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Добірка наукової літератури з теми "Single particle ICP-MS/MS"

Автор: Grafiati

Опубліковано: 31 серпня 2024

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Статті в журналах з теми "Single particle ICP-MS/MS"

1

Bustos, Antonio R. Montoro, and Michael R. Winchester. "Single-particle-ICP-MS advances." Analytical and Bioanalytical Chemistry 408, no. 19 (May 21, 2016): 5051–52. http://dx.doi.org/10.1007/s00216-016-9638-1.

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2

Mitrano, Denise M., Angela Barber, Anthony Bednar, Paul Westerhoff, Christopher P. Higgins, and James F. Ranville. "Silver nanoparticle characterization using single particle ICP-MS (SP-ICP-MS) and asymmetrical flow field flow fractionation ICP-MS (AF4-ICP-MS)." Journal of Analytical Atomic Spectrometry 27, no. 7 (2012): 1131. http://dx.doi.org/10.1039/c2ja30021d.

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3

Correia, Manuel, Toni Uusimäki, Allan Philippe, and Katrin Loeschner. "Challenges in Determining the Size Distribution of Nanoparticles in Consumer Products by Asymmetric Flow Field-Flow Fractionation Coupled to Inductively Coupled Plasma-Mass Spectrometry: The Example of Al2O3, TiO2, and SiO2 Nanoparticles in Toothpaste." Separations 5, no. 4 (November 27, 2018): 56. http://dx.doi.org/10.3390/separations5040056.

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According to the current European regulation on cosmetics, any ingredient present as a nanomaterial should be indicated in the ingredient list. There is a need for analytical methods capable of determining the size of the relevant ingredients and thus assessing if these are nanomaterials or not. An analytical method based on asymmetric flow field-flow fractionation (AF4) and inductively coupled plasma-mass spectrometry (ICP-MS) was developed to determine the size of particles present in a commercial toothpaste. Multi-angle light scattering (MALS) was used for on-line size determination. The number-based particle size distributions (PSDs) of the particles were retrieved upon mathematical conversion of the mass-based PSDs recovered from the AF4-ICP-MS fractograms. AF4-ICP-MS allowed to separate and detect Al2O3 and TiO2 particles in the toothpaste and to retrieve a correct TiO2 number-based PSD. The potential presence of particles in the lower size range of the Al2O3 mass-based PSD had a strong impact on sizing and nanomaterial classification upon conversion. AF4 coupled with ICP-MS and MALS was found to be a powerful approach for characterization of different particles in a multiple-particle system such as toothpaste. Confirmation of particle size by a secondary method such as single particle ICP-MS or hydrodynamic chromatography was crucial.

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4

Yongyang, Su, Wang Wei, Li Zhiming, Deng Hu, Zhou Guoqing, Xu Jiang, and Ren Xiangjun. "Direct detection and isotope analysis of individual particles in suspension by single particle mode MC-ICP-MS for nuclear safety." Journal of Analytical Atomic Spectrometry 30, no. 5 (2015): 1184–90. http://dx.doi.org/10.1039/c4ja00339j.

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5

Walbrück, Katharina, Fabian Kuellmer, Steffen Witzleben, and Klaus Guenther. "Synthesis and Characterization of PVP-Stabilized Palladium Nanoparticles by XRD, SAXS, SP-ICP-MS, and SEM." Journal of Nanomaterials 2019 (April 17, 2019): 1–7. http://dx.doi.org/10.1155/2019/4758108.

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Due to increased emissions of palladium nanoparticles in recent years, it is important to develop analytical techniques to characterize these particles. The synthesis of defined and stable particles plays a key role in this process, as there are not many materials commercially available yet which could act as reference materials. Polyvinylpyrrolidone- (PVP-) stabilized palladium nanoparticles were synthesized through the reduction of palladium chloride by tetraethylene glycol (TEG) in the presence of KOH. Four different methods were used for particle size analysis of the palladium nanoparticles. Palladium suspensions were analyzed by scanning electron microscopy (SEM), small angle X-ray scattering (SAXS), single-particle ICP-MS (SP-ICP-MS), and X-ray diffraction (XRD). Secondary particles between 30 nm and 130 nm were detected in great compliance with SAXS and SP-ICP-MS. SEM analysis showed that the small particulates tend to form agglomerates.

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6

Kajner, Gyula, Ádám Bélteki, Martin Cseh, Zsolt Geretovszky, Tibor Ajtai, Lilla Barna, Mária A. Deli, Bernadett Pap, Gergely Maróti, and Gábor Galbács. "Design, Optimization, and Application of a 3D-Printed Polymer Sample Introduction System for the ICP-MS Analysis of Nanoparticles and Cells." Nanomaterials 13, no. 23 (November 25, 2023): 3018. http://dx.doi.org/10.3390/nano13233018.

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Commonly used sample introduction systems for inductively coupled plasma mass spectrometry (ICP-MS) are generally not well-suited for single particle ICP-MS (spICP-MS) applications due to their high sample requirements and low efficiency. In this study, the first completely 3D-printed, polymer SIS was developed to facilitate spICP-MS analysis. The system is based on a microconcentric pneumatic nebulizer and a single-pass spray chamber with an additional sheath gas flow to further facilitate the transport of larger droplets or particles. The geometry of the system was optimized using numerical simulations. Its aerosol characteristics and operational conditions were studied via optical particle counting and a course of spICP-MS measurements, involving nanodispersions and cell suspensions. In a comparison of the performance of the new and the standard (quartz microconcentric nebulizer plus a double-pass spray chamber) systems, it was found that the new sample introduction system has four times higher particle detection efficiency, significantly better signal-to-noise ratio, provides ca. 20% lower size detection limit, and allows an extension of the upper limit of transportable particle diameters to about 25 µm.

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7

Meng, Ziwei, Lingna Zheng, Hao Fang, Pu Yang, Bing Wang, Liang Li, Meng Wang, and Weiyue Feng. "Single Particle Inductively Coupled Plasma Time-of-Flight Mass Spectrometry—A Powerful Tool for the Analysis of Nanoparticles in the Environment." Processes 11, no. 4 (April 17, 2023): 1237. http://dx.doi.org/10.3390/pr11041237.

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Анотація:

Single-particle inductively coupled plasma-mass spectrometry (SP-ICP-MS) has emerged as an important tool for the characterization of inorganic nanoparticles (NPs) in the environment. Although most SP-ICP-MS applications rely on the quadrupole ICP-MS (ICP-QMS), it is limited by the slow scanning speed of the quadrupole. Recent advancements in instrumentation have led to the development of inductively coupled plasma time-of-flight mass spectrometry (ICP-TOF-MS) which offers a viable solution. In this review, we discuss the recent advances in instrumentation and methodology of ICP-TOF-MS, followed by a detailed discussion of the applications of SP-ICP-TOFMS in analyzing NPs in the environment. SP-ICP-TOFMS has the potential to identify and quantify both anthropogenic and natural NPs in the environment, providing valuable insights into their occurrence, fate, behavior, and potential environmental risks.

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8

Franze, Bastian, Ingo Strenge, and Carsten Engelhard. "Separation and detection of gold nanoparticles with capillary electrophoresis and ICP-MS in single particle mode (CE-SP-ICP-MS)." Journal of Analytical Atomic Spectrometry 32, no. 8 (2017): 1481–89. http://dx.doi.org/10.1039/c7ja00040e.

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9

Rua-Ibarz, Ana, Eduardo Bolea-Fernandez, Guillermo Pozo, Xochitl Dominguez-Benetton, Frank Vanhaecke, and Kristof Tirez. "Characterization of iron oxide nanoparticles by means of single-particle ICP-mass spectrometry (SP-ICP-MS) – chemical versus physical resolution to overcome spectral overlap." Journal of Analytical Atomic Spectrometry 35, no. 9 (2020): 2023–32. http://dx.doi.org/10.1039/d0ja00183j.

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In this work, different single-particle ICP-MS (SP-ICP-MS) approaches, relying on either chemical or physical resolution to overcome spectral overlap, have been assessed for their utility in the characterization of iron oxide nanoparticles (IONPs).

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10

Venkatesan, Arjun K., Blanca T. Rodríguez, Aurelie R. Marcotte, Xiangyu Bi, Jared Schoepf, James F. Ranville, Pierre Herckes, and Paul Westerhoff. "Using single-particle ICP-MS for monitoring metal-containing particles in tap water." Environmental Science: Water Research & Technology 4, no. 12 (2018): 1923–32. http://dx.doi.org/10.1039/c8ew00478a.

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Більше джерел

Дисертації з теми "Single particle ICP-MS/MS"

1

Lui, Kwok-on, and 呂國安. "Single particle analysis by time-resolved ICP-MS measurement." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2011. http://hub.hku.hk/bib/B46582630.

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2

Givelet, Lucas. "Détection et caractérisation des nanoparticules de dioxyde de titane dans les aliments par AF4-ICP-MS et Sp-ICP-MS." Thesis, Université Grenoble Alpes (ComUE), 2019. http://www.theses.fr/2019GREAI037/document.

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Les travaux de thèse portent sur le développement de méthodes pour la caractérisation des nanoparticules (NPs) de dioxyde de titane (TiO2) dans les aliments. L’étude a été séparée distinctement en deux axes. Le développement de la méthode AF4-ICP-MS (I) au sein de la Plateforme Nano-Sécurité du CEA de Grenoble et le développement de la méthode Sp-ICP-MS (II) au sein du Laboratoire de la Sécurité Aliments de l’Anses à Maisons-Alfort.Pour le premier axe, les interactions électrostatiques entre les particules et la membrane de l’AF4 ont été étudiées. La charge de surface (potentiel zêta) a été mesuré pour différentes type de particule et membrane en fonction de plusieurs paramètres du solvant tel que le pH, la force ionique ainsi que la présence de tensio-actifs. Suite aux nombreuses analyses effectuées plusieurs conditions de solvant ont été identifiées comme favorable à la répulsion électrostatique entre les particules et la membrane ce qui permettrai de diminuer les pertes de particules au niveau de la membrane. Plusieurs conditions ont donc été testées directement pour l’analyse de NPs de TiO2 en AF4-ICP-MS. Il a ainsi été montré que les conditions favorisant les répulsions électrostatiques permettaient d’améliorer le taux dé récupération des particules au niveau du système AF4. Cependant les analyses ont aussi montré que les NPs de TiO2 n’étaient pas suffisamment dispersées pour pouvoir obtenir une distribution en taille fiable.Le second volet de la thèse, a eu pour but, dans un premier temps, d’optimiser le traitement de données de la méthode Sp-ICP-MS. Plusieurs améliorations ont été réalisées comme le calcul automatique du seuil bruit de fond-particule, le calcul de l'efficacité de transport où encore l'ajout de paramètres de contrôle qualité. Ce traitement de données a ensuite été comparée à un logiciel dédié aux analyses par Sp-ICP-MS et a permis de mettre en avant que la feuille de calcul interne donne des résultats avec une meilleure justesse, tout en fournissant des paramètres supplémentaires.Dans un second temps une optimisation de la méthode Sp-ICP-MS a été réalisée. Plusieurs paramètres ont donc été évalués comme le choix de l’isotope de titane, le temps d’acquisition, le type de solvant pour disperser les particules, ainsi que le mode de prélèvement de l’échantillon et son débit.Enfin, plusieurs aliments ont été analysés après avoir mis en place un protocole d’extraction des NPs. Les résultats obtenus ont permis de déterminer une distribution en taille des NPs de TiO2 présentes dans les échantillons
The thesis focuses on the development of methods for the titanium dioxide (TiO2) nanoparticles (NPs) characterization in food products. The study was separated distinctly into two axes. The development of the AF4-ICP-MS (I) method within the CEA Nano-Safety Platform in Grenoble and the development of the Sp-ICP-MS (II) method within the Food Safety Laboratory of the Anses in Maisons-Alfort.For the first axis, the electrostatic interactions between the particles and the AF4 membrane were studied. The surface charge (zeta potential) was measured for particles and membranes depending on several solvent parameters such as pH, ionic strength and the presence of surfactants. Following the several analyzes carried out, several solvent conditions have been identified as promoting the electrostatic repulsion between the particles and the membrane, which will make it possible to reduce the losses of particles at the level of the membrane. Several conditions were therefore directly tested for NPs analysis of TiO2 in AF4-ICP-MS. It has thus been shown that the conditions favoring electrostatic repulsions make it possible to improve the efficiency of the particles at the level of the AF4 system. However, the analyzes also showed that the TiO2 NPs were not sufficiently dispersed to obtain a reliable size distribution.The second part of the thesis aimed at first optimizing the data treatment of the Sp-ICP-MS method. Several improvements have been made such as the automatic calculation of the background-particle threshold, the calculation of the transport efficiency or the addition of quality control parameters. This data treatment was then compared to a software dedicated to analyzes by Sp-ICP-MS and made it possible to highlight that the internal spreadsheet gives results with a better accuracy, while providing additional parameters.In a second time an optimization of the Sp-ICP-MS method was carried out. Several parameters were therefore evaluated such as the choice of the titanium isotope, the acquisition time, the type of solvent to disperse the particles, as well as the sample collection mode and its flow rate.Finally, several foods were analyzed after setting up an extraction protocol for NPs. The results obtained made it possible to determine a size distribution of the NPs of TiO2 present in the samples

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3

Mozhayeva, Darya [Verfasser]. "Single particle ICP-MS : capabilities of microsecond time resolution and coupling to capillary electrophoresis / Darya Mozhayeva." Siegen : Universitätsbibliothek der Universität Siegen, 2019. http://d-nb.info/1193252180/34.

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4

Craig, Grant. "Improving the utility of LA-ICP-MS for isotope ratio analyses of single particles with application to uranium oxide." Thesis, Loughborough University, 2016. https://dspace.lboro.ac.uk/2134/21518.

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The determination of the isotopic composition of single uranium oxide particles, size 0.3-2 μm, for nuclear safeguards is current performed by either thermal ionisation mass spectrometry (TIMS) or Secondary Ion Mass Spectrometry (SIMS). Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS), a well-established analytical technique for determining the isotopic composition of solid materials, has the potential to be another method by which single uranium oxide particles can be analysed, complementing established protocol, but requires optimisation. In this study the ability of LA-ICP-MS to determine the isotopic composition, principally 234U/238U, 235U/238U and 236U/238U, of glass reference materials and sub-micron uranium oxide particles is investigated. To achieve the best detection efficiency a prototype high-speed ablation cell and injector design, designed previously at Loughborough University, was coupled to a high efficiency multi collector (MC-) ICP-MS. As a result an increase in signal-to-noise ratio and a measured detection efficiency of 5-7% was achieved for a LA-MC-ICP-MS system. The capability of the LA-MC-ICP-MS system, for the determination of the uranium isotopic composition of single particles was compared to a more established low-volume ablation cell. A source of additional uncertainty, blind time arising from incompatibilities with the mixed detector array of the MC-ICP-MS was identified. The impact of the additional uncertainty on isotope ratio analysis was modeled and a method developed to filter out affected data. LA-ICP-MS and LA-MC-ICP-MS were used to successfully determine the uranium isotopic compositions of sub-micron uranium oxide particles, of a known certified composition. A sample planchet containing particles of two distinct isotopic compositions was resolved. The utility of three data evaluation strategies to determine the isotopic composition of single uranium oxide particles was investigated. The necessity and advantages of calculating isotope ratios using the geometric mean is demonstrated, which has application for isotope ratio analysis performed on all forms of mass spectrometry. A novel approach to prepare particulate samples for laser ablation analysis, cytocentrifugation, is described. By using as the solvent, a mixture of nail polish and acetone, dispersed particles are held in a strong film layer thin enough to allow embedded particles to be imaged by SEM-EDX. A sample of uranium oxide particles in an environmental matrix prepared using cytocentrifugation is analysed by LA-MC-ICP-MS and their isotopic composition resolved.

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5

Schmidt, Benita. "Detection and Characterisation of Nanoparticles using Inductively Coupled Plasma Mass Spectrometry." Doctoral thesis, Humboldt-Universität zu Berlin, 2019. http://dx.doi.org/10.18452/20162.

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Анотація:

In dieser Doktorarbeit wurde eine analytische Methode zur Charakterisierung metallischer Nanopartikel (NPs) entwickelt und die Methode bei der Untersuchung natürlicher Proben angewendet. Mit einem analytisches System bestehend aus einem Mikrotropfengenerator (microdroplet generator, MDG) zusammen mit einem pneumatischen Zerstäuber und einem induktiv gekoppeltem Plasma-Massenspektrometer (ICP-MS) konnte eine quantitative und qualitative Charakterisierung von NPs durchgeführt werden. Der MDG wurde verwendet um die Kalibrierungsfunktion für die massenspektrometrische Quantifizierung der Metalle in den Nanopartikelproben, die über den pneumatischen Zerstäuber eingeführt wurden, einzurichten. Der Hauptvorteil dieser Anordnung besteht darin, dass mit dem MDG für jedes Metall Tropfen einer gewünschten Größe hergestellt werden können und eine 100 %-ige Transporteffizienz gegeben ist. Die eingeführte Masse korrelierte mit der Signalintensität von Nanopartikeln, so dass die mit dem MDG generierten Tropfen für die Kalibrierung verwendet werden konnten ohne dass Referenzmaterial erforderlich war. Die aufwändige und fehleranfällige Bestimmung der Effizienz eines Zerstäubers, die für die Bestimmung des Metallgehaltes von NPs mittels eines Einzelpartikel-ICP-MS (spICP-MS) erforderlich ist, konnte dadurch vermieden werden. Unter Anwendung dieser dualen Einführungsmethode wurden Größen und Konzentrationen einer Reihe von Standard Silber (Ag) NPs und Referenz Gold (Au) NPs mit hoher Genauigkeit bestimmt. Zusätzlich wurde mit einem neuen kommerziell verfügbaren ICP-Flugzeitmassenspektrometer (ICP-TOF-MS) Ag und Au NPs in unterschiedlichen Matrices charakterisiert: in verschiedenen Salzsäure (HCl)- und Salpetersäure (HNO3)- Konzentrationen und in Gegenwart verschiedener Elemente. Bei den unterschiedlichen Matrices war die Größenbestimmung innerhalb der gegebenen Standardabweichungen korrekt.
In this doctoral thesis an analytical method for characterising metal nanoparticles (NPs) was developed and its application for investigating natural samples verified. An analytical system consisting of a microdroplet generator (MDG) used in combination with a pneumatic nebuliser (PN) and an inductively coupled plasma mass spectrometer (ICP-MS) proved capable of quantitatively and qualitatively identifying NPs. The MDG was used to establish the calibration function for mass quantification of the metal present in the sample NPs introduced via the PN. The major advantage of this configuration is that the MDG generated droplets of tailored size for any given metal while offering a 100 % transport efficiency. The introduced mass correlated with signal intensities of NPs and thus the microdroplet generated droplets could be used for calibration purposes without the need for any reference material. Thus, the tedious and error-prone nebuliser efficiency determination step that is required when determining the NP metal content using the single particle mode ICP-MS (spICP-MS) approach, could be avoided. With this dual sample introduction method, the sizes and concentrations of a range of standard silver (Ag) NPs and gold (Au) reference NPs were determined with high accuracy. Additionally, together with a new commercially available ICP-time of flight-MS (ICP-TOF-MS) the characterisation of Ag- and Au-NPs was carried out in various matrices: In hydrochloric (HCl) and nitric acid (HNO3) at a range of concentration and in different elemental environments. In the presence of matrices, it was found that the size characterisation of the NPs is correct within the standard deviation.

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Sötebier, Carina Anna. "Charakterisierung von Silber-Nanopartikeln mit der Feldflussfraktionierung, Hochdruckflüssigkeitschromatographie und der induktiv gekoppelten Plasma-Massenspektrometrie." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät, 2017. http://dx.doi.org/10.18452/17743.

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Im Rahmen dieser Arbeit wurden vier verschiedene Methoden zur Separation, Identifikation sowie Quantifizierung von Silber-Nanopartikeln (Ag-NP) entwickelt. Mittels asymmetrischer Fluss-Feldflussfraktionierung (AF4) in Kombination mit einem induktiv gekoppelten Plasma-Massenspektrometer (ICP-MS) konnten eine gute Trennung und hohe Wiederfindungsraten gefunden werden. Eine systematische Studie möglicher Probenverluste während der Methodenoptimierung zeigte, dass der größte Verlust durch die Ag+-Ionen verursacht wurde, während Verluste durch Ablagerungen auf der Membran vernachlässigbar waren. Für Citrat-stabilisierte Ag-NP konnten mittels Hohlfaser-Fluss-Feldflussfraktionierung (HF5) gute Trennergebnisse erreicht und der hydrodynamische Durchmesser bestimmt werden. Zur Bestimmung der Partikelanzahlgrößenverteilung und des geometrischen Durchmessers von Partikeln in unbekannter Matrix wurde die Isotopenverdünnungsanalyse (IVA) erfolgreich mit der Einzelpartikel ICP-MS kombiniert. Weiterhin wurde eine Hochdruckflüssigkeitschromatographie(HPLC)-IVA-ICP-MS-Methode entwickelt, mit welcher NP und ihre korrespondierenden Ionen getrennt und quantifiziert werden konnten. Ein Vergleich der Ansätze zeigt, dass eine Kombination mehrerer Methoden nötig ist, um alle relevanten Informationen über die NP zu erhalten. Zum Abschluss wurde mit den entwickelten Methoden das Umweltverhalten der Ag-NP in einer Huminsäure(HS)-Suspension untersucht. Hierbei wurden erste Stabilisierungseffekte in Bezug auf die Ag-Konzentration und Partikelanzahl festgestellt. Zudem konnte mittels HF5 und HPLC für kleine NP in HA eine Modifikation in Form der Ausbildung eines zweiten, kleineren NP-Signals beobachtet werden.
In this work, four different methods for the separation, identification, and quantification of silver nanoparticles (Ag-NP) were developed. Using asymmetric flow field-flow fractionation (AF4) in combination with inductively coupled plasma mass spectrometry (ICP-MS), a good separation and high recovery rates were found. A systematic investigation of possible sample losses during the method optimization showed that Ag+ ions caused the highest loss and only negligible amounts of Ag residues on the membrane were found. For citrate-stabilized Ag-NP, hollow fiber flow-field flow fractionation (HF5) analyses achieved good results for the separation and calculation of the hydrodynamic diameters. In order to determine the particle number size distribution and the geometric diameter for samples in unknown matrices, isotope dilution analysis (IVA) was successfully combined with single particle ICP-MS. Additionally, a high-performance liquid chromatography (HPLC)-IVA-ICP-MS approach was developed, which was able to separate and quantify NP and their corresponding ions. A comparison of the methods showed that a combination of different approaches is necessary to obtain all relevant information. Finally, the methods were applied to analyze the environmental behavior of Ag-NP in a humic acid (HS) suspension. Here, first stabilization effects in terms of the Ag concentration and particle number concentration were detected. Using HF5 and HPLC for the analysis of small NPs in HS, a modification in the form of a second, smaller NP signal was observed.

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Bastardo-Fernandez, Isabel. "Vers une fiabilité améliorée de la détermination de (nano)particules de TiO2 par single particle inductively coupled plasma-mass spectrometry : application à la caractérisation des aliments et aux études de migration." Electronic Thesis or Diss., Maisons-Alfort, École nationale vétérinaire d'Alfort, 2024. http://www.theses.fr/2024ENVA0001.

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Le projet de thèse NanoTi-Food vise principalement à améliorer la fiabilité de la caractérisation des nanoparticules de TiO2 (NPs) et à acquérir des connaissances sur l'additif alimentaire E171 y compris la migration de ces NP à partir des emballages alimentaires. Dans la première partie de l'étude (à réaliser à Anses), une nouvelle approche pour la caractérisation des NP de TiO2 sera développée et optimisée en utilisant l'approche « single particle » en combinaison avec la spectrométrie de masse à plasma à couplage inductif triple quadripôle (Sp-ICP- QQQMS). À cette fin, les paramètres analytiques les plus critiques, tels que les méthodes de calcul de l'efficacité du transport (TE) et le système d'introduction des échantillons seront évalués dans différentes conditions de travail (par exemple gaz de réaction, choix de l'isotope). Dans ce dernier cas, deux systèmes d'introduction d'échantillons à haut rendement (type APEX) seront comparés. Par ailleurs, une approche Sp complémentaire basée sur la MS-ICP haute résolution (Sp-ICP-HR MS) sera développée au LNE. La nouveauté dans ce cas sera l'utilisation d'un ICP-MS à haute résolution (champ de secteur magnétique) pour la détection, qui est la technique de pointe pour la détermination des éléments traces métalliques fortement interférés tels que le Ti. Un système d'injection interne sera également optimisé pour augmenter l'efficacité et la sensibilité du transport de l'échantillon. La validation de la méthode sera réalisée par comparaison inter-laboratoires entre le LNE et l'Anses. Une véritable valeur ajoutée du projet sera l'évaluation de l'incertitude de mesure liée à la caractérisation des NP de TiO2 par les deux approches Sp-ICP-MS (QQQ et HR). Les calculs d'incertitude prendront en compte non seulement la reproductibilité expérimentale et les incertitudes de chacune des variables nécessaires pour convertir le signal ICP-MS en taille et concentration de NPs, mais aussi et pour la première fois, l'effet du choix du seuil pour discriminer le signal ionique ICP-MS de celui des NP. L'effet des écarts par rapport à la forme sphérique sur les tailles sera également étudié et comparé à la microscopie électronique à balayage (MEB), qui est la méthode de référence pour la caractérisation des NP. Le projet vise également la préparation et la caractérisation exhaustive d'un matériau de référence réel (additif alimentaire) contenant des nanoparticules de TiO2. Une étude de faisabilité du développement d'une MR à base de E171 sous forme de suspension sera réalisée. À cette fin, un échantillon E171 représentatif sera préparé et entièrement caractérisé par un panel de techniques complémentaires, telles que SEM, Sp-ICP-QQQMS, Sp-ICP-HR MS, diffraction des rayons X (XRD) pour évaluer avec précision les principaux paramètres d'intérêt, tels que le diamètre médian et moyen, la distribution de taille, la fraction de nanoparticules, les impuretés chimiques et la fraction cristallographique. Enfin, les deux approches analytiques développées à l'Anses et au LNE, dont la méthode développée pour l'évaluation de l'incertitude globale, seront appliquées à l'étude du transfert des NP de TiO2 à partir des emballages alimentaires. Tout au long du projet, les données de taille obtenues en utilisant les nouvelles approches basées sur l'approche « single particle » pour la caractérisation des NP de TiO2 seront comparées aux mesures SEM, qui est la méthode de référence pour la taille dans ce domaine d'étude. Les études sur la migration des emballages alimentaires sont en effet une étude de cas sélectionnée où la Sp-ICP-MS a le potentiel de fournir des informations supplémentaires par rapport à d'autres paramètres tels que la concentration de particules, la proportion de particules par rapport à la forme dissoute, qui sont également importantes pour la migration qui est important afin d'améliorer les études d'évaluation des risques
This PhD project aims primarily to improve the reliability of the characterisation of TiO2 nanoparticles (NPs) and to gain knowledge of the food additive E171 and in real-life applications such as migration of these NPs from food packaging. In the first part of the study (to be carried out at Anses), a new approach for TiO2 NPs characterisation will be developed and optimized by using the single particle approach in combination with inductively coupled plasma-triple quadrupole mass spectrometry (Sp-ICP-QQQMS). For this purpose, the most critical analytical parameters, such as the transport efficiency (TE) calculation methods and the sample introduction system will be assessed under different working conditions (e.g. reaction gas, choice of isotope). In the latter case, two high efficiency sample introduction systems (APEX type) will be critically compared. Further, a complementary Sp approach based on ICP-high resolution MS (Sp-ICP-HRMS) will be developed at LNE. The novelty in this case will be the use of a high resolution (magnetic sector field) ICP-MS for detection, which is the state-of-the art technique for trace and ultra-trace metals determination of highly interfered elements such as the case of Ti. An in-house injection system will also be optimized to increase the transport efficiency and sensitivity. Method validation by inter-laboratory comparison between LNE and ANSES will be achieved here. A truly added value of the project will be the assessment of the measurement uncertainty related to TiO2 NPs characterization by both Sp-ICP-MS (QQQ and HR) approaches. The uncertainty calculations will take into account, not only the experimental reproducibility and the uncertainties of each variables required to convert ICP-MS signal into NPs size and concentration, but also and for the first time, the effect of the choice of the cut-off to discriminate the ICP-MS ionic signal from that of NPs. The effect of deviations from the spherical shape on the sizes will also be explored and compared with scanning electron microscopy (SEM), which is the reference method for NPs characterisation. The project also aims at the preparation and exhaustive characterization of a real-life (food additive) reference material containing TiO2 nanoparticles. A feasibility study of the development of an E171-based RM under a suspension form will be carried out. For this purpose, a representative E171 sample will be prepared and fully characterized by a panel of complementary techniques, such as SEM, Sp-ICP-QQQ MS, Sp-ICP-HRMS, X-ray diffraction (XRD) to accurately assess the main parameters of interest, such as the median and mean diameter, size distribution, fraction of nanoparticles, chemical impurities and crystallographic fraction. Finally, both analytical approaches developed at Anses and LNE, including the developed method for global uncertainty assessment, will be applied to the study of the transfer of TiO2 NPs from food packaging. All along the project, the size data obtained by using the newly developed “single particle” based approaches for TiO2 NPs characterisation will be compared to SEM measurements, which is the reference method for size in this study field. Food packaging migration studies is indeed a selected case study where Sp-ICP-MS has the potential of supplying additional information compared to other instruments, such as: particle concentration, proportion of particulate vs. dissolved form, which are of importance for migration as well as to improve risk assessment studies

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Chan, Ka-lok, and 陳嘉樂. "Single droplet generation by dripping-mode electrospray for ICP-MS measurement." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/202348.

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9

Löhr, Konrad. "Arraying of single cells for high throughput elemental analysis using LA-ICP-MS." Doctoral thesis, Humboldt-Universität zu Berlin, 2019. http://dx.doi.org/10.18452/20573.

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Induktiv gekoppelte Plasma-Massenspektrometrie mit Laserablation (LA-ICP-MS) wird zunehmend für die Einzelzellanalyse eingesetzt, jedoch wird eine weitere verbreitete Verbreitung durch den geringen Durchsatz behindert. Daher wurde in dieser Arbeit der Durchsatz von Einzelzellen-LA-ICP-MS untersucht und verbessert. Zunächst werden die beiden möglichen Ablationsmodi, Bildgebung und Einzelpunktanalyse (SSA), hinsichtlich ihrer analytischen Gütezahlen (Signal-Rausch-Verhältnis, Präzision, Genauigkeit, Durchsatz) verglichen. Hierfür wurden adhärente 3T3-Fibroblastenzellen mit zwei Metallfarbstoffen angefärbt und mit beiden Methoden mehrere Dutzend Zellen vermessen. SSA zeigte überlegene Eigenschaften hinsichtlich Durchsatz und Nachweisgrenzen. Darüber hinaus wurde gezeigt, dass >400 Zellen analysiert werden müssen, um zufriedenstellende Statistiken für einen quantitativen Vergleich der Ergebnisse zu erhalten, was als zu mühsam befunden wurde. Daher wurde ein Einzelzellen-Arraying-Schritt integriert, um eine automatisierte LA-ICP-MS-Analyse zu ermöglichen. Hierfür wurden zwei Arrayingverfahren getestet: Zunächst wurde das mikrofluidische Arraying von Zellen getestet, jedoch verhinderte das Einklemmen von weichen PDMS-Chips eine erfolgreiche Anwendung, und eine Neugestaltung des Chips wäre erforderlich. Daraufhin wurde eine neuartige Technologie getestet, die auf dem Arraying von Tröpfchen in Verbindung mit der Bilderkennung von Zellen beruht, wobei ein Anordnungsdurchsatz von 550 Zellen pro Stunde und eine beispiellose Einzelzellengenauigkeit (> 99%) gefunden wurde. In einem Proof-of-Principle-Experiment wurde ein Zellarray von THP-1-Suspensionszellen mittels LA-ICP-TOF-MS analysiert und erstmals gleichzeitig endogene und exogene Isotope einzelner Zellen als Isotopen-Fingerabdrücke von Zellen mit Nachweisgrenzen von lediglich wenigen hundert attogramm. Schließlich wurden diese Ergebnisse mit der derzeit gebräuchlichsten Analysemethode Single-Cell (sc)-ICP-MS verglichen.
Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is increasingly used for single-cell analysis. However, a more widespread use of LA-ICP-MS in single cell analysis is hampered by its low throughput. Hence, in this work the throughput of single cell LA-ICP-MS was studied and improved. First, the two possible ablation modes, imaging and single spot analysis (SSA) of single cells using a large laser spot, are compared regarding their analytical figures of merit (signal to noise, precision, accuracy, throughput), as well as regarding ease of operation and data evaluation. For that, adherent 3T3 fibroblast cells were stained with two metal dyes and several dozen cells were measured using both modes. SSA showed superior characteristics regarding throughput and detection limits. Moreover, it was shown that >400 cells must be analyzed to reach satisfactory statistics for a quantitative comparison of results, which would have been too laborious. Thus, a single cell arraying step was integrated to enable automated LA-ICP-MS analysis. Two different arraying methods were evaluated: First, arraying via hydrodynamic front trapping of cells using a microfluidic device was tested, but clamping of soft PDMS-chips prevented successful arraying and it was concluded that a major redesign of the chip is necessary. Secondly, and a novel technology relying on a microdroplet arrayer in conjunction with image recognition of cells was tested and a moderate arraying throughput (550 cells per hour) and an unprecedented single-cell accuracy (>99%) was found. In a proof of principle experiment, a cell array of THP-1 suspension cells was analyzed using LA-ICP-TOF-MS and endogenic and exogenic isotopes of individual cells were detected for the first time simultaneously as isotopic fingerprints of cells with detection limits as low as hundred attogram. Finally, these results were compared to the currently more commonly used analysis method single-cell (sc)-ICP-MS.

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10

Stenberg, Anna. "Isotopic analyses of biological materials by single and multi-collector sector field ICP-MS." Licentiate thesis, Luleå, 2004. http://epubl.luth.se/1402-1757/2004/011.

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Частини книг з теми "Single particle ICP-MS/MS"

1

Mozhayeva, Darya, and Carsten Engelhard. "CE Coupled to ICP-MS and Single Particle ICP-MS for Nanoparticle Analysis." In Capillary Electrophoresis-Mass Spectrometry, 243–57. New York, NY: Springer US, 2022. http://dx.doi.org/10.1007/978-1-0716-2493-7_16.

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2

Miyashita, Shin-ichi, Shin-ichiro Fujii, Kaori Shigeta, and Kazumi Inagaki. "Single Cell Analysis by Using ICP-MS." In Metallomics, 107–24. Tokyo: Springer Japan, 2017. http://dx.doi.org/10.1007/978-4-431-56463-8_5.

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3

Paulsen, Susan C., and E. John List. "A Study of Transport and Mixing in Natural Waters Using ICP-MS: Water-Particle Interactions." In The Interactions Between Sediments and Water, 149–56. Dordrecht: Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-011-5552-6_16.

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4

Zhang, Peng, Songzhe Chen, Laijun Wang, and Ping Zhang. "Study on the High-Performance Catalyst for Sulfuric Acid Decomposition in the IS Cycle." In Proceedings of the 10th Hydrogen Technology Convention, Volume 1, 370–82. Singapore: Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-99-8631-6_36.

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AbstractThe iodine-sulfur cycle coupled with a high-temperature gas-cooled reactor is a clean and efficient hydrogen production technology. The sulfuric acid decomposition reaction is the highest temperature process in the iodine-sulfur cycle, which requires 850 °C high temperature and catalyst to carry out at a high conversion rate. This study prepared a series of loaded sulfuric acid decomposition catalysts using anatase TiO2 and Ta2O5 as catalyst carriers and precious metal Pt as the active component. XRD, BET, and ICP-MS characterization of the catalysts demonstrated that the high calcination temperature could increase the crystallinity and content of the active components and decrease the specific surface area of the catalysts. The Pt/TiO2-850 catalyst showed good performance under different feed concentrations, reaction temperatures, and particle sizes. In addition, the scale-up production does not affect the Pt/TiO2-850 catalyst reaction performance. The Pt/TiO2-850 catalyst was tested in a bayonet-tube SiC reactor with a 100-h high throughput lifetime, which proved that the Pt/TiO2-850 catalyst has good stability.

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5

Goenaga-Infante, Heidi, and Dorota Bartczak. "Single particle inductively coupled plasma mass spectrometry (spICP-MS)." In Characterization of Nanoparticles, 65–77. Elsevier, 2020. http://dx.doi.org/10.1016/b978-0-12-814182-3.00003-1.

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6

Montaño, Manuel David. "Single Particle Inductively Coupled Plasma-Mass Spectrometry (spICP-MS): Engineered Nanoparticle Characterization." In Dekker Encyclopedia of Nanoscience and Nanotechnology, Third Edition, 1–7. Taylor & Francis, 2015. http://dx.doi.org/10.1081/e-enn3-120053517.

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7

Sumalatha, Edapalli, Dachepalli Ravinder, Nyathani Maramu, Shubha, Butreddy Ravinder Reddy, Sadhana Katlakunta, Koteswari Gollapudi, and Rajender Thota. "Crystal Chemistry, Rietveld Analysis, Structural and Electrical Properties of Cobalt-Erbium Nano-Ferrites." In Ferrite [Working Title]. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.98864.

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Synthesis of Cobalt-Erbium nano-ferrites with formulation CoErxFe2-xO4 (x = 0, 0.005, 0.010, 0.015, 0.020, 0.025, and 0.030) using technique of citrate-gel auto-combustion was done. Characterization of prepared powders was done by using XRD, EDAX, FESEM, AFM and FTIR Spectroscopy, DC resistivity properties respectively. XRD Rietveld Analysis, SEM, TEM and EDAX analysis were taken up in studying spectral, structural, magnetic and electrical properties. XRD pattern of CEF nano particles confirm single phase cubic spinal structure. The structural variables given by lattice constant (a), lattice volume (v), average crystallite size (D) and X-ray density(dx), Bulk density (d), porosity (p), percentage of pore space (P%), surface area (s), strain (ε), dislocation density (δ), along with ionic radii, bond length and hoping length were calculated. SEM and TEM results reveal homogeneous nature of particles accompanied by clusters having no impurity pickup. TEM analysis gives information about particle size of nanocrystalline ferrite while EDAX analysis confirm elemental composition. Emergence of two arch shaped frequency bands (ν1 and ν2) that represent vibrations at tetrahedral site (A) and octahedral site(B) was indicated by spectra of FTIR. The samples electrical resistivity (DC) was measured between 30°C -600°C with Two probe method. XRD Rietveld analysis confirm crystallite size lying between 20.84 nm–14.40 nm while SEM analysis indicate formation of agglomerates and TEM analysis indicate particle size ranging between 24 nm–16 nm. DC Electrical measurements indicate continuous decrease in resistivity with increasing temperature while increasing doping decreases curie temperature. The Magnetic parameters such as Saturation magnetization (Ms), Remanent magnetization (Mr), Coercivity (Hc) and Squareness ratio (R = Mr/Ms), Magnetic moment (nB) were altered by doping of Er+3 content in the increasing order (x = 0.00 to 0.030). The increasing erbium content decreases magnetization thus converting the sample into soft magnetic material. Observations indicated strong dependence of magnetic properties on Erbium substitution and coercivity varies in accordance with anisotropy constant. Due to the presence of magnetic dipole Erbium substituted cobalt ferrites can be used in electromagnetic applications. The present study investigates the effect of different compositions of Er3+ replaced for Fe on structural properties and electrical resistivity of cobalt ferrites.

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8

Montes-Bayón, Maria, Mario Corte-Rodríguez, Roberto Álvarez-Fernández García, and Juliana Severo Fagundes. "Biomedical analysis by ICP-MS: A focus on single cell strategies." In Comprehensive Analytical Chemistry. Elsevier, 2022. http://dx.doi.org/10.1016/bs.coac.2022.03.002.

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9

Montes-Bayón, Maria, Mario Corte-Rodríguez, Roberto Álvarez-Fernández García, and Juliana Severo Fagundes. "Biomedical analysis by ICP-MS: A focus on single cell strategies." In Comprehensive Analytical Chemistry. Elsevier, 2022. http://dx.doi.org/10.1016/bs.coac.2022.03.002.

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10

Álvarez-Fernández García, Roberto, Mario Corte-Rodríguez, Paula García-Cancela, Jörg Bettmer, and María Montes-Bayón. "Application of online sample introduction systems for single-cell analysis with ICP-MS." In Analytical Nebulizers, 197–216. Elsevier, 2023. http://dx.doi.org/10.1016/b978-0-323-91181-8.00011-4.

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Тези доповідей конференцій з теми "Single particle ICP-MS/MS"

1

Mansor, Muammar, Ankita Chauhan, Sören Drabesch, Anh Van Le, Timm Bayer, and Andreas Kappler. "Single particle ICP-MS for the analysis of nanoparticles and colloids in the environment." In Goldschmidt2021. France: European Association of Geochemistry, 2021. http://dx.doi.org/10.7185/gold2021.3085.

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2

Cheng, X., X. He, and Y. Zhang. "An Atomic Force Microscopic Investigation on Single Secondary Particle of Silica Aerogel Monolith." In MS&T19. TMS, 2019. http://dx.doi.org/10.7449/2019mst/2019/mst_2019_1343_1350.

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3

Cheng, X., X. He, and Y. Zhang. "An Atomic Force Microscopic Investigation on Single Secondary Particle of Silica Aerogel Monolith." In MS&T19. TMS, 2019. http://dx.doi.org/10.7449/2019/mst_2019_1343_1350.

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4

Tharaud, Mickael, Lukas Schlatt, Phil Shaw, and Dr Marc Benedetti. "(Nano)particle classification/identification using single particle ICP-Time of Flight-MS acquisition coupled to cluster analysis." In Goldschmidt2021. France: European Association of Geochemistry, 2021. http://dx.doi.org/10.7185/gold2021.5193.

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5

Chaussidon, Marc, Mickael Tharaud, Emeline Moreira, Etienne Deloule, Marc Benedetti, and Julien Mercadier. "Developments of single particle analysis by TOF-ICP-MS for study of nanosize matrix phases in primitive meteorites." In Goldschmidt2023. France: European Association of Geochemistry, 2023. http://dx.doi.org/10.7185/gold2023.17872.

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6

Quarles Jr, C. Derrick, Benjamin Manard, Veronica Bradley, Lyndsey Hendriks, Hunter Andrews, Patrick Sullivan, and Cole Hexel. "Development of a High-Throughput Method for Elemental and Isotopic Characterization of Nanoparticles via Single Particle-ICP-TOF-MS." In Goldschmidt2023. France: European Association of Geochemistry, 2023. http://dx.doi.org/10.7185/gold2023.20370.

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7

Cao, Dongqing, Ayman Almohsin, Ming Han, and Bader Al-Harbi. "Mixed Preformed Particle Gel System for Water Shutoff in Fractured Carbonate Reservoir." In International Petroleum Technology Conference. IPTC, 2023. http://dx.doi.org/10.2523/iptc-23006-ms.

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Abstract Water shutoff from production well using particle type material is a great challenge due to the complex pressure and flow distributions near wellbore. A mixed preformed particle gel (PPG) system was developed to enhance the performance for water shutoff in fractured carbonate reservoirs. The PPG blocking behaviors in fractures and methods to improve the water flush tolerance were investigated. PPG strength dominated the water shutoff performances in fractures. PPG with medium to high strength showed better performance than other samples due to the well-adjusted properties in blocking and flush tolerance. For the selected PPG, 30 mesh sample showed the best blocking performance among single mesh samples from 20 mesh to 80 mesh in the fractured artificial metal plug. Using 30 mesh sample as base sample, the 30 mesh and 40 mesh mixture with weight ratio 2:1 produced highest pressure build-up in two-size PPG mixtures. Further increasing the particle size distribution by combining various particle size PPGs, the blocking performance was improved. An optimized combination of 30 mesh, 40 mesh, 50 mesh and 60 mesh particles with weigh ratio of 4:2:1:0.25 was developed. In addition, a fiber material, added in the PPG, significantly improved the water flush tolerance of the PPG pack. A particle size combination of PPGs mixed with the fiber material generated better blocking performances than the other combinations. This study provides insights on packing behavior of deformable gel particles in fractures with a practical PPG based system for water shutoff treatments.

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8

Ge, Xiaojing, Rong Lu, Ghith Biheri, Abdulmohsin Imqam, and Baojun Bai. "Prediction of Single Proppant Terminal Settling Velocity in High Viscosity Friction Reducers by Using Artificial Neural Networks and XGBoost." In SPE Western Regional Meeting. SPE, 2023. http://dx.doi.org/10.2118/212964-ms.

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Abstract High viscosity friction reducers (HVFRs) have been recently gaining more attention and increasing in use, not only as friction-reducing agents but also as proppant carriers. The settling velocity of the proppant is one of the key outputs to describe their proppant transport capability. However, it is influenced by many factors such as fluid properties, proppant properties, and fracture properties. Many empirical/physics-based models and correlations to predict particle settling velocity have been developed. However, they are usually based on certain assumptions and have applicable limits. In contrast, machine learning models can be considered as a black box. The objective of this study is to use machine learning models to find the relationship between the multiple factors mentioned above and particle settling velocity in order to correctly predict it. Two of the most popular and powerful machine learning algorithms, Artificial neural networks (ANN) and XGBoost, were comparatively investigated with standard data processing and training procedures. Mean Absolute Errors (MAEs) for ANNs and XGBoost were 0.010379 and 0.004253 respectively. The XGBoost learning algorithm had overall better prediction performance than the ANN model in terms of the data sets used for this study and had the potential to properly handle missing values by itself.

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9

Troup, Duncan. "Complete Analysis of a Complex Sand Screen Completion in a Single Run in Hole is Enabled by Combination of Novel Passive Acoustic Tools with Conventional PLT and Caliper Techniques." In SPE/ICoTA Well Intervention Conference and Exhibition. SPE, 2022. http://dx.doi.org/10.2118/209030-ms.

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Abstract Wells with sand control measures may still exhibit onset of sanding during production, often due to isolated damage of individual screen sections. Positive identification of the location of the sand production allows targeted mitigation to remove the sanding source while retaining as much hydrocarbon flow as possible. This paper discusses the novel acoustic techniques used to identify productive zones and areas of sand production in a well suffering a sanding event. Ultrasonic methods for sand detection in a downhole environment have proved troublesome primarily due to the difficulty in separating acoustic signatures due to particle impacts from those generated by turbulent flow. Advances in sensor technology and digital sampling have enabled reliable discrimination of turbulence and particle signatures in both controlled flow-loop conditions and in real producing wells. Novel processing algorithms have been developed to not only detect sand ingress points, but also to quantify and characterise sand particles in the flow stream. A horizontal oil producing well exhibited a change of behaviour following an increase in choke opening, when it started to produce sand along with an increased water cut. A toolstring combining production logging, acoustic sand detection and multifinger caliper with a tractor for conveyance was deployed in the well and a number of passes were made combining continuous logging and stationary recordings. The acquired data indicated there was no crossflow during shut-in, while there were indications of sand build-up over the lower sections of screens. With the well flowing, the PL data showed the inflow profile across all screens and identified a point of very large influx of mostly water. Analysis of the acoustic data using transient statistical sampling techniques showed this to be the main source of sand entering the wellbore and was able to verify sand transport in the flow stream. Analysis using general noise level sampling was able to detect energy due to turbulent flow in and into the wellbore, correlated with spinner responses, and also in the near wellbore environment behind certain screens. Multifinger caliper data confirmed the general integrity of the screens and enabled the planning of isolation measures to shut off sand production while minimising production loss. The verified ability of the new tool to separate the acoustic signatures of particle impacts from turbulent flow noise brings an additional aspect to production logging interpretation, allowing inflow profiling for solids as well as fluid phases. Statistical analysis of the broad-spectrum noise recorded also reveals information about fluid flow not just in the wellbore but also in the near-wellbore environment behind the primary tubular. This information can prove critical in analysis of completion design.

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Mardhatillah, Mutia Kharunisa, Muhammad Aslam Md Yusof, Alva Andhika Sa'id, Iqmal Irsyad Mohammad Fuad, Yens Adams Sokama Neuyam, and Nur Asyraf Md Akhir. "Predictive Modelling of Carbon Dioxide Injectivity Using SVR-Hybrid." In Offshore Technology Conference Asia. OTC, 2022. http://dx.doi.org/10.4043/31472-ms.

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Abstract Southeast Asia is increasingly gaining attention as a promising geological site for permanent CO2 sequestration in deep saline aquifers. During CO2 injection into saline reservoirs, the reaction between injected CO2, the resident formation brine, and the reservoir rock could cause injectivity change due to salt precipitation, mineral dissolution, and fine particles migration. The underlying mechanisms have been extensively studied, both experimentally and numerically and the governing parameters have been identified and studied. However, the current models that have been widely adopted to investigate reactive transport and its impact on CO2 injectivity have fundamental limitations when applied to solve small, high dimensional, and non-linear data. The objective of this study is to develop efficient and robust predictive models using support vector regression (SVR) integrated with hyperparameter tuning optimization algorithms, including genetic algorithm (GA). To develop the model, 44 datasets are used to predict the CO2 injectivity change with its influencing variables such as brine salinity, injection flow rate, particle size, and particle concentration. The performance for each model is analyzed and compared with previous models by determination of coefficient (R2), adjusted determination of coefficient (R¯2), average absolute percentage error (AAPE), root mean square error (RMSE) and mean absolute error (MAE). The model with the highest R2 is selected as the predictive model for CO2 injectivity impairment during CO2 sequestration in a saline aquifer. The results revealed that both SVR and GA-SVR are able to capture the precise correlation between measured and predicted data. However, the GA-SVR model slightly outperformed the SVR model by a higher R2 value of 0.9923 compared to SVR with R2 value of 0.9918. Based on SHAP value analysis, brine salinity had the highest impact on CO2 injectivity change, followed by injection flow rate, particle concentration, and jamming ratio. It was also found that hybridization of genetic algorithm with support vector regression does improve the model performance contrary to single algorithm and contributes to the determination of the most impactful factors that induce CO2 injectivity change. The proposed model can be upscaled and integrated into field-scale models to improve the optimization of CO2 injectivity in deep saline reservoirs.

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Звіти організацій з теми "Single particle ICP-MS/MS"

1

Pinet, N., O. H. Ardakani, J. Cesar, D. C. Petts, C. Debuhr, and P J Sack. Exploring the link between organic matter and Carlin-type gold mineralization: new insights from Yukon deposits. Natural Resources Canada/CMSS/Information Management, 2022. http://dx.doi.org/10.4095/330086.

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The link between organic matter and gold in sediment-hosted Carlin-type deposits is controversial. This study aims to tackle this potential link by documenting the occurrence of organic matter in a single borehole from a Carlin-type gold deposit in Yukon and by considering, in a preliminary way, the spatial and/or temporal relationship between organic matter and gold mineralization. The sedimentary succession hosting the Conrad deposit was relatively rich in organic matter, possibly related to Archea. Despite the high maturation of samples, the total organic carbon (TOC) content of the limestone unit averages 1.31 wt. % (maximum = 3.18 wt. %). Petrographic observations indicate that pore and fracture filling pyrobitumen is the dominant organic matter maceral in the studied samples. This type of pyrobitumen was matured after its emplacement, indicating that hydrocarbon fluids cannot have served as an agent for gold transport. Pyrobitumen disseminated in the rock or associated with stylolites are also documented. The correlation between TOC and Tl (the best proxy for Au) for selected samples and the high As content of pyrobitumen filling pores may suggest a link between organic matter content and gold deposition, but this was not demonstrated by LA-ICP-MS micro-scale mapping. This study also highlights the challenges of establishing a direct spatial relationship between 'invisible' gold and very small (&lt; 10 µm) pyrobitumen particles.

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2

Denton, Joanna S., Travis Jay Tenner, Todd L. Williamson, Stephen Philip Lamont, and Robert Ernest Steiner. Plutonium particle analysis by LG-SIMS and LA-MC-ICP-MS for environmental safeguards. Office of Scientific and Technical Information (OSTI), May 2018. http://dx.doi.org/10.2172/1438129.

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3

Knight, R. D., and B. A. Kjarsgaard. Comparative pXRF and Lab ICP-ES/MS methods for mineral resource assessment, Northwest Territories. Natural Resources Canada/CMSS/Information Management, 2022. http://dx.doi.org/10.4095/331239.

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The Geological Survey of Canada undertook a mineral resource assessment for a proposed national park in northern Canada (~ 33,500 km2) spanning the transition from boreal forest to barren lands tundra. Bedrock geology of this region is complex and includes the Archean Slave Craton, the Archean and Paleoproterozoic Rae domain of the Churchill Province, the Paleoproterozoic Thelon and Taltson magmatic-tectonic zones, and the Paleoproterozoic East Arm sedimentary basin. The area has variable mineral potential for lode gold, kimberlite-hosted diamonds, VMS, vein uranium and copper, SEDEX, as well as other deposit types. A comparison of analytical methods was carried out after processing the field collected samples to acquire both the &lt; 2 mm and for the &lt; 0.063 mm size fractions for 241 surficial sediment (till) samples, collected using a 10 x 10 km grid. Analytical methods comprised: 1) aqua regia followed by ICP-MS analysis, 2) 4-acid hot dissolution followed by ICP-ES/MS analysis, 3) lithium metaborate/tetraborate fusion methods followed by ICP-ES for major elements and ICP-MS for trace elements and, 4) portable XRF on dried, non-sieved sediment samples subjected to a granular segregation processing technique (to produce a clay-silt proxy) for seventeen elements (Ba, Ca, Cr, Cu, Fe, K, Mn, Ni, Pb, Rb, Sr, Th, Ti, U, V, Zn, and Zr) Results indicate that pXRF data do not replicate exactly the laboratory 4-acid and fusion data (in terms of precision and accuracy), but the relationship between the datasets is systematic as displayed in x-y scattergrams. Interpolated single element plots indicate that till samples with anomalies of high and low pXRF concentration levels are synonymous with high and low laboratory-based analytical concentration levels, respectively. The pXRF interpolations thus illustrate the regional geochemical trends, and most importantly, the significant geochemical anomalies in the surficial samples. These results indicate that pXRF spectrometry for a subset of elements is comparable to traditional laboratory methods. pXRF spectrometry also provides the benefit of rapid analysis and data acquisition that has a direct influence on real time sampling designs. This information facilitates efficient and cost-effective field projects (i.e. where used to identify regions of interest for high density sampling), and to prioritize samples to be analyzed using traditional geochemical methods. These tactics should increase the efficiency and success of a mineral exploration and/or environmental sampling programs.

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4

Porat, Ron, Doron Holland, and Linda Walling. Identification of Citrus Fruit-Specific and Pathogen-Induced Promoters and Their Use in Molecular Engineering. United States Department of Agriculture, January 2001. http://dx.doi.org/10.32747/2001.7585202.bard.

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This one year BARD project was funded to develop methods to monitor promoter activity a gene expression patterns in citrus fruit. To fulfill this goal, we divided the research tasks between both labs so that the Israeli side evaluated the use of microprojectile bombardment ; a tool to evaluate transient gene expression in various citrus fruit tissues, and the US side optimized technical parameters required for Agrobacterium-mediated transformation of various citrus cultivars. Microprojectile bombardment appeared to be a very efficient method for transient gene expression analysis in citrus leaf tissues but was somewhat less applicable in fruit tissues. Nevertheless, we did succeeded to achieve significant levels of 35S-GUS gene expression in young green flavedo tissue. However, only single random spots of 35S-GUS gene expression were detected mature flavedo and in juice sacs and albedo tissue. Overall, we assume that following some more technical improvements particle bombardment could provide a useful technique to rapidly analyze promoter activity at least in the flavedo tissue. For Agrobacterium-mediated transformation, we found that shoot cultures of 'Washington' navel oranges,'Fairchild' mandarins,'Eureca' lemons,'Troyer' citrange and various grapefruits provided a more reliable and consistent source of tissue for transformation than germinated seedlings. Moreover, various growth media's (McCown, Quoirin & Lepoivre, DCR) further improved shoot and root growth relative to MS mineral media, which is commonly used. Also pure white light (using bulbs which do not emit UV or blue light) improved shoot growth in various citrus varieties, and paromomycin appeared to be a more efficient antibiotic for the selection of transgenic plants than Kanamycin. Overall, these optimizations improve transformation efficacy and shoot growth and rooting capacity. In addition to the development of transformation methods, both Israeli and US labs achieved progress in the identification of citrus fruit-specific promoters. In Israel, we isolated a 3.6 kb promoter fragment of the thiamine biosynthesis c-thi gene, which is highly expressed in fruit peel tissue, whereas in the US we isolated a 1.5 kb promoter fragment of the citrus seed-specific cDNA CssH. The identification of more fruit-specific cDNAs and their corresponding promoter regions is currently in progress.

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5

Gadd, M. G., J. M. Peter, and D. Layton-Matthews. Genesis of hyper-enriched black shale Ni-Mo-Zn-Pt-Pd-Re mineralization in the northern Canadian Cordillera. Natural Resources Canada/CMSS/Information Management, 2022. http://dx.doi.org/10.4095/328013.

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Polymetallic (Ni-Mo-Zn-Pt-Pd-Au-Re) hyper-enriched black shales in the northern Canadian Cordillera consist of thin, semi-massive sulfides interbedded with black shale. We studied HEBS deposits at Nick, Peel River, Monster River, and Moss in northern Yukon, and at a single locality underlying the Cardiac Creek Pb-Zn-Ag deposit in northeastern British Columbia. High-grade mineralization contains up to 7.4 weight per cent Ni, 2.7 weight per cent Zn, 0.38 weight per cent Mo, 400 ppb Pt, 250 ppb Pd, 160 ppb Au, and 58.5 ppm Re. Sulfide mineralization formed during syngenesis to later diagenesis. Analyses by LA-ICP-MS indicate that pyrite is the principal host of platinum-group elements, Au, and Re. Mineralization and sedimentation were coeval based on the overlap between Re-Os geochronology of HEBS at Nick and Peel River (390.7 ± 5.1 and 387.3 ± 4.4 Ma, respectively) and conodont biostratigraphic ages of sedimentary host rocks. Bulk S isotope composition of HEBS is uniformly negative, indicating that bacterial reduction of seawater sulfate generated sulfur to precipitate sulfide minerals. The initial Os ratios at Peel River (0.25 ± 0.07) and Nick (0.32 ± 0.20) overlap with Middle Devonian seawater, suggesting that elemental enrichment was derived from seawater.

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