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Автор: Grafiati
Опубліковано: 14 березня 2023

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1

Dalton, L. R. "Organic electro-optic materials." Pure and Applied Chemistry 76, no. 7-8 (January 1, 2004): 1421–33. http://dx.doi.org/10.1351/pac200476071421.

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Анотація:
The macroscopic electrooptic activity of organic materials depends upon the molecular hyperpolarizability, beta, of individual organic chromophores and upon the product of number density, N, and noncentrosymmetric order, <cos3theta>, of the chromophores in a hardened polymer lattice. Quantum and statistical mechanical calculations provide the basis for rational improvement of these parameters leading to electro-optic coefficients (at telecommunication wavelengths) of greater than 100 pm/V (a factor of 3 larger than values for the best inorganic material, lithium niobate). Such calculations also provide insight into what further improvements can be expected. Owing to low and relatively dispersionless dielectric constants and refractive indicies, organic materials facilitate the fabrication of devices with 3 dB operational bandwidths of greater than 100 GHz. Moreover, robust and low optical loss materials can be fabricated by design. An under-appreciated advantage of organic electro-optic materials is their processability, and a variety of stripline, cascaded prism and super-prism, and ring microresonator devices are readily fabricated. Conformal, flexible, and three-dimensional devices are also readily produced. With ring microresonator devices, active wavelength division multiplexing, optical network reconfiguration, and laser frequency tuning are straightforwardly accomplished.
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2

Kim, Tae-Dong, Kwang-Sup Lee, So Young Lee, Young Joe Kim, and Jae Won Song. "Organic-Inorganic Hybrid Material for Electro-Optic Modulator." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 371, no. 1 (October 2001): 337–40. http://dx.doi.org/10.1080/10587250108024755.

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3

Jin, Wenwei, Peter V. Johnston, Delwin L. Elder, Karl T. Manner, Kerry E. Garrett, Werner Kaminsky, Ruimin Xu, Bruce H. Robinson, and Larry R. Dalton. "Structure–function relationship exploration for enhanced thermal stability and electro-optic activity in monolithic organic NLO chromophores." Journal of Materials Chemistry C 4, no. 15 (2016): 3119–24. http://dx.doi.org/10.1039/c6tc00358c.

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Анотація:
Structure–function relationship study in a series of organic monolithic electro-optic materials has revealed the impact of donor and bridge molecular modification, leading to material with increased EO behavior and improved thermal stability.
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4

Jie, Sun, Zhu Gui-Hua, Sun Xiao-Qiang, Li Tong, Gao Wei-Nan, Zhang Da-Ming, and Hou A-Lin. "High Cost Performance Organic–Inorganic Hybrid Material for Electro-optic Devices." Chinese Physics Letters 26, no. 2 (February 2009): 024206. http://dx.doi.org/10.1088/0256-307x/26/2/024206.

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5

Liu, Fenggang, Ziying Zeng, Abdul Rahman, Xunyu Chen, Zhiwei Liang, Xiaoqing Huang, Shumin Zhang, Huajun Xu, and Jiahai Wang. "Design and synthesis of organic optical nonlinear multichromophore dendrimers based on double-donor structures." Materials Chemistry Frontiers 5, no. 24 (2021): 8341–51. http://dx.doi.org/10.1039/d1qm01337h.

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6

Mohammad, Syuhaimi Ab Rahman, Mohamed Shaktur Khaled, and Mohammad Rahmah. "Organic Polymer Integrated Optics: Recently Design and Simulation of an Electro-Optic 2x3 Switch." Advanced Materials Research 230-232 (May 2011): 80–84. http://dx.doi.org/10.4028/www.scientific.net/amr.230-232.80.

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Анотація:
Electrooptic waveguide technology is suitable for realization of an electro-optic 2x3 switch based on integrated Mach-Zehnder interferometer using polymer material, where ESO of polymeric materials were used. It can provide high performances and it is applicable for all optical switching networks. The relatively low cost technology, easy fabrication process with standard optoelectronic fabrication process and with high degree of integration compared to other technologies make the development of optical switch based on this technology favorable one.
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7

ZHANG Feng, 张峰, 李晓东 LI Xiao-dong, 谭震宇 TAN Zhen-yu, 李涛 LI Tao, 陈长鸣 CHEN Chang-ming, and 张大明 ZHANG Da-ming. "Strip-loaded Waveguide Electro-optic Modulator Based on Bonded Organic-inorganic Hybrid Material." ACTA PHOTONICA SINICA 40, no. 4 (2011): 569–72. http://dx.doi.org/10.3788/gzxb20114004.0569.

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8

Meredith, Gerald R. "Organic Materials for Nonlinear Optics." MRS Bulletin 13, no. 8 (August 1988): 24–29. http://dx.doi.org/10.1557/s0883769400064642.

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Анотація:
were very exciting but speculative, being technologically feasible only if new classes of materials could be developed The subject of materials in nonlinear optics (NLO) encompasses a wide range of important topics. Today the line between materials and NLO processes has become fuzzy, particularly for newer NLO processes (e.g. photorefrac-tion, and optical bistability, logic and computing). For more established NLO processes (e.g., harmonic generation, parametric processes, linear electro-optic effect, etc.) the subjects are well studied and the importance of various materials properties on the NLO process are known, though these properties are not necessarily predictable, controllable, or optimized in current materials.A decade ago, having been introduced to NLO phenomena through postdoctoral research, I had an opportunity to define and pursue an NLO research program at Xerox's Webster Research Center. The question was posed: “Are new materials needed for NLO applications?” The answer must start with another question: “Which NLO process … with light of what wavelength, pulse duration, and power… and for what purpose?”It was clear that important limitations to many of the novel things one might do with optics were: insufficient nonlin-earity magnitude, inability to fabricate reliable device structures, occurrence of deleterious optical properties, and restrictions due to other material properties. The newer NLO phenomena. Use of older NLO processes in new technological applications seemed a more down-to-earth quest.
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9

Shimoga, Ganesh, and Sang-Youn Kim. "High-k Polymer Nanocomposite Materials for Technological Applications." Applied Sciences 10, no. 12 (June 20, 2020): 4249. http://dx.doi.org/10.3390/app10124249.

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Understanding the properties of small molecules or monomers is decidedly important. The efforts of synthetic chemists and material engineers must be appreciated because of their knowledge of how utilize the properties of synthetic fragments in constructing long-chain macromolecules. Scientists active in this area of macromolecular science have shared their knowledge of catalysts, monomers and a variety of designed nanoparticles in synthetic techniques that create all sorts of nanocomposite polymer stuffs. Such materials are now an integral part of the contemporary world. Polymer nanocomposites with high dielectric constant (high-k) properties are widely applicable in the technological sectors including gate dielectrics, actuators, infrared detectors, tunable capacitors, electro optic devices, organic field-effect transistors (OFETs), and sensors. In this short colloquy, we provided an overview of a few remarkable high-k polymer nanocomposites of material science interest from recent decades.
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10

Palmer, Robert, Wolfgang Freude, Juerg Leuthold, Christian Koos, Sebastian Koeber, Delwin L. Elder, Markus Woessner, et al. "High-Speed, Low Drive-Voltage Silicon-Organic Hybrid Modulator Based on a Binary-Chromophore Electro-Optic Material." Journal of Lightwave Technology 32, no. 16 (August 15, 2014): 2726–34. http://dx.doi.org/10.1109/jlt.2014.2321498.

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11

Wang, Long-De, Jie Tang, Ruo-Zhou Li, Tong Zhang, Ling Tong, Jing Tang, and Li Xu. "Synthesis and characterization of electro-optic polyurethane-imide and fabrication of optical waveguide device." High Performance Polymers 29, no. 8 (August 19, 2016): 879–88. http://dx.doi.org/10.1177/0954008316663611.

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Анотація:
The novel electro-optic (EO) polymers of fluorinated cross-linkable Y-type polyurethane-imides (PUI) were designed and synthesized by polycondensation of second-order non-linear optical azo-based chromophores, phenyl diisocyanate, and aromatic dianhydride. Molecular structural characterization for the resulting polymers was achieved by proton nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, elemental analysis, and gel permeation chromatography. The resulting polymers exhibited good film-forming properties, high glass transition temperature in the range from 186°C to 198°C and thermal stability up to 300°C, high EO coefficient ( γ33 = 43–60 pm/V) at 1550 nm wavelength, good stabilization of electrically induced chromophore dipole alignment and low optical propagation losses in the range of 1.5–1.7 dB/cm at 1550 nm, which are suitable for the EO modulators. Using the synthesized EO PUI as the active core material and of a fluorinated polyimide as cladding material, we have designed and fabricated the high-performance polymer waveguide Mach-Zehnder EO modulators. Obvious modulation was observed by application of ac voltage signal to the EO modulators.
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12

Gupta, Deepak, Przemyslaw Kula, and Ayon Bhattacharjee. "Mesomorphic, electro-optic and dielectric behaviour of a semi-fluorinated chiral liquid crystalline material forming polar smectic phases." Journal of Molecular Structure 1219 (November 2020): 128557. http://dx.doi.org/10.1016/j.molstruc.2020.128557.

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13

Wang, Yan, Tongtong Liu, Jiangyi Liu, Chuanbo Li, Zhuo Chen, and Shuhui Bo. "Organic electro-optic polymer materials and organic-based hybrid electro-optic modulators." Journal of Semiconductors 43, no. 10 (October 1, 2022): 101301. http://dx.doi.org/10.1088/1674-4926/43/10/101301.

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Анотація:
Abstract High performance electro-optic modulator, as the key device of integrated ultra-wideband optical systems, have become the focus of research. Meanwhile, the organic-based hybrid electro-optic modulators, which make full use of the advantages of organic electro-optic (OEO) materials (e.g. high electro-optic coefficient, fast response speed, high bandwidth, easy processing/integration and low cost) have attracted considerable attention. In this paper, we introduce a series of high-performance OEO materials that exhibit good properties in electro-optic activity and thermal stability. In addition, the recent progress of organic-based hybrid electro-optic devices is reviewed, including photonic crystal-organic hybrid (PCOH), silicon-organic hybrid (SOH) and plasmonic-organic hybrid (POH) modulators. A high-performance integrated optical platform based on OEO materials is a promising solution for growing high speeds and low power consumption in compact sizes.
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14

Xu, Huajun, Lewis E. Johnson, Yovan de Coene, Delwin L. Elder, Scott R. Hammond, Koen Clays, Larry R. Dalton, and Bruce H. Robinson. "Bis(4-dialkylaminophenyl)heteroarylamino donor chromophores exhibiting exceptional hyperpolarizabilities." Journal of Materials Chemistry C 9, no. 8 (2021): 2721–28. http://dx.doi.org/10.1039/d0tc05700b.

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15

Zhang, Maolin, Huajun Xu, Mingkai Fu, Min Yang, Bing He, Xiaoling Zhang, Zhonghui Li, Guowei Deng, Shuhui Bo, and Jialei Liu. "Optimizing the molecular structure of 1,1,7,7-tetramethyl julolidine fused furan based chromophores by introducing a heterocycle ring to achieve high electro-optic activity." New Journal of Chemistry 43, no. 39 (2019): 15548–54. http://dx.doi.org/10.1039/c9nj02309g.

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16

Dalton, L. R. "Rational design of organic electro-optic materials." Journal of Physics: Condensed Matter 15, no. 20 (May 9, 2003): R897—R934. http://dx.doi.org/10.1088/0953-8984/15/20/203.

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17

Thapliya, Roshan, Shigetoshi Nakamura, and Takashi Kikuchi. "Electro-optic multimode interference device using organic materials." Applied Optics 45, no. 21 (July 20, 2006): 5404. http://dx.doi.org/10.1364/ao.45.005404.

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18

Dalton, Larry R. "Theory-inspired development of organic electro-optic materials." Thin Solid Films 518, no. 2 (November 2009): 428–31. http://dx.doi.org/10.1016/j.tsf.2009.07.001.

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19

Sullivan, Philip A., and Larry R. Dalton. "Theory-Inspired Development of Organic Electro-optic Materials." Accounts of Chemical Research 43, no. 1 (January 19, 2010): 10–18. http://dx.doi.org/10.1021/ar800264w.

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20

Wu, Jieyun, Hongyan Xiao, Ling Qiu, Zhen Zhen, Xinhou Liu, and Shuhui Bo. "Comparison of nonlinear optical chromophores containing different conjugated electron-bridges: the relationship between molecular structure-properties and macroscopic electro-optic activities of materials." RSC Adv. 4, no. 91 (2014): 49737–44. http://dx.doi.org/10.1039/c4ra09368b.

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Анотація:
In electro-optic (EO) materials, realization of large EO coefficients for organic EO materials requires the simultaneous optimization of chromophore first hyperpolarizability, acentric order, molecular shape etc.
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21

Li, Ming, Su Huang, Xing-Hua Zhou, Yue Zang, Jieyun Wu, Zhanchen Cui, Jingdong Luo, and Alex K. Y. Jen. "Poling efficiency enhancement of tethered binary nonlinear optical chromophores for achieving an ultrahigh n3r33 figure-of-merit of 2601 pm V−1." Journal of Materials Chemistry C 3, no. 26 (2015): 6737–44. http://dx.doi.org/10.1039/c5tc01049g.

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22

Wu, Jieyun, Jingdong Luo, Nathan Cernetic, Kaixin Chen, Kin-Seng Chiang, and Alex K. Y. Jen. "PCBM-doped electro-optic materials: investigation of dielectric, optical and electro-optic properties for highly efficient poling." Journal of Materials Chemistry C 4, no. 43 (2016): 10286–92. http://dx.doi.org/10.1039/c6tc03932d.

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23

Dalton, Larry R., William H. Steier, Bruce H. Robinson, Chang Zhang, Albert Ren, Sean Garner, Antao Chen, et al. "From molecules to opto-chips: organic electro-optic materials." Journal of Materials Chemistry 9, no. 9 (1999): 1905–20. http://dx.doi.org/10.1039/a902659b.

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24

Firestone, Kimberly A., Philip Reid, Rhys Lawson, Sei-Hum Jang, and Larry R. Dalton. "RETRACTED: Advances in organic electro-optic materials and processing." Inorganica Chimica Acta 357, no. 13 (November 2004): 3957–66. http://dx.doi.org/10.1016/j.ica.2004.07.031.

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25

Apitz, D., C. Svanberg, K. G. Jespersen, T. G. Pedersen, and P. M. Johansen. "Orientational dynamics in dye-doped organic electro-optic materials." Journal of Applied Physics 94, no. 10 (November 15, 2003): 6263–68. http://dx.doi.org/10.1063/1.1621725.

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26

Dalton, Larry R., Stephanie J. Benight, Lewis E. Johnson, Daniel B. Knorr, Ilya Kosilkin, Bruce E. Eichinger, Bruce H. Robinson, Alex K. Y. Jen, and René M. Overney. "Systematic Nanoengineering of Soft Matter Organic Electro-optic Materials†." Chemistry of Materials 23, no. 3 (February 8, 2011): 430–45. http://dx.doi.org/10.1021/cm102166j.

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27

Dalton, Larry, and Stephanie Benight. "Theory-Guided Design of Organic Electro-Optic Materials and Devices." Polymers 3, no. 3 (August 19, 2011): 1325–51. http://dx.doi.org/10.3390/polym3031325.

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28

Shi, Shouyuan, and Dennis W. Prather. "Ultrabroadband Electro-Optic Modulator Based on Hybrid Silicon-Polymer Dual Vertical Slot Waveguide." Advances in OptoElectronics 2011 (September 1, 2011): 1–6. http://dx.doi.org/10.1155/2011/714895.

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Анотація:
We present a novel hybrid silicon-polymer dual slot waveguide for high speed and ultra-low driving voltage electro-optic (EO) modulation. The proposed design utilizes the unique properties of ferroelectric materials such as LiNbO3 to achieve dual RF and optical modes within a low index nanoslot. The tight mode concentration and overlap in the slot allow the infiltrated organic EO polymers to experience enhanced nonlinear interaction with the applied electric field. Half-wavelength voltage-length product and electro-optic response are rigorously simulated to characterize the proposed design, which reveals ultrabroadband operation, up to 250 GHz, and subvolt driving voltage for a 1 cm long modulator.
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29

Kim, Se-In, Bong Joo Kang, Chan-Uk Jeong, Myeong-Hoon Shin, Won Tae Kim, Mojca Jazbinsek, Woojin Yoon, et al. "Electro-Optic Crystals: Fluorinated Organic Electro-Optic Quinolinium Crystals for THz Wave Generation (Advanced Optical Materials 4/2019)." Advanced Optical Materials 7, no. 4 (February 2019): 1970013. http://dx.doi.org/10.1002/adom.201970013.

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30

Zhang, Hui, Yanxin Tian, Shuhui Bo, Linghan Xiao, Yuhui Ao, Ji Zhang, and Ming Li. "A study on regulating the conjugate position of NLO chromophores for reducing the dipole moment and enhancing the electro-optic activities of organic materials." Journal of Materials Chemistry C 8, no. 4 (2020): 1380–90. http://dx.doi.org/10.1039/c9tc05704h.

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31

Sherwood, John N. "The growth, perfection and structural properties of organic electro-optic materials." Pure and Applied Optics: Journal of the European Optical Society Part A 7, no. 2 (March 1998): 229–38. http://dx.doi.org/10.1088/0963-9659/7/2/013.

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32

Benight, Stephanie J., Lewis E. Johnson, Robin Barnes, Benjamin C. Olbricht, Denise H. Bale, Philip J. Reid, Bruce E. Eichinger, Larry R. Dalton, Philip A. Sullivan, and Bruce H. Robinson. "Reduced Dimensionality in Organic Electro-Optic Materials: Theory and Defined Order." Journal of Physical Chemistry B 114, no. 37 (September 23, 2010): 11949–56. http://dx.doi.org/10.1021/jp1022423.

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33

Williams, GRJ. "Nonlinear Susceptabilities of Conjugated Organic Systems: Fused-ring Oligomers." Australian Journal of Physics 44, no. 3 (1991): 299. http://dx.doi.org/10.1071/ph910299.

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Анотація:
The finite-field modified neglect of diatomic overlap (MNDO) molecular orbital technique has been used to calculate the second hyperpolarisability (the molel:ular counterpart to the macroscopic nonlinear susceptability tensor X3) for selected fused-ring oligomers. The fusedring segments are the active electro-optic units in ladder polymers and rigid-rod/flexible-chain copolymers that are under current investigation as polymeric materials with applications in ultrafast optoelectronic devices.
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34

Gao, Wu, Jialei Liu, and Iwan V. Kityk. "The Progress in the Field Auxiliary Donors and their Application in Novel Organic Second-Order Nonlinear Optical Chromophores." Mini-Reviews in Organic Chemistry 16, no. 3 (January 25, 2019): 228–35. http://dx.doi.org/10.2174/1570193x15666180627150155.

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Анотація:
Conversion efficiency between electrical and optical signals is very important for the development of modern information technologies. Due to their advantages in half-wave voltage, bandwidth, cost and integration, as well as organic electro-optic (EO) parameters, these materials are widely studied and used in microwave photonic devices. Second order nonlinear optical (NLO) chromophores, as the core of organic EO materials have an increasing interest in this branch. Auxiliary donors present a new direction for the design and improvement of organic NLO chromophores. In this short review, the advantages, theoretical calculations and experimental results of auxiliary donors are reviewed and discussed in detail.
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35

Chen, Changming, Xiaoqiang Sun, Fei Wang, Feng Zhang, Hui Wang, Zuosen Shi, Zhanchen Cui, and Daming Zhang. "Electro-Optic Modulator Based on Novel Organic-Inorganic Hybrid Nonlinear Optical Materials." IEEE Journal of Quantum Electronics 48, no. 1 (January 2012): 61–66. http://dx.doi.org/10.1109/jqe.2011.2179019.

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36

Anestopoulos, D., G. Tsigaridas, P. Persephonis, V. Giannetas, I. Spiliopoulos, P. Karastatiris, and J. Mikroyannidis. "Electro-optic characterization of two novel organic materials in thin polymeric films." Chemical Physics Letters 390, no. 1-3 (May 2004): 98–103. http://dx.doi.org/10.1016/j.cplett.2004.03.130.

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37

Luo, Jingdong, Su Huang, Zhengwei Shi, Brent M. Polishak, Xing-Hua Zhou, and Alex K−Y Jen. "Tailored Organic Electro-optic Materials and Their Hybrid Systems for Device Applications†." Chemistry of Materials 23, no. 3 (February 8, 2011): 544–53. http://dx.doi.org/10.1021/cm1022344.

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38

WANG Xi-bin, 王希斌, 曹子谏 CAO Zi-jian, 靳琳 JIN Lin, 任殿福 REN Dian-fu, and 张大明 ZHANG Da-ming. "Preparation of Electro-Optic Waveguide Based on KH560 Modified Organic/Inorganic Hybrid Materials." ACTA PHOTONICA SINICA 40, no. 4 (2011): 561–64. http://dx.doi.org/10.3788/gzxb20114004.0561.

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39

Luo, Jingdong, Xing-Hua Zhou, and Alex K. Y. Jen. "Rational molecular design and supramolecular assembly of highly efficient organic electro-optic materials." Journal of Materials Chemistry 19, no. 40 (2009): 7410. http://dx.doi.org/10.1039/b907173c.

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40

Mahmood, M. H., and H. L. Saadon. "Study of the electro-optic effect in new organic nonlinear optical polymeric materials." Journal of Physics D: Applied Physics 45, no. 23 (May 22, 2012): 235302. http://dx.doi.org/10.1088/0022-3727/45/23/235302.

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41

Sreeja, R., S. Najidha, S. Remya Jayan, P. Predeep, Maciej Mazur, and P. D. Sharma. "Electro-optic materials from co-polymeric elastomer–acrylonitrile butadiene rubber (NBR)." Polymer 47, no. 2 (January 2006): 617–23. http://dx.doi.org/10.1016/j.polymer.2005.09.024.

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42

Dalton, Larry R., Philip A. Sullivan, and Denise H. Bale. "Electric Field Poled Organic Electro-optic Materials: State of the Art and Future Prospects." Chemical Reviews 110, no. 1 (January 13, 2010): 25–55. http://dx.doi.org/10.1021/cr9000429.

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43

Bhowmik, Achintya K., Shida Tan, and A. Claude Ahyi. "On the electro-optic measurements in organic single-crystal films." Journal of Physics D: Applied Physics 37, no. 23 (November 20, 2004): 3330–36. http://dx.doi.org/10.1088/0022-3727/37/23/016.

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