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Автор: Grafiati
Опубліковано: 18 травня 2024

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1

Hussain, Mukhtiar, Muhammad Zaman, Muhammad Hanif, Saqib Ali, and Muhammad Danish. "Synthesis and structural characterization of organotin(IV) complexes formed with [o,o] donor atoms of carboxylic acids." Journal of the Serbian Chemical Society 73, no. 2 (2008): 179–87. http://dx.doi.org/10.2298/jsc0802179h.

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Анотація:
Organotin(IV) carboxylates of the general formula RnSnL4-n (where R = Me, n-Bu or Ph, and L = ?-phenyl-2,3-(methylenedioxy)cinnamate anion or 2-(2,3-dimethlylanilino)nicotinate anion) have been prepared. The mono-, di- and tri-organotin(IV) carboxylates were synthesized by the reaction of organotin(IV) oxides or hydroxides with a stoichiometric amount of the ligand acids at an elevated temperature in dry toluene. The composition of the synthesized organotin(IV) complexes, the bonding behavior of the donor groups and structural assignments were studied by elemental analysis, FT-IR, 1H-, 13C-NMR and mass spectrometry. The spectral data suggest that the ligand acts in a bidentate manner, coordinating through the oxygen atoms. These spectroscopic techniques revealed a distorted tetrahedral geometry in the solution state for the tri-organotins, while a mean coordination number between five to six for the diorganotin(IV) dicarboxylates. In the solid phase, the tri-organotins were essentially trigonal bipyramidal polymeric while the di-organotins were octa?hedral. However, mono-organotin tricarboxylates were predicted to exist in the octahedral state both in solution as well as in the solid phase.
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2

Mazhar, M., M. Aziz Choudhary, Saqib Ali, Qing-Lan Xie, and Xueqing Song. "ChemInform Abstract: Organotin Carboxylates." ChemInform 33, no. 17 (May 22, 2010): no. http://dx.doi.org/10.1002/chin.200217255.

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3

Bonire, Josiah J., G. Adefikayo Ayoko, Philip F. Olurinola, Joseph O. Ehinmidu, Neelam S. N. Jalil, and Andrew A. Omachi. "Synthesis and Antifungal Activity of Some Organotin(IV) Carboxylates." Metal-Based Drugs 5, no. 4 (January 1, 1998): 233–36. http://dx.doi.org/10.1155/mbd.1998.233.

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Six diorganotin(IV) carboxylates prepared by reacting diorganotin(IV) dichlorides with the respective silver carboxylate have been tested for antifungal activity against Aspergillus. niger, Aspergilluus flavus and Pencillium. citrinum in Sabourand dextrose broth. The compounds generally exhibit greater fungitoxicity than the diorganotin(IV) dichlorides and the carboxylic acids from which they were synthesized. In keeping with the generally accepted notion that the organotin moiety plays an important role in deciding the antifungal activity of an organotin compound, the diphenyltin(IV) compounds were more active than their di-n-butyltin(IV) analogues. However, the order of increasing fungitoxicity of the compounds parallels that of the uncomplexed carboxylic acids. The implications of the results are discussed.
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4

Sandhu, Gurmit K., Neelam Sharma, and Edward R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 371, no. 1 (July 1989): C1—C3. http://dx.doi.org/10.1016/0022-328x(89)85215-5.

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5

Parulekar, C. S., V. K. Jain, T. K. Das, A. R. Gupta, B. F. Hoskins, and E. R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 372, no. 2 (August 1989): 193–99. http://dx.doi.org/10.1016/0022-328x(89)87093-7.

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6

Sandhu, G. K., S. P. Verma, and E. R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 393, no. 2 (August 1990): 195–200. http://dx.doi.org/10.1016/0022-328x(90)80198-9.

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7

Vatsa, Charu, Vimal K. Jain, T. Kesavadas, and Edward R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 410, no. 2 (June 1991): 135–42. http://dx.doi.org/10.1016/0022-328x(91)80002-2.

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8

Ng, Seik Weng, V. G. Kumar Das, and Edward R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 403, no. 1-2 (February 1991): 111–17. http://dx.doi.org/10.1016/0022-328x(91)83092-i.

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9

Sandhu, Gurmit K., Neelam Sharma, and Edward R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 403, no. 1-2 (February 1991): 119–31. http://dx.doi.org/10.1016/0022-328x(91)83093-j.

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10

Tiekink, Edward R. T. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 408, no. 3 (May 1991): 323–27. http://dx.doi.org/10.1016/0022-328x(91)83203-g.

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11

Ng, Seik Weng, V. G. Kumar Das, and Edward R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 411, no. 1-2 (July 1991): 121–29. http://dx.doi.org/10.1016/0022-328x(91)86011-e.

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12

Sandhu, Gurmit K., Rajbir Hundal, and Edward R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 412, no. 1-2 (July 1991): 31–38. http://dx.doi.org/10.1016/0022-328x(91)86038-r.

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13

Vatsa, Charu, Vimal K. Jain, T. Kesavadas, and Edward R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 408, no. 2 (May 1991): 157–66. http://dx.doi.org/10.1016/0022-328x(91)86379-5.

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14

Vasta, C., V. K. Jain, T. K. Das, and Edward R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 421, no. 1 (December 1991): 21–28. http://dx.doi.org/10.1016/0022-328x(91)86428-s.

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15

Sandhu, Gurmit K., Rajbir Hundal, and Edward R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 430, no. 1 (June 1992): 15–23. http://dx.doi.org/10.1016/0022-328x(92)80091-b.

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16

Mokal, V. B., Vimal K. Jain, and Edward R. T. Tiekink. "Structural chemistry of organotin carboxylates." Journal of Organometallic Chemistry 431, no. 3 (July 1992): 283–88. http://dx.doi.org/10.1016/0022-328x(92)83332-c.

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17

Amir, Muhammad Kashif, Shahanzeb Khan, Zia-ur-Rehman, Afzal Shah, and Ian S. Butler. "Anticancer activity of organotin(IV) carboxylates." Inorganica Chimica Acta 423 (November 2014): 14–25. http://dx.doi.org/10.1016/j.ica.2014.07.053.

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18

Devendra, Ransi, Neil R. Edmonds, and Tilo Söhnel. "Organotin carboxylate catalyst in urethane formation in a polar solvent: an experimental and computational study." RSC Advances 5, no. 60 (2015): 48935–45. http://dx.doi.org/10.1039/c5ra03367e.

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19

Xiao, Xiao, Wenliang Li, Chengwu Liang, and Wenxiu Zhao. "Organotin carboxylates: from structures to antitumour activities." European Journal of BioMedical Research 1, no. 4 (December 28, 2015): 23. http://dx.doi.org/10.18088/ejbmr.1.4.2015.pp23-27.

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20

Hussain, Shabbir, Saqib Ali, Saira Shahzadi, Saroj K. Sharma, Kushal Qanungo, and Muhammad Shahid. "Synthesis, Characterization, Semiempirical and Biological Activities of Organotin(IV) Carboxylates with 4-Piperidinecarboxylic Acid." Bioinorganic Chemistry and Applications 2014 (2014): 1–11. http://dx.doi.org/10.1155/2014/959203.

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Анотація:
Organotin (IV) carboxylates with the general formulae R2Sn(Cl)L [R = Me (1),n-Bu (2), Ph (3)] and R3SnL [R = Me (4), Ph (5)] have been synthesized by the reaction of 4-piperidinecarboxylic acid (HL) with KOH and R2SnCl2(R = Me,n-Bu, Ph)/R3SnCl (R = Me, Ph) in methanol under stirring conditions. The metal ligand binding site, structure, and stability of complexes have been verified by FT-IR, (1H,13C) NMR, EI-MS technique, and semiempirical study. The FT-IR data indicate the bidentate chelating mode of the carboxylate ligand which is also confirmed by semiempirical study. In solution state, five and four coordinated geometry around tin was confirmed by NMR spectroscopy. The EI-MS data agreed well with the molecular structure of the complexes. Thermodynamic parameters and molecular descriptors were calculated by using semiempirical PM3 method. HOMO-LUMO calculations show that chlorodiorganotin complexes are more susceptible to nucleophilic attack as compared to triorganotin complexes. Computed negative heat of formation indicates that complexes1–4are thermodynamically stable. The organotin(IV) carboxylates displayed powerful antimicrobial activities against various strains of bacteria and fungi and their minimal inhibitory concentration were also evaluated. The complexes exhibited comparatively higher hemolytic activity as compared to free ligand.
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21

Petrosyan, V. S., N. S. Yashina, S. V. Ponomarev, A. S. Zolotareva, S. N. Nikolaeva, and Τ. V. Drovetskaia. "THE COMPARATIVE STUDIES OF ORGANOTIN AND ORGANOGERMANIUM CARBOXYLATES." Main Group Metal Chemistry 19, no. 6 (January 1996): 397–408. http://dx.doi.org/10.1515/mgmc.1996.19.6.397.

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22

Predarska, Ivana, Mohamad Saoud, Ibrahim Morgan, Peter Lönnecke, Goran N. Kaluđerović, and Evamarie Hey-Hawkins. "Triphenyltin(IV) Carboxylates with Exceptionally High Cytotoxicity against Different Breast Cancer Cell Lines." Biomolecules 13, no. 4 (March 26, 2023): 595. http://dx.doi.org/10.3390/biom13040595.

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Анотація:
Organotin(IV) carboxylates are a class of compounds explored as alternatives to platinum-containing chemotherapeutics due to propitious in vitro and in vivo results, and distinct mechanisms of action. In this study, triphenyltin(IV) derivatives of non-steroidal anti-inflammatory drugs (indomethacin (HIND) and flurbiprofen (HFBP)) are synthesized and characterized, namely [Ph3Sn(IND)] and [Ph3Sn(FBP)]. The crystal structure of [Ph3Sn(IND)] reveals penta-coordination of the central tin atom with almost perfect trigonal bipyramidal geometry with phenyl groups in the equatorial positions and two axially located oxygen atoms belonging to two distinct carboxylato (IND) ligands leading to formation of a coordination polymer with bridging carboxylato ligands. Employing MTT and CV probes, the antiproliferative effects of both organotin(IV) complexes, indomethacin, and flurbiprofen were evaluated on different breast carcinoma cells (BT-474, MDA-MB-468, MCF-7 and HCC1937). [Ph3Sn(IND)] and [Ph3Sn(FBP)], unlike the inactive ligand precursors, were found extremely active towards all examined cell lines, demonstrating IC50 concentrations in the range of 0.076–0.200 µM. Flow cytometry was employed to examine the mode of action showing that neither apoptotic nor autophagic mechanisms were triggered within the first 48 h of treatment. However, both tin(IV) complexes inhibited cell proliferation potentially related to the dramatic reduction in NO production, resulting from downregulation of nitric oxide synthase (iNOS) enzyme expression.
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23

Abbas, Syed Mustansar, Saqib Ali, Syed Tajammul Hussain, and Saira Shahzadi. "Review: structural diversity in organotin(IV) dithiocarboxylates and carboxylates." Journal of Coordination Chemistry 66, no. 13 (June 11, 2013): 2217–34. http://dx.doi.org/10.1080/00958972.2013.802310.

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24

G. Hadi, Angham, Khudheir Jawad, Dina S. Ahmed, and Emad Yousif. "Synthesis and Biological Activities of Organotin (IV) Carboxylates: A Review." Systematic Reviews in Pharmacy 10, no. 1 (December 14, 2018): 26–31. http://dx.doi.org/10.5530/srp.2019.1.5.

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25

Molloy, Kieran C. "Solid state 119Sn NMR study of organotin carboxylates and thiophosphates." Inorganica Chimica Acta 141, no. 2 (January 1988): 151–52. http://dx.doi.org/10.1016/s0020-1693(00)83897-9.

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26

Del Re, Ryan, James Passarelli, Miriam Sortland, Brian Cardineau, Yasin Ekinci, Elizabeth Buitrago, Mark Neisser, Daniel A. Freedman, and Robert L. Brainard. "Low-line edge roughness extreme ultraviolet photoresists of organotin carboxylates." Journal of Micro/Nanolithography, MEMS, and MOEMS 14, no. 4 (November 9, 2015): 043506. http://dx.doi.org/10.1117/1.jmm.14.4.043506.

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27

Liu, Dong, Wen-Can Chen, Guo-Li Shen, and Ru-Qin Yu. "Polymeric membrane salicylate-sensitive electrodes based on organotin(IV) carboxylates." Analyst 121, no. 10 (1996): 1495. http://dx.doi.org/10.1039/an9962101495.

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28

PETROSYAN, V. S., N. S. YASHINA, S. V. PONOMAREV, A. S. ZOLOTAREVA, S. N. NIKOLAEVA, and T. V. DROVETSKAIA. "ChemInform Abstract: The Comparative Studies of Organotin and Organogermanium Carboxylates." ChemInform 27, no. 50 (August 4, 2010): no. http://dx.doi.org/10.1002/chin.199650253.

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29

Levent, Emre, Oliver Sala, Lukas F. B. Wilm, Pawel Löwe, and Fabian Dielmann. "Heterobimetallic complexes composed of bismuth and lithium carboxylates as polyurethane catalysts – alternatives to organotin compounds." Green Chemistry 23, no. 7 (2021): 2747–55. http://dx.doi.org/10.1039/d1gc00446h.

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30

Vinayak, Richa, and Hari Pada Nayek. "Selective sensing of a Cu(ii) ion by organotin anchored keto-enamine ligands." New Journal of Chemistry 43, no. 40 (2019): 16050–57. http://dx.doi.org/10.1039/c9nj03204e.

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Анотація:
New organotin carboxylates [{(n-Bu)2Sn(HL)}2O]2 (1), [(t-Bu)2Sn(HL)2] (2) and [Ph3Sn(HL)] (3) have been synthesized and used for sensing of Cu(ii) ion. Complex 3 shows highest binding constant and better limit of detection than other complexes.
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31

Vinayak, Richa, and Hari Pada Nayek. "Organotin metalloligands for selective sensing of metal ions." New Journal of Chemistry 43, no. 19 (2019): 7259–68. http://dx.doi.org/10.1039/c9nj00944b.

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Four new organotin carboxylates, [(t-C4H9)2Sn(L1)2] (1), [(t-C4H9)2Sn(L2)2] (2), [{(n-C4H9)2Sn(L1)}2O]2 (3) and [{(n-C4H9)2Sn(L2)}2O]2 (4), are reported. All complexes selectively recognize Cu(ii) and Fe(iii) ions in solution. Complex 1 was found to be the best one for sensing those ions among all complexes.
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32

Salma, U., Imtiaz-ud-Din, M. Mazhar, and Khalid Mohammed Khan. "Germatranyl Substituted Organotin (IV) Carboxylates: Synthesis Spectroscopic Characterization and Biological Activities." Medicinal Chemistry 5, no. 6 (November 1, 2009): 543–48. http://dx.doi.org/10.2174/157340609790170489.

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33

Iqbal, Muhammad, Saqib Ali, Niaz Muhammad, Masood Parvez, Peter Langer, and Alexander Villinger. "Synthesis, characterization, crystal structures and electrochemical studies of organotin(IV) carboxylates." Journal of Organometallic Chemistry 723 (January 2013): 214–23. http://dx.doi.org/10.1016/j.jorganchem.2012.10.006.

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34

Danish, M., N. Ahmad, N. Zahara, S. Ali, and N. Muhammad. "Thermokinetic studies of organotin(IV) carboxylates derived from para-methoxyphenylethanoic acid." Journal of the Iranian Chemical Society 7, no. 4 (December 2010): 846–52. http://dx.doi.org/10.1007/bf03246078.

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35

Xiao, Xiao, Lisong Yan, Zemin Mei, Dongsheng Zhu, and Lin Xu. "Two novel macrocyclic organotin(iv) carboxylates based on amide carboxylic acids." RSC Adv. 4, no. 6 (2014): 3096–101. http://dx.doi.org/10.1039/c3ra46198j.

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36

Sakho, Adama Moussa, Dafeng Du, Wenjie Li, Shuangshuang Liu, Dongsheng Zhu, and Lin Xu. "Synthesis, crystal structures, and antitumor activity of three new organotin carboxylates." Heteroatom Chemistry 21, no. 5 (June 22, 2010): 304–13. http://dx.doi.org/10.1002/hc.20614.

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37

Abbas, Syed Mustansar, Saqib Ali, Syed Tajammul Hussain, and Saira Shahzadi. "ChemInform Abstract: Review: Structural Diversity in Organotin(IV) Dithiocarboxylates and Carboxylates." ChemInform 44, no. 49 (November 14, 2013): no. http://dx.doi.org/10.1002/chin.201349225.

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38

Tiekink, Edward R. T. "Structural chemistry of organotin carboxylates: a review of the crystallographic literature." Applied Organometallic Chemistry 5, no. 1 (January 1991): 1–23. http://dx.doi.org/10.1002/aoc.590050102.

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39

Wang, Zhi-Hong, Yan-Zhao Guo, Jun Zhang, Lin Ma, Hai-Bin Song, and Zhi-Jin Fan. "Synthesis and Biological Activity of Organotin 4-Methyl-1,2,3-thiadiazole-5-carboxylates and Benzo[1,2,3]thiadiazole-7-carboxylates†." Journal of Agricultural and Food Chemistry 58, no. 5 (March 10, 2010): 2715–19. http://dx.doi.org/10.1021/jf902168d.

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40

Ahmet, Mustafa T., Andrew Houlton, Christopher S. Frampton, John R. Miller, Roger M. G. Roberts, Jack Silver, and Bahram Yavari. "Tin-119 Mössbauer and nuclear magnetic resonance studies of organotin compounds. Part 2. Sterically crowded organotin halides and carboxylates." J. Chem. Soc., Dalton Trans., no. 20 (1993): 3085–92. http://dx.doi.org/10.1039/dt9930003085.

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41

AHMET, M. T., A. HOULTON, C. S. FRAMPTON, J. R. MILLER, R. M. G. ROBERTS, J. SILVER, and B. YAVARI. "ChemInform Abstract: Tin-119 Moessbauer and NMR Studies of Organotin Compounds. Part 2. Sterically Crowded Organotin Halides and Carboxylates." ChemInform 25, no. 5 (August 19, 2010): no. http://dx.doi.org/10.1002/chin.199405030.

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42

Zhang, Yuan-Yuan, Ru-Fen Zhang, Shao-Liang Zhang, Shuang Cheng, Qian-Li Li, and Chun-Lin Ma. "Syntheses, structures and anti-tumor activity of four new organotin(iv) carboxylates based on 2-thienylselenoacetic acid." Dalton Transactions 45, no. 20 (2016): 8412–21. http://dx.doi.org/10.1039/c6dt00532b.

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Анотація:
With the 2-thienylselenoacetic acid ligand, four new organotin complexes have been synthesized and characterized by X-ray crystallography, elemental analysis, FT-IR and NMR (1H,13C, and119Sn) spectroscopy.
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43

Geng, Wen-Qian, Hong-Ping Zhou, Long-Huai Cheng, Fu-Ying Hao, Guo-Yi Xu, Fei-Xia Zhou, Zhi-Peng Yu, et al. "Synthesis and structural characterization of organotin(IV) carboxylates based on different heterocyclic substituents." Polyhedron 31, no. 1 (January 2012): 738–47. http://dx.doi.org/10.1016/j.poly.2011.10.032.

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44

Xiao, Xiao, Dafeng Du, Min Tian, Xiao Han, Jingwen Liang, Dongsheng Zhu, and Lin Xu. "Organotin(IV) carboxylates based on benzenedicarboxylic acid derivatives: Syntheses, crystal structures and characterizations." Journal of Organometallic Chemistry 715 (September 2012): 54–63. http://dx.doi.org/10.1016/j.jorganchem.2012.05.038.

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45

Xiao, Xiao, Xiao Han, Zemin Mei, Dongsheng Zhu, Kuizhan Shao, Jingwen Liang, Min Tian, and Lin Xu. "Organotin(IV) carboxylates based on amide carboxylic acids: Syntheses, crystal structures and characterizations." Journal of Organometallic Chemistry 729 (April 2013): 28–39. http://dx.doi.org/10.1016/j.jorganchem.2013.01.017.

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46

TIEKNIK, E. R. T. "ChemInform Abstract: Structural Chemistry of Organotin Carboxylates: A Review of the Crystallographic Literature." ChemInform 23, no. 21 (August 22, 2010): no. http://dx.doi.org/10.1002/chin.199221322.

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