Дисертації з теми "Polymer Nanocomposite coatings"
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Brandt, Jennifer M. "Rheological and abrasion resistant properties of transparent polymer/silicate nanocomposite coatings." [Gainesville, Fla.] : University of Florida, 2005. http://purl.fcla.edu/fcla/etd/UFE0010040.
Повний текст джерелаEaves, Elizabeth. "Soft-soft nanocomposite coating materials produced by emulsion polymerisation." Thesis, University of Manchester, 2015. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.654865.
Повний текст джерелаBeemat, Jaspreet S. "Processing and Properties of Hybrid Silane-Epoxy Nanocomposite Coatings." University of Cincinnati / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1352992819.
Повний текст джерелаShabani-Nooshabadi, M., and Y. Jafari. "Electropolymerized Coatings of Poly (o-anisidine) and Poly (o-anisidine)-TiO2 Nanocompsite on Aluminum Alloy 3004 by using the Galvanostatic Method and Their Corrosion Protection Performance." Thesis, Sumy State University, 2012. http://essuir.sumdu.edu.ua/handle/123456789/34811.
Повний текст джерелаJafarzadeh, Shadi. "Functional composite coatings containing conducting polymers." Doctoral thesis, KTH, Yt- och korrosionsvetenskap, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-155132.
Повний текст джерелаQC 20141103
Rosidian, Aprillya. "Nanocomposite of ZrO2/Polymer Thin-Film Coatings by the Ionically Self-Assembled Monolayer Technique." Thesis, Virginia Tech, 1998. http://hdl.handle.net/10919/36560.
Повний текст джерелаMaster of Science
Yang, Hongjiang. "Synthesis, Processing and Characterization of Polymer Derived Ceramic Nanocomposite Coating Reinforced with Carbon Nanotube Preforms." Master's thesis, University of Central Florida, 2014. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/6387.
Повний текст джерелаM.S.M.E.
Masters
Mechanical and Aerospace Engineering
Engineering and Computer Science
Mechanical Engineering; Mechanical Systems Track
Tong, Zhaohui. "Water-based suspension of polymer nanoclay composite prepared via miniemulsion polymerization." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2007. http://hdl.handle.net/1853/19763.
Повний текст джерелаCommittee Chair: Yulin Deng; Committee Member: Howard (Jeff) L. Empie; Committee Member: J. Carson Meredith; Committee Member: Jeffery S. Hsieh; Committee Member: Timothy Patterson.
Santese, Francesca. "Molecular modeling of multi-functional nanostructured materials and coatings." Doctoral thesis, Università degli studi di Trieste, 2014. http://hdl.handle.net/10077/9974.
Повний текст джерелаMateriali e rivestimenti nanostrutturati possono potenzialmente apportare significativi cambiante nel campo della nanoscienze, nonché offrire una nuova generazione di materiali con caratteristiche e performance migliori. A questo proposito le tecniche computazionali diventano uno strumento fondamentale, in grado di ridurre notevolmente i tempi che vanno dall’idea iniziale al prodotto finito. La simulazione molecolare permette infatti la previsione delle proprietà macroscopiche prima che i materiali vengano preparati e caratterizzati sperimentalmente; consente inoltre una migliore comprensione dei fenomeni fisici su scala nanometrica. In questo lavoro di tesi sono presentati alcuni casi studio in cui vengono proposte diverse procedure computazionali per affrontare importanti aspetti come la bagnabilità della superficie, l’effetto della dimensione e della forma delle nanoparticelle e i loro meccanismi di aggregazione/dispersione. In questo contesto, si è dimostrata la vasta applicabilità della modellazione molecolare evidenziando quindi come questa rappresenti un potente strumento per comprendere e controllare le proprietà finali di materiali nanostrutturati, aprendo così la strada ad una progettazione in silico di nuovi materiali.
Nanostructured materials and coatings have the potential to change materials science significantly, as well as to provide a new generation of materials with a quantum improvement in properties. In this regard computational materials science becomes a powerful tool. It is able to rapidly reduce the time from concept to end product. Molecular simulation enables the prediction of properties of these new materials before preparation, processing, and experimental characterization, as well as a better understanding of the physical phenomena at the nanoscale level. In this thesis we present several study cases in which we propose different computational recipes to deal with different important topics such as surface wettability, effect of nanoparticles size and shape and nanoparticles aggregation/dispersion. In this context, we demonstrate the broad applicability of the molecular modelling and we ascertain that molecular simulation represent a powerful tool to understand and control the nanomaterials properties thus opening avenues for the in silico design of new materials.
XXVI Ciclo
1985
Xu, Jianhua. "Rheology of polymeric suspensions polymer nanocomposites and waterborne coatings /." Columbus, Ohio : Ohio State University, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1127317214.
Повний текст джерелаStevenson, Alexandra Rose. "Revision-Polyurethane-Graphene Nanocomposites for Corrosion-Resistant Coatings." DigitalCommons@CalPoly, 2015. https://digitalcommons.calpoly.edu/theses/1492.
Повний текст джерелаGeng, Kebin. "MECHANICAL EVALUATION OF NANOCOMPOSITE COATINGS." UKnowledge, 2006. http://uknowledge.uky.edu/gradschool_diss/395.
Повний текст джерелаMASOOD, MUHAMMAD TAMOOR. "Improving tribomechanical properties of polymeric nanocomposite coatings." Doctoral thesis, Università degli studi di Genova, 2018. http://hdl.handle.net/11567/930597.
Повний текст джерелаKönig, Meike. "Functional Coatings with Polymer Brushes." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2013. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-126365.
Повний текст джерелаShan, Fei Shan. "SYSTEMATIC STUDIES ON HIGH PERFORMANCE FLAME RETARDANT OF THIAZOLE SUBSTITUTED POLYBENZOXAZINE AND POLYBENZOXAZINE-LAPONITE NANOCOMPOSITE CONTAINING HIGH NANOFILLER CONTENT." Case Western Reserve University School of Graduate Studies / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=case1522861786561848.
Повний текст джерелаMohomed, Kadine. "Thermal analyses of hydrophilic polymers used in nanocomposites and biocompatible coatings." [Tampa, Fla] : University of South Florida, 2006. http://purl.fcla.edu/usf/dc/et/SFE0001442.
Повний текст джерелаShah, Kunal G. "Conducting Polymers / Polyimide-Clay Nanocomposite Coatings for Corrosion Protection of AA-2024 Alloy." Cincinnati, Ohio : University of Cincinnati, 2004. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=ucin1083723910.
Повний текст джерелаFogelström, Linda. "Polymer Nanocomposites in Thin Film Applications." Doctoral thesis, KTH, Ytbehandlingsteknik, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-12400.
Повний текст джерелаQC20100621
Wang, Nannan. "Carbon-coated nanoparticles and their application in high performance polymer nanocomposites." Thesis, University of Exeter, 2018. http://hdl.handle.net/10871/33110.
Повний текст джерелаAl-Kawaz, Ammar. "Development and rheological analysis of a surface polymer nanocomposite anti-friction." Thesis, Strasbourg, 2015. http://www.theses.fr/2015STRAE025/document.
Повний текст джерелаThe goal of this thesis is the identification of couplings (nanoparticles / matrix poly (methyl methacrylate) PMMA) which ensure PMMA surface rigidity while maintaining maximum transparency. The choice fell on three types of carbonaceous nanoparticles: Few layer graphene (FLG), graphene oxide (GO) and carbon nanotubes (MWCNT). A first part describes the preparation and functionalization of these three types of nanoparticles to provide a better dispersion in the matrix. Two methods were used to prepare nanocomposite materials: bulk polymerization and solution blending. A second part presents the characterization of the mechanical properties of these coatings in three stages: volume, surface and thin layer coating (15-20μm). The main results show that nanocomposites made delay the onset of plasticity compared with pure PMMA, even at a low percentage, and help to limit the effects of surface scratches. The small percentage of reinforcement keeps the transparency and the more the thickness decreases the more the rate of reinforcement can increase without degrading the mechanical properties of the coating. Moreover, nanoparticles chosen as the polymer matrix of reinforcing agents prove to be very good candidates for reduction in friction compared to a plasticizer such Erucamide
Metzman, Jonathan Seth. "Nanoparticle Encapsulation and Aggregation Control in Anti-reflection Coatings and Organic Photovoltaics." Diss., Virginia Tech, 2018. http://hdl.handle.net/10919/85580.
Повний текст джерелаPh. D.
Investigations are presented on the quality of distribution or dispersion of functional inorganic (composed of silicon dioxide or silver) particles that have dimensions of less than 100 nanometers, called nanoparticles. The nanoparticle surfaces were covered with polymer layers, where polymers are organic materials with repeating molecular structures. The study of these nanoparticle distribution effects were first examined in anti-reflection coatings (ARCs). ARCs induce transparency of windows or glasses through a reduction in the reflection of light. Here, the ARCs were fabricated as self-assembled thin-films (films with thicknesses ranging from 1 to 2000 nanometers). The self-assembly process here was carried out by immersing a charged substrate (microscope slide) into a solution with an oppositely-charged material. The attraction of the material to the substrate leads to thin-film growth. The process can continue by sequentially immersing the thin-film into oppositely-charged solutions for a desired number of thin-film layers. This technique is called ionic self-assembled multilayers (ISAMs). ARCs created by ISAM with charged polymers (polyelectrolytes) and silicon dioxide nanoparticles (SiO2 NPs) can lead to highly-transparent films, but unfortunately, they lack the stability and scratch-resistance necessary for commercial applications. In this dissertation, we address the lack of stability in the ISAM ARCs by adding additional polyelectrolyte layers that can develop strong, covalent bonds, while also examining nanoparticle dispersive properties. First, SiO2 NP surfaces were coated in solution with a polyelectrolyte called diazo-resin, which can form covalent bonds by UV-light exposure of the film. After tuning the concentration for the added diazo-resin, the coated SiO2 NPs were used to make ARCs ISAM films. The ARCs had excellent nanoparticle dispersion, high levels of transparency, and chemical stability. Chemically stability entails that the integrity of the film was unaffected by exposure to polar organic solvents or strong polyelectrolytes. In a second method, two additional v polyelectrolyte layers were added into the original polyelectrolyte/SiO2 NP design. Here, heating of the film to 200 oC temperatures induced strong covalent bonding between the polyelectrolytes. Variation of the solution pH dramatically changed the polyelectrolyte thickness, the nanoparticle dispersion, the scratch-resistance, and the anti-reflection. An optimum trade-off was discovered at a pH of 5.2, where the anti-reflection was excellent (amount of transmitted light over 99%), along with a substantially improved scratch-resistance. A change of pH from 6.0 (highest tested pH) to 5.2 (optimal) caused a difference in the scratch-resistance by a factor of seven. In these findings, we introduce stability enhancing properties from films composed purely of polyelectrolytes into nanoparticle-containing ISAM films. We also show that a simple adjustment of solution parameters, such as the pH value, can cause substantial differences in the film properties. Nanoparticle dispersion properties were next investigated in organic photovoltaics (OPVs) OPVs use semiconducting polymers to convert sunlight into usable electricity. They have many advantages over traditional solar cells, including their simple processing, low-cost, flexibility, and lightweight. However, OPVs are limited by their total optical absorption or the amount of light that can potentially be converted to electricity. The addition of plasmonic nanoparticles into an OPV device is a suitable way to increase optical absorption without changing the other device properties. Plasmonic nanoparticles, which are composed of noble metals (such as silver or gold), act as “light antennas” that concentrate incoming light and radiate it around the particle. In this dissertation, we investigate the dispersion and stability effects of polymer or metallic layers on silver nanoplates (AgNPs). The stability of the AgNPs was found to be greatly enhanced by coating the nanoparticle edges with a thin gold layer (AuAgNPs). AuAgNPs could then be introduced into a conductive, acidic layer of the OPVs (PEDOT:PSS) to increase the overall light absorption, which otherwise would be impossible with uncoated AgNPs. Next, the AgNPs were distributed on top of the photoactive layer or the layer that is responsible for absorbing light. Coating the AgNPs with a polystyrene polymer layer (PS-AgNPs) allowed for excellent dispersion on this layer and contrastingly, dispersion of the uncoated AgNPs was poor. An increased amount PS-AgNPs added on top of the photoactive layer progressively increased the optical absorption of the OPV devices. However, trends were quite different for the power conversion efficiency or the ratio of electricity power to sunlight power in the OPV device. The greatest PCE enhancements (27 – 32%) were found at a relatively low coverage level (using a solution concentration of 0.29 to 0.57 nM) of the PS-AgNPs on the photoactive layer.
Musino, Dafne. "Impact of surface modification on the structure and dynamics of silica-polymer nanocomposites." Thesis, Montpellier, 2017. http://www.theses.fr/2017MONTS015/document.
Повний текст джерелаNanocomposite materials made by dispersion of nano-scale fillers in a soft polymer matrix attract industrial interest because of their enhanced properties. During their formulation, filler-filler and filler-polymer interactions affect the dispersion of the particles, and thus the final nanocomposite structure. The filler dispersion as well as dynamical properties control many material properties and in particular the mechanical response of these materials.In this PhD work, we propose the study of nanocomposites made by dispersion of nano-metric hydrophilic silica particles in a soft hydrophobic polymer matrix of styrene/butadiene (SB), which is commonly used in car tire manufacturing. Since coating agents can react with the filler surface tuning the silica-silica and the silica-polymer interactions, they have been used to promote the compatibility between silica and SB. Firstly, we investigate “simplified industrial nanocomposites” obtained by solid mixing of SB and millimetric silica pellets. By a multiscale approach (microscopy and X-ray scattering, SAXS) we show that: i) the presence of a catalyzer (DPG) unambiguously amplifies the action of the coating agent; ii) the increase of silane content induces the progressive decrease of silica aggregate size. The study of the simplified industrial nanocomposites has been extended to a silica/SB model system. We developed an efficient method to surface-modify colloidal silica NPs in ethanol/water, to stabilize them in the same solvent (MEK) used to dissolve the polymer, and to obtain the final model nanocomposite by solvent casting. For the structural characterization of this multi-step system, we propose a combined SAXS-reverse Monte Carlo approach which allows to investigate the dispersion state of surface-modified silica NPs in precursor solvents (i.e., ethanol/water and MEK) and in the polymer matrix. The filler dispersion is influenced by the characteristics of the grafted silane molecule (varying hydrophobicity, grafting function, and density) and it is shown the quality of the dispersion state is maintained from the precursor suspension to the nanocomposite. Moreover, Broadband Dielectric Spectroscopy (BDS) has been used to investigate the role of silane coating agents in the segmental dynamics of model nanocomposites. We show that the silane molecules can act as plasticizers in pure styrene-butadiene matrices, inducing a significant decrease of the glass transition temperature. We also prove that the chemical surface-modification of the fillers does not affect the segmental dynamics (α-relaxation) in nanocomposites, whereas the presence of “free” silane molecules in the polymer bulk can induce a detectable plasticization effect
Laine, Guy C. "CHARACTERIZATION OF AND CONTROLLING MORPHOLOGY OF ULTRA-THIN NANOCOMPOSITES." UKnowledge, 2013. http://uknowledge.uky.edu/cme_etds/23.
Повний текст джерелаChunder, Anindarupa. "FABRICATION OF FUNCTIONAL NANOSTRUCTURES USING POLYELECTROLYTE NANOCOMPOSITES AND REDUCED GRAPHENE OXIDE ASSEMBLIES." Doctoral diss., University of Central Florida, 2010. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/3082.
Повний текст джерелаPh.D.
Department of Chemistry
Sciences
Chemistry PhD
COLOMBO, ANNALISA. "Synthesis and characterization of TiO2 polymeric nanocomposites with tailorable optical properties." Doctoral thesis, Università degli Studi di Milano-Bicocca, 2012. http://hdl.handle.net/10281/28632.
Повний текст джерелаZhu, Honggang. "Development of epoxy-organoclay nanocomposite as high performance coating and as matrix material of durable GFRP composite for civil engineering applications /." View abstract or full-text, 2009. http://library.ust.hk/cgi/db/thesis.pl?CIVL%202009%20ZHU.
Повний текст джерелаPrandato, Emeline. "Relations structure-propriétés et résistance à l’endommagement de vernis acrylate photo-polymérisables pour substrats thermoplastiques : évaluation de monomères bio-sourcés et de nano-charges." Thesis, Lyon, INSA, 2013. http://www.theses.fr/2013ISAL0103/document.
Повний текст джерелаThe aim of this work was to develop 100% solids photo-polymerizable acrylate coatings, intended to protect thermoplastic pieces made of polycarbonate against mechanical damage, in particular scratches. The relationships between the composition, the structure and the properties of these coatings were examined. For this purpose the morphology, the thermomechanical properties and the scratch resistance of the materials, assessed by micro-scratch tests, were studied. The kinetics of the polymer network formation was also studied by photo-DSC experiments. All the materials feature a high elastic modulus and a broad mechanical relaxation in dynamic thermomechanical analysis. A 100% solids petro-based coating (standard) constituted the starting point of this work. First it was compared to a commercial photo-polymerizable coating containing solvents, specially designed to protect thermoplastic pieces. This commercial coating turned out to be more efficient against scratches. In a second time was studied the influence of the percentage of a multicyclic monomer, taking part in the composition of the standard petro-based coating, on the properties of the latter. The modification of its proportion does not bring any advantage concerning the scratch resistance. Silica, alumina and zirconia nanoparticles, dispersed in an acrylate monomer, were then incorporated in the standard petro-based coating. A particular organization of the silica or alumina nanoparticles in the materials could be observed by transmission electron microscopy. A high filler content is required to observe an increase in the elastic modulus and an enhancement of the scratch resistance of the coating (≥15% by weight for the nano-silica). Moreover, no change of the photo-polymerization kinetics was noticed through the addition of 5% by weight of nano-silica in the coating. Finally, some of the petro-based acrylate compounds of the standard coating were substituted by commercially available bio-based acrylate monomers. Both types of coatings feature similar polymerization kinetics. The conclusions concerning the comparison of the scratch resistance of the bio-based and standard petro-based coatings depend on their thickness. The incorporation of a bio-based monoacrylate compound in low thickness coatings tends to improve the elastic recovery. Isobornyl acrylate is particularly interesting since it also tends to delay the apparition of cracks along the scratch
Swartz, Natasja Alexandria. "Rational Design of Materials for the Protection of Outdoor Metalworks." PDXScholar, 2015. https://pdxscholar.library.pdx.edu/open_access_etds/2488.
Повний текст джерелаLima, Kelly Santana. "Estudo de nanocompósitos poli(metacrilato de hidroxietila) / laponita para revestimento de sementes." Pós-Graduação em Química, 2018. http://ri.ufs.br/jspui/handle/riufs/7941.
Повний текст джерелаThe search for more productive seeds and with better transport and storage conditions has developed the interest of companies and researchers. In this section, nanotechnology, in particular, polymer / clay nanocomposites has proved to be an excellent alternative. By means of these nanomaterials it is possible to transport assets that allow the plant to better growth, productivity and germination rates, through the transport of fertilizers, agrochemicals or even essential micronutrients. The aim of this work was to synthesize and study nanocomposites polymer / clay; poly (hydroxyethyl methacrylate), pure laponite (pHEMA / Lap) and enriched with manganese micronutrients (pHEMA / LapMn). These materials aim to provide water and concomitantly provide nutrients to the seeds. The best formulation for the samples, amounts of polymer and clay was studied, and from this the micronutrient was incorporated into the formulation. The materials were characterized by absorption spectroscopy in the infrared region (FTIR), X-ray diffractometry (XRD) and thermogravimetry (TG). In addition, the water uptake capacity of the samples was evaluated. TG results showed an increase in thermal stability due to the interaction of the polymer chain with the clay. The XRD study showed that pure Lap and Lap Mn presented similar basal spacing to that found in the literature and that the nanocomposite had an exfoliated structure of the materials. The observation of the degree of swelling of the samples showed that the nanocomposites showed a capacity of water absorption 10% higher than the pure hydrogel. The seed coating affected the germination rate of the seeds, showing an optimization of this process.
A busca por sementes mais produtivas e com melhores condições de transporte e armazenamento tem desenvolvido o interesse de empresas e pesquisadores. Nesta vertente, a nanotecnologia, em especial, os nanocompósitos polímero/argila tem se mostrado uma excelente alternativa. Por meio destes nanomateriais é possível transportar ativos que possibilitem a planta melhor crescimento, produtividade e taxas de germinação, por meio do transporte de fertilizantes, agroquímicos ou até micronutrientes essenciais. Neste trabalho buscou-se sintetizar e estudar nanocompósitos polímero/argila; poli(metacrilato de hidroxietila) (pHEMA), laponita pura (pHEMA/Lap) e enriquecida com micronutrientes manganês (pHEMA/LapMn). Estes materiais tem por objetivo fornecer água e concomitantemente fornecer nutrientes para as sementes. Estudou-se qual a melhor formulação para as amostras, quantidades de polímero e de argila e a partir desta incorporou-se o micronutriente a formulação. Os materiais foram caracterizados por espectroscopia de absorção na região do infravermelho (FTIR), difratometria de raios X (DRX) e termogravimetria (TG). Além disso, a capacidade de absorção de água das amostras foi avaliada. Houve aumento da estabilidade térmica decorrente da interação da cadeia polimérica com a argila. O estudo por DRX mostrou que a Lap pura e a Lap Mn apresentaram espaçamento basal similar ao encontrado na literatura e que o nanocompósito apresentou estrutura esfoliada dos materiais. A observação do grau de intumescimento das amostras mostrou que os nanocompósitos apresentaram uma capacidade de absorção de água 10% superior à do hidrogel puro. O revestimento das sementes prejudicou a taxa de germinação das mesmas mostrando-se necessário uma otimização deste processo.
São Cristóvão, SE
Augry, Ludivine. "Contrôle des mécanismes d’interactions nanocharge/polymère en milieu solvant : application aux revêtements à base de PVC et de PAI." Thesis, Lyon, INSA, 2011. http://www.theses.fr/2011ISAL0027.
Повний текст джерелаThis study aims at improving some properties of functional PVC- and PAI- based coatings by adding preformed inorganic lamellar or spherical nanofillers. The compatibilization of nanofiller with the polymer matrix in which they are introduced, is required in order to obtain nanocomposite films with an homogeneous distribution and a dispersion state as fine as possible. Different compatibilization strategies, well-suited for each system, have been studied: compatibilizer physisorption, chemisorption, intercalation or chelation. The new modified nanofillers have been characterized before their introduction into the matrix. Various strategies have been considered to obtain the “compatibilized” nanocomposite films such as the solution mixing and/or the in-situ polymerization, followed by a physical gelation or curing step for PVC- or PAI-based nanocomposites, respectively. The morphological characterization of the films, through XRD and SEM/TEM analysis, and the thermal and thermomecanical properties, evaluated by TGA, DSC and DMA, underlined the importance of two parameters: the nanofiller surface chemistry, responsible for the nanofiller/polymer interfacial interactions, and the elaboration process of the nanocomposite
Martínez, Sanz Marta. "Bacterial cellulose nanowhiskers to enhance the properties of plastics and bioplastics of interest in food packaging." Doctoral thesis, Universitat Politècnica de València, 2013. http://hdl.handle.net/10251/30312.
Повний текст джерелаMartínez Sanz, M. (2013). Bacterial cellulose nanowhiskers to enhance the properties of plastics and bioplastics of interest in food packaging [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/30312
TESIS
Premiado
Shelemin, Artem. "Plasma polymers in the nanostructured and nanocomposite coatings." Doctoral thesis, 2017. http://www.nusl.cz/ntk/nusl-379655.
Повний текст джерелаJagadeshvaran, P. L. "Smart textiles with Tuneable Architectures for Multifunctional Applications." Thesis, 2022. https://etd.iisc.ac.in/handle/2005/6106.
Повний текст джерела