Дисертації з теми "Metal complexes and nanoparticles"
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Zapiter, Joan Marie Diangson. "Transition Metal Complexes Anchored on Europium Oxide Nanoparticles." Thesis, Virginia Tech, 2014. http://hdl.handle.net/10919/24786.
Повний текст джерелаMaster of Science
Kamras, Brian Leon. "Application-Focused Investigation of Monovalent Metal Complexes for Nanoparticle Synthesis." Thesis, University of North Texas, 2019. https://digital.library.unt.edu/ark:/67531/metadc1538771/.
Повний текст джерелаLuska, Kylie. "The catalytic application of ionic liquid-stabilized metal nanoparticles and molecular complexes." Thesis, McGill University, 2012. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=110575.
Повний текст джерелаLes liquides ioniques (LIs) ont fait l'objet d'une attention considérable en tant qu'alternatives potentielles aux solvants à base de composés organiques volatiles du fait de leur faible pression de vapeur saturante et de la facilité avec laquelle on peut les récupérer et les recycler. La recherche sur les LIs a par ailleurs révélé de nombreuses propriétés telles que : une grande stabilité chimique et thermique, de bonnes solubilités pour les gaz, une large fenêtre de stabilité électrochimique, une bonne conductivité électrique, une bonne mobilité ionique et une immiscibilité avec certains solvants organiques et l'eau. L'exploitation de ces propriétés ont étendues le champ des applications pour comprendre : la chimie analytique, la catalyse, l'électrochimie, la nanotechnologie, la synthèse et la purification. Cette thèse traite de l'utilisation des LIs pour la synthèse de nanoparticules (NPs) métalliques et de complexes, ainsi que de leur utilisation en catalyse biphasique. Des NPs métalliques ont été synthétisées directement dans les LIs à base de cations imidazolium ou phosphonium. Ces LIs jouent le rôle de solvant et de stabilisants électrostatiques pour les NPs. Des LIs fonctionnalisés avec une espèce ligante (i.e. un thiolate ou une phosphine), appelés LIs fonctionnalisés (LIFs), ont été employés pour la synthèse de NPs pour améliorer leur stabilité par attachement direct du LI à la surface métallique. Les NPs de métaux de transition ainsi obtenues sont très actives en catalyse biphasique d'hydrogénation des alcènes et des arènes et recyclables. Les LIFs ont également été employés comme ligands pour des complexes moléculaires utilisés en catalyse biphasique d'hydroformylation des oléfines à longue chaine. Au centre de cette étude, les paramètres moléculaires des LIs (i.e. le groupement cationique, la longueur de la chaine alkyle, le contre-ion) se sont révélés influer sur les propriétés des NPs métalliques et des complexes moléculaires (i.e. la taille des NPs, leur bande plasmon, leur stabilité en condition catalytique, leur activité catalytique et leur sélectivité). Les LIs constituent une classe de composés hautement versatiles, qui permettent le contrôle des propriétés des espèces métalliques qu'ils stabilisent.
Rogers, Nicola Jane. "The development of gold nanoparticles labelled with transition metal complexes for imaging applications." Thesis, University of Birmingham, 2014. http://etheses.bham.ac.uk//id/eprint/5058/.
Повний текст джерелаYakushev, I. A., N. Y. Kozitsyna, O. N. Kondratyeva, M. N. Vargaftik, and I. I. Moiseev. "Mixed-Metal Palladium(II) Complexes: a Way from Heterometallic Carboxylates to Bimetallic Nanoparticles." Thesis, Sumy State University, 2013. http://essuir.sumdu.edu.ua/handle/123456789/35239.
Повний текст джерелаThangwane, Selaelo Christabel. "Synthesis and characterization of substituted dithiocarbamates ligands and complexes as a source of metal (Pb, Ni & Co) sulphide nanoparticles." Thesis, Vaal University of Technology, 2017. http://hdl.handle.net/10352/396.
Повний текст джерелаLead, nickel and cobalt dithiocarbamates complexes were synthesized using methanol and water as solvents. All complexes were refluxed at 60 °C, cooled at room temperature, washed with methanol to remove the impurities and dried under the fume hood. A combination of Fourier transformer infrared (FTIR), elemental analysis (EA) and thermogravimetric analysis (TGA) were used to characterize these complexes. There was shifting of bands from low to high frequencies of the dithiocarbamates complexes compared to benzimidazole derivatives. The absence of the N-H band and the presence of new C=S bands confirmed that the complexes can be used in the preparation of metal sulphide nanoparticles. Elemental analysis showed that there was a percentage mismatch for the complexes I, III, IV and V. Complexes II and VI calculated percentages were within the limits with the found percentages except for sulphur which was low. The TGA curves decomposed to form a mixture of metal and metal sulphides for complex I, II, III and IV except for complex VI which gave metal sulphide only. All benzimidazole complexes decomposed at higher temperatures and were considered as stable complexes. Lead sulphide (PbS) is an important group IV-VI metal chalcogenide semiconductor. It has a direct narrow band gap of 0.41 eV at 300K and a large excitonic Bohr radius of 18 nm. Lead sulphide absorption band can be tuned to anywhere between near IR to UV (0.4μm) covering the entire visible spectrum, while achieving the quantum confinement region. The synthesis of lead sulphide nanoparticles was conducted by varying the effect of the reaction conditions such as the type of capping agents and temperature. Lead dithiocarbamate complex derived from benzimidazole, [Pb(S2N2C8H5)2] was thermolysed in hexadecylamine (HDA) and trioctylphosphine oxide (TOPO) at different reaction temperatures (140, 160 and 180 °C) to produce HDA and TOPO capped PbS nanoparticles. The nanoparticles were characterized using X-ray diffraction (XRD) for structural analysis, transmission electron microscopy (TEM) for shape and size, Ultraviolet visible (UV/Vis) and Photoluminescence (PL) spectroscopy for optical properties. An increase in temperature gave a decrease in the sizes of the nanoparticles when using the HDA capped lead benzimidazole dithiocarbamate complex. The observed morphology was cubes. TOPO capped lead benzimidazole dithiocarbamate complex gave no specific trend when temperature was varied. A cross-like layer with quasi spherical particles on top was observed at 160 °C. At 180 °C, the cross-like layer decomposed into rods- like materials with quasi spherical particles on top for TOPO capped PbS nanoparticles. For lead 2-methylbenzimidazole [Pb(S2N2C9H7)2] dithiocarbamate complex, TOPO capped PbS produced agglomerated cubic morphology at low temperature but as the temperature was increased agglomerated cylindrical shapes were observed. HDA capped PbS produced polydispersed nanocubes which were increasing in size when the temperature was increased. Nanoparticles displayed a blue shift in band edges with good photoluminescence behaviour which was red shifted from their respective band edges all temperatures and capping agents. XRD confirmed the crystal structure of cubic phase (galena) of PbS at all temperatures except for HDA capped PbS nanoparticles at 140 °C from lead benzimidazole dithiocarbamate complex which confirmed the crystal structure of face-centred cubic phase of PbS nanoparticles. Nickel sulphide has much more complicated phase diagram than cobalt sulfides and iron sulfides. Their chemical composition has many crystalline phases such as α-NiS, β=NiS, NiS2, Ni3S2, Ni3S4, Ni7S6 and Ni9S8. Ni3S2 phase has shown potential as a low-cost counter electrode material in dye sensitised solar cells, while the α-NiS phase has been applied as a cathode Material in lithium-ion batteries. The synthesis of nickel sulphide nanoparticles was done by varying the effect of the reaction conditions such concentration and temperature. Nickel benzimidazole dithiocarbamate [Ni(S2N2C8H5)2] and nickel 2-methylbenzimidazole [Ni (S2N2C9H7)2] dithiocarbamates complexes were thermolysed in hexadecylamine (HDA) at different reaction temperatures (140, 160 and 180 °C) and precursor concentrations (0.30, 0.35 and 0.40 g) to produce HDA capped NiS nanoparticles. It was observed that increasing both temperature and precursor concentration increased the size of the nanoparticles. Anisotropic particles were observed for both complexes when varying precursor concentration and temperature. Nickel benzimidazole dithiocarbamate complex produced stable shapes (spheres and cubes) of nickel sulphide nanoparticles. Nickel 2-methylbenzimidazole dithiocarbamate complex produced a mixture of spheres, cubes, triangles and rods nickel sulphide nanoparticles at all concentrations. But when varying temperature, it only produced that mixture at 160 °C. The optical measurements supported the presence of smaller particles at all temperatures and concentrations. XRD showed the presence of C7OS8 and pure nickel as impurities. However, the crystal structure of cubic Ni3S4 was observed at low temperatures and an introduction of monoclinic NixS6 at high temperature (180 °C) when varying temperature for both complexes. When varying concentration using nickel benzimidazole dithiocarbamate complex, XRD showed the presence of NiSO4.6H2O impurities at high temperatures. At 160 °C a mixture of hexagonal NiS and cubic Ni3S4 was observed. At low temperatures only nickel as a metal was found as an impurity and the crystal structure of cubic Ni3S4 was observed. When nickel 2-methylbenzimidazole complex was used, C7OS8 and pure nickel were found as impurities but the crystal structure of cubic Ni3S4 was observed. Cobalt sulphide (CoS) belongs to the family of group II-IV compounds with considerable potential for application in electronic devices. They have a complex phase diagram and their chemical composition have many phases such as Co4S3, Co9S8, CoS, Co1-xS, Co3S4, Co2S3 and CoS2. The synthesis of cobalt sulphide nanoparticles was conducted by varying the effect of temperature on size and shape of the nanoparticles. Nickel benzimidazole dithiocarbamate, [Ni(S2N2C8H5)2] and nickel 2-methylbenzimidazole [Ni(S2N2C9H7)2] complexes were thermolysed in hexadecylamine (HDA) at different reaction temperatures (140, 160 and 180 °C) to produce HDA capped CoS nanoparticles. Cobalt benzimidazole dithiocarbamate complex produced close to spherical shapes nanoparticles at all temperatures. The images showed that as temperature was increased, the size of the particles decreased. All the main reflection peaks were indexed to face-centred cubic Co3S4 and there were some impurities of C7OS8 at all temperatures. The optical measurements supported the presence of smaller particles at all temperatures. Cobalt 2-methylbenzimidazole dithiocarbamate complex produced big and undefined morphology. The optical properties were also featureless and XRD only showed impurities of C7OS8. The impurity is thought to be generated from a side reaction between benzimidazole and carbon disulphide to give this persistent organic moiety.
Roffey, A. R. "Dithiocarbamate complexes as single source precursors to metal sulfide nanoparticles for applications in catalysis." Thesis, University College London (University of London), 2014. http://discovery.ucl.ac.uk/1437012/.
Повний текст джерелаTilbury, Rhys David. "Investigation into Electronic Interactions Between Tetrazolato Complexes and Metal Nanoparticles Synthesised via Laser Ablation." Thesis, Curtin University, 2017. http://hdl.handle.net/20.500.11937/57109.
Повний текст джерелаZalich, Michael Andrew. "Physical Properties of Magnetic Macromolecule-Metal and Macromolecule-Metal Oxide Nanoparticle Complexes." Diss., Virginia Tech, 2005. http://hdl.handle.net/10919/27528.
Повний текст джерелаPh. D.
Eriksson, Kristofer. "Development and Applications of Surface-Confined Transition Metal Complexes : Heterogeneous Catalysis and Anisotropic Particle Surfaces." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2013. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-88215.
Повний текст джерелаAt the time of doctoral defence the following paper were unpublished and had a status as follows: Paper1: Manuscript; Paper 4: Manuscript
Atoini, Youssef. "New luminescent hybrid materials : synthesis and properties." Thesis, Strasbourg, 2017. http://www.theses.fr/2017STRAF004/document.
Повний текст джерелаThe aim of this thesis is the synthesis, characterization and investigation of luminescent metalcomplexes, and in particular of Pt(II) compounds, their aggregation properties in solution but inconfined space as well. The incorporation of transition metal complexes in porous structure, and inparticular in a metal-organic framework (MOF), by post-synthesis grafting, have been investigated.Luminescence properties of amphiphilic Pt(II) complexes were enhanced inside mesoporous silicananoparticles by the creation of a confined space. Similar effect is observed by deposition offunctionalized Pt(II) complexes on gold nanoparticles surface. Luminescence of metal organicframework was tuned by post-synthetic grafting of Ir(III) and Pt(II) complexes
TRASATTI, Andrea. "New heteroscorpionate and macrocyclic ligands, related metal complexes and novel Gold nanoparticles: synthesis, structure analysis and biological studies." Doctoral thesis, Università degli Studi di Camerino, 2013. http://hdl.handle.net/11581/401702.
Повний текст джерелаArnedo-Sanchez, Leticia. "Lanthanide and transition metal complexes as building blocks for supramolecular functional materials." Thesis, Strasbourg, 2016. http://www.theses.fr/2016STRAF047.
Повний текст джерелаThis thesis deals with coordination compounds based on transition metals and lanthanides as key components of functional materials. Besides a brief summary of photophysics, supramolecular gels and metal nanoparticles, an overview of the instruments and techniques employed in this work is included. This thesis is further divided into four chapters focused on optically active metalcomplexes (chapters 3 and 4), stimuli responsive metallogels (chapter 5) and functionalized nanomaterials for sensing applications (chapter 6). In chapter 3, the synthesis and characterization of anionic lanthanide complexes is reported. Analytical techniques, emission spectroscopy and X-ray crystallography were employed to characterize these complexes. ln chapter 4, the study of light emitting metal complexes is extended to transition metal complexes, in particular to iridium (lll) complexes. A family of neutral bis-cyclometallated iridium (lll) complexes that exhibit an intense red emission under photo- or electro-excitation is studied. ln chapter 5 the design and investigation of a new family of low molecular weight gelators based on perfluorinated terpyridines is reported. The morphology and mechanical and thermodynamical properties of these metallogels is studied. Chapter 6 studies the excellent cooperation between coordination compounds and nanomaterials to yield optical sensors. A new colorimetric sensor for pyrophosphate consisting of gold nanoparticles acting as reporting units functionalized with a thiol-modified aminoterpyridine-Zn complex is described
Santos, Jonnatan Julival dos. "Ouro: um metal multifuncional. Estudo das propriedades eletrônicas e espectroscópicas de suspensões e filmes de nanopartículas de ouro aplicados a sensoriamento." Universidade de São Paulo, 2013. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-16012014-081808/.
Повний текст джерелаGold nanoparticles are \"building blocks\" very versatile for the preparation of new functional hybrid nanomaterials . Their physicochemical properties allow the creation of systems capable of absorbing light, electron transportation, or even interact with molecules and biomolecules. In this thesis we studied the factors that influence the surface enhanced Raman scattering (SERS), in order to increase the sensitivity of the technique by forming composites with magnetic nanoparticles, as well as explore the coordinative assembly strategy for the preparation of hybrid nanomaterials containing complexes ruthenium for the development of sensors for molecules and/or molecular ions . Thus, it was shown how is possible to increase the Raman signal obtained by at least 30 % just controlling the relative number of molecules/gold nanoparticle. That is, it was found that the best signal to noise ratio was achieved with about 16 thousand of molecules per nanoparticle ~ 42 nm, more defined and generating spectra without the presence of undesirable bands, for example, associated with stabilizers. This property of gold nanoparticles was enhanced by association with superparamagnetic nanoparticles of iron oxide generating sensitive SERS substrates, reproducible, with simple preparation methodology and inexpensive. The interaction between the gold nanoparticles and superparamagnetic nanoparticles were monitored by electronic spectroscopy in the ultraviolet -visible, scanning electron microscopy and transmission electron microscopy and dark field and hyperspectral microscopy. It was found that the nanoparticles interact strongly which can be attracted and concentrated using a magnet for the realization of Raman spectroscopy measurements / SERS. This new methodology, and SERS substrate, allowing the quantification of methylene blue concentrations and phenantroline in the range of 5x10-9 to 5x10-11 mol dm-3. In fact , we observed an increase in the Raman signal up to 60 times when compared to the signal without the magnetic concentration. Finally, the interaction of gold nanoparticles with three different clusters trigonal ruthenium acetate (or simply ruthenium clusters) symmetrical with the ligand 4- cyanopyridine, 4,4\'-bispiridina and trans-1,2-bis(4-pyridyl) ethylene axial been explored as substituents for the preparation of functional coordination polymers. Ruthenium Clusters were characterized by electron spectroscopy in the ultraviolet-visible, electrochemical and spectroelectrochemical. After that, the ruthenium clusters were used as \"molecular rulers\", exploring the size difference and the fact that they can act as \" molecules-bridges \" for studies of plasmon coupling, following up this phenomenon by electronic spectroscopy in the ultraviolet - visible. The interaction between the gold nanoparticles and ruthenium clusters could be studied by spectroscopy, surface plasmon resonance (SPR), where it investigated the process of formation of films by the technique. These were characterized by Raman spectroscopy using laser excitation of 532 and 785 nm, which were observed vibrational bands of ruthenium clusters and contributions resonant electromagnetic and transfer cargana Raman enhancement. These hybrid nanomaterials were also immobilized on glass electrodes and conductive used as electrochemical sensors for the detection of nitrite concentrations in the range of 0.5 x10-6 to 1x10-3 mol dm-3.
Bräuer, Björn. "Synthesis of bis(oxamato) transition metal complexes and Ni nanoparticles and their structural, magnetic, optical, and magneto-optical characterization." Doctoral thesis, Universitätsbibliothek Chemnitz, 2008. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-200800928.
Повний текст джерелаEscárcega, Bobadilla Martha Verónica. "Organometallic compounds and metal nanoparticles as catalysts in low environmental impact solvents." Doctoral thesis, Universitat Rovira i Virgili, 2011. http://hdl.handle.net/10803/9114.
Повний текст джерелаAquesta Tesi s'enfoca en l'ús de mitjans de reacció alternatius i sostenibles, com són els líquids iònics (ILs), el diòxid de carboni supercrític (scCO2) i la barreja de ambdós dissolvents, amb l'objectiu de disminuir l'ús de dissolvents orgànics convencionals i la seva aplicació en els següents processos catalítics: hidrogenació asimètrica, reacció de Suzuki d'acoblament creuat C-C, reacció d'alquilació al·lílica asimètrica i la hidrogenació de arens.
In the last decades, the design of processes in the framework of the sustainable chemistry has been exponentially growing. The constant searching of cleaner processes has led to a lot of effort to obtain higher yields by activation of specific sites, and improving chemo-, regio- and enantio-selectivities, which are crucial from a point of view of an atom economy strategy. In this sense, solvents play a critical role.
This PhD thesis focuses on the use of alternative sustainable reaction media such as ionic liquids (ILs), supercritical carbon dioxide (scCO2) and mixtures of both solvents in different catalytic processes, with the aim of decreasing the use of conventional organic solvents applied in the following catalytic reactions: homogeneous and supported rhodium catalysed asymmetric hydrogenation, biphasic palladium catalysed Suzuki C-C cross-coupling, homogeneous palladium catalysed asymmetric allylic alkylation, and ruthenium and rhodium nanoparticles catalysed arene hydrogenation were tested.
Mefford, Olin Thompson. "Physical Properties of Macromolecule-metal oxide nanoparticle complexes: Magnetophoretic Mobility, Size, and Interparticle Potentials." Diss., Virginia Tech, 2007. http://hdl.handle.net/10919/28133.
Повний текст джерелаPh. D.
Manrique, Salas Ester. "Development of new transition metal complexes for their use in sustainable catalytic processes and as antitumoral agents." Doctoral thesis, Universitat de Girona, 2018. http://hdl.handle.net/10803/668830.
Повний текст джерелаEn aquesta tesi es presenta la síntesi de diferents tipus de complexos de ruteni i manganès que contenen lligands N-donadors en combinació amb altres lligands monodentats, i la seva completa caracterització mitjançant tècniques espectroscòpiques i electroquímiques. Els complexos han estat avaluats com a catalitzadors en epoxidació d'olefines i hidròlisi de nitrils en fase homogènia. Per altra banda, tenint en compte la importància i els avantatges de la catàlisi heterogènia, s’ha dut a terme la immobilització d’alguns d’aquests complexos sobre suports tipus sílice i nanopartícules magnètiques i se n'ha avaluat l'activitat catalítica, comparant-los amb els anàlegs en fase homogènia, i s'han pogut reutilitzar durant diversos cicles mantenint alts valors de selectivitat per l'epòxid. Alguns dels complexos, juntament amb d'altres sintetitzats anteriorment al grup de recerca, han estat avaluats com agents antitumorals
HONEMANN, YVONNE CARINA. "DESIGN, CHARACTERIZATION AND APPLICATION OF HETEROGENEOUS SILICA SUPPORTED CATALYSTS, BASED ON PD NANOPARTICLES AND METAL SINGLE SITES (RH, CU)." Doctoral thesis, Università degli Studi di Milano, 2013. http://hdl.handle.net/2434/214937.
Повний текст джерелаUpadhyay, Prabhat Kumar. "Design, Synthesis, and Characterization of Aqueous Polymeric Hybrid Composites and Nanomaterials of Platinum(II) and Gold(I) Phosphorescent Complexes for Sensing and Biomedical Applications." Thesis, University of North Texas, 2015. https://digital.library.unt.edu/ark:/67531/metadc822788/.
Повний текст джерелаTambosi, Reem. "Stress and toxicity of metal in photosynthetic bacteria : multi-scale study of the effects and the targets of metal ions and nanoparticles Silver and Copper Acute Effects on Membrane Proteins and Impact on Photosynthetic and Respiratory Complexes in Bacteria Silver Effect on Bacterial Cell Membrane Structure Investigated by Atomic Force and Scanning Electron Microscopes Cadmium and Copper Cross-tolerance. Cu+ alleviates Cd2+ toxicity, and both cations target heme and chlorophyll biosynthesis pathway in Rubrivivax gelatinosus Additive effects of metal excess and superoxide, a highly toxic mixture in bacteria." Thesis, université Paris-Saclay, 2020. http://www.theses.fr/2020UPASL070.
Повний текст джерелаThe extensive use of metal ions in industry and agriculture represents a serious threat to the environment and to all living being because of the acute toxicity of these ions. However, it can also be a promising tool, silver ions and nanoparticles are some of the most widely used metals in various industrial and health applications. The antimicrobial effect of these nanoparticles is in part related to the released Ag⁺ ions and their ability to interact with bacterial membranes. The goal of this project is to study the interaction between biological subject (the bacteria) and physical objects (metals), and more specifically to understand the impact of metals in different forms (ions, nanoparticles and nanostructures) on the growth of the bacterial cells using different approaches : physiology, biochemistry, genetics and cell biology. We used as biological models, principally the purple photosynthetic bacterium Rubrivivax (R.) gelatinosus, but also Escherichia coli; and for physical objects, we used silver as main metal but also other metals (copper, cadmium and nickel) for comparison. The main objectives are: 1- to study the impact and the mechanisms of toxicity of these metallic ions/NPs on the bacterial respiratory and photosynthesis metabolisms. 2- To identify the bacterial genes involved in response to excess silver. 3- To study the internalization and interaction of metals ions and NPs within biological membranes. The results showed that we were able to identify, both in vitro and in vivo, specific targets of Ag⁺ and Cu²⁺ ions within the membrane of bacteria. This include complexes involved in photosynthesis, but also complexes involved in respiration. Ag⁺ and Cu²⁺ were shown to specificaly target a solvent exposed bacteriochlorophyll in the light harvesting antennae of the photosystem. This also presents, in our knowledge, the first direct evidence of silver ions damages to membrane proteins involved in these metabolisms. We also carried out a microscopy (AFM/ SEM) comparative study of the effect of Ag⁺ ions or Ag-NPs synthesized in our laboratory, on the bacterial cell morphology
Carrara, Serena. "Towards new efficient nanostructured hybrid materials for ECL applications." Thesis, Strasbourg, 2017. http://www.theses.fr/2017STRAF016/document.
Повний текст джерелаThis doctoral dissertation aim to develop new hybrid materials for ECL applications. In the field of metal complexes, the electrochemiluminescent properties of new Pt(II) and Ir(III) complexes were investigated as alternative of existing complexes. Passing to nanomaterials, the combination of labels and NCNDs bearing primary or tertiary groups on the surface as alternative co-reactant species resulted an interesting strategy to eliminate the toxic TPrA. In particular, NCNDs in covalently linked system with metal complexes is not only an innocent carrier for ECL active species, but act also as co-reactant in the ECL process, revealing itself an ECL self-enhancing platform. Finally, a real immunoassay for cardiac marker detection has been built with enhanced sensitivity and stability, which is of fundamental importance for biological and bio-medical detection applications. The same technology can be applied to a variety of other analytes opening the venue to other assays
Rico, Santacruz Marisa. "Band gap control in hybrid titania photocatalysts." Doctoral thesis, Universidad de Alicante, 2014. http://hdl.handle.net/10045/42201.
Повний текст джерелаDeVries, Gretchen Anne. "Divalent metal nanoparticles." Thesis, Massachusetts Institute of Technology, 2008. http://hdl.handle.net/1721.1/44387.
Повний текст джерелаIncludes bibliographical references.
Metal nanoparticles hold promise for many scientific and technological applications, such as chemical and biological sensors, vehicles for drug delivery, and subdiffraction limit waveguides. To fabricate such devices, a method to position particles in specific locations relative to each other is necessary. Nanoparticles tend to spontaneously aggregate into ordered two- and three-dimensional assemblies, but achieving one-dimensional structures is less straightforward. Because of their symmetry, nanoparticles lack the ability to bond along specific directions. Thus, the technological potential of nanoparticles would be greatly enhanced by the introduction of a method to break the interaction symmetry of nanoparticles, thus inducing valency and directional interparticle interactions. When a nanoparticle is coated with a mixture of two different ligands, the ligands have been shown to phase-separate into ordered domains encircling or spiraling around the core. Topological constraints inherent in assembling two-dimensional vectors (e.g., ligands) onto a sphere (the core of the nanoparticle) dictate the necessary formation of two diametrically opposed defect points within the ligand shell. The molecules at these points are not optimally stabilized by intermolecular interactions and thus these sites are highly reactive. By functionalizing the polar singularities with a third type of molecule, we generate divalent nanoparticles with "chemical handles" that can be used to direct the assembly of the particles into chains. For example, taking inspiration from the wellknown interfacial polymerization synthesis of nylon, we place carboxylic acid terminated molecules at the polar defect points and join the newly bifunctional nanoparticles into chains by reacting them with 1,6-diaminohexane through an interfacial reaction.
(cont.) Furthermore, we perform a full kinetic and thermodynamic characterization of the molecularly defined polar defect points. We demonstrate that the rate of place-exchange at these points is significantly faster than it is elsewhere in the ligand shell. We also determine the equilibrium constant and standard free energy of the place-exchange reaction at the polar defect sites and demonstrate that the reaction is strongly affected by the molecular environment, i.e. the composition of the ligand shell.
by Gretchen Anne DeVries.
Ph.D.
Kumar, Sachin. "Electrocatalysis at Metal Nanoparticles." Miami University / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=miami1218138524.
Повний текст джерелаChui, Yu-hang, and 崔宇恒. "Molecular simulations of metal nanoparticles." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2003. http://hub.hku.hk/bib/B29288733.
Повний текст джерелаRogers, S. M. "Designing metal nanoparticles for catalysis." Thesis, University College London (University of London), 2017. http://discovery.ucl.ac.uk/1560408/.
Повний текст джерелаMartinsson, Erik. "Nanoplasmonic Sensing using Metal Nanoparticles." Doctoral thesis, Linköpings universitet, Molekylär fysik, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-111841.
Повний текст джерелаBahadory, Mozhgan Solomon Sally. "Synthesis of noble metal nanoparticles /." Philadelphia, Pa. : Drexel University, 2008. http://hdl.handle.net/1860/2901.
Повний текст джерелаBrayshaw, Simon Keith. "Metal complexes bearing pendant alkynes and metal complexes of N-heterocyclic carbenes." University of Western Australia. School of Biomedical and Chemical Sciences, 2004. http://theses.library.uwa.edu.au/adt-WU2005.0017.
Повний текст джерелаBarron, Andrew Ross. "Transition metal aluminohydride complexes." Thesis, Imperial College London, 1986. http://hdl.handle.net/10044/1/37935.
Повний текст джерелаAlem, Nassreen. "Zeolite encapsulated metal complexes." Thesis, University of Reading, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239055.
Повний текст джерелаJasim, Naseralla. "Transition metal bifluoride complexes." Thesis, University of York, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.323538.
Повний текст джерелаBuha, Jelena. "Nonaqueous syntheses of metal oxide and metal nitride nanoparticles." Phd thesis, Universität Potsdam, 2008. http://opus.kobv.de/ubp/volltexte/2008/1836/.
Повний текст джерелаNanostrukturierte Materialien sind Materialien, die aus nanopartikulären Baueinheiten in der Größenordnung von Nanonmetern (d.h. 10-9 m) bestehen. Zusammensetzung, Kristallinität und Morphologie können die natürlichen Eigenschaften dieser Materialien verbessern oder zusätzliche Eigenschaften erzeugen, die für heutige und zukünftige Anwendungen und Verfahren wünschenswert sind. In dieser Arbeit präsentieren wir neue Strategien zur Synthese von Nanopartikeln der Metaloxide und Metalnitride. Im einführenden Teil wird die nichtwässrige Synthese von Metaloxidnanopartikeln beschrieben. Uns gelang die Darstellung von In2O3 Nanopartikeln, deren Größe und Form wir durch die Wahl des Prekursors und des Lösemittels deutlich beeinflussen konnten; von ZnO Mesokristallen durch den Einsatz von Acetonitril als Lösemittel; von Übergangsmetalloxiden (Nb2O5, Ta2O5 and HfO2), die besonders schwer im Nanomaßstab zu erhalten sind und von anderen, technisch relevanten Materialien. Die Möglichkeiten der solvothermalen Synthese sind nicht mit der Darstellung von Oxidmaterialen erschöpft. Im zweiten Teil zeigen wir einige Beispiele nichtwässriger, solvothermaler Synthese von Metalnitriden auf; das Hauptaugenmerk liegt aber auf einer Betrachtung der Einflüsse der Morphologie von Metaloxidnanopartikelprekursoren auf die Bildung der Metalnitridnanopartikel. Die Anzahl und Vielfalt bekannter nanokristalliner Metalnitride ist verschwindend klein im Vergleich zu den Metaloxiden, die in der Fachliteratur etabliert sind und demzufolge einen reichen Baukasten an Prekursoren zur Darstellung von Metalnitriden liefern. Durch die Reaktion von Metaloxidnanopartikeln mit Cyanamid, Urea oder Melamine bei Temperaturen von 800 bis 900 °C unter Stickstofffluss konnten Metalnitride erhalten werden. Eine detaillierte Studie der Reaktionsbedingungen und des Reaktionsablaufs zeigte auf, dass Größe und Kristallinität der Metaloxide, die Art der Stickstoffquelle und die Temperatur die entscheidenden Faktoren sind und legte eine Auflösungs-Rekristallisation als Modelmechanismus dieser Art Reaktion nahe. Darüber hinaus konnte gezeigt worden, dass die anfängliche Morphologie des Oxids unter einem Ammoniafluss beibehalten werden konnte.
Warne, Barnaby. "Nanoparticles prepared from reactive metal surfactants." Thesis, University of Bristol, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.311430.
Повний текст джерелаGaskell, Christine V. "Tailored metal nanoparticles for selective catalysis." Thesis, Cardiff University, 2012. http://orca.cf.ac.uk/44554/.
Повний текст джерелаSteven, Christopher R. "Plasmonic metal nanoparticles : synthesis and applications." Thesis, University of Strathclyde, 2017. http://digitool.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=27939.
Повний текст джерелаAksomaityte, Gabriele. "Synthesis of metal and metal oxide nanoparticles in supercritical fluids." Thesis, University of Nottingham, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.523001.
Повний текст джерелаTejpal, Jyoti. "The use of metal and metal oxide nanoparticles against biofilms." Thesis, De Montfort University, 2016. http://hdl.handle.net/2086/13114.
Повний текст джерелаAnderson, Amanda E. "Strategic immobilisation of catalytic metal nanoparticles in metal-organic frameworks." Thesis, University of St Andrews, 2017. http://hdl.handle.net/10023/10816.
Повний текст джерелаHumphrey, Elizabeth Rebecca. "Tris(pyrazolyl)borate metal complexes : new ligands and metal-metal interactions." Thesis, University of Bristol, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.340301.
Повний текст джерелаZhao, Ningfeng Eichhorn David M. "Cyano-substituted polypyrazolylborate metal complexes." Diss., Click here for available full-text of this thesis, 2005. http://library.wichita.edu/digitallibrary/etd/2005/d019.pdf.
Повний текст джерела"December 2005." Title from PDF title page (viewed on February 8, 2007). Thesis adviser: David Eichhorn. Includes bibliographic references (leaves 123-128).
Rao, Sumitrananda N. R. "Novel adsorbents using metal complexes." Thesis, Georgia Institute of Technology, 1993. http://hdl.handle.net/1853/10200.
Повний текст джерелаFelsher, Dave. "Electrowinning of metal - DETA complexes." Thesis, McGill University, 2000. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=33329.
Повний текст джерелаRecycle tests for copper showed that a steady DETA concentration was achieved after ca. six hours. In the case of nickel, the system seemed to continually deteriorate. A pH range of 4.6 to 4.8 maximized the current efficiency, due to a competition between hydrogen formation at low pH and increased complex stability at high pH. Both increasing Ni concentration and temperature increased the current efficiency, while increasing the DETA to nickel ratio lowered it.
Tovilla, Cao-Romero Jorge Alberto Francisco. "Molecular recognition with metal complexes." Thesis, Imperial College London, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.436343.
Повний текст джерелаHarrison, Simon. "Metal-arene complexes and clusters." Thesis, University of Nottingham, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.280332.
Повний текст джерелаJones, P. "Studies of chiral metal complexes." Thesis, Bucks New University, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373593.
Повний текст джерелаBlackwell, Elizabeth Sarah. "Fluxionality in organonitrogen metal complexes." Thesis, University of Exeter, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.332328.
Повний текст джерелаHarrison, Stephen Anthony. "Novel chiral cyclopentadienyl metal complexes." Thesis, University of Southampton, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.442873.
Повний текст джерелаVeighy, Clifford Robert. "Novel cyclopentadienyl transition metal complexes." Thesis, University of Southampton, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.327366.
Повний текст джерела