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Готові списки джерел за темами / Modular catalysis / Статті в журналах

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Статті в журналах з теми "Modular catalysis"

Автор: Grafiati

Опубліковано: 19 квітня 2025

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1

Khettar, Ibrahim, Alicja Malgorzata Araszczuk, and Rosaria Schettini. "Peptidomimetic-Based Asymmetric Catalysts." Catalysts 13, no. 2 (2023): 244. http://dx.doi.org/10.3390/catal13020244.

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Анотація:

Despite the great advantages of peptidomimetic scaffolds, there are only a few examples of their application in the field of asymmetric catalysis. Peptidomimetic scaffolds offer numerous advantages related to their easy preparation, modular and tunable structures, and biomimetic features, which make them well suited as chiral catalysts. This review underlines the structure–function relationship for catalytic properties towards efficient enantioselective catalysis.

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2

Burk, Mark J. "Modular Phospholane Ligands in Asymmetric Catalysis." Accounts of Chemical Research 33, no. 6 (2000): 363–72. http://dx.doi.org/10.1021/ar990085c.

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3

Llorente, Nuria, Héctor Fernández-Pérez, José L. Núñez-Rico, et al. "Efficient modular phosphorus-containing ligands for stereoselective catalysis." Pure and Applied Chemistry 91, no. 1 (2019): 3–15. http://dx.doi.org/10.1515/pac-2018-0805.

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Abstract Over several years, our research team has contributed to ligand design for metal-catalyzed stereoselective transformations. This has been achieved with the synthesis and application to organic transformations of interest of an array of structurally diverse P-containing ligands. These range from highly modular enantiopure phosphine–phosphite ligands to supramolecularly regulated enantioselective phosphorus-based catalysts. Our research in supramolecular interactions has also led to the discovery of an unprecedented halogen-bonded rhodium-catalyst.

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4

Burk, Mark J. "ChemInform Abstract: Modular Phospholane Ligands in Asymmetric Catalysis." ChemInform 31, no. 36 (2010): no. http://dx.doi.org/10.1002/chin.200036267.

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5

Lin, Wenbin. "Metal-Organic Frameworks for Asymmetric Catalysis and Chiral Separations." MRS Bulletin 32, no. 7 (2007): 544–48. http://dx.doi.org/10.1557/mrs2007.104.

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Metal-organic frameworks (MOFs) are an interesting class of molecule-based hybrid materials built from metal-connecting points and bridging ligands. MOFs have received much attention, owing to their potential impact on many technological areas, including gas storage, separation, and heterogeneous catalysis. The modular nature of MOFs endows them with facile tunability, and as a result, properly designed MOFs can yield ideal heterogeneous catalysts with uniform active sites through judicious choice of the building blocks. Homochiral MOFs, which can be prepared by numerous approaches (constructi

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6

Geri, Jacob B., Joanna L. Ciatti, and Nathaniel K. Szymczak. "Charge effects regulate reversible CO2 reduction catalysis." Chemical Communications 54, no. 56 (2018): 7790–93. http://dx.doi.org/10.1039/c8cc04370a.

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Modular but geometrically constrained ligands were used to investigate the impact of key ligand design parameters (charge and bite angle) on CO<sub>2</sub> hydrogenation and formic acid dehydrogenation activity.

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7

Dimian, Alexandre C., and Gadi Rothenberg. "An effective modular process for biodiesel manufacturing using heterogeneous catalysis." Catalysis Science & Technology 6, no. 15 (2016): 6097–108. http://dx.doi.org/10.1039/c6cy00426a.

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8

Delpont, Nicolas, Imma Escofet, Patricia Pérez-Galán, et al. "Modular chiral gold(i) phosphite complexes." Catalysis Science & Technology 3, no. 11 (2013): 3007. http://dx.doi.org/10.1039/c3cy00250k.

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9

Xiong, Thao M., Edzna S. Garcia, Junfeng Chen, Lingyang Zhu, Ariale J. Alzona, and Steven C. Zimmerman. "Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors." Chemical Communications 58, no. 7 (2022): 985–88. http://dx.doi.org/10.1039/d1cc05578j.

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10

Schramm, Michael, Cindy Pham, Michelle Park, Jenny Pham, and Sadie Martin. "Modular Preparation of Diverse Dipyrrolemethanes." Synthesis 45, no. 09 (2013): 1165–73. http://dx.doi.org/10.1055/s-0032-1318503.

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11

Abet, Valentina, Robert Evans, Florian Guibbal, Stefano Caldarelli, and Raphaël Rodriguez. "Modular Construction of Dynamic Nucleodendrimers." Angewandte Chemie International Edition 53, no. 19 (2014): 4862–66. http://dx.doi.org/10.1002/anie.201402400.

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12

Loch, Jennifer A., and Robert H. Crabtree. "Rapid screening and combinatorial methods in homogeneous organometallic catalysis." Pure and Applied Chemistry 73, no. 1 (2001): 119–28. http://dx.doi.org/10.1351/pac200173010119.

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Анотація:

Methods are discussed for rapid screening of soluble and polymer-bound homo-geneous catalysts for activity. A polymer-bound phosphine library is synthesized, and a modular tridentate pincer CNC bis-carbene Pd complex is described. The possibility of C-bound His in metalloenzymes is raised.

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13

van Slagmaat, Christian A. M. R., Khi Chhay Chou, Lukas Morick, Darya Hadavi, Burgert Blom, and Stefaan M. A. De Wildeman. "Synthesis and Catalytic Application of Knölker-Type Iron Complexes with a Novel Asymmetric Cyclopentadienone Ligand Design." Catalysts 9, no. 10 (2019): 790. http://dx.doi.org/10.3390/catal9100790.

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Asymmetric catalysis is an essential tool in modern chemistry, but increasing environmental concerns demand the development of new catalysts based on cheap, abundant, and less toxic iron. As a result, Knölker-type catalysts have emerged as a promising class of iron catalysts for various chemical transformations, notably the hydrogenation of carbonyls and imines, while asymmetric versions are still under exploration to achieve optimal enantio-selectivities. In this work, we report a novel asymmetric design of a Knölker-type catalyst, in which the C2-rotational symmetric cyclopentadienone ligand

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14

Zipse, Hendrik, Ingmar Held, and Shangjie Xu. "Modular Design of Pyridine-Based Acyl-Transfer Catalysts." Synthesis 2007, no. 8 (2007): 1185–96. http://dx.doi.org/10.1055/s-2007-965973.

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15

Reuland, Steven N., Alexander P. Vlasov, and Sergey A. Krupenko. "Modular organization of FDH: Exploring the basis of hydrolase catalysis." Protein Science 15, no. 5 (2006): 1076–84. http://dx.doi.org/10.1110/ps.052062806.

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16

Chen, Bin, Yunxing Zhang, Rui Wu, et al. "Modular Synthesis of 2,8-Dioxabicyclo[3.2.1]octanes by Sequential Catalysis." ACS Catalysis 9, no. 12 (2019): 11788–93. http://dx.doi.org/10.1021/acscatal.9b04183.

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17

Uchida, Masaki, Kimberly McCoy, Masafumi Fukuto, et al. "Modular Self-Assembly of Protein Cage Lattices for Multistep Catalysis." ACS Nano 12, no. 2 (2017): 942–53. http://dx.doi.org/10.1021/acsnano.7b06049.

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18

Andersen, Nalin I., Kateryna Artyushkova, Ivana Matanović, et al. "Modular Microfluidic Paper‐Based Devices for Multi‐Modal Cascade Catalysis." ChemElectroChem 6, no. 9 (2019): 2448–55. http://dx.doi.org/10.1002/celc.201900211.

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19

Blackmore, Caroline E., Neil V. Rees, and Richard E. Palmer. "Modular construction of size-selected multiple-core Pt–TiO2 nanoclusters for electro-catalysis." Physical Chemistry Chemical Physics 17, no. 42 (2015): 28005–9. http://dx.doi.org/10.1039/c5cp00285k.

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20

Đokić, Miloš, and Han Sen Soo. "Artificial photosynthesis by light absorption, charge separation, and multielectron catalysis." Chemical Communications 54, no. 50 (2018): 6554–72. http://dx.doi.org/10.1039/c8cc02156b.

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Анотація:

We highlight recent novel approaches in the field of artificial photosynthesis. We emphasize the potential of a highly modular plug-and-play concept that we hope will persuade the community to explore a more inclusive variety of multielectron redox catalysis to complement the proton reduction and water oxidation half-reactions in traditional solar water splitting systems.

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21

Stojanovic, Milan N., and Dmitry M. Kolpashchikov. "Modular Aptameric Sensors." Journal of the American Chemical Society 126, no. 30 (2004): 9266–70. http://dx.doi.org/10.1021/ja032013t.

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22

Mann, Samuel I., Tillmann Heinisch, Andrew C. Weitz, Michael P. Hendrich, Thomas R. Ward, and A. S. Borovik. "Modular Artificial Cupredoxins." Journal of the American Chemical Society 138, no. 29 (2016): 9073–76. http://dx.doi.org/10.1021/jacs.6b05428.

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23

Barluenga, Sofia, Pilar Lopez, Emilie Moulin, and Nicolas Winssinger. "Modular Asymmetric Synthesis of Pochonin C." Angewandte Chemie International Edition 43, no. 26 (2004): 3467–70. http://dx.doi.org/10.1002/anie.200454108.

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24

Mesnage, Stéphane, and Agnès Fouet. "Plasmid-Encoded Autolysin in Bacillus anthracis: Modular Structure and Catalytic Properties." Journal of Bacteriology 184, no. 1 (2002): 331–34. http://dx.doi.org/10.1128/jb.184.1.331-334.2002.

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ABSTRACT A Bacillus anthracis virulence plasmid-encoded peptidoglycan hydrolase (AmiA) with sequence similarity to N-acetylmuramoyl-l-alanine amidases hydrolyzes peptidoglycan independently of cell wall binding. Residues H341, E355, H415, and E486 are absolutely required for catalysis. Many AmiA paralogs are fused to different sorting signals, suggesting that these modular proteins result from domain shuffling.

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25

Yang, Hai-Bin, Zhi-Hou Wang, Jin-Mei Li та Chuande Wu. "Modular synthesis of α-aryl β-perfluoroalkyl ketones via N-heterocyclic carbene catalysis". Chemical Communications 56, № 26 (2020): 3801–4. http://dx.doi.org/10.1039/d0cc00293c.

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26

Stibingerova, Iva, Svatava Voltrova, Sarka Kocova, Matthew Lindale, and Jiri Srogl. "Modular Approach to Heterogenous Catalysis. Manipulation of Cross-Coupling Catalyst Activity." Organic Letters 18, no. 2 (2015): 312–15. http://dx.doi.org/10.1021/acs.orglett.5b03480.

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27

Jacobsen, Christian Borch, Daniel Steen Nielsen, Morten Meldal, and Frederik Diness. "Azotides as Modular Peptide-Based Ligands for Asymmetric Lewis Acid Catalysis." Journal of Organic Chemistry 84, no. 11 (2019): 6940–45. http://dx.doi.org/10.1021/acs.joc.9b00732.

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28

Hahn, Björn T, Friederike Tewes, Roland Fröhlich, and Frank Glorius. "Olefin-Oxazolines (OlefOx): Highly Modular, Easily Tunable Ligands for Asymmetric Catalysis." Angewandte Chemie International Edition 49, no. 6 (2010): 1143–46. http://dx.doi.org/10.1002/anie.200905712.

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29

Pandey, Ramesh Prasad, and Jae Kyung Sohng. "In Vitro Type I Modular Polyketide Synthase Catalysis for New Antibiotics." Bulletin of the Korean Chemical Society 39, no. 4 (2018): 421–22. http://dx.doi.org/10.1002/bkcs.11416.

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30

Reed, Kevin B., and Hal S. Alper. "Modular biocatalysis for polyamines." Nature Catalysis 4, no. 6 (2021): 449–50. http://dx.doi.org/10.1038/s41929-021-00636-8.

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31

Zhang, Bohan, Silei Bai, Xiangyu Chao, et al. "Molecularly pure miktoarm spherical nucleic acids: preparation and usage as a scaffold for abiotic intracellular catalysis." Chemical Science 12, no. 48 (2021): 15843–48. http://dx.doi.org/10.1039/d1sc04833c.

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32

Casertano, Marcello, Brian G. Kelly, Malachi W. Gillick-Healy, Paolo Grieco, and Mauro F. A. Adamo. "Synthesis of Indole-Based Derivatives Containing Ammonium Salts, Diamines and Aminoureas for Organocatalysis." Organics 6, no. 2 (2025): 15. https://doi.org/10.3390/org6020015.

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Indole heterocycles have an established reactivity, and these compounds are H-bond donors via a peculiar non-basic NH. However, the indole core has been scarcely employed in organocatalysis, with only a few examples relevant to electrophilic halogenation reported. To expand the range of potential transformations achievable via indole catalysis, we have designed a set of new organic species incorporating an indole core, alongside three privelaged chiral moieties found in many known organocatalysts, namely a quaternary ammonium salt, a diamine and an amino-urea. Herein, we report an optimised sy

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33

Straub, Bernd, Michael Bessel, and Frank Rominger. "Modular Trimethylene-Linked Bisimidazol(in)ium Salts." Synthesis 2010, no. 09 (2010): 1459–66. http://dx.doi.org/10.1055/s-0029-1218702.

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34

Hirschhäuser, Christoph, Claire A. Haseler, and Timothy Gallagher. "Core Modification of Cytisine: A Modular Synthesis." Angewandte Chemie International Edition 50, no. 22 (2011): 5162–65. http://dx.doi.org/10.1002/anie.201100441.

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35

Szymański, Wiktor, Willem A. Velema, and Ben L. Feringa. "Photocaging of Carboxylic Acids: A Modular Approach." Angewandte Chemie International Edition 53, no. 33 (2014): 8682–86. http://dx.doi.org/10.1002/anie.201402665.

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36

Tanaka, Yoshie, Hiroshi Katagiri, Yoshio Furusho, and Eiji Yashima. "A Modular Strategy to Artificial Double Helices." Angewandte Chemie International Edition 44, no. 25 (2005): 3867–70. http://dx.doi.org/10.1002/anie.200501028.

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37

Xu, Kaidi, Zhi‐Yuan Zhang, Chengmao Yu, et al. "A Modular Synthetic Strategy for Functional Macrocycles." Angewandte Chemie International Edition 59, no. 18 (2020): 7214–18. http://dx.doi.org/10.1002/anie.202000909.

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38

Paul, Avishek, Eliza M. Warszawik, Mark Loznik, Arnold J. Boersma, and Andreas Herrmann. "Modular and Versatile Trans‐Encoded Genetic Switches." Angewandte Chemie International Edition 59, no. 46 (2020): 20328–32. http://dx.doi.org/10.1002/anie.202001372.

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39

Nagy, Krisztina S., Krisztina Toth, Eva Pallinger, et al. "Folate-Targeted Monodisperse PEG-Based Conjugates Made by Chemo-Enzymatic Methods for Cancer Diagnosis and Treatment." International Journal of Molecular Sciences 22, no. 19 (2021): 10347. http://dx.doi.org/10.3390/ijms221910347.

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This paper focuses on preliminary in vitro and in vivo testing of new bivalent folate-targeted PEGylated doxorubicin (DOX) made by modular chemo-enzymatic processes (FA2-dPEG-DOX2). A unique feature is the use of monodisperse PEG (dPEG). The modular approach with enzyme catalysis ensures exclusive γ-conjugation of folic acid, full conversion and selectivity, and no metal catalyst residues. Flow cytometry analysis showed that at 10 µM concentration, both free DOX and FA2-dPEG-DOX2 would be taken up by 99.9% of triple-negative breast cancer cells in 2 h. Intratumoral injection to mice seemed to

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40

Woods, R. Jeremy, Justin O. Brower, Elena Castellanos та ін. "Cyclic Modular β-Sheets". Journal of the American Chemical Society 129, № 9 (2007): 2548–58. http://dx.doi.org/10.1021/ja0667965.

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41

Oltra, Núria Sancho, and Gerard Roelfes. "Modular assembly of novel DNA-based catalysts." Chemical Communications, no. 45 (2008): 6039. http://dx.doi.org/10.1039/b814489c.

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42

Beaupérin, Matthieu, Radomyr Smaliy, Hélène Cattey, et al. "Modular functionalized polyphosphines for supported materials: previously unobserved31P-NMR «through-space» ABCD spin systems and heterogeneous palladium-catalysed C–C and C–H arylation." Chem. Commun. 50, no. 67 (2014): 9505–8. http://dx.doi.org/10.1039/c4cc04307c.

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43

Evans, P. Andrew, Mai-Jan Tom, and Ben W. H. Turnbull. "A Concise and Modular Three-Step Synthesis of (S)-Verapamil using an Enantioselective Rhodium-Catalyzed Allylic Alkylation Reaction." Synthesis 52, no. 15 (2020): 2185–89. http://dx.doi.org/10.1055/s-0040-1707390.

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A concise and modular asymmetric synthesis of the calcium channel blocker (S)-verapamil is described. This approach employs an enantioselective rhodium-catalyzed allylic alkylation reaction between an α-isopropyl-substituted benzylic nitrile and allyl benzoate to construct the challenging acyclic quaternary stereocenter. The terminal olefin then serves as a convenient synthetic handle for a hydroamination to introduce the phenethylamine moiety, furnishing (S)-verapamil in three steps and 55% overall yield, thus providing the most efficient synthesis of this important pharmaceutical reported to

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44

Peng, Yaguang, Qiang Tan, Hongliang Huang, et al. "Customization of functional MOFs by a modular design strategy for target applications." Chemical Synthesis 2, no. 3 (2022): 15. http://dx.doi.org/10.20517/cs.2022.15.

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Herein, we propose a versatile “functional modular assembly” strategy for customizing MOFs that allows installing the desired functional unit into a host material. The functional unit could be switched according to different applications. MOF-808, a highly stable Zr-MOF containing dangling formate groups, was selected as a host material for demonstration. Functional molecules with carboxyl connectors can be directly inserted into MOF-808 to form functional modular MOFs (FM-MOFs) through single substitution, while for those without carboxyl connectors, a pre-designed convertor was grafted first

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45

Taniguchi, Ryo, Naoki Noto, Seiya Tanaka та ін. "Simple generation of various α-monofluoroalkyl radicals by organic photoredox catalysis: modular synthesis of β-monofluoroketones". Chemical Communications 57, № 21 (2021): 2609–12. http://dx.doi.org/10.1039/d0cc08060h.

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46

Talbot, Fabien J. T., Shibo Zhang, Bishnupada Satpathi, et al. "Modular Synthesis of Stereodefined Benzocyclobutene Derivatives via Sequential Cu- and Pd-Catalysis." ACS Catalysis 11, no. 23 (2021): 14448–55. http://dx.doi.org/10.1021/acscatal.1c04496.

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47

Dong, Zhe, Gang Lu, Jianchun Wang, Peng Liu, and Guangbin Dong. "Modular ipso/ortho Difunctionalization of Aryl Bromides via Palladium/Norbornene Cooperative Catalysis." Journal of the American Chemical Society 140, no. 27 (2018): 8551–62. http://dx.doi.org/10.1021/jacs.8b04153.

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48

Liu, Haoying, Weijun Tang, Jianliang Xiao, and Chao Wang. "Cyclometallated Chiral Ru Complexes with a Single Labile Coordination Site for Asymmetric Reduction of Amino Ketones." Organic Chemistry Frontiers, 2025. https://doi.org/10.1039/d5qo00284b.

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Анотація:

The development of versatile and selective catalysts is crucial for asymmetric catalysis. Modular chiral Ru complexes featuring a single labile coordination site (SLCS) and cyclometallation have been designed and synthesized....

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49

van Koten, Gerard, Arjan W. Kleij, Rob van de Coevering, et al. "Modular Approaches Towards Metallodendritic Homogeneous Catalysis." ChemInform 34, no. 27 (2003). http://dx.doi.org/10.1002/chin.200327262.

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50

Matich, Olivia, Mohinder Maheshbhai Naiya, Joanne Salam, Bryan Andres Tiban Anrango, and Jack Li-Yang Chen. "Modular Assembly and Optimization of an Artificial Esterase from Functionalized Surfactants." ChemCatChem, June 21, 2024. http://dx.doi.org/10.1002/cctc.202400945.

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Анотація:

A strategy for the screening and optimization of an artificial esterase is presented that utilizes the self‐assembly of amphiphilic molecules. Unlike conventional approaches that rely on the attachment of key functional groups onto molecular scaffolds or surfaces, the modular assembly of amphiphiles allows a large number of catalytic combinations to be investigated with minimal synthetic effort. In this study, iterative combinatorial screens led to an optimized esterase comprising amphiphiles that act as a nucleophilic catalyst, an oxyanion hole and a metal ion chelator. Cooperativity is obser

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