Дисертації з теми "Metal Coordination Chemistry"
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Hannon, Michael John. "Metal ion control in oligopyridine coordination chemistry." Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272558.
Повний текст джерелаArrowood, Kimberly Ann. "Combining cyclic peptides with metal coordination." Thesis, Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29700.
Повний текст джерелаCommittee Chair: Weck, Marcus; Committee Member: Collard, David; Committee Member: Kubanek, Julia. Part of the SMARTech Electronic Thesis and Dissertation Collection.
Sze-To, Lap, and 司徒立. "The structural chemistry of coordination compounds containing d-block or f-block metals." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B45204470.
Повний текст джерелаLin, Xiang. "The supramolecular chemistry of metal-organic coordination oligomers and polymers." Thesis, University of Nottingham, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.416395.
Повний текст джерелаQuirk, Jeffrey. "Coordination chemistry of selenoether macrocyclic ligands with transition metal ions." Thesis, University of Southampton, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242624.
Повний текст джерелаNäslund, Jan. "Solvated trivalent metal ions in solution : a coordination chemistry study /." Uppsala : Swedish University of Agricultural Sciences, 2000. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=009419319&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.
Повний текст джерелаHall, Christopher. "The coordination of alkanes to transition metal fragments." Thesis, University of York, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.331939.
Повний текст джерелаParrott, Suzanne J. "The coordination chemistry of hydrazide and diazenide complexes of rhenium." Thesis, University of Essex, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315728.
Повний текст джерелаOgilvie, Stephen Hudson. "Coordination Frameworks: Host-Guest Chemistry and Structural Dynamics." Thesis, The University of Sydney, 2015. http://hdl.handle.net/2123/15897.
Повний текст джерелаHigginson, Joshua J. "Synthesis and coordination chemistry of ditopic ligands capable of coordinating metal ions and interacting with anions." Thesis, University of Huddersfield, 2015. http://eprints.hud.ac.uk/id/eprint/26444/.
Повний текст джерелаHall, Andrew J. "Transition metal ion coordination in hydrophilic polymer membranes." Thesis, Aston University, 1994. http://publications.aston.ac.uk/9746/.
Повний текст джерелаBachmann, Julien. "Metal-ligand redox interaction in the multielectron chemistry of porphyrinogen coordination compounds." Thesis, Massachusetts Institute of Technology, 2006. http://hdl.handle.net/1721.1/35314.
Повний текст джерелаThis electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.
Vita. Page 257 blank.
Includes bibliographical references.
Metal complexes of the macrocycle porphyrinogen (calix[4]pyrrole) are studied with an emphasis on the redox activity ("non-innocence") of the ligand (Chapter I). Porphyrinogen complexes of spherical, redox-inert metal dications exist in three oxidation states, dianionic, neutral, and dicationic, characterized structurally by zero, one, and two direct bonds between adjacent pyrroles, respectively. All three are isolated on the preparative scale, and interconverted electrochemically (Chapter II). Each carbon-carbon bond functions as a reservoir of two redox equivalents. The neutral oxidation state exhibits an optical intervalence charge transfer transition, characteristic of ligand-based two-electron mixed valency (Chapter III). Dianionic zinc porphyrinogen reacts with carbon dioxide, and neutral zirconium(IV) porphyrinogen with dioxygen. Two zirconium porphyrinogen units can carry a water molecule as an oxo bridging the metals and two protons on the ligands (Chapter IV). Iron porphyrinogen has three available oxidation states, a dianion, a monoanion, and a dication. The interconversion of the latter two is a selective three-electron transformation, preparatively and electrochemically (Chapter V). complex are largely decoupled from each other and can be chosen independently (Chapter IX).
(cont.) Crystallographic analysis shows that both anionic oxidation states contain the reduced ligand, whereas the dicationic state is based on the oxidized ligand (with two C - C bonds). Paramagnetic NMR confirms the structures in solution. Spectroscopies (EPR, Mössbauer) allow the assignment of well-defined individual oxidation and spin states states for the metal within each overall oxidation state of the complex (Chapter VI). The iron porphyrinogen dication is an oxidant based on an iron(II) center; it oxidizes iodide to diiodine (Chapter VII). The cobalt(II) porphyrinogen dianion can take up two protons, then photoreact to yield reduction of at least one proton to a metalbound hydride, as evidenced by infrared spectroscopy (Chapter VIII). Overall, the results afford a picture of metal-porphyrinogens including structure, electronic structure, and reactivity. The ligand supplements the central metal ion by functioning as a multielectron reservoir. Therefore, the (metal-based) coordination and (ligand-based) redox properties of a given porphyrinogen
by Julien Bachmann.
Ph.D.
Schulte, Thorben Rüdiger. "Metal- and Ligand-Centered Chirality in Square-Planar Coordination Compounds." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/21.11130/00-1735-0000-0005-126A-0.
Повний текст джерелаPartridge, Martin Graham. "Activation and coordination of organic ligands by cyclopentadienyl metal complexes." Thesis, University of York, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.304072.
Повний текст джерелаAtkinson, Nigel Anthony. "Transition metal complexes with sulphur/nitrogen donor macrocycles and related ligands." Thesis, University of Huddersfield, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.290395.
Повний текст джерелаRizzuto, Felix. "Allosteric interactions in coordination cages." Thesis, University of Cambridge, 2018. https://www.repository.cam.ac.uk/handle/1810/278963.
Повний текст джерелаAnderson, Carly Elizabeth. "Synthesis of multidentate PNE ligands and their late transition metal coordination chemistry." Thesis, Durham University, 2007. http://etheses.dur.ac.uk/2598/.
Повний текст джерелаBajwa, Somia Ehsan. "Hybrid multidentate phosphine-alkene ligands for transition metal coordination chemistry and catalysis." Thesis, University of York, 2012. http://etheses.whiterose.ac.uk/2633/.
Повний текст джерелаAnsari, Nasrin. "Coordination properties of aminophosphine with first row transition metal nitrosyl complexes." Thesis, University of Ottawa (Canada), 1994. http://hdl.handle.net/10393/6862.
Повний текст джерелаO'Connor, Alice. "High pressure studies of metal-organic frameworks and coordination complexes." Thesis, University of Nottingham, 2017. http://eprints.nottingham.ac.uk/40333/.
Повний текст джерелаMartinez, Ortega Maria Eugenia. "Lipid metal organic networks." To access this resource online via ProQuest Dissertations and Theses @ UTEP, 2009. http://0-proquest.umi.com.lib.utep.edu/login?COPT=REJTPTU0YmImSU5UPTAmVkVSPTI=&clientId=2515.
Повний текст джерелаFleming, James S. "d'8-metal complexes of 1,8-divinylnaphthalene and 1,2-divinylbenzene." Thesis, University of Bristol, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.385969.
Повний текст джерелаRooke, Stephanie Jane. "Transition metal coordination polymers of novel siloxanes bearing N- donor groups." Thesis, Imperial College London, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.271532.
Повний текст джерелаCuster, Paul D. "Transition Metal Coordination for the Construction of Supramolecular Molecules." University of Akron / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=akron1226957658.
Повний текст джерелаChan, Hoi-shan. "Syntheses, reactivity and coordination chemistry of d10 metal complexes of phosphorus and nitrogen donating polydentate ligands /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B2079289X.
Повний текст джерелаCarter, Timothy Glen 1976. "New supramolecular assemblies of toxic metal coordination complexes." Thesis, University of Oregon, 2010. http://hdl.handle.net/1794/10562.
Повний текст джерелаSupramolecular chemistry is a relatively new and exciting field offering chemists simplistic approaches to generating complex assemblies through strategically designed ligands. Much like the many spectacular examples of supramolecular assemblies in nature, so too are chemists able to construct large, elegant assemblies with carefully designed ligands which bind preferentially to target metal ions of choice. An important concept of supramolecular chemistry, often subtle and overlooked, is secondary bonding interactions (SBIs) which in some cases, act as the glue to hold supramolecular assemblies together. This dissertation examines SBIs in a number of systems involving the pnictogen elements of arsenic and antimony as well as aromatic interactions in self-assembled monolayers. The first half of this dissertation is an introduction to the concepts of supramolecular chemistry and secondary bonding interactions and how they are used in the self-assembly process in the Darren Johnson laboratory. Chapter I describes how secondary bonding interactions between arsenic and aryl ring systems and antimony and aryl ring systems assist with the assembly process. Chapter II is a continuation of the discussion of SBIs but focuses on the interactions between arsenic and heteroatoms. The second half of this dissertation will describe work performed in collaboration with Pacific Northwest National Laboratory (PNNL) in Richland, WA. This work was performed under the guidance of Dr. R. Shane Addleman in conjunction with Professor Darren W. Johnson of the University of Oregon. This portion describes novel systems for use in heavy metal ion remediation from natural and unnatural water sources. Chapters III-V describe functionalized mesoporous silica for use in heavy metal uptake from contaminated water sources. Chapter V describes a new technology invented during this internship at PNNL which utilizes weak bonding interactions between aryl ring systems to produce regenerable green materials for toxic metal binding. This work is ongoing in the Darren Johnson lab. This dissertation includes my previously published and co-authored material.
Committee in charge: Michael Haley, Chairperson, Chemistry; Darren Johnson, Member, Chemistry; Shih-Yuan Liu, Member, Chemistry; James Hutchison, Member, Chemistry; Eric Johnson, Outside Member, Biology
Nayak, Sanjit. "The Use of Coordination Chemistry Principles to Control Aggregation Processes of Metal Ions." [S.l. : s.n.], 2008. http://digbib.ubka.uni-karlsruhe.de/volltexte/1000009969.
Повний текст джерелаGibson, Alexander. "Syntheses and studies on transition metal complexes involving phosphine and thioether ligands." Thesis, University of Southampton, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243147.
Повний текст джерелаJones, Peter Leslie. "The synthesis and study of metal complexes of novel functionalised poly(pyrazol-1-yl)borate ligands." Thesis, University of Bristol, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.336874.
Повний текст джерелаWan, Chun-wai. "Spectroscopic properties and coordination chemistry of d10 metal complexes with the polypyridyl and naphthyridyl ligands /." Hong Kong : University of Hong Kong, 2000. http://sunzi.lib.hku.hk/hkuto/record.jsp?B22227301.
Повний текст джерела陳凱珊 and Hoi-shan Chan. "Syntheses, reactivity and coordination chemistry of d10 metal complexes of phosphorus and nitrogen donating polydentate ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31220368.
Повний текст джерелаLu, Jianjiang. "Crystal engineering of metal-carboxylate based coordination polymers." [Tampa, Fla.] : University of South Florida, 2004. http://purl.fcla.edu/fcla/etd/SFE0000361.
Повний текст джерелаOtter, Carl A. "The synthesis and coordination chemistry of mixed donor pyridine/phenol and pyridine/sulfonamide ligands." Thesis, University of Bristol, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.246241.
Повний текст джерелаKemats, Kyle. "Examining the Gas-Phase Fragmentation of Select Metal ß-diketonate Complexes Using Computational Methods." Youngstown State University / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1410787738.
Повний текст джерелаKaur, Gurpreet. "Structure and reactivity of dinuclear and polynuclear metal complexes." Thesis, University of Canterbury. Chemistry, 2014. http://hdl.handle.net/10092/9945.
Повний текст джерелаBoyd, Thomas. "From molecular assemblies to extended frameworks of polyoxometalates through secondary metal ion coordination." Thesis, University of Glasgow, 2013. http://theses.gla.ac.uk/4492/.
Повний текст джерелаFaustino, Brissos Rosa Maria. "Coordination, organometallic and supramolecular chemistry approaches to the design of metal-based cytotoxic agents." Doctoral thesis, Universitat de Barcelona, 2018. http://hdl.handle.net/10803/544129.
Повний текст джерелаEl descobriment que cisplatí és un fàrmac molt útil en quimioteràpia ha encoratjat el desenvolupament de fàrmacs antitumorals basats en metalls. El projecte de recerca d’aquesta Tesi Doctoral inclou tres aproximacions diferents pel disseny de nous compostos citotòxics basats en metalls. Així doncs, tant la química de coordinació com l’organometàl·lica i supramolecular s’han emprat per desenvolupar tres famílies de compostos amb propietats biològiques molt prometedores. S’han preparat complexos de Cu(II) amb imines (bases de Shiff) de diverses nuclearitats. S’ha trobat que els complexos interaccionen fortament amb l’ADN sense escindir-lo i tenen citotoxicitats elevades en diverses línies de cèl·lules canceroses de ratolí i també humanes. S’han estudiat també compostos organometàl·lics de Ru(II) amb fosfines terciàries PR3 i s’ha trobat que són molt citotòxics en un ampli espectre de línies cel·lulars canceroses humanes. A més, presententen un efecte antimetastàtic molt interessant. S’han establert relacions estructura-propietat, fet que il·lustra el gran potencial i versatilitat d’aquesta família de molècules perquè les propietats es poden modular segons el lligand fosfina unit al metall. Finalment, s’ha desenvolupat una nova família de compostos supramoleculars amb l’objectiu que interaccionin amb el solc gran de l’ADN i/o estabilitzar estructures no convencionals de l’ADN com per exemple unions triples (3WJ). Així doncs, s’ha trobat que els metal·lohelicats de Fe(III) que s’han preparat s’uneixen al solc major de l’ADN però no son capaços d’estabilitzar les unions triples 3WJ. Alguns d’aquests compostos presenten propietats citotòxiques interessants i un d’ells fins i tot indueix l’apoptosi cel·lular.
Marquez, Acuna Victoria Elena. "Coordination chemistry of macrocycles and metal complexes containing a nitrogen and sulphur donor set." Thesis, University of Cambridge, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.279727.
Повний текст джерела尹俊偉 and Chun-wai Wan. "Spectroscopic properties and coordination chemistry of d10 metal complexes with the polypyridyl and naphthyridyl ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B31223564.
Повний текст джерелаHager, Emma. "The design and synthesis of new transition metal coordination complexes as potential anti-malarial agents." Doctoral thesis, University of Cape Town, 2011. http://hdl.handle.net/11427/10667.
Повний текст джерелаPastor, Michael Bernard. "Bimetallic complexes: The fundamental aspects of metal-metal interactions, ligand sterics and application." Scholarly Commons, 2018. https://scholarlycommons.pacific.edu/uop_etds/3559.
Повний текст джерелаHewson, Sean. "Active metal template synthesis of [2]rotaxanes." Thesis, Queensland University of Technology, 2021. https://eprints.qut.edu.au/212366/1/Sean_Hewson_Thesis.pdf.
Повний текст джерелаHashiguchi, Ryota. "Studies on Polynuclear Metal Complexes and Low-Dimensional Mixed-Valence Halogen-Bridged Transition Metal Complexes Based on them." 京都大学 (Kyoto University), 2017. http://hdl.handle.net/2433/225426.
Повний текст джерелаOlson, Justine Rose. "Early transition metal and actinide coordination chemistry of a bicyclic guanidinate ligand: synthesis, characterization, and luminescence." Diss., University of Iowa, 2017. https://ir.uiowa.edu/etd/5588.
Повний текст джерелаCetin, Anil. "TRANSITION METAL COMPLEXES OF PORPHYRIN ANALOGS AND BORATE-BASED COORDINATION COMPLEXES." University of Akron / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=akron1176390111.
Повний текст джерелаHasan, Md Faruque. "Synthesis and Characterization of Cobalt-Based Coordination Complexes with Various Organic Linkers." Youngstown State University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1532001654030436.
Повний текст джерелаCollins, David J. "Synthesis of Heterobimetallic Clusters and Coordination Networks via Hard-Soft Interactions." Miami University / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=miami1209484624.
Повний текст джерелаClough, Benjamin. "New scandium and titanium borylimido chemistry." Thesis, University of Oxford, 2017. https://ora.ox.ac.uk/objects/uuid:1a9dbfb3-98c3-4fd6-96ac-5fba09f3ffcd.
Повний текст джерелаMouttaki, Hasnaa. "Quest toward the Design and Synthesis of Functional Metal-Organic Materials (MOMs): A Supermolecular Building Layer Approach (SBL)." Scholar Commons, 2015. https://scholarcommons.usf.edu/etd/5540.
Повний текст джерелаMoleko, Pulleng. "The coordination and extractive chemistry of the later 3d transition metal ions with N, N'-donor imidazole-based ligands." Thesis, Nelson Mandela Metropolitan University, 2014. http://hdl.handle.net/10948/8382.
Повний текст джерела