Дисертації з теми "Strontium (Sr)"
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El, Meknassi Sofia. "Enregistrement des isotopes du Sr dans les coquilles et l'eau de mer côtière : réévaluation multi-échelles du cycle du Sr pour des implications paléoenvironnementales et chimiostratigraphiques." Thesis, Toulouse 3, 2019. http://www.theses.fr/2019TOU30200.
Повний текст джерелаPast reconstructions of the isotopic Sr composition (87Sr / 86Sr) of marine carbonate skeletons (MCS) are very widely used by chemostratigraphs and palaeoenvironmentalists because they allow to reconstruct variations of the 87Sr/86Sr ratio of the ocean across geological time. Paleoenvironmental reconstructions and chemostratigraphic dating are based on the consensus that MCS precipitate their carbonate skeletons at the isotopic equilibrium with surrounded seawater, that is considered as homogeneous at global scale due to a residence time of Sr (2 Ma) higher than the global ocean mixing duration(1600 years). Their reliability as chemostratigraphic tools can therefore be questioned, in particular because no formal evaluation of biological and environmental biases has been carried out at a global scale. This study proposes a global reassessment of the Sr isotopic composition of both MCS and seawater of coastal and oligotrophic environments. The isotopic signature of MCS and coastal water is largely influenced by continental inputs that can modify their isotopic signatures. In fact, given these heterogeneities, this study has recalculated the Sr residence time. Finally, this study propose a better understanding of the global strontium cycle at different time scale
Dennebouy, Stéphane. "Mise en évidence et caractérisation de la variabilité haute fréquence du rapport 87 Sr / 86 Sr du strontium océanique." Paris, ENMP, 2001. http://www.theses.fr/2001ENMP1102.
Повний текст джерелаDennebouy, Stéphane. "Mise en évidence et caractérisation de la variabilité haute fréquence du rapport ⁸⁷Sr : ⁸⁶Sr du strontium océanique /." Paris : École des mines de Paris, Centre de géotechnique et d'exploitation du sous-sol - sédimentologie, 2002. http://catalogue.bnf.fr/ark:/12148/cb391803290.
Повний текст джерелаAvila, Teresa D. "Seafloor weathering and the Middle to Late Ordovician seawater 87Sr/86Sr inflection point preserved in conodont apatite." The Ohio State University, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=osu1565961269717394.
Повний текст джерелаBorkar, Hemant. "Texture and microstructure on magnesium-magnase-strontium (Mg-Mn-Sr) extrusion alloys." Thesis, McGill University, 2013. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=114461.
Повний текст джерелаLes alliages de magnésium pour l'extrusion ont reçu une attention toute particulière au cours des dernières années pour ce qui a trait aux applications automobiles étant donné leur potentiel pour la réduction de poids. L'alliage de Mg-1%Mn (M1) offre une bonne formabilité, cependant, la faible résistance offerte par cet alliage est un problème majeur. L'extrusion des alliages de magnésium démontre une texture finale avec des plans de base alignés avec l'axe d'extrusion qui ainsi résulte dans une asymétrie des propriétés de tension et de compression. Il a été démontré expérimentalement que des additions de terres rares telles que Ce et Nd aux alliages de magnésium affaiblissent la texture et améliorent la formabilité pour l'extrusion et le laminage. Le strontium (Sr) qui est un affineur de grains utile possède un diagramme de phase similaire aux autres éléments des terres rares et est présumé avoir le même effet dans les alliages de Mg-Mn. Ce travail de recherche a été orienté vèrs le développement de nouvelles compositions d'alliages de magnésium basées sur le système Mg-Sr. L'objectif de ce projet a été d'analyser l'effet du Sr sur le comportement des alliages lors de l'extrusion et les propriétées des alliages de Mg-1Mn. Cet effet a été étudié par l'analyse de la microstructure et l'évolution de la texture lors de l'extrusion des échantillons d'alliages Mg-Mn-Sr et par la détection du rôle des précipités dans les mécanismes de recristallisation dynamique lors de l'extrusion. Ce travail a été suivi par l'étude de l'effet des additions de strontium sur les caractéristiques de la déformation à chaud et l'évolution de la texture de l'alliage Mg-1Mn (M1). Ceci a été analysé par la réalisation d'essais de compression à chaud effectués à 400 ºC et à une vitesse d'allongement de 0.1mm/s. La texture de l'alliage M1 après l'essai de compression à chaud était de type basale mais affaiblie lors de l'augmentation des additions de Sr.Dans la seconde partie de ce travail de recherche, l'effet de l'addition de Sr jusqu'à 2% poids sur la texture et sur les propriétées mécaniques de l'alliage M1 après extrusion a été étudié. L'extrusion a été effectuée à une température de 350 ºC. Les alliages M1-Sr ont montré un affaiblissement de la texture par le développement de composés avec une texture aléatoire lors de l'extrusion. La variation aléatoire de la texture a été attribuée à la stimulation des particules de nucléation autour des composés intermétalliques Mg-Sr au cours de la recristallisation. Les compositions M1-Sr ont été celles qui ont montré une augmentation de la force de résistance et aussi de la ductilité ainsi que la réduction du cédage asymétrique. Dans la dernière partie de cette étude l'effet de la température d'extrusion sur l'évolution de la texture et la recristallisation des alliages M1 et M1-1.6Sr a été analysé. L'alliage M1 a montré une texture plus faible après l'extrusion à 300 ºC, mais a développé une structure basale forte à 350 et 400 ºC. L'alliage M1-1.6Sr a développé des textures plus faibles à toutes les températures d'extrusion et ceci a donné comme résultat une formation préférentielle de PSN à cause des composés intermétalliques Mg-Sr qui ont formé des grains avec des orientations aléatoires.Dans la dernière partie de l'étude, l'effet des paramètres d'extrusion sur évolution de la texture, recristallisation et les propriétés mécaniques des alliages extrudés a été analysée. M1-Sr alliages eu les plus faibles, des textures résistance améliorée, une plus grande ductilité et un rendement réduit l'asymétrie. La dernière tâche de cette phase était l'extrusion industrielle des alliages M1-Sr à l'usine d'extrusion du partenaire industriel au Mexique.Les compositions d'alliage optimales dans les deux cas (l'échelle du laboratoire et industriel) étaient les mêmes à 350 °C i.e, Mg-1Mn-2.1Sr.
Ward, Brittany Marie. "Reconstruction of Holocene coupling between the South America Monsoon System and local moisture variability from speleothem δ¹⁸O and ⁸⁷Sr/⁸⁶Sr records:". Thesis, Boston College, 2018. http://hdl.handle.net/2345/bc-ir:108373.
Повний текст джерелаInvestigating controls on past variability of South American hydroclimate is critical to assessing its response to future warming scenarios. δ¹⁸O records from South America offer insight into past variability of the South American Monsoon System (SAMS). The controls on precipitation δ¹⁸O values, however, can be decoupled from precipitation amount and thereby limit investigations of variability in local moisture conditions. Here we use a principle components analysis to assess the coherence of speleothem and lake core Holocene δ¹⁸O records in tropical South America to evaluate the extent to which δ¹⁸O variability reflects changes in SAMS intensity at different sites across the region. The main mode of variability across Holocene δ¹⁸O records (PC1) closely tracks austral summertime insolation, consistent with existing work. PC1 is strongly expressed at sites towards the periphery of the continent, while variability at interior sites bear little similarity that implicates controls, in addition to monsoon intensity, on these δ¹⁸O records. Further, we develop speleothem ⁸⁷Sr/⁸⁶Sr records spanning the Holocene from Tamboril Cave (Brazilian Highlands), Paraíso Cave (eastern Amazon Basin), Jaraguá Cave (Mato Grosso Plateau), and Botuverá Cave (Atlantic coastal plain) to investigate coupling between reconstructed monsoon variability and local moisture conditions. Speleothem ⁸⁷Sr/⁸⁶Sr variability is interpreted as a proxy of local moisture conditions, reflecting the degree of water-rock interaction with the cave host rock as driven by variations in water residence time. Speleothem ⁸⁷Sr/⁸⁶Sr records from all the sites, except Botuverá cave, do not co-vary with PC1, suggesting that local moisture conditions do not necessary follow variations in monsoon intensity at these interior sites. These speleothem ⁸⁷Sr/⁸⁶Sr records, however, generally suggest dry mid-Holocene conditions, consistent with interpretations of other paleo-moisture records in the region. These results highlight that dynamics, in addition to SAMS variability, might influence δ¹⁸O variability as well as local moisture conditions at interior sites, and highlight the need for δ¹⁸O-independent reconstructions of moisture conditions
Thesis (MS) — Boston College, 2018
Submitted to: Boston College. Graduate School of Arts and Sciences
Discipline: Earth and Environmental Sciences
Porter, Courtney. "Solute Inputs to Soil and Stream Waters in a Seasonally Snow-Covered Mountain Catchment Determined Using Ge/Si, ⁸⁷SR/⁸⁶SR and Major Ion Chemistry: Valles Caldera, New Mexico." Thesis, The University of Arizona, 2012. http://hdl.handle.net/10150/265377.
Повний текст джерелаBouchard, Laurianne. "Rb-Sr Age Estimates of Pore Fluids in Sedimentary Rocks, DGR Site, Kincardine, Ontario." Thesis, Université d'Ottawa / University of Ottawa, 2015. http://hdl.handle.net/10393/32271.
Повний текст джерелаHerman, Staci. "Isolation and Fate of Sr-90 in a High-Calcium, Post-Detonation Matrices." University of Cincinnati / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1554121065195439.
Повний текст джерелаMARTINELLI, ANTONIO E. "Efeito da adicao de chumbo na formacao de fases supercondutoras em ceramicas de Bi-Sr-Ca-Cu-O." reponame:Repositório Institucional do IPEN, 1991. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10260.
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Dissertacao (Mestrado)
IPEN/D
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
Zattoni, Ana Paula. "Separation and analysis of Sr-90 and Zr-90 for nuclear forensic applications." Master's thesis, Université Laval, 2015. http://hdl.handle.net/20.500.11794/26052.
Повний текст джерелаIn this work, a technological development to determine the age of radioactive strontium sources through the [Zr-90]/[Sr-90] ratio using mass spectrometry and liquid scintillation to quantify both isotopes is presented. Because Sr-90 and Zr-90 are isobaric interferences in mass spectrometry, a radiochemical separation to isolate Zr-90 has been shown to be mandatory prior to analysis. Four commercial resins (AG50W-X9, Dowex1-X8, Sr and DGA resins) were tested to isolate Zr-90 from Sr-90. Best performance was observed for the DGA resin, including recoveries higher than 99% for Zr-90. DGA has also demonstrated to be the faster approach and the most efficient not only to eliminate isobaric interferences from Sr-90, but also from Y-90, potentially present in samples containing high levels of radioactivity. Experiments using a collision cell to eliminate isobaric interferences in a triple quadrupole mass spectrometer (ICP-QQQMS) have also been carried out, but results have demonstrated insufficient decontamination factors for nuclear forensic applications.
Wise, Peter Leonard. "Structure-microwave dielectric property relations in Sr and Ca titanates." Thesis, University of Sheffield, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.391169.
Повний текст джерелаAl-Nasri, Salam Khudhair Abdullah. "Treatment of wastewater containing cobalt (Co-59) and strontium (Sr-89) as a model to remove radioactive Co-60 and Sr-90 using hierarchical structures incorporating zeolites." Thesis, University of Manchester, 2015. https://www.research.manchester.ac.uk/portal/en/theses/treatment-of-wastewater-containing-cobalt-co59-and-strontium-sr89-as-a-model-to-remove-radioactive-co60-and-sr90-using-hierarchical-structures-incorporating-zeolitesa(ff5cff3e-1366-4a35-9b15-0246811d6ad1).html.
Повний текст джерелаBUSTAMANTE, ANDREA N. P. "Yb sup3+:Sr sub5(VOsub4)sub3 F .Crescimento, caracterizacao espectroscopica e desenvolvimento do laser." reponame:Repositório Institucional do IPEN, 1999. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10732.
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Tese(Doutoramento)
IPEN/T
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
Umholtz, Nicholas Moehle. "Middle to Late Ordovician δ13C and 87Sr/86Sr stratigraphy in Virginia and West Virginia: implications for the timing of the Knox unconformity". The Ohio State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=osu1400681920.
Повний текст джерелаRobson, Matthew. "Statistical mechanics of the square lattice planar rotator model and metamagnetism in bilayer strontium ruthenate Sr₃Ru₂O₇." Thesis, University of Birmingham, 2018. http://etheses.bham.ac.uk//id/eprint/8072/.
Повний текст джерелаAshworth, Hollie. "Partitioning of Sr-90 and Cs-137 in nuclear fuel storage ponds." Thesis, University of Manchester, 2017. https://www.research.manchester.ac.uk/portal/en/theses/partitioning-of-sr90-and-cs137-in-nuclear-fuel-storage-ponds(8ed21ee5-009d-4cd2-813a-bebad75e7a15).html.
Повний текст джерелаVisser, Gledus. "The application of Sr-spec resin in the analysis of 90Sr in effluent and environmental samples at KNPS." Thesis, Cape Peninsula University of Technology, 2016. http://hdl.handle.net/20.500.11838/2327.
Повний текст джерелаRadiostrontium (90Sr and 89Sr) has been released to the environment by global fall-out following atmospheric nuclear explosions, by waste discharges and fall-out from the Chernobyl. 89Sr, with a half-life of 50.5 days, quickly decays to undetectable levels, while 90Sr is radiobiologically more important because of its longer half-life of 28.78 years, and because it behaves chemically similar to Ca, and accumulates in bones and teeth. Cost effective and relatively simple procedures for determination of radiostrontium are desirable. An accurate determination of radionuclides from various sources in the environment is essential for assessment of the potential hazards and suitable countermeasures both in case of accidents, authorised releases and routine surveillances. Reliable radiochemical separation and detection techniques are needed for accurate determination of alpha and beta emitters. Rapid analytical methods are needed in case of an accident for early decision-making. At the Koeberg Nuclear Power Station (KNPS), 90Sr analysis are performed on liquid effluent samples making use of the traditional fuming nitric acid method, and subsequent counting of particulate samples on an alpha/beta proportional counter. This method is often at times very time – consuming, and involves many precipitation steps. The use of fuming nitric acid is also very dangerous and could lead to severe personnel injuries in the event of an accident. This project focussed on the application of Sr-Spec resin in the analysis of 90Sr. This work presents the methods for 90Sr analysis for both effluent samples as well as environmental samples. This research also focussed on the calibration of the different radiometric instruments, which are the Liquid Scintillation Counter, the Alpha/Beta Counter as well as the Gamma Detector.
Warham, Joseph O. "Mapping biosphere strontium isotope ratios across major lithological boundaries. A systematic investigation of the major influences on geographic variation in the 87Sr/86Sr composition of bioavailable strontium above the Cretaceous and Jurassic rocks of England." Thesis, University of Bradford, 2011. http://hdl.handle.net/10454/5500.
Повний текст джерелаBritish Geological Survey¿s British University Funding Initiative (BUFI) and the School of Life Sciences at the University of Bradford joint funding.
Warham, Joseph Olav. "Mapping biosphere strontium isotope ratios across major lithological boundaries : a systematic investigation of the major influences on geographic variation in the 87Sr/86Sr composition of bioavailable strontium above the Cretaceous and Jurassic rocks of England." Thesis, University of Bradford, 2011. http://hdl.handle.net/10454/5500.
Повний текст джерелаChen, Xiyong. "Thermo-mechanical/structural properties and oxygen permeation behavior of mixed ionic electronic conductors La(1-x)Sr(x)CoO(3-delta) /." Thesis, Connect to this title online; UW restricted, 2007. http://hdl.handle.net/1773/9893.
Повний текст джерелаFontaine, Chantal. "Heteroepitaxie par jets moeculaires : systeme (ca,sr)f::(2) - gaas." Toulouse 3, 1987. http://www.theses.fr/1987TOU30135.
Повний текст джерелаSalas, Valero Lady Maria 1981. "Elaboração e caracterização de filmes a base de alginato de sódio, reticulados com íons bário (Ba²+), estrôncio (Sr²+) ou alumínio (Al³+)." [s.n.], 2011. http://repositorio.unicamp.br/jspui/handle/REPOSIP/256486.
Повний текст джерелаDissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia de Alimentos
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Resumo: Alginatos são polissacarídeos extraídos de algas pardas que apresentam uma grande gama de aplicações tecnológicas devido a sua conhecida habilidade em formar géis fortes, biodegradáveis e insolúveis em água ao ser reticulado com Ca2+. Biofilmes baseados nesse mecanismo podem ser confeccionados, formando estruturas transparentes e de alta resistência mecânica, mas que exigem considerável quantidade de plastificante para adequar sua flexibilidade. O objetivo deste trabalho foi desenvolver e caracterizar filmes de alginato reticulados com cátions Ba2+, Sr2+ ou Al3+ e seus atributos funcionais foram comparados aos de filmes de alginato de cálcio. Filmes de diferentes espessuras foram elaborados por casting em processo em duas etapas: um protótipo de filme foi inicialmente formado, vertendo alíquotas de uma solução aquosa contendo alginato de sódio, glicerol como agente plastificante e uma pequena quantidade de íons cálcio para promover uma pré-reticulação, em placas quadradas de acrílico e submetidas a secagem a 40°C. A reticulação destes pré-filmes foi complementada por imersão em soluções de cloreto de bário, de estrôncio ou de alumínio. Filmes com diferentes graus de reticulação, e diferentes concentrações de glicerol foram caracterizados em relação a suas propriedades, tais como: aspecto visual, conteúdo de umidade, massa solubilizada, permeabilidade ao vapor de água, intumescimento em água, resistência mecânica à tração, alongamento, observações por microscopia eletrônica de varredura, opacidade e cor. O estudo indica que o cloreto de bário é uma alternativa eficiente como agente reticulante por apresentar rápida e intensa reticulação da camada superficial dos filmes de alginato formando filmes com boas propriedades funcionais, excelente manuseabilidade, e altos valores de alongamento, porém menos transparentes. Filmes reticulados com Sr2+ apresentaram características funcionais superiores aos filmes reticulados com Ca2+ de mesma espessura, exceto quanto à permeabilidade ao vapor d¿água, que foi ligeiramente mais alta. O uso do íon trivalente Al3+, que é pequeno e lábil, como agente reticulante formou filmes densos devido à reticulação em todo o seu volume, exibindo limitados atributos funcionais, sobretudo em relação a flexibilidade, pois sua compacta estrutura tridimensional impedia a incorporação de glicerol
Abstract: Alginates are polysaccharides extracted from brown seaweeds with a large range of technological applications due to their well known ability to form strong gels that are biodegradable and insoluble in water when crosslinked with calcium ions. Films based on this mechanism can be confectioned, forming transparent structures with high mechanical resistance, but require considerable amount of plasticizers in order to become flexible. This work evaluated the development and characterization of alginate films reticulated with Ba2+, Sr2+ or Al3+ and their functional attributes were compared to films of calcium alginate. Prototypes of films with distinct thicknesses were confectioned by casting in a two-step procedure: different aliquots of an aqueous solution containing sodium alginate, glycerol as plasticizer and a small amount of calcium chloride in order to promote a weak crosslinking were poured in Plexiglas square dishes and dried at 40ºC. The crosslinking of these pre-films were further complemented by immersion in solutions containing barium, strontium or aluminum chloride. Films of different degrees of reticulation and different concentration of glycerol were characterized as to visual appearance, water content, swelling degree, soluble mass, water vapor permeability, mechanical resistance to tension and elongation, opacity, color and were also submitted to SEM observation. This investigation selects barium as an excellent alternative crosslinking agent, since it promotes a fast and intense surface reticulation producing films with good physical attributes and handling, due to their high values of elongation. Films reticulated with Sr2+ show slightly better functional properties compared to calcium alginate films of the same thickness. The use of the small and labile trivalent Al3+ ion as reticulant led to very dense structures due to its ability to crosslink the film core. The films formed, however, were brittle due to lack of flexibility, since the tight tridimensional structure hindered the incorporation of glycerol
Mestrado
Engenharia de Alimentos
Mestre em Engenharia de Alimentos
Efstathiou, Paraskevi. "Investigating Sr₁₋ₓNbO₃ for H₂ evolution and as part of systems attempting water splitting under visible light irradiation". Thesis, University of St Andrews, 2014. http://hdl.handle.net/10023/6314.
Повний текст джерелаInglês, Daniella. "ESTRUTURA E PROPRIEDADES ÓPTICAS DO SISTEMA TITANATO-ESTANATO DE ESTRÔNCIO [Sr(Ti1-xSnx)O3 x = 0; 0,25; 0,50; 0,75; 1]." UNIVERSIDADE ESTADUAL DE PONTA GROSSA, 2013. http://tede2.uepg.br/jspui/handle/prefix/2109.
Повний текст джерелаCoordenação de Aperfeiçoamento de Pessoal de Nível Superior
Titanates have perovskite crystalline structure very known for electrical and optical properties used in the electronic devices such as sensors, capacitors, nonvolatile and dynamic random access memories. In particular, titanates structures are characterized for the ABO3 formula being A crystallographic site formed by 12 atoms neighbors and B crystallographic site formed by 6 atoms neighbors. However, researches about strontium titanate-stannate system are found minimally in the literature. Articles discussing synthesis, characterization and compositions are insufficiently presented. This project shows a theoretical study of the structure and optical properties of the strontium titanate-stannate system for different substitutions [Sr(Ti1-xSnx)O3 x = 0; 0,25; 0,50; 0,75; 1]. It was used theoretical-computational methodology based on, Density Functional Theory (DFT) with B3LYP functional to calculate the structure of the models SrTiO3 (STO), Sr(Ti1-xSnx)O3 (STS) and SrSnO3 (SSO). Theoretical data of parameter lattice, cell unit angles, volume, band gap, overlap population, charges and free energy are presented as well as analysis and discussion of the results for band structure (EB), density of states (DOS), electron density maps. Thus, one may present the data obtained and investigate the properties of the materials.
Titanatos possuem estrutura cristalina perovskita muito conhecida pelas propriedades elétricas e ópticas utilizadas em dispositivos eletrônicos como sensores, capacitores, memória de acesso randômico dinâmica e não volátil. Em particular, as estruturas de titanatos são caracterizadas pela fórmula ABO3 sendo A sítio cristalográfico formado por 12 átomos vizinhos e B o sítio cristalográfico formado por 6 átomos vizinhos. No entanto, pesquisas sobre o sistema titanato-estanato de estrôncio são encontradas minimamente na literatura. Artigos que discutem a síntese, caracterização e composições são insuficientemente apresentados. Este trabalho apresenta o estudo teórico da estrutura e propriedades ópticas do sistema titanato-estanato de estrôncio para diferentes substituições [Sr(Ti1-xSnx)O3 x = 0; 0,25; 0,50; 0,75; 1]. Utilizou-se metodologia teórico-computacional baseada em, Teoria do Funcional de Densidade (DFT) com funcional B3LYP, para cálculo da estrutura dos modelos SrTiO3 (STO), Sr(Ti1-xSnx)O3 (STS) e SrSnO3 (SSO). Dados teóricos de parâmetro de rede, ângulos da célula unitária, band gap, recobrimento populacional, cargas e energia livre são apresentados como também a análise e discussão dos resultados por meio de estrutura de bandas (EB), densidade de estados (DOS), mapas de densidade eletrônica. Desta forma, podem-se apresentar os dados obtidos e investigar as propriedades dos materiais.
De, roubin Antoine. "Mass measurements of neutron-rich strontium and rubidium isotopes in the A ≈ 100 and development of an electrospray ionization ion source." Thesis, Bordeaux, 2016. http://www.theses.fr/2016BORD0426/document.
Повний текст джерелаAn extension of the atomic mass surface in the region A ≈ 100 is performed via massmeasurements of the 100-102Sr and 100-102Rb isotopes with the ion-trap mass spectrometer ISOLTRAPat CERN-ISOLDE. The first direct mass measurements of 102Sr and 101;102Rb are reported here. Thesemeasurements confirm the continuation of the region of nuclear deformation with the increase of neutronnumber, at least as far as N = 65.In order to interpret the deformation in the strontium isotopic chain and to determine whether an onsetof deformation is present in heavier krypton isotopes, a comparison is made between experimentalvalues and theoretical calculations available in the literature. To complete this comparison, Hartree-Fock-Bogoliubov calculations for even and odd isotopes are also presented, illustrating the competitionof nuclear shapes in the region.The development of an electrospray ionization ion source is presented. This source can delivera large range of isobaric masses for calibration purposes. The early commissioning of the sourceis discussed, including the results from the first mass scans detected behind the quadrupole massspectrometer. A resolution of a few atomic mass units is reached
Forsberg, Sverker. "Behaviour of ¹³⁷Cs and ⁹⁰Sr in agricultural soils : influence of ageing and soil type on availability, migration and plant uptake /." Uppsala : Swedish Univ. of Agricultural Sciences (Sveriges lantbruksuniv.), 2000. http://epsilon.slu.se/avh/2000/91-576-5735-1.pdf.
Повний текст джерелаBrazier, Jean-Michel. "Rôle des phases minérales des sols en tant que réservoirs de nutriments : approche expérimentale (abiotique), en milieu naturel et multi-isotopique (isotopes stables Ca-Sr)." Thesis, Strasbourg, 2018. http://www.theses.fr/2018STRAH005/document.
Повний текст джерелаThis PhD thesis examined the mechanisms of storage and release, from and elementary and isotopically point of view, of calcium (Ca) and strontium (Sr) onto or into mineral phases commonly encountered within soils (primary minerals, clay minerals, oxy-hydroxides, pedogenic carbonate). A robust δ88Sr measurements method had to be developed in the laboratory and validated by the measurement of international reference materials, mostly never measured in the literature. The results of this work show that Ca adsorption onto phyllosilicate minerals generates a quantifiable isotopic fractionation by preferential uptake of the light isotope (40Ca) under our experimental conditions when the minerals have a significant structural charge and specific surface area and/or an interlayer space open to hydrated cations adsorption. A study on rhizoliths in natural environment has also highlighted that the combination of Ca and Sr isotopes allows an effective tracing of sources and mechanisms in the problematic related to the storage of these two elements within soils
Amsellem, Elsa. "Le fractionnement isotopique du Ca et du Sr à haute température : apport sur la formation et l’évolution de la Terre." Thesis, Université de Paris (2019-....), 2019. https://wo.app.u-paris.fr/cgi-bin/WebObjects/TheseWeb.woa/wa/show?t=3979&f=25544.
Повний текст джерелаThe formation of the Solar System and its evolution remain poorly known despite the explosion of space exploration in the mid 20th century. Meteorites and terrestrial igneous rocks are particularly useful objects of study for gaining insights into the formation and evolution of the Earth: the former existed before the planets and the latter reflect the composition of the terrestrial mantle. For this thesis, we performed Ca, Sr and Rb isotopic analyses using MC-ICP-MS technique on a variety of terrestrial and extra-terrestrial rocks. The fractionation of Ca and Sr stable isotopes allows for tracing processes and source effects and Rb-Sr system enables us to date primordial events. Chondrules, a major component of chondrites, are analysed for Ca isotopic composition to test and confirm the pebble accretion model for the formation of the Earth. The timing of the heating event of thermally metamorphosed carbonaceous chondrites is estimated using Rb-Sr chronology and reveals the process of the event as impacts in the asteroid belt. From Earth, komatiites, OIBs and MORBs samples are analysed to estimate the Ca and Sr isotopic composition and evolution of the mantle. The stable isotopic composition of Sr in the mantle is homogenous through the evolution of the mantle while Ca isotopes reveal preservation of early heterogeneities. Carbonatites, rare igneous rocks containing 50 % of carbonate minerals, are studied for Ca isotopic composition in order to indicate their origin. We suggest that the enrichment in lighter Ca isotopes of the carbonatites compared to the bulk silicate Earth’s value derives from a contribution of recycled components through subduction in their mantle source. This thesis explores the wide applications of Ca and Sr isotopic fractionation in high temperature geochemistry
OLIVEIRA, ELAINE M. de. "Avaliacao do efeito biologico da radiacao beta do sup[90]Sr em celulas sanguineas humanas e elaboracao de curva dose resposta." reponame:Repositório Institucional do IPEN, 2000. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10815.
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Dissertacao (Mestrado)
IPEN/D
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
Potot, Cécile. "Étude hydrochimique du système aquifère de la basse vallée du Var : apport des éléments traces et des isotopes (Sr, Pb, O, Ra)." Nice, 2011. http://www.theses.fr/2011NICE4004.
Повний текст джерелаThe main goal of this study is to improve the knowledge of the Lower Var Valley aquifers, under both Mediterranean and Alpine influences. Majors, trace elements, and O, Sr and Pb isotopes have been analysed under various hydrological conditions in water of the Low Var Valley including the alluvial aquifer, the Var River, its tributaries and groundwaters from Jurassic limestones and Pliocene conglomerates, which are the substrate of alluvia. Concentrations of most majors and trace elements are often close to the natural background, which gives a baseline quality of waters. High sensitivity in trace element measurement may allow to early detect contamination in any water body. Agricultural and / or residential contaminations have been detected in limestone and above all in conglomerate groundwater. The Var River is the main source of water of the alluvial aquifer, especially in upstream part. Conglomerate groundwater inputs stand for about 20 % of alluvial water recharge, which is lower than previously estimated. The use of both major and trace elements gives evidences of high heterogeneity in conglomerate groundwater and leads to estimate the proportions of inputs to the alluvial aquifer. Recharge of the alluvial aquifer by Jurassic limestones seems to be significant. Strong influence of Triassic evaporates in most samples gives limitation to the use of strontium isotopes as tracers of water origin. Pb isotopes gave complex results, which could suggest both a natural origin and an anthropogenic one that could be related to rainwater. Radium isotopes were used to estimate the flow velocity in the alluvial aquifer. Several techniques demonstrate the analytical feasibility of this approach and despite important exchanges with aquifer matrix, the use of isotopic ratios apparently minimizes the effect of complex processes
Salgado, Souto Sergio Adrian, and Souto Sergio Adrian Salgado. "A Re-Os Geochronology and Multi Stable Isotope (C, N, S, Sr, Pb) Systematics of Source Rocks and Crude Oils from the Sonda de Campeche Petroleum System, Mexico." Diss., The University of Arizona, 2018. http://hdl.handle.net/10150/626760.
Повний текст джерелаITEPAN, NATANAEL M. "Aplicacao da tecnica de fluorescencia de raios X na marcacao com Mn, Sr e Cu, do parasitoide e do hospedeiro: Muscidifurax uniraptor Kogan e Legner, 1970 (Hymenoptera: Pteromalidae) e Musca domestica L., 1758 (Diptera: Muscidae)." reponame:Repositório Institucional do IPEN, 2003. http://repositorio.ipen.br:8080/xmlui/handle/123456789/11144.
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Tese (Doutoramento)
IPEN/T
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
Bernard, Caroline. "Synthèse hydrothermale d'oxydes La(1-x)Sr(x)MnO(3+8) et ZrO(2)-8%Y(2)O(3) sous forme de poudre et de couches minces et caractérisations." Toulouse 3, 2003. http://www.theses.fr/2003TOU30098.
Повний текст джерелаThe aim of my research work was to develop hydrothermal synthesis procedure to get powders and films of strontium doped lanthanum manganite La1-xSrxMnO3+d, (LSMO) and yttrium stabilized zirconia ZrO2-8mol% Y2O3 (YSZ) and to optimize the properties of materials with significiant ratio surface/volume. The use of hydrothermal synthesis at low temperature under homogeneous pressure appeared recently. For the synthesis of powders, first we defined the parameters leading to single phased un-doped manganite samples. We investigated the crystallization stage of the amorphous powder resulting from the hydrothermal synthesis by W. A. X. S. . We also characterized some physical properties by internal friction technique. For LSMO, the procedure was developped involving the methodology of experimental research. This choice is positive, because we obtain the oxide wished after two plans experimentation originals. We optimized the hydrothermal synthesis and characterized 8 mol % Y2O3 stabilized zirconia. In the second time, we investigated the deposition of films: YSZ layers on polycristalline aAl2O3 and LaMnO3+d substrates; LaMnO3+d layers on polycristalline aAl2O3, YSZ and Mn doped YSZ supports. We obtained covering layers but ould not avoid the formation of cracks
Hammouche, Abderrezak. "Contribution à l'étude de La(1-x)Sr(x)MnO3 comme matériau d'électrode à oxygène à haute température." Grenoble INPG, 1989. http://www.theses.fr/1989INPG0075.
Повний текст джерелаKazakov, Serguei. "A la recherche de nouveaux supraconducteurs à haute température critique dans le système Sr-K-Bi-O." Université Joseph Fourier (Grenoble), 1998. http://www.theses.fr/1998GRE10169.
Повний текст джерелаHajj, Fadi. "Utilisation des isotopes stables et radiogéniques du strontium pour tracer la provenance des bois : application à des épaves sous-marines." Thesis, Université de Lorraine, 2017. http://www.theses.fr/2017LORR0334.
Повний текст джерелаIn the Early Modern Age (16th - 18th centuries), the construction of ocean-going ships was paramount to the development of cultural encounters in what became the Age of Discovery and European expansion. Spain was one of the biggest forces of that time. The European project “ForSEAdiscovery” seeks answers in this context to the following key questions: Could Spanish forest resources sustain the increasing demand of timber, or were the wood imported from elsewhere? If Spanish forests were not the only wood supplier, how were the trade networks organized? This project will address these questions through a multidisciplinary and innovative training research program to improve the understanding of our historical past, our cultural heritage, and our knowledge of the use of resources for shipbuilding. The objective of this PhD thesis, taking part of this project, is to identify the provenance of the Iberian shipbuilding wood using geochemical tracers. The hypothesis is that trees growing on contrasted rocks and soils have specific geochemical signatures, which can be an indicator of geographic provenance. In this context, the Sr isotopic signature (87Sr/86Sr) was characterized in shipwreck wood samples and wood from living trees, soils and rocks collected from the Spanish forest stands indicated as potential source of wood between the 16th - 18th centuries. The δ88/86Sr signatures were also characterized in the samples. The rock types and ages were characterized at the selected sites and the link between the 87Sr/86Sr and δ88/86Sr in rocks, soils and trees was studied on the sampled Spanish sites. The local signature of Spanish potential sites was determined for provenance of wood. Our results indicate that 87Sr/86Sr isotope ratios in trees reflect the signature of the corresponding soil exchangeable pool while δ88/86Sr was shown to be affected by mass-dependent fractionation with trees taking up lighter (86Sr) isotopes, leaving the soil exchangeable pool enriched with the heavier isotopes (88Sr). This fractionation observed for oak trees, was not found in pines suggesting that the isotopic fractionation during tree uptake is species dependent. The contamination of wood from shipwrecks by seawater elements was identified. Marine Sr was found to be adsorbed on the wood or included in the precipitated minerals in the waterlogged wood. Several extraction experiments were tested and an adapted protocol was developed to extract the seawater elements and retrieve the original signature of the archaeological wood. We succeeded to validate an extraction protocol and retrieve the original signature of one wood sample. This result underline the potential and importance of a new method combining 87Sr/86Sr and δ88/86Sr values for future provenance studies on wood or other materials. However, our results also indicated that most of our shipwreck wood samples did not conserve their original Sr. Therefore, preconizations were suggested in order to extend the use of this tracer in future provenance studies on archaeological wood from shipwrecks
MURAKAMI, DANIELLA. "Efeitos das radiacoes gama (sup 60 Co) e beta (sup 90 Sr) em celulas de ovario de hamster chines (CHO-K1): inducao de micronucleos e morte celular." reponame:Repositório Institucional do IPEN, 2003. http://repositorio.ipen.br:8080/xmlui/handle/123456789/11113.
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Dissertacao (Mestrado)
IPEN/D
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
Vella, Virginie. "Les chronomètres U-Pb, Rb-Sr, K-Ar appliqués à l'évolution d'un gisement uranifère en milieu sédimentaire : cas du bassin permien de Lodève (Hérault)." Montpellier 2, 1989. http://www.theses.fr/1989MON20154.
Повний текст джерелаBARRIO, GRACIELA. "Desenvolvimento de tecnologias de preparo de geradores de sup(90)Sr/sup(90)Y na Diretoria de Radiofarmacia do IPEN/CNEN-SP." reponame:Repositório Institucional do IPEN, 2010. http://repositorio.ipen.br:8080/xmlui/handle/123456789/9600.
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Dissertacao (Mestrado)
IPEN/D
Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP
Heidinger, Bertrand. "Synthèse par broyage réactif de perovskites (La,Sr,Ce)(Mn,Fe,Co)O3 : Caractérisation et propriétés catalytiques dans la réaction d'oxydation totale du toluène." Thesis, Lille 1, 2019. http://www.theses.fr/2019LIL1R057.
Повний текст джерелаPerovskite ABO3 materials (A: La; B: Mn, Fe, Co) have been synthesized by an original reactive grinding method, which has the advantage of being very simple to use, inexpensive and involves little or no solvent. The synthesis was carried out in three successive steps: (i) high temperature calcination to obtain the perovskite structure from the respective single oxides; (ii) high energy grinding to reduce the size of the crystalline domain (Dc) from micrometric to nanometric level by fractionation; (iii) low energy grinding to increase the specific surface area by deagglomeration of the particles. The materials obtained after these three steps showed reduced crystallite sizes (Dc ~10-20 nm), a reasonable specific surface area (respectively 10, 19 and 20 m2·g-1 for LaMnO3,15, LaFeO3 and LaCoO3) and increased reducibility of the B site. The improvement of the textural and redox properties of materials leads to a significant improvement in catalytic performance with respect to the total oxidation reaction of toluene. The LaCoO3 composition presented the best results and this formulation was then used as the starting point for evaluating the impact of the substitution of strontium or cerium at site A: La1-xSrxCoO3 (x = 0.05-0.40) and La1-xCexCoO3 (x = 0.01-0.20). The substituted materials showed similar textural properties and catalytic properties superior to the non-substituted reference (LaCoO3), with an optimum observed for La0.8Sr0.2CoO3 and La0.99Ce0.01CoO3. For La1-xCexCoO3, only a small amount of cerium can be inserted into the structure, with a secondary CeO2 phase forming beyond and poisoning the catalyst. In the case of La1-xSrxCoO3, the incorporation of strontium is complete, inducing: (i) a localized structural disorder allowing better oxygen mobility, as well as (ii) a significant modification of cobalt reducibility, up to its total reduction at low temperature for the highest strontium contents
Castagné, Jean. "ETUDE DES PREMIERES ETAPES DE LA CROISSANCE PAR JETS MOLECULAIRES SUR LES SYSTEMES HETEROEPITAXIAUX GaAs-(Ca, Sr)F2 ET GaAs/Si." Toulouse, INSA, 1987. http://www.theses.fr/1987ISAT0025.
Повний текст джерелаRutkowski, Mitchell M. "Growth Parameter Dependence and Correlation of Native Point Defects and Dielectric Properties in BaxSr1-xTiO3 Grown by Molecular Beam Epitaxy." The Ohio State University, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=osu1366299175.
Повний текст джерелаLe, Quilleuc Meryll. "Caractérisation élémentaire et isotopique (Sr et Nd) des dépôts d'aérosols sahariens sur la marge sénégalaise : implications pour la signature géochimique des sources." Thesis, Lille 1, 2019. http://www.theses.fr/2019LIL1R075.
Повний текст джерелаMineral aerosols emitted in arid and semi-arid regions of the Earth represent an active element of the global climate system. In fact, due to their optical properties and their role in nucleation processes in the atmosphere, they have an impact on the radiative budget and the hydrological cycle. They also take part in many biogeochemical cycles in the ocean and on land through the input of micro-nutriments in regions where they are deposited. Mineral dust is also an indicator of paleo-environmental conditions changes in sedimentary archives. Mineral dust impact in the climate system depends on the amount of particles transported in the atmosphere, on their grain size distributions and on their geochemical compositions. Yet, these characteristics are often insufficiently quantified, particularly in the vast Sahara-Sahel domain (the largest source worldwide), due to the numerous emissions areas and to their intermittency. The characteristics of Saharan dust deposits are especially poorly constrained, although they are essentials to estimate the dust impact on biogeochemical cycles, to make the connection with sedimentary deposits, and to validate dust transport model outputs. A study of eolian deposits was carried out on the Senegalese coast in order to improve our knowledge of the chemical composition of mineral aerosols transported over the West African margin and of the geochemical signature of the source regions. For this purpose, a passive collector was set up in 2006 at Mbour, allowing the build up of a long continuous time series dust deposits with a sampling resolution of a week or less (down to 24h). Elemental composition (major and trace elements) of the <30µm carbonate-free, silicate fraction of 221 dust deposit samples was determined (including a two-year continuous time series between March 2013 and February 2015), as well as the Sr and Nd isotopic ratios for 63 of them. Concurrently, investigations on the sources feeding our sampling site were conducted with the help of the IDDI satellite product as well as air masses backtrajectories calculated with the HYSPLIT model. The study of the 2013-2015 continuous time series of dust deposits revealed a large variability in the chemical composition of the dust, suggesting an important diversity in the geochemistry of the contributing sources. This long time series brought to light marked seasonal changes, both in the mass flux and the chemical composition, that can be linked to changes in provenance and transporting wind systems between the dry season (winter-spring) during which aerosols are transported in the trade winds that sweep across West Africa, and the wet season (summer) when dust deposit result to some degree from the scavenging by precipitations of dust transported at high altitude in the Saharan Air Layer (SAL)
DELACARTE, VALERIE, and Daniel Vivien. "Cristallogenese et etude spectroscopique de l'aluminate de strontium lanthane sr#1#-#xla#xmg#xal#1#2#-#xo#1#9 (asl) dope nd, cr, nd-cr ou pr. Proprietes laser de l'asl : nd." Paris 6, 1994. http://www.theses.fr/1994PA066543.
Повний текст джерелаGangloff, Sophie. "Evaluation of the mechanisms of trace elements transport (Pb, Rare Earth Elements,... ) and the elemental and isotopic fractionation (Ca and Sr) at the interface water-soil-plant." Thesis, Strasbourg, 2016. http://www.theses.fr/2016STRAH002/document.
Повний текст джерелаThis work is focused on the study of a profile of soil and soil solutions collected on an experimental plot covered with spruce. All these samples come from the watershed of the Strengbach (environment - OHGE Hydrogeochimique Observatory), were sampled at different depths (5, 10, 30 and 60 cm) and during the period between 2009 and 2013. Characterizations of soil extracts by infrared spectroscopy allowed to highlight changes in the organic functional groups with depth and that these changes have a significant impact on the behaviour of the cations (major and trace) in the soil. Ultrafiltration experiments helped to identify flows of colloidal and dissolved organic carbon as well as those of the major and trace-element present in soil solutions. The joint use of isotope tracers (87Sr / 86Sr and δ44 / 40 Ca) and chemical (Rare Earth Elements) have highlighted processes taking place at the water-soil-plant interface, as the uptake by root or soil alteration
Medini, Salim. "Traçage géographique des huiles d’olive par les isotopes du Sr : développement analytique et application aux huiles AOP de Nîmes." Thesis, Aix-Marseille, 2015. http://www.theses.fr/2015AIXM4306/document.
Повний текст джерелаFor many years, an approach based on the identification of the geographical origin for food product has been implemented through the knowledge of its Sr isotopes, particularly through the analysis of 87Sr / 86Sr ratio. The objective of this thesis is to develop a similar strategy for the olive oils, from the example of PDO Nimes (Gard), in southern France. A specific methodology is necessary since the existing purification protocols of Sr revealed themselves inadequate because of viscosity, high organic load, low Sr content of this matrix In order to proceed to the analysis of the isotopic composition (IC), the first part of the study highlights the definition and validation of a specific method for the treatment of olive oils and strontium purification. The second part of the study is dedicated to expose the processes of assimilation and transfer of strontium into the olive tree. This approach, conducted through a detailed study of one of Nîmes PDO mills, demonstrated that the transfer of strontium from soils to olive tree, and within the olive tree, occurs without isotope fractionation.The last part of the manuscript studies the isotopic ratios 87Sr / 86Sr of the ten PDO olive oils of Nimes and consists in a comparison of this signature with the geological formations underlying the cultivation soils. This approach allows discussing quality of Sr isotopic tool in the geographical recognition of the olive products. The observed similarity between th IC from oils and soil allow us to conclude that, in this context of production, the Sr isotopes are a efficient tool to trace and certify the geographical origin of the oil
Pachot, Stéphanie. "Etudes structurales des composés à échelles de spins du type A14 Cu24 O[41+(delta)] (A = Sr, Ca, Ba, Nd, Y, Na, K)." Université Joseph Fourier (Grenoble), 1999. http://www.theses.fr/1999GRE10133.
Повний текст джерелаBentahila, Yasmine. "Sédimentation autour de Taiwan de 35000 ans à l'actuel : variations des sources (isotopes du Pb-Sr-Zn) et des conditions environnementales (isotopes du Cu-Zn)." Phd thesis, Université Montpellier II - Sciences et Techniques du Languedoc, 2006. http://tel.archives-ouvertes.fr/tel-00103456.
Повний текст джерелаA l'échelle des derniers 35ka, d'importantes variations isotopiques en Sr-Pb (terrigène) et en Cu-Zn (carbonate) sont enregistrées dans les échantillons du forage ODP 1202D (Bassin d'Okinawa). Les isotopes du Sr et du Pb mettent en évidence une augmentation des apports lœssiques durant la période du Younger Dryas : cette augmentation est reliée à une intensification de la mousson d'hiver, engendrant des vents plus forts provenant du continent asiatique. Parallèlement, les fractionnements isotopiques importants du Cu et du Zn enregistrés depuis 6.9ka seraient liés à l'incorporation préférentielle des isotopes légers par l'activité biologique dans la zone euphotique. Ainsi, les faibles fractionnements isotopiques mesurés dans les échantillons du Younger Dryas seraient dus à un mélange entre les eaux de surfaces et les eaux plus profondes du fait de l'intensification des vents, provoquant ainsi une homogénéisation isotopique.
Noudem, Jacques Guillaume. "Texturation des céramiques supraconductrices Bi-Pb-Sr-Ca-Cu-O par combinaison des effets du champ magnétique et de la contrainte uniaxiale à haute température." Université Joseph Fourier (Grenoble), 1995. http://www.theses.fr/1995GRE10169.
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