Статті в журналах з теми "Morpholino Monomers"

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1

Paul, Sibasish, Bappaditya Nandi, Sankha Pattanayak, and Surajit Sinha. "Synthesis of 5-alkynylated uracil–morpholino monomers using Sonogashira coupling." Tetrahedron Letters 53, no. 32 (August 2012): 4179–83. http://dx.doi.org/10.1016/j.tetlet.2012.05.141.

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2

Paul, Sibasish, Santanu Jana, Jhuma Bhadra, and Surajit Sinha. "Photophysical studies and submicron ring formation of morpholino U-nucleoside monomers." Chemical Communications 49, no. 96 (2013): 11278. http://dx.doi.org/10.1039/c3cc45082a.

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3

Paul, Sibasish, Bappaditya Nandi, Sankha Pattanayak, and Surajit Sinha. "ChemInform Abstract: Synthesis of 5-Alkynylated Uracil-Morpholino Monomers Using Sonogashira Coupling." ChemInform 43, no. 47 (October 30, 2012): no. http://dx.doi.org/10.1002/chin.201247164.

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4

Vejlegaard, Kim, Sibasish Paul, Tamer Kosbar, Jesper Wengel, and Marvin H. Caruthers. "Oligodeoxynucleotides containing 2′-amino-LNA nucleotides as constrained morpholino phosphoramidate and phosphorodiamidate monomers." Bioorganic & Medicinal Chemistry Letters 27, no. 14 (July 2017): 3173–76. http://dx.doi.org/10.1016/j.bmcl.2017.05.023.

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5

Pattanayak, Sankha, Sibasish Paul, Bappaditya Nandi, and Surajit Sinha. "Improved Protocol for the Synthesis of Flexibly Protected Morpholino Monomers from Unprotected Ribonucleosides." Nucleosides, Nucleotides and Nucleic Acids 31, no. 11 (November 2012): 763–82. http://dx.doi.org/10.1080/15257770.2012.724491.

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6

Cale, Jessica M., Kane Greer, Sue Fletcher, and Steve D. Wilton. "Proof-of-Concept: Antisense Oligonucleotide Mediated Skipping of Fibrillin-1 Exon 52." International Journal of Molecular Sciences 22, no. 7 (March 27, 2021): 3479. http://dx.doi.org/10.3390/ijms22073479.

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Анотація:
Marfan syndrome is one of the most common dominantly inherited connective tissue disorders, affecting 2–3 in 10,000 individuals, and is caused by one of over 2800 unique FBN1 mutations. Mutations in FBN1 result in reduced fibrillin-1 expression, or the production of two different fibrillin-1 monomers unable to interact to form functional microfibrils. Here, we describe in vitro evaluation of antisense oligonucleotides designed to mediate exclusion of FBN1 exon 52 during pre-mRNA splicing to restore monomer homology. Antisense oligonucleotide sequences were screened in healthy control fibroblasts. The most effective sequence was synthesised as a phosphorodiamidate morpholino oligomer, a chemistry shown to be safe and effective clinically. We show that exon 52 can be excluded in up to 100% of FBN1 transcripts in healthy control fibroblasts transfected with PMO52. Immunofluorescent staining revealed the loss of fibrillin 1 fibres with ~50% skipping and the subsequent re-appearance of fibres with >80% skipping. However, the effect of exon skipping on the function of the induced fibrillin-1 isoform remains to be explored. Therefore, these findings demonstrate proof-of-concept that exclusion of an exon from FBN1 pre-mRNA can result in internally truncated but identical monomers capable of forming fibres and lay a foundation for further investigation to determine the effect of exon skipping on fibrillin-1 function.
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7

Nandi, Bappaditya, Sankha Pattanayak, Sibasish Paul, and Surajit Sinha. "Synthesis of Nucleobase-Functionalized Morpholino-Modified Nucleoside Monomers Through Palladium-Catalyzed Cross-Coupling Reactions." European Journal of Organic Chemistry 2013, no. 7 (January 18, 2013): 1271–86. http://dx.doi.org/10.1002/ejoc.201201384.

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8

Pattanayak, Sankha, Sibasish Paul, Bappaditya Nandi, and Surajit Sinha. "ChemInform Abstract: Improved Protocol for the Synthesis of Flexibly Protected Morpholino Monomers from Unprotected Ribonucleosides." ChemInform 44, no. 17 (April 4, 2013): no. http://dx.doi.org/10.1002/chin.201317042.

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9

Nandi, Bappaditya, Sankha Pattanayak, Sibasish Paul, and Surajit Sinha. "ChemInform Abstract: Synthesis of Nucleobase-Functionalized Morpholino-Modified Nucleoside Monomers Through Palladium-Catalyzed Cross-Coupling Reactions." ChemInform 44, no. 35 (August 8, 2013): no. http://dx.doi.org/10.1002/chin.201335159.

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10

Grigale-Soročina, Zane, Elina Vindedze, Julija Kozela, and Ingmārs Birks. "Evaluation of Reactive Diluent Impact on Stability of Systems Viscosity in UV-Curable Compositions." Solid State Phenomena 320 (June 30, 2021): 150–54. http://dx.doi.org/10.4028/www.scientific.net/ssp.320.150.

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This study investigated the impact of various reactive diluents on viscosity of uncured mixture at 50 °C over a 12-week period. This criterion is important to predict the shelf life of uncured composition. Studied mono-functional acrylate monomers were: hydroxypropyl methacrylate (HPMA), hydroxyethyl methacrylate (HEMA), tetrahydrofurfuryl acrylate (THFA), isobornyl methacrylate (IBOMA), isobornyl acrylate (IBOA), 2-(2-Ethoxyethoxy)ethyl acrylate (EOEOEA), acryloyl morpholine (ACMO), glacial methacrylic acid (GMAA) and phosphate acrylate monomer (PAM); and various solvents: isopropanol(IP) ethyl acetate (EA), butyl acetate (BA). There was found the difference of effect on the systems viscosity in time between the mono-functional monomers and solvents. HPMA and IPA showed the most stable viscosity values in time.
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11

Huang, Weiwei, and Jin-Ho Jang. "Photografting of PET Fabrics with Vinyl Pyrrolidone and Acryloyl Morpholine Monomers." Textile Coloration and Finishing 20, no. 5 (October 27, 2008): 28–34. http://dx.doi.org/10.5764/tcf.2008.20.5.028.

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12

Ozcan, Fatma, Zekeriya Dogruyol, and Sevnur Keskin Dogruyol. "4-methyl-4-[2-(naphthalene)-2-oxoethyl] morpholin-4-ium iodide as a water soluble photoinitiator." Polimery 68, no. 4 (June 27, 2023): 215–20. http://dx.doi.org/10.14314/polimery.2023.4.3.

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Quaternary ammonium salt namely 4-methyl-4-[2-(naphthalen-2-yl)-2-oxoethyl] morpholin-4-ium iodide (WSMPM) was synthesized and characterized. High molar absorptivity at 347 nm (1910 L・mol-1・cm-1) and good solubility in distilled water (10-2 M) allows WSMPM to be used as an effective photoinitiator also in water-soluble systems. Photopolymerization of acrylamide monomer with WSMPM (10-3 M) and a tertiary amine (N-methyldiethanolamine), resulted in 84.4% monomer to polymer conversion. Based on laser photolysis and electron spin resonance, a photoinitiator mechanism was proposed.
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13

Peng, Xingzhou, Marc Behl, Pengfei Zhang, Magdalena Mazurek-Budzyńska, Yakai Feng, and Andreas Lendlein. "Synthesis and Characterization of Multiblock Poly(Ester-Amide-Urethane)s." MRS Advances 2, no. 47 (2017): 2551–59. http://dx.doi.org/10.1557/adv.2017.486.

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ABSTRACTIn this study, a multiblock copolymer containing oligo(3-methyl-morpholine-2,5-dione) (oMMD) and oligo(3-sec-butyl-morpholine-2,5-dione) (oBMD) building blocks obtained by ring-opening polymerization (ROP) of the corresponding monomers, was synthesized in a polyaddition reaction using an aliphatic diisocyanate. The multiblock copolymer (pBMD-MMD) provided a molecular weight of 40,000 g·mol−1, determined by gel permeation chromatography (GPC). Incorporation of both oligodepsipeptide segments in multiblock copolymers was confirmed by 1H NMR and Matrix Assisted Laser Desorption/Ionization Time Of Flight Mass Spectroscopy (MALDI-TOF MS) analysis. pBMD-MMD showed two separated glass transition temperatures (61 °C and 74 °C) indicating a microphase separation. Furthermore, a broad glass transition was observed by DMTA, which can be attributed to strong physical interaction i.e. by H-bonds formed between amide, ester, and urethane groups of the investigated copolymers. The obtained multiblock copolymer is supposed to own the capability to exhibit strong physical interactions.
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14

Aldea, Anca, Ana-Maria Albu, Alina Nicolescu, and Victorita Tecuceanu. "Kinetics of Free Radical Polymerization of N-Substituted Amides and Their Structural Implications." Advances in Materials Science and Engineering 2016 (2016): 1–9. http://dx.doi.org/10.1155/2016/6430416.

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Two N-substituted amides (N-acryloyl morpholine and N-methyl-N-vinylacetamide) were polymerized in different solvents using radical initiator. The tacticity of obtained polymers was determined by 400 MHz1H-NMR and13C-NMR. At a given temperature, the syndiotacticity increased with increasing the solvent polarity. This solvent effect may be related to the hydrogen bonding interaction among solvent, monomer, and/or growing species. A peculiar aspect regards the steric hindrance at the nitrogen atom.
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15

Ince, Ahmet, and Niyazi Bicak. "Crosslinking Copolymerization of Vinyl Monomers Using Non-Vinyl Crosslinker: Morpholine Substituted Poly (vinyl methyl ketone)." Macromolecular Symposia 352, no. 1 (June 2015): 38–41. http://dx.doi.org/10.1002/masy.201400149.

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16

Sameni, Farzaneh, Basar Ozkan, Sarah Karmel, Daniel S. Engstrøm, and Ehsan Sabet. "Large Scale Vat-Photopolymerization of Investment Casting Master Patterns: The Total Solution." Polymers 14, no. 21 (October 29, 2022): 4593. http://dx.doi.org/10.3390/polym14214593.

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The material properties and processing of investment casting patterns manufactured using conventional wax injection Molding and those manufactured by vat photopolymerization can be substantially different in terms of thermal expansion and mechanical properties, which can generate problems with dimensional accuracy and stability before and during ceramic shelling and shell failures during the burn-out of the 3D printed casting patterns. In this paper and for the first time, the monofunctional Acryloyl morpholine monomer was used for 3D printing of casting patterns, due to its thermoplastic-like behavior, e.g., softening by heat. However, the hydrophilic behavior of this polymer led to an incorporation of up to 60 wt% of Hexanediol diacrylate, to control the water absorption of the network, which to some extent, compromised the softening feature of Acryloyl morpholine. Addition of a powdered wax filler resulted in a delayed thermal decomposition of the polymer network, however, it helped to reduce the thermal expansion of the parts. The dimensional accuracy and stability of the wax-filled formulation indicated an excellent dimensional tolerance of less than ±130 µm. Finally, the 3D printed patterns successfully went through a burn out process with no damages to the ceramic shell.
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17

Li, Shao-Lu, Pengfei Wu, Juntao Wang, Jing Wang, and Yunxia Hu. "Fabrication of high performance polyamide reverse osmosis membrane from monomer 4-morpholino-m-phenylenediamine and tailoring with zwitterions." Desalination 473 (January 2020): 114169. http://dx.doi.org/10.1016/j.desal.2019.114169.

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18

Vejjasilpa, Ketpat, Iram Maqsood, Michaela Schulz-Siegmund, and Michael C. Hacker. "Adjustable Thermo-Responsive, Cell-Adhesive Tissue Engineering Scaffolds for Cell Stimulation through Periodic Changes in Culture Temperature." International Journal of Molecular Sciences 24, no. 1 (December 29, 2022): 572. http://dx.doi.org/10.3390/ijms24010572.

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A three-dimensional (3D) scaffold ideally provides hierarchical complexity and imitates the chemistry and mechanical properties of the natural cell environment. Here, we report on a stimuli-responsive photo-cross-linkable resin formulation for the fabrication of scaffolds by continuous digital light processing (cDLP), which allows for the mechano-stimulation of adherent cells. The resin comprises a network-forming trifunctional acrylate ester monomer (trimethylolpropane triacrylate, or TMPTA), N-isopropyl acrylamide (NiPAAm), cationic dimethylaminoethyl acrylate (DMAEA) for enhanced cell interaction, and 4-acryloyl morpholine (AMO) to adjust the phase transition temperature (Ttrans) of the equilibrium swollen cross-polymerized scaffold. With glycofurol as a biocompatible solvent, controlled three-dimensional structures were fabricated and the transition temperatures were adjusted by resin composition. The effects of the thermally induced mechano-stimulation were investigated with mouse fibroblasts (L929) and myoblasts (C2C12) on printed constructs. Periodic changes in the culture temperature stimulated the myoblast proliferation.
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19

Clay, Anthony M., Joshua R. Mitchell, Zachary R. Boelter, and John J. La Scala. "Superior Properties through Feedstock Development for Vat Photopolymerization Additive Manufacturing of High-Performance Biobased Feedstocks." Materials 14, no. 17 (August 26, 2021): 4843. http://dx.doi.org/10.3390/ma14174843.

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Vat photopolymerization additive manufacturing (Vat AM) technologies have found niche industrial use being able to produce personalized parts in moderate quantity. However, Vat AM lacks in its ability to produce parts of satisfactory thermal and mechanical properties for structural applications. The purpose of this investigation was to develop high-performance resins with glass transition temperatures (Tg) above 200 °C for Vat AM, evaluate the properties of the produced thermosets and establish a structure–property relationship of the thermosets produced. Herein, we have developed SLA-type resins that feature bio-derived monomer hesperetin trimethacrylate (HTM) synthesized from the flavonone hesperetin. Diluents 4-acryloyl morpholine, styrene, 4-methyl styrene and 4-tert butylstyrene (tbutylsty) were photocured with HTM as the monomer and all produced thermosets with Tg values above 200 °C. Investigations of suitable crosslinkers urethane dimethacrylate, the vinyl ester CN 151 and Ebecryl 4859 (Eb4859) showed that each crosslinker displayed different benefits when formulated with HTM as the monomer and tbutylSty as the diluent (HTM:crosslinker:tbutylSty with mass ratio 2:1:2). The crosslinker CN 151 produced the thermoset of greatest onset of thermal decomposition temperature (T0) of 352 °C. Eb4859 produced the thermoset of highest tensile strength, 19 ± 7 MPa, amongst the set of varied crosslinkers. The formulation featuring UDM (HTM:UDM:tbutysty) offered ease of processing and was seemingly the easiest to print. Investigations of reactive diluent showed that styrene produced the thermoset of the highest extent of cure and the overall highest tensile strength, 25 ± 5 MPa, while tbutylSty produced the thermoset with the greatest Tan-δ Tg, 231 °C. HTM was synthesized, formulated with diluents, crosslinkers and initiators. The HTM resins were then 3D printed to produce thermosets of Tg values greater than 200 °C. The polymer properties were evaluated and a structure–reactivity relationship was discussed.
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20

Sielaff, Bernhard, and Jan R. Andreesen. "Analysis of the nearly identical morpholine monooxygenase-encoding mor genes from different Mycobacterium strains and characterization of the specific NADH : ferredoxin oxidoreductase of this cytochrome P450 system." Microbiology 151, no. 8 (August 1, 2005): 2593–603. http://dx.doi.org/10.1099/mic.0.28039-0.

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Cloning and sequencing of the morABC operon region revealed the genes encoding the three components of a cytochrome P450 monooxygenase, which is required for the degradation of the N-heterocycle morpholine by Mycobacterium sp. strain HE5. The cytochrome P450 (P450mor) and the Fe3S4 ferredoxin (Fdmor), encoded by morA and morB, respectively, have been characterized previously, whereas no evidence has hitherto been obtained for a specifically morpholine-induced reductase, which would be required to support the activity of the P450mor system. Analysis of the mor operon has now revealed the gene morC, encoding the ferredoxin reductase of this morpholine monooxygenase. The genes morA, morB and morC were identical to the corresponding genes from Mycobacterium sp. strain RP1. Almost identical mor genes in Mycobacterium chlorophenolicum PCP-1, in addition to an inducible cytochrome P450, pointing to horizontal gene transfer, were now identified. No evidence for a circular or linear plasmid was found in Mycobacterium sp. strain HE5. Analysis of the downstream sequences of morC revealed differences in this gene region between Mycobacterium sp. strain HE5 and Mycobacterium sp. strain RP1 on the one hand, and M. chlorophenolicum on the other hand, indicating insertions or deletions after recombination. Downstream of the mor genes, the gene orf1′, encoding a putative glutamine synthetase, was identified in all studied strains. The gene morC of Mycobacterium sp. strain HE5 was heterologously expressed. The purified recombinant protein FdRmor was characterized as a monomeric 44 kDa protein, being a strictly NADH-dependent, FAD-containing reductase. The K m values of FdRmor for the substrate NADH (37·7±4·1 μM) and the artificial electron acceptors potassium ferricyanide (14·2±1·1 μM) and cytochrome c (28·0±3·6 μM) were measured. FdRmor was shown to interact functionally with its natural redox partner, the Fe3S4 protein Fdmor, and with the Fe2S2 protein adrenodoxin, albeit with a much lower efficiency, but not with spinach ferredoxin. In contrast, adrenodoxin reductase, the natural redox partner of adrenodoxin, could not use Fdmor in activity assays. These results indicated that FdRmor can utilize different ferredoxins, but that Fdmor requires the specific NADH : ferredoxin oxidoreductase FdRmor from the P450mor system for efficient catalytic function.
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21

Shi, Chang-Xia, Yu-Ting Guo, Yu-Huan Wu, Zhao-Yue Li, Yao-Zong Wang, Fu-Sheng Du, and Zi-Chen Li. "Synthesis and Controlled Organobase-Catalyzed Ring-Opening Polymerization of Morpholine-2,5-Dione Derivatives and Monomer Recovery by Acid-Catalyzed Degradation of the Polymers." Macromolecules 52, no. 11 (May 29, 2019): 4260–69. http://dx.doi.org/10.1021/acs.macromol.8b02498.

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22

Angira, Deekshi, Althaf Shaik, Sivapriya Kirubakaran, and Vijay Thiruvenkatam. "Exploring a solvated dimer of Gefitinib: a quantitative analysis." Acta Crystallographica Section C Structural Chemistry 74, no. 8 (July 19, 2018): 944–50. http://dx.doi.org/10.1107/s2053229618009671.

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Gefitinib or Iressa is an orally administered anilinoquinazoline used in cancer chemotherapy for the treatment of lung and breast cancer. It is reported to exist in two polymorphic forms, a stable form I and a metastable form II. Both of the forms belong to the triclinic P\overline{1} space group. In this work, we report the crystallization of Gefitinib to form a methanol solvate [systematic name: N-(3-chloro-4-fluorophenyl)-7-methoxy-6-[3-(morpholin-4-yl)propoxy]quinazolin-4-amine methanol hemisolvate, C22H24ClFN4O3·0.5CH3OH] that was theoretically and experimentally investigated. The unit cell is composed of two independent Gefitinib molecules (A and B) that form a stable molecular complex with methanol in the crystal lattice. To understand the crystal lattice stabilization, a combination of techniques, namely X-ray diffraction, IR spectroscopy, thermogravimetric/differential scanning calorimetry (TG-DSC), Hirshfeld surface analysis and CLP-PIXEL methods were used. The analysis of the crystal structure of this dimer revealed a three-dimensional isostructurality with the already reported form II. The A and B molecules are connected via trifurcated C—H...O and N—H...O hydrogen bonding. In addition, the presence of the methanol molecule stabilizes the crystal structure via C—H...O, N—H...O and C—H...Cl interactions between the two monomers. The IR analysis of the dimer has shown characteristic fingerprint values when compared to the commercial form. The TG-DSC analysis of the solvated dimer is in good agreement with the patent reporting cocrystals of Gefitinib. Finally, theoretical calculations by the CLP-PIXEL method and Hirshfeld surface and two-dimensional (2D) fingerprint plot analysis were carried out in order to quantify the different intermolecular interactions and their energies in the crystal packing.
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23

Morozova, Sofia M., Alexander S. Shaplov, Elena I. Lozinskaya, Petr S. Vlasov, Haritz Sardon, David Mecerreyes, and Yakov S. Vygodskii. "Poly(ionic liquid)-based polyurethanes having imidazolium, ammonium, morpholinium or pyrrolidinium cations." High Performance Polymers 29, no. 6 (April 10, 2017): 691–703. http://dx.doi.org/10.1177/0954008317701551.

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The synthesis of cationic polyelectrolytes based on condensation-derived backbone is rarely performed due to the difficulty obtaining of the respective ionic monomers in high purity. Despite such an approach is favorable as it results in ionic polymers with well-defined chemical structure and ionic group distribution. In this work two efficient methods are presented for the synthesis of ionic diols in high purity, namely the technique with pyranyl protection of OH-groups and the direct quaternization of tertiary amine alcohols. Applying these methods five novel ionic diols bearing various cations, namely, 1,1-bis(2-hydroxyethyl)pyrrolidin-1-ium bromide, 4,4-bis(2-hydroxyethyl)morpholin-4-ium bromide, N, N-bis(2-hydroxyethyl)-N-methylethanammonium, 1,1′-(pentane-1,5-diyl)bis(1-(2-hydroxyethyl)pyrrolidin-1-ium) dibromide, and 3-(2-hydroxyethyl)-1-(5-(3-(3-hydroxypropyl)-1H-imidazol-3-ium-1-yl)pentyl)-1H-imidazol-3-ium dibromide, were synthesized in high purity and high yields. The tin(II) mediated solution polycondensation of ionic diols with commercial hexamethylene diisocyanate or 4,4′-methylenebis(cyclohexyl isocyanate) resulted in a series of ionic, high molecular weight ( Mw = 2.3 × 104 −8.0 × 104) polyurethanes (PUs). The influence of various reaction parameters including reaction temperature and time, catalyst concentration and solvent nature upon PUs molecular weight was investigated. After the exchange of bromide to (CF3SO2)2N- anion the obtained poly(ionic liquid)s exhibit high thermal stability with onset mass loss above 225°C and demonstrate glass transition temperatures in the wide range from −22°C to 76°C depending on the nature of ionic diol used. Ionic PUs present excellent solubility in most organic solvents and are capable to form tough, flexible films with tensile strength up to 29.7 MPa.
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24

Venediktov, E. A., E. Yu Tulikova та V. E. Maizlish. "Photogeneration of singlet molecular oxygen (1O2, 1Δ g ) using monomeric and aggregated forms of copper tetra-4-(morpholine-4-yl)-tetra-5-(2-naphthoxy)phthalocyanine in organic solvents". Russian Journal of General Chemistry 82, № 6 (червень 2012): 1145–52. http://dx.doi.org/10.1134/s1070363212060187.

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25

Papis, Marta, Camilla Loro, Michele Penso, Gianluigi Broggini, and Francesca Foschi. "Synthesis of Morpholino Nucleosides Starting From Enantiopure Glycidol." Organic Chemistry Frontiers, 2022. http://dx.doi.org/10.1039/d2qo00400c.

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Анотація:
A protocol for the synthesis of modified morpholino monomers was performed in few steps through the condensation between 6-hydroxymethyl-morpholine acetal and nucleobases under Lewis acid conditions. The key common precursor...
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26

Bhadra, Jhuma, Sankha Pattanayak, and Surajit Sinha. "Synthesis of Morpholino Monomers, Chlorophosphoramidate Monomers, and Solid‐Phase Synthesis of Short Morpholino Oligomers." Current Protocols in Nucleic Acid Chemistry 62, no. 1 (September 2015). http://dx.doi.org/10.1002/0471142700.nc0465s62.

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27

Das, Arnab, Atanu Ghosh, and Surajit Sinha. "C5-Pyrimidine-Functionalized Morpholino Oligonucleotides Exhibit Differential Binding Affinity, Target Specificity and Lipophilicity." Organic & Biomolecular Chemistry, 2023. http://dx.doi.org/10.1039/d2ob01759h.

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C5-substituted uridine and cytidine morpholino chlorophosphoramidate monomers were synthesized and incorporated into a 12-mer Phosphorodiamidate Morpholino Oligonucleotide (PMO) using semi-automated solid phase synthesis. 5-Substituted pyrimidines incorporated PMO significantly increase the...
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28

Kundu, Jayanta, Ujjwal Ghosh, Atanu Ghosh, Sankha Pattanayak, Arnab Das, and Surajit Sinha. "Synthesis of Chlorophosphoramidate Monomer Morpholinos and PMOs." Current Protocols 3, no. 2 (February 2023). http://dx.doi.org/10.1002/cpz1.686.

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29

DU PREEZ, J. G. H., T. I. A. GERBER, and O. KNOESEN. "ChemInform Abstract: THE CHEMISTRY OF RHENIUM AND TECHNETIUM. PART IV. FACILE CLEAVAGE OF THE TECHNETIUM-OXYGEN DOUBLE BOND IN THE OXOTETRACHLOROTECHNETIUM(V) ANION BY MORPHOLINE-N-CARBODITHIOATE TO YIELD THE EIGHT-COORDINATE MONOMERIC TETRACARBODITHIOATE." Chemischer Informationsdienst 16, no. 36 (September 10, 1985). http://dx.doi.org/10.1002/chin.198536273.

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