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Статті в журналах з теми "Sesamoline"

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Автор: Grafiati

Опубліковано: 30 травня 2022

Оновлено: 31 травня 2022

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1

Rosalina, Reny, and Natthida Weerapreeyakul. "An Insight into Sesamolin: Physicochemical Properties, Pharmacological Activities, and Future Research Prospects." Molecules 26, no. 19 (September 27, 2021): 5849. http://dx.doi.org/10.3390/molecules26195849.

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Анотація:

Sesame seeds are rich in lignan content and have been well-known for their health benefits. Unlike the other sesame lignan compounds (i.e., sesamin and sesamol), the study of the pharmacological activity of sesamolin has not been explored widely. This review, therefore, summarizes the information related to sesamolin’s pharmacological activities, and the mechanism of action. Moreover, the influence of its physicochemical properties on pharmacological activity is also discussed. Sesamolin possessed neuroprotective activity against hypoxia-induced reactive oxygen species (ROS) and oxidative stress in neuron cells by reducing the ROS and inhibiting apoptosis. In skin cancer, sesamolin exhibited antimelanogenesis by affecting the expression of the melanogenic enzymes. The anticancer activity of sesamolin based on antiproliferation and inhibition of migration was demonstrated in human colon cancer cells. In addition, treatment with sesamolin could stimulate immune cells to enhance the cytolytic activity to kill Burkitt’s lymphoma cells. However, the toxicity and safety of sesamolin have not been reported. And there is also less information on the experimental study in vivo. The limited aqueous solubility of sesamolin becomes the main problem, which affects its pharmacological activity in the in vitro experiment and clinical efficacy. Therefore, solubility enhancement is needed for further investigation and determination of its pharmacological activity profiles. Since there are fewer reports studying this issue, it could become a future prospective research opportunity.

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2

Bochkarev, Sergiy, Anna Belinska, Oleksandra Varankina, Valeriya Ananieva, Igor Petik, Andrii Koshyl, Olha Yevstifieieva, and Kateryna Rudnieva. "RESEARCH OF QUALITY INDICATORS OF PROTEIN-FAT MIXTURE FROM FLAX AND SESAME SEEDS FOR NUTRITION OF ATHLETES." EUREKA: Life Sciences 5 (September 17, 2019): 64–69. http://dx.doi.org/10.21303/2504-5695.2019.001001.

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The aim of the research is to determine the microbiological stability of a protein-fat mixture of flax and sesame seeds that allows to correct its storage life. A protein-fat mixture has a high content of irreplaceable amino acids ВСАА and polyunsaturated fatty acids of w-3group, so it may be positioned as a component of nutrition for athletes. Flax and sesame seeds, cultivated in Ukraine, were used as research materials. The product was created, based on comminuted flax and sesame seeds in ratio 1:1. There were determined organoleptic (outlook, taste, smell, color) and physical-chemical (mass share of moisture, ash, protein, fat, acidic, peroxide, anisidine number) parameters of the product. There was determined the microbiological stability of the protein-fat mixture of the increased food value for athletes nutrition after 6 months. It has been proved, that as opposite to the control sample, the protein-fat mixture of the developed composition manifests its microbiological stability by the following parameters: content of mesophilic aerobic and facultative anaerobic microorganisms, molds, yeast, bacteria of the colon bacillus group and pathogenic microorganisms. The control sample that is comminuted flax seeds doesn’t manifest at the end of the storage term any correspondence of microbiological parameters by the content of mesophilic aerobic and facultative anaerobic microorganisms, molds, and bacteria of the colon bacillus group. This regularity is explained by the presence of lignans, sesamol and sesamoline, with preservative properties in the developed product. The obtained data may be used for reasoning recipes of products, based on the protein-fat mixture and correction of the food supplements ratio in them.

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3

Lim, Jin Seon, Yoshikazu Adachi, Yoko Takahashi, and Takashi Ide. "Comparative analysis of sesame lignans (sesamin and sesamolin) in affecting hepatic fatty acid metabolism in rats." British Journal of Nutrition 97, no. 1 (January 2007): 85–95. http://dx.doi.org/10.1017/s0007114507252699.

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Effects of sesamin and sesamolin (sesame lignans) on hepatic fatty acid metabolism were compared in rats. Rats were fed either a lignan-free diet, a diet containing 0·6 or 2 g/kg lignan (sesamin or sesamolin), or a diet containing both sesamin (1·4 g/kg) and sesamolin (0·6 g/kg), for 10 d. Sesamin and sesamolin dose-dependently increased the activity and mRNA abundance of various enzymes involved in hepatic fatty acid oxidation. The increase was much greater with sesamolin than with sesamin. These lignans increased parameters of hepatic fatty acid oxidation in an additive manner when added simultaneously to an experimental diet. In contrast, they decreased the activity and mRNA abundance of hepatic lipogenic enzymes despite dose-dependent effects not being necessarily obvious. Sesamin and sesamolin were equally effective in lowering parameters of lipogenesis. Sesamolin accumulated in serum at 33- and 46-fold the level of sesamin at dietary concentrations of 0·6 and 2 g/kg, respectively. The amount of sesamolin accumulated in liver was 10- and 7-fold that of sesamin at the respective dietary levels. Sesamolin rather than sesamin can account for the potent physiological effect of sesame seeds in increasing hepatic fatty acid oxidation observed previously. Differences in bio-availability may contribute to the divergent effects of sesamin and sesamolin on hepatic fatty acid oxidation. Sesamin compared to sesamolin was more effective in reducing serum and liver lipid levels despite sesamolin more strongly increasing hepatic fatty acid oxidation.

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4

Baek, Seung-Hwa, Myung-Gyun Kang, and Daeui Park. "Inhibitory Effect of Sesamolin on Melanogenesis in B16F10 Cells Determined by In Vitro and Molecular Docking Analyses." Current Pharmaceutical Biotechnology 21, no. 2 (February 12, 2020): 169–78. http://dx.doi.org/10.2174/1389201020666191011151123.

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Background: Melanin protects the skin against the harmful effects of ultraviolet irradiation. However, melanin overproduction can result in several aesthetic problems, including melasma, freckles, age spots and chloasma. Therefore, development of anti-melanogenic agents is important for the prevention of serious hyperpigmentation diseases. Sesamolin is a lignan compound isolated from sesame seeds with several beneficial properties, including potential for melanin inhibition. Objective: The aim of this study was to evaluate the anti-melanogenic effect of sesamolin in cell culture in vitro and the underlying mechanism of inhibition using molecular docking simulation. Methods: Melanogenesis was induced by 3-isobutyl-1-methylxanthine in B16F10 melanoma cells, and the inhibitory effects of sesamolin were evaluated using zymography, a tyrosinase inhibitory activity assay, western blotting, and real-time reverse transcription-polymerase chain reaction analysis. Docking simulations between sesamolin and tyrosinase were performed using Autodock vina. Results: Sesamolin significantly inhibited the expression of melanogenesis-related factors tyrosinase, and tyrosinase-related proteins 1 and 2 at the mRNA and protein levels. Treatment of melanoma cells with 50 µM sesamolin demonstrated the strongest inhibition against intercellular tyrosinase and melanin synthesis without exerting cytotoxic effects. Sesamolin significantly reduced mushroom tyrosinase activity in a dose-dependent manner via a competitive inhibition mechanism. Tyrosinase docking simulations supported that sesamolin (-6.5 kcal/mol) bound to the active site of tyrosinase more strongly than the positive control (arbutin, -5.7 kcal/mol). Conclusion: Sesamolin could be developed as a melanogenesis inhibiting agent owing to its dual function in blocking the generation of melanogenesis-related enzymes and inhibiting the enzymatic response of tyrosinase.

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5

Xu, Fangtao, Rong Zhou, Senouwa Segla Koffi Dossou, Shengnan Song, and Linhai Wang. "Fine Mapping of a Major Pleiotropic QTL Associated with Sesamin and Sesamolin Variation in Sesame (Sesamum indicum L.)." Plants 10, no. 7 (June 30, 2021): 1343. http://dx.doi.org/10.3390/plants10071343.

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Deciphering the genetic basis of quantitative agronomic traits is a prerequisite for their improvement. Herein, we identified loci governing the main sesame lignans, sesamin and sesamolin variation in a recombinant inbred lines (RILs, F8) population under two environments. The content of the two lignans in the seeds was investigated by HPLC. The sesamin and sesamolin contents ranged from 0.33 to 7.52 mg/g and 0.36 to 2.70 mg/g, respectively. In total, we revealed 26 QTLs on a linkage map comprising 424 SSR markers, including 16 and 10 loci associated with sesamin and sesamolin variation, respectively. Among them, qSmin_11.1 and qSmol_11.1 detected in both the two environments explained 67.69% and 46.05% of the phenotypic variation of sesamin and sesamolin, respectively. Notably, qSmin11-1 and qSmol11-1 were located in the same interval of 127-127.21cM on LG11 between markers ZMM1776 and ZM918 and acted as a pleiotropic locus. Furthermore, two potential candidate genes (SIN_1005755 and SIN_1005756) at the same locus were identified based on comparative transcriptome analysis. Our results suggest the existence of a single gene of large effect that controls expression, both of sesamin and sesamolin, and provide genetic information for further investigation of the regulation of lignan biosynthesis in sesame.

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6

Matsumura, Shinichi, Kazuya Murata, Nobuhiro Zaima, Yuri Yoshioka, Masanori Morimoto, Hideaki Matsuda та Masahiro Iwaki. "Inhibitory Activities of Sesame Seed Extract and its Constituents against β-Secretase". Natural Product Communications 11, № 11 (листопад 2016): 1934578X1601101. http://dx.doi.org/10.1177/1934578x1601101112.

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The need for a preventive agent against dementia led us to screen natural plant resources. Among the herbs and spices tested, sesame seed prepared from Sesamum indicum seeds showed potent β-secretase inhibitory activity. The active principles were determined to be sesamin and sesamolin, typical lignans in S. indicum. The IC50 values of sesamin and sesamolin were 257 and 140 μM, respectively. These compounds were investigated in a preliminary absorption experiment. After oral administration, these compounds were detected in an intact form in the brain and serum. These results suggest that consumption of sesame seeds may prevent dementia by sesamin and sesamolin, the constituents in sesame seeds.

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7

Jeng, K., and R. Hou. "Sesamin and Sesamolin: Natures Therapeutic Lignans." Current Enzyme Inhibition 1, no. 1 (January 1, 2005): 11–20. http://dx.doi.org/10.2174/1573408052952748.

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8

Hofer, Otmar, Gerda Lutz, Günter Brader, and Christoph Kratky. "Conformational Analysis of Tetrahydrofurofuran Lignans: Sesamolin." HETEROCYCLES 45, no. 2 (1997): 287. http://dx.doi.org/10.3987/com-96-7651.

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9

Bedigian, Dorothea, David S. Seigler, and Jack R. Harlan. "Sesamin, sesamolin and the origin of sesame." Biochemical Systematics and Ecology 13, no. 2 (May 1985): 133–39. http://dx.doi.org/10.1016/0305-1978(85)90071-7.

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10

Hadeel, S. Y., S. A. Khalida, and Marie Walsh. "Antioxidant activity of sesame seed lignans in sunflower and flaxseed oils." Food Research 4, no. 3 (December 22, 2019): 612–22. http://dx.doi.org/10.26656/fr.2017.4(3).331.

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This study investigated the antioxidant activity of crude lignan extracts and purified lignans (sesamin, sesamolin, and sesamol) in sunflower and flaxseed oils. Lignan extracts were prepared from roasted sesame seed oil (LRSO) and unroasted sesame seed oil (LUSO). Additionally, the individual lignans were purified from both oils. The crude extracts and purified lignans were added at concentrations of 0.01, 0.02 and 0.03% to the oils and stored at 25 and 65°C over time and peroxide values and thiobarbituric acid values were measured. Each oil showed an increase in oxidation over time, with the samples stored at 65°C exhibiting accelerated oxidation. In general, LRSO showed higher antioxidant activity than LUSO and the antioxidant activity was similar to the antioxidant activity of butylated hydroxytoluene (0.02% BHT) in both oils when used at concentrations of 0.02 and 0.03%. Sesamol showed the highest antioxidant activity of each of the purified lignans followed by sesamin and sesamolin respectively. Crude and purified sesame lignans may have potential applications as natural antioxidants in food systems

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11

LUTZ, G., O. HOFER, G. BRADER, and C. KRATKY. "ChemInform Abstract: Conformational Analysis of Tetrahydrofurofuran Lignans: Sesamolin." ChemInform 28, no. 34 (August 3, 2010): no. http://dx.doi.org/10.1002/chin.199734276.

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12

Kang, Myung-Hwa, Michitaka Naito, Nobuko Tsujihara, and Toshihiko Osawa. "Sesamolin Inhibits Lipid Peroxidation in Rat Liver and Kidney." Journal of Nutrition 128, no. 6 (June 1, 1998): 1018–22. http://dx.doi.org/10.1093/jn/128.6.1018.

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13

Kitipaspallop, Wannakarn, Siwapech Sillapaprayoon, Preecha Phuwapraisirisan, Woo-Keun Kim, Chanpen Chanchao, and Wittaya Pimtong. "Developmental effects of sesamolin on zebrafish (Danio rerio) embryos." Comparative Biochemistry and Physiology Part C: Toxicology & Pharmacology 256 (June 2022): 109319. http://dx.doi.org/10.1016/j.cbpc.2022.109319.

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14

Muangrat, Rattana, Yongyut Chalermchart, Supachet Pannasai, and Sukhuntha Osiriphun. "Effect of Roasting and Vacuum Microwave Treatments on Physicochemical and Antioxidant Properties of Oil Extracted from Black Sesame Seeds." Current Research in Nutrition and Food Science Journal 8, no. 3 (December 28, 2020): 798–814. http://dx.doi.org/10.12944/crnfsj.8.3.12.

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Unroasted, roasted (at roasting temperatures of 100, 150 and 200 C and roasting times of 10, 20 and 30 min) and vacuum microwaved (at microwave watt powers of 800, 1440, 2400 and 3600 watts/kg black sesame seeds, for heating times of 10, 20 and 30 min) black sesame seeds were processed to extract oil using a single screw press at a constant pressing temperature of 50 C. The results revealed that different heat pre-treatments significantly affected yield and physiochemical and antioxidant properties of extracted oils. The extracted oil samples exhibited significantly different levels of total phenolic compounds, sesamin, sesamolin, and DPPH• and ABTS•+ scavenging activity. Additionally, it was found that these values of roasted and vacuum microwaved black sesame seed oils were significantly higher than those of unroasted oil. Sesamin, sesamolin, total content of phenolic compounds, and DPPH• and ABTS•+ scavenging activity of extracted black sesame oils increased when the roasting temperature and watt power increased. Black sesame oil obtained from unroasted, roasted and vacuum microwaved dried black sesame seeds contained linoleic and oleic acids as major fatty acids. Black sesame oil extracted from roasting and vacuum microwave treatments for 10 min at higher roasting temperature and microwave watt power had higher total phenolic content leading to a reduction of peroxide value and elevated stability of soybean oil when it was added during storage time at temperature of 65 °C.

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15

OSAWA, Toshihiko, Masayasu NAGATA, Mitsuo NAMIKI, and Yasuko FUKUDA. "Sesamolinol, a novel antioxidant isolated from sesame seeds." Agricultural and Biological Chemistry 49, no. 11 (1985): 3351–52. http://dx.doi.org/10.1271/bbb1961.49.3351.

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16

Osawa, Toshihiko, Masayasu Nagata, Mitsuo Namiki, and Yasuko Fukuda. "Sesamolinol, a Novel Antioxidant Isolated from Sesame Seeds." Agricultural and Biological Chemistry 49, no. 11 (November 1985): 3351–52. http://dx.doi.org/10.1080/00021369.1985.10867272.

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17

MOAZZAMI, Ali A., Rolf E. ANDERSSON, and Afaf KAMAL-ELDIN. "Characterization and Analysis of Sesamolinol Diglucoside in Sesame Seeds." Bioscience, Biotechnology, and Biochemistry 70, no. 6 (June 23, 2006): 1478–81. http://dx.doi.org/10.1271/bbb.60013.

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18

Junhom, C., B. Siriwarin, N. Weerapreeyakul, and S. Barusrux. "210: Effect of sesamin, sesamolin and sesamol on P-glycoprotein mediated efflux." European Journal of Cancer 50 (July 2014): S48. http://dx.doi.org/10.1016/s0959-8049(14)50181-5.

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19

NAGATA, Masayasu, Toshihiko OSAWA, Mitsuo NAMIKI, Yasuko FUKUDA, and Tatsuhiko OZAKI. "Stereochemical structures of antioxidative bisepoxylignans, sesaminol and its isomers, transformed from sesamolin." Agricultural and Biological Chemistry 51, no. 5 (1987): 1285–89. http://dx.doi.org/10.1271/bbb1961.51.1285.

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20

Liang, Ming-Tsai, Ru-Chien Liang, Li-Rong Huang, Ping-Hsuan Hsu, Yu-Hsuan Wu, and Hung-En Yen. "Separation of Sesamin and Sesamolin by a Supercritical Fluid-Simulated Moving Bed." American Journal of Analytical Chemistry 03, no. 12 (2012): 931–38. http://dx.doi.org/10.4236/ajac.2012.312a123.

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21

Huang, Jinian, Guohui Song, Lixia Zhang, Qiang Sun, and Xin Lu. "A novel conversion of sesamolin to sesaminol by acidic cation exchange resin." European Journal of Lipid Science and Technology 114, no. 7 (March 5, 2012): 842–48. http://dx.doi.org/10.1002/ejlt.201100247.

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22

Hou, Rolis Chien-Wei, Hsueh-Meei Huang, Jason T. C. Tzen, and Kee-Ching G. Jeng. "Protective effects of sesamin and sesamolin on hypoxic neuronal and PC12 cells." Journal of Neuroscience Research 74, no. 1 (September 11, 2003): 123–33. http://dx.doi.org/10.1002/jnr.10749.

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23

Nagata, Masayasu, Toshihiko Osawa, Mitsuo Namiki, Yasuko Fukuda, and Tatsuhiko Ozaki. "Stereochemical Structures of Antioxidative Bisepoxylignans, Sesaminol and Its Isomers, Transformed from Sesamolin." Agricultural and Biological Chemistry 51, no. 5 (May 1987): 1285–89. http://dx.doi.org/10.1080/00021369.1987.10868187.

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24

Srisayam, Montra, Natthida Weerapreeyakul, and Kwanjai Kanokmedhakul. "Inhibition of two stages of melanin synthesis by sesamol, sesamin and sesamolin." Asian Pacific Journal of Tropical Biomedicine 7, no. 10 (October 2017): 886–95. http://dx.doi.org/10.1016/j.apjtb.2017.09.013.

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25

Keowkase, Roongpetch, Natthawut Shoomarom, Worawee Bunargin, Worapan Sitthithaworn та Natthida Weerapreeyakul. "Sesamin and sesamolin reduce amyloid-β toxicity in a transgenic Caenorhabditis elegans". Biomedicine & Pharmacotherapy 107 (листопад 2018): 656–64. http://dx.doi.org/10.1016/j.biopha.2018.08.037.

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26

Grougnet, Raphael, Prokopios Magiatis, Helene Laborie, Despina Lazarou, Athanasios Papadopoulos, and Alexios-Leandros Skaltsounis. "Sesamolinol Glucoside, Disaminyl Ether, and Other Lignans from Sesame Seeds." Journal of Agricultural and Food Chemistry 60, no. 1 (December 28, 2011): 108–11. http://dx.doi.org/10.1021/jf2040687.

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27

Fukuda, Yasuko, Minoru Isobe, Masayasu Nagata, Toshihiko Owaea, and Mitsuo Namiki. "Acidic Transformation of Sesamolin, the Sesami-oil Constituent, into an Antioxidant Bisepoxylignan, Sesaminol." HETEROCYCLES 24, no. 4 (1986): 923. http://dx.doi.org/10.3987/r-1986-04-0923.

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28

Tsai, Hsin-Ya, Wei-Ju Lee, I.-Hsuan Chu, Wei-Ching Hung, and Nan-Wei Su. "Formation of Samin Diastereomers by Acid-Catalyzed Transformation of Sesamolin with Hydrogen Peroxide." Journal of Agricultural and Food Chemistry 68, no. 23 (May 12, 2020): 6430–38. http://dx.doi.org/10.1021/acs.jafc.0c01616.

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29

AMAROWICZ, R., F. SHAHIDI, and R. B. PEGG. "APPLICATION OF SEMIPREPARATIVE RP-18 HPLC FOR THE PURIFICATION OF SESAMIN AND SESAMOLIN." Journal of Food Lipids 8, no. 2 (June 2001): 85–94. http://dx.doi.org/10.1111/j.1745-4522.2001.tb00186.x.

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30

Lee, Jae Kwon. "Sesamolin promotes cytolysis and migration activity of natural killer cells via dendritic cells." Archives of Pharmacal Research 43, no. 4 (April 2020): 462–74. http://dx.doi.org/10.1007/s12272-020-01229-y.

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31

Plaitho, Yossaporn, Pawaweena Rattanasena, Pittaya Chaikham, and Pattaneeya Prangthip. "Biochemical and Antioxidative Properties of Unprocessed and Sterilized White and Black Sesame By-product from Northern Thailand." Current Research in Nutrition and Food Science Journal 5, no. 3 (November 30, 2017): 196–205. http://dx.doi.org/10.12944/crnfsj.5.3.03.

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The objectives of this research were to determine the effects of sterilization on storage stability of white and black sesame by-products. Results showed that sterilization at 120 ºC for 10 min had no effect on proximate compositions and mineral contents of both sesame seed cakes, but the significant reductions of thiamine, riboflavin, sesamin, sesamolin, total phenolic compounds and antioxidant capacity (DPPH and FRAP assays) were observed. During the storage at 37 ºC, all bioactive components and antioxidant properties apparently tended to decrease when the storage time rose. At the end of storage, PV (peroxide value) and TBARS (thiobarbituric acid-reactive substances) values of stored black sesame seed cakes were shown to be significantly lower than that in white sesame seed cakes. This study may suggest the application of black and white sesame seeds cakes as functional food ingredients in the future production.

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32

Dehkordi, Farshad Roghani, and Mehrdad Roghani. "Mechanisms Underlying Sesamolin-Induced Attenuation of Vascular Dysfunction in Rats With Streptozotocin-Induced Diabetes." International Journal of Endocrinology & Metabolism 9, no. 2 (January 8, 2012): 311–16. http://dx.doi.org/10.5812/kowsar.1726913x.2380.

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33

FUKUDA, Yasuko, Toshihiko OSAWA, Shunro KAWAGISHI, and Mitsuo NAMIKI. "Comparison of contents of sesamolin and lignan antioxidants in sesame seeds cultivated in Japan." NIPPON SHOKUHIN KOGYO GAKKAISHI 35, no. 7 (1988): 483–86. http://dx.doi.org/10.3136/nskkk1962.35.7_483.

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34

Wu, Ming-Shun, Levent Bless B. Aquino, Marjette Ylreb U. Barbaza, Chieh-Lun Hsieh, Kathlia A. De Castro-Cruz, Ling-Ling Yang, and Po-Wei Tsai. "Anti-Inflammatory and Anticancer Properties of Bioactive Compounds from Sesamum indicum L.—A Review." Molecules 24, no. 24 (December 4, 2019): 4426. http://dx.doi.org/10.3390/molecules24244426.

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The use of foodstuff as natural medicines has already been established through studies demonstrating the pharmacological activities that they exhibit. Knowing the nutritional and pharmacological significance of foods enables the understanding of their role against several diseases. Among the foods that can potentially be considered as medicine, is sesame or Sesamum indicum L., which is part of the Pedaliaceae family and is composed of its lignans such as sesamin, sesamol, sesaminol and sesamolin. Its lignans have been widely studied and are known to possess antiaging, anticancer, antidiabetes, anti-inflammatory and antioxidant properties. Modern chronic diseases, which can transform into clinical diseases, are potential targets of these lignans. The prime example of chronic diseases is rheumatic inflammatory diseases, which affect the support structures and the organs of the body and can also develop into malignancies. In line with this, studies emphasizing the anti-inflammatory and anticancer activities of sesame have been discussed in this review.

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35

Chasquibol, N. A., R. B. Gómez-Coca, J. C. Yácono, Á. Guinda, W. Moreda, C. Del Aguila, and M. C. Pérez-Camino. "Markers of quality and genuineness of commercial extra virgin sacha inchi oils." Grasas y Aceites 67, no. 4 (December 1, 2016): 169. http://dx.doi.org/10.3989/gya.0457161.

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This work tackles the study of the quality and authenticity of oils labeled and commercialized as extra virgin sacha inchi oil. Major and minor components as triglycerides, fatty acid methyl esters, tocopherols, sterols and hydrocarbons are determined as well as other physicochemical parameters (density, viscosity, acidity and peroxide value). The results showed that some of the commercialized oils do not fulfill the basic requirement established in the regulation such as the content of α-linolenic acid, higher than 44.7 or 55.0% in the cases of P. volubilis and P. huayllabambana, respectively. The calculated stigmasterol/campesterol ratio for genuine sacha inchi oils should be around 4, however not all commercial oils analyzed comply with this requirement. The presence of the flavons sesamin and sesamolin indicates the addition of compounds from sesame oils. Finally, some of the commercial oils showed to contain trans fatty acids although this was not accompanied by the sterene hydrocarbon presence.

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36

Hou, Rolis Chien-Wei, Chia-Chuan Wu, Chia-Hung Yang, and Kee-Ching G. Jeng. "Protective effects of sesamin and sesamolin on murine BV-2 microglia cell line under hypoxia." Neuroscience Letters 367, no. 1 (August 2004): 10–13. http://dx.doi.org/10.1016/j.neulet.2004.05.073.

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37

Takano, Seiichi, Takehiko Ohkawa, Shun'ichi Tamori, Shigeki Satoh, and Kunio Ogasawara. "Enantio-controlled route to the furofuran lignans: the total synthesis of (–)-sesamolin, (–)-sesamin, and (–)-acuminatolide." J. Chem. Soc., Chem. Commun., no. 3 (1988): 189–91. http://dx.doi.org/10.1039/c39880000189.

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38

Wang, Linhai, Yanxin Zhang, Peiwu Li, Xuefang Wang, Wen Zhang, Wenliang Wei, and Xiurong Zhang. "HPLC Analysis of Seed Sesamin and Sesamolin Variation in a Sesame Germplasm Collection in China." Journal of the American Oil Chemists' Society 89, no. 6 (January 14, 2012): 1011–20. http://dx.doi.org/10.1007/s11746-011-2005-7.

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39

Ogata, Naoki, and Masako Kato. "alf-Diallel Analysis for Sesamin and Sesamolin Contents of Sesame (Sesamum indicum L.) Seeds." Japanese journal of crop science 85, no. 3 (2016): 302–8. http://dx.doi.org/10.1626/jcs.85.302.

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40

Sirato-Yasumoto, Satoko, Masumi Katsuta, Yoshinao Okuyama, Yoko Takahashi, and Takashi Ide. "Effect of Sesame Seeds Rich in Sesamin and Sesamolin on Fatty Acid Oxidation in Rat Liver." Journal of Agricultural and Food Chemistry 49, no. 5 (May 2001): 2647–51. http://dx.doi.org/10.1021/jf001362t.

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41

Chantzos, Nickolaos, and Constantinos Georgiou. "Monitoring lipid oxidation events at frying temperatures through radical scavenging assays." Chemical Industry and Chemical Engineering Quarterly 13, no. 3 (2007): 163–66. http://dx.doi.org/10.2298/ciceq0703163c.

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This communication proposes an alternative approach for monitoring oils during thermal stress at frying temperatures through radical scavenging assays. Oxidation events for extra virgin olive, pomace, sesame, sunflower, soybean, corn and of a commercial blend of oils are followed through the DPPH assay during heating at 100, 150 and 190?C. Radical scavenging activity decrease expressed as trolox equivalent antioxidant capacity (?TEAC, mmol trolox kg-1 oil) is found to be linearly related to increases in total oxidation (?TOTOX) values. This relationship is valid down to a certain - ?TEAC value cutoff that is different for different oils. Considerable consumption of antioxidants demonstrated by high -?TEAC values renders the linear relationship invalid indicating that antioxidants cannot control late events of oxidative damage. Radical scavenging activity is found to increase upon sesame oil heating in contrast to all other oils. It is postulated that sesamolin, a phenolic antioxidant, decomposes during heating to the more potent antioxidant sesamol accounting for the increase of radical scavenging activity upon heating. This paper demonstrates prospects of radical scavenging activity assays as a tool for monitoring oxidation events during frying and warrants further research and evaluation.

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42

Andargie, Mebeaselassie, Maria Vinas, Anna Rathgeb, Evelyn Möller, and Petr Karlovsky. "Lignans of Sesame (Sesamum indicum L.): A Comprehensive Review." Molecules 26, no. 4 (February 7, 2021): 883. http://dx.doi.org/10.3390/molecules26040883.

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Major lignans of sesame sesamin and sesamolin are benzodioxol--substituted furofurans. Sesamol, sesaminol, its epimers, and episesamin are transformation products found in processed products. Synthetic routes to all lignans are known but only sesamol is synthesized industrially. Biosynthesis of furofuran lignans begins with the dimerization of coniferyl alcohol, followed by the formation of dioxoles, oxidation, and glycosylation. Most genes of the lignan pathway in sesame have been identified but the inheritance of lignan content is poorly understood. Health-promoting properties make lignans attractive components of functional food. Lignans enhance the efficiency of insecticides and possess antifeedant activity, but their biological function in plants remains hypothetical. In this work, extensive literature including historical texts is reviewed, controversial issues are critically examined, and errors perpetuated in literature are corrected. The following aspects are covered: chemical properties and transformations of lignans; analysis, purification, and total synthesis; occurrence in Seseamum indicum and related plants; biosynthesis and genetics; biological activities; health-promoting properties; and biological functions. Finally, the improvement of lignan content in sesame seeds by breeding and biotechnology and the potential of hairy roots for manufacturing lignans in vitro are outlined.

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Kumazaki, Tadashi, Yuko Yamada, Shusaku Karaya, Mariko Kawamura, Tatsuya Hirano, Satoko Yasumoto, Masumi Katsuta, and Hiroyasu Michiyama. "Effects of Day Length and Air and Soil Temperatures on Sesamin and Sesamolin Contents of Sesame Seed." Plant Production Science 12, no. 4 (January 2009): 481–91. http://dx.doi.org/10.1626/pps.12.481.

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44

Wang, Xiao, Yunliang Lin, Yanling Geng, Fuwei Li, and Daijie Wang. "Preparative Separation and Purification of Sesamin and Sesamolin from Sesame Seeds by High-Speed Counter-Current Chromatography." Cereal Chemistry Journal 86, no. 1 (January 2009): 23–25. http://dx.doi.org/10.1094/cchem-86-1-0023.

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45

Kim, Jeong Hwa, and Jae Kwon Lee. "Sesamolin enhances NK cell lysis activity by increasing the expression of NKG2D ligands on Burkitt's lymphoma cells." International Immunopharmacology 28, no. 2 (October 2015): 977–84. http://dx.doi.org/10.1016/j.intimp.2015.08.014.

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46

Rangkadilok, Nuchanart, Nanthanit Pholphana, Chulabhorn Mahidol, Wasana Wongyai, Kanya Saengsooksree, Sumontha Nookabkaew, and Jutamaad Satayavivad. "Variation of sesamin, sesamolin and tocopherols in sesame (Sesamum indicum L.) seeds and oil products in Thailand." Food Chemistry 122, no. 3 (October 2010): 724–30. http://dx.doi.org/10.1016/j.foodchem.2010.03.044.

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47

Lee, Jinyoung, Yoosung Lee, and Eunok Choe. "Effects of sesamol, sesamin, and sesamolin extracted from roasted sesame oil on the thermal oxidation of methyl linoleate." LWT - Food Science and Technology 41, no. 10 (December 2008): 1871–75. http://dx.doi.org/10.1016/j.lwt.2007.11.019.

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48

Kancharla, Pavan Kumar, and Neelakantan Arumugam. "Variation of Oil, Sesamin, and Sesamolin Content in the Germplasm of the Ancient Oilseed Crop Sesamum indicum L." Journal of the American Oil Chemists' Society 97, no. 5 (March 15, 2020): 475–83. http://dx.doi.org/10.1002/aocs.12346.

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49

Shin, Bo Ram, Seung-Ok Yang, Hye-Won Song, Myung-Sub Chung, and Young-Suk Kim. "Effects of adsorbents on benzo(a)pyrene, sesamol, and sesamolin contents and volatile component profiles in sesame oil." Food Science and Biotechnology 24, no. 6 (December 2015): 2017–22. http://dx.doi.org/10.1007/s10068-015-0266-x.

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50

Jeon, Je-Seung, Chae Lee Park, Ahmed Shah Syed, Young-Mi Kim, Il Je Cho, and Chul Young Kim. "Preparative separation of sesamin and sesamolin from defatted sesame meal via centrifugal partition chromatography with consecutive sample injection." Journal of Chromatography B 1011 (February 2016): 108–13. http://dx.doi.org/10.1016/j.jchromb.2015.12.062.

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