Добірка наукової літератури з теми "Thermoresponsivity"
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Статті в журналах з теми "Thermoresponsivity"
Pineda-Contreras, Beatriz A., Holger Schmalz, and Seema Agarwal. "pH dependent thermoresponsive behavior of acrylamide–acrylonitrile UCST-type copolymers in aqueous media." Polymer Chemistry 7, no. 10 (2016): 1979–86. http://dx.doi.org/10.1039/c6py00162a.
Повний текст джерелаLi, Yinwen, Huilong Guo, Yunfei Zhang, Jian Zheng, Jianqun Gan, Xiaoxiao Guan, and Mangeng Lu. "Pseudo-graft polymer based on adamantyl-terminated poly(oligo(ethylene glycol) methacrylate) and homopolymer with cyclodextrin as pendant: its thermoresponsivity through polymeric self-assembly and host–guest inclusion complexation." RSC Adv. 4, no. 34 (2014): 17768–79. http://dx.doi.org/10.1039/c3ra47861k.
Повний текст джерелаAmemori, Shogo, Kazuya Iseda, Shizuka Anan, Toshikazu Ono, Kenta Kokado, and Kazuki Sada. "Thermoresponsivity of polymer solution derived from a self-attractive urea unit and a self-repulsive lipophilic ion unit." Polymer Chemistry 8, no. 26 (2017): 3921–25. http://dx.doi.org/10.1039/c7py00591a.
Повний текст джерелаZhang, Hongcan, Jian Zhang, Wenxue Dai, and Youliang Zhao. "Facile synthesis of thermo-, pH-, CO2- and oxidation-responsive poly(amido thioether)s with tunable LCST and UCST behaviors." Polymer Chemistry 8, no. 37 (2017): 5749–60. http://dx.doi.org/10.1039/c7py01351e.
Повний текст джерелаFischer, Thorsten, Dan E. Demco, Radu Fechete, Martin Möller, and Smriti Singh. "Poly(vinylamine-co-N-isopropylacrylamide) linear polymer and hydrogels with tuned thermoresponsivity." Soft Matter 16, no. 28 (2020): 6549–62. http://dx.doi.org/10.1039/d0sm00408a.
Повний текст джерелаCazares-Cortes, Esther, Benjamin C. Baker, Kana Nishimori, Makoto Ouchi, and François Tournilhac. "Polymethacrylic Acid Shows Thermoresponsivity in an Organic Solvent." Macromolecules 52, no. 15 (August 2019): 5995–6004. http://dx.doi.org/10.1021/acs.macromol.9b00412.
Повний текст джерелаLiu, Fangyao, and Seema Agarwal. "Thermoresponsive Gold Nanoparticles with Positive UCST-Type Thermoresponsivity." Macromolecular Chemistry and Physics 216, no. 4 (December 18, 2014): 460–65. http://dx.doi.org/10.1002/macp.201400497.
Повний текст джерелаMarsili, Lorenzo, Michele Dal Bo, Federico Berti, and Giuseppe Toffoli. "Chitosan-Based Biocompatible Copolymers for Thermoresponsive Drug Delivery Systems: On the Development of a Standardization System." Pharmaceutics 13, no. 11 (November 5, 2021): 1876. http://dx.doi.org/10.3390/pharmaceutics13111876.
Повний текст джерелаBurova, Tatiana V., Valerij Y. Grinberg, Natalia V. Grinberg, Alexander S. Dubovik, Alexander P. Moskalets, Vladimir S. Papkov, and Alexei R. Khokhlov. "Salt-Induced Thermoresponsivity of a Cationic Phosphazene Polymer in Aqueous Solutions." Macromolecules 51, no. 20 (October 2, 2018): 7964–73. http://dx.doi.org/10.1021/acs.macromol.8b01621.
Повний текст джерелаGhosh, Partha S., and Andrew D. Hamilton. "Supramolecular Dendrimers: Convenient Synthesis by Programmed Self-Assembly and Tunable Thermoresponsivity." Chemistry - A European Journal 18, no. 8 (January 20, 2012): 2361–65. http://dx.doi.org/10.1002/chem.201103051.
Повний текст джерелаДисертації з теми "Thermoresponsivity"
Glassman, Matthew James. "Synthesis, nanostructure, and mechanics of thermoresponsively tough biomaterials from artificial polypeptides." Thesis, Massachusetts Institute of Technology, 2015. http://hdl.handle.net/1721.1/101505.
Повний текст джерелаCataloged from PDF version of thesis.
Includes bibliographical references.
Artificial protein hydrogels have attracted interest as injectable fillers and scaffolds for tissue engineering and regeneration, but the same features that enable minimally-invasive implantation of these biomaterials typically make them susceptible to mechanical degradation in the tissue environment. Achieving a rapid and sufficiently large increase in gel toughness post-injection is a crucial challenge for developing load-bearing injectable implants that persist for the needed lifetime of the implant. To address these complex goals, the objective of this thesis has been to engineer physical hydrogels that shear-thin at low temperatures but responsively assemble into a nanostructured, reinforced state at body temperature. For this purpose, the thermoresponsive aggregation of poly(N-isopropylacrylamide) (PNIPAM) and elastin-like polypeptides (ELPs) was leveraged to assemble nanostructured hydrogels from dual-associative block copolymers. Hybrid protein-polymers or protein fusions were formed by fusing PNIPAM or ELPs to the termini of a soluble artificial polypeptide decorated with self-associating [alpha]-helical domains. In cold solutions, these polypeptide block copolymers formed weak, injectable gels due to helix-associations alone; upon heating to physiological temperatures, the endblocks aggregated to form a reinforcing network of close-packed micelles throughout the gel, leading to over a 10-fold increase in elastic modulus and over 10³-fold increase in the longest stress relaxation time. Micelle packing and morphology could be tuned by endblock chemistry and block architecture, allowing for orthogonal control of gel viscoelasticity over timescales separated by four orders of magnitude. Furthermore, through the discovery of a new gelation mechanism for ELPs, simple but tough hydrogels were engineered and explored as biocompatible substrates for tissue engineering. Unlike solutions of other ELPs that have been studied extensively for decades, ELPs that have an alanine mutation in the third position of the repeat unit (i.e. VPAVG) were found to undergo arrested phase separation upon heating when formulated above a critical concentration. Solidification resulted in a bicontinuous, nanoscale network that could be manipulated by ELP design. Critically, this reversible mechanism produced extremely stiff physical gels with a relaxation time greater than 10³ seconds and shear moduli almost 10 MPa, nearly that of natural rubber despite consisting of 70% water. These ELPs were chain-extended via reversible coupling of terminal cysteine residues, leading to oxidatively-responsive increases in gel extensibility and overall toughness. Biofunctionalized gels maintained the viability of mesenchymal stem cells and chondrocytes in 2D and 3D, respectively, making these simple gel formulations a promising platform for biomedical applications. Ultimately, through controlled macromolecular synthesis and functionalization, combined with a fundamental understanding of the structure and mechanics of these new materials, this thesis has led to the development of responsively tough biomaterials that are promising for long-term performance under physiological conditions.
by Matthew James Glassman.
Ph. D.
Частини книг з теми "Thermoresponsivity"
Iwasaki, Yasuhiko. "Modern Synthesis and Thermoresponsivity of Polyphosphoesters." In Biomedical Engineering - Frontiers and Challenges. InTech, 2011. http://dx.doi.org/10.5772/18538.
Повний текст джерела