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1
Martinez, Santiago, Simona Merola, and Adrian Irimescu. "Flame Front and Burned Gas Characteristics for Different Split Injection Ratios and Phasing in an Optical GDI Engine." Applied Sciences 9, no. 3 (January 28, 2019): 449. http://dx.doi.org/10.3390/app9030449.
Повний текст джерелаАнотація:
Direct-injection in spark-ignition engines has long been recognized as a valid option for improving fuel economy, reducing CO2 emissions and avoiding knock occurrence due to higher flexibility in control strategies. However, problems associated with mixture formation are responsible for soot emissions, one of the most limiting factors of this technology. Therefore, the combustion process and soot formation were investigated with different injection strategies on a gasoline direct injection (GDI) engine. The experimental analysis was realized on an optically accessible single cylinder engine when applying single, double and triple injection strategies. Moreover, the effect of fuel delivery phasing was also scrutinized by changing the start of the injection during late intake- and early compression-strokes. The duration of injection was split in different percentages between two or three pulses, so as to obtain close to stoichiometric operation in all conditions. The engine was operated at fixed rotational speed and spark timing, with wide-open throttle. Optical diagnostics based on cycle resolved digital imaging was applied during the early and late stages of the combustion process. Detailed information on the flame front morphology and soot formation were obtained. The optical data were correlated to in-cylinder pressure traces and exhaust gas emission measurements. The results suggest that the split injection of the fuel has advantages in terms of reduction of soot formation and NOx emissions and a similar combustion performance with respect to the single injection timing. Moreover, an early injection resulted in higher rates of heat release and in-cylinder pressure, together with a reduction of soot formation and flame distortion. The double injection strategy with higher percentage of fuel injected in the first pulse and early second injection pulse showed the best results in terms of combustion evolution and pollutant emissions. For the operative condition studied, a higher time for mixture homogenization and split of fuel injected in the intake stroke shows the best results.
2
Ax, Holger, Oliver Lammel, Rainer Lückerath, and Michael Severin. "High-Momentum Jet Flames at Elevated Pressure, C: Statistical Distribution of Thermochemical States Obtained From Laser-Raman Measurements." Journal of Engineering for Gas Turbines and Power 142, no. 7 (July 1, 2020). http://dx.doi.org/10.1115/1.4045483.
Повний текст джерелаАнотація:
Abstract A detailed investigation on flame structures and stabilization mechanisms of confined high momentum jet flames by one-dimensional (1D)-laser Raman measurements is presented. The flames were operated with natural gas (NG) at gas turbine relevant conditions in an optically accessible high-pressure test rig. The generic burner represents a full scale single nozzle of a high temperature FLOX® gas turbine combustor including a pilot stage. 1D-laser Raman measurements were performed on both an unpiloted and a piloted flame and evaluated on a single shot basis revealing the thermochemical states from unburned inflow conditions to burned hot gas in terms of average and statistical values of the major species concentrations, the mixture fraction and the temperature. The results show a distinct difference in the flame stabilization mechanism between the unpiloted and the piloted case. The former is apparently driven by strong mixing of fresh unburned gas and recirculated hot burned gas that eventually causes autoignition. The piloted flame is stabilized by the pilot stage followed by turbulent flame propagation. The findings help to understand the underlying combustion mechanisms and to further develop gas turbine burners following the FLOX concept.
3
Welch, Cooper, Lars Illmann, Marius Schmidt, Andreas Dreizler, and Benjamin Böhm. "Experimental evaluation of spark behavior under diluted conditions in an optically accessible engine." International Journal of Engine Research, October 18, 2023. http://dx.doi.org/10.1177/14680874231197492.
Повний текст джерелаАнотація:
An optically accessible single-cylinder spark-ignition engine operated under homogeneous, part-load conditions is experimentally investigated using optical and spark diagnostics to evaluate the relationship between the spark, flow, and flame with increasing dilution using several levels of exhaust gas recirculation (EGR). Voltage and current measurements of the secondary spark circuit are compared with simultaneous high-speed spark plasma imaging, particle image velocimetry measurements of the flow field, and burned gas images. Specifically, characteristic restrike cycles and normal cycles are examined under the 0 % EGR and 12.9 % EGR conditions to reveal a relationship between the magnitude and direction of the velocity near the spark plug and the spark’s behavior coupled with that of the subsequent flame propagation. Through the use of conditional statistics and correlation analysis of data sets of all non-restrike and all restrike cycles, the horizontal velocity across the spark gap was identified as a critical quantity in facilitating more stable and faster combustion under diluted mixture conditions.
4
Leschowski, Martin, Thomas Dreier, and Christof Schulz. "A Standard Burner for High Pressure Laminar Premixed Flames: Detailed Soot Diagnostics." Zeitschrift für Physikalische Chemie 229, no. 5 (January 28, 2015). http://dx.doi.org/10.1515/zpch-2014-0631.
Повний текст джерелаАнотація:
AbstractSoot formation and oxidation in high-pressure combustion is of high practical relevance but still sparsely investigated because of its experimental complexity. In this work we present a high-pressure burner for studying sooting premixed flames at pressures up to 30 bar. An optically accessible vessel houses a burner that stabilizes a rich premixed ethylene/air flame on a porous sintered stainless-steel plate. The flame is surrounded by a non-sooting rich methane/air flame and an air coflow for reducing temperature gradients, buoyancy-induced instabilities, and heat loss of the innermost flame. Spectrally-resolved soot pyrometry was used for determining gas temperatures. These were introduced into model functions to fit the temporal signal decay curves obtained from two-color time-resolved laser-induced incandescence (TiRe-LII) measurements for extracting soot volume fractions and mean particle size as a function of height above burner and gas pressure. The derived mean particle sizes and soot concentrations were compared against thermophoretically sampled soot analyzed via transmission electron microscopy (TEM) and laser extinction measurements at 785 nm, respectively. Soot volume fractions derived from LII peak signal intensities need to be corrected for signal attenuation at the high soot concentrations present in the investigated flame. From the various heat conduction models employed in deriving mean soot particle diameters from TiRe-LII, the Fuchs model gave remarkably good agreement with TEM on sampled soot at various heights above the burner.
5
Severin, Michael, Oliver Lammel, Holger Ax, Rainer Lückerath, Wolfgang Meier, Manfred Aigner, and Johannes Heinze. "High Momentum Jet Flames at Elevated Pressure: Detailed Investigation of Flame Stabilization With Simultaneous Particle Image Velocimetry and OH-LIF." Journal of Engineering for Gas Turbines and Power 140, no. 4 (November 7, 2017). http://dx.doi.org/10.1115/1.4038126.
Повний текст джерелаАнотація:
A model FLOX® combustor, featuring a single high momentum premixed jet flame, has been investigated using laser diagnostics in an optically accessible combustion chamber at a pressure of 8 bar. The model combustor was designed as a large single eccentric nozzle main burner (Ø 40 mm) together with an adjoining pilot burner and was operated with natural gas. To gain insight into the flame stabilization mechanisms with and without piloting, simultaneous particle image velocimetry (PIV) and OH laser-induced fluorescence (LIF) measurements have been performed at numerous two-dimensional (2D) sections of the flame. Additional OH-LIF measurements without PIV particles were analyzed quantitatively resulting in absolute OH concentrations and temperature fields. The flow field looks rather similar for both the unpiloted and the piloted cases, featuring a large recirculation zone next to the high momentum jet. However, flame shape and position change drastically. For the unpiloted case, the flame is lifted and widely distributed. Isolated flame kernels are found at the flame root in the vicinity of small-scale vortices. For the piloted flame, on the other hand, both pilot and main flame are attached to the burner base plate, and flame stabilization seems to take place on much smaller spatial scales with a connected flame front and no isolated flame kernels. The single-shot analysis gives rise to the assumption that for the unpiloted case, small-scale vortices act like the pilot burner flow in the opposed case and constantly impinge and ignite the high momentum jet at its root.
6
Wahls, Benjamin Harvey, and Srinath Ekkad. "Temperature reconstruction of an axisymmetric enclosed reactive flow using simultaneous background oriented schlieren and infrared thermography." Measurement Science and Technology, July 25, 2022. http://dx.doi.org/10.1088/1361-6501/ac83e2.
Повний текст джерелаАнотація:
Abstract The temperature distribution of a premixed methane air flame running at a Reynolds number of 1300 on a circular burner, 12.7mm diameter, enclosed in a fused silica cylindrical liner has been experimentally reconstructed using a non-invasive approach combining Background Oriented Schlieren (BOS) and Infrared (IR) thermography. BOS is used to characterize both the air ambient to the system, using an existing technique called 3D ray tracing, and the reactive flow inside the enclosure, with a novel modified version of 3D ray tracing. IR thermography is used to characterize the thermal/optical characteristics of the quartz glass enclosure itself since the information is required as BOS is a line of sight imaging technique. Out of necessity, an approximated species independent relationship is used to calculate flow temperature from refractive index. A simulation is used to show this error is in the range of 5.8%-7%. Additionally, it is found that drastically simplifying the approach by removing the IR thermography system entirely and using the near outer wall air temperature from BOS/3D ray tracing to characterize the internal temperature of the quartz liner itself only causes a 1.5%-3.8% degradation in the accuracy of the reconstructed temperature field. The technique as presented is a relatively inexpensive, experimentally simple approach capable of determining the steady state temperature characteristics of optically accessible axisymmetric reactive flows.
7
Gobin, Bradley, Paul Reiter, Sean Whalen, and Gregory Young. "Extinguishing and Combustion Characteristics of Electrically Controllable Solid Propellants Under Elevated Pressures." Journal of Propulsion and Power, October 24, 2023, 1–12. http://dx.doi.org/10.2514/1.b39189.
Повний текст джерелаАнотація:
An experimental study was conducted on electrically controllable solid propellants (ECSPs) created using a polyethylene oxide polymer binder, lithium perchlorate, and multiwalled carbon nanotubes. The propellants decompose and ignite shortly after the application of a voltage potential and extinguish when the voltage is removed under atmospheric conditions. The ignition delay as a function of the applied voltage magnitude was determined for a range of ECSP compositions. Pressurized experiments were conducted in an optically accessible strand burner to characterize the burning properties of the ECSPs as a function of pressure and electrical power. Additional experiments were conducted at elevated pressures where the voltage potential was removed and reapplied to extinguish and reignite the propellant and determine the self-extinction limits of the ECSPs. The results demonstrate that small compositional changes can drastically impact the ability to extinguish the ECSPs at elevated pressures.
8
Meier, Ulrich, Johannes Heinze, Stefan Freitag, and Christoph Hassa. "Spray and Flame Structure of a Generic Injector at Aeroengine Conditions." Journal of Engineering for Gas Turbines and Power 134, no. 3 (December 30, 2011). http://dx.doi.org/10.1115/1.4004262.
Повний текст джерелаАнотація:
In support of the development of CFD for aeroengine combustion, quantitative measurements of spray properties and temperature were made. A generic swirling air blast injector was designed and built to produce well defined inlet conditions and for ease of numerical description for the CFD development. The measurements were performed in an optically accessible single sector combustor at pressures of 4 and 10 bar and preheat temperatures of 550 and 650 K, respectively. Jet A-1 was used as fuel. The burner air to fuel ratio was 20 and the pressure loss was set to 3%. Sauter mean diameter profiles and liquid mass flux distributions were generated from the phase Doppler anemometry measurements of the evaporating spray drop sizes and velocities. With planar measurements of Mie scattering and kerosene-LIF, the distribution of kerosene (liquid and vapor phase) was imaged. Temperatures were measured with OH-LIF. The burner was designed with a straight outlet to exhibit lifted flames. Hence initial distributions of size, velocity and density of the spray were measured before it entered the flame. Almost complete prevaporization was seen at least for the four bar flame. Compared with atmospheric investigations, the smaller diameters of the droplets and the small streamline curvature of the configuration led to a more uniform behavior of the spray.
9
Tartsch, Simon, Saskia Flebbe, Joao Germano Marques de Sousa Ponte, and Thomas Sattelmayer. "Effect of Fuel Reactivity and Operating Conditions On Flame Anchoring in the Premixing Zone of a Swirl Stabilized Gas Turbine Combustor." Journal of Engineering for Gas Turbines and Power, October 7, 2023, 1–24. http://dx.doi.org/10.1115/1.4063688.
Повний текст джерелаАнотація:
Abstract Flashback with subsequent flame anchoring (FA) is an inherent risk of lean premixed gas turbine combustors operated with highly reactive fuel. The present study has been performed to characterize flame stabilization in the premixing zone of a lean premixed swirl stabilized burner and to identify critical combustion characteristics. An optically accessible burner was used for experimental investigations under atmospheric pressure and elevated preheat temperatures. The air mass flow rate, global equivalence ratio and preheat temperature were systematically varied to identify critical operating parameters. Hydrogen-natural gas mixtures with hydrogen mass fractions from 15 to 100 % were studied to evaluate the impact of fuel reactivity. The air-fuel mixture was ignited with a focused single laser pulse to trigger FA in the premixing zone during steady operation. High speed imaging with OH*-chemiluminescence were applied to observe flame characteristics and evaluate flame anchoring propensity. Flame anchoring limits (FAL) are reported in terms of the minimum global equivalence ratio at which the flame was blown out of the premixing zone within a critical time period. A comparison of characteristic time scales at FAL shows that the main impact during flame anchoring is given by the fuel reactivity and to some extent by preheat temperature. A Damköhler criterion is derived from the FAL that allows prediction of FA propensity based on operating conditions and 1-D reacting simulations.
10
Genova, Tommy, Michelle Otero, Jonathan Reyes, Scott Martin, and Kareem Ahmed. "Partial Premixing Effects on the Reacting Jet of a High-Pressure Axially Staged Combustor." Journal of Engineering for Gas Turbines and Power 143, no. 3 (February 8, 2021). http://dx.doi.org/10.1115/1.4049700.
Повний текст джерелаАнотація:
Abstract The effects of partial premixing on a reacting jet-in-crossflow is investigated in a five atmosphere axially staged combustor at stationary gas turbine relevant conditions. The facility consists of a dump style headend burner that provides a crossflow with a quasi-uniform velocity and temperature profile to the axial stage to isolate the effects of the jet-in-crossflow. The headend burner is run with methane and air at a lean equivalence ratio to match industry emission standards. For this work, the total air to the headend and axial stage is kept constant, and fuel is split between the headend and axial stage to represent different gas turbine loading conditions. For the cases analyzed, the fuel split to the axial stage went up to 25%. The axial stage consists of an optically accessible test section with a coaxial injector that provides variability to how long the methane and air can mix before entering the facility. Three different premixed levels are studied: fully premixed, nonpremixed, and partially premixed. The flow-field characteristics of the reacting jet-in-crossflow are analyzed using particle image velocimetry (PIV), and flame behavior is quantified by employing CH* chemiluminescence. NO measurements are made at the exit of the facility using a Horiba emissions analyzer. Two different flames are observed: flames that burn in the leeward recirculation region and flames that burn at the core of the jet.
11
Gövert, Simon, Johannes Berger, Jonathan T. Lipkowicz, Thomas Soworka, Christoph Hassa, Thomas Behrendt, and Bertram Janus. "Experimental and Numerical Investigation of Hydrogen Combustion in a Dual-Swirl Burner for Aero-Engine Applications." Journal of Engineering for Gas Turbines and Power, July 11, 2024, 1–12. http://dx.doi.org/10.1115/1.4065925.
Повний текст джерелаАнотація:
Abstract Green hydrogen produced by electrolysis offers a high potential for reducing CO2 emissions and thus represents a promising approach for the decarbonization of aviation. However, propulsion systems based on direct hydrogen combustion require modified fuel injectors and combustion chambers to account for the particular combustion characteristics of hydrogen. Engineering those modifications requires the acquisition of experimental and numerical tools especially suited for this task and in the end validating them in a suitable environment. In this context, hydrogen combustion and its numerical simulation is presented with a dual-swirl burner in an optically accessible atmospheric combustor as an intermediate step. To ensure safe operation and to reduce the risk of flashback, fuel and air are injected non-premixed. Good flame stability and mixing, which leads to potentially low NOx values, is achieved by introducing a swirling motion into the flows. In this study, the combustor is operated under atmospheric pressure at a globally lean equivalence ratio. Measurements of OH* radical chemiluminescence as well as infrared radiation as marker of the hot water vapor distribution have been carried out to identify the flame location and shape. The configuration is further analyzed by means of reacting Large-Eddy-Simulations. The comparison of the simulation results with the experimental reference data shows that the flame lift of height and global flame spread are correctly predicted by the simulation for both operating conditions. However, the combustion model does not precisely capture the flame stabilization mechanism, leading to a radial offset of the flame front.
12
Morovatiyan, Mohammadrasool, Martia Shahsavan, Jonathan Aguilar, and J. Hunter Mack. "Effect of Argon Concentration on Laminar Burning Velocity and Flame Speed of Hydrogen Mixtures in a Constant Volume Combustion Chamber." Journal of Energy Resources Technology 143, no. 3 (August 27, 2020). http://dx.doi.org/10.1115/1.4048019.
Повний текст джерелаАнотація:
Abstract Hydrogen combustion, coupled with the use of argon as a working fluid, is a promising approach to delivering clean and efficient energy from internal combustion (IC) engines. The use of hydrogen-oxygen-argon (H2/O2/Ar) mixtures in combustion aids in mitigating harmful environmental pollutants and enables a highly efficient energy conversion process. The use of argon as a working fluid decreases the NOx emissions and increases the thermal efficiency of internal combustion engines due to the high specific heat ratio of noble gases. In this study, premixed hydrogen combustion was investigated with the purpose of examining the effect of the full or partial substitution of argon for nitrogen in air on laminar burning velocity (LBV), flame speed, flame morphology, and instability. The experimental approach uses an optically accessible constant volume combustion chamber (CVCC) with central ignition; the spherical flame development was studied using a high-speed Z-type Schlieren visualization system. Moreover, a numerical model was developed to convert the experimental dynamic pressure rise data to laminar burning velocity. Coupling the model to a chemical equilibrium code aids in determining the burned gas properties. Additionally, an image processing technique has been suggested to compute the flame propagation speed. The experimental and numerical investigations indicate that increasing the concentration of argon as the working fluid in the mixture increases the laminar burning velocity and flame speed while extending the lean flammability limit.
13
Beerer, David, Vincent McDonell, Peter Therkelsen, and Robert K. Cheng. "Flashback and Turbulent Flame Speed Measurements in Hydrogen/Methane Flames Stabilized by a Low-Swirl Injector at Elevated Pressures and Temperatures." Journal of Engineering for Gas Turbines and Power 136, no. 3 (November 5, 2013). http://dx.doi.org/10.1115/1.4025636.
Повний текст джерелаАнотація:
This paper reports flashback limits and turbulent flame local displacement speed measurements in flames stabilized by a low swirl injector operated at elevated pressures and inlet temperatures with hydrogen and methane blended fuels. The goal of this study is to understand the physics that relate turbulent flame speed to flashback events at conditions relevant to gas turbine engines. Testing was conducted in an optically accessible single nozzle combustor rig at pressures ranging from 1 to 8 atm, inlet temperatures from 290 to 600 K, and inlet bulk velocities between 20 and 60 m/s for natural gas and a 90%/10% (by volume) hydrogen/methane blend. The propensity of flashback is dependent upon the proximity of the lifted flame to the nozzle that is itself dependent upon pressure, inlet temperature, and bulk velocity. Flashback occurs when the leading edge of the flame in the core of the flow ingresses within the nozzle, even in cases when the flame is attached to the burner rim. In general the adiabatic flame temperature at flashback is proportional to the bulk velocity and inlet temperature and inversely proportional to the pressure. The unburned reactant velocity field approaching the flame was measured using a laser Doppler velocimeter with water seeding. Turbulent displacement flame speeds were found to be linearly proportional to the root mean square of the velocity fluctuations about the mean velocity. For identical inlet conditions, high-hydrogen flames had a turbulent flame local displacement speed roughly twice that of natural gas flames. Pressure, inlet temperature, and flame temperature had surprisingly little effect on the local displacement turbulent flame speed. However, the flow field is affected by changes in inlet conditions and is the link between turbulent flame speed, flame position, and flashback propensity.
14
Tiwari, Arpit, Preethi Nanjundan, Ravi Ranjan Kumar, and Vijay Kumar Soni. "A framework for natural resource management with geospatial machine learning: a case study of the 2021 Almora forest fires." Fire Ecology 20, no. 1 (August 27, 2024). http://dx.doi.org/10.1186/s42408-024-00293-9.
Повний текст джерелаАнотація:
Abstract Background Wildfires have a substantial impact on air quality and ecosystems by releasing greenhouse gases (GHGs), trace gases, and aerosols into the atmosphere. These wildfires produce both light-absorbing and merely scattering aerosols that can act as cloud condensation nuclei, altering cloud reflectivity, cloud lifetime, and precipitation frequency. Uttarakhand province in India experiences frequent wildfires that affect its protected ecosystems. Thus, a natural resource management system is needed in this region to assess the impact of wildfire hazards on land and atmosphere. We conducted an analysis of a severe fire event that occurred between January and April 2021 in the Kumaun region of Uttarakhand, by utilizing open-source geospatial data. Near-real-time satellite observations of pre- and post-fire conditions within the study area were used to detect changes in land and atmosphere. Supervised machine learning algorithm was also implemented to estimate burned above ground biomass (AGB) to monitor biomass stock. Results The study found that 21.75% of the total burned area burned with moderate to high severity, resulting in a decreased Soil Adjusted Vegetation Index value (> 0.3), a reduced Normalized Differential Moisture Index value (> 0.4), and a lowered Normalized Differential Vegetation Index (> 0.5). The AGB estimate demonstrated a significant simple determination (r2 = 0.001702) and probability (P < 2.2 10−16), along with a positive correlation (r ≤ 0.24) with vegetation and soil indices. The algorithm predicted that 17.56 tonnes of biomass per hectare burned in the Kumaun forests. This fire incident resulted in increased emissions of carbon dioxide (CO2; ~ 0.8 10−4 kg carbon h−1), methane (CH4; ~ 200 10−9 mol fraction in dry air), carbon monoxide (CO; 2000 1015 molecules cm−2 total column), and formaldehyde (HCHO; 3500 1013 molecules cm−2 total column), along with increased aerosol optical thickness (varying from 0.2 to 0.5). Conclusions We believe that our proposed operational framework for managing natural resources and assessing the impact of natural hazards can be used to efficiently monitor near-real-time forest-fire-caused changes in land and atmosphere. This method makes use of openly accessible geospatial data that can be employed for several objectives, including monitoring carbon stocks, greenhouse gas emissions, criterion air pollution, and radiative forcing of the climate, among many others. Our proposed framework will assist policymakers and the scientific community in mitigating climate change problems and in developing adaptation policies.
15
Duva, B. C., L. E. Chance, and E. Toulson. "Effect of CO2 Dilution on the Laminar Burning Velocities of Premixed Methane/Air Flames at Elevated Temperature." Journal of Engineering for Gas Turbines and Power 142, no. 3 (February 3, 2020). http://dx.doi.org/10.1115/1.4044641.
Повний текст джерелаАнотація:
Abstract With increased interest in reducing emissions, the staged combustion concept for gas turbine combustors is gaining in popularity. For this work, the effect of CO2 dilution on laminar burning velocities of premixed methane/air flames was investigated at elevated temperature through both experiments and numerical simulations. Validation of the experimental setup and methodology was completed through experimental testing of methane/air mixtures at 1 bar and 298 K. Following validation, high temperature experiments were conducted in an optically accessible constant volume combustion chamber at 1 bar and 473 K. Laminar burning velocities of premixed methane/air flames with 0%, 5%, 10%, and 15% CO2 dilution were determined using the constant pressure method enabled via schlieren visualization of the spherically propagating flame front. Results show that laminar burning velocities of methane/air mixtures at 1 bar increase by 106–145% with initial temperature increases from 298 K to 473 K. Additions of 5%, 10%, and 15% CO2 dilution at 1 bar and 473 K cause a 30–35%, 51–54%, and 66–68% decrease in the laminar burning velocity, respectively. Numerical results were obtained with CHEMKIN (Kee et al., 1985, “PREMIX: A Fortran Program for Modeling Steady Laminar One-Dimensional Premixed Flames,”) using the GRI-Mech 3.0 (Smith et al., 2019) and the San Diego (“Chemical-Kinetic Mechanisms for Combustion Applications,” San Diego Mechanism Web Page, Mechanical and Aerospace Engineering (Combustion Research), University of California at San Diego, San Diego, CA) mechanisms. It is concluded that the GRI-Mech 3.0 (Smith et al.., 2019) better captures the general overall trend of the experimental laminar flame speeds of methane/air/CO2 mixtures at 1 bar and 473 K. Additionally, the dilution, thermal-diffusion, and chemical effects of CO2 on the laminar burning velocities of methane/air mixtures were investigated numerically by diluting the mixtures with both chemically active and inactive CO2 following the determination of the most important elementary reactions on the burning rate through sensitivity analysis. Finally, it was shown that CO2 dilution suppresses the flame instabilities during combustion, which is attributable to the increase in the burned gas Markstein length (Lb) with the addition of diluent.