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Статті в журналах з теми "Methane activation chemistry"
Sharma, Richa, Hilde Poelman, Guy B. Marin, and Vladimir V. Galvita. "Approaches for Selective Oxidation of Methane to Methanol." Catalysts 10, no. 2 (February 6, 2020): 194. http://dx.doi.org/10.3390/catal10020194.
Повний текст джерелаSchwarz, Helmut. "Activation of Methane." Angewandte Chemie International Edition in English 30, no. 7 (July 1991): 820–21. http://dx.doi.org/10.1002/anie.199108201.
Повний текст джерелаChoudhary, Tushar V., Erhan Aksoylu, and D. Wayne Goodman. "Nonoxidative Activation of Methane." Catalysis Reviews 45, no. 1 (January 5, 2003): 151–203. http://dx.doi.org/10.1081/cr-120017010.
Повний текст джерелаSherry, Alan E., and Bradford B. Wayland. "Metalloradical activation of methane." Journal of the American Chemical Society 112, no. 3 (January 1990): 1259–61. http://dx.doi.org/10.1021/ja00159a064.
Повний текст джерелаYu, Yue, Zhixiang Xi, Bingjie Zhou, Binbo Jiang, Zuwei Liao, Yao Yang, Jingdai Wang, Zhengliang Huang, Jingyuan Sun, and Yongrong Yang. "Enhancing Methane Conversion by Modification of Zn States in Co-Reaction of MTA." Catalysts 11, no. 12 (December 17, 2021): 1540. http://dx.doi.org/10.3390/catal11121540.
Повний текст джерелаBaerns, M. "Workshop on basic research opportunities in methane activation chemistry." Applied Catalysis 18, no. 1 (September 1985): 211–12. http://dx.doi.org/10.1016/s0166-9834(00)80330-9.
Повний текст джерелаMeyet, Jordan, Mark A. Newton, Jeroen A. van Bokhoven, and Christophe Copéret. "Molecular Approach to Generate Cu(II) Sites on Silica for the Selective Partial Oxidation of Methane." CHIMIA International Journal for Chemistry 74, no. 4 (April 29, 2020): 237–40. http://dx.doi.org/10.2533/chimia.2020.237.
Повний текст джерелаButschke, Burkhard, Maria Schlangen, Helmut Schwarz, and Detlef Schröder. "C–H Bond Activation ofMethane with Gaseous [(CH3)Pt(L)]+ Complexes (L = Pyridine, Bipyridine, and Phenanthroline)." Zeitschrift für Naturforschung B 62, no. 3 (March 1, 2007): 309–13. http://dx.doi.org/10.1515/znb-2007-0302.
Повний текст джерелаTian, Yudong, Lingyu Piao, and Xiaobo Chen. "Research progress on the photocatalytic activation of methane to methanol." Green Chemistry 23, no. 10 (2021): 3526–41. http://dx.doi.org/10.1039/d1gc00658d.
Повний текст джерелаCui, Weihong, X. Peter Zhang, and Bradford B. Wayland. "Bimetallo-Radical Carbon−Hydrogen Bond Activation of Methanol and Methane." Journal of the American Chemical Society 125, no. 17 (April 2003): 4994–95. http://dx.doi.org/10.1021/ja034494m.
Повний текст джерелаДисертації з теми "Methane activation chemistry"
Brimacombe, Lyn M. "Activation of methane on supported metal catalysts." Thesis, University of Ottawa (Canada), 1991. http://hdl.handle.net/10393/7805.
Повний текст джерелаLoader, Peter Kelvin. "An investigation of the activation of methane on heterogeneous catalysts." Thesis, University of Reading, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.359396.
Повний текст джерелаKopp, Daniel Arthur. "Mechanistic studies of electron transfer, complex formation, C-H bond activation, and product binding in soluble methane monooxygenase." Thesis, Massachusetts Institute of Technology, 2003. http://hdl.handle.net/1721.1/16915.
Повний текст джерелаVita.
Includes bibliographical references.
This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.
Chapter 1. Soluble Methane Monooxygenase: Activation of Dioxygen and Methane The mechanisms by which soluble methane monooxygenase uses dioxygen to convert methane selectively to methanol have come into sharp focus. Diverse techniques have clarified subtle details about each step in the reaction, from binding and activating dioxygen, to hydroxylation of alkanes and other substrates, to the electron transfer events required to complete the catalytic cycle. Chapter 2. Electron Transfer Reactions of the Reductase Component of Soluble Methane Monooxygenase from Methylococcus capsulatus (Bath) Soluble methane monooxygenase (sMMO) catalyzes the hydroxylation of methane by dioxygen to afford methanol and water, the first step of carbon assimilation in methanotrophic bacteria. This enzyme comprises three protein components: a hydroxylase (MMOH) that contains a dinuclear non-heme iron active site, a reductase (MMOR) that facilitates electron transfer from NADH to the diiron site of MMOH, and a coupling protein (MMOB). MMOR uses a non-covalently bound FAD cofactor and a [2Fe-2S] cluster to mediate electron transfer. The gene encoding MMOR was cloned from Methylococcus capsulatus (Bath) and expressed in Escherichia coli in high yield. Purified recombinant MMOR was indistinguishable from the native protein in all aspects examined, including activity, mass, cofactor content, and EPR spectrum of the [2Fe-2S] cluster. Redox potentials for the FAD and [2Fe-2S] cofactors, determined by reductive titrations in the presence of indicator dyes ...
(cont.) The midpoint potentials of MMOR are not altered by the addition of MMOH, MMOB, or both MMOH and MMOB. The reaction of MMOR with NADH was investigated by stopped-flow UV-visible spectroscopy, and the kinetic and spectral properties of intermediates are described. The effects of pH on the redox properties of MMOR are described and exploited in pH jump kinetic studies to measure the rate constant of 130 +/- s-1 for electron transfer between the FAD and [2Fe-2S] cofactors in two-electron reduced MMOR. The thermodynamic and kinetic parameters determined significantly extend our understanding of the sMMO system. Chapter 3. Structural Features of the MMOH/MMOR Complex as Revealed by Mass Spectrometric Analysis of Covalently Cross-linked Proteins. Soluble methane monooxygenase requires complexes between its three component proteins for efficient catalytic turnover. The hydroxylase (MMOH) must bind both to the reductase (MMOR) for electron transfer and to the regulatory protein (MMOB) to allow reaction with substrates. Although structures of MMOH, MMOB, and one domain of MMOR have been determined, little is known about structures of the complexes. Proteins cross-linked by a carbodiimide reagent were analyzed by specific proteolysis and capillary HPLC-mass spectrometry. Tandem mass spectra conclusively identified two amine-to-carboxylate cross-linked sites involving the alpha subunit of MMOH and the [2Fe-2S] domain of MMOR (MMOR-Fd). The amino terminus of the MMOH alpha subunit cross-links to the side chains of MMOR-Fd residues Glu56 and Glu91. These Glu residues are close to one another on the surface of MMOR-Fd and far from the [2Fe-2S] cluster ...
by Daniel A. Kopp.
Ph.D.
Yu, Jenwei Roscoe. "Methane activation over molybdenum disulfide, molybdenum carbide, and silver(110). Molecular orbital theory." Case Western Reserve University School of Graduate Studies / OhioLINK, 1990. http://rave.ohiolink.edu/etdc/view?acc_num=case1059138320.
Повний текст джерелаPahls, Dale R. "Pathways for C—H Activation and Functionalization by Group 9 Metals." Thesis, University of North Texas, 2015. https://digital.library.unt.edu/ark:/67531/metadc801909/.
Повний текст джерелаJen, Shu-Fen. "Oxidation and reduction of carbon monoxide and methane carbon-hydrogen bond activation: Molecular orbital theory." Case Western Reserve University School of Graduate Studies / OhioLINK, 1991. http://rave.ohiolink.edu/etdc/view?acc_num=case1056129369.
Повний текст джерелаNajafian, Ahmad. "Activation of Small Molecules by Transition Metal Complexes via Computational Methods." Thesis, University of North Texas, 2020. https://digital.library.unt.edu/ark:/67531/metadc1703353/.
Повний текст джерелаGrinenval, Éva. "Chimie organométallique de surface sur hétéropolyacides anhydres de type Keggin : application en catalyse." Thesis, Lyon 1, 2009. http://www.theses.fr/2009LYO10184.
Повний текст джерелаThe aim of this work was the preparation and characterization of anhydrous heteropolyanions on oxide supports using surface organometallic chemistry approach. Anhydrous H3PMo12O40 and H3PW12O40 were prepared on partially dehydroxylated silica. This reaction led to an ionic interaction by protonation of surface silanols. The reactivity of these heteropoly compounds with alkylsilanes was studied in homogeneous conditions and led to the formation of cationic silicon species [Et2MeSi+]3[HPA3-] and release of hydrogen. This reactivity was then applied in heterogeneous conditions by introduction of silane groups [(≡SiO)SiMe2H] at the silica surface and led to the formation of a surface polyoxometalate species covalently bonded to the support. The introduction of chloroalkylsilane groups [(≡SiO)SiMeCl2] and [(≡SiO)2SiMeCl] has also enabled the formation of covalent bonds Si Support-O-M HPA. In addition, methane activation was observed on all HPA/SiO2 solids through the releases of CO2, H2O, H2. The C-H activation takes place on these systems even at low temperature and obtained data suggest the formation of a methoxy surface species by reaction of stronf acidic protons with methane
Zaher, Hasna. "The activation of small molecules using frustrated Lewis pairs." Thesis, University of Oxford, 2012. http://ora.ox.ac.uk/objects/uuid:82848f03-2269-4e76-9b01-d89a6d22cd71.
Повний текст джерелаKumar, Rahul. "Mechanistic Insights Into Small Molecule (Amine-Boranes, Hydrogen, Methane, Formic Acid Carbon dioxide) Activation Using Electrophilic Ru(II)-Complexes." Thesis, 2016. http://etd.iisc.ernet.in/handle/2005/2744.
Повний текст джерелаЧастини книг з теми "Methane activation chemistry"
begum, Pakiza, and Ramesh c. deka. "A comparative theoretical investigation on the activation of C-H bond in methane on mono and bimetallic Pd and Pt subnanoclusters." In Computational Chemistry Methodology in Structural Biology and Materials Sciences, 243–58. Toronto; New Jersey: Apple Academic Press, 2017.: Apple Academic Press, 2017. http://dx.doi.org/10.1201/9781315207544-8.
Повний текст джерелаArndt, S., and R. Schomäcker. "Methane Activation." In Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Elsevier, 2014. http://dx.doi.org/10.1016/b978-0-12-409547-2.10948-5.
Повний текст джерелаHoffmann, Roald, and Pierre Laszlo. "Protean." In Roald Hoffmann on the Philosophy, Art, and Science of Chemistry. Oxford University Press, 2012. http://dx.doi.org/10.1093/oso/9780199755905.003.0015.
Повний текст джерелаChizoo, Esonye. "Alkali Homogeneous Catalyzed Methyl Ester Synthesis from Chrysophyllum albidum Seed Oil: An Irreversible Consecutive Mechanism Approach." In Alkaline Chemistry and Applications. IntechOpen, 2022. http://dx.doi.org/10.5772/intechopen.95519.
Повний текст джерелаТези доповідей конференцій з теми "Methane activation chemistry"
Mehdi, Ghazanfar, Maria Grazia De Giorgi, Donato Fontanarosa, Sara Bonuso, and Antonio Ficarella. "Ozone Production With Plasma Discharge: Comparisons Between Activated Air and Activated Fuel/Air Mixture." In ASME Turbo Expo 2021: Turbomachinery Technical Conference and Exposition. American Society of Mechanical Engineers, 2021. http://dx.doi.org/10.1115/gt2021-60167.
Повний текст джерелаPashkov, V. V., D. V. Golinsky, N. V. Vinichenko, and A. S. Belyi. "Non-oxidative activation of methane under a pulsed mode in the presence of supported platinum-containing catalysts." In 21ST CENTURY: CHEMISTRY TO LIFE. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5122940.
Повний текст джерелаHolton, M. M., P. Gokulakrishnan, M. S. Klassen, R. J. Roby, and G. S. Jackson. "Autoignition Delay Time Measurements of Methane, Ethane, and Propane Pure Fuels and Methane-Based Fuel Blends." In ASME Turbo Expo 2009: Power for Land, Sea, and Air. ASMEDC, 2009. http://dx.doi.org/10.1115/gt2009-59309.
Повний текст джерелаPeswani, Mohnish, and Brian McN Maxwell. "Performance of a Generic 4-Step Global Reaction Mechanism With Equilibrium Effects for Detonation Applications." In ASME 2020 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/imece2020-23786.
Повний текст джерела