus has been given to generate more sustainable energy from alternative renewable sources. Storage of these energies for future usage solely banks on energy storage devices. A diversity of electrode materials based on two-dimensional (2D) transition metals and their derivatives have enticed the whole world owing to their tunable properties. Transition metal trichalcogenides (MX3 type) are the emergent class of 2D materials, which gathered a lot of interest because of their quasi-one-dimensional anisotropic properties with the van der Waals force of attraction in between the layers. Herein, TiS3 being a MX3-type of material is preferred as the battery type-supercapacitor electrode for energy storage applications with detailed theoretical predications and experimental validations. The highest capacitance attained for TiS3 is found to be 235 F/g (105 C/g) at 5 mV/s with a battery type of charge storage mechanism. The asymmetric hybrid device is fabricated using Ti3C2Tx MXene nanosheets as a negative electrode, and a brilliant 91% of capacitance retention is accomplished with an extensive potential window of 1.5 V. The investigational discoveries are substantiated by theoretical simulation in terms of the quantum capacitance assessment and charge storage mechanisms.

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30

Sysoev, Victor V., Andrey V. Lashkov, Alexey Lipatov, Ilya A. Plugin, Michael Bruns, Dirk Fuchs, Alexey S. Varezhnikov, Mustahsin Adib, Martin Sommer, and Alexander Sinitskii. "UV-Light-Tunable p-/n-Type Chemiresistive Gas Sensors Based on Quasi-1D TiS3 Nanoribbons: Detection of Isopropanol at ppm Concentrations." Sensors 22, no. 24 (December 14, 2022): 9815. http://dx.doi.org/10.3390/s22249815.

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The growing demand of society for gas sensors for energy-efficient environmental sensing stimulates studies of new electronic materials. Here, we investigated quasi-one-dimensional titanium trisulfide (TiS3) crystals for possible applications in chemiresistors and on-chip multisensor arrays. TiS3 nanoribbons were placed as a mat over a multielectrode chip to form an array of chemiresistive gas sensors. These sensors were exposed to isopropanol as a model analyte, which was mixed with air at low concentrations of 1–100 ppm that are below the Occupational Safety and Health Administration (OSHA) permissible exposure limit. The tests were performed at room temperature (RT), as well as with heating up to 110 °C, and under an ultraviolet (UV) radiation at λ = 345 nm. We found that the RT/UV conditions result in a n-type chemiresistive response to isopropanol, which seems to be governed by its redox reactions with chemisorbed oxygen species. In contrast, the RT conditions without a UV exposure produced a p-type response that is possibly caused by the enhancement of the electron transport scattering due to the analyte adsorption. By analyzing the vector signal from the entire on-chip multisensor array, we could distinguish isopropanol from benzene, both of which produced similar responses on individual sensors. We found that the heating up to 110 °C reduces both the sensitivity and selectivity of the sensor array.

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31

Talib, Mohammad, Nishant Tripathi, Samrah Manzoor, Prachi Sharma, Vladimir Pavelyev, Valentyn S. Volkov, Aleksey V. Arsenin, Sergey M. Novikov, and Prabhash Mishra. "TiS3 Nanoribbons: A Novel Material for Ultra-Sensitive Photodetection across Extreme Temperature Ranges." Sensors 23, no. 10 (May 21, 2023): 4948. http://dx.doi.org/10.3390/s23104948.

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Photodetectors that can operate over a wide range of temperatures, from cryogenic to elevated temperatures, are crucial for a variety of modern scientific fields, including aerospace, high-energy science, and astro-particle science. In this study, we investigate the temperature-dependent photodetection properties of titanium trisulfide (TiS3)- in order to develop high-performance photodetectors that can operate across a wide range of temperatures (77 K–543 K). We fabricate a solid-state photodetector using the dielectrophoresis technique, which demonstrates a quick response (response/recovery time ~0.093 s) and high performance over a wide range of temperatures. Specifically, the photodetector exhibits a very high photocurrent (6.95 × 10−5 A), photoresponsivity (1.624 × 108 A/W), quantum efficiency (3.3 × 108 A/W·nm), and detectivity (4.328 × 1015 Jones) for a 617 nm wavelength of light with a very weak intensity (~1.0 × 10−5 W/cm2). The developed photodetector also shows a very high device ON/OFF ratio (~32). Prior to fabrication, the TiS3 nanoribbons were synthesized using the chemical vapor technique and characterized according to their morphology, structure, stability, and electronic and optoelectronic properties; this was performed using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA), and a UV–Visible–NIR spectrophotometer. We anticipate that this novel solid-state photodetector will have broad applications in modern optoelectronic devices.

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32

Aierken, Yierpan, Deniz Çakır, and Francois M. Peeters. "Strain enhancement of acoustic phonon limited mobility in monolayer TiS3." Physical Chemistry Chemical Physics 18, no. 21 (2016): 14434–41. http://dx.doi.org/10.1039/c6cp01809b.

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33

Papadopoulos, Nikos, Eduardo Flores, Kenji Watanabe, Takashi Taniguchi, Jose R. Ares, Carlos Sanchez, Isabel J. Ferrer, Andres Castellanos-Gomez, Gary A. Steele, and Herre S. J. van der Zant. "Multi-terminal electronic transport in boron nitride encapsulated TiS3 nanosheets." 2D Materials 7, no. 1 (November 4, 2019): 015009. http://dx.doi.org/10.1088/2053-1583/ab4ef3.

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34

Gorlova, I. G., and V. Ya Pokrovskii. "Collective conduction mechanism in a quasi-one-dimensional TiS3 compound." JETP Letters 90, no. 4 (October 2009): 295–98. http://dx.doi.org/10.1134/s0021364009160140.

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35

El-Sayed, M. A., N. V. Doroshina, D. I. Yakubovsky, P. Mishra, and A. V. Syuy. "Laser Etching of Quasi-1D TiS3 Nanoribbons by Raman Spectrophotometer." Bulletin of the Russian Academy of Sciences: Physics 86, S1 (December 2022): S135—S140. http://dx.doi.org/10.3103/s1062873822700551.

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36

Molina-Mendoza, Aday J., Mariam Barawi, Robert Biele, Eduardo Flores, José R. Ares, Carlos Sánchez, Gabino Rubio-Bollinger, et al. "Electronic Bandgap and Exciton Binding Energy of Layered Semiconductor TiS3." Advanced Electronic Materials 1, no. 9 (July 15, 2015): 1500126. http://dx.doi.org/10.1002/aelm.201500126.

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37

Molina-Mendoza, Aday J., Mariam Barawi, Robert Biele, Eduardo Flores, José R. Ares, Carlos Sánchez, Gabino Rubio-Bollinger, et al. "Electronic Bandgap and Exciton Binding Energy of Layered Semiconductor TiS3." Advanced Electronic Materials 1, no. 11 (November 2015): n/a. http://dx.doi.org/10.1002/aelm.201500332.

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38

Hawkins, Casey G., and Luisa Whittaker-Brooks. "Controlling Sulfur Vacancies in TiS2–x Cathode Insertion Hosts via the Conversion of TiS3 Nanobelts for Energy-Storage Applications." ACS Applied Nano Materials 1, no. 2 (January 31, 2018): 851–59. http://dx.doi.org/10.1021/acsanm.7b00266.

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39

Rocca, Riccardo, Mauro Francesco Sgroi, Bruno Camino, Maddalena D’Amore, and Anna Maria Ferrari. "Disordered Rock-Salt Type Li2TiS3 as Novel Cathode for LIBs: A Computational Point of View." Nanomaterials 12, no. 11 (May 27, 2022): 1832. http://dx.doi.org/10.3390/nano12111832.

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The development of high-energy cathode materials for lithium-ion batteries with low content of critical raw materials, such as cobalt and nickel, plays a key role in the progress of lithium-ion batteries technology. In recent works, a novel and promising family of lithium-rich sulfides has received attention. Among the possible structures and arrangement, cubic disordered Li2TiS3 has shown interesting properties, also for the formulation of new cell for all-solid-state batteries. In this work, a computational approach based on DFT hybrid Hamiltonian, localized basis functions and the use of the periodic CRYSTAL code, has been set up. The main goal of the present study is to determine accurate structural, electronic, and spectroscopic properties for this class of materials. Li2TiS3 precursors as Li2S, TiS2, and TiS3 alongside other formulations and structures such as LiTiS2 and monoclinic Li2TiS3 have been selected as benchmark systems and used to build up a consistent and robust predictive scheme. Raman spectra, XRD patterns, electronic band structures, and density of states have been simulated and compared to available literature data. Disordered rock-salt type Li2TiS3 structures have been derived via a solid solution method as implemented into the CRYSTAL code. Representative structures were extensively characterized through the calculations of their electronic and vibrational properties. Furthermore, the correlation between structure and Raman fingerprint was established.

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40

ГОРЛОВА, И. Г., А. В. ФРОЛОВ, А. П. ОРЛОВ, В. Я. ПОКРОВСКИЙ та ВУ ПАЙ ВОЕЙ. "ЭФФЕКТ ПОЛЯ В ЛИНЕЙНОЙ И НЕЛИНЕЙНОЙ ПРОВОДИМОСТИ СЛОИСТОГО КВАЗИОДНОМЕРНОГО ПОЛУПРОВОДНИКА TIS3". ПИСЬМА В ЖУРНАЛ ЭКСПЕРИМЕНТАЛЬНОЙ И ТЕОРЕТИЧЕСКОЙ ФИЗИКИ 110, № 5-6(9) (2019): 400–406. http://dx.doi.org/10.1134/s0370274x19180097.

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41

Silva-Guillén, J. A., E. Canadell, F. Guinea, and R. Roldán. "Strain Tuning of the Anisotropy in the Optoelectronic Properties of TiS3." ACS Photonics 5, no. 8 (June 6, 2018): 3231–37. http://dx.doi.org/10.1021/acsphotonics.8b00467.

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42

Pawbake, Amit S., Joshua O. Island, Eduardo Flores, Jose Ramon Ares, Carlos Sanchez, Isabel J. Ferrer, Sandesh R. Jadkar, Herre S. J. van der Zant, Andres Castellanos-Gomez, and Dattatray J. Late. "Temperature-Dependent Raman Spectroscopy of Titanium Trisulfide (TiS3) Nanoribbons and Nanosheets." ACS Applied Materials & Interfaces 7, no. 43 (October 22, 2015): 24185–90. http://dx.doi.org/10.1021/acsami.5b07492.

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43

Lipatov, Alexey, Michael J. Loes, Haidong Lu, Jun Dai, Piotr Patoka, Nataliia S. Vorobeva, Dmitry S. Muratov, et al. "Quasi-1D TiS3 Nanoribbons: Mechanical Exfoliation and Thickness-Dependent Raman Spectroscopy." ACS Nano 12, no. 12 (November 30, 2018): 12713–20. http://dx.doi.org/10.1021/acsnano.8b07703.

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44

Randle, Michael, Alexey Lipatov, Avinash Kumar, Chun-Pui Kwan, Jubin Nathawat, Bilal Barut, Shenchu Yin, et al. "Gate-Controlled Metal–Insulator Transition in TiS3 Nanowire Field-Effect Transistors." ACS Nano 13, no. 1 (December 26, 2018): 803–11. http://dx.doi.org/10.1021/acsnano.8b08260.

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45

Bolotina, N. B., I. G. Gorlova, I. A. Verin, A. N. Titov, and A. V. Arakcheeva. "Defect structure of TiS3 single crystals of the A-ZrSe3 type." Crystallography Reports 61, no. 6 (November 2016): 923–30. http://dx.doi.org/10.1134/s1063774516060055.

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46

Gorlova, I. G., V. Ya Pokrovskii, S. G. Zybtsev, A. N. Titov, and V. N. Timofeev. "Features of the conductivity of the quasi-one-dimensional compound TiS3." Journal of Experimental and Theoretical Physics 111, no. 2 (August 2010): 298–303. http://dx.doi.org/10.1134/s1063776110080248.

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47

Barawi, M., E. Flores, I. J. Ferrer, J. R. Ares, and C. Sánchez. "Titanium trisulphide (TiS3) nanoribbons for easy hydrogen photogeneration under visible light." Journal of Materials Chemistry A 3, no. 15 (2015): 7959–65. http://dx.doi.org/10.1039/c5ta00192g.

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48

Sakuma, Tasuku, Shunsuke Nishino, Masanobu Miyata, and Mikio Koyano. "Thermoelectric Properties for a Suspended Microribbon of Quasi-One-Dimensional TiS3." Journal of Electronic Materials 47, no. 6 (February 2, 2018): 3177–83. http://dx.doi.org/10.1007/s11664-018-6086-z.

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49

Lian, Zhen, Zeyu Jiang, Tianmeng Wang, Mark Blei, Ying Qin, Morris Washington, Toh-Ming Lu, Sefaattin Tongay, Shengbai Zhang, and Su-Fei Shi. "Anisotropic band structure of TiS3 nanoribbon revealed by polarized photocurrent spectroscopy." Applied Physics Letters 117, no. 7 (August 17, 2020): 073101. http://dx.doi.org/10.1063/5.0019828.

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50

Liu, Sijie, Wenbo Xiao, Mianzeng Zhong, Longfei Pan, Xiaoting Wang, Hui-Xiong Deng, Jian Liu, Jingbo Li, and Zhongming Wei. "Highly polarization sensitive photodetectors based on quasi-1D titanium trisulfide (TiS3)." Nanotechnology 29, no. 18 (March 8, 2018): 184002. http://dx.doi.org/10.1088/1361-6528/aaafa2.

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