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1
Soloshenko, N. G., M. V. Streletskaya, M. V. Chervyakovskaya, and D. V. Kiseleva. "Implementation and experience of using methods for analyzing the isotopic composition of Sm and Nd, Rb and Sr in rock samples at the Geoanalitik Center for Collective Use." LITHOSPHERE (Russia) 24, no. 2 (May 7, 2024): 364–75. http://dx.doi.org/10.24930/1681-9004-2024-24-2-364-375.
Анотація:
Research subject. AGV-2 and BHVO-2 geochemical reference materials for studying the Sm, Nd and Rb, Sr isotope systems along with various rocks and mineral samples. Materials and Methods. An analysis of the isotopic composition of Sm, Nd and Rb, Sr was carried out using Neptune Plus and Triton Plus mass spectrometers. Aim. To implement analytical techniques for the isotopic composition of Sm and Nd, Rb, and Sr in various rock and mineral samples using two types of multicollector mass spectrometers – inductively coupled plasma NeptunePlus and thermal ionization TritonPlus (Thermo-Fisher), as well as a description of the procedure of processing experimental data and the experience in using techniques at the “Geoanalitik” shared research facilities of the IGG UB RAS for the period 2015-2023. Results. The analytical techniques implemented included (1) column chromatography using various ion-exchange resins, optimised for the ratio of labour costs/quality of analytical results; (2) the measurement of isotope ratios using two types of mass spectrometers; (3) the correction of mass bias of isotope ratios and the determination of Sm and Nd, Rb, and Sr concentrations by the isotope dilution method using 149Sm+150Nd and 85Rb+84Sr spikes. Testing of the techniques was carried out using the AGV-2 and BHVO-2 geochemical reference materials; their metrological characteristics were presented. When using TritonPlus, the reproducibility (BHVO-2, n=60) of measurements of 143Nd/144Nd, 147Sm/144Nd isotope ratios and Sm and Nd concentrations are ±0.000020, ±0.0004, ±1.3 and ±0.4, respectively; indicators of correctness of determining the ratios 143Nd/144Nd and 147Sm/144Nd – 0.001 and 0.25% and concentrations of Sm and Nd – 2%; the reproducibility (BHVO-2, n=63) of measurements of 87Sr/86Sr, 87Rb/86Sr isotope ratios and concentrations (Rb and Sr) are ±0.0025%, ±1.5%, ±2%, respectively. The uncertainty of a single measurement of the 143Nd/144Nd and 87Sr/86Sr isotope ratio, represented by the standard error of the average single measurement in the sample, does not exceed 0.0025%. Conclusions: the results obtained for the geochemical reference materials are in satisfactory agreement with those provided in the GeoReM database, as well as with the certified values provided by the United States Geological Survey (USGS). The described analytical techniques are used at the “Geoanalitik” shared research facilities of the IGG UB RAS to analyse various rock and mineral samples. The work presents a number of experimental results obtained, which are subsequently used in geochronological applications.
2
Chervyakovskaya, M. V., and V. S. Chervyakovskiy. "Determination of Sm/Nd and Sr isotopic composition using an ICP-MS Neptune Plus equipped with an NWR 213 attachment for laser ablation." LITHOSPHERE (Russia) 21, no. 5 (October 31, 2021): 712–23. http://dx.doi.org/10.24930/1681-9004-2021-21-5-712-723.
Анотація:
Research subject. The Sm/Nd isotope system was investigated using inter-laboratory natural samples of apatite, titanite, allanite, monazite, as well as intra-laboratory samples of apatite (from carbonatites, Ilmenogorsk massif, Ural), monazite (from pegmatites of the Aduy granite massif and its framing, Middle Urals) and titanite (from calcite veins, Saranov skoye chromite deposit, Middle Urals and from alkaline pegmatite, Shpat mine, Vishnevy mountains, South Urals). The Sr isotope system was investigated using inter-laboratory natural apatite samples and intra-laboratory apatite samples (from the apatite-carbonate vein, Slyudyanogorskoe deposit, Irkutsk region and from carbonatites, Ilmenogorsk massif, Ural).Methods. The research was carried using a Neptune Plus multicollector mass spectrometer with inductively coupled plasma (ThermoFisher) equipped with an NWR 213 (ESI) laser ablation attachment, located in a room of ISO class 7 at the “Geoanalyst” Center for Collective Use (IGG Ural Branch of the Russian Academy of Sciences, Ekaterinburg). Results. The article describes methodological approaches for studying Sm/Nd and Sr isotope systems in natural phosphate and silicate minerals by inductively coupled plasma mass spectrometry with laser ablation, implemented on the equipment of the Center for Collective Use “Geoanalyst” (IGG Ural Branch of the Russian Academy of Sciences, Ekaterinburg). A comparative analysis of the obtained results with those reported in literature showed their satisfactory agreement. The developed analytical approaches were used to study apatite samples (analysis of the Sr isotope system) and those of apatite, monazite, titanite (analysis of the Sr isotope system). Conclusions. The developed approaches to the analysis of Sm/Nd and Sr isotopic systems can be recommended for investigating such minerals, as apatite, titanite, allanite, monazite (analysis of the Sm/Nd isotope system); apatite (analysis of the Sr isotope system). The achieved analysis errors allow the results to be used for interpreting various geochemical processes.
3
Huber, Miłosz A., Stanisław Hałas, Yuri N. Neradovsky, Tamara B. Bayanova, Artem W. Mokrushin, and Lesia Lata. "Stable isotope geochemistry of sulfides from intrusion in Monchegorsk, northern part of Baltic Shield." Geochronometria 43, no. 1 (June 1, 2016): 96–101. http://dx.doi.org/10.1515/geochr-2015-0034.
Анотація:
Abstract The sulfide minerals from old mafic intrusion rocks from the Kola Peninsula were analyzed on stable sulfur isotopes. These samples were already dated by the Sm-Nd method. These sulfide samples were evaluated upon a geochemical composition by ICP-MS. The sulfide mineral samples were selected from the main ore-bearing rocks of the Monchetundra layered intrusion. The analyzed sulfides formed several generations of mineralization associated with primary and hydrothermal stage of formation of the deposits. Isotopic studies confirm a few consecutive stages of mineralization. These data were compared with the results of Sm-Nd dating of sulfide mineralization. The results of geochemical and geochronological studies indicate a complementarity in the context of determining the mineralization stages.
4
Öhlander, Björn, Johan Ingri, Magnus Land, and Hans Schöberg. "Change of Sm-Nd isotope composition during weathering of till." Geochimica et Cosmochimica Acta 64, no. 5 (March 2000): 813–20. http://dx.doi.org/10.1016/s0016-7037(99)00365-8.
5
Azovskova, O. B., E. I. Soroka, M. Yu Rovnushkin, and N. G. Soloshenko. "Sm-Nd isotopy of the dykes of the Vorontsovskoe gold-ore deposit (Northern Urals)." Vestnik of Geosciences 9 (2020): 3–6. http://dx.doi.org/10.19110/geov.2020.9.1.
Анотація:
The Vorontsovskoye gold-ore deposit (Northern Urals) generally corresponds to the Carlin-type. One of the deposit features is the presence of numerous dykes of mafic and middle chemical composition, of normal and increased alkalinity. Sm-Nd isotope studies for the first time confirmed the dykes formation age 340 ± 35 Ma. These data can be indicative of the post-collisional stage of magmatism in this area. The positive Nd values suggest a probable abyssal magmatic source of Nd.
6
SHELLNUTT, J. GREGORY, TUNG-YI LEE, CHIH-CHENG YANG, SHIN-TAI HU, JONG-CHANG WU, KUO-LUNG WANG, and CHING-HUA LO. "Late Permian mafic rocks identified within the Doba basin of southern Chad and their relationship to the boundary of the Saharan Metacraton." Geological Magazine 152, no. 6 (May 6, 2015): 1073–84. http://dx.doi.org/10.1017/s0016756815000217.
Анотація:
AbstractThe Doba gabbro was collected from an exploration well through the Cretaceous Doba basin of southern Chad. The gabbro is composed mostly of plagioclase, clinopyroxene and Fe–Ti oxide minerals and displays cumulus mineral textures. Whole-rock40Ar–39Ar step-heating geochronology yielded a Late Permian plateau age of 257 ± 1 Ma. The major and trace elemental geochemistry shows that the gabbro is tholeiitic in composition and has trace element ratios (i.e. La/YbN> 7; Sm/YbPM> 3.4; Nb/Y > 1; Zr/Y > 5) indicative of a basaltic melt derived from a garnet-bearing mantle source. The moderately enriched Sr–Nd isotopes (i.e. ISr= 0.70495 to 0.70839; ɛNd(T)= −1.0 to −1.3) fall within the mantle array (i.e. OIB-like) and are similar to other Late Permian plutonic rocks of North-Central Africa (i.e. ISr= 0.7040 to 0.7070). The enriched isotopic composition of the Doba gabbro contrasts with the more depleted compositions of the spatially associated Neoproterozoic post-Pan-African within-plate granites. The contrasting Nd isotope composition between the older within-plate granites and the younger Doba gabbro indicates that different mantle sources produced the rocks and thus may mark the southern boundary of the Saharan Metacraton.
7
Lastochkin, E. I., G. S. Ripp, D. S. Tsydenova, V. F. Posokhov, and A. E. Murzintseva. "Epithermal Fluorite Deposits in Transbaikalia (Geochemical Features, Sources of Matter and Fluids, and Genesis)." Russian Geology and Geophysics 62, no. 4 (April 1, 2021): 415–26. http://dx.doi.org/10.2113/rgg20194128.
Анотація:
Abstract —We consider the isotope-geochemical features of epithermal fluorite deposits in Transbaikalia, including the REE compositions, Sr isotope ratios, Sm–Nd systems, and isotope compositions of oxygen, carbon, hydrogen, and sulfur. The 87Sr/86Sr ratios in fluorites are within 0.706–0.708, and the εNd values are negative. Oxygen in quartz, the main mineral of the deposits, has a light isotope composition (δ18O = –3.4 to +2.6‰), and the calculated isotope composition of oxygen in the fluid in equilibrium with quartz (δ18O = –9 to –16‰) indicates the presence of meteoric water. The latter is confirmed by analysis of the isotope compositions of oxygen and hydrogen in gas–liquid inclusions in fluorites from three deposits. These isotope compositions are due to recycling caused by the impact of shallow basic plutons. The isotope composition of sulfur indicates its deep source. During ascent, sulfur became enriched in its light isotope (δ34S = –1.8 to –7.7‰). We assess the association of fluorite ores with basaltoids widespread in the study area. The isotope and geochemical parameters suggest their spatial proximity. Probably, the basaltoids were responsible for the recycling of meteoric water. It is shown that the epithermal fluorite deposits formed by the same mechanism as fissure–vein thermal waters in western Transbaikalia.
8
Serov, Pavel A., and Tamara B. Bayanova. "The Sulfide/Silicate Coefficients of Nd and Sm: Geochemical “Fingerprints” for the Syn- and Epigenetic Cu-Ni-(PGE) Ores in the NE Fennoscandian Shield." Minerals 11, no. 10 (September 29, 2021): 1069. http://dx.doi.org/10.3390/min11101069.
Анотація:
One of the current directions of the Sm-Nd isotope systematics development is a dating of the ore process using sulfide minerals. Yet, the issue of the existence of rare earth elements (REE) in sulfides is still a matter for discussion. Sulfides from ore-bearing rocks of Proterozoic (2.53–1.98 Ga) Cu-Ni and platinum group elements (PGE) deposits of the Fennoscandian Shield were studied. It is found that the most probable source of REE in sulfide minerals from Cu-Ni-PGE complexes could be submicronic fluid inclusions, which are trapped at the mineral crystallization stage. In such a case, fluid or melt inclusions are specimens of the syngenetic parental melt, from which the base mineral formed, and these reflect a composition of the parental fluid. The mineral–rock partition coefficients for Nd and Sm can be used as “fingerprints” for individual deposits, and these are isotope-geochemical indicators of the ore-caused fluid that is syngenetic to sulfide. Moreover, the DNd/DSm ratio for various sulfide minerals can be used as a prospective geochemical tool for reconstructing a mineral formation sequence in ore complexes. On the other hand, differences in isotope compositions of sulfide neodymium could be markers of some ore-caused fluids and related to certain generations of sulfide minerals.
9
Belka, Z., J. Dopieralska, M. Jakubowicz, S. Skompski, A. Walczak, D. Korn, and M. Siepak. "Nd isotope record of ocean closure archived in limestones of the Devonian–Carboniferous carbonate platform, Greater Karatau, southern Kazakhstan." Journal of the Geological Society 178, no. 1 (September 4, 2020): jgs2020–077. http://dx.doi.org/10.1144/jgs2020-077.
Анотація:
The neodymium isotope composition of micritic limestones from the Devonian–Carboniferous carbonate platform of the Greater Karatau (southern Kazakhstan) was investigated to test the ability of calcite micrite to archive Nd isotope signatures of seawater. The carbonate fraction that displays seawater-like rare earth element (REE + Y) signatures is often more radiogenic than the dispersed terrigenous material in the samples. Hence, its Nd isotope composition is interpreted to correspond to the seawater from which the micrite was precipitated. The seawater on the Karatau platform exhibited an extremely wide range of εNd(t) values from –9.3 to +4.3 (the most radiogenic value measured for past seawater to date) and very uniform Sm/Nd ratios, from 0.19 to 0.22, lying within the range characteristic for modern oceanic water. The temporal trend in εNd(t) values is interpreted to document the final closure of the Uralian–Turkestan Ocean. It shows that the subduction along Kazakhstan's active margin had already started at the beginning of the Tournaisian (c. 355 Ma), at least 23 Myr earlier than previously thought. The application of Nd isotope time series on biostratigraphically dated carbonates opens a new direction for geotectonic studies. This approach has the potential to provide useful constraints for the precise dating of the duration of geotectonic and volcanic events.Supplementary material: Nd isotope and REE concentration data, summary of stratigraphic and lithological data, field photographs and additional geochemical plots are available at: https://doi.org/10.6084/m9.figshare.c.5110163
10
Fridovsky, V. Yu, A. E. Vernikovskaya, K. Yu Yakovleva, N. V. Rodionov, A. V. Travin, N. Yu Matushkin, and P. I. Kadilnikov. "Geodynamic Formation Conditions and Age of Granitoids from Small Intrusions in the West of the Yana–Kolyma Gold Belt (Northeast Asia)." Russian Geology and Geophysics 63, no. 4 (April 1, 2022): 483–502. http://dx.doi.org/10.2113/rgg20214442.
Анотація:
Abstract We report results of geological, mineralogical-petrographic, geochemical, isotope-geochemical (Sm–Nd, Rb–Sr), and geochronological (U–Pb, 40Ar/39Ar) studies of acid and intermediate intrusive rocks (granodiorites, leucocratic granites, subalkaline granites, and subalkaline leucocratic granites, diorites, and quartz diorites) of the Bukeschen and Samyr small plutons in the western part of the Yana–Kolyma gold belt (northeast Asia). These rocks are combined with Late Jurassic (151–145 Ma) dikes of basic, intermediate, and acid compositions into a single complex of small intrusions. They intrude the Upper Triassic–Middle Jurassic terrigenous deposits of continental margin blocks in the eastern part of the Verkhoyansk–Kolyma folded area. Our new U–Pb data for zircon (SHRIMP-II) indicate that the Bukeschen and Samyr pluton granitoids formed in the Berriasian, at 144.5 and 143 Ma, respectively. The small-intrusion granitoids have geochemical and isotope (Sm–Nd and Rb–Sr) characteristics similar to those of Late Jurassic dikes of varying composition. Therefore, they can be united into a single complex of small intrusions generated from a mixed source with the participation of mantle (OIB- and E-MORB type), lower crust, and subduction components and with Paleoproterozoic–Mesoproterozoic Sm–Nd model age estimates for the magma sources. Late Jurassic–Early Cretaceous magmatic and postmagmatic events and cooling of the intrusions played an important role in the processes of gold localization in the western part of the Yana–Kolyma gold belt. This is reflected in two tectonothermal stages (accounting for closing temperatures of the U–Pb, 40Ar/39Ar, and Re–Os isotope systems for different minerals) estimated at 151–141 and 138–137 Ma. These results for the small-intrusion complex agree with the tectonic model of the evolution of an active continental margin (northeastern Siberia) in the Mesozoic era, whose final development stage in the Berriasian age saw the formation of mostly small granitoid plutons.
11
Svetlitskaya, T. V. "GEOCHEMICAL AND Sr-Nd ISOTOPE SYSTEMATICS OF THE LATE PERMIAN–EARLY TRIASSIC TRAPS FROM THE KUZNETSK BASIN: MAGMA SOURCES AND CORRELATION WITH THE NORIL’SK REGION VOLCANICS." Доклады Российской академии наук. Науки о Земле 510, no. 2 (June 1, 2023): 149–60. http://dx.doi.org/10.31857/s2686739722602277.
Анотація:
The study provides whole-rock geochemical and Rb-Sr and Sm-Nd isotope examinations of Permian-Triassic volcanics (basalts, basaltic andesites) and sills (trachydolerites, monzodiorites) from the Kuznetsk Basin, which is part of the Siberian Large Igneous Province. It is shown that the volcanic section of the Kuznetsk Basin consists of the Lower (I and II units: TiO2 = 1.6–1.9 wt.%, Gd/Yb = 2.0–2.1) and Upper (III–VIII units: TiO2 = 1.4–1.8 wt.%, Gd/Yb = 1.7–1.9) Sequences. The Mayzass sill is geochemically correlated with the Unit II basaltic andesite of the Lower Sequence, and the Syrkashev sill is geochemically akin to the Upper Sequence. The Kuznetsk traps originated from the partial melting of a Sr-Nd isotopically heterogeneous subduction-modified lithospheric mantle. They are geochemically comparable to low-Ti basalts of the low–middle Nadezhdinsky suite from the Noril’sk region, but differ in Sr-Nd isotope composition. The Sr-Nd isotope signatures of the uncontaminated lavas and Syrkashev sill rocks (εNd(T) = (+4.6)–(+2.4), (87Sr/86Sr)T = 0.7047–0.7054) are inherited from the ancient lithospheric mantle and do not represent the contribution of the Siberian plume. The Mayzass sill rocks (εNd(T) = (+2.2)–(+2.1); (87Sr/86Sr)T = 0.7055–0.7063)are derived from a parental melt contaminated with crustal carbonates.
12
Pollock, J. C., P. J. Sylvester, and S. M. Barr. "Lu–Hf zircon and Sm–Nd whole-rock isotope constraints on the extent of juvenile arc crust in Avalonia: examples from Newfoundland and Nova Scotia, Canada." Canadian Journal of Earth Sciences 52, no. 3 (March 2015): 161–81. http://dx.doi.org/10.1139/cjes-2014-0157.
Анотація:
Avalonia, the largest accreted crustal block in the Appalachian orogen, consists of Neoproterozoic magmatic arc sequences that represent protracted and episodic subduction-related magmatism before deposition of an Ediacaran–Ordovician cover sequence including siliciclastic rocks. Zircon crystals were obtained from arc-related magmatic rocks and from clastic sedimentary sequences and analyzed in situ for their Hf-isotope composition. The majority of magmatic and detrital zircons are dominated by initial 176Hf/177Hf values that are more radiogenic than chondritic uniform reservoir (CHUR) with calculated crust formation Hf–TDM model ages that range from 0.84 to 1.30 Ga. These results suggest formation by partial melting of juvenile mantle in a Neoproterozoic continental arc. Some zircons have Hf–TDM model ages ca. 1.39–3.09 Ga with εHf values of –33.9 to –0.5 and more clearly indicate involvement of older lithosphere in their petrogenesis. Whole-rock Sm–Nd isotopic compositions from felsic volcanic rocks are characterized by positive initial εNd values with Mesoproterozoic depleted mantle model ages consistent with juvenile extraction. Results suggest a dominant mantle component with long-term light rare earth element (LREE) depletion mixed with an older crustal component with long-term LREE enrichment. The pattern of TDM model ages and variations in Lu–Hf and Sm–Nd isotopic character are compatible with a ca. 1.0–1.2 Ga igneous tectonomagmatic event that formed basement to Neoproterozoic magmatic arcs in Avalonia. The presence of evolved isotopic signatures, however, indicates that significant older Proterozoic crust is present locally beneath Avalonia, suggesting that Avalonia formed in a single Neoproterozoic arc system that generated juvenile mantle-derived crust, coupled with lesser anatectic reworking of significantly older crust.
13
Zhang, Zhiyuan, Guiqing Xie, Jingwen Mao, Wengang Liu, Paul Olin, and Wei Li. "Sm-Nd Dating and In-Situ LA-ICP-MS Trace Element Analyses of Scheelite from the Longshan Sb-Au Deposit, Xiangzhong Metallogenic Province, South China." Minerals 9, no. 2 (January 30, 2019): 87. http://dx.doi.org/10.3390/min9020087.
Анотація:
Longshan is an important Sb-Au ore deposit (3.7 Mt @4.5 wt. % Sb and 4.6 g/t Au) in the Xiangzhong metallogenic province (XZMP), South China. In the present work, trace element composition, Sm-Nd isotope dating, and Sr isotope of scheelite from the Longshan Sb-Au deposit are used to constrain the genesis of the deposit. Based on mineral assemblages and geological characteristics, two types of scheelites can be distinguished (Sch1 and Sch2). Sch1 is granular and cemented by stibnite, while Sch2 is commonly present in stibnite, pyrite, calcite, and quartz veins, indicating that Sch2 is later than Sch1. The Sm-Nd isochron age defined by Sch1 is 210 ± 2 Ma (MSWD = 1.0, n = 4). This age is interpreted as the age of Sb-Au mineralization and overlaps with the 201–228 Ma granitic rocks in the XZMP. Sch1 exhibits high ΣREE + Y contents (43.5 to 104 ppm), low Sr values (2687 to 6318 ppm, average of 4018 ppm), and a narrow range of 87Sr/86Sr values (0.7209 to 0.7210, average of 0.7209). In contrast, the elevated Sr abundance (4525 to 11,040 ppm, average of 6874 ppm) and wide 87Sr/86Sr ratios (0.7209 to 0.7228, average of 0.7214) in Sch2 were possibly caused by fluid-rock interaction mixing with Sr-enriched basement rocks. Sulfides have a narrow range of δ34S values of −1.8‰ to 3.2‰, with an average value of 1.1‰ (n = 7). Geochronological, geochemical and isotopic data suggest that the Longshan Sb-Au deposit is possible genetically related to the Late Triassic granitic intrusion in the XZMP.
14
Kostitsyn, Y. A., A. R. Tskhovrebova, I. T. Rass, and M. O. Anosova. "Sr–Nd Isotopic Evidence of a Heterogeneous Magmatic Source of Alkaline–Carbonatite Rocks of the Odikhincha Alkaline–Carbonatite Massif (Maimecha-Kotui Province, Siberia)." Geochemistry International 61, no. 12 (December 2023): 1221–40. http://dx.doi.org/10.1134/s0016702923120030.
Анотація:
Abstract This study focuses on the igneous rocks composing the Odikhincha massif. The massif is typical ring alkaline–ultrabasic massif with carbonatites, second largest in the Maimecha-Kotui province. The Sr-Nd isotopic values of the traps of the Arydzhang Formation and the host dolomites were also determined for comparison. The Rb–Sr isotope system of phlogopite and calcite from the Od-16-19 carbonatite of the Odikhincha massif is disturbed; the obtained age on the mineral isochrone (245 ± 3 Ma) is close to the time of formation of the Siberian traps and rocks of the ultrabasic–alkaline Maimecha-Kotui complex, but the large scatter of analytical points (MSWD = 22) does not allow this date to be considered as reliable. The disturbance of the isotope system is probably related to the fact that the strontium isotope ratio in the fluid was not constant during autometasomatic phlogopitization of carbonatite. The U–Pb isotopic system of titanite and perovskite from the same carbonatite sample Od-16-19 also appeared to be disturbed, since data points formed discordia. The U–Pb age obtained for titanite and perovskite are 244 ± 5 Ma (MSWD = 1.8) and 247 ± 18 Ma (MSWD = 4), respectively. Apparently, the age values provided by the two isotopic systems (245 ± 3 Ma by Rb–Sr and 247 ± 18 and 244 ± 5 Ma by U–Pb) are consistent with each other and reflect the time of metasomatic processes, i.e., phlogopitization and iolitization. Rb–Sr and Sm–Nd isotope data for ultrabasic–alkaline intrusive rocks with carbonatites of the Odikhincha massif and volcanics of the Arydzhang Formation indicate an enriched, relative to the composition of the convecting mantle, isotopically heterogeneous source of their parent melts. This source could be a combination of ultrabasic mantle rocks and rocks of basic composition (basites). The latter played the role of an enriched component. No signs of contamination of the melts with the host sedimentary rocks in situ were found, however, variations of Sr and Nd isotopic ratios in the rocks of the Odikhincha massif may indicate that during the introduction of deep magmas their interaction and substance exchange with the surrounding rocks of the lithosphere continued up to complete solidification of the melts, as indicated by the nature of local isotopic heterogeneity within the Odikhincha intrusion.
15
Sakhno, V. G., and L. S. Tsurikova. "Isotopic and geochemical features of the genesis of igneous complexes and ore-magmatic systems in the Chukotka sector of the Russian Arctic coast." LITHOSPHERE (Russia) 20, no. 2 (April 25, 2020): 196–211. http://dx.doi.org/10.24930/1681-9004-2020-20-2-196-211.
Анотація:
Research subject. The isotopic composition (Pb-Pb, Sm-Nd, Rb-Sr, Os/Os, Hf/Hf, 3 He/4 He, etc.) of magmatic complexes and ore-magmatic systems (OMS) of two ore clusters (Kupolsky and Ilirneysky) located in the subpolar Western Chukotka was studied. These ore clusters differ from each other both in their structural position and the age of their magmatic complexes, within which the largest deposits of Au-Ag type are known. Materials and methods. The Pb-Pb, Rb-Sr, SmNd, Re-Os, Lu-Hf, 3 He/4 He, 40Ar/36Ar and sulphur isotopic systems were studied at the VSEGEI centre for isotopic studies (St. Petersburg), as well as at the Institute of Geology, Geochemistry and Ore Deposits (IGEM, Moscow) and the Laboratory of Stable Isotopes of the Far Eastern Geological Institute (FEGI, Vladivostok). Re and Os were measured using an ELEMENT-2 inductively coupled plasma single-collector mass spectrometer. Sulphur isotopic ratios were measured using a Finnigan MAT 253 isotope mass spectrometer. Results and conclusions. On the basis of the isotope-geochemical data obtained, an assumption was made that various deep sources participated in the magma generation, and the differentiated composition of late melts may reflect the melting processes of the crust upper horizons. When comparing the data on the magmatism of the Ilirneysky and Kupolsky ore clusters, a different degree of crustal rock influence on melt generation was revealed. The Kupolsky ore cluster is characterised by a large influence of mantle sources in intraplate magmatism associated with ore formation processes. This is likely to have determined a greater amount of mineralisation in the Kupolsky cluster compared to the Ilirneysky ore cluster.
16
Vetrov, E. V., A. N. Uvarov, I. A. Vishnevskaya, M. V. Chervyakovskaya, N. I. Vetrova, F. I. Zhimulev, and E. S. Andreeva. "STRUCTURE, AGE, GEOCHEMICAL AND ISOTOPE-GEOCHEMICAL (SM/ND) COMPOSITION OF THE SERLIGSKAYA FORMATION, TANNU-OLA TERRAIN OF TUVA." Geology and mineral resources of Siberia, no. 1 (2020): 81–94. http://dx.doi.org/10.20403/2078-0575-2020-1-81-94.
17
Vasyukova, E. A., D. V. Metelkin, F. A. Letnikov, and E. F. Letnikova. "New isotope constraints on the time of formation of the Nersinskii dolerite complex from the Biryusa-Sayan area." Доклады Академии наук 485, no. 5 (May 23, 2019): 594–98. http://dx.doi.org/10.31857/s0869-56524855594-598.
Анотація:
New data on the Sm-Nd isotopic composition of the dolerites of the Nersinskii complex that are consistent with the petrographic study and the U-Pb dating of detrital zircon from the overlying sedimentary sequences of the Biryusa-Sayan area are presented. The data obtained indicate the absence of the supposed magmatic event 1.6 billion years ago and clearly indicate the Neoproterozoic age of the intrusions. Their source could have been the metasomatized mantle; after formation, dolerites went through several stages of metasomatism, which was reflected in the evolution of its isotopic systems.
18
КУЗНЕЦОВА, Л. Г., С. И. ДРИЛЬ, and С. И. ШКОЛЬНИК. "THE AGE, COMPOSITION, AND PROVENANCES OF TERRIGENOUS ROCKS IN THE SOUTH OF THE SANGILEN BLOCK OF THE CENTRAL ASIAN OROGENIC BELT." Геология и геофизика 65, no. 3 (June 3, 2024): 353–75. http://dx.doi.org/10.15372/gig2023185.
Анотація:
Впервые получены петрогеохимические, изотопные (Sm-Nd) и геохронологические U-Th-Pb (LA-ICP-MS по детритовым цирконам) характеристики терригенных пород из мощной толщи в южной части Сангиленского блока, входящего в состав Центрально-Азиатского складчатого пояса (ЦАСП). Установлено, что они фациально неоднородны: в субширотном направлении с запада на восток наблюдается переход от граувакковых песчаников с примесью пирокластики к существенно более кремнекислым литоидным аренитам. Геохронологические данные по детритовым цирконам из преобладающих граувакковых песчаников позволяют выделить следующие интервалы конкордантных оценок их возраста (млн лет): 787—907, 1873—2236, 2613—2725 и 2902—2977. С учетом максимального из установленного на сегодняшний день раннекембрийского (520 млн лет) возраста прорывающих их магматических пород возможный период накопления терригенных толщ южной части Сангиленского блока оценивается значительным интервалом 520—790 млн лет. На основании анализа полученных геохимических, изотопных (Sm-Nd) и геохронологических (U-Th-Pb) данных вероятными источниками сноса для терригенных отложений южной полосы (ЮП) являлись неопротерозойские и раннедокембрийские островодужные и окраинно-континентальные комплексы. Их относительные пропорции в составе осадков, по-видимому, изменялись с удалением от бассейна седиментации (в современных координатах с запада на восток): снижалась доля ранненеопротерозойских ювенильных пород и возрастала доля раннедокембрийских метаморфических комплексов. Обнаружение в терригенных породах Сангиленского блока детритовых цирконов палеопротерозойского и мезоархейского возраста, поставщиками которых не могли быть известные комплексы композитного докембрийского фундамента Тувино-Монгольского микроконтинента, позволяет рассматривать в качестве их источников другие кратонные блоки ЦАСП We have first determined the petrogeochemical, Sm–Nd isotope, and U–Th–Pb geochronological (detrital-zircon LA-ICP-MS) characteristics of terrigenous rocks from a thick sequence in the south of the Sangilen block, which is part of the Central Asian Orogenic Belt (CAOB). The rocks are heterogeneous in facies composition: From west to east, there is a transition from graywacke sandstones with an admixture of pyroclastics to much more silicic lithoid arenites. Geochronological data on detrital zircons from the predominant graywacke sandstones mark the following intervals of concordant ages (Ma): 787–907, 1870–2236, 2613–2725, and 2900–2980. With regard to the oldest determined age (early Cambrian, 520 Ma) of the igneous rocks intruding these sandstones, the possible period of accumulation of terrigenous sequences in the south of the Sangilen block is estimated at 790–520 Ma. The obtained geochemical, Sm–Nd isotope, and U–Th–Pb geochronological data point to Neoproterozoic and early Precambrian island arc and continent-marginal complexes as probable provenances for the terrigenous deposits of the “southern band”. The relative proportions of rocks of these complexes in the deposits changed with distance from the sedimentary basin (from west to east, in modern coordinates): The portion of early Neoproterozoic juvenile rocks decreased, and the portion of early Precambrian metamorphic complexes increased. The Paleoproterozoic and Mezoarchean detrital zircons found in the terrigenous rocks of the Sangilen block could not originate from any known Precambrian complexes of the Tuva–Mongolian microcontinent. This gives grounds to regard other craton blocks of the CAOB as their sources
19
Rizvanova, Nailya G., Antonina A. Alenicheva, Sergey G. Skublov, Sergey A. Sergeev, and Dmitriy A. Lykhin. "Early Ordovician Age of Fluorite-Rare-Metal Deposits at the Voznesensky Ore District (Far East, Russia): Evidence from Zircon and Cassiterite U–Pb and Fluorite Sm–Nd Dating Results." Minerals 11, no. 11 (October 20, 2021): 1154. http://dx.doi.org/10.3390/min11111154.
Анотація:
This article presents new isotope-geochronological results for the granites of the Voznesensky ore district (southeastern part of the Khanka massif). The granites are associated with extensive rare-metal–fluorite, tin and tantalum mineralization. Despite the numerous published results of Rb–Sr, Sm–Nd and U–Pb dating of ore-bearing granites and associated ores, the issues of age correlation and the genetic relationship of igneous rocks and mineralization remain unclear. U–Pb zircon SHRIMP dating reveals synchronous ages of 478 ± 4 Ma and 481 ± 7 Ma for two samples of biotite leucogranites as the age of magmatic crystallization of the Voznesensky granites. The composition of the studied zircon demonstrates the typical features of magmatic zircon and has the typical features of zircon exposed to fluids at the late/post-magmatic stage. Sm–Nd ID-TIMS dating of the fluorite of the Voznesenskoe deposit yields an age of 477 ± 9 Ma, and U–Pb ID-TIMS dating of cassiterite from the Yaroslavskoe and Chapaevskoe tin deposits yields an age of 480 ± 4 Ma, which confirms the direct genetic and age relationship of ore formation with granite magmatism.
20
d'Lemos, R. S., and M. Brown. "Sm–Nd isotope characteristics of late Cadomian granite magmatism in northern France and the Channel Islands." Geological Magazine 130, no. 6 (November 1993): 797–804. http://dx.doi.org/10.1017/s0016756800023165.
Анотація:
AbstractSm–Nd isotopic studies of granites within the late Precambrian, Cadomian, orogenic belt of the North Armorican Massif (northwestern France) and Channel Islands reveal differences between arc-related granite magmatism in outboard terranes and intracrustal granite magmatism in inboard terranes. Late Cadomian (c. 570 Ma), arc-related granitoids exhibit a range of εnd( - 2 to - 6) and Nd model ages (TDM1.0–1.3 Ga) reflecting variable contamination between late Precambrian mantle derived magmas and ancient (c. 2.0 Ga?) continental crust. The contamination did not involve exposed granitic Icartian basement to anygreat degree, a more likely contaminant being unexposed lower crust of intermediate to acidic granulitic composition, or early Cadomian plutons which were themselves contaminated by lower crust. Voluminous granites of the Mancellian region (c. 550–540 Ma) share common isotopic characteristics (εNd-4 to -7, TDM1.5–1.7 Ga) with migmatites and anatectic granites produced by partial melting of metasedimentary sequences within the St Malo region consistent with a common source.
21
KIM, MUN GI, YONG IL LEE, TAEJIN CHOI, and YUJI ORIHASHI. "The tectonic setting of the eastern margin of the Sino-Korean Block inferred from detrital zircon U–Pb age and Nd isotope composition of the Pyeongan Supergroup (upper Palaeozoic – Lower Triassic), Korea." Geological Magazine 156, no. 3 (November 20, 2017): 471–84. http://dx.doi.org/10.1017/s0016756817000899.
Анотація:
AbstractThe upper Palaeozoic succession (Pyeongan Supergroup) in central eastern Korea is well correlated with the equivalent successions distributed in North China, suggestive of the Korean upper Palaeozoic being part of the Sino-Korean Block. Detrital zircon U–Pb ages and Sm–Nd isotope compositions of the Pyeongan Supergroup in the Samcheok coalfield of the Taebaeksan Basin were analysed. A single predominant zircon age peak at c. 1.9 Ga (> 70%) is marked in all sedimentary units, followed by varying amounts of minor late Palaeozoic grains (up to 30%). The rarity of Meso- to Neoproterozoic- and Silurian-aged zircons confirms that sediment influx from the South China and Qinling blocks was insignificant. The 2.0–1.8 Ga-dominated zircon age pattern and the Nd isotope composition (average εNd(0) = −15.5±4.0) of the Pyeongan Supergroup most closely reflect the signature of the Yeongnam Massif basements, which supports a previous hypothesis that the Pyeongan Supergroup was mostly derived from a palaeo-orogen located to the east–southeast. Relatively higher εNd(0) values (> −10.1) in the lowermost and the upper parts of the succession are closely matched by the increased occurrence of syn-depositional-aged zircons, which indicates considerable mixing of juvenile materials at c. 320 Ma and 260 Ma. Both arc-related magmatic events are interpreted to have been related to oceanic subduction, suggesting that the eastern margin of the Sino-Korean Block was an active continental margin during late Palaeozoic times.
22
van de Ven, Mathijs, Anouk Borst, Gareth Davies, Emma Hunt, and Adrian Finch. "Hydrothermal Alteration of Eudialyte-Hosted Critical Metal Deposits: Fluid Source and Implications for Deposit Grade." Minerals 9, no. 7 (July 10, 2019): 422. http://dx.doi.org/10.3390/min9070422.
Анотація:
Eudialyte-hosted critical metal deposits potentially represent major sources of rare earth elements (REE), zirconium and niobium. Here, we study the chemical and isotopic composition of fresh and altered eudialyte in nepheline syenite from the Ilímaussaq Complex, Greenland, one of the world’s largest known eudialyte-hosted deposits. Late-magmatic hydrothermal alteration caused partial replacement of primary magmatic eudialyte by complex pseudomorph assemblages of secondary Zr-, Nb-, and REE-minerals. Three secondary assemblage types are characterised by the zirconosilicates catapleiite, gittinsite and zircon, respectively, of which the catapleiite type is most common. To investigate elemental exchange associated with alteration and to constrain the nature of the metasomatic fluids, we compare trace elements and Sm/Nd isotope compositions of unaltered eudialyte crystals and their replaced counterparts from five syenite samples (three catapleiite-type, one gittinsite-type, and one zircon-type assemblage). Trace element budgets for the catapleiite-type pseudomorphs indicate a 15–30% loss of REE, Ta, Nb, Zr, Sr and Y relative to fresh eudialyte. Moreover, the gittinsite- and zircon-type assemblages record preferential heavy REE (HREE) depletion (≤50%), suggesting that the metasomatic fluids mobilised high field strength elements. Initial Nd isotope ratios of unaltered eudialyte and catapleiite- and gittinsite-type pseudomorphs are indistinguishable, confirming a magmatic fluid origin. However, a higher initial ratio and stronger HREE depletion in the zircon-type pseudomorphs suggests a different source for the zircon-forming fluid. Although alteration reduces the metal budget of the original eudialyte volume, we infer that these elements re-precipitate nearby in the same rock. Alteration, therefore, might have little effect on overall grade but preferentially separates heavy and light REE into different phases. Targeted processing of the alteration products may access individual rare earth families (heavy vs. light) and other metals (Zr, Nb, Ta) more effectively than processing the fresh rock.
23
Braid, James A., J. Brendan Murphy, Cecilio Quesada, Luke Bickerton, and James K. Mortensen. "Probing the composition of unexposed basement, South Portuguese Zone, southern Iberia: implications for the connections between the Appalachian and Variscan orogens." Canadian Journal of Earth Sciences 49, no. 4 (April 2012): 591–613. http://dx.doi.org/10.1139/e11-071.
Анотація:
Geochemistry and Sm–Nd and U–Pb (magmatic zircon) isotope data from a postcollisional batholith that crosscuts the allochthonous South Portuguese Zone (SPZ) of southern Iberia suggest that the basement is compositionally more juvenile than the exposed upper crust. The SPZ is an allochthonous terrane of the late Paleozoic Variscan orogen. The oldest exposed units in the SPZ are Late Devonian continental clastics, and as a result, the origins of the SPZ are unknown. Multifaceted inherited zircon cores from a granitoid batholith (Sierra Norte Batholith, SNB) reveal Neoproterozoic (ca. 561–647 Ma) and Mesoproterozoic ages (ca. 1075 – ca. 1116 Ma). Granitoid samples are characterized by εNd values ranging from +1.4 to –9.6 and model ages ca. 0.76–1.8 Ga. Conversely, the exposed Late Devonian clastics of the SPZ are characterized by more negative εNd values (–7.5 to –10.4). Taken together, U–Pb and Sm–Nd data indicate the lower crust that melted to yield the SNB was (i) Neoproterozoic (ca. 560–650 Ma) to Mesoproterozoic (ca. 1.0–1.2 Ga) in age, (ii) was not compositionally similar to the overlying Devono-Carboniferous continental detritus but was instead more juvenile, with model ages between ca. 0.9–1.2 Ga. This unusual relationship is similar to the relationship between the relatively juvenile basement and ancient upper crust documented in the exposed portion of the Meguma terrane in the northern Appalachians, which paleogeographic reconstructions show was immediately outboard of southern Iberia in the Late Devonian.
24
France-Lanord, Christian, and Patrick Le Fort. "Crustal melting and granite genesis during the Himalayan collision orogenesis." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 79, no. 2-3 (1988): 183–95. http://dx.doi.org/10.1017/s0263593300014206.
Анотація:
ABSTRACTThis paper reviews the petrogenesis of Himalayan leucogranites (HHγ) on the basis of field, petrological and geochemical data collected over the last fifteen years. HHγ are intruded at the top of the 2 to 8km-thick High Himalayan Crystallines (HHC). These are metamorphosed (Ky to Sill) and present much evidence of partial melting. During the MCT thrusting, the already metamorphosed HHC were thrust on top of the weakly metamorphosed Midland Formations, inducing the main phase of Himalayan metamorphism. The genesis of HHγ and North Himalaya leucogranites (NHγ) associates thrusting along the MCT, propagation of inverted metamorphism, liberation of large quantities of fluid in the Midlands, and partial melting of the HHC.The restricted compositions of the granites are close to minimum melt compositions; variations in the alkali ratio probably relate to the variable amount of B, F and H2O. The HHγ were issued from the migmatitic zone around 700°C and 800 MPa., and still emplaced some 10 to 15 km below the surface. This syn- to late-tectonic emplacement of the leucogranites lasted for more than 10 Ma according to isotopic ages (25 to 14 Ma).O, Rb–Sr, Nd–Sm and Pb isotope studies corroborate the unambiguous filiation between the HHC and the leucogranites in central Nepal. They also imply that the plutons are generated as numerous poorly mixed batches of magma produced preferentially in specific zones of the source rock. δD values may be explained by infiltration of water from the Midlands in the melting zone, and/or by water degassing during crystallisation. The positive covariations between Sr-, Nd- and O-isotope ratios relate to the variations in the original sediment composition of the source gneisses. Whereas trace element characteristics often date back to the anatectic process, limited magmatic differentiation is recorded by the biotite. These granites are typical crustal products, keeping track of some of the pre-Himalayan evolution together with that of their own origin.
25
Smol’kin, Valery F., and Artem V. Mokrushin. "Paleoproterozoic Layered Intrusions of the Monchegorsk Ore District: Geochemistry and U–Pb, Sm–Nd, Re–Os Isotope Analysis." Minerals 12, no. 11 (November 11, 2022): 1432. http://dx.doi.org/10.3390/min12111432.
Анотація:
The paper concerns the geochemical analysis of rocks from the ore-bearing layered intrusions that belong to two age groups of the Monchepluton and the Imandra–Umbarechka Complex (2.50 and 2.44 Ga) and the largest gabbro-anorthosite of the Main Ridge Complex (2.51–2.45 Ga). The intrusion of these complexes happened at different depths when the endogenous and geodynamic settings changed at the beginning of the Paleoproterozoic Era. Five megacycles are distinguished in a generalized cross-section of the two-chamber Monchepluton. The megacycles differ in rock composition, rock geochemical features, and mineralization types, i.e., the chromite, sulfide Cu–Ni–PGE and low-sulfide PGE types. The abrupt changes in isotope indicators (εNd, 87Sr/86Sr) mark their boundaries. At a depth of 2037–2383 m, the M-1 borehole intersects a standalone intrusive body that is essentially a magma feeder channel. The intrusive body’s geochemical characteristics and U–Pb isotope age correlate to the Monchepluton rocks. The gabbro-anorthosite massifs united in the Main Ridge Complex were intruded in the following order: the Monchetundra, Chunatundra, Volchetundra, and Losevo–Medvezhye tundras. The largest Monchetundra massif was formed as a result of multiple intrusions of mafic magmatic melt from the deep reservoirs. The melts intruded in two stages, i.e., 2.51–2.49 Ga and 2.48–2.47 Ga, and their composition changed gradually. The gabbro-pegmatites and coeval harrisite dykes are more recent ones (2.46–2.45 Ga). The summarized results of the U–Pb, Sm–Nd, and Re–Os systems research allowed us to establish genetic relations between the studied geological objects. We proposed a model where there was an uplift of a mantle plume to the lower crust area at the age of 2.5 Ga, the deep mantle reservoirs were formed, and a large-scale interaction happened between the parental magma and granulite–eclogite complex rocks. Local contamination and assimilation processes took place during the uplifting of magmas in areas where the magmatic feeding system contacted the host amphibolite–gneiss Archean complexes.
26
Smolkin, Valeriy, Artem Mokrushin, Tamara Bayanova, Pavel Serov, and Aleksey Ariskin. "Magma feeding paleochannel in the Monchegorsk ore region: geochemistry, isotope U-Pb and Sm-Nd analysis (Kola region, Russia)." Записки Горного института 255 (July 26, 2022): 405–18. http://dx.doi.org/10.31897/pmi.2022.48.
Анотація:
A comprehensive study of a 340 m thick lenticular-sheet body of ultramafic composition penetrated by structural well M-1 at a depth of about 2.2 km was accomplished. Its main volume is composed of plagioharzburgite; fine-grained rocks of norite and orthopyroxenite chilling zones are preserved on endocontacts. The rocks of the body are similar in composition to the rocks near the underlying ore-bearing layered intrusion – the Monchepluton. The age of intrusion of the ultramafic body is 2510 ± 9 Ma (U-Pb, ID-TIMS, zircon) and, taking into account analytical errors, is comparable with the formation period of the Monchepluton (2507-2498 Ma). According to the study of the Sm-Nd system in rocks and minerals, a positive value of the eNd (+1.1) parameter was established, similar to that in dunites and chromitites of the Monchepluton. Based on these results, the ultramafic body penetrated at depth was assigned to the magma feeding paleochannel through which the ultramafic, weakly contaminated magma entered the overlying magma chamber. This body is a unique example of a magma-feeding system for the ore-bearing layered intrusion of Precambrian age.
27
Shardakova, G. Yu, and A. V. Korovko. "Vendian-Cambrian granites of the Salatim suture zone (the Northern Urals): Geochemistry of zircons, source composition, geochronological and geodynamical consequences." LITHOSPHERE (Russia) 21, no. 1 (March 4, 2021): 32–54. http://dx.doi.org/10.24930/1681-9004-2021-21-1-32-54.
Анотація:
Research subject. The composition and isotope systems of zircons and their host granites from the Krutorechensky complex (western part of the Main Uralian fault zone, Northern Urals) were investigated. Methods. The U-Pb age, trace element contents and Lu-Hf isotopes in the zircons under study were determined by LA-ICP-MS (Ulan-Ude, Ekaterinburg). TIMS was used to determine Sm-Nd isotopes in the rocks. Results and Discussion. It was shown that the morphology and composition of the main zircon group from granites confirm their magmatic origin and the absence of alteration. It means that the previously defined Vendian-Cambrian (542 Ma) age of the granites remains valid. The relics ancient (1043–122 Ma) cores were probably inherited from Isherim suite rocks. The source of such detrital grains could have been the rocks from the East-European platform basement. Young zircons (400 Ma) differing strongly from others in composition could have been formed around the already existing grains produced by a fluid generated under the action of plume activity. The source for granite melting was mainly of a crust nature: εNd(t) = –6, εHf(t) = –6…–9, initial ratio (87Sr/86Sr)i = 0.796943. In terms of lithology, the source rocks correspond to sandstones with a small admixture of clay components. The obtained information confirms the necessity to further investigate questions concerning the area of distribution and the age of the Sarankhapnorsk suite within the Krutorechensky complex, as well as the position of the eastern boundary of the Isherim block. Conclusion. The obtained results can be used in geological mapping.
28
Haydoutov, Ivan, and Christian Pin. "Geochemical and Nd isotope characteristics of pre-Variscan ophiolites and meta-igneous rocks from the Struma Diorite Formation in SW Bulgaria." Geologica Balcanica 23, no. 6 (December 30, 1993): 51–59. http://dx.doi.org/10.52321/geolbalc.23.6.51.
Анотація:
Recent research carried out in SW Bulgaria has distinguished two ophiolite blocks along the Variscan Thracian suture. These ophiolite fragments are closely associated with the Struma Diorite Formation (SDF), with which they are tectonically imbricated. The ophiolite fragments are formed by a dyke complex considered as dismembered part of a sheeted dyke unit. The SDF is a metamorphosed igneous complex built up of rocks with variable composition (mafic to acid), multistage origin (intrusive, volcanic) and calc-alkaline character. In many localities dykes of SDF rocks intersect the ophiolites. Combined trace element and Sm-Nd isotopic data document different origins for both complexes. The ophiolite association is formed by transitional oceanic basalts, extracted from depleted mantle. For the SDF an origin from less depleted source material in an ensimatic island arc setting is favoured.
29
Larin, A. M., A. B. Kotov, E. B. Salnikova, S. D. Velikoslavinskii, V. P. Kovach, T. M. Skovitina, A. A. Ivanova, Yu V. Plotkina, and N. Yu Zagornaya. "AGE AND TECTONIC SETTING OF THE KOPRI-TYPE GRANITOIDS OF THE JUNCTION ZONE OF THE DZHUGDZHUR-STANOVOY AND WEST-STANOVOY SUPERTERRANES OF THE CENTRAL ASIAN FOLD BELT." Доклады Российской академии наук. Науки о Земле 509, no. 1 (March 1, 2023): 5–13. http://dx.doi.org/10.31857/s268673972260237x.
Анотація:
Geochemical, geochronological (U-Pb on ID TIMS zircons), and isotope-geochemical (Sm-Nd) studies of the Kopri-type granitoids of the Tukuringra Complex have been done. The granitoids localized exclusively in the zone of the Dzheltulak suture, which separates the Dzhugdzhur-Stanovoy and West Stanovoy superterranes of the Central Asian fold belt. It has been established that they can be classified as postcollision granitoids of elevated alkalinity and basicity of the adakite type, formed in the age range of 127 ± 1–126 ± 1 Ma, which are part of the Late Mesozoic postcollision Stanovoy volcano-plutonic belt extending in the sublatitudinal direction from the Sea of Okhotsk inland continent subparallel to the Mongolo-Okhotsk suture zone for more than 1000 km and stitching the Dzhugdzhur-Stanovoy and West- Stanovoy superterranes. The structural position of massifs of the Kopri-type granitoids fixes the upper age boundary of the formation of the Dzheltulak suture. The formation of the initial magmas of these granitoids is connected with an essentially lithospheric source formed as a result of mixing of the Early Precambrian and younger, apparently, Phanerozoic component. The similarity in the Nd isotopic composition of the granitoids of the Kopri-type with similar in composition and age granitoids of the West Stanovoy superterrane most likely indicates the similarity of their sources, as well as the fact that the Dzheltulak suture zone “plunges” in the northeast direction under the structures of the Dzhugdzhur–Stanovoy superterrane. This is in full accordance with modern ideas about the features of the deep structure of the junction of the Eurasian and Amur lithospheric plates.
30
Sushchevskaya, N. M., T. A. Shishkina, M. V. Portnyagin, V. G. Batanova, and B. V. Belyatsky. "Long-lasting influence of the Discovery plume on tholeiitic magmatism in the South Atlantic: data on basalts recovered by hole 513a, dsdp leg 71." Геохимия 64, no. 2 (March 15, 2019): 107–27. http://dx.doi.org/10.31857/s0016-7525642107-127.
Анотація:
The paper presents the very first data on concentrations of major and trace elements; Sr, Nd, and Pb isotopic ratios of rocks; and the composition of olivine phenocrysts of 38-Ma basalts recovered by Hole 513a (DSDP Leg 71) in the South Atlantic. The bulk-rock samples and the chilled glasses are mildly magnesian (7–8 wt % MgO) and bear elevated FeO and low Na2O concentrations, as is typical of MORB of the TOR-1 type. Olivine phenocrysts (Fo84.5–88) in these rocks contain concentrations of trace elements (Ni, Mn, Cr, and Zn) that are typical of classic MORB, which are produced by partial melting mantle peridotite. The rocks are strongly depleted in incompatible elements [(La/Sm)n ~ 0.6] but have elevated Ba/Nb, K/Nb, and Pb/Ce ratios and Cu, Ag, and Au concentrations that are 1.5–4 times higher than in typical depleted MORB (N-MORB) and in most rift basalts in the South Atlantic. Isotope compositions of the basalts (average ratios 206Pb/204Pb ~ 18.0; 207Pb/204Pb ~ 15.6, 208Pb/204Pb ~ 38.0, 143Nd/144 Nd ~ 0.5130, and 87Sr/86Sr ~ 0.7040) are close to those in modern tholeiites from the southern MAR segment (SMAR) north of the Agulhas Fracture Zone. The data indicate that the magmas were derived from a strongly depleted mantle source that contained a minor (~3%) admixture of an enriched component, which is discernible in the magmas of the Discovery hotspot. The composition of the source, which is more depleted than DM, and the high degrees of melting of this source explain why the basalts from DSDP Hole 513a are enriched in chalcophile elements. It is believed that spreading magmatism at 45°–48° S in SMAR as far back as 40 Ma was already affected by the Discovery hotspot. This hotspot might be related to the Tristan plume system, and its origin and long-lasting influence on spreading magmatism in the South Atlantic are regarded as evidence of the extensive effect of the Tristan plume.
31
Vervoort, Jeffrey D., and John C. Green. "Origin of evolved magmas in the Midcontinent rift system, northeast Minnesota: Nd-isotope evidence for melting of Archean crust." Canadian Journal of Earth Sciences 34, no. 4 (April 1, 1997): 521–35. http://dx.doi.org/10.1139/e17-042.
Анотація:
The North Shore Volcanic Group (NSVG) of northeast Minnesota is a thick (9 km) sequence of plateau volcanic rocks that constitutes an important part of the Midcontinent rift system. This volcanic sequence is unique among the Midcontinent rift lavas, because it is composed of up to 25% rhyolite flows. We have analyzed Sm- and Nd-isotope compositions of 20 of the largest rhyolite and icelandite flows from the NSVG and seven comparably sized granophyres in the subjacent Duluth and Beaver Bay complexes. The lavas vary in composition from primitive basalt and basaltic andesite to icelandite and rhyolite, with a bimodal distribution. The rhyolites have much lower initial εNd values (−2 to −15, most samples < −10) than either the icelandites (0 to −6) or granophyres (0 to −8). Most rhyolites cannot be related to either the icelandites or more mafic magmas by simple fractionation, but rather have been produced by melting and assimilation of older, evolved crust. We suggest that the bimodal magmatism in the NSVG, and probably throughout the Midcontinent rift, has been produced by two fundamentally different processes. The bulk of the magmatism is basaltic; magmas originate in the mantle and migrate through the lithosphère with minor compositional change. Assimilation and fractional crystallization occur to varying degrees in the crust and, in some cases, produce icelandites, some small-volume rhyolites, and the granophyres, with Nd compositions dominated by the mantle component. The melting that produced the large-volume rhyolites is the result of a multistage process induced by these mantle-derived magmas that pond within the crust. This process appears to occur during a period of slowed extension and causes widespread heating and eventually localized extensive melting of the crust.
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Sazonov, Anatoly M., Igor F. Gertner, Agababa A. Mustafaev, Tatyana S. Krasnova, Yurii V. Kolmakov, Cole G. Kingsbury, and Vera A. Gogoleva. "Early Triassic Episode of the Kresty Volcano–Plutonic Complex Formation in the Maymecha-Kotuy Alkaline Province, Polar Siberia: Geochemistry, Petrology and Uranium–Lead Geochronology." Minerals 14, no. 1 (January 11, 2024): 83. http://dx.doi.org/10.3390/min14010083.
Анотація:
The Kresty volcano–plutonic complex (KVPC) is one of the representatives of the alkaline–ultrabasic magmatism in the Maymecha-Kotuy Alkaline Province in Polar Siberia. The geological structure of the KVPC consists of intrusive formations of olivinite–pyroxenite and melilitolite–monticellitolite bodies, a series of rocks that break through dikes of trachydolerites, syenites, granosyenites, alkaline picrites and lamprophyres. This paper summarizes the results of the authors’ long-term research on the geological structure and features of the material composition of the intrusive magmatic rocks, including geochemistry, mineralogy, distribution of rare earth elements (REE), as well as the results of isotope studies. The multielement composition of the KVPC intrusions demonstrates a complex geodynamic paleoenvironment of the formation as plume nature with signs of subduction and collision. For the ultrabasic series with normal alkalinity from the first phase of the KVPC, a Sm-Nd isochron age yielded an Early Triassic (T1) result of 251 ± 25 Ma. Here, we present U-Pb dating of zircons and perovskite of high-calcium intrusive formations and a dyke complex of alkaline syenites. Thus, for the intrusion of kugdite (according to perovskite), the age determination was 249 ± 4 Ma, and for the crosscutting KVPC dykes of syenites (according to zircon) 249 ± 1 Ma and 252 ± 1 Ma. The age of the most recent dike is almost identical to the age of the main intrusive phases of the KVPC (T1), which corresponds to a larger regional event of the Siberian LIP—251 Ma. According to isotopic Sr-Nd parameters, the main source of KVPC magmas is a PREMA-type material. For dyke varieties, we assume there was an interaction of plume melts with the continental crust. The new age results obtained allow us to further constrain the episodes of alkaline–ultrabasic intrusions in Polar Siberia, taking into account the interaction of mantle plume matter and crustal material.
33
Pe-Piper, Georgia, David J. W. Piper, and Gilles Dessureau. "Mineralogy of the Steel Mountain Anorthosite Complex, Western Newfoundland Appalachians, Canada: Petrogenesis and Tectonic Affinity." Minerals 14, no. 1 (January 11, 2024): 81. http://dx.doi.org/10.3390/min14010081.
Анотація:
The Steel Mountain complex in western Newfoundland is one of several possible peri-Gondwanan basement slivers that have been emplaced along the northwestern margin of the Appalachian Orogen. The complex includes feldspathic anorthosite, gabbronorite, and magnetite-ilmenite ore. Megacrysts of plagioclase (andesine), orthopyroxene (hypersthene) and amphibole (hornblende) were analyzed by electron microprobe and they are of similar composition to the groundmass minerals. The ferromagnesian megacrysts have exsolution lamellae of Fe-Ti oxides, magnesio–hornblende, and clinopyroxene. The hornblende megacrysts and the lack of plagioclase in the exsolution lamellae are unusual for Proterozoic anorthosites and result from unusual abundance of water in the parental magma. Whole-rock Nd-Sm isotope determinations give an isochron age of ~1.2 Ga. Ar-Ar dating of biotite rims on hornblende shows an early Ordovician plateau age and the final heating step suggests a ~0.8 Ga age for the amphibole itself. Taken together with published zircon geochronology, these data suggest a provenance in the southern peri-Gondwanan Appalachians.
34
Nozhkin, A. D., N. V. Popov, N. V. Dmitrieva, A. A. Storozhenko, and N. F. Vasil’ev. "Neoproterozoic collisional S-type granitoids of the Yenisei Ridge: petrogeochemical composition and U-Pb, Ar-Ar, and Sm-Nd isotope data." Russian Geology and Geophysics 56, no. 5 (May 2015): 689–95. http://dx.doi.org/10.1016/j.rgg.2015.04.001.
35
Nozhkin, A. D., O. M. Turkina, and I. I. Likhanov. "Neoproterozoic Collision Granitoids in the Southwestern Margin of the Siberian Craton: Chemical Composition, U−Pb Age, and Formation Conditions of the Gusyanka Massif." Геохимия 68, no. 5 (May 1, 2023): 471–87. http://dx.doi.org/10.31857/s0016752523050060.
Анотація:
The paper provides evidence that collisional magmatism related to the Neoproterozoic (880−860 Ma) orogenic event occurred in the southwest of the Siberian Craton. Newly obtained data are presented on the major-component and trace-element composition, U−Pb (SHRIMP II) zircon age, and Sm−Nd isotope composition for rocks of the Gusyanka granitoid massif in the Yenisei fault zone of the Yenisei Ridge. The concordant U−Pb zircon age of the Gusyanka massif is 871 ± 11 Ma indicates that its rocks were formed in the mid-Early Neoproterozoic, simultaneously with the rocks of the Kalama and Eruda massifs in the Tatarka−Ishimba fault system, during the same stage of the collisional events at approximately 880–860 Ma. The calc-alkaline granites, granodiorites, and leucogranites of the Gusyanka massif are classified, on the basis of their high alumina content and trace element composition, as S-type and were derived from a metapelitic source. Many trace-element parameters of rocks of the Kalama and Eruda massifs correspond to those of low-potassium I-type granites, which were most likely derived from mafic rocks and tonalites. The granitoids of the Gusyanka massif, on the one hand, and the Kalama and Middle Tyrada massifs, on the other, differ contrastingly in Nd isotope composition. The source of the former was either metapelites of the Tungusik Group or metasedimentary rocks of the Sukhoi Pit Group, with the involvement of juvenile material. The melts of granites of the Kalama and Middle Tyrada massifs might have been derived from a source with the involvement of an older, possibly Paleoproterozoic, crustal material and a juvenile mafic source. Thus, the orogenic events at 880−860 Ma led to the generation of melts at different levels of the Paleo- to Mesoproterozoic crust of the trans-Angara region of the Yenisei Ridge. The geodynamic history of the region is correlated with the synchronous successions and similar style of tectono-thermal events along the peripheries of the large Precambrian cratons of Laurentia and Baltica, and this is consistent with paleocontinental reconstructions of the close spatiotemporal relations between these cratons, Siberia, and their incorporation into Rodinia.
36
Shelepaev, Roman, Maria Shapovalova, Vera Egorova, Yaroslav Shelepov, Tumen-Ulzii Oyunchimeg, and Nadezhda Tolstykh. "Petrology and Age of the Yamaat Uul Mafic Complex, Khangai Mountains, Western Mongolia." Minerals 13, no. 6 (June 20, 2023): 833. http://dx.doi.org/10.3390/min13060833.
Анотація:
The Yamaat Uul mafic complex with Cu-Ni mineralization is located in the Khangai Mountains of Western Mongolia. We have received new unique data for mafic rocks of the complex: U-Pb dating (SHRIMP II), mineralogy (WDS) and geochemistry (XRF, ICP-MS), Sm-Nd and Rb-Sr isotope data and sulphur isotopes. The Yamaat Uul mafic complex consists of two intrusions: Intrusion 1 is represented by rocks of plagioclase cumulates and olivine–pyroxene cumulates; Intrusion 2 consists of monzogabbro. Intrusions 1 and 2 are different in composition of minerals such as olivine, plagioclase and biotite. The monzogabbro has higher contents of incompatible elements (REE, K, Ti, P) than rocks of Intrusion 1. Zircon U-Pb dating of the anorthosite and Bt-Am-Ol gabbronorite shows a Late Permian age (255.8 ± 2.9 Ma and 262.6 ± 3.1 Ma, respectively) for the Yamaat Uul mafic complex. All of the rocks of the complex are derived from a unified parental melt due to different amounts of trapped melts in plagioclase and olivine–pyroxene cumulates and without crustal contamination. The Cu-Ni mineralization of the complex has a low degree of evolution of the sulphide melt, similar to PGE-Cu-Ni mafic–ultramafic intrusions of the Khangai Mountains (Nomgon and Oortsog Uul). The Yamaat Uul mafic complex together with other mafic–ultramafic intrusions of the Khangai Mountains is related to the Khangai LIP and can be considered as potential for the PGE-Cu-Ni. The new geological, petrological, geochemical and isotope–geochronological data can later be used to reconstruct the geotectonics of the Khangai Mountains and the Central Asian orogenic belt as a whole.
37
Maslov, A. V., O. V. Artyushkova, R. Ch Tagarieva, D. V. Kiseleva, M. V. Streletskaya, M. V. Chervyakovskaya, and N. V. Cherednichenko. "REE, Y, Th, U and Mn systematics of Upper Devonian conodonts in the West Uralian Folded Zone (Southern Urals)." LITHOSPHERE, no. 2 (June 12, 2019): 250–68. http://dx.doi.org/10.24930/1681-9004-2019-19-2-250-268.
Анотація:
Research subject. This article presents the results of a study undertaken to investigate the systematics of rare-earth elements (REE), Y, Th, U and Mn in the Upper Devonian conodonts of the Western Ural region of the foreland fold of the Southern Urals (Askyn and Makarovo horizons, Kukkarauk, Ryauzyak and Lemezinsky sections).Methods. The conodonts were isolated from carbonate rocks using the conventional method of their dissolution in organic acids, mainly formic acid. Sample preparation and mass spectrometric analysis were carried out in the class 1000 and 10 000 cleanroom facilities of the Zavaritsky Institute of Geology and Geochemistry. A PerkinElmer ELAN 9000 quadrupole ICP mass-spectrometer was used to determine the concentration of the trace elements under study. Sm and Nd isotope ratios were measured from a 3% nitric acid solution by a Thermo Fischer Neptune Plus multicollector inductively coupled plasma mass-spectrometer. The long-term reproducibility and accuracy of the measurement procedure were evaluated using a standard Merck Nd solution based on the NIST Nd2O3 and yielded 143Nd/144Nd = 0.511720 ± 15 (1 SD, n = 40).Results. The established features of PAAS-normalised lanthanide distributions in the conodont bulk samples (10.4–21.8 mg), Ce-anomalies, high REE values (173–1211 ppm) and a number of other parameters indicate the leading role of late diagenetic processes in the formation of conodont REE systematics. This is also evidenced by the Y/Ho values (≈26–32) specific for the studied conodont samples.Conclusions. In general, the distribution of lanthanides in the conodonts suggests that this process was mainly controlled by a lithogenic (from 90 to more than 99%) REE source. The εNd (t) (–4.0…–2.8) values characteristic of the cono donts of the Askyn and Makarovo horizons suggest that their Nd isotopic composition was either formed under the influence of the open ocean (island arc basin), characterised by a significant share of radiogenic Nd, or due to the entry of radiogenic waters of the ocean into the shelf zone at the peak of the marine transgression that took place in the region under consideration in the Famennian.
38
Humbert, F., A. Hofmann, M. de Kock, A. Agangi, Y.-M. Chou, and P. W. Mambane. "A geochemical study of the Crown Formation and Bird Member lavas of the Mesoarchaean Witwatersrand Supergroup, South Africa." South African Journal of Geology 124, no. 3 (September 1, 2021): 663–84. http://dx.doi.org/10.25131/sajg.124.0022.
Анотація:
Abstract The ca. 2.97 to 2.80 Ga Witwatersrand Supergroup, South Africa, represents the oldest intracontinental sedimentary basin of the Kaapvaal craton. Two volcanic units occur in this supergroup: the widespread Crown Formation lavas in the marine shale-dominated West Rand Group and the more geographically restricted Bird Member lavas, intercalated with fluvial to fluvio-deltaic sandstone and conglomerate of the Central Rand Group. These units remain poorly studied as they are rarely exposed and generally deeply weathered when cropping out. We report whole-rock major and trace elements, Hf and Nd-isotope whole-rock analyses of the lavas from core samples drilled in the south of the Witwatersrand basin and underground samples from the Evander Goldfield in the northeast. In the studied areas, both the Crown Formation and Bird Member are composed of two units of lava separated by sandstone. Whereas all the Crown Formation samples show a similar geochemical composition, the upper and lower volcanic units of the Bird Member present clear differences. However, the primitive mantle-normalized incompatible trace element concentrations of all Crown Formation and Bird Member samples show variously enriched patterns and marked negative Nb and Ta anomalies relative to Th and La. Despite the convergent geodynamic setting of the Witwatersrand Supergroup suggested by the literature, the Crown Formation and Bird Member are probably not related to subduction-related magmatism but more to decompression melting. Overall, the combined trace element and Sm-Nd isotopic data indicate melts from slightly to moderately depleted sources that were variably contaminated with crustal material. Greater contamination, followed by differentiation in different magma chambers, can explain the difference between the two signatures of the Bird Member. Finally, despite previous proposals for stratigraphically correlating the Witwatersrand Supergroup to the Mozaan Group of the Pongola Supergroup, their volcanic units are overall geochemically distinct.
39
Ivanov, K. S., N. V. Vakhrusheva, P. B. Shiryaev, S. I. Drill, and A. E. Stepanov. "On the Nature of the Kharamatolou Structure and the Ratio of the Amount of Ultramafic Rocks of the Voykar-Synya Massif to That of the Ray-Iz Massif, Polar Urals." Geodynamics & Tectonophysics 15, no. 3 (June 18, 2024): 0758. http://dx.doi.org/10.5800/gt-2024-15-3-0758.
Анотація:
There have been petrographic, geochemical, geochronological (Rb-Sr, Ar-Ar) and isotopic (Sm-Nd) studies done on the metamorphic formations of the Kharamatolou structure of the Polar Urals, which were usually assigned to the Precambrian. The temperatures of metamorphism have been shown to range from 450 to 626 °C, and the pressures – from 3.7–9.1 kbar once PT-conditions reached the amphibolite facies. The amphibolites of the Kharamatolou formation are geochemically divided into two groups. According to the distribution spectra of lanthanides and Nd isotope composition, one group has the characteristics similar to depleted N-MORB basalts εNd(0)=+7.0, and another group – those similar to moderately enriched E-MORB basalts εNd(0)=+(4.5–2.4). It has been found that the Kharamatolou structure is probably composed of the Early to Middle Paleozoic continental rise deposit of the Russian Platform, which passed the main stage of folding and metamorphism in the Late Devonian (Rb-Sr, 366±11 Ma). The gabbro-ultrabasic Ray-Iz and Voykar-Synya massifs have been shown to be one during most of their Pre-Triassic history. Now these ultrabasite massifs are separated by the young (Triassic) Kharamatolou uplift which is an erosive-tectonic semi-window where ultrabasic rocks of the Polar-Ural belt are exposed at the base of the thrust fault. The Kharamatolou structure is one of the transverse uplifts of the Urals which probably resulted from the Middle to Late Triassic compression therealong. As a result of the Middle to Late Triassic uplift of the Haramatolou metamorphites, the overlying ultrabasites were washed away by erosion. The mélange serpentinites observed in the center of the Kharamatolou structure are uneroded remnants of the link that once existed between the Ray-Iz and Voikar-Synya massifs. This significantly increases the metallogenic potential of the Voikar-Synya massif, as the Ray-Iz hosts the largest known chromite deposits in Russia.
40
Digonnet, Stéphane, Normand Goulet, James Bourne, Ross Stevenson, and Doug Archibald. "Petrology of the Abloviak Aillikite dykes, New Québec: evidence for a Cambrian diamondiferous alkaline province in northeastern North America." Canadian Journal of Earth Sciences 37, no. 4 (April 3, 2000): 517–33. http://dx.doi.org/10.1139/e00-008.
Анотація:
A dozen ultramafic lamprophyre dykes have been identified in the eastern part of Ungava Bay, Québec. The dark grey dykes are composed of macrocrysts of olivine and phlogopite featuring tetraferriphlogopite rims. These minerals are included in a matrix consisting of fine-grained phlogopite, olivine, spinel, and interstitial carbonate. The geochemical composition, mineral assemblage, chemical analyses of the xenocrysts and phenocrysts and Sm-Nd isotopic signature indicate that these rocks are carbonated ultramafic lamprophyre dykes. The chemical zonation of the micas and the presence of andradite suggest a complex sequence of crystallization. An Ar isotope correlation analysis indicates an age of approximately 550 Ma. The dykes have intruded the Tasiuyak gneiss, a suite of Paleoproterozoic metasedimentary rocks. This unit occupies the Torngat Orogen collision zone between the Rae Province and the Nain Province. The dykes are considered to have been emplaced within tension gashes during reactivation of major Paleoproterozoic structures and fractures associated with the opening of the Iapetus Ocean. They are possibly related to a mantle plume that simultaneously caused both the rupture of the Laurentia and the formation of the ultramafic magma. The Abloviak lamprophyres have quite similar analogues in southwest Greenland. The age, geochemical characteristics, isotopic signature common to all these dykes, the geological environment of the southwest Greenland are all comparable with the data presented here for the Abloviak lamprophyres. Furthermore their pre-drift geographical proximity, prior to the opening of the Labrador Sea, suggests that they are related to a common magmatic event which constitutes a diamondiferous alkaline province located in northeastern North America.
41
Gintov, O. B. "What happened to the Early Precambrian granulite complexes of the Bug region (Ukrainian shield) and the Limpopo belt (South Africa) and how to stratify them? A tectonist’s view." Geofizicheskiy Zhurnal 44, no. 1 (April 3, 2022): 55–82. http://dx.doi.org/10.24028/gzh.v44i1.253711.
Анотація:
The author reviews two alternative approaches (stratigenic-metamorphogenic and deformation-metamorphogenic) to the geology and mapping of the Earth’s oldest crust rocks that were metamorphized in РТ-conditions of the granulite facies, on the examples of two granulite belts — the Bug area complex (Ukrainian shield) and Limpopo belt (Southern Africa).
There was shown a fairly good correlation of the composition and metamorphism (including the dynamometamorphism) of the rock complexes of both belts and their at least three-stage origin and transformation. The granulitic metamorphism processes within both belts happened before 3,0 b.y.a., 2,6—2,8, and c. 2,0 b.y.a. The structural-metamorphic transformations of the granulitic complexes, formation of their new structural plans with the destruction of the former (archean) by the following (proterozoan) do not allow falsifiably stratifying the archean granulitic complexes within the stratigenic-metamorphogenic approach already at the facies level. For the Bug area granulitic belt it is feasible only to isolate the Dniester-Bug and Bug series. Two of the important processes of the belt development are rock deformation in the compression and slip conditions and formation within the granulitic complexes of the sub-vertically-layered medium, slip folds with sub-vertical folds’ joints and wings. In both belts these processes began in the Neoarchean. This shows that in that time the tectonic processes were already to some significant degree propelled by plate tectonics mechanisms. Both belts had in common the formation of the linear-typeshearzonesat micro- to macroscale and their superimposition onto the deformation structures of the granulitic complexes of the preceding developmental stages. On their basis there formed the internal structure of the belts’ and their interconnections with the adjacent blocks of crust. Presumably, the archean charnokitoids and TTG-granitoids form the same structural layer of the crust, given their geochemical similarity and close age, and this layer is the base for the greenstone belts. The mineral composition, РТ-metamorphism conditions and age of granulitic belt rocks based on their U-Pb, Lu-Hf, Sm-Nd isotope systems compositions andoxygen isotope composition in Zirconium grains suggest that in the eo- and paleoarchean mantle and crust there should have already been amassed large quantities of medium-acidic matter which gave rise to the TTG complexes.
42
Vezinet, Adrien, Emilie Thomassot, Yan Luo, Chiranjeeb Sarkar, and D. Graham Pearson. "Diachronous Redistribution of Hf and Nd Isotopes at the Crystal Scale—Consequences for the Isotopic Evolution of a Poly-Metamorphic Crustal Terrane." Geosciences 12, no. 1 (January 12, 2022): 36. http://dx.doi.org/10.3390/geosciences12010036.
Анотація:
In metamorphic rocks, mineral species react over a range of pressure–temperature conditions that do not necessarily overlap. Mineral equilibration can occur at varied points along the metamorphic pressure–temperature (PT) path, and thus at different times. The sole or dominant use of zircon isotopic compositions to constrain the evolution of metamorphic rocks might then inadvertently skew geological interpretations towards one aspect or one moment of a rock’s history. Here, we present in-situ U–Pb/Sm–Nd isotope analyses of the apatite crystals extracted from two meta-igneous rocks exposed in the Saglek Block (North Atlantic craton, Canada), an Archean metamorphic terrane, with the aim of examining the various signatures and events that they record. The data are combined with published U–Pb/Hf/O isotope compositions of zircon extracted from the same hand-specimens. We found an offset of nearly ca. 1.5 Gyr between U-Pb ages derived from the oldest zircon cores and apatite U–Pb/Sm–Nd isotopic ages, and an offset of ca. 200 Ma between the youngest zircon metamorphic overgrowths and apatite. These differences in metamorphic ages recorded by zircon and apatite mean that the redistribution of Hf isotopes (largely hosted in zircon) and Nd isotopes (largely hosted in apatite within these rocks), were not synchronous at the hand-specimen scale (≤~0.001 m3). We propose that the diachronous redistribution of Hf and Nd isotopes and their parent isotopes was caused by the different PT conditions of growth equilibration between zircon and apatite during metamorphism. These findings document the latest metamorphic evolution of the Saglek Block, highlighting the role played by intra-crustal reworking during the late-Archean regional metamorphic event.
43
Huong, Tran Thi, and Nguyen Hoang. "Petrology, geochemistry, and Sr, Nd isotopes of mantle xenolith in Nghia Dan alkaline basalt (West Nghe An): implications for lithospheric mantle characteristics beneath the region." VIETNAM JOURNAL OF EARTH SCIENCES 40, no. 3 (June 4, 2018): 207–27. http://dx.doi.org/10.15625/0866-7187/40/3/12614.
Анотація:
Study of petrological and geochemical characteristics of mantle peridotite xenoliths in Pliocene alkaline basalt in Nghia Dan (West Nghe An) was carried out. Rock-forming clinopyroxenes, the major trace element containers, were separated from the xenoliths to analyze for major, trace element and Sr-Nd isotopic compositions. The data were interpreted for source geochemical characteristics and geodynamic processes of the lithospheric mantle beneath the region. The peridotite xenoliths being mostly spinel-lherzolites in composition, are residual entities having been produced following partial melting events of ultramafic rocks in the asthenosphere. They are depleted in trace element abundance and Sr-Nd isotopic composition. Some are even more depleted as compared to mid-ocean ridge mantle xenoliths. Modelled calculation based on trace element abundances and their corresponding solid/liquid distribution coefficients showed that the Nghia Dan mantle xenoliths may be produced of melting degrees from 8 to 12%. Applying various methods for two-pyroxene temperature- pressure estimates, the Nghia Dan mantle xenoliths show ranges of crystallization temperature and pressure, respectively, of 1010-1044°C and 13-14.2 kbar, roughly about 43km. A geotherm constructed for the mantle xenoliths showed a higher geothermal gradient as compared to that of in the western Highlands (Vietnam) and a conductive model, implying a thermal perturbation under the region. The calculated Sm-Nd model ages for the clinopyroxenes yielded 127 and 122 Ma. If the age is meaningful it suggests that there was a major geodynamic process occurred beneath Western Nghe An in the middle- Early Cretaceous that was large enough to cause perturbation in the evolutional trend of the Sm-Nd isotopic system.ReferencesAn A-R., Choi S.H., Yu Y-g., Lee D-C., 2017. Petrogenesis of Late Cenozoic basaltic rocks from southern Vietnam. Lithos, 272-273 (2017), 192-204.Anders E., Grevesse N., 1989. Abundances of the elements: meteorite and solar. Geochimica et Cosmochimica Acta, 53, 197-214.Anderson D.L, 1994. The subcontinental mantle as the source of continental flood basalts; the case against the continental lithosphere mantle and plume hear reservoirs. Earth and Planetary Science Letter, 123, 269-280.Arai S., 1994. Characterization of spinel peridotites by olivine-spinel compositional relationships: review and interpretation. Chemical Geology, 113, 191-204.Ballhaus C., Berry R.G., Green D.H., 1991. 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Earth Planet Science Letters, 114, 477-489.Hoang-Thi H.A., Choi S.H., Yongjae Yu Y-g., Pham T.H., Nguyen K.H., Ryu J-S., 2018. Geochemical constraints on the spatial distribution of recycled oceanic crust in the mantle source of late Cenozoic basalts, Vietnam. Lithos, 296-299 (2018), 382-395.Izokh A.E., Smirnov S.Z., Egorova V.V., Tran T.A., Kovyazin S.V., Ngo T.P., Kalinina V.V., 2010. The conditions of formation of sapphire and zircon in the areas of alkali-basaltoid volcanism in Central Vietnam. Russian Geology and Geophysics, 51(7), 719-733.Johnson K.T., Dick H.J.B. and Shimizu N., 1990. Melting in the oceanic upper mantle: An ion microprobe study of diopsides in abyssal peridotites. Journal of Geophysical Research (solid earth), 95, 2661-2678.Kölher T.P., Brey G.P., 1990. Calcium exchange between olivine and clinopyroxene calibrated as a geothermobarometer for natural peridotites from 2 to 60 kb with applications. 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Journal of Geophysical Research (solid earth), 120, 1377-1399. Doi:10.1002/2014JB011686.Li C.-F., et al., 2014. Ages and magnetic structures of the South China Sea constrained by deep tow magnetic surveys and IODP Expedition 349 Geochemistry, Geophysics, Geosystems, 14, 4958-4983.Malinovsky A.I., Rashidov V.A., 2015. Compositional characteristics of sedimentary and volcano-sedimentary rocks of Phu Quy-Catwick island group in the continental shelf of Vietnam. Bulletin of Kamchatka Regional Association of ‘Educational - Scientific’ Center, Earth Sciences, 27(3), 12-34 (in Russian with English summary).McCulloch M.T., Wasserburg G.J., 1978. Sm-Nd and Rb-Sr chronology of continental crust formation. Science, 200(4345), 1003-1011.Menzies M.A., Arculus R.L., Best M.G., et al., 1987. A record of subduction process and within-plate volcanism in lithospheric xenoliths of the southwestern USA. In P.H. Nixon (Editor), Mantle Xenoliths, John Wiley & Sons, Chichester, 59-74.Nguyen Hoang, Ogasawara M., Tran Thi Huong, Phan Van Hung, Nguyen Thi Thu, Cu Sy Thang, Pham Thanh Dang, Pham Tich Xuan, 2014. Geochemistry of Neogene Basalts in the Nghia Dan district, western Nghe An. J. Sci. of the Earth, 36, 403 -412.Nguyen Kinh Quoc, Nguyen Thu Giao, 1980. Cenozoic volcanic activity in Viet Nam. Geology and Mineral Resources, 2, 137-151 (in Vietnamese with English abstract).Nixon P.H., 1987 (Editor). Mantle xenoliths. John Wiley and Sons, 844p.Norman M.D. and Garcia M.O., 1999. Primitive magmas and source characteristics of the Hawaiian plume: petrology and geochemistry of shield picrites. Earth and Planetary Science Letters, 168, 27-44.Pollack H.N., Chapman D.S., 1977. On the regional variation of heat flow, geotherms and lithospheric thickness. Tectonophysics, 38, 279-296.Putirka K., 2008. Thermometers and Barometers for Volcanic Systems. In: Putirka, K., Tepley, F. (Eds.), Minerals, Inclusions and Volcanic Processes, Reviews in Mineralogy and Geochemistry, Mineralogical Soc. Am., 69, 61-120. Putirka K.D., 2017. Down the craters: where magmas stored and why they erupt. Methods and Further Reading. Supplement to February 2017 issue of Elements, 3(1), 11-16.Putirka K.D., Johnson M., Kinzler R., Longhi J., Walker D., 1996. Thermobarometry of mafic igneous rocks based on clinopyroxene-liquid equilibria, 0-30 kbar. Contributions to Mineralogy and Petrology, 123, 92-108. Putirka K.D., Mikaelian H., Ryerson F., Shaw H., 2003. New clinopyroxene-liquid thermobarometers for mafic, evolved, and volatile-bearing lava compositions, with applications to lavas from Tibet and the Snake River Plain, Idaho. American Mineralogist, 88, 1542-1554. Qi Q., Taylor L.A., Zhou X., 1995. Petrology and geochemistry of mantle peridotite xenoliths from SE China. Journal of Petrology, 36, 55-79.Sachtleben T.H., Seck H.A., 1981. 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Kostitsyn, Yuri, Nadezhda Krivolutskaya, Alina V. Somsikova, Maria Anosova, Svetlana Demidova, and Artem Konyshev. "Geochemical Features of Potentially Ore-Bearing Mafic Intrusions at the Eastern Norilsk Region and Their Relationships with Lavas (NW Siberian Traps Province)." Minerals 13, no. 2 (February 1, 2023): 213. http://dx.doi.org/10.3390/min13020213.
Анотація:
The problem of the world-class PGE-Cu-Ni Norilsk deposits’ origin has attracted geologists for several decades. The main goal of this study is to determine the specific features of ore-bearing intrusions in comparison with thousands of similar barren intrusions widespread within the Siberian igneous province, and to establish their genesis. As a result of statistical processing of previously published isotope-geochemical data and obtained by the authors, systematic differences were found in the distribution of the isotopic ratio of Nd in ore-bearing and barren intrusions, as well as in volcanic rocks at the Norilsk region. Thus, ore-bearing rocks in ten deposits (Talnakh, Kharayelakh, Norilsk 1, South-Maslovsky, North-Maslovsky, Norilsk 2, Chernogorsky, Zub-Mrksheydersky, Pyasino-Vologochansky, Imangdinsky), different in Ni and PGE reserves, show a very narrow range of Nd isotopic ratio, ԐNd(T) = 1.0 ± 1.0 (2σ, N = 139), whereas barren and volcanic rocks are characterized by a rather wide ԐNd(T) range, from −10 to +7 units (N = 256). Furthermore, ore-bearing intrusions are characterized by reduced and compact variations of the La/Lu ratio due to lower concentrations of light lanthanides. For the first time the authors studied two new intrusions penetrated by MD-48 and MD-60 boreholes drilled by Norislkgeologia LLT at the eastern part of the Mikchangda area. Their economic values are still unclear and should be estimated using geochemical methods. Both intrusions lie in the Devonian rocks, have similar thickness and mineral composition, but differ in textural and structural features, which indicate a rapid crystallization of the MD-48 intrusion. According to the contents of the major oxides, the rocks in MD-48 and MD-60 are identical, but they differ in U/Nb, La/Sm, and Gd/Yb ratios. It is important that the rocks in the MD-60 borehole are characterized by ԐNd(T) = 1.0 ± 0.6 (2σ) and fall into the range of ore-bearing intrusions, whereas the rocks in MD-48 have ԐNd(T) 2.4 ± 0.9, and, thus, are outside of ore-bearing intrusions. Therefore, ԐNd(T) values can be used as a local criterion for the estimation of economic potential of mafic intrusions, which is demonstrated for the Mikachangda area.
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KHILLER, Vera Vitalievna. "Chemical composition and age of monazite-(Ce) in granitoids of the crystalline basement from the South Yamal." NEWS of the Ural State Mining University, no. 4 (December 20, 2020): 28–34. http://dx.doi.org/10.21440/2307-2091-2020-4-28-34.
Анотація:
The relevance of the work is due to the need to improve the method of chemical dating as applied to high-thorium accessory minerals, which are difficult to date by isotope research methods. Purpose of the work: study of the chemical composition of accessory monazite from granitoids of the crystalline basement of the South Yamal and determination of its age. Research methodology: quantitative analysis of the chemical composition of monazite was carried out using X-ray spectral electron probe microanalyzer CAMECA SX 100 (electron beam diameter from 1 μm, BSE, SE, Cat modes, determination of elements from beryllium to uranium). The spectra were obtained with the help of inclined wave spectrometers, the intensity was measured using analytical lines: Th Ma, U Mb, Pb Ma, Y La, Si Ka, Ca Ka, P Ka, Ce La, La La, Pr Lb, Nd La, Sm Lb, Dy La, Gd Lb. The age calculation was carried out according to the well-known methods of foreign authors in addition to some developments of the author. Results. The chemical composition of monazite makes it possible to classify it as a cerium variety, the content of radiogenic components varies greatly (in wt.%): ThO2 – 5.37–16.31, UO2 – 0.40–0.81, PbO – 0.08–0,19. There are significant concentrations of SiO2 (up to 3.5 wt.%), Y2 O3 (up to 1.8 wt.%) and CaO (up to 1.2 wt.%). It turns out that monazite implements hattonite (Th4+(U4+)+Si4+ → REE3++P5+) and cheralite (Th4+(U4+)+Ca2+(Sr2+,Ba2+,Pb2+) → 2REE3+) isomorphism types. The decent content of lead and high crystallinity of the substance makes it possible to use this mineral as a geochronometer mineral. Conclusions. New data on the chemical composition of monazite have been obtained, and the late Permian age of granitoids has been determined by microprobe dating. The values of the point U–Th–Pb ages of monazite together give a weighted average age of 256 ± 10 Ma (MSWD = 0.15) and an isochron of 254 ± 19 Ma (MSWD = 0.28), which almost ideally coincides with the results of isotopic U–Pb zircon dating from the same rock, 254 ± 3 Ma.
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Johansson, Å., D. G. Gee, L. Björklund, and P. Witt-Nilsson. "Isotope studies of granitoids from the Bangenhuk Formation, Ny Friesland Caledonides, Svalbard." Geological Magazine 132, no. 3 (May 1995): 303–20. http://dx.doi.org/10.1017/s0016756800013625.
Анотація:
AbstractThe Caledonian Hecla Hoek succession in Ny Friesland, eastern Svalbard has been interpreted, for many decades, to be a continuous stratigraphic sequence. Early Palaeozoic and Neoproterozoic strata in its upper parts pass more or less conformably down into amphibolite facies rocks (Stubendorffbreen Supergroup) at depth. Recent isotopic age-determination and structural studies have indicated that the Stubendorffbreen succession is tectonostratigraphic and made up of at least three major thrust sheets. This paper provides new data from two meta-igneous units within the succession, the Bangenhuk and Instrumentberget gneisses. Both are granitoid sheets, consisting mainly of red, strongly lineated gneisses of monzogranitic composition; the Bangenhuk unit also contains some lenses of little deformed granitoids, as well as cross-cutting aplite dykes, amphibolitized dolerites and subordinate metasedimentary rocks. The latter are locally cut by granitoids. U—Pb zircon dating of six samples of variably deformed Bangenhuk granitoids, including one cross-cutting aplitic dyke, has yielded ages between 1720 and 1770 Ma, the higher values generally from the less deformed samples. The Instrumentberget gneissic granite yielded an age of 1737+46−41 Ma. These ages are interpreted to date the time of intrusion of the granitoids at around 1750 Ma; the younger ages may have been slightly lowered by Caledonian deformation, particularly those from specimens located close to a major fracture (the Billefjorden Fault Zone) in Wijdefjorden—Austfjorden. U—Pb dating of titanite from the least deformed granitoid also yields comparable Palaeoproterozoic ages; in the more deformed rocks, however, titanites give evidence of Caledonian ductile deformation at c. 410 Ma. The Rb—Sr system of the corresponding whole rock samples has been disturbed and yields an errorchron age of about 1650 Ma and, for some samples, an impossibly low initial Sr ratio. The Sm—Nd system may be more intact and yields initial εNd values of −2 to −3, suggesting some contribution from older crustal material to the granitoid magmas. The results indicate the presence of extensive units of Palaeoproterozoic granitic basement within the Lower Hecla Hoek succession of Ny Friesland, supporting the hypothesis that the latter is composed of tectonically intercalated basement and cover units.
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Skublov, S. G., A. V. Berezin, and L. I. Salimgaraeva. "COMMENTS ON THE ARTICLE AUTHORED BY M.V. MINTS AND K.A. DOKUKINA – THE BELOMORIAN ECLOGITE PROVINCE (EASTERN FENNOSCANDIAN SHIELD, RUSSIA): MESO-NEOARCHEAN OR LATE PALEOPROTEROZOIC?" Geodynamics & Tectonophysics 12, no. 3 (September 17, 2021): 652–61. http://dx.doi.org/10.5800/gt-2021-12-3-0544.
Анотація:
The comments are given on the article authored by M.V. Mints and K.A. Dokukina – The Belomorian Eclogite Province (Eastern Fennoscandian Shield, Russia): Meso-Neoarchean or Late Paleoproterozoic? (Geodynamics & Tectonophysics 2020, 11 (1), 151–200). The Belomorian (White Sea) province of the Fennoscandia Shield is a key site for studying the tectonics of the early periods because numerous Precambrian eclogites have been found there. It was not anticipated, but the problem of age determinations of the eclogite metamorphism of gabbroids in the White Sea mobile belt has turned out to be extremely relevant not only for this region, but also for the Precambrian geology in general. The reason is that a number of authors determine the age of eclogites as Archean (2.7–2.8 Ga), which makes the White Sea mobile belt the only example of the Archean eclogite metamorphism in the world and, therefore, the only dated evidence in support of the plate tectonic model of the evolution of the Earth’s crust at the earliest stage of its formation. The article consistently provides a critical analysis of the arguments put forward by the supporters of the Archean age of the eclogites of the White Sea mobile belt. Special emphasis is made on the isotope geochronological and geochemical features of the composition of zircons from eclogite samples, as well as on the phase and chemical compositions and distribution patterns of mineral inclusions. Considering the age of eclogite metamorphism that led to the formation of eclogites in the White Sea mobile belt, we propose our interpretation based on a set of independent isotope geochemical dating methods, including the local U- Pb method for heterogeneous zircons with magmatic cores and eclogite rims, the Lu-Hf and Sm-Nd methods for the minerals of eclogite paragenesis (garnet and omphacite). And this age interpretation is fundamentally different from the one described in the commented article: all the three methods independently determine the eclogite metamorphism as Paleoproterozoic and yield the same age of circa 1.9 Ga. According to our data, the eclogites of the White Sea mobile belt are among the most ancient high-pressure rocks, their reliably established age of metamorphism is circa 1.9 Ga, and the age of the magmatic protolith is the range of 2.2–2.9 Ga.
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Vorontsov, Alexander A., Andrey E. Izoh, Vladimir V. Yarmolyuk, Tatyana Y. Komaritsyna, Anatoly V. Nikiforov, Olga Y. Perfilova, Sergei I. Dril, Nailya G. Rizvanova, and Egor P. Dushkin. "Evolution of Syenite Magmas: Insights from the Geology, Geochemistry and O-Nd Isotopic Characteristics of the Ordovician Saibar Intrusion, Altai-Sayan Area, Russia." Minerals 11, no. 5 (April 30, 2021): 473. http://dx.doi.org/10.3390/min11050473.
Анотація:
In this paper, we provide insight into the evolution of syenite magmas based on geological data and petrographic, geochemical, and O-Nd isotope parameters of rocks of the Saibar intrusion located within the Minusinsk Trough, Altay-Sayan area. The intrusive suite includes predominant syenites, few bodies of melanocratic and leucocratic nepheline syenites (foyaites), and granites. In addition, dykes of granites and mafic rocks are present. The U-Pb zircon age from the melanocratic foyaites was determined to be 457 ± 10 Ma? Examined rocks show fractionated light rare earth element patterns, normalized to chondrite, with (La/Sm)n varying from 4 to 9, and a weakly fractionated distribution of medium and heavy rare elements, with (Dy/Yb)n from 0.35 to 1.23 and (Sm/Yb)n from 0.63 to 2.62. The spidergram normalized to the primitive mantle shows negative Ba, Sr, Nb, Ta, Ti, and Eu anomalies (Eu* = 0.48–0.60) and positive Rb, Th, and U anomalies. The δ18O values vary within 6.3 to 10.2‰, and εNd(t) from +4.1 to +5.0. We observe gradual transitions from syenites to foyaites. Assimilation by syenite magma of the host carbonate rocks was followed to transition from silica-saturated to silica-undersaturated conditions and removal of anorthite from the melt, which then led to nepheline. Granites of the main phase show depleted lithophile incompatible elements in comparison with syenites and foyaites. They originate via interaction of magmas at the marginal part (endocontact zone) of the intrusion, corresponding to north contact of the granites with the host felsic rocks. In comparison, the rock composition of granite dykes is enriched in lithophile incompatible elements, except for Zr, Hf, and Ti. These rocks are formed due to the differentiation of syenite magma without a significant effect of host rock assimilation. Mantle magmas must be used as parent magmas for syenites based on analysis of the formation model of other alkaline intrusions, which are similar in age to the Saibar intrusion. In the line of syenite intrusions of the Altai-Sayan province, the Saibar intrusion is no exception, and its origin is related to the evolution of mafic magmas that arose during the melting of the mantle under the influence of a mantle plume.
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Oberthür, T., T. G. Blenkinsop, U. F. Hein, M. Höppner, A. Höhndorf, and T. W. Weiser. "Gold mineralization in the Mazowe area, Harare-Bindura-Shamva greenstone belt, Zimbabwe: II. Genetic relationships deduced from mineralogical, fluid inclusion and stable isotope studies, and the Sm-Nd isotopic composition of scheelites." Mineralium Deposita 35, no. 2-3 (March 13, 2000): 138–56. http://dx.doi.org/10.1007/s001260050012.
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Zakharov, Anatoliy Vladimirovich, and Vera Vitalʹevna Khiller. "Monazite from lithium-bearing pegmatites of the Lipovskoye vein field, Middle Urals (composition and chemical dating)." NEWS of the Ural State Mining University, no. 2 (June 15, 2023): 24–31. http://dx.doi.org/10.21440/2307-2091-2023-2-24-31.
Анотація:
The relevance of the research is due to the need to improve the method of chemical dating as applied to high-thorium accessory minerals, which are difficult to study by isotope research methods. Purpose of the research is to study the chemical composition of monazite from lithium-bearing granite pegmatites of the Lipovskoye vein field and to determine their age. Research methodology. The quantitative analysis of the chemical composition of monazite was performed on a CAMECA SX 100 electron probe microanalyzer (IGG UB RAS, Ekaterinburg). Measurement conditions: accelerating voltage 15 kV, current strength 250 nA, electron beam diameter 2 μm. The pressure in the sample chamber is 2 ⋅ 10–4 Pa. The spectra were obtained on tilted wave spectrometers, the intensity was measured using analytical lines: Th Ma, U Mb, Pb Ma, Y La, Si Ka, Ca Ka, P Ka, Ce La, La La, Pr Lb, Nd La, Sm Lb, Dy La, Gd Lb. Standard samples: ThO2 , UO2 , Pb2 P2 O7 , diopside, synthetic rare-earth phosphates. The intensity measurement time at the peak for Th is 180 s, U is 100 s, and Pb is 500 s (240 s on one and simultaneously 260 s on another spectrometer), for Y and Si 20 s each, for the other elements 10 s; on the background – two times less. The detection limits for Th, U, and Pb in monazite are 290, 350, and 64 ppm, respectively. The oxygen content was determined under the assumption of the stoichiometry of the composition. Results. It has been established that monazite belongs to the cerium variety and is characterized by high contents of thorium (ThO2 up to 23.6 wt. %) and uranium (UO2 up to 2.5 wt. %). At the same time, cheralite-type isomorphism is realized in phosphate. In a closed Th–U–Pb-system (β = 0.92–0.97), according to the results of chemical dating (according to 20 analyses), monazite-(Ce) shows a weighted average age of 243 ± 7 Ma. When plotting the dependence (ThO2 + UO2 eq) – PbO, the points fall on one isochrone. Calculation of the age from the slope of the isochron gave a dating of 242 ± 17 Ma, MSWD = 0.21, probability = 1.00. Conclusion. It has been established that accessory monazite from lithium-bearing granitic pegmatites of the Lipovskoye vein field (Middle Urals) is of Triassic age. Apparently, this dating shows the time of the secondary transformation of lithium-bearing granitic pegmatites, which are often tectonized, and in some places even boudinaged.