Дисертації з теми "Mineral trace elements"
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Peters, James C. "Evaluating the efficacy of dietary organic and inorganic trace minerals in reproducing female pigs on reproductive performance and body mineral composition." Columbus, Ohio : Ohio State University, 2006. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1141661190.
Повний текст джерелаTanner, Dominique. "In situ mineral geochemistry as a guide to ore-forming processes." Phd thesis, Canberra, ACT : The Australian National University, 2014. http://hdl.handle.net/1885/125140.
Повний текст джерелаMorrison, Elizabeth. "The contribution of Australian wheat and wheat products essential trace mineral intake." Thesis, Queensland University of Technology, 1996. https://eprints.qut.edu.au/36731/1/36731_Morrison_1996.pdf.
Повний текст джерелаMartins, Lucelene. "Geração e migração de magmas graníticos na crosta continental: estudos de detalhe em granitos e migmatitos da região de Nazaré Paulista (SP)." Universidade de São Paulo, 2006. http://www.teses.usp.br/teses/disponiveis/44/44135/tde-19042007-155618/.
Повний текст джерелаThe conditions of melt generation and migration in the continental crust were investigated through a detailed study of two outcrops of the anatectic Nazaré Paulista granites (Socorro-Guaxupé, Nappe, Atibaia region, SE Brazil), using as main tools the rock and mineral major and trace-element geochemistry and Sr-Nd isotopy. The Nazaré Paulista granite shows a wide compositional variation, and can be grouped into two main types: a garnet leucogranite and a veined grey garnet-biotite granite, the latter dated at ~625 Ma (monazite U-Pb ID-TIMS). These types occur as subconcordant bodies 10-50 m wide and are present in both outcrops; where observed, the contact relationships show that the garnet leucogranites intruded after the grey granites. Two types of leucosome were recognized in migmatitic paragneisses associated to the Nazaré Paulista granites: (1) garnet-biotite tonalite with low Rb/Sr (0.3 ), slightly fractionated REE patterns ((La/Yb)N = 4-5) with negative Eu anomalies and Sr-Nd isotope signature identical to that of the mesosome; and (2) garnet leucogranite, with Rb/Sr ~0.56, slightly fractionated REE patterns ((La/Yb)N ~ 5) with positive Eu anomalies, eNd(t) identical to that of the mesosome, but lower 87Sr/86Sr(t). Both leucosomes are different from the granites, and were interpreted as the products of water-present melting of the paragneiss, respectively before and after the crystallization of K-feldspar in the protolith. Some relevant geochemical contrasts are observed between the two types of Nazaré Paulista granites: compared to the leucogranites, the gray granites show greater mg# and Zr and more fractionated REE patterns; the Rb/Sr ratios of both are low (0.4-0.7). The Sr-Nd isotope signature has important variations (eNd(t) = -16 to -13 and 87Sr/86Sr(t) = 0.716-0.728); only two leucogranite samples have signatures that are coincident with the field of the regional paragneisses. Assuming the paragneisses as the only source of the Nazaré Paulista granites would require that melting occurred under disequilibrium and water-present conditions. The trace-element chemistry of garnet was important to identify the differentiation processes that respond for the observed variety of anatectic granites. Part of the gray granites carries a restitic component, represented by ETRP+Y-rich garnet cores that are similar to the garnets from the country-rock paragneisses. The garnet leucogranite veins that cut the gray granite were probably formed by \"partial remelting\" of the original mush during rapid ascent, their idiomorphic garnet crystals have a distinctive composition (low HREE in the cores, increasing slightly to the rims), interpreted as magmatic. Some of the leucogranites forming isolated bodies may have been generated by fractionation from the gray granite, as indicated by field relations and rock geochemistry. On the other hand, the leucogranite with high 87Sr/86Sr(t) has ETRP+Y-rich garnet cores and its monazite is compositionally similar to that of the paragneisses, features indicative that they were probably produced by direct melting of these rocks.
Hill, David T. "Removal of trace elements from coal using a multiple-property processing circuit." Thesis, This resource online, 1994. http://scholar.lib.vt.edu/theses/available/etd-01242009-063125/.
Повний текст джерелаMarozas, Dianne Catherine. "The effects of mineral reactions on trace metal characteristics of groundwater in desert basins of southern Arizona." Diss., The University of Arizona, 1987. http://hdl.handle.net/10150/191127.
Повний текст джерелаNel, Marika Verita. "The influence of coal-associated trace elements on sintering and agglomeration of a model coal mineral mixture / M.V. Nel." Thesis, North-West University, 2009. http://hdl.handle.net/10394/6413.
Повний текст джерелаThesis (Ph.D. (Chemistry))--North-West University, Potchefstroom Campus, 2010.
Ashley, Kyle Thomas. "Constraining Metamorphic and Tectonic Evolution in Convergent Terranes: How Trace Elements and Mineral Inclusions Shape Mechanical and Reconstructive Models." Diss., Virginia Tech, 2015. http://hdl.handle.net/10919/52888.
Повний текст джерелаPh. D.
Will, Sonia Elisabete Alves de Lima. "Avaliação da concentração de elementos traço e respectivos mapas de distribuição em placenta bovina." Universidade de São Paulo, 2010. http://www.teses.usp.br/teses/disponiveis/10/10132/tde-28032011-102928/.
Повний текст джерелаThe healthy and harmonious development of a gestation is directly associated to a balanced fetus nutrition. Some minerals are essential because of their functions developed in the metabolism, maintenance and fetus development. Mineral deficiencies are among the factors that contribute the most for a low productivity of the cattle, generating significant economic loss. Thus, studies that help understand the reasons for a low productivity in cattle are important. The placenta works as a selective barrier to the adequate supply of nutrients during the gestation. The aim of this study was to determine the concentration of trace elements for non-manipulative animals (GCO) and cloned animals (GCL) for gestational periods and to obtain maps of qualitative distribution for the placenta of bovines GCO and GCL. Samples of placenta tissues were selected and grouped in three gestational periods: stage 1, 90 days; stage 2, 135 days; and stage 3, 235 days. All the samples were analyzed for the constituent elements and traces by X Rays Spectrometry. The results obtained in the analyses of placenta tissue bearing constituent elements and trace indicated that the procedures of preparation were adequate. The results indicated significant variations for the elements Na, Mg, P, Cl, K e Ca. The maps of elementary distribution confirmed that the highest elementary concentration occurred in the region of inter-digitation of carunculate vaults of the uterine epithelium and cotiledonary vilosities with trophoblast cells, in the regions of the placentons and endometrial glands of the interplacentomal region, confirming that, in these regions, nutrient exchanges intensify between mother and fetus. For the results obtained in evaluation of the elementary interrelation in relation to the samples of cloned bovine placentons we observed that the maps demonstrated several interrelations between Ca-Fe, Cu-Fe, Zn-Ca, Fe-Zn, Ca-Cu, and Cu-Zn. By these results, we concluded that the chemical analyses were adequate for the determination of the elementary concentration of constituent elements and trace and also that the qualitative analysis of the bi-dimensional maps and correlated maps obtained through experiments with Synchrotron radiation were essential for the discussion on alterations on selected regions and on evaluated periods of gestations.
Moura, e. Silva Francisco César de [UNESP]. "Avaliação dos valores séricos e hepáticos de elementos minerais em novilhas nelore, criadas extensivamente, suplementadas com mistura mineral comercial." Universidade Estadual Paulista (UNESP), 2006. http://hdl.handle.net/11449/89296.
Повний текст джерелаFundação para o Desenvolvimento da UNESP (FUNDUNESP)
O presente trabalho teve como objetivo determinar os elementos minerais no soro sangüíneo (magnésio, cobre, selênio, zinco, fósforo, cálcio, potássio, ferro) e no tecido hepático (cobalto, cobre, selênio, manganês, molibdênio e zinco) em seis diferentes momentos durante um período de dezesseis meses e verificar se houve variação entre eles. Foram utilizadas 25 novilhas mestiças Nelore, com idade média de 18 meses, que permaneceram durante todo o tempo do experimento no mesmo pasto de Brachiaria brizantha. Os animais ainda receberam mistura mineral comercial em cocho coberto e água à vontade e foram submetidos à coleta de fragmentos hepáticos e sangue para obtenção de soro. Análises da pastagem também foram realizadas nos mesmos momentos em que foram colhidas as amostras de soro e fígado (exceto em fevereiro 2003). A água e o sal mineral também foram analisadas. Os níveis médios dos elementos no tecido hepático foram, respectivamente para as seis diferentes colheitas: Co 0,27;0,27; 0,23;0,21; 0,23 e 0,24 ppm; Mn 9,07; 8,55; 8,67; 8,40; 7,90 e 7,25 ppm; Mo 4,18; 3,85; 3,68; 3,32; 3,54; 3,19 ppm; Zn 113,4; 101,94; 97,91; 92,46; 88,29 e 81,74 ppm; Cu 40,76; 36,33; 24,50; 24,70; 77,75 e 128,03 ppm e Se 0,86; 1,09; 0,72; 1,21; 0,91 e 0,75 ppm. Destes, os níveis de Co, Mn, Mo, Se e Zn foram considerados adequados para bovinos. Os níveis médios dos elementos no soro foram, para as quatro diferentes colheitas: Ca 118,72; 129,36; 125,19; 112,90; 96,76; 85,37 mg/L; P 109,28; 106,30; 117,03; 103,39; 115,78 e 107,75 mg/L; Mg 19,75; 23,62; 26,54; 20,96; 20,80 e 23,12 mg/L; K 139,64; 134,85; 114,19; 131,65; 130,57 e 116,60 mg/L; Cu 0,52; 0,73; 0,41; 0,59; 0,60 e 0,73 mg/L; Zn 1,19; 1,87; 1,38; 1,13;1,28 e 1,37 mg/L; Fe 2,52; 3,44; 2,21; 3,08; 3,00 e 2,89 mg/L e Se 1,19; 1,87; 0,19; 0,44, 0,40 e 0,51 mg/L...
The objective of the present work was to determinate the mineral levels in beef cattle blood serum (magnesium, copper, selenium, zinc, phosphorus, calcium, potassium, iron) and liver (cobalt, copper, selenium, manganese, molibdenium and zinc) at six different moments throughout sixteen months, to verify the occurrence of variation among them. Twenty-five half-breed nelore heifers, all of them about 18 months old, stayed during the experiment in the same Brachiaria brizantha pasture. They also received commercial mineral mixture in appropriate feeders and free acess to water. Pasture were also analised at the same moments we did for serum and liver (except february 2003). Water and mineral mixture were analised as well. The average levels of the elements in the liver, respectively for the six different moments: Co 0.27,0.27, 0.23, 0.21, 0.23 and 0.24 ppm; Mn 9.07, 8.55, 8.67, 8.40, 7.90 and 7.25 ppm; Mo 4.18, 3.85, 3.68, 3.32, 3.54, 3.19 ppm; Zn 113.4, 101.94, 97.91, 92.46, 88.29 and 81.74 ppm; Cu 40.76, 36.33, 24.50, 24.70, 77.75 and 128.03 ppm and Se 0.86, 1.09, 0.72, 1.21, 0.91 and 0.75 ppm. The levels of Co, Mn, Mo, Se and Zn were considered appropriate for cattle. The average levels of the elements in the serum were, for the six different moments: Ca 118.72, 129.36, 125.19, 112.90, 96.76, 85.37 mg/L; P 109.28, 106.30, 117.03, 103.39, 115.78 and 107.75 mg/L; Mg 19.75, 23.62, 26.54, 20.96, 20.80 and 23.12 mg/L; K 139.64, 134.85, 114.19, 131.65, 130.57 and 116.60 mg/L; Cu 0.52, 0.73, 0.41, 0.59, 0.60 and 0,73 mg/L; Fe 2,52; 3,44; 2,21; 3,08; 3,00 and 2,89 mg/L; Se 1.19, 1.87, 0.19, 0.44, 0.40 and 0.51 mg/L and Zn 1.19, 1.87, 1.38, 1.13,1.28 and 1.37 mg/L. In the serum, Ca, P, Mg, Zn, Fe and Se levels were considered appropriate for beef cattle. There was correlation between the hepatic and serum levels of Cu...(Complete abstract, click electronic address below)
Peplow, Dan. "The influence of mine waste contamination on invertebrates and fish in the Methow River Valley, Okanogan County, Washington (U.S.A.) /." Thesis, Connect to this title online; UW restricted, 2003. http://hdl.handle.net/1773/5519.
Повний текст джерелаMoura, e. Silva Francisco César de. "Avaliação dos valores séricos e hepáticos de elementos minerais em novilhas nelore, criadas extensivamente, suplementadas com mistura mineral comercial /." Botucatu : [s.n.], 2007. http://hdl.handle.net/11449/89296.
Повний текст джерелаBanca: Márcio Rubens Graaf Kuchembuck
Banca: Ivan Roque de Barros Filho
Resumo: O presente trabalho teve como objetivo determinar os elementos minerais no soro sangüíneo (magnésio, cobre, selênio, zinco, fósforo, cálcio, potássio, ferro) e no tecido hepático (cobalto, cobre, selênio, manganês, molibdênio e zinco) em seis diferentes momentos durante um período de dezesseis meses e verificar se houve variação entre eles. Foram utilizadas 25 novilhas mestiças Nelore, com idade média de 18 meses, que permaneceram durante todo o tempo do experimento no mesmo pasto de Brachiaria brizantha. Os animais ainda receberam mistura mineral comercial em cocho coberto e água à vontade e foram submetidos à coleta de fragmentos hepáticos e sangue para obtenção de soro. Análises da pastagem também foram realizadas nos mesmos momentos em que foram colhidas as amostras de soro e fígado (exceto em fevereiro 2003). A água e o sal mineral também foram analisadas. Os níveis médios dos elementos no tecido hepático foram, respectivamente para as seis diferentes colheitas: Co 0,27;0,27; 0,23;0,21; 0,23 e 0,24 ppm; Mn 9,07; 8,55; 8,67; 8,40; 7,90 e 7,25 ppm; Mo 4,18; 3,85; 3,68; 3,32; 3,54; 3,19 ppm; Zn 113,4; 101,94; 97,91; 92,46; 88,29 e 81,74 ppm; Cu 40,76; 36,33; 24,50; 24,70; 77,75 e 128,03 ppm e Se 0,86; 1,09; 0,72; 1,21; 0,91 e 0,75 ppm. Destes, os níveis de Co, Mn, Mo, Se e Zn foram considerados adequados para bovinos. Os níveis médios dos elementos no soro foram, para as quatro diferentes colheitas: Ca 118,72; 129,36; 125,19; 112,90; 96,76; 85,37 mg/L; P 109,28; 106,30; 117,03; 103,39; 115,78 e 107,75 mg/L; Mg 19,75; 23,62; 26,54; 20,96; 20,80 e 23,12 mg/L; K 139,64; 134,85; 114,19; 131,65; 130,57 e 116,60 mg/L; Cu 0,52; 0,73; 0,41; 0,59; 0,60 e 0,73 mg/L; Zn 1,19; 1,87; 1,38; 1,13;1,28 e 1,37 mg/L; Fe 2,52; 3,44; 2,21; 3,08; 3,00 e 2,89 mg/L e Se 1,19; 1,87; 0,19; 0,44, 0,40 e 0,51 mg/L...(Resumo completo, clicar acesso eletrônico abaixo)
Abstract: The objective of the present work was to determinate the mineral levels in beef cattle blood serum (magnesium, copper, selenium, zinc, phosphorus, calcium, potassium, iron) and liver (cobalt, copper, selenium, manganese, molibdenium and zinc) at six different moments throughout sixteen months, to verify the occurrence of variation among them. Twenty-five half-breed nelore heifers, all of them about 18 months old, stayed during the experiment in the same Brachiaria brizantha pasture. They also received commercial mineral mixture in appropriate feeders and free acess to water. Pasture were also analised at the same moments we did for serum and liver (except february 2003). Water and mineral mixture were analised as well. The average levels of the elements in the liver, respectively for the six different moments: Co 0.27,0.27, 0.23, 0.21, 0.23 and 0.24 ppm; Mn 9.07, 8.55, 8.67, 8.40, 7.90 and 7.25 ppm; Mo 4.18, 3.85, 3.68, 3.32, 3.54, 3.19 ppm; Zn 113.4, 101.94, 97.91, 92.46, 88.29 and 81.74 ppm; Cu 40.76, 36.33, 24.50, 24.70, 77.75 and 128.03 ppm and Se 0.86, 1.09, 0.72, 1.21, 0.91 and 0.75 ppm. The levels of Co, Mn, Mo, Se and Zn were considered appropriate for cattle. The average levels of the elements in the serum were, for the six different moments: Ca 118.72, 129.36, 125.19, 112.90, 96.76, 85.37 mg/L; P 109.28, 106.30, 117.03, 103.39, 115.78 and 107.75 mg/L; Mg 19.75, 23.62, 26.54, 20.96, 20.80 and 23.12 mg/L; K 139.64, 134.85, 114.19, 131.65, 130.57 and 116.60 mg/L; Cu 0.52, 0.73, 0.41, 0.59, 0.60 and 0,73 mg/L; Fe 2,52; 3,44; 2,21; 3,08; 3,00 and 2,89 mg/L; Se 1.19, 1.87, 0.19, 0.44, 0.40 and 0.51 mg/L and Zn 1.19, 1.87, 1.38, 1.13,1.28 and 1.37 mg/L. In the serum, Ca, P, Mg, Zn, Fe and Se levels were considered appropriate for beef cattle. There was correlation between the hepatic and serum levels of Cu...(Complete abstract, click electronic address below)
Mestre
Ma, Yamin. "Vegetation as a biotic driver for the formation of soil geochemical anomalies for mineral exploration of covered terranes." University of Western Australia. School of Earth and Geographical Sciences, 2008. http://theses.library.uwa.edu.au/adt-WU2008.0235.
Повний текст джерелаKIRA, CARMEN S. "Estudo da composicao mineral e dos elementos-traco essenciais em amostras de leite e produtos lacteos por espectrometria de emissao atomica com plasma induzido e analise por ativacao com neutrons." reponame:Repositório Institucional do IPEN, 2002. http://repositorio.ipen.br:8080/xmlui/handle/123456789/11040.
Повний текст джерелаMade available in DSpace on 2014-10-09T14:08:36Z (GMT). No. of bitstreams: 1 08714.pdf: 5593309 bytes, checksum: 07a3421e8c97a3073c8119f90a38d4ac (MD5)
Dissertacao (Mestrado)
IPEN/D
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
Silva, Felipe. "The Effects of Injectable Trace Mineral Supplements in Donor Cows at the Initiation of a Superovulation Protocol on Embryo Outcomes and Pregnancy Rates in Recipient Females." Thesis, North Dakota State University, 2018. https://hdl.handle.net/10365/28856.
Повний текст джерелаNantapo, Carlos Wyson Tawanda. "Effect of stage of lactation on milk yield, somatic cell counts, mineral and fatty acid profiles in pasture-based Friesian, Jersey and Friesian × Jersey cows." Thesis, University of Fort Hare, 2012. http://hdl.handle.net/10353/d1006810.
Повний текст джерелаGriffault, Lise. "Bilan des transferts de matière (majeurs et terres rares) dans les altérations hydrothermales des granites : exemple du granite du ballon d'alsace (vosges méridionales)." Poitiers, 1987. http://www.theses.fr/1987POIT2302.
Повний текст джерелаFrança, Elvis Joacir de. "A biomonitoração da Mata Atlântica na conservação da biodiversidade: espécies arbóreas nativas acumuladoras de elementos químicos." Universidade de São Paulo, 2006. http://www.teses.usp.br/teses/disponiveis/91/91131/tde-17102006-170028/.
Повний текст джерелаThe BIOTA Project Diversity, dynamic and conservation of forests from the São Paulo State: 40 ha of permanent parcels has been conducted to provide the knowledge on the generation, sustainability and regulation processes of the biodiversity of the State. A long-term plot (permanent parcel) was installed in the conservation unit corresponding to the Dense Ombrophilous Forest (Atlantic Forest) for the environmental characterization of the ecosystem. The investigation of chemical elements in this highly threatened forest was performed in this Doctorate Thesis. Several processes are responsible for the sustainability of the natural ecosystems. Mineral cycling defines the pathway of chemical elements from non-biotic compartments (soil and atmosphere) to biotic compartments (leaf and litter). The complexity of this regulatory mechanism is related to the deficiency, toxicity, phytoavailability and the interactions of the chemical elements, in addition to environmental growth conditions like luminosity, temperature and humidity. Due to its adaptability, plants are able to uptake and accumulate chemical elements in their tissues. This accumulation is an active process in which the plants tend to maintain the concentrations of some chemical elements independently of the environmental conditions. Such characteristic corroborates the use of these organisms for quantifying the environmental quality by biomonitoring studies of atmospheric pollution. Instrumental neutron activation analysis INAA was the analytical technique employed for biomonitoring due to its high metrological level and its capability for simultaneous determination of several chemical elements. For the comparability of the results, the quality of analytical procedure, the representativeness of samples and the effect of contamination with earth particles adhered to the leaf surface were also studied. The chemical composition of the soil, litter and leaf compartments was evaluated by INAA. The concentrations of some elements were higher for the soils of the valleys and considerably lower for the soils at higher altitudes. Such variability was not observed for the concentrations found in leaves, indicating the intrinsic chemical composition in plants. The concentrations in leaf did not change significantly (at the 95% confidence level) as demonstrated by the results from four different periods of sampling. Some tree species were able to accumulate the nutrients Ca, Co, K, Na, Se and Zn, the trace elements Br, Ba, Cs, Rb, Sc and Sr and the lanthanides Ce, Eu, La, Sm, Tb and Yb. The use of plants species for biomonitoring the long-term plot provided knowledge on the background concentrations of chemical elements. The Atlantic Forest can be considered to have a low status of pollution since most plants have shown concentrations within the expected range with exception of the accumulator species. Concentrations of some trace elements like As, Cd, Cr and Ni were below the detection limits. This work concentrated efforts to establish reference standards for studies on environmental impact considering the chemical composition in the long-term plot of the Atlantic Forest. The reservoir of chemical elements in the ecosystem was estimated, evidencing the importance of such knowledge for the biodiversity conservation.
Bosze, Stephanie Lynn. "SURFACE STRUCTURALLY CONTROLLED SECTORAL ZONING IN FLUORITE: IMPLICATIONS TO UNDERSTANDING HETEROGENEOUS REACTIVITY AT THE MINERAL-WATER INTERFACE." Oxford, Ohio : Miami University, 2001. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=miami981052842.
Повний текст джерелаNelson, Wendy Rae. "Mineral-Scale Sr Isotopic Study of Plagioclase in the Mafic Dikes of the North American Wall and the Diorite of the Rockslides, Yosemite Valley, California." Diss., CLICK HERE for online access, 2006. http://contentdm.lib.byu.edu/ETD/image/etd1204.pdf.
Повний текст джерелаHartung, Eva. "Early magmatism and the formation of a ‘Daly Gap’ at Akaroa Shield Volcano, New Zealand." Thesis, University of Canterbury. Geological Sciences, 2011. http://hdl.handle.net/10092/5584.
Повний текст джерелаYang, Panseok. "Trace element partitioning between coexisting metamorphic minerals and trace element zoning in metamorphic minerals from Gagnon Terrane, western Labrador /." Internet access available to MUN users only, 2002. http://collections.mun.ca/u?/theses,35173.
Повний текст джерелаAkinyemi, Segun Ajayi. "Geochemical and mineralogical evaluation of toxic contaminants mobility in weathered coal fly ash: as a case study, Tutuka dump site, South Africa." Thesis, University of the Western Cape, 2011. http://etd.uwc.ac.za/index.php?module=etd&action=viewtitle&id=gen8Srv25Nme4_1226_1360593017.
Повний текст джерелаThe management and disposal of huge volumes of coal combustion by products such as fly ash has constituted a major challenge to the environment. In most cases due to the inadequate alternative use of coal fly ash, the discarded waste is stored in holding ponds, slag heaps, or stock piled in ash dumps. This practice has raised concerns on the prospect of inorganic metals release to the surface and groundwater in the vicinity of the ash dump. Acceptable scientific studies are lacking to determine the best ash disposal practices. Moreover, knowledge about the mobility patterns of inorganic species as a function of mineralogical association or pH susceptibility of the dry disposed ash dump under natural weathering conditions are scarce in the literature. Fundamental understanding of chemical interactions of dry disposed ash with ingressed CO2 from atmosphere, percolating rain water and brine irrigation within ash disposal sites were seen as key areas requiring investigation. The mineralogical association of inorganic species in the dry disposed ash cores can be identified and quantified. This would provide a basis for understanding of chemical weathering, mineralogical transformations or mobility patterns of these inorganic species in the dry ash disposal scenario. The current study therefore aims to provide a comprehensive characterisation of weathered dry disposed ash cores, to reveal mobility patterns of chemical species as a function of depth and age of ash, with a view to assessing the potential environmental impacts. Fifty-nine samples were taken from 3 drilled cores obtained respectively from the 1 year, 8 year and 20-year-old sections of sequentially dumped, 
weathered, dry disposed ash in an ash dump site at Tutuka - a South African coal burning power station. The core samples were characterized using standard analytical procedures viz: X-ray fluorescence (XRF), X-ray diffraction (XRD), Fourier transforms infrared (FTIR) techniques, Scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) and Acid neutralisation capacity (ANC) test. A modified sequential extraction (SE) method was used in this study. The chemical partitioning, mobility and weathering patterns in 1 year, 8 year and 20-year-old sections of the ash dump were respectively investigated using this modified sequential extraction scheme. The sequence of the extractions was as follows: (1) water soluble, (2) exchangeable, (3) carbonate, (4) iron and manganese and (5) residual. The results obtained from the 5 steps sequential extraction scheme were validated with the total metal content of the original sample using mass balance method. The distribution of major and trace elements in the different liquid fractions obtained after each step of sequential extraction of the 59 drilled core samples was determined by inductively coupled plasma mass spectrometry (ICPMS). The data generated for various ash core samples were explored for the systematic analysis of mineralogical transformation and change in ash chemistry with ageing of the ash. Furthermore, the data was analyzed to reveal the impact of ingressed CO2 from atmosphere, infiltrating rain water and brine irrigation on the chemistry of ash core samples. Major mineral phases in original ash core samples prior to extraction are quartz (SiO2) and mullite (3Al2O3·
2SiO2). Other minor mineral phases identified were hematite (Fe2O3), calcite (CaCO3), lime (CaO), anorthite (CaAl2Si2O8), mica (Ca (Mg, Al)3 (Al3Si) O10 (OH)2), and enstatite (Mg2Si2O6). X-ray diffraction results show significant loss of crystallinity in the older ash cores. The presence of minor phases of calcite and mica in dry disposed ash cores are attributed to reduction in the pore water pH due to hydration, carbonation and pozzolanic reactions. The X-ray diffraction technique was unable to detect Fe-oxyhydroxide phase and morealuminosilicate phases in ash core samples due to their low abundance and amorphous character. X-ray fluorescence results of the original ash core samples showed the presence of major oxides, such as SiO2, Al2O3, Fe2O3, while CaO, K2O, TiO2, Na2O, MnO, MgO, P2O5, and SO3 occur in minor concentrations. The ratio of SiO2/Al2O3 classified the original core samples prior to extraction as a silico-aluminate class F fly ash. The ternary plot of major elements in 1-year-old ash core samples was both sialic and ferrocalsialic but 8 year and 20-year-old ash core samples were sialic in chemical composition. It is noteworthy that the mass % of SiO2 varies through the depth of the core with an increase of nearly 3 %, to 58 mass % of SiO2 at a depth of 6 m in the 1-year-old core whereas in the case of the 8-year-old core a 2 % increase of SiO2 to a level of 57.5 mass % can be observed at levels between 4-8 m, showing dissolution of major components in the matrix of older ash cores.. The Na2O content of the Tutuka ash cores was low and varied between 0.6-1.1 mass % for 1-year-old ash cores to around 0.6-0.8 mass % for 8-year-old ash cores. Sodium levels were higher in 1-year-old ash cores compared to 8 year and 20-year-old ashcores. Observed trends indicate that quick weathering of the ash (within a year) leached out Na+ from the ash dump. No evidence of Na+ encapsulation even though the ash dump was brine irrigated. Thus the dry disposal ash placement method does not result in a sustainable salt sink for Na-containing species over time. The total content of each of the elements in 1 year and 20-year-old ash cores was normalised with their total content in fresh ash from same power station to show enrichment and depletion factor. Major elements such as K+, Mn showed enrichment in 1-year-old ash cores whereas Al, Si, Na+, Ti, Ca, Mg, S and Fe showed depletion due to over time erosion. Trace elements such as Cr, Sr, P, Ba, Pb, V and Zn showed enrichment but Ni, Y, Zr showed depletion attributed to over time erosion. In 20-year-old ash cores, major elements such as Al, Na+ and Mn showed enrichment while Si, K+, Fe, Mg and Ca showed depletion highlighting their mobility. Trends indicated intensive flushing of major soluble components such as buffering constituents (CaO) by percolating rain water. The 1-year-old and 20-year-old coal ash cores showed a lower pH and greater loss/depletion of the soluble buffering constituents than the 2-week-old placed ash, indicating significant chemical weathering within a year. Based 
on ANC results the leaching behaviours of Ca, Mg, Na+, K+, Se, Cr, and Sr were found to be controlled by the pH of the leachant indicating high mobility of major soluble species in the ash cores when in contact with slightly acid rain water. Other investigated toxic metals such as As, Mo and Pb showed amphoteric behaviour with respect to the pH of the leachant. Chemical alterations and formation of transient minor secondary mineral phases was found to have a significant effect on the acid susceptibility and depletion pattern of chemical species in the core ash samples when compared to fresh ash. These ANC results correlated well with the data generated from the sequential extraction scheme. Based on sequential extraction results elements, showed noticeable mobility in the water soluble, exchangeable and carbonate fractions due to adsorption and desorption caused by variations in the pore water pH. In contrast, slight mobility of elements in the Fe and Mn, and residual fractions of dry disposed fly ashes are attributed to the co-precipitation and dissolution of minor amount of less soluble secondary phase overtime. The 1-year-old dry disposed ash cores were the least weathered among the 3 drilled ash cores. Therefore low concentration of toxic metals in older ash cores were ascribed to extensive weathering with slower release from residual mineral phases over time. Elements were found to associate with different mineral phases depending on the age or depth of the core samples showing greater heterogeneity in dispersion. For instance the average amount of total calcium in different mineral associations of 1-year-old ash cores is as follows
water soluble (10.2 %), exchangeable (37.04 %), carbonate (37.9 %), Fe and Mn (7.1 %) and residual (2.97 %). The amount of total Na+ in different mineral phases of 1-year-old ash cores followed this trend: water soluble (21 %), exchangeable (11.26 %), carbonate (2.6 %), Fe and Mn (4.7 %) and residual (53.9 %). The non-leachable portion of the total Na+ content (namely that contained in the residual fraction) in the 1-year-old ash core samples under conditions found in nature ranged between 5-91 %. This non-leachable portion of the Na+ showed the metastability of the mineral phases with which residual Na+ associates. Results showed older ash cores are enriched in toxic elements. Toxic elements such as As, B, Cr, Mo and Pb are enriched in the residual fraction of older ash cores. For instance As concentration in the residual fraction varied between 0.0003- 0.00043 mg kg-1 for 1-year-old ash cores to around 0.0003-0.0015 mg kg-1 for 20-year-old ash cores. This suggests that the older ash is enriched in toxic elements hence dust from the ash dump would be toxic to human health. The knowledge of mobility and ecotoxicological significance of coal fly ash is needed when considering its disposal or reuse in the environment. The mobility and ecotoxicology of inorganic metals in coal fly ash are determined by (i) mineralogical associations of inorganic species (ii) in-homogeneity in the ash dumps (iii) long and short term exposure to ingress CO2 and percolating rain water. Management issues such as inconsistent placement of ash in the dumps, poor choice of ash dump site, in-homogeneity in brine irrigation, no record of salt load put on the ash dumps and lack of proper monitoring requires improvement. The thesis provides justification for the use of the modified sequential extraction scheme as a predictive tool and could be employed in a similar research work. This thesis also proved that the dry ash disposal method was not environmental friendly in terms of overall leaching potential after significant chemical weathering. Moreover the study proved that the practice of brine co-disposal or irrigation on ash dumps is not sustainable as the ash dump did not act as a salt sink.
Hassani, Bibizahra 1959. "Binding of trace elements with various dietary fiber sources." Thesis, The University of Arizona, 1989. http://hdl.handle.net/10150/277058.
Повний текст джерелаBouch, Jonathan E. E. "Trace element geochemistry of authigenic heavy minerals in reservoir sandstones." Thesis, University of Aberdeen, 1996. http://digitool.abdn.ac.uk/R?func=search-advanced-go&find_code1=WSN&request1=AAIU089767.
Повний текст джерелаSze, Kwan-Lok, and 施均樂. "Electrophoretic methodologies for the determinations of minerals and trace elements in milk." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2009. http://hub.hku.hk/bib/B43085246.
Повний текст джерелаAhmed, Shafiqur Rahman. "Studies on metabolism of minerals and trace elements in vitamin A deficiency." Kyoto University, 1997. http://hdl.handle.net/2433/202192.
Повний текст джерелаSze, Kwan-Lok. "Electrophoretic methodologies for the determinations of minerals and trace elements in milk." Click to view the E-thesis via HKUTO, 2009. http://sunzi.lib.hku.hk/hkuto/record/B43085246.
Повний текст джерелаROCKWAY, SUSIE WILSON. "INTERACTION AND BIOAVAILABILITY OF TRACE MINERALS WITH CEREAL BRANS (FIBER, COPPER)." Diss., The University of Arizona, 1985. http://hdl.handle.net/10150/187963.
Повний текст джерелаZack, Thomas. "Trace element mineral analysis in high pressure metamorphic rocks from Trescolmen, Central Alps." [S.l. : s.n.], 1999. http://deposit.ddb.de/cgi-bin/dokserv?idn=963753924.
Повний текст джерелаDabbs, Jennifer Marie, and Jennifer Marie Dabbs. "Trace Element Composition of Apatite from Intrusive Rocks in Northeastern Nevada, USA." Thesis, The University of Arizona, 2016. http://hdl.handle.net/10150/620842.
Повний текст джерелаSmith, Cornel. "The effect of preserving liver tissue in formalin on the concentration of trace minerals in the liver." Pretoria : [s.n.], 2005. http://upetd.up.ac.za/thesis/available/etd-08052005-101056/.
Повний текст джерелаEvans, Guy Nathaniel. "Trace element proxies and mineral indicators of hydrothermal fluid composition and seafloor massive sulfide deposit formation processes." Thesis, Massachusetts Institute of Technology, 2017. http://hdl.handle.net/1721.1/111731.
Повний текст джерелаCataloged from PDF version of thesis.
Includes bibliographical references.
This thesis analyzes compositions of seafloor massive sulfide (SMS) deposits and related hydrothermal vent fluids to identify proxies of reaction zone conditions (host-rock lithology, hydrothermal fluid temperature and chemistry). Chapter 2 investigates the morphology, mineralogy, and geochemistry of SMS deposits from six vent fields along the Eastern Lau Spreading Center (ELSC), demonstrating that ELSC SMS deposits record differences in hydrothermal fluid temperature, pH, sulfur fugacity and host-rock lithology related to proximity to the nearby Tonga Subduction Zone. Chapters 3 and 4 focus on partitioning of Co, Ni, Ga, Ag, and In between hydrothermal vent fluids and chalcopyrite lining fluid conduits in black smoker chimneys. Chapter 3 develops secondary ion mass spectrometry (SIMS) as a technique to measure Co, Ni, Ga, Ag, and In in chalcopyrite and identifies a correlation between Ga and In in chalcopyrite and hydrothermal fluid pH. Chapter 4 presents new data on these elements in ELSC hydrothermal fluids that, combined with SIMS analyses of chalcopyrite chimney linings and previously published data on vent fluids from the Manus Basin, provide evidence that supports partitioning of Ag a lattice substitution for Cu. Together, concentrations of Ga, In, and Ag in chalcopyrite provide proxies of hydrothermal fluid pH and metal (i.e., Ag and Cu) contents.
by Guy Nathaniel Evans.
Ph. D. in Marine Geology
Moretto, Robert. "Étude sédimentologique et géochimique des dépôts de la série salifère paléogène du bassin de Bourg-en-Bresse (France)." Nancy 1, 1986. http://www.theses.fr/1986NAN10393.
Повний текст джерелаMonnin, Christophe. "Thermodynamique des eaux naturelles concentrees : solubilite des mineraux a haute temperature et a haute pression et coefficients d'activite des elements en trace." Toulouse 3, 1989. http://www.theses.fr/1989TOU30073.
Повний текст джерелаSchröder, Annette [Verfasser], and Gerhard [Akademischer Betreuer] Schmiedl. "Changes of clay mineral and trace element characteristics of sinking particulate matter during transport into the Deep South China Sea / Annette Schröder. Betreuer: Gerhard Schmiedl." Hamburg : Staats- und Universitätsbibliothek Hamburg, 2016. http://d-nb.info/1095766333/34.
Повний текст джерелаSchröder, Annette Verfasser], and Gerhard [Akademischer Betreuer] [Schmiedl. "Changes of clay mineral and trace element characteristics of sinking particulate matter during transport into the Deep South China Sea / Annette Schröder. Betreuer: Gerhard Schmiedl." Hamburg : Staats- und Universitätsbibliothek Hamburg, 2016. http://d-nb.info/1095766333/34.
Повний текст джерелаRobert, Maya [Verfasser], Dieter [Akademischer Betreuer] Wolf-Gladrow, Victor [Gutachter] Smetacek, and Uta [Gutachter] Passow. "Importance of Polysaccharides for the cycling of Minerals and trace elements in the ocean / Maya Robert ; Gutachter: Victor Smetacek, Uta Passow ; Betreuer: Dieter Wolf-Gladrow." Bremen : Staats- und Universitätsbibliothek Bremen, 2010. http://d-nb.info/1154925927/34.
Повний текст джерелаRobert, Maya [Verfasser], Dieter [Akademischer Betreuer] Wolf-Gladrow, Uta [Gutachter] Passow, and Victor [Gutachter] Smetacek. "Importance of polysaccharides for the cycling of minerals and trace elements in the ocean / Maya Robert ; Gutachter: Uta Passow, Victor Smetacek ; Betreuer: Dieter Wolf-Gladrow." Bremen : Staats- und Universitätsbibliothek Bremen, 2010. http://d-nb.info/1162620609/34.
Повний текст джерелаFranzan, Renata. "Preparação e caracterização físico-química de complexos de hidrolisados parciais de proteína com minerais." Universidade de São Paulo, 2006. http://www.teses.usp.br/teses/disponiveis/60/60137/tde-02062008-104546/.
Повний текст джерелаThe essential minerals participate in many vital functions in the organism, its deficiencies contribute in significant way for the morbidity and mortality in the childhood, especially in developing countries, being considered as public health problem in the whole world. Minerals presented in the form of organics complexes have been considered a good choice for these deficiencies, because it presents greater bioavailability when compared with the equivalents inorganic salts. The minerals copper, iron, manganese and zinc are essential to the organisms (human and animal), its physiological levels in accordance with the necessity contribute for the health maintence, resulting in economical benefits. In the present work it was carried through preparation and physical and chemical characterization of mineral complexes of Copper (Cu), Iron (Fe), Manganese (Mn) and Zinc (Zn) with partial hydrolysates of soy protein. The hydrolyses using the Aranzime and Alcalase enzymes had been more efficient than other enzymatic or acid hydrolyses, however only the Alcalase enzyme is approved for the manufacture of alimentary products for human consumption. Coordination between metals and the hydrolysate can be confirmed by the displacement of the ?NH2, ?aCOO- and ?sCOO- bands. The gotten copper, iron, manganese and zinc complexes, had the respective percentages of metal in its composition: 2,21%, 1,22%, 12,38% e 10,40%.
Thorette, Jacques. "Contribution à l'étude de l'hydrothermalisme océanique : exemple du district minéralisé de York-Harbour (massif ophiolitique de Blow-Me-Down, Bay-of-Islands, Terre-Neuve)." Brest, 1986. http://www.theses.fr/1986BRES2002.
Повний текст джерелаBenzaazoua, Mostafa. "Caractérisation physico-chimique et minéralogique de produits miniers sulfurés en vue de la réduction de leur toxicité et de leur valorisation." Vandoeuvre-les-Nancy, INPL, 1996. http://docnum.univ-lorraine.fr/public/INPL_T_1996_BENZAAZOUA_M.pdf.
Повний текст джерелаMacDonald, James Douglas. "The partitioning of Cd, Cu, Pb and Zn between the solid and solution phase of forest floor horizons in podzolic soils near metal smelters /." Thesis, McGill University, 2005. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=85575.
Повний текст джерелаWe developed a standard protocol to produce solutions that resemble lysimeter solutions from podzolic soils using air-dried samples. We hypothesized that the stabilization point of the electrical conductivity (EC) of the soil solution is indicative of the point in which soluble salts and organic material precipitated during sampling and storage are removed from the soil particle surfaces. Solutions produced by leaching the soils, once the EC of wash solutions had stabilized, were comparable to lysimeter solutions from the area where samples were collected with respect to the concentrations of divalent cations, pH, EC and dissolved organic carbon (DOC). The applicability of this procedure to trace metal partitioning in forest floors was explored. Laboratory extractions produced partition coefficients (log Kd) similar to observed lysimeter solutions ranging from 3.4 to 3.9 for Cd, 3.4 to 3.9 for Cu, 3.4 to 4.1 for Ni, 4.1 to 5.2 for Pb and 3.2 to 3.5 for Zn. According to a semi-mechanistic regression model based on observed lysimeter concentrations, the metal concentrations in solution were appropriate relative to known factors that influence metal partitioning in soils: pH, the concentrations of total metals and DOC.
While chemical characteristics of soils have been consistently observed to play important roles in the partitioning and toxicity of metals we wished to place the importance of the chemical characteristics of soil on mobility and toxicity in context. We interpreted field data that had been collected from transects established with distance from two point source emitters in Rouyn PQ, and Sudbury ON. Canada find developed equations that predict dissolved metal concentrations from total metal concentrations, soil pH, soil organic matter (SOM), and DOC contents. We integrated these equations into a simple box model that calculates changes in the concentration of metals in the organic and upper mineral horizons and includes a loop for vegetative return of metals to the forest floor.
Ver, Hoeve Thomas James. "Applications of LA-ICP-MS analysis to zircon : assessing downhole fractionation and pre-treatment effects for U-Pb geochronology and trace element variations in accessory minerals from the Bushveld Complex." Thesis, University of British Columbia, 2016. http://hdl.handle.net/2429/60201.
Повний текст джерелаScience, Faculty of
Earth, Ocean and Atmospheric Sciences, Department of
Graduate
Zahaby, Mohamed El. "Contribution à la définition d'une norme des sites pollués : élaboration d'une méthodologie pour l'évaluation de la contamination d'un sol par éléments tracés." Vandoeuvre-les-Nancy, INPL, 1998. http://www.theses.fr/1998INPL045N.
Повний текст джерелаMoulahoum, Omar. "Dualité du magmatisme d'âge pan-africain : Aspects structuraux et pétrologiques des granites subalcalins et alumineux de la région de Tamanrasset (Hoggar central, Algérie." Nancy 1, 1988. http://www.theses.fr/1988NAN10049.
Повний текст джерелаTang, Eng Hoo Joseph. "The Petrogenesis Of The Station Creek Igneous Complex And Associated Volcanics, Northern New England Orogen." Thesis, Queensland University of Technology, 2004. https://eprints.qut.edu.au/15902/1/Joseph_Tang_Thesis.pdf.
Повний текст джерелаTang, Eng Hoo Joseph. "The Petrogenesis Of The Station Creek Igneous Complex And Associated Volcanics, Northern New England Orogen." Queensland University of Technology, 2004. http://eprints.qut.edu.au/15902/.
Повний текст джерелаVILA, GUSTAVO B. "Caracterização de silicatos e carbonatos de cálcio aplicados à dosimetria de doses altas." reponame:Repositório Institucional do IPEN, 2012. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10201.
Повний текст джерелаMade available in DSpace on 2014-10-09T13:59:32Z (GMT). No. of bitstreams: 0
Tese (Doutoramento)
IPEN/T
Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP
Al-Amer, Saleh Suliaman. "Nutritional and toxicological studies on New Zealand mutton bird meat (Puffinus griseus)." Lincoln University, 2009. http://hdl.handle.net/10182/1659.
Повний текст джерела