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Автор: Grafiati

Опубліковано: 6 вересня 2023

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1

Chen, Guangming, Zongneng Qi, and Deyan Shen. "Shear-induced ordered structure in polystyrene/clay nanocomposite." Journal of Materials Research 15, no. 2 (February 2000): 351–56. http://dx.doi.org/10.1557/jmr.2000.0055.

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Анотація:

A shear-induced ordered structure in an exfoliated polystyrene (PS)/clay nanocomposite is reported. X-ray diffraction (XRD), transmission electron microscopy (TEM), and infrared dichroism techniques have been employed to investigate the shear-induced ordered structure in the exfoliated PS/clay nanocomposite. Compared with the broad amorphous peaks before extrusion, a series of sharp diffraction peaks were observed in XRD pattern for the extruded PS/clay nanocomposite pellet sample, showing that an ordered structure occurred under shear flow. TEM images confirmed directly that the origin of the ordered structure was mainly due to the planar orientation of the primary particles of silicate layers as well as local ordered microstructure of the primary particles, induced by shear flow. The infrared dichroism study indicated that the phenyl group of PS apparently oriented parallel to the film surface, whereas no obvious orientation of the aliphatic chain could be observed. Based on these investigations, a possible mechanism was deduced for the formation of the ordered structure induced by shear flow in the exfoliated PS/clay nanocomposite.

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2

Kausar, Ayesha. "Polymeric nanocomposites reinforced with nanowires: Opening doors to future applications." Journal of Plastic Film & Sheeting 35, no. 1 (August 15, 2018): 65–98. http://dx.doi.org/10.1177/8756087918794009.

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This article presents a state-of-the-art overview on indispensable aspects of polymer/nanowire nanocomposites. Nanowires created from polymers, silver, zinc, copper, nickel, and aluminum have been used as reinforcing agents in conducting polymers and non-conducting thermoplastic/thermoset matrices such as polypyrrole, polyaniline, polythiophene, polyurethane, acrylic polymers, polystyrene, epoxy and rubbers. This review presents the combined influence of polymer matrix and nanowires on the nanocomposite characteristics. This review shows how the nanowire, the nanofiller content, the matrix type and processing conditions affect the final nanocomposite properties. The ensuing multifunctional polymer/nanowire nanocomposites have high strength, conductivity, thermal stability, and other useful photovoltaic, piezo, and sensing properties. The remarkable nanocomposite characteristics have been ascribed to the ordered nanowire structure and the development of a strong interface between the matrix/nanofiller. This review also refers to cutting edge application areas of polymer/nanowire nanocomposites such as solar cells, light emitting diodes, supercapacitors, sensors, batteries, electromagnetic shielding materials, biomaterials, and other highly technical fields. Modifying nanowires and incorporating them in a suitable polymer matrix can be adopted as a powerful future tool to create useful technical applications.

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3

Zhang, Yi He, Qing Song Su, Li Yu, Li Bing Liao, Hong Zheng, Hai Tao Huang, Guo Ge Zhang, Ying Bang Yao, Cindy Lau, and Helen Lai Wah Chan. "Preparation of Low-K Fluorinated Polyimide/Phlogopite Nanocomposites." Advanced Materials Research 47-50 (June 2008): 987–90. http://dx.doi.org/10.4028/www.scientific.net/amr.47-50.987.

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Phlogopite with layered silicate structure had been firstly chemically modified via an in situ intercalation method, and phlogopite-polymer nanocomposite films were prepared from 2,2'-bis (3,4-dicarboxyphenyl) hexafluropropane dianhydride (6FDA) and oxydimethyl aniline (ODA) in N,N-dimethylacetamide as a solvent by using in-situ polymerization process combined with ultrasonic dispersion and multi-step curing. The structure of phlogopite minerals and its polymer nanocomposites were characterized by X-ray diffraction (XRD) and infrared spectra (FTIR) respectively. The experimental results indicated that the phlogopites with layered nanostructure had lost their ordered structure and had been exfoliated or intercalated. Thereafter, they were dispersed randomly in the polyimide matrix. The dependence of dielectric properties and thermal stabilities of the nanocomposite films on the phlogopite content and frequency were studied.

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4

Masuda, Hideki, Kenji Yasui, Mitsuo Watanabe, Kazuyuki Nishio, Tata N. Rao, and Akira Fujishima. "Fabrication of Ordered Diamond/metal Nanocomposite Structures." Chemistry Letters 29, no. 10 (October 2000): 1112–13. http://dx.doi.org/10.1246/cl.2000.1112.

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5

Lunn, Jonathan D., and Daniel F. Shantz. "Peptide Brush—Ordered Mesoporous Silica Nanocomposite Materials." Chemistry of Materials 21, no. 15 (August 11, 2009): 3638–48. http://dx.doi.org/10.1021/cm901025n.

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6

Andrieux, Sébastien, Lilian Medina, Michael Herbst, Lars A. Berglund, and Cosima Stubenrauch. "Monodisperse highly ordered chitosan/cellulose nanocomposite foams." Composites Part A: Applied Science and Manufacturing 125 (October 2019): 105516. http://dx.doi.org/10.1016/j.compositesa.2019.105516.

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7

Zhao, Ziguang, Ruochen Fang, Qinfeng Rong, and Mingjie Liu. "Bioinspired Nanocomposite Hydrogels with Highly Ordered Structures." Advanced Materials 29, no. 45 (October 23, 2017): 1703045. http://dx.doi.org/10.1002/adma.201703045.

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8

Matsumoto, Taki, Nobuo Iyi, Yoshiro Kaneko, Kenji Kitamura, Satoru Masaki, Tomohito Imai, Wataru Sugimoto, Yoshio Takasu, and Yasushi Murakami. "Preparation of a transparent and flexible self-standing film of layered titania/isostearate nanocomposite." Journal of Materials Research 20, no. 5 (May 2005): 1308–15. http://dx.doi.org/10.1557/jmr.2005.0165.

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A titania-based self-standing film with high transparency and flexibility was successfully prepared via a sol-gel process, in which a titanium tetraisopropoxide/isostearate complex (precursor), n-hexylammonium isostearate (catalyst), and o-xylene (solvent) were used. The sol obtained by the sol-gel reaction was floated on a water surface to form an unsupported film. This film was composed of a titania/isostearate nanocomposite with ordered layer structure. The basal spacings of the nanocomposites depended on the chain length of the carboxylate modifier.

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9

Tao, Bai Rui, Feng Juan Miao, and Yong Jie Zheng. "Preparation and Characterization of Electrochemical Glucose Sensor Based on Nickel Electrodes Supported by Silicon Microchannel Plates." Applied Mechanics and Materials 138-139 (November 2011): 1126–31. http://dx.doi.org/10.4028/www.scientific.net/amm.138-139.1126.

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A novel nickel nanocomposite electrode supported by 3D ordered silicon microchannel plates (MCP) had been reported and its electrocatalytic toward the oxidation of glucose for sensor had been studied. The 3D ordered Si MCP electrodes were first fabricated by electrochemical etching and then Nickel nanoparticles were deposited onto the sidewall of the MCP via electroless deposition followed by annealing at 300°C for 300 s under argon to stabilize the structure. The morphology of the Ni/Si-MCP electrode was characterized by Scanning electron microscope (SEM) and X-ray diffraction (XRD). The electrochemical methods were employed to investigate the Ni/Si-MCP materials. The Ni/Si-MCP nanocomposites exhibit superior electrocatalytic properties towards glucose electro-oxidation in alkaline solutions, in addition to showing excellent long-term stability and good reproducibility.

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10

Qin, Yuyang, Qingyu Peng, Yue Zhu, Xu Zhao, Zaishan Lin, Xiaodong He, and Yibin Li. "Lightweight, mechanically flexible and thermally superinsulating rGO/polyimide nanocomposite foam with an anisotropic microstructure." Nanoscale Advances 1, no. 12 (2019): 4895–903. http://dx.doi.org/10.1039/c9na00444k.

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11

Jalani, Mohamad Azani, Leny Yuliati, Siew Ling Lee, and Hendrik Oktendy Lintang. "Highly ordered mesoporous silica film nanocomposites containing gold nanoparticles for the catalytic reduction of 4-nitrophenol." Beilstein Journal of Nanotechnology 10 (July 5, 2019): 1368–79. http://dx.doi.org/10.3762/bjnano.10.135.

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We report that transparent mesostructured silica/gold nanocomposite materials with an interpore distance of 4.1 nm, as-synthesized from a templated sol–gel synthesis method using discotic trinuclear gold(I) pyrazolate complex, were successfully utilized for the fabrication of thin film mesoporous silica nanocomposites containing gold nanoparticles. The material exhibited a highly ordered hexagonal structure when subjected to a thermal hydrogen reduction treatment at 210 °C. In contrast, when the material was subjected to calcination as a heat treatment from 190 to 450 °C, the thin film nanocomposites showed an intense d 100 X-ray diffraction peak. Moreover, gold nanoparticles inside the thin film nanocomposites were confirmed by the presence of the d 111 diffraction peak at 2θ = 38.2°, a surface plasmon resonance peak between 500–580 nm, and the spherical shape observed in the transmission electron microscope images, as well as the visual change in color from pink to purple. Interestingly, by simply dipping the material into a reaction solution of 4-nitrophenol at room temperature, the highly ordered structure of the as-fabricated silica/gold nanoparticle thin film composite after thermal hydrogen reduction at 210 °C resulted in an improved catalytic activity for the reduction of 4-nitrophenol to 4-aminophenol compared to the material calcined at 250 °C. Such catalytic activity is due to the presence of gold nanoparticles of smaller size in the silicate channels of the highly ordered mesoporous film nanocomposites.

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12

Xia, Z., W. A. Curtin, and B. W. Sheldon. "Fracture Toughness of Highly Ordered Carbon Nanotube/Alumina Nanocomposites." Journal of Engineering Materials and Technology 126, no. 3 (June 29, 2004): 238–44. http://dx.doi.org/10.1115/1.1751179.

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The fracture toughness of highly-ordered multi-wall carbon-nanotube-reinforced alumina composites is calculated from experimental data on nanoindentation cracking. A combined analytical and numerical model, using cohesive zone models for both matrix cracking and nanotube crack bridging and accounting for residual stresses, is developed to interpret the indentation results and evaluate the fracture toughness of the composite. Results show that residual stress and nanotube bridging play important roles in the nanocomposite fracture. The contribution to toughness from the nanotube bridging for cracking transverse to the axis of the nanotubes is calculated to be ∼5 MPa-m1/2. From the nanotube bridging law, the nanotube strength and interfacial frictional stress are also estimated and range from 15–25 GPa and 40–200 MPa, respectively. These preliminary results demonstrate that nanotube-reinforced ceramics can exhibit the interfacial debonding/sliding and nanotube bridging necessary to induce nanoscale toughening, and suggest the feasibility of engineering residual stresses, nanotube structure, and composite geometry to obtain high-toughness nanocomposites.

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13

Dabbaghianamiri, M., and G. W. Beall. "Self-assembling nanostructured intercalates via ion–dipole bonding." Dalton Transactions 47, no. 9 (2018): 3178–84. http://dx.doi.org/10.1039/c7dt03900j.

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14

Gupta, Pallav, Naseem Ahamad, Jimmy Mehta, Devendra Kumar, Mumtaz A. Quraishi, Moti L. Rinawa, Sumit Gupta, Vijay Chaudhary, and Kishor K. Sadasivuni. "Corrosion, optimization and surface analysis of Fe-Al₂O₃-CeO₂ metal matrix nanocomposites." Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science 236, no. 8 (December 7, 2021): 4346–56. http://dx.doi.org/10.1177/09544062211047844.

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In the present work, metal matrix nanocomposites are being prepared using Fe as base material reinforced with Al2O3 and doped with CeO2. Nanocomposite specimens were synthesized using powder metallurgy technique. Tafel Polarization, Corrosion Behavior and its optimization using Analysis of Variance (ANOVA) as well as Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS) along with Phase and Microstructure of prepared samples have been investigated. It was observed that corrosion rate and corrosion current density was highest for pure Fe samples whereas 1.0% CeO2 doped Fe-Al2O3 metal matrix nanocomposite system showed the formation of nano amorphous layer on the specimen surface. Analysis of Variance shows that the different compositions of samples have changed outcome on corrosion behavior. Technique for Order of Preference by Similarity to Ideal Solution analysis shows ordered preference of sample as per the readings of corrosion rate.

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15

Tavares, Albaniza Alves, Maria Dennise Medeiros Macêdo, Pedro Henrique Correia de Lima, Rossemberg Cardoso Barbosa, Wladymyr Jefferson Bacalhau Sousa, Cristiano José de Farias Braz, Matheus Ferreira de Souza, Camila Melo Gadelha Pereira Diniz, Marcus Vinícius Lia Fook, and Suédina Maria de Lima Silva. "Chitosan-clay nanocomposite as a drug delivery system of ibuprofen." Research, Society and Development 11, no. 1 (January 6, 2022): e25911124684. http://dx.doi.org/10.33448/rsd-v11i1.24684.

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Chitosan/montmorillonite nanocomposite films were prepared by the solvent evaporation method to immobilize the drug ibuprofen (IBU) and delay its release in a medium that simulates the environment of the gastrointestinal tract. The effects of montmorillonite, at different mass proportions (10, 20, and 50%), on the morphological and physical properties of the films were studied. The samples were characterized by X-ray diffraction (XRD), Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), degree of swelling, drug encapsulation, and drug release efficiency. According to the XRD it was evidenced that the incorporation of montmorillonite to chitosan led to the formation of nanocomposites of ordered morphology. The infrared spectra confirmed the good interaction between montmorillonite and chitosan by the formation of nanocomposites. This fact, which favored the imprisonment of the IBU, reduced the diffusion coefficient in the studied systems. The micrographs comproved the formation of dense and uniform films. The controlled release profile, especially for the nanocomposite with 10% clay mass, showed a slow drug release rate. The incorporation of montmorillonite at different proportions produced different morphologies, with good encapsulation efficiency and an adequate profile for the controlled release of the drug.

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16

Andreeva, Yaroslava, Alexander Suvorov, Evgeniy Grigoryev, Dmitry Khmelenin, Mikhail Zhukov, Vladimir Makin, and Dmitry Sinev. "Laser Fabrication of Highly Ordered Nanocomposite Subwavelength Gratings." Nanomaterials 12, no. 16 (August 16, 2022): 2811. http://dx.doi.org/10.3390/nano12162811.

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Optical nanogratings are widely used for different optical, photovoltaic, and sensing devices. However, fabrication methods of highly ordered gratings with the period around optical wavelength range are usually rather expensive and time consuming. In this article, we present high speed single-step approach for fabrication of highly ordered nanocomposite gratings with a period of less than 355 nm. For the purpose, we used commercially available nanosecond-pulsed fiber laser system operating at the wavelength of 355 nm. One-dimensional and two-dimensional nanostructures can be formed by direct laser treatment with different scan speed and intensity. These structures exhibit not only dispersing, but also anisotropic properties. The obtained results open perspectives for easier mass production of polarization splitters and filters, planar optics, and also for security labeling.

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17

Lim, Chang-Sung. "Fabrication of ordered porous nanocomposite materials using templating." Analytical Science and Technology 23, no. 3 (June 25, 2010): 233–39. http://dx.doi.org/10.5806/ast.2010.23.3.233.

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18

Lee, Chang-Wook, Kwang Chul Roh, and Kwang-Bum Kim. "A highly ordered cubic mesoporous silica/graphene nanocomposite." Nanoscale 5, no. 20 (2013): 9604. http://dx.doi.org/10.1039/c3nr03108j.

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19

Kiani, M. A., Hadi Khani, and Nourali Mohammadi. "MnO2/ordered mesoporous carbon nanocomposite for electrochemical supercapacitor." Journal of Solid State Electrochemistry 18, no. 4 (January 4, 2014): 1117–25. http://dx.doi.org/10.1007/s10008-013-2367-x.

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20

Ganji, Nasim, Babak Karimi, Sepideh Najafvand-Derikvandi, and Hojatollah Vali. "Palladium supported on a novel ordered mesoporous polypyrrole/carbon nanocomposite as a powerful heterogeneous catalyst for the aerobic oxidation of alcohols to carboxylic acids and ketones on water." RSC Advances 10, no. 23 (2020): 13616–31. http://dx.doi.org/10.1039/c9ra10941b.

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21

Jirakittidul, Kittimon, Darawan Limthin, Sarita Mahithithummathorn, and Seenam Phaewchimphlee. "Effects of Annealing Temperature and Time on Properties of Thermoplastic Polyurethane Based on Different Soft Segments/Multi-Walled Carbon Nanotube Nanocomposites." Polymers 15, no. 2 (January 10, 2023): 364. http://dx.doi.org/10.3390/polym15020364.

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Typically, polymer chains can move under the annealing process, resulting in an ordered structure arrangement. This causes an improvement in nanocomposite properties and in the dispersion of filler. In this research, annealed thermoplastic polyurethane (PU)/multi-walled carbon nanotube (MWCNT) nanocomposites were studied to investigate the effect of annealing on the selective dispersion of MWCNTs. PU matrices were composed of two different soft segments, i.e., polyether (PU-Ether) and polyester (PU-Ester). Nanocomposites were prepared by the melt mixing process and annealed at 80 to 120 °C for 6 to 24 h. The increases in annealing time and temperature resulted in microphase separation in segmented PU and the orientation of crystalline structures in the segregated hard domain. Nanocomposites showed higher electrical conductivity after annealing. This implies that the movement of PU chains during heat treatment encouraged the development of the MWCNT network. However, the increase in ordered structures could obstruct the MWCNT network, resulting in lower electrical conductivity levels. Considering the selective dispersion of MWCNT in PU matrices, it was found that MWCNTs dispersed in soft segments of PU-Ether, leading to a significant decrease in elongation at the break after annealing. On the other hand, a decrease in elasticity of PU-Ester nanocomposites was not observed as a result of MWCNT dispersal in hard segments.

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22

Liang, Yeru, Lifeng Cai, Luyi Chen, Xidong Lin, Ruowen Fu, Mingqiu Zhang, and Dingcai Wu. "Silica nanonetwork confined in nitrogen-doped ordered mesoporous carbon framework for high-performance lithium-ion battery anodes." Nanoscale 7, no. 9 (2015): 3971–75. http://dx.doi.org/10.1039/c4nr06611a.

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23

Huang, Yifan, Weicheng Jiao, Yue Niu, Guomin Ding, and Rongguo Wang. "Improving the mechanical properties of Fe3O4/carbon nanotube reinforced nanocomposites by a low-magnetic-field induced alignment." Journal of Polymer Engineering 38, no. 8 (August 28, 2018): 731–38. http://dx.doi.org/10.1515/polyeng-2017-0257.

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Abstract The aim of the paper is to develop a novel nanocomposite with high mechanical properties. The mechanical properties are improved by aligning the Fe3O4/multi-walled carbon nanotubes (MWCNTs) into a highly oriented manner in epoxy resin (EP) via a low magnetic field. Fe3O4 nanoparticles were tethered onto the surface of MWCNTs by a novel water-in-oil (W/O) method without heating at high temperatures or the protection of inert gas. Then, the modified magnetic MWCNTs (m-MWCNTs) were added into EP and aligned in a low magnetic field (100 mT). A method was presented to estimate the minimum magnetic field strength for aligning the m-MWCNTs. Besides, the morphology and microstructures of the fabricated m-MWCNTs and m-MWCNTs/EP highly ordered nanocomposites were characterized. Finally, the mechanical properties measurements were performed. The results of the experiments showed that this method was very efficient in aligning m-MWCNTs embedded in polymer matrix leading to a highly ordered composite for improving mechanical properties.

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24

Mahesh, Dabbugalla, and Swapan K. Mandal. "Multiferroicity in ZnO nanodumbbell/BiFeO3 nanoparticle heterostructures." International Journal of Modern Physics B 30, no. 12 (May 6, 2016): 1650074. http://dx.doi.org/10.1142/s0217979216500740.

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We report here on the multiferroic properties of ZnO–BiFeO3 (BiFeO3 referred hereinafter as BFO) nanocomposite structures obtained by using a facile solution-based synthesis route. ZnO is found to grow in the form of well-crystallized and self-assembled dumbbell-like structures. BFO nanoparticles (NPs) are deposited onto ZnO nanodumbbells (NDs) to obtain ZnO–BFO heterostructures. The nanocomposites show prominent ferroelectric polarization hysteresis loop along with enhanced magnetization in comparison to pure BFO NPs. The ordered alignment of spins along with the suppression of Fe–O–Fe antiferromagnetic super-exchange interactions at the ZnO/BFO interface plausibly gives rise to observed multiferroic properties.

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25

Andrade-Melecio, Hugo A., Víctor H. Antolín-Cerón, Abraham G. Alvarado-Mendoza, Milton Vázquez-Lepe, Karla A. Barrera-Rivera, Antonio Martínez-Richa, and Sergio M. Nuño-Donlucas. "Semi-Continuous Heterophase Polymerization to Synthesize Poly(methacrylic acid)-Based Nanocomposites for Drug Delivery." Polymers 14, no. 6 (March 16, 2022): 1195. http://dx.doi.org/10.3390/polym14061195.

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The design of nanocomposites with the potential for drug delivery is a topic of great interest. In this work, the synthesis of nanocomposites of poly(methacrylic acid) (PMAA) grafted onto carbon nanotubes (CNTs) functionalized with poly(amidoamine) (PAMAM) dendrimer by semicontinuous heterophase polymerization SHP, at three different methacrylic acid (MAA) dosing rates, is reported. SHP is a polymerization technique poorly used to prepare nanocomposites containing CNTs and has the potential to produce more ordered alkyl methacrylic polymer chains, which could favor the obtaining of a homogenous nanocomposite. For the nanocomposites synthesized, a lowest addition rate monomer-starved condition was reached. Analysis by X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA) demonstrate that functionalized CNTs are grafted onto the PMAA matrix. The ability of prepared nanocomposites to deliver hydrocortisone was evaluated by ultraviolet-visible spectroscopy (UV-Vis). The hydrocortisone release profiles of pure PMAA and of their nanocomposites prepared at the lowest monomer fed rate were fitted with Higuchi and Korsmeyer–Peppas models, successfully. Functionalized CNTs have a crucial role to induce an effective release of hydrocortisone from the prepared nanocomposites.

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26

Sun, Xing, Judith L. MacManus-Driscoll, and Haiyan Wang. "Spontaneous Ordering of Oxide-Oxide Epitaxial Vertically Aligned Nanocomposite Thin Films." Annual Review of Materials Research 50, no. 1 (July 1, 2020): 229–53. http://dx.doi.org/10.1146/annurev-matsci-091719-112806.

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The emerging field of self-assembled vertically aligned nanocomposite (VAN) thin films effectively enables strain, interface, and microstructure engineering as well as (multi)functional improvements in electric, magnetic, optical, and energy-related properties. Well-ordered or patterned microstructures not only empower VAN thin films with many new functionalities but also enable VAN thin films to be used in nanoscale devices. Comparative ordered devices formed via templating methods suffer from critical drawbacks of processing complexity and potential contamination. Therefore, VAN thin films with spontaneous ordering stand out and display many appealing features for next-generation technological devices, such as electronics, optoelectronics, ultrahigh-density memory systems, photonics, and 3D microbatteries. The spontaneous ordering described in this review contains ordered/patterned structures in both in-plane and out-of-plane directions. In particular, approaches to obtaining spontaneously ordered/patterned structures in-plane are systematically reviewedfrom both thermodynamic and kinetic perspectives. Out-of-plane ordering is also discussed in detail. In addition to reviewing the progress of VAN films with spontaneous ordering, this article also highlights some recent developments in spontaneous ordering approaches and proposes future directions.

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27

Kazemi, Sayed Habib, Babak Karimi, Siamak Abdollahi Aghdam, Hesam Behzadnia, and Mohammad Ali Kiani. "Polyaniline–ionic liquid derived ordered mesoporous carbon nanocomposite: synthesis and supercapacitive behavior." RSC Advances 5, no. 84 (2015): 69032–41. http://dx.doi.org/10.1039/c5ra09136e.

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A nanocomposite of polyaniline formed within ionic liquid derived ordered mesoporous carbon (PANi@IOMC) was prepared by polymerization of aniline in the presence of IOMC for electrochemical capacitors.

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28

Song, Lihong, Ling Li, Xin Gao, Jiaxin Zhao, Ting Lu, and Zhi Liu. "A facile synthesis of a uniform constitution of three-dimensionally ordered macroporous TiO2–carbon nanocomposites with hierarchical pores for lithium ion batteries." Journal of Materials Chemistry A 3, no. 13 (2015): 6862–72. http://dx.doi.org/10.1039/c4ta06985d.

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A novel 3DOM TiO₂–carbon nanocomposite is fabricated via a simple multicomponent infiltration of three-dimensionally ordered templates, and exhibits superior lithium ion storage performance.

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29

Ma, Xinyu, Wenyan Liao, Huaxu Zhou, Yun Tong, Fei Yan, Hongliang Tang, and Jiyang Liu. "Highly sensitive detection of rutin in pharmaceuticals and human serum using ITO electrodes modified with vertically-ordered mesoporous silica–graphene nanocomposite films." Journal of Materials Chemistry B 8, no. 46 (2020): 10630–36. http://dx.doi.org/10.1039/d0tb01996h.

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A vertically-ordered silica–graphene nanocomposite film modified transparent ITO electrode was prepared by a one-step electrodeposition method for antifouling detection of rutin in pharmaceuticals and human serum.

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Lu, X. L., J. W. Zhang, C. F. Zhang, J. C. Zhang, and Y. Hao. "Highly ordered core–shell CoFe2O4–BiFeO3 nanocomposite arrays from dimension confined phase separation and their interfacial magnetoelectric coupling properties." RSC Advances 5, no. 72 (2015): 58640–43. http://dx.doi.org/10.1039/c5ra05106a.

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31

Ha, Yung-Hoon, Younghwan Kwon, Thomas Breiner, Edwin P. Chan, Theodora Tzianetopoulou, Robert E. Cohen, Mary C. Boyce, and Edwin L. Thomas. "An Orientationally Ordered Hierarchical Exfoliated Clay−Block Copolymer Nanocomposite." Macromolecules 38, no. 12 (June 2005): 5170–79. http://dx.doi.org/10.1021/ma0476792.

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Yadav, Arti, M. Muthukumar, and M. S. Bobji. "Porous alumina based ordered nanocomposite coating for wear resistance." Materials Research Express 3, no. 8 (August 12, 2016): 085021. http://dx.doi.org/10.1088/2053-1591/3/8/085021.

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33

Shalin, A. S. "Effect of the absolute transparency of an ordered nanocomposite." JETP Letters 90, no. 4 (October 2009): 257–62. http://dx.doi.org/10.1134/s0021364009160073.

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Kruk, Michal, and Mietek Jaroniec. "Gas Adsorption Characterization of Ordered Organic−Inorganic Nanocomposite Materials." Chemistry of Materials 13, no. 10 (October 2001): 3169–83. http://dx.doi.org/10.1021/cm0101069.

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35

Cook, Ray, Yihong Chen, and Gary W. Beall. "Highly Ordered Self-Assembling Polymer/Clay Nanocomposite Barrier Film." ACS Applied Materials & Interfaces 7, no. 20 (May 15, 2015): 10915–19. http://dx.doi.org/10.1021/acsami.5b02162.

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36

Rodríguez Hernández, José Carlos, Ángel Serrano Aroca, José Luis Gómez Ribelles, and Manuel Monleón Pradas. "Three-dimensional nanocomposite scaffolds with ordered cylindrical orthogonal pores." Journal of Biomedical Materials Research Part B: Applied Biomaterials 84B, no. 2 (2008): 541–49. http://dx.doi.org/10.1002/jbm.b.30902.

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37

Masuda, Hideki, Kenji Yasui, Mitsuo Watanabe, Kazuyuki Nishio, Tata N. Rao, and Akira Fujishima. "ChemInform Abstract: Fabrication of Ordered Diamond/Metal Nanocomposite Structures." ChemInform 32, no. 5 (January 30, 2001): no. http://dx.doi.org/10.1002/chin.200105256.

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38

Huang, Hui, Jun Zhou, Jie Zhou, and Mingshan Zhu. "Structure-retentive synthesis of a highly ordered mesoporous Nb2O5/N-doped graphene nanocomposite with superior interfacial contacts and improved visible-light photocatalysis." Catalysis Science & Technology 9, no. 13 (2019): 3373–79. http://dx.doi.org/10.1039/c9cy00555b.

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39

Garcia-Osorio, Daniel, Helton P. Nogueira, Josué M. Gonçalves, Sergio H. Toma, Sergio Garcia-Segura, and Koiti Araki. "SPION-decorated organofunctionalized MCM48 silica-based nanocomposites for magnetic solid-phase extraction." Materials Advances 2, no. 3 (2021): 963–73. http://dx.doi.org/10.1039/d0ma00989j.

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Анотація:

(a) Cubic structures formed by CTAB above critical micellar concentration used as a template to generate highly ordered mesoporous silica. (b) Photo showing the magnetic recovery of MCM48/SPION/C8 nanocomposite in 60 s.

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40

Gao, Xin, Ling Li, Lihong Song, Ting Lu, Jiaxin Zhao, and Zhi Liu. "Highly dispersed MnOx nanoparticles supported on three-dimensionally ordered macroporous carbon: a novel nanocomposite for catalytic reduction of NOx with NH3 at low temperature." RSC Advances 5, no. 37 (2015): 29577–88. http://dx.doi.org/10.1039/c4ra16141f.

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A novel MnO_x/3DOMC nanocomposite is fabricated via a simple multicomponent infiltration of three-dimensionally ordered templates, and exhibits superior NH₃-SCR of NO_x performance.

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41

Conterosito, Eleonora, Luca Palin, Diego Antonioli, Maria Riccardi, Enrico Boccaleri, Maurizio Aceto, Marco Milanesio, and Valentina Gianotti. "On the Rehydration of Organic Layered Double Hydroxides to form Low-Ordered Carbon/LDH Nanocomposites." Inorganics 6, no. 3 (August 14, 2018): 79. http://dx.doi.org/10.3390/inorganics6030079.

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Low-ordered carbon/layered double hydroxide (LDH) nanocomposites were prepared by rehydration of the oxides produced by calcination of an organic LDH. While the memory effect is a widely recognized effect on oxides produced by inorganic LDH, it is unprecedented from the calcination/rehydration of organic ones. Different temperatures (400, 600, and 1100 °C) were tested on the basis of thermogravimetric data. Water, instead of a carbonate solution, was used for the rehydration, with CO2 available from water itself and/or air to induce a slower process with an easier and better intercalation of the carbonaceous species. The samples were characterized by X-ray powder diffraction (XRPD), infrared in reflection mode (IR), and Raman spectroscopies and scanning electron microscopy (SEM). XRPD indicated the presence of carbonate LDH, and of residuals of unreacted oxides. IR confirmed that the prevailing anion is carbonate, coming from the water used for the rehydration and/or air. Raman data indicated the presence of low-ordered carbonaceous species moieties and SEM and XRPD the absence of separated bulky graphitic sheets, suggesting an intimate mixing of the low ordered carbonaceous phase with reconstructed LDH. Organic LDH gave better memory effect after calcination at 400 °C. Conversely, the carbonaceous species are observed after rehydration of the sample calcined at 600 °C with a reduced memory effect, demonstrating the interference of the carbonaceous phase with LDH reconstruction and the bonding with LDH layers to form a low-ordered carbon/LDH nanocomposite.

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42

Šesták, Petr, Martin Friák, David Holec, Monika Všianská, and Mojmír Šob. "Strength and Brittleness of Interfaces in Fe-Al Superalloy Nanocomposites under Multiaxial Loading: An ab initio and Atomistic Study." Nanomaterials 8, no. 11 (October 24, 2018): 873. http://dx.doi.org/10.3390/nano8110873.

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We present an ab initio and atomistic study of the stress-strain response and elastic stability of the ordered Fe 3 Al compound with the D0 3 structure and a disordered Fe-Al solid solution with 18.75 at.% Al as well as of a nanocomposite consisting of an equal molar amount of both phases under uniaxial loading along the [001] direction. The tensile tests were performed under complex conditions including the effect of the lateral stress on the tensile strength and temperature effect. By comparing the behavior of individual phases with that of the nanocomposite we find that the disordered Fe-Al phase represents the weakest point of the studied nanocomposite in terms of tensile loading. The cleavage plane of the whole nanocomposite is identical to that identified when loading is applied solely to the disordered Fe-Al phase. It also turns out that the mechanical stability is strongly affected by softening of elastic constants C ′ and/or C 66 and by corresponding elastic instabilities. Interestingly, we found that uniaxial straining of the ordered Fe 3 Al with the D0 3 structure leads almost to hydrostatic loading. Furthermore, increasing lateral stress linearly increases the tensile strength. This was also confirmed by molecular dynamics simulations employing Embedded Atom Method (EAM) potential. The molecular dynamics simulations also revealed that the thermal vibrations significantly decrease the tensile strength.

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43

Jafari Nasab, Mina, and Ali Reza Kiasat. "Synthesis and characterization of bifunctional lipophilic and basic mesoporous organosilica supported palladium nanoparticles as an efficient and ecofriendly nanocomposite in aqueous Heck reaction." RSC Advances 6, no. 85 (2016): 81614–21. http://dx.doi.org/10.1039/c6ra17452c.

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In the present study, a highly ordered mesoporous organosilica nanocomposite having modified pore channels with both lipophilic and basic units, SBA-R/Im-NH₂, was synthesized through surfactant-templated sol–gel methodology and post modification process.

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44

Tomer, Vijay K., and Surender Duhan. "Correction: Ordered mesoporous Ag-doped TiO2/SnO2 nanocomposite based highly sensitive and selective VOC sensors." Journal of Materials Chemistry A 8, no. 38 (2020): 20189–90. http://dx.doi.org/10.1039/d0ta90213f.

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Correction for ‘Ordered mesoporous Ag-doped TiO₂/SnO₂ nanocomposite based highly sensitive and selective VOC sensors’ by Vijay K. Tomer et al., J. Mater. Chem. A, 2016, 4, 1033–1043, DOI: 10.1039/C5TA08336B.

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45

Razie, Dahti, Khodaveisi Javad, and Seyyed Moradi. "The inclusion of MgH2 into iron oxide and nickel oxide modified mesoporous carbon sorbent, an investigation on hydrogen production." Chemical Industry 66, no. 3 (2012): 317–25. http://dx.doi.org/10.2298/hemind110929107b.

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In the present work, we investigated the hydrogen desorption properties of nano-sized MgH2 that was loaded on ordered mesoporous carbon (OMC) surface that had been already modified with nickel and iron oxide nanoparticles. The surface modified mesoporous carbon was characterized by BET surface area and X-ray diffraction (XRD) analysis. The amount of MgH2 on the carbon surface was confirmed by thermogravimetric analysis (TGA). Dehydrogenation data of MgH2 on the ordered mesoporous carbon were collected for the pressure up to 8 MPa (80 bar) at 500 K. The incorporated MgH2 on nickel oxide-mesoporous carbon nanocomposite had faster dehydrogenation kinetics compared to incorporated MgH2 on iron oxide-mesoporous carbon nanocomposite as well as incorporated MgH2 on mesoporous carbon. This can be attributed to the particle size of the former being smaller than that of the latter, as well as much accessible nanosized surface of loaded MgH2.

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46

Xue Shuang-Xi, Wang Hao, and Wong S. P. "Low-temperature ordered CoPtCu/Ag nanocomposite film with (001) texture." Acta Physica Sinica 56, no. 6 (2007): 3533. http://dx.doi.org/10.7498/aps.56.3533.

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47

Tomer, Vijay K., and Surender Duhan. "Ordered mesoporous Ag-doped TiO2/SnO2 nanocomposite based highly sensitive and selective VOC sensors." Journal of Materials Chemistry A 4, no. 3 (2016): 1033–43. http://dx.doi.org/10.1039/c5ta08336b.

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48

Diaz, Javier, Marco Pinna, Andrei V. Zvelindovsky, and Ignacio Pagonabarraga. "Hybrid Time-Dependent Ginzburg–Landau Simulations of Block Copolymer Nanocomposites: Nanoparticle Anisotropy." Polymers 14, no. 9 (May 7, 2022): 1910. http://dx.doi.org/10.3390/polym14091910.

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Block copolymer melts are perfect candidates to template the position of colloidal nanoparticles in the nanoscale, on top of their well-known suitability for lithography applications. This is due to their ability to self-assemble into periodic ordered structures, in which nanoparticles can segregate depending on the polymer–particle interactions, size and shape. The resulting coassembled structure can be highly ordered as a combination of both the polymeric and colloidal properties. The time-dependent Ginzburg–Landau model for the block copolymer was combined with Brownian dynamics for nanoparticles, resulting in an efficient mesoscopic model to study the complex behaviour of block copolymer nanocomposites. This review covers recent developments of the time-dependent Ginzburg–Landau/Brownian dynamics scheme. This includes efforts to parallelise the numerical scheme and applications of the model. The validity of the model is studied by comparing simulation and experimental results for isotropic nanoparticles. Extensions to simulate nonspherical and inhomogeneous nanoparticles are discussed and simulation results are discussed. The time-dependent Ginzburg–Landau/Brownian dynamics scheme is shown to be a flexible method which can account for the relatively large system sizes required to study block copolymer nanocomposite systems, while being easily extensible to simulate nonspherical nanoparticles.

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Kostrichenko, A. B., and Kyaw Ye Ko. "Preparation of Low-Density Polyethylene Composite with Copper Nanoparticles." WSEAS TRANSACTIONS ON APPLIED AND THEORETICAL MECHANICS 16 (September 15, 2021): 150–57. http://dx.doi.org/10.37394/232011.2021.16.16.

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In this work, devoted to the preparation and study of the properties of copper-containing nanocomposites based on linear low density polyethylene, it is shown that the composition of the resulting nanocomposite is not complicated by phase transformations during its synthesis. Varying the concentration of copper (II) formate (1.2÷50.8 wt%) makes it possible to control the size of the formed nanoparticles (10.2±2.0÷ 21.3±1,5 nm). It has been shown that the presence of Cu nanoparticles in a polymer matrix leads to a decrease in its degree of crystallinity - the value decreases from 42% for polyethylene to 37% for 3Cu / LLDPE, which is due to the restriction of the free movement of polymer chain segments by metal nanoparticles and, accordingly, the formation of a less ordered crystal structure.

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Wu, Ying Bing, Zun Li Mo, Hong Chen, and Gui Ping Niu. "Synthesis and Characterization of Polyaniline/Montmorillonite/La³⁺ Nanocomposites." Advanced Materials Research 79-82 (August 2009): 1547–50. http://dx.doi.org/10.4028/www.scientific.net/amr.79-82.1547.

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A new nanocomposite consisting of polyaniline (PANI), montmorillonite (MMT) and La3+ was developed via in-situ polymerization of aniline in the presence of MMT and La3+ through emulsion polymerization, and also a novel network structure consisting of nanowires had been shaped. The morphology and the chemical structure of the product were studied by transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The thermal property was exmined by mean of gravimetric analysis (TGA). The results indicated that PANI/MMT/ La3+ namocomposite has formed nanowires with diameter about 5 nm. The novel network structure consisting of nanowires has been shaped and overlapped towards certain direction. The formation of this network structure reveals that PANI molecules have been successfully inserted into the interlayer of MMT. Meanwhile, this conductivity network is believed to lead to the great improvement of the electrical conductivity for the nanocomposites. The FT-IR spectra reveal that PANI is obtained via in situ polymerization of the aniline monomer and there is a strong interaction between PANI and MMT. From XRD analysis, it can be also seen that the PANI molecules had been successfully intercalated into the galleries of the MMT. Moreover, the arrangement of PANI is more ordered in PANI/MMT/La3+ nanocomposite than that of pure PANI. From TGA curves, it is apparent that the introduction of MMT and rare-earth ions (La3+) exhibited a beneficial effect on the thermal stability of pure PANI. This markedly enhanced thermal stability of the nanocomposites can be ascribed to the MMT nanolayers acting as barriers for the degradation of PANI in the interlayer spacings and the inorganic nanoparticles trammeled the movement of the PANI molecule chains. They make the thermal decomposition of the nanocomposites at a disadvantage. As a consequence, the needed energy of the thermal decomposition increased, the thermal stability of nanocomposite increased. The paper offers a novel PANI/MMT/La3+ nanowire composites.

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