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Статті в журналах з теми "Rechargeable-Iron Batteries"

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Автор: Grafiati

Опубліковано: 6 вересня 2023

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1

Ritchie, A. G., P. G. Bowles, and D. P. Scattergood. "Lithium-ion/iron sulphide rechargeable batteries." Journal of Power Sources 136, no. 2 (October 2004): 276–80. http://dx.doi.org/10.1016/j.jpowsour.2004.03.043.

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2

You, Gongchuan, and Liang He. "High Performance Electrolyte for Iron-Ion batteries." Academic Journal of Science and Technology 5, no. 2 (April 2, 2023): 244–47. http://dx.doi.org/10.54097/ajst.v5i2.6995.

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Анотація:

Aqueous rechargeable batteries have received widespread attention due to their excellent power density, simple manufacturing process, and inexpensive electrolyte. Iron-ion batteries are expected to meet the goals of high safety, low cost, and non-toxicity pursued in the field of rechargeable batteries. However, passivation, parasitic hydrogen evolution reaction (HER), and low electroplating efficiency (50%-70%) limit the improvement of electrochemical performance, which greatly restricts their practical application. In this study, a high-performance electrolyte for iron-ion batteries was prepared, and the effect of zinc chloride (ZnCl2) additives on inhibiting HER and the improvement of coulomb efficiency in ferrous chloride (FeCl2) electrolyte was explored. Additionally, the effect of the addition of complexing agents in the electrolyte on the coulomb efficiency of the electrodes was studied. It’s demonstrated that the electrode can still obtain a coulomb efficiency of nearly 100% after 20 hours cycling in the electrolyte containing ZnCl2 additive and FeCl2, while in FeCl2 electrolyte, its coulomb efficiency after 20 hours of cycling is only 65%.

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3

He, Z., F. Xiong, S. Tan, X. Yao, C. Zhang, and Q. An. "Iron metal anode for aqueous rechargeable batteries." Materials Today Advances 11 (September 2021): 100156. http://dx.doi.org/10.1016/j.mtadv.2021.100156.

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4

Kumar, Harish, and A. K. Shukla. "Fabrication Fe/Fe₃O₄/Graphene Nanocomposite Electrode Material for Rechargeable Ni/Fe Batteries in Hybrid Electric Vehicles." International Letters of Chemistry, Physics and Astronomy 19 (October 2013): 15–25. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.19.15.

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Fe/Fe3O4/Graphene composite electrode material was synthesized by a thermal reduction method and then used as anode material along with Nickel cathode in rechargeable Ni/Fe alkaline batteries in hybrid electric vehicles. Reduced graphene /Fe/Fe3O4 composite electrode material was prepared using a facile three step synthesis involving synthesis of iron oxalate and subsequent reduction of exfoliated graphene oxide and iron oxalate by thermal decomposition method. The synthesis approach presents a promising route for a large-scale production of reduced graphene /Fe/Fe3O4 composite as electrode material for Ni/Fe rechargeable batteries. The particle size and structure of the samples were characterized by SEM and XRD.

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5

Kumar, Harish, and A. K. Shukla. "Fabrication Fe/Fe<sub>3</sub>O<sub>4</sub>/Graphene Nanocomposite Electrode Material for Rechargeable Ni/Fe Batteries in Hybrid Electric Vehicles." International Letters of Chemistry, Physics and Astronomy 19 (October 2, 2013): 15–25. http://dx.doi.org/10.56431/p-oqaeru.

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Fe/Fe3O4/Graphene composite electrode material was synthesized by a thermal reduction method and then used as anode material along with Nickel cathode in rechargeable Ni/Fe alkaline batteries in hybrid electric vehicles. Reduced graphene /Fe/Fe3O4 composite electrode material was prepared using a facile three step synthesis involving synthesis of iron oxalate and subsequent reduction of exfoliated graphene oxide and iron oxalate by thermal decomposition method. The synthesis approach presents a promising route for a large-scale production of reduced graphene /Fe/Fe3O4 composite as electrode material for Ni/Fe rechargeable batteries. The particle size and structure of the samples were characterized by SEM and XRD.

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6

Hayashi, Kazushi, Yasutaka Maeda, Tsubasa Suzuki, Hisatoshi Sakamoto, Toshihiro Kugimiya, Wai Kian Tan, Go Kawamura, Hiroyuki Muto, and Atsunori Matsuda. "Development of Iron-Based Rechargeable Batteries with Sintered Porous Iron Electrodes." ECS Transactions 75, no. 18 (January 10, 2017): 111–16. http://dx.doi.org/10.1149/07518.0111ecst.

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7

Paulraj, Alagar Raj, Yohannes Kiros, Björn Skårman, and Hilmar Vidarsson. "Core/Shell Structure Nano-Iron/Iron Carbide Electrodes for Rechargeable Alkaline Iron Batteries." Journal of The Electrochemical Society 164, no. 7 (2017): A1665—A1672. http://dx.doi.org/10.1149/2.1431707jes.

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8

Mayer, Sergio Federico, Cristina de la Calle, María Teresa Fernández-Díaz, José Manuel Amarilla, and José Antonio Alonso. "Nitridation effect on lithium iron phosphate cathode for rechargeable batteries." RSC Advances 12, no. 6 (2022): 3696–707. http://dx.doi.org/10.1039/d1ra07574h.

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9

Abdalla, Abdallah H., Charles I. Oseghale, Jorge O. Gil Posada, and Peter J. Hall. "Rechargeable nickel–iron batteries for large‐scale energy storage." IET Renewable Power Generation 10, no. 10 (November 2016): 1529–34. http://dx.doi.org/10.1049/iet-rpg.2016.0051.

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10

Morzilli, S., and B. Scrosati. "Iron oxide electrodes in lithium organic electrolyte rechargeable batteries." Electrochimica Acta 30, no. 10 (October 1985): 1271–76. http://dx.doi.org/10.1016/0013-4686(85)85002-7.

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11

Tsuneishi, Taku, Takuma Esaki, Hisatoshi Sakamoto, Kazushi Hayashi, G. Kawamura, Hiroyuki Muto, and Atsunori Matsuda. "Iron Composite Anodes for Fabricating All-Solid-State Iron-Air Rechargeable Batteries." Key Engineering Materials 616 (June 2014): 114–19. http://dx.doi.org/10.4028/www.scientific.net/kem.616.114.

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Hydroxide ion conductors containing KOH were prepared for application in an all-solid-state Fe–air battery. ZrO2 and Mg–Al layered double hydroxide (LDH) were employed as the matrix materials. The ionic conductivity and conducting ion species were evaluated by impedance and electromotive force measurements. Repeated charge and discharge were achieved by using negative electrodes composed of the solid electrolyte and iron oxide-supported carbon.

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12

Parola, Valeria La, Vincenzo Turco Liveri, Lorena Todaro, Domenico Lombardo, Elvira Maria Bauer, Alessandro Dell'Era, Alessandro Longo, et al. "Iron and lithium-iron alkyl phosphates as nanostructured material for rechargeable batteries." Materials Letters 220 (June 2018): 58–61. http://dx.doi.org/10.1016/j.matlet.2018.02.112.

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13

Weinrich, Henning, Yasin Emre Durmus, Hermann Tempel, Hans Kungl, and Rüdiger-A. Eichel. "Silicon and Iron as Resource-Efficient Anode Materials for Ambient-Temperature Metal-Air Batteries: A Review." Materials 12, no. 13 (July 2, 2019): 2134. http://dx.doi.org/10.3390/ma12132134.

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Анотація:

Metal-air batteries provide a most promising battery technology given their outstanding potential energy densities, which are desirable for both stationary and mobile applications in a “beyond lithium-ion” battery market. Silicon- and iron-air batteries underwent less research and development compared to lithium- and zinc-air batteries. Nevertheless, in the recent past, the two also-ran battery systems made considerable progress and attracted rising research interest due to the excellent resource-efficiency of silicon and iron. Silicon and iron are among the top five of the most abundant elements in the Earth’s crust, which ensures almost infinite material supply of the anode materials, even for large scale applications. Furthermore, primary silicon-air batteries are set to provide one of the highest energy densities among all types of batteries, while iron-air batteries are frequently considered as a highly rechargeable system with decent performance characteristics. Considering fundamental aspects for the anode materials, i.e., the metal electrodes, in this review we will first outline the challenges, which explicitly apply to silicon- and iron-air batteries and prevented them from a broad implementation so far. Afterwards, we provide an extensive literature survey regarding state-of-the-art experimental approaches, which are set to resolve the aforementioned challenges and might enable the introduction of silicon- and iron-air batteries into the battery market in the future.

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14

Weinrich, Henning, Jérémy Come, Hermann Tempel, Hans Kungl, Rüdiger-A. Eichel, and Nina Balke. "Understanding the nanoscale redox-behavior of iron-anodes for rechargeable iron-air batteries." Nano Energy 41 (November 2017): 706–16. http://dx.doi.org/10.1016/j.nanoen.2017.10.023.

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15

Shakoor, Rana A., Chan Sun Park, Arsalan A. Raja, Jaeho Shin, and Ramazan Kahraman. "A mixed iron–manganese based pyrophosphate cathode, Na2Fe0.5Mn0.5P2O7, for rechargeable sodium ion batteries." Physical Chemistry Chemical Physics 18, no. 5 (2016): 3929–35. http://dx.doi.org/10.1039/c5cp06836c.

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16

Ellis, B. L., W. R. M. Makahnouk, Y. Makimura, K. Toghill, and L. F. Nazar. "A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries." Nature Materials 6, no. 10 (September 9, 2007): 749–53. http://dx.doi.org/10.1038/nmat2007.

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17

Berger, Cornelius M., Abdelfattah Mahmoud, Raphaël P. Hermann, Waldemar Braun, Elena Yazhenskikh, Yoo Jung Sohn, Norbert H. Menzler, Olivier Guillon, and Martin Bram. "Calcium-Iron Oxide as Energy Storage Medium in Rechargeable Oxide Batteries." Journal of the American Ceramic Society 99, no. 12 (August 8, 2016): 4083–92. http://dx.doi.org/10.1111/jace.14439.

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18

PIETRZAK, TOMASZ K., IRENA GORZKOWSKA, JAN L. NOWIŃSKI, JERZY E. GARBARCZYK, and MAREK WASIUCIONEK. "PREPARATION OF TRIPHYLITE-LIKE GLASSES AND NANOMATERIALS IN THE LiFePO4-V2O5 SYSTEM AND STUDY ON THEIR ELECTRICAL CONDUCTIVITY." Functional Materials Letters 04, no. 02 (June 2011): 143–45. http://dx.doi.org/10.1142/s1793604711001750.

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Анотація:

Research on lithium iron phosphates is stimulated by their application as cathodes in Li -ion rechargeable batteries. The aim of this study was to enhance its initially poor electronic conductivity. A thermal nanocrystallization is applied to lithium-iron-phosphate and lithium-vanadium-iron-phosphates materials resulting in a significant increase of the electronic conductivity of the latter (almost 10-6 S/cm). The obtained nanomaterial exhibits very good thermal stability (up to 625°C), the activation energy 0.51 eV and moderate electronic conductivity at the room temperature, which is, however, a good starting point for further enhancement.

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19

Khezri, Ramin, Kridsada Jirasattayaporn, Ali Abbasi, Thandavarayan Maiyalagan, Ahmad Azmin Mohamad, and Soorathep Kheawhom. "Three-Dimensional Fibrous Iron as Anode Current Collector for Rechargeable Zinc–Air Batteries." Energies 13, no. 6 (March 19, 2020): 1429. http://dx.doi.org/10.3390/en13061429.

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A three-dimensional (3D) fibrous structure with a high active surface and conductive pathway proved to be an excellent anode current collector for rechargeable zinc–air batteries (ZABs). Herein, a cost-effective and highly stable zinc (Zn) electrode, based on Zn electrodeposited on iron fibers (Zn/IF), is duly examined. Electrochemical characteristics of the proposed electrode are seen to compete with a conventional zinc/nickel foam (Zn/NF) electrode, implying that it can be a suitable alternative for use in ZABs. Results show that the Zn/IF electrode exhibits an almost similar trend as Zn/NF in cyclic voltammetry (CV). Moreover, by using a Zn/IF electrode, electrochemical impedance spectroscopy (EIS) demonstrates lower charge transfer resistance. In the application of a rechargeable ZAB, the fibrous Zn/IF electrode exhibits a high coulombic efficiency (CE) of 78%, close to the conventional Zn/NF (80%), with almost similar capacity and lower charge transfer resistance, after 200 charge/discharge cycles. It is evident that all the positive features of Zn/IF, especially its low cost, shows that it can be a valuable anode for ZABs.

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20

Manohar, Aswin K., Chenguang Yang, Souradip Malkhandi, Bo Yang, G. K. Surya Prakash, and S. R. Narayanan. "Understanding the Factors Affecting the Formation of Carbonyl Iron Electrodes in Rechargeable Alkaline Iron Batteries." Journal of The Electrochemical Society 159, no. 12 (2012): A2148—A2155. http://dx.doi.org/10.1149/2.021301jes.

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21

Sun, Ling Na. "Research of LiFePO₄ as Positive Electrode Materials." Applied Mechanics and Materials 217-219 (November 2012): 792–95. http://dx.doi.org/10.4028/www.scientific.net/amm.217-219.792.

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LiFePO4 is a promising cathode material for the next generation of a lithium-ion rechargeable battery. This paper introduces the research progress in recent years on LiFePO4 as positive electrode materials for lithium ion batteries. The methods of the preparation and modification, relation ship between structure and performance, and prospect of olivine-type lithium iron phosphate cathode materials was reviewed. Porous structures offer the potential to improve the electrochemical properties of LiFePO4.

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22

Yu, S. H., M. Shokouhimehr, T. Hyeon, and Y. E. Sung. "Iron Hexacyanoferrate Nanoparticles as Cathode Materials for Lithium and Sodium Rechargeable Batteries." ECS Electrochemistry Letters 2, no. 4 (February 6, 2013): A39—A41. http://dx.doi.org/10.1149/2.008304eel.

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23

Peng, Zhuo, Qiulong Wei, Shuangshuang Tan, Pan He, Wen Luo, Qinyou An, and Liqiang Mai. "Novel layered iron vanadate cathode for high-capacity aqueous rechargeable zinc batteries." Chemical Communications 54, no. 32 (2018): 4041–44. http://dx.doi.org/10.1039/c8cc00987b.

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A facile water bath method was developed to synthesize layered iron vanadate Fe₅V₁₅O₃₉(OH)₉·9H₂O (FVO) nanosheets. As a cathode material FVO delivers a high capacity of 385 mA h g⁻¹ at 0.1 A g⁻¹ due to the high proportion of variable valence elements (Fe and V). A remarkable cycling performance at a high current density is achieved in a Zn(TFSI)₂ electrolyte.

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24

Lu, Jiechen, Shin-ichi Nishimura, and Atsuo Yamada. "A Fe-rich sodium iron orthophosphate as cathode material for rechargeable batteries." Electrochemistry Communications 79 (June 2017): 51–54. http://dx.doi.org/10.1016/j.elecom.2017.04.012.

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25

Yang, Fan, Jinhao Xie, Xiaoqing Liu, Yinxiang Zeng, Minghua Chen, and Xihong Lu. "Iron-based nanoparticles encapsulated in super-large 3D carbon nanotube networks as a bifunctional catalyst for ultrastable rechargeable zinc–air batteries." Journal of Materials Chemistry A 8, no. 48 (2020): 25913–18. http://dx.doi.org/10.1039/d0ta09115d.

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26

He, Ting, Bingzhang Lu, Yang Chen, Yong Wang, Yaqiang Zhang, John L. Davenport, Alan P. Chen, et al. "Nanowrinkled Carbon Aerogels Embedded with FeNx Sites as Effective Oxygen Electrodes for Rechargeable Zinc-Air Battery." Research 2019 (December 20, 2019): 1–13. http://dx.doi.org/10.34133/2019/6813585.

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Rational design of single-metal atom sites in carbon substrates by a flexible strategy is highly desired for the preparation of high-performance catalysts for metal-air batteries. In this study, biomass hydrogel reactors are utilized as structural templates to prepare carbon aerogels embedded with single iron atoms by controlled pyrolysis. The tortuous and interlaced hydrogel chains lead to the formation of abundant nanowrinkles in the porous carbon aerogels, and single iron atoms are dispersed and stabilized within the defective carbon skeletons. X-ray absorption spectroscopy measurements indicate that the iron centers are mostly involved in the coordination structure of FeN4, with a minor fraction (ca. 1/5) in the form of FeN3C. First-principles calculations show that the FeNx sites in the Stone-Wales configurations induced by the nanowrinkles of the hierarchically porous carbon aerogels show a much lower free energy than the normal counterparts. The resulting iron and nitrogen-codoped carbon aerogels exhibit excellent and reversible oxygen electrocatalytic activity, and can be used as bifunctional cathode catalysts in rechargeable Zn-air batteries, with a performance even better than that based on commercial Pt/C and RuO2 catalysts. Results from this study highlight the significance of structural distortions of the metal sites in carbon matrices in the design and engineering of highly active single-atom catalysts.

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27

Lei, Danni, Dong-Chan Lee, Alexandre Magasinski, Enbo Zhao, Daniel Steingart, and Gleb Yushin. "Performance Enhancement and Side Reactions in Rechargeable Nickel–Iron Batteries with Nanostructured Electrodes." ACS Applied Materials & Interfaces 8, no. 3 (January 14, 2016): 2088–96. http://dx.doi.org/10.1021/acsami.5b10547.

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28

Myung, Seung-Taek, Shuhei Sakurada, Hitoshi Yashiro, and Yang-Kook Sun. "Iron trifluoride synthesized via evaporation method and its application to rechargeable lithium batteries." Journal of Power Sources 223 (February 2013): 1–8. http://dx.doi.org/10.1016/j.jpowsour.2012.09.027.

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29

Kim, Hyungsub, Gabin Yoon, Inchul Park, Jihyun Hong, Kyu-Young Park, Jongsoon Kim, Kug-Seung Lee, Nark-Eon Sung, Seongsu Lee, and Kisuk Kang. "Highly Stable Iron- and Manganese-Based Cathodes for Long-Lasting Sodium Rechargeable Batteries." Chemistry of Materials 28, no. 20 (October 14, 2016): 7241–49. http://dx.doi.org/10.1021/acs.chemmater.6b01766.

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30

Ait Salah, A., P. Jozwiak, K. Zaghib, J. Garbarczyk, F. Gendron, A. Mauger, and C. M. Julien. "FTIR features of lithium-iron phosphates as electrode materials for rechargeable lithium batteries." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 65, no. 5 (December 2006): 1007–13. http://dx.doi.org/10.1016/j.saa.2006.01.019.

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31

Ramzan, M., S. Lebègue, and R. Ahuja. "Ab initio study of lithium and sodium iron fluorophosphate cathodes for rechargeable batteries." Applied Physics Letters 94, no. 15 (April 13, 2009): 151904. http://dx.doi.org/10.1063/1.3119704.

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32

Li, Chilin, Lin Gu, Jianwei Tong, Susumu Tsukimoto, and Joachim Maier. "A Mesoporous Iron-Based Fluoride Cathode of Tunnel Structure for Rechargeable Lithium Batteries." Advanced Functional Materials 21, no. 8 (March 4, 2011): 1391–97. http://dx.doi.org/10.1002/adfm.201002213.

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33

Wu, Kunze, Lei Zhang, Yifei Yuan, Linxin Zhong, Zhongxin Chen, Xiao Chi, Hao Lu, et al. "An Iron‐Decorated Carbon Aerogel for Rechargeable Flow and Flexible Zn–Air Batteries." Advanced Materials 32, no. 32 (July 2020): 2002292. http://dx.doi.org/10.1002/adma.202002292.

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34

ZHAO, Ming, Li-Fang JIAO, Hua-Tang YUAN, Jun-Li SUN, and Yan FENG. "High-rate Lithium Iron(II) Phosphate as Cathode Material for Rechargeable Lithium Batteries." Chinese Journal of Chemistry 26, no. 2 (February 2008): 290–94. http://dx.doi.org/10.1002/cjoc.200890057.

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35

Saiful Islam, M., and Peter R. Slater. "Solid-State Materials for Clean Energy: Insights from Atomic-Scale Modeling." MRS Bulletin 34, no. 12 (December 2009): 935–41. http://dx.doi.org/10.1557/mrs2009.216.

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AbstractFundamental advances in solid-state ionics for energy conversion and storage are crucial in addressing the global challenge of cleaner energy sources. This review aims to demonstrate the valuable role that modern computational techniques now play in providing deeper fundamental insight into materials for solid oxide fuel cells and rechargeable lithium batteries. The scope of contemporary work is illustrated by studies on topical materials encompassing perovskite-type proton conductors, gallium oxides with tetrahedral moieties, apatite-type silicates, and lithium iron phosphates. Key fundamental properties are examined, including mechanisms of ion migration, dopant-defect association, and surface structures and crystal morphologies.

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36

Shangguan, Enbo, Fei Li, Jing Li, Zhaorong Chang, Quanmin Li, Xiao-Zi Yuan, and Haijiang Wang. "FeS/C composite as high-performance anode material for alkaline nickel–iron rechargeable batteries." Journal of Power Sources 291 (September 2015): 29–39. http://dx.doi.org/10.1016/j.jpowsour.2015.05.019.

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37

Yu, Tingting, Qiang Li, Xiangyu Zhao, Hui Xia, Liqun Ma, Jinlan Wang, Ying Shirley Meng, and Xiaodong Shen. "Nanoconfined Iron Oxychloride Material as a High-Performance Cathode for Rechargeable Chloride Ion Batteries." ACS Energy Letters 2, no. 10 (September 14, 2017): 2341–48. http://dx.doi.org/10.1021/acsenergylett.7b00699.

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38

Lei, Danni, Dong-Chan Lee, Enbo Zhao, Alexandre Magasinski, Hong-Ryun Jung, Gene Berdichevsky, Daniel Steingart, and Gleb Yushin. "Iron oxide nanoconfined in carbon nanopores as high capacity anode for rechargeable alkaline batteries." Nano Energy 48 (June 2018): 170–79. http://dx.doi.org/10.1016/j.nanoen.2018.03.035.

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39

Meng, Fanlu, Haixia Zhong, Junmin Yan, and Xinbo Zhang. "Iron-chelated hydrogel-derived bifunctional oxygen electrocatalyst for high-performance rechargeable Zn–air batteries." Nano Research 10, no. 12 (January 14, 2017): 4436–47. http://dx.doi.org/10.1007/s12274-016-1343-z.

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40

Jadhav, Harsharaj S., Ramchandra S. Kalubarme, Arvind H. Jadhav, and Jeong Gil Seo. "Iron-nickel spinel oxide as an electrocatalyst for non-aqueous rechargeable lithium-oxygen batteries." Journal of Alloys and Compounds 666 (May 2016): 476–81. http://dx.doi.org/10.1016/j.jallcom.2016.01.131.

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41

MAINGOT, S., R. BADDOUR, J. P. PEREIRA-RAMOS, N. BAFFIER, and P. WILLMANN. "ChemInform Abstract: A New Iron V2O5 Bronze as Electrode Material for Rechargeable Lithium Batteries." ChemInform 25, no. 6 (August 19, 2010): no. http://dx.doi.org/10.1002/chin.199406015.

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42

Ichu. B. C and ONOCHOJA U. F.C. "Lithium ion battery research and development: the Nigerian potential." Pacific International Journal 3, no. 1 (March 31, 2020): 13–18. http://dx.doi.org/10.55014/pij.v3i1.88.

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Lithium-ion batteries (LiBs) are growing in popularity as energy storage devices. Handheld, portable electronic devices use LiBs based on Lithium Cobalt Oxide (LiCoO2) which in spite of its attendant safety risks offers high energy density. Other types of LiBsbased on Lithium iron phosphate (LiFePO4), Lithium-ion manganese oxide (LiMn2O4, Li2MnO3, or LMO), and Lithium nickel manganese cobalt oxide (LiNiMnCoO2 or NMC) have better safety issues with lower energy density. These batteries which are rechargeable are used in cell phones, laptops and tablets, electric and hybrid cars (EV), grid storage, cordless power tools, medical equipment, and other high-tech devices. Nigeria, with a population above two hundred million, is a big market for lithium-ion batteries. The mineral ore for the cathode of lithium-ion batteries is available in Kogi, Nasarawa, Ekiti, Kwara, Cross River, Oyo, and the Plateau States. These include amblygonite(Li,Na)AlPO4(F,OH), Lithium Sodium Aluminum Phosphate Fluoride Hydroxide and lepidolite (K(Li,Al)3(Al,Si, Rb)4O10(F,OH)2, Potassium lithium aluminum silicate hydroxide fluoride, spodumene: (LiAl(SiO3)2 Lithium Aluminum Silicate, petalite: (LiAl(Si2O5)2 aluminum hydroxy-[hydroxy(oxo)silyl]oxy- oxosilane; lithium), and graphite which is used as the anode material is available in Kaduna and the Adamawa States. In view of these available resources, the Projects Development Institute (PRODA) Enugu, a Science and Engineering based Research Institute under the supervision of the Federal Ministry of Science and Technology has pioneered battery research and development with a particular focus on Lithium-ion batteries. It is expected in the long run that lithium-ion batteries would be produced locally for rechargeable lanterns in view of the country’s energy deficit. This would spring up small and medium enterprises that would drive the economy by the beneficiation and refining of the content of the raw material which is available in the country and thus creating wealth for our citizenry.

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Manohar, Aswin K., Chenguang Yang, Souradip Malkhandi, G. K. Surya Prakash, and S. R. Narayanan. "Enhancing the Performance of the Rechargeable Iron Electrode in Alkaline Batteries with Bismuth Oxide and Iron Sulfide Additives." Journal of The Electrochemical Society 160, no. 11 (2013): A2078—A2084. http://dx.doi.org/10.1149/2.066311jes.

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44

Weinrich, Henning, Markus Gehring, Hermann Tempel, Hans Kungl, and Rüdiger-A. Eichel. "Impact of the charging conditions on the discharge performance of rechargeable iron-anodes for alkaline iron–air batteries." Journal of Applied Electrochemistry 48, no. 4 (February 23, 2018): 451–62. http://dx.doi.org/10.1007/s10800-018-1176-4.

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45

Liu, Ying, Jungwon Heo, Xueying Li, Yuanzheng Sun, Younki Lee, Du-Hyun Lim, Hyo-Jun Ahn, Kwon-Koo Cho, Rong Yang, and Jou-Hyeon Ahn. "Iron Disulfide Cathode Material Incorporated in Highly Ordered Mesoporous Carbon for Rechargeable Lithium Ion Batteries." Science of Advanced Materials 12, no. 9 (September 1, 2020): 1265–70. http://dx.doi.org/10.1166/sam.2020.3815.

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A highly ordered mesoporous carbon@iron disulfide (CMK-5@FeS2) composite was prepared via an in-situ impregnation and sulfurization method. The CMK-5 matrix with excellent conductivity and high surface area not only formed a continuous conductive network to improve the performance of the CMK-5@FeS2 composite, but also provided sufficient space to buffer the volume changes during cycling. The CMK-5@FeS2 cell exhibited excellent electrochemical performance. After 80 cycles, the CMK-5@FeS2 cell showed the discharge capacities of 650 and 380 mAh g–1 at 2 C and 5 C, respectively. The excellent results show that CMK-5 with unique mesoporous structure can contribute to accelerating ion transfer in the electrode due to the easy accessibility of the electrolyte, which implies CMK-5@FeS2 composite could be a promising cathode active material for rechargeable lithium ion (Li-ion) batteries.

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46

Zhao, Meiqi, Haoran Liu, Hongwei Zhang, Wen Chen, Hanqin Sun, Zhenhua Wang, Biao Zhang, et al. "A pH-universal ORR catalyst with single-atom iron sites derived from a double-layer MOF for superior flexible quasi-solid-state rechargeable Zn–air batteries." Energy & Environmental Science 14, no. 12 (2021): 6455–63. http://dx.doi.org/10.1039/d1ee01602d.

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47

Li, Jing, Jiaqian Zheng, Chengke Wu, Huijie Zhang, Tingyi Jin, Fuquan Wang, Quanmin Li, and Enbo Shangguan. "Facile synthesis of Fe3S4 microspheres as advanced anode materials for alkaline iron-based rechargeable batteries." Journal of Alloys and Compounds 874 (September 2021): 159873. http://dx.doi.org/10.1016/j.jallcom.2021.159873.

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48

Yabuuchi, Naoaki, and Shinichi Komaba. "Recent research progress on iron- and manganese-based positive electrode materials for rechargeable sodium batteries." Science and Technology of Advanced Materials 15, no. 4 (August 2014): 043501. http://dx.doi.org/10.1088/1468-6996/15/4/043501.

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49

Braun, Waldemar, Viktoria Erfurt, Florian Thaler, Norbert H. Menzler, Robert Spatschek, and Lorenz Singheiser. "Kinetic Study of Iron Based Storage Materials for the Use in Rechargeable Oxide Batteries (ROB)." ECS Transactions 75, no. 43 (January 5, 2017): 59–73. http://dx.doi.org/10.1149/07543.0059ecst.

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50

Mathur, Ankita, and Aditi Halder. "One-step synthesis of bifunctional iron-doped manganese oxide nanorods for rechargeable zinc–air batteries." Catalysis Science & Technology 9, no. 5 (2019): 1245–54. http://dx.doi.org/10.1039/c8cy02498g.

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Iron doped MnO₂ nanorods are successfully synthesized via one step hydrothermal method. The nanorods shows remarkable high bifunctional electrocatalytic activity for oxygen reduction as well as oxygen evolution reaction. For practical applications, a solid-state zinc–air battery was made for powering a light emitting diode.

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