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1

Renne, Paul R. "Progress and Challenges in K-Ar and40Ar/39Ar Geochronology." Paleontological Society Papers 12 (October 2006): 47–66. http://dx.doi.org/10.1017/s1089332600001340.

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K-Ar and more recently the40Ar/39Ar variant are well established dating methods. The40Ar/39Ar method requires irradiation with neutrons, posing some complications that are greatly outweighed by the benefits. The40Ar/39Ar method is particularly powerful due to the availability of internal reliability criteria, the ability to analyze single crystals, and the amenability of the analyses to automation.40Ar/39Ar dating has the capability for unsurpassed precision and is applicable to the broadest range of geologic environments and time scales of any radioisotope dating technique. For chronostratigraphic applications,40Ar/39Ar is most important in the Cenozoic, becoming progressively less useful into the early Phanerozoic due to alteration and loss of radiogenic argon. Precision and accuracy of40Ar/39Ar dating have been improved considerably in recent years, but an uncertainty of about 1% in the decay constant for40K, probably mainly in the electron capture decay branch, still limits accuracy at about this level. Inconsistent use of standards (neutron fluence monitors) and attribution of variable ages to standards is still a source of confusion, but straightforward recalculation procedures can overcome the underlying problems provided that appropriate standards are used.
2

Carter, Jack, Ryan B. Ickert, Darren F. Mark, Marissa M. Tremblay, Alan J. Cresswell, and David C. W. Sanderson. "Production of <sup>40</sup>Ar by an overlooked mode of <sup>40</sup>K decay with implications for K-Ar geochronology." Geochronology 2, no. 2 (November 26, 2020): 355–65. http://dx.doi.org/10.5194/gchron-2-355-2020.

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Abstract. The decay of 40K to the stable isotopes 40Ca and 40Ar is used as a measure of time for both the K-Ca and K-Ar geochronometers, the latter of which is most generally utilized by the variant 40Ar∕39Ar system. The increasing precision of geochronology has forced practitioners to deal with the systematic uncertainties rooted in all radioisotope dating methods. A major component of these systematic uncertainties for the K-Ar and 40Ar∕39Ar techniques is imprecisely determined decay constants and an incomplete knowledge of the decay scheme of 40K. Recent geochronology studies question whether 40K can decay to 40Ar via an electron capture directly to ground state (ECground), citing the lack of experimental verification as reasoning for its omission. In this study, we (1) provide a theoretical argument in favor of the presence of this decay mode and (2) evaluate the magnitude of this decay mode by calculating the electron capture to positron ratio (ECground/β+) and comparing calculated ratios to previously published calculations, which yield ECground/β+ between 150–212. We provide support for this calculation through comparison of the experimentally verified ECground/β+ ratio of 22Na with our calculation using the theory of β decay. When combined with measured values of β+ and β− decay rates, the best estimate for the calculated ECground/β+ for 40K yields a partial decay constant for 40K direct to ground-state 40Ar of 11.6±1.5×10-13 a−1 (2σ). We calculate a partial decay constant of 40K to 40Ar of 0.592±0.014×10-10 a−1 and a total decay constant of 5.475±0.107×10-10 a−1 (2σ), and we conclude that although omission of this decay mode can be significant for K-Ar dating, it is minor for 40Ar∕39Ar geochronology and is therefore unlikely to have significantly biased published measurements.
3

Lentz, Carlin, Kathleen Thorne, Christopher R. M. McFarlane, and Douglas A. Archibald. "U-Pb, Ar-Ar, and Re-Os Geochronological Constraints on Multiple Magmatic–Hydrothermal Episodes at the Lake George Mine, Central New Brunswick." Minerals 10, no. 6 (June 23, 2020): 566. http://dx.doi.org/10.3390/min10060566.

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The Lake George antimony mine was at one time North America’s largest producer of antimony. Despite being widely known for the antimony mineralization, the deposit also hosts a range of styles of mineralization such as multiple generations of W-Mo bearing quartz veins as well as a system of As-Au bearing quartz–carbonate veins. In situ U-Pb zircon geochronology, using LA ICP-MS, of the Lake George granodiorite yielded a weighted mean 206Pb/238U age of 419.6 ± 3.0 Ma. Step heating of phlogopite separated from the lamprophyre dykes produced a 40Ar/39Ar plateau segment date of 419.4 ± 1.4 Ma. Single molybdenite crystal analysis for Re-Os geochronology was conducted on two W-Mo-bearing quartz veins, which cross-cut altered granodiorite and altered metasedimentary rocks and yielded two dates of 415.7 ± 1.7 Ma and 416.1 ± 1.7 Ma respectively. 40Ar/39Ar geochronology of muscovite from alteration associated with Au-bearing quartz–carbonate veins yielded one representative plateau segment date of 414.1 ± 1.3 Ma. The dates produced in this study revealed that the different magmatic–hydrothermal events at the Lake George mine occurred over approximately a 10-million-year period at the end of the Silurian and the start of the Devonian following the termination of the Acadian orogeny.
4

MacIntyre, D. G., and M. E. Villeneuve. "Geochronology of mid-Cretaceous to Eocene magmatism, Babine porphyry copper district, central British Columbia." Canadian Journal of Earth Sciences 38, no. 4 (April 1, 2001): 639–55. http://dx.doi.org/10.1139/e00-107.

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New U/Pb and 40Ar/39Ar isotopic dating in the Babine porphyry copper district of central British Columbia documents three distinct magmatic events at 107–104, 85–78, and 54–50 Ma. The earliest event involved emplacement of rhyolite domes into submarine volcanic rocks of the Rocky Ridge Formation. The rhyolite domes and related dacitic to basaltic volcanic rocks gave a U–Pb age of 107.9 ± 0.2 Ma and an 40Ar/39Ar age of 104.8 ± 1.2 Ma. The rhyolites, which were previously mapped as Eocene, are reinterpreted to be part of a previously unrecognized mid-Cretaceous cauldron subsidence complex. The regionally extensive Late Cretaceous magmatic event is also recognized in the Babine district and is represented by 40Ar/39Ar ages of 85.2 ± 2.8 and 78.3 ± 0.8 Ma on two Bulkley intrusions, one of which has associated porphyry copper mineralization. The final magmatic event is the most widespread and involved emplacement of the Babine intrusions and formation of numerous porphyry copper deposits including the Bell and Granisle past producers. Twenty-one new 40Ar/39Ar isotopic ages for these intrusions and coeval andesites of the Newman Formation have a narrow range from 53.6 ± 0.9 to 49.9 ± 0.6 Ma, whereas previous K–Ar isotopic dating had a possible range of 15 Ma. The mid-Cretaceous, Late Cretaceous, and Eocene magmatic suites in the Babine district are interpreted to be part of a long-lived volcano-plutonic complex that was the site of periodic magmatism and porphyry copper mineralization over a 60 Ma time period. This complex may have evolved within a zone of extension (pull-apart basins) situated between dextral strike-slip faults that were active during periods of rapid oblique plate convergence.
5

Reid, Anthony, Marnie Forster, Wolfgang Preiss, Alicia Caruso, Stacey Curtis, Tom Wise, Davood Vasegh, Naina Goswami, and Gordon Lister. "Complex 40Ar ∕ 39Ar age spectra from low-grade metamorphic rocks: resolving the input of detrital and metamorphic components in a case study from the Delamerian Orogen." Geochronology 4, no. 2 (July 20, 2022): 471–500. http://dx.doi.org/10.5194/gchron-4-471-2022.

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Abstract. In this study, we provide 40Ar / 39Ar geochronology data from a suite of variably deformed rocks from a region of low-grade metamorphism within the Cambro–Ordovician Delamerian Orogen, South Australia. Low-grade metamorphic rocks such as these can contain both detrital minerals and minerals newly grown or partly recrystallised during diagenesis and metamorphism. Hence, they typically yield complex 40Ar / 39Ar age spectra that can be difficult to interpret. Therefore, we have undertaken furnace step heating 40Ar / 39Ar geochronology to obtain age spectra with many steps to allow for application of the method of asymptotes and limits and recognition of the effects of mixing. The samples analysed range from siltstone and shale to phyllite and contain muscovite or phengite with minor microcline as determined by hyperspectral mineralogical characterisation. Whole rock 40Ar / 39Ar analyses were undertaken in most samples due to their very fine-grained nature. All samples are dominated by radiogenic 40Ar, and contain minimal evidence for atmospheric Ca- or Cl-derived argon. Chloritisation may have resulted in limited recoil, causing 39Ar argon loss in some samples, which is especially evident within the first few percent of gas released. Most of the age data, however, appear to have some geological significance. Viewed with respect to the known depositional ages of the stratigraphic units, the age spectra from this study do appear to record both detrital mineral ages and ages related to the varying influence of either cooling or deformation-induced recrystallisation. The shape of the age spectra and the degree of deformation in the phyllites suggest the younger ages may record recrystallisation of detrital minerals and/or new mica growth during deformation. Given that the younger limit of deformation recorded in the high-metamorphic-grade regions of the Delamerian Orogen is ca. 490 Ma, the ca. 470 to ca. 458 Ma ages obtained in this study suggest deformation in low-grade shear zones within the Delamerian Orogen may have persisted until ca. 20–32 million years after high-temperature ductile deformation in the high-grade regions of the orogen. We suggest that these younger ages for deformation could reflect reactivation of older structures formed both during rift basin formation and during the main peak of the Delamerian orogeny itself. The younger ca. 470 to ca. 458 Ma deformation may have been facilitated by far-field tectonic processes occurring along the eastern paleo-Pacific margin of Gondwana.
6

Hart, Craig JR, and Mike Villeneuve. "Geochronology of Neogene alkaline volcanic rocks (Miles Canyon basalt), southern Yukon Territory, Canada: the relative effectiveness of laser 40Ar/39Ar and K-Ar geochronology." Canadian Journal of Earth Sciences 36, no. 9 (September 1, 1999): 1495–507. http://dx.doi.org/10.1139/e99-049.

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Miles Canyon basalt is an informal term used to describe numerous exposures of young alkaline olivine basalt flows in southern Yukon. The volcanic rocks are part of the Northern Cordilleran volcanic province. K-Ar and Ar-Ar whole-rock dates indicate that the Miles Canyon succession of flows at the Whitehorse Rapids are clearly Late Miocene in age (ca. 8.4 Ma). The largest exposure of the Miles Canyon basalt occurs at the Alligator Lake volcanic complex where two nearly concordant Pliocene Ar-Ar dates indicate eruption at ca. 3.2 Ma. K-Ar analyses from other sites yield dates of 2.4 and 7.1 Ma and indicate an episodic Neogene volcanic history for the region. There is no evidence of Quaternary or postglacial volcanism. The dates are older than assumed by previous workers, and in some cases the K-Ar dates are strongly discordant from Ar-Ar determinations. More accurate Ar-Ar determinations may result from the method's ability to select smaller amounts of better material for analysis. Excess 40Ar was not encountered. As a result, the accuracy of any single or several discordant K-Ar determinations for Neogene subaerial volcanic rocks, particularly low-K rocks such as basalts, should be questioned and resulting interpretations made with caution. Models accounting for the eruption of the Northern Cordilleran volcanic province lavas have typically relied upon extension along north-trending faults that were generated by stresses along the continental margin. However, we consider a slab window model which better accounts for the initiation and distribution of northern Cordilleran Neogene volcanic activity.
7

VASCONCELOS, PAULO M., ARTUR T. ONOE, KOJI KAWASHITA, ADALBERTO J. SOARES, and WILSON TEIXEIRA. "40Ar/39Ar geochronology at the Instituto de Geociências, USP: instrumentation, analytical procedures, and calibration." Anais da Academia Brasileira de Ciências 74, no. 2 (June 2002): 297–342. http://dx.doi.org/10.1590/s0001-37652002000200008.

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Laser heating 40Ar/39Ar geochronology provides high analytical precision and accuracy, mum-scale spatial resolution, and statistically significant data sets for the study of geological and planetary processes. A newly commissioned 40Ar/39Ar laboratory at CPGeo/USP, São Paulo, Brazil, equips the Brazilian scientific community with a new powerful tool applicable to the study of geological and cosmochemical processes. Detailed information about laboratory layout, environmental conditions, and instrumentation provides the necessary parameters for the evaluation of the CPGeo/USP 40Ar/39Ar suitability to a diverse range of applications. Details about analytical procedures, including mineral separation, irradiation at the IPEN/CNEN reactor at USP, and mass spectrometric analysis enable potential researchers to design the necessary sampling and sample preparation program suitable to the objectives of their study. Finally, the results of calibration tests using Ca and K salts and glasses, international mineral standards, and in-house mineral standards show that the accuracy and precision obtained at the 40Ar/39Ar laboratory at CPGeo/USP are comparable to results obtained in the most respected laboratories internationally. The extensive calibration and standardization procedures undertaken ensure that the results of analytical studies carried out in our laboratories will gain immediate international credibility, enabling Brazilian students and scientists to conduct forefront research in earth and planetary sciences.
8

Wu, Meng, Liang Li, Jing-gui Sun, and Rui Yang. "Geology, geochemistry, and geochronology of the Laozuoshan gold deposit, Heilongjiang Province, Northeast China: implications for multiple gold mineralization events and geodynamic setting." Canadian Journal of Earth Sciences 55, no. 6 (June 2018): 604–19. http://dx.doi.org/10.1139/cjes-2018-0038.

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The Laozuoshan gold deposit, located in the central part of the Jiamusi Massif, is hosted by the contact zone between granitic complex and Proterzoic strata. In this study, we present the results of geochronology and geochemistry of ore-related granodiorite and diorite porphyry, and hydrothermal sericite 40Ar/39Ar dating. The granodiorite and diorite porphyry in the Laozuoshan gold deposit are calc-alkaline and high-K (calc-alkaline) series, which are enriched in LREE and LILE and depleted in HFSE, with no depletion of Eu. The geochronology data show that zircon U–Pb ages of the granodiorite and diorite porphyry are ∼262 Ma and ∼105 Ma, respectively. The sericite 40Ar/39Ar ages are ∼194 Ma and ∼108 Ma. On the basis of previous researches, ore geology and geochronology studies show that the Laozuoshan gold deposit underwent at least two gold mineralization events. We suggest that the first one, which was related to skarnization, resulted from the collision between the Jiamusi and Songnen Massifs in Late Permian. The subsequent gold mineralization resulted from the subduction of the paleo-Pacific Plate in Early Cretaceous.
9

Radhakrishna, T., H. Maluski, J. G. Mitchell, and M. Joseph. "40Ar/39Ar and K/Ar geochronology of the dykes from the south Indian granulite terrain." Tectonophysics 304, no. 1-2 (March 1999): 109–29. http://dx.doi.org/10.1016/s0040-1951(98)00288-1.

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10

Dunlop, David J. "Grenvillia and Laurentia — a Precambrian Wilson cycle?" Canadian Journal of Earth Sciences 51, no. 3 (March 2014): 187–96. http://dx.doi.org/10.1139/cjes-2013-0101.

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John Tuzo Wilson coined the term “plate” in plate tectonics. He is famous for inventing transform boundaries, hot spot tracks, and the Wilson cycle of ocean birth, growth, and decline. Less well remembered is his work in the 1950s on tectonic and radiometric age provinces of the Canadian Shield, as part of which he fathered U/Pb geochronology in Canada. This work gave strong support to the notion of continental growth through accretion of successively younger terranes onto an ancient cratonic core. The present paper reviews how paleomagnetism can trace the motions of continents to test Wilson’s ideas. Continental accretion often involves deep burial of one of the colliding elements through subduction or crustal underplating; such was the case with the Grenville orogen and its subprovinces in their Proterozoic accretion onto the Laurentian craton. The resulting heating and metamorphism erases most pre-collisional magnetic information but adds something new: the possibility of following the post-metamorphic uplift and cooling history, in time and space. The time element is provided by a new form of isotopic geochronology, thermochronometry, which provides dates for specific minerals together with the temperatures at which they became closed to isotopic migration. U/Pb dating of sphene is one method used; another is the 40Ar/39Ar variant of K/Ar dating applied to hornblende, micas, and feldspars, which have a wide range of Ar closure temperatures. The two specific Grenville studies described deal with parallel uplift histories determined by 40Ar/39Ar dating and by magnetics for the accreted terranes of the Central Metasedimentary Belt in Ontario and with the paleomagnetic detection of the post-1240 Ma closing of a small ocean between the Elsevir terrane and Laurentia during the Grenvillian orogeny.
11

Webster, Ewan R., Douglas A. Archibald, David R. M. Pattison, Jessica A. Pickett, and Joel C. Jansen. "Tectonic domains and exhumation history of the Omineca Belt in southeastern British Columbia from 40Ar/39Ar thermochronology." Canadian Journal of Earth Sciences 57, no. 8 (August 2020): 918–46. http://dx.doi.org/10.1139/cjes-2019-0131.

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A large geochronological data set comprising 40Ar/39Ar and K–Ar (hornblende, muscovite, biotite, and K-feldspar), Rb–Sr (muscovite), fission track (zircon and apatite) and U–Pb (zircon and monazite) dates has been compiled for the southern Kootenay Arc and western Purcell anticlinorium in the Omineca Belt of the Canadian Cordillera in southeastern British Columbia. New 40Ar/39Ar data for hornblende, muscovite, biotite, and alkali feldspar are presented and combined with data from other studies. We integrate these data with recent advances in the geology of the region to define three partially fault-bounded domains with differing geological and exhumation histories, here termed the western, central, and eastern domains. The western domain is characterized by (1) late synkinematic Jurassic plutons with hornblende, muscovite, and biotite 40Ar/39Ar plateau dates between 170 and 165 Ma, some of which are within error of the U–Pb zircon dates for these plutons, and (2) late Early Cretaceous (118–102 Ma) plutons commonly with concordant mica 40Ar/39Ar plateau dates of a similar age range, indicating rapid cooling following emplacement of both suites. The central domain is bounded by regional-scale normal faults (Gallagher and Midge Creek faults, Blazed Creek/Next Creek faults, and Purcell Trench fault) and contains superposed Early and Late Cretaceous zones of Barrovian metamorphic rocks and several mid- to Late Cretaceous, post-kinematic plutons. The transition from the western domain into the central domain is characterized by 40Ar/39Ar mica age spectra showing a progression of increasing thermal overprinting. Along the north–south length of the central domain, biotite and muscovite yield Paleocene to Eocene K–Ar and 40Ar/39Ar plateau dates between 66 and 40 Ma. The eastern domain consists of (1) a southern portion that occurs in the hanging wall of the Purcell Trench fault, comprising mid-Cretaceous intrusions of the Bayonne magmatic suite emplaced into biotite zone metasedimentary rocks of the Mesoproterozoic Belt-Purcell Supergroup in the western Purcell anticlinorium, and (2) a northern portion that shows a continuous transition with the northern part of the central domain north of the terminus of the Purcell Trench fault. Cretaceous igneous rocks in the southern portion of the eastern and western domains have 40Ar/39Ar mica plateau dates that are <9 Myr younger than U–Pb zircon dates, indicating rapid cooling shortly after emplacement. 40Ar/39Ar step-heating reveals that there was a mid- to Late Cretaceous thermal disturbance in the eastern domain, possibly related to emplacement of younger plutons at deeper crustal levels and the Late Cretaceous Barrovian metamorphic event recorded in rocks of the central domain, such that biotite with dates <ca. 73 Ma yield plateau age spectra but those with older dates are disturbed. The new geochronology, combined with recent mapping and metamorphic studies, leads to the conclusion that the exhumation of the Barrovian metamorphic rocks of the central domain was a multi-stage process. The central domain experienced rapid tectonic decompression and minor pluton emplacement in the Late Cretaceous to early Paleocene (76–61 Ma) when the Cordilleran orogen was under regional contraction during which most of the exhumation occurred. Final exhumation in the footwall of Eocene normal faults was less significant and occurred between 53 and ca. 46 Ma when the Cordilleran orogen had transitioned to regional extension, by which time the three domains had attained a similar crustal level. These episodes of exhumation are similar to those found in other core complexes in the southern Canadian Cordillera and contiguous northern Idaho and Washington. The earlier episode is coincident with regional-scale, Late Cretaceous thrust faulting in the Foreland Belt of the Rocky Mountains. Eocene normal faulting and final exhumation of core complexes in the Omineca Belt mark the end of contraction in the Foreland Belt.
12

Marchev, Peter, Peter Kibarov, Richard Spikings, Maria Ovtcharova, István Márton, and Robert Moritz. "40Ar/39Ar and U-Pb geochronology of the Iran Tepe volcanic complex, Eastern Rhodopes." Geologica Balcanica 39, no. 3 (December 2010): 3–12. http://dx.doi.org/10.52321/geolbalc.39.3.3.

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The Iran Tepe volcanic complex occurs in the south-eastern part of the Eastern Rhodope massif. The rocks are represented by calc-alkaline and high-K calc-alkaline basaltic andesite to dacite epiclastics, lava flows and dikes, which are crosscut by andesitic and latitic dikes and rhyolitic dykes from the Planinets dyke swarm. Stratigraphic data and existing K/Ar ages suggest that the Iran Tepe volcanic complex is Upper Eocene (35-39 Ma), and is one of the oldest volcanic structures in the Eastern Rhodopes. However, new 40Ar/39Ar laser fusion and incremental step-heating experiments on biotites and isotope dilution – thermal ionization mass spectrometry (ID-TIMS) U-Pb age data on single zircons from the bottom and top lava flows and dykes more precisely constrain the ages and time span of volcanic activity, and show that the volcanism is younger. Volcanic activity started with calc-alkaline andesites and dacites at the beginning of the Oligocene (~33.9 Ma) and culminated with the intrusion of latitic dykes at ~33.0 Ma. Rhyolites from the Planinets dyke swarm yield a similar age (32.8 Ma), but their genetic relationship with the more mafic Iran Tepe lavas remains unclear.
13

Riley, Teal R., and Kim B. Knight. "Age of Pre-Break-Up Gondwana Magmatism." Antarctic Science 13, no. 2 (June 2001): 99–110. http://dx.doi.org/10.1017/s0954102001000177.

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Extensive outpourings of basalt, and to a lesser extent rhyolite, are closely associated with continental break-up and plume–lithosphere interactions. The Gondwana supercontinent began to fragment during Early–Middle Jurassic times and was associated with the eruption of over three million km3 of dominantly basaltic magma. This intense magmatic episode is recorded in volcanic rocks of the Karoo (Africa), Ferrar (Antarctica) and Chon Aike (South America). K–Ar and Rb–Sr whole rock geochronology has consistently failed to produce reliable ages for these volcanic rocks, but in the last four years, the wider application of single grain 40Ar/39Ar and/or U–Pb geochronology has produced more robust and precise dating of the magmatism. This paper reviews the recent advances in high precision geochronology and provides a full recalibrated 40Ar/39Ar dataset. Application of these methods across the majority of the volcanic provinces indicates that approximately 80% of the volcanic rocks were erupted within a short, 3–4 Myr period at c. 182 Ma. This burst of magmatism occurred in the Karoo province at c. 183 Ma and in the Ferrar provinces at c. 180 Ma, and was dominated by mafic volcanism. This peak in volcanism is coincident with a second order mass extinction event at the end of the Pliensbachian when c. 5% of marine families were wiped out coinciding with widespread oceanic anoxia in the early Toarcian. A prolonged period of silicic volcanism occurred along the proto-Pacific margin, prior to, and during the main phase of break-up. Silicic volcanism was initially coincident with the plume related Karoo-Ferrar provinces, but continued over c. 40 Myr, associated with lithospheric extension and subduction along the proto-Pacific continental margin.
14

TAKAGI, Tetsuichi, and Atsushi KAMEI. "40Ar-39Ar and K-Ar geochronology for plutonic rocks in the central Abukuma Plateau, northeastern Japan." Journal of Mineralogical and Petrological Sciences 103, no. 5 (2008): 307–17. http://dx.doi.org/10.2465/jmps.071120.

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15

Fitch, F. J., P. J. Hooker, J. A. Miller, J. G. Mitchell, and R. T. Watkins. "Reconnaissance potassium–argon geochronology of the Suregei–Asille district, northern Kenya." Geological Magazine 122, no. 6 (November 1985): 609–22. http://dx.doi.org/10.1017/s0016756800032027.

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AbstractPotassium–argon dating of 44 samples of basalt lavas and pantelleritic ignimbrites provides a provisional chronology for the 1900-metre thick Cenozoic succession of the Suregei–Asille district, northeast of Lake Turkana. Volcanic rocks of the Asille Group range in age from late Oligocene (Chattian) to late Miocene (Tortonian). Data obtained from conventional K–Ar total-rock analysis of basalt samples are appraised statistically to indicate the presence of three periods of enhanced volcanism centred around 27, 17 and 11.5 Ma. Equivalent ages obtained from the pyroclastic pantellerites by conventional K–Ar total-rock analysis and 40Ar/39Ar analysis of sanidine concentrates indicate that basic and acid eruptions were closely spaced in time. Continental tholeiite flood lavas belonging to the Gombe Group are of Pliocene age, but are difficult to date precisely because of their young ages and relatively high atmospheric contamination occurring as a result of the secondary alteration in the ubiquitous glass mesostasis. Those ages involving least atmospheric correction are considered most reliable, and are closely similar for the Chen Alia and Harr formations at around 4.85 Ma, although later flood eruptions may have occurred to the south and west of the Suregei–Asille district at about 3.85 Ma.
16

Montemagni, Chiara, Chiara Montomoli, Salvatore Iaccarino, Rodolfo Carosi, Arvind K. Jain, Hans-J. Massonne, and Igor M. Villa. "Dating protracted fault activities: microstructures, microchemistry and geochronology of the Vaikrita Thrust, Main Central Thrust zone, Garhwal Himalaya, NW India." Geological Society, London, Special Publications 481, no. 1 (April 17, 2018): 127–46. http://dx.doi.org/10.1144/sp481.3.

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AbstractThe timing of shearing along the Vaikrita Thrust, the upper structural boundary of the Main Central Thrust Zone in the Garhwal Himalaya, was constrained by combined microstructural, microchemical and geochronological investigations. Three different biotite–muscovite growth and recrystallization episodes were observed: a relict mica-1; mica-2 along the main mylonitic foliation; and mica-3 in coronitic structures around garnet during its breakdown. Electron microprobe analyses of biotite showed chloritization and a bimodal composition of biotite-2 in one sample. Muscovite-2 and muscovite-3 differed in composition from each other. Biotite and muscovite 39Ar–40Ar age spectra from all samples showed both inter- and intra-sample discrepancies. Biotite step-ages ranged between 8.6 and 16 Ma and muscovite step-ages between 3.6 and 7.8 Ma. These ages cannot be interpreted as ‘cooling ages’ because samples from the same outcrop cooled simultaneously. Instead, the Ar systematics reflect sample-specific recrystallization markers. Intergrown impurities were diagnosed by the Ca/K ratios. The age data of biotite were interpreted as a mixture of true biotite-2 (9.00 ± 0.10 Ma) and two alteration products. The negative Cl/K–age correlation identified a Cl-poor muscovite-2 (>7 Ma) and a Cl-rich, post-deformational, coronitic muscovite-3 grown at ≤5.88 ± 0.03 Ma. The Vaikrita Thrust was active at least from 9 to 6 Ma at c. 600°C; its movement had ended by 6 Ma.Supplementary material: Thermometric and 39Ar–40Ar data are available at https://doi.org/10.6084/m9.figshare.c.4069076
17

Delgado-Argote, L. A., M. López-Martínez, D. York, and C. M. Hall. "Geologic framework and geochronology of ultramafic complexes of southern Mexico." Canadian Journal of Earth Sciences 29, no. 7 (July 1, 1992): 1590–604. http://dx.doi.org/10.1139/e92-125.

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In southern Mexico, discrete ultramafic intrusive bodies larger than 4 km2 are genetically related to their enclosing volcano-sedimentary terranes. These terranes are the Cuicateco and Guerrero, which include the Cuicateco and Tierra Caliente metamorphic complexes, respectively. Their basement is largely unknown, and the ultramafic masses previously have been interpreted as allochthonous dismembered ophiolites. To constrain the age of these accreted terranes, the geologic setting and 40Ar/39Ar ages are presented from the localities of Loma Baya – El Tamarindo, Guerrero, and San Pedro Limón, State of México, in the Tierra Caliente Complex, and Teotitlán – Conceptión Pápalo, Oaxaca, in the Cuicateco Complex. The Teotitlán – Conceptión Pápalo area is characterized by a sequence of metamorphosed intermediate granitoid rocks, andesitic lavas, tuffs, and psammites. The intrusive rocks and lavas are pervasively mylonitized and show abundant ultramafic segregations. The largest ultramafic bodies were emplaced into metatuffs, following the regional east-verging structural trend. Three hornblende separates from a hornblende diorite and one from a hornblende-rich clinopyroxenite yielded plateau ages of ca. 130 Ma. The ultramafic rocks in the Tierra Caliente Complex lack orthopyroxene and transitionally grade outward into hornblende diorites. The El Tamarindo ultramafic body (4.6 km2) rose as a diapir into an Albian volcano-sedimentary sequence. The best estimate for the age of this body is ca. 112 Ma from a hornblende separated from a pegmatite dike sample. This age is similar to the Albian fauna reported at Zihuatanejo and other K–Ar ages from ultramafic rocks at Camalotitos. The rigid and poorly serpentinized San Pedro Limon Stock (15 km2) was vertically emplaced into the Xochipala Formation (Cenomanian) during a regional Neogene transpressive disturbance. Four hornblende samples from hornblende clinopyroxenites and hornblendites yielded remarkably flat age spectra, indicating an age of ca. 105 Ma for the San Pedro Limon Stock. Based on the good correlation between the 40Ar/39Ar ages reported here and earlier faunistic data, it is concluded that the ultramafic rocks cooled penecontemporaneously with the deposition of the enclosing volcano-sedimentary sequences.
18

Arancibia, G., S. J. Matthews, and C. Pérez de Arce. "K–Ar and 40Ar/39Ar geochronology of supergene processes in the Atacama Desert, Northern Chile: tectonic and climatic relations." Journal of the Geological Society 163, no. 1 (January 2006): 107–18. http://dx.doi.org/10.1144/0016-764904-161.

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19

Chetel, Lauren M., J. A. (Toni) Simo, and Brad S. Singer. "40Ar/39Ar geochronology and provenance of detrital K-feldspars, Ordovician, Upper Mississippi Valley." Sedimentary Geology 182, no. 1-4 (December 2005): 163–81. http://dx.doi.org/10.1016/j.sedgeo.2005.07.010.

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20

Segev, Amit. "40Ar/39Ar and K–Ar geochronology of Berriasian–Hauterivian and Cenomanian tectonomagmatic events in northern Israel: implications for regional stratigraphy." Cretaceous Research 30, no. 3 (June 2009): 810–28. http://dx.doi.org/10.1016/j.cretres.2009.01.003.

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21

Harlaux, Matthieu, Daniel J. Kontak, Alan H. Clark, Kalin Kouzmanov, Christopher S. Holm-Denoma, Stefano Gialli, Oscar Laurent, et al. "Depositing &gt;1.5 Mt of Tin Within &lt;1 m.y. of Initial Granitic Intrusion in the San Rafael Tin (-Copper) Deposit, Southeastern Peru." Economic Geology 118, no. 6 (September 1, 2023): 1371–96. http://dx.doi.org/10.5382/econgeo.5021.

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Abstract The San Rafael Sn (-Cu) deposit, located in the Eastern Cordillera of southeast Peru, is one of the world’s largest cassiterite-bearing vein systems (&gt;1 Mt Sn produced since 1969). The deposit consists of a quartz-cassiterite-chlorite-sulfide lode system spatially associated with an upper Oligocene (ca. 24 Ma) S-type granitic pluton. Based on a revised paragenetic sequence for the deposit, we interpret the temporal setting of both magmatic (biotite, K-feldspar) and hydrothermal (muscovite, adularia, cassiterite) minerals analyzed by 40Ar/39Ar step-heating and U-Pb laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) geochronology. The least-disturbed biotite sample from the megacrystic monzogranite yielded a 40Ar/39Ar plateau age of 24.10 ± 0.26 Ma (2σ), which constrains the time of cooling of the upper part of the pluton to below 300°C. Greisen developed on top of the granitic cupola and its immediate metamorphic aureole dated at 24.24 ± 0.24 Ma (2σ; 40Ar/39Ar muscovite average plateau age) is interpreted to be contemporaneous with the emplacement of pre-ore quartz-tourmaline veins and breccias. In situ U-Pb dating of cassiterite, including both botryoidal cassiterite (“wood tin”) and coarse-grained cassiterite in quartz-chlorite veins and breccias, constrains the timing of the main Sn ore stage to between 24.10 ± 0.37 and 23.47 ± 0.53 Ma (2σ). Botryoidal and coarse-grained cassiterite are characterized by similar trace element compositions with fluctuating metal concentrations across growth banding, suggesting significant changes of physicochemical conditions of the hydrothermal system during cassiterite precipitation, likely caused by rapid and repeated mixing between magmatic fluids and meteoric groundwaters. Polymetallic sulfide-rich veins and quartz-carbonate veins are constrained to have formed between 22.72 ± 0.11 and 22.29 ± 0.24 Ma (2σ), based on adularia 40Ar/39Ar plateau ages. The latter overlap partially reset 40Ar/39Ar age spectra for K-feldspar megacrysts in the host granite and thus reflect pervasive alteration by hydrothermal fluids. Collectively, the results show the magmatic-hydrothermal system spanned at least 2 m.y. with the main Sn ore stage representing &lt;1 m.y. in the lifetime of the deposit. The latest polymetallic stages postdate the main Sn ore stage by ca. 1 m.y. and reflect the waning of the hydrothermal system, accompanied by additional incursion of meteoric groundwaters. This study provides further evidence that the present-day exposed level of the San Rafael granite was a passive host for the Sn mineralization and only provided the structural focusing for the mineralizing fluids derived from a deeper part of the magmatic system.
22

Vetrov, Evgeny, Johan De Grave, Natalia Vetrova, Fedor Zhimulev, Simon Nachtergaele, Gerben Van Ranst, and Polina Mikhailova. "Tectonic History of the South Tannuol Fault Zone (Tuva Region of the Northern Central Asian Orogenic Belt, Russia): Constraints from Multi-Method Geochronology." Minerals 10, no. 1 (January 9, 2020): 56. http://dx.doi.org/10.3390/min10010056.

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In this study, we present zircon U/Pb, plagioclase and K-feldspar 40Ar/39Ar and apatite fission track (AFT) data along the South Tannuol Fault Zone (STFZ). Integrating geochronology and multi-method thermochronology places constraints on the formation and subsequent reactivation of the STFZ. Cambrian (~510 Ma) zircon U/Pb ages obtained for felsic volcanic rocks date the final stage of STFZ basement formation. Ordovician (~460–450 Ma) zircon U/Pb ages were obtained for felsic rocks along the structure, dating their emplacement and marking post-formational local magmatic activity along the STFZ. 40Ar/39Ar stepwise heating plateau-ages (~410–400 Ma, ~365 and ~340 Ma) reveal Early Devonian and Late Devonian–Mississippian intrusion and/or post-magmatic cooling episodes of mafic rocks in the basement. Permian (~290 Ma) zircon U/Pb age of mafic rocks documents for the first time Permian magmatism in the study area creating prerequisites for revising the spread of Permian large igneous provinces of Central Asia. The AFT dating and Thermal history modeling based on the AFT data reveals two intracontinental tectonic reactivation episodes of the STFZ: (1) a period of Cretaceous–Eocene (~100–40 Ma) reactivation and (2) the late Neogene (from ~10 Ma onwards) impulse after a period of tectonic stability during the Eocene–Miocene (~40–10 Ma).
23

BARROS, MÁRCIA APARECIDA DE SANT’ANA, ANA MARIA MIZUSAKI, RICARDO WESKA, ANDRÉ DE BORBA, FARID CHEMALE JR, and ELISON CARMO DA COSTA. "Petrografia, Geoquímica, Análises Isotópicas (Sr, Nd) e Geocronologia Ar-Ar dos Basaltos de Tapirapuã (Tangará da Serra, Mato Grosso, Brasil)." Pesquisas em Geociências 33, no. 2 (June 29, 2006): 71. http://dx.doi.org/10.22456/1807-9806.19515.

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The basaltic flows from Tapirapuã Formation are exposed at Tangará da Serra region, 250 km from Cuiabá (MT) and the thickness can reach 310 meters. The basalts range from massive dark gray, with colunar disjunctions at the base to purple amygdaloidal at the top. They are generally fine-grained, however gabroics portions have been identified. In thin section the Tapirapuã basalts show subophitic texture. Chemical analyses in these rocks suggest tholeiitic compositions, within continental tectonic environment. There is an enrichment of light rare earth elements when compared to heavy rare earth elements. The studied samples have low contents of TiO2 and P2O5 being similar to low P2O5 and TiO2 group from Serra Geral Formation (Paraná Basin). Analyses of Sr and Nd isotopes show the following results: 87Sr/86Sr between 0.703 and 0.707, ∈Nd from –0.01 to + 2.32 and model ages (TDM)= (931 to 1.267 Ma). 40Ar / 39Ar geochronology of plagioclase crystals from Tapirapuã basalts presented a plateau age of 206 ± 6 Ma, in agreement with previous ages obtained from Anari and Tapirapuã sub-provinces. This result places the volcanic event at the limit of the Triassic-Jurassic periods, related to the opening of the North Atlantic.
24

McDOUGALL, IAN, and RONALD T. WATKINS. "Geochronology of the Nabwal Hills: a record of earliest magmatism in the northern Kenyan Rift Valley." Geological Magazine 143, no. 1 (October 28, 2005): 25–39. http://dx.doi.org/10.1017/s0016756805001184.

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The Nabwal Hills, northeast of Lake Turkana, contain a record of magmatism associated with the initiation and early development of the East African Rift System in northernmost Kenya. The predominantly volcanic Asille Group, 1400 m thick, directly overlies metamorphic basement and comprises a sequence of basaltic lava flows with significant intervals of rhyolitic pyroclastic units, and minor intercalations of fluviatile sediments. The basement gneisses yield K–Ar cooling ages on biotite of 510 and 522 Ma, typically Pan-African. The 40Ar–39Ar ages on alkali feldspar crystals from the rhyolitic units are concordant and show that the Asille Group spans an interval from at least 34.3 to 15.8 Ma, continuing to at least as young as 13 Ma based on previous measurements. Vertebrate fossil sites, containing primate remains, at Irile and Nabwal are shown to be 17 ± 2 Ma old, Early Miocene, based upon K–Ar age measurements on immediately overlying basalts. Variably reliable whole rock K–Ar ages, determined on basalt samples from low in the sequence, indicate that volcanism commenced as early as 34.8 Ma ago. The overall geochronological results show that magmatism in the Nabwal Hills began about 35 Ma ago in Late Eocene times, interpreted as the time of initiation of crustal extension that led to the development of this segment of the East African Rift System. The Asille Group is tilted about 6° to the SSW. This tilting occurred later than 13 Ma ago, and prior to the eruption of the flat-lying Gombe Group basalts. These basalts may have begun erupting about 6 Ma ago in Late Miocene times, although much of this volcanism occurred between about 3.9 and 4.2 Ma ago in Pliocene times. It is suggested that the main rifting, which continues today, commenced in Late Miocene times, less than 13 Ma ago, and is partly reflected in the tilting of the Asille Group.
25

Guo, Jian, Youyue Lu, Jianming Fu, Zhengwei Qin, Yongyun Ning, and Zunzun Zhang. "Geology and Geochronology of the Maozaishan Sn Deposit, Hunan Province: Constraints from Zircon U–Pb and Muscovite Ar–Ar Dating." Minerals 9, no. 12 (December 11, 2019): 773. http://dx.doi.org/10.3390/min9120773.

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The Maozaishan Sn deposit, located south of the Dayishan ore field in the Nanling Range, is a newly explored greisen-type Sn deposit. Two muscovite samples from tin-bearing ores yielded 40Ar/39Ar plateau ages of 154.7 ± 1.1 Ma (Mean standard weighted deviation (MSWD) = 0.48) and 152.6 ± 0.7 Ma (MSWD = 0.25), respectively. Zircon U–Pb dating result of fine-grained biotite monzogranite in the Maozaishan mining area shows that these zircon grains can be subdivided into two populations, with ages of 154.2 ± 2.0 Ma (MSWD = 0.51) and 159.6 ± 1.9 Ma (MSWD = 0.09), respectively, indicating that the monzogranite is formed by a multi-stage magmatic event. It is indicated that formation of the Maozaishan Sn deposit is closely related to the Middle Jurassic granitic magmatism. Based on the trace element compositions of zircon grains, the calculated magma temperatures and oxygen fugacity (log(fO2)) values range from 638 °C to 754 °C (mean = 704 °C) and from −18.9 to −15.8 (mean = −17.1), respectively. In addition, these intrusive rocks in the Dayishan ore field belong to highly fractionated granites and are characterized by low oxygen fugacity and crust–mantle origin, which are consistent to these tin-bearing granites in the Nanling Range and in favor of the Sn mineralization.
26

Zhang, Shaohua, Chiyang Liu, Jianqiang Wang, Jianke Bai, Xiaochen Zhao, Long Zhang, Nan Jia, Lijun Song, and Heng Peng. "Zircon U-Pb-Hf Isotopes, Biotite 40Ar/39Ar Geochronology, and Whole-Rock Geochemistry of the Baogeqi Gabbro in the Northern Alxa, Southernmost Central Asian Orogenic Belt." Minerals 12, no. 5 (May 23, 2022): 656. http://dx.doi.org/10.3390/min12050656.

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The final closure time of the Paleo-Asian Ocean and the Permo-Carboniferous tectonic settings in the northern Alxa are very important but controversial tectonic issues. The geochronology and petrogenesis of mafic igneous rocks are superior in clarifying regional tectonic settings. Here, we report on zircon U-Pb-Hf isotopes, biotite 40Ar/39Ar geochronology and whole-rock geochemical data of the hornblende gabbro from the Baogeqi gabbro pluton in the northern Alxa. The LA-ICP MS U-Pb analysis of zircon grains from the hornblende gabbro yield a weighted mean age of 262.7 ± 2.3 Ma (2σ, MSWD = 0.74), manifesting that the Baogeqi gabbro pluton emplacement was during the late Middle Permian (Capitanian). The 40Ar/39Ar dating of biotite grains from the hornblende gabbro yields a plateau age of 231.3 ± 1.6 Ma (2σ, MSWD = 0.55), indicating that the Baogeqi gabbro pluton cooled to below 300 ℃ in the Triassic. The hornblende gabbro samples are calc-alkaline with metaluminous character, and show enrichment in large ion lithophile elements (e.g., Rb, Ba, Sr, and K) but depletion in Nb, Ta, P, Th, and Ti relative to primitive mantle. Combined with the positive zircon εHf(t) values (+4.9–+9.4), we suggest that the magmas formed from the partial melting of depleted mantle were metasomatized by slab-derived fluids. Together with regional geology, these geochemical data suggest that the Baogeqi gabbro pluton was formed in an intracontinental extension setting, further indicating that the Paleo-Asian Ocean in the northern Alxa was closed prior to the late Middle Permian (Capitanian), and this region was in a post-collision extensional setting during the Capitanian-Late Permian. In addition, the Triassic cooling of the gabbro pluton may be a record of the decline of the Capitanian-Late Permian post-collisional extension basin due to the far-field effect of subduction-collision during the closure of the Paleo-Tethys Ocean.
27

Picazo, Suzanne M., Tanya A. Ewing, and Othmar Müntener. "Paleocene metamorphism along the Pennine–Austroalpine suture constrained by U–Pb dating of titanite and rutile (Malenco, Alps)." Swiss Journal of Geosciences 112, no. 2-3 (September 13, 2019): 517–42. http://dx.doi.org/10.1007/s00015-019-00346-1.

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Abstract We present in situ rutile and titanite U–Pb geochronology for three samples from the Ur breccia, which forms the boundary between the Malenco unit and the Margna nappe (Eastern Central Alps) near Pass d’Ur in southeast Switzerland. These sampled both oceanic brecciated material and a blackwall reaction zone in contact with a micaschist and serpentinized peridotite. Peak temperatures during Alpine metamorphism in these units were ~ 460 ± 30 °C. Textural observations combined with new geochronological data indicate that rutile and titanite both grew below their closure temperatures during Alpine metamorphism. We present a technique to calculate the most precise and accurate ages possible using a two-dimensional U–Pb isochron on a Wetherill concordia. Rutile from two samples gave a U–Pb isochron age of 63.0 ± 3.0 Ma. This age conflicts with previous 39Ar–40Ar data on heterogeneous amphiboles from which an age of 90–80 Ma was inferred for the high pressure part of the Alpine evolution, but is consistent with K–Ar ages and Ar–Ar ages on phengitic white mica. Titanite from three samples gave a U–Pb isochron age of 54.7 ± 4.1 Ma. This age is consistent with Rb–Sr isochron ages on mylonites along and in the footwall of the Lunghin–Mortirolo movement zone, a major boundary that separates ductile deformation in the footwall from mostly localized and brittle deformation in the hangingwall. Our ages indicate a Paleocene rather than upper Cretaceous metamorphism of the Pennine–Austroalpine boundary and permit at most ~ 15 Myr, and possibly much less, between the growth of rutile and titanite.
28

Li, Yang, and Pieter Vermeesch. "Short communication: Inverse isochron regression for Re–Os, K–Ca and other chronometers." Geochronology 3, no. 2 (August 2, 2021): 415–20. http://dx.doi.org/10.5194/gchron-3-415-2021.

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Abstract. Conventional Re–Os isochrons are based on mass spectrometric estimates of 187Re/188Os and 187Os/188Os, which often exhibit strong error correlations that may obscure potentially important geological complexity. Using an approach that is widely accepted in 40Ar/39Ar and U–Pb geochronology, we here show that these error correlations are greatly reduced by applying a simple change of variables, using 187Os as a common denominator. Plotting 188Os/187Os vs. 187Re/187Os produces an “inverse isochron”, defining a binary mixing line between an inherited Os component whose 188Os/187Os ratio is given by the vertical intercept, and the radiogenic 187Re/187Os ratio, which corresponds to the horizontal intercept. Inverse isochrons facilitate the identification of outliers and other sources of data dispersion. They can also be applied to other geochronometers such as the K–Ca method and (with less dramatic results) the Rb–Sr, Sm–Nd and Lu–Hf methods. Conventional and inverse isochron ages are similar for precise datasets but may significantly diverge for imprecise ones. A semi-synthetic data simulation indicates that, in the latter case, the inverse isochron age is more accurate. The generalised inverse isochron method has been added to the IsoplotR toolbox for geochronology, which automatically converts conventional isochron ratios into inverse ratios, and vice versa.
29

Terhune, Patrick J., Jeffrey A. Benowitz, Jeffrey M. Trop, Paul B. O’Sullivan, Robert J. Gillis, and Jeffrey T. Freymueller. "Cenozoic tectono-thermal history of the southern Talkeetna Mountains, Alaska: Insights into a potentially alternating convergent and transform plate margin." Geosphere 15, no. 5 (July 16, 2019): 1539–76. http://dx.doi.org/10.1130/ges02008.1.

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Abstract The Mesozoic–Cenozoic convergent margin history of southern Alaska has been dominated by arc magmatism, terrane accretion, strike-slip fault systems, and possible spreading-ridge subduction. We apply 40Ar/39Ar, apatite fission-track (AFT), and apatite (U-Th)/He (AHe) geochronology and thermochronology to plutonic and volcanic rocks in the southern Talkeetna Mountains of Alaska to document regional magmatism, rock cooling, and inferred exhumation patterns as proxies for the region’s deformation history and to better delineate the overall tectonic history of southern Alaska. High-temperature 40Ar/39Ar thermochronology on muscovite, biotite, and K-feldspar from Jurassic granitoids indicates postemplacement (ca. 158–125 Ma) cooling and Paleocene (ca. 61 Ma) thermal resetting. 40Ar/39Ar whole-rock volcanic ages and 45 AFT cooling ages in the southern Talkeetna Mountains are predominantly Paleocene–Eocene, suggesting that the mountain range has a component of paleotopography that formed during an earlier tectonic setting. Miocene AHe cooling ages within ∼10 km of the Castle Mountain fault suggest ∼2–3 km of vertical displacement and that the Castle Mountain fault also contributed to topographic development in the Talkeetna Mountains, likely in response to the flat-slab subduction of the Yakutat microplate. Paleocene–Eocene volcanic and exhumation-related cooling ages across southern Alaska north of the Border Ranges fault system are similar and show no S-N or W-E progressions, suggesting a broadly synchronous and widespread volcanic and exhumation event that conflicts with the proposed diachronous subduction of an active west-east–sweeping spreading ridge beneath south-central Alaska. To reconcile this, we propose a new model for the Cenozoic tectonic evolution of southern Alaska. We infer that subparallel to the trench slab breakoff initiated at ca. 60 Ma and led to exhumation, and rock cooling synchronously across south-central Alaska, played a primary role in the development of the southern Talkeetna Mountains, and was potentially followed by a period of southern Alaska transform margin tectonics.
30

Zhou, Xiaolong, Klaudia Kuiper, Jan Wijbrans, Katharina Boehm, and Pieter Vroon. "Eruptive history and <sup>40</sup>Ar∕<sup>39</sup>Ar geochronology of the Milos volcanic field, Greece." Geochronology 3, no. 1 (May 5, 2021): 273–97. http://dx.doi.org/10.5194/gchron-3-273-2021.

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Abstract. High-resolution geochronology is essential for determining the growth rate of volcanoes, which is one of the key factors for establishing the periodicity of volcanic eruptions. However, there are less high-resolution eruptive histories (> 106 years) determined for long-lived submarine arc volcanic complexes than for subaerial complexes, since submarine volcanoes are far more difficult to observe than subaerial ones. In this study, high-resolution geochronology and major-element data are presented for the Milos volcanic field (VF) in the South Aegean Volcanic Arc, Greece. The Milos VF has been active for over 3 Myr, and the first 2 × 106 years of its eruptive history occurred in a submarine setting that has been emerged above sea level. The long submarine volcanic history of the Milos VF makes it an excellent natural laboratory to study the growth rate of a long-lived submarine arc volcanic complex. This study reports 21 new high-precision 40Ar/39Ar ages and major-element compositions for 11 volcanic units of the Milos VF. This allows us to divide the Milos volcanic history into at least three periods of different long-term volumetric volcanic output rate (Qe). Periods I (submarine, ∼ 3.3–2.13 Ma) and III (subaerial, 1.48 Ma–present) have a low Qe of 0.9 ± 0.5 × 10−5 and 0.25 ± 0.05 × 10−5 km3 yr−1, respectively. Period II (submarine, 2.13–1.48 Ma) has a 3–12 times higher Qe of 3.0 ± 1.7 × 10−5 km3 yr−1. The Qe of the Milos VF is 2–3 orders of magnitude lower than the average for rhyolitic systems and continental arcs.
31

Arancibia, Gloria, Stephen J. Matthews, Paula Cornejo, Carlos Pérez de Arce, José I. Zuluaga, and Stabro Kasaneva. "40Ar/39Ar and K–Ar geochronology of magmatic and hydrothermal events in a classic low-suphidation epithermal bonanza deposit: El Peñon, northern Chile." Mineralium Deposita 41, no. 5 (July 27, 2006): 505–16. http://dx.doi.org/10.1007/s00126-006-0078-2.

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32

Jicha, B. R., M. L. Coombs, A. T. Calvert, and B. S. Singer. "Geology and 40Ar/39Ar geochronology of the medium- to high-K Tanaga volcanic cluster, western Aleutians." Geological Society of America Bulletin 124, no. 5-6 (March 9, 2012): 842–56. http://dx.doi.org/10.1130/b30472.1.

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33

Walker, Jordan T., Andres Aslan, Rex D. Cole, and Michael T. Heizler. "New age constraints on the Late Cretaceous lower Williams Fork Formation, Coal Canyon, Colorado." Mountain Geologist 58, no. 1 (January 1, 2021): 5–26. http://dx.doi.org/10.31582/rmag.mg.58.1.5.

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The precise age of terrestrial sediments in the Late Cretaceous Williams Fork Formation of western Colorado is poorly constrained due to a paucity of radiometric data. Sanidine and zircon dating of a volcanic ash encased in coal (i.e., the Coal Canyon ash) within the Cameo-Wheeler coal zone of the lower Williams Fork Formation in Coal Canyon, Colorado provides an important new age constraint for the southwestern Piceance Basin. A 10-30 cm thick, light gray, clayey mudstone encased in coal was sampled for both zircon U-Pb and sanidine 40Ar/39Ar geochronology. The presence of numerous euhedral zircon crystals, a lenticular geometry, and a clayey texture suggest that the mudstone is a minimally reworked and slightly altered volcanic ash. Analysis of the euhedral zircon crystals (n=108) in the ash produced a statistically robust U-Pb date with 93 grains yielding a weighed mean age of 74.52 ±0.11 Ma (1σ analytical uncertainty). 40Ar/39Ar sanidine analyses yielded a younger weighted mean age of 73.10 ±0.12 Ma (1σ analytical uncertainty) based on 6 of the 36 grains analyzed. Our preferred age is given by the weighted mean age of the sanidine as it is based on higher precision analyses that can better discriminate older inherited grains that are likely included in the zircon mean-age calculation. Isotopic data for the Coal Canyon ash overlap in age with a K-Ar date of 72.5 ±5.1 Ma for a widespread Williams Fork Formation tonstein, known as the Yampa Bed, found in coal-bearing outcrops and mine workings throughout the northern Piceance and Sand Wash basins and Axial Basin Uplift. Based on the similarity in isotopic age, sedimentologic context and stratigraphic position, we suggest that the Coal Canyon ash and the regionally extensive Yampa Bed are coeval. Additionally, this correlation corroborates that the Cameo-Wheeler coal zone of the Williams Fork Formation in the southwestern Piceance Basin is correlative with the Middle coal zone of the Danforth Hills and Yampa regions. Lastly, this proposed correlation may suggest that the Coal Canyon ash, like the Yampa Bed, correlates with the Baculites reesidei ammonite zone, which is associated regionally with a bentonite dated to 72.94 ±0.45 Ma. Detrital sanidine geochronology of two lower Williams Fork sandstone units that overly the Coal Canyon ash did not produce grains younger than the ash and thus do not quantitatively improve the chronostratigraphy of these specific units. Lastly, the Coal Canyon ash date serves as a basis for future evaluations of the diachroneity of non-marine strata of the Williams Fork Formation.
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OLIVEROS, VERóNICA, LUIS AGUIRRE, DIEGO MORATA, ANTONIO SIMONETTI, MARIO VERGARA, MAURICIO BELMAR, and SERGIO CALDERóN. "Geochronology of very low-grade Mesozoic Andean metabasites; an approach through the K–Ar, 40Ar/39Ar and U–Pb LA-MC-ICP-MS methods." Journal of the Geological Society 165, no. 2 (February 1, 2008): 579–84. http://dx.doi.org/10.1144/0016-76492007-113.

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35

Holm, Daniel, and David Schneider. "40Ar/39Ar evidence for ca. 1800 Ma tectonothermal activity along the Great Falls tectonic zone, central Montana." Canadian Journal of Earth Sciences 39, no. 12 (December 1, 2002): 1719–28. http://dx.doi.org/10.1139/e02-069.

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Late Paleoproterozoic (1900–1600 Ma) tectonothermal activity on all borders of the Archean Wyoming Province has long been established by low-precision K–Ar and Rb–Sr studies. However, recent tectonic models advanced for supercontinent aggregation require improved constraints on the timing of tectonothermal activity along major boundaries. On its northwestern boundary, the Great Falls tectonic zone separates the Archean Wyoming and Hearne provinces. Recently published U/Pb ages and geochemical data reveal the presence of a Paleoproterozoic (ca. 1860 Ma) marginal-arc magmatic complex along a portion of the Great Falls tectonic zone in central Montana. We present nine new 40Ar/39Ar mineral ages (on hornblende and biotite) from these same arc rocks, which indicate ca. 1800 Ma thermal activity (>500°C) and subsequent rapid cooling to below 300°C by 1775 Ma. This new data set constrains the timing of Wyoming–Hearne collision to between 1860 and 1800 Ma and the timing of last significant tectonothermal activity of this portion of the Great Falls tectonic zone (1800–1775 Ma). We note that our data add to a growing geochronologic database indicating ca. 1800 Ma tectonothermal activity (via either initial suturing or continued tectonic activity) associated with Paleoproterozoic docking of the Wyoming Province with Laurentia.
36

Nikolenko, Evgeny I., Konstantin V. Lobov, Alexey M. Agashev, Nikolay S. Tychkov, Maria V. Chervyakovskaya, Igor S. Sharygin, and Anna M. Nikolenko. "40Ar/39Ar Geochronology and New Mineralogical and Geochemical Data from Lamprophyres of Chompolo Field (South Yakutia, Russia)." Minerals 10, no. 10 (October 6, 2020): 886. http://dx.doi.org/10.3390/min10100886.

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The alkaline igneous rocks of the Chompolo field (Aldan shield, Siberian craton), previously defined as kimberlites or lamproites, are more correctly classified as low-Ti lamprophyres. The emplacement age of the Ogonek pipe (137.8 ± 1.2 Ma) and the Aldanskaya dike (157.0 ± 1.6 Ma) was obtained using 40Ar/39Ar K-richterite dating. The Chompolo rocks contain abundant xenocrysts of mantle minerals (chromium-rich pyropic garnets, Cr-diopsides, spinels, etc.). The composition of the mantle xenocrysts indicates the predominance of spinel and garnet–spinel lherzolites, while the presence of garnet lherzolites, dunites, harzburgites, and eclogites is minor. The Chompolo rocks are characterized by large-ion lithophile element (LILE) and Light Rare Earth Element (LREE) enrichments, and high field strength element (HFSE) depletions. The rocks of the Ogonek pipe have radiogenic Sr (87Sr/86Sr (t) = 0.70775 and 0.70954), and highly unradiogenic εNd(t) (−20.03 and −20.44) isotopic composition. The trace element and isotopic characteristics of the Chompolo rocks are indicative of the involvement of subducted materials in their ancient enriched lithospheric mantle source. The Chompolo rocks were formed at the stage when the Mesozoic igneous activity was triggered by global tectonic events. The Chompolo field of alkaline magmatism is one of the few available geological objects, which provides the opportunity to investigate the subcontinental lithospheric mantle beneath the south part of the Siberian craton.
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Feng, R., R. Kerrich, S. McBride, and E. Farrar. "40Ar/39Ar age constraints on the thermal history of the Archean Abitibi greenstone belt and the Pontiac Subprovince: implications for terrane collision, differential uplift, and overprinting of gold deposits." Canadian Journal of Earth Sciences 29, no. 7 (July 1, 1992): 1389–411. http://dx.doi.org/10.1139/e92-112.

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40Ar/39Ar mineral age spectra of granitic and metamorphic rocks, in conjunction with existing conventional zircon geochronology, indicate that at least two major late Archean thermal events affected tectonic blocks of the Abitibi Southern Volcanic Zone (SVZ) and the juxtaposed Pontiac Subprovince. The earlier thermal activity (2690–2670 Ma) was accompanied by the intrusion of voluminous syntectonic plutons and caused low-pressure, greenschist-facies metamorphism in the SVZ and intermediate-pressure metamorphism in the Pontiac Subprovince. The second thermal event (2660–2630 Ma) was coeval with the emplacement of syncollisional, S-type garnet–muscovite granites in the Pontiac Subprovince and the higher grade Lacorne block of the Abitibi SVZ, and reset the K–Ar systems in preexisting rocks.Magmatic amphibole from the syntectonic Round Lake batholith (~2695 Ma U–Pb zircon age) of the Abitibi SVZ has a slightly disturbed Ar release spectrum with an upper plateau age of 2669 ± 6 Ma, signifying that the low-grade Round Lake block cooled through 500 °C at a slow rate. Amphiboles in syntectonic batholiths from the higher grade Lacorne block and the Pontiac Subprovince have substantially disturbed Ar release spectra, with high-temperature steps giving apparent ages of 2681 ± 4 to 2679 ± 4 Ma; these overlap zircon ages of 2690–2670 Ma, indicating relatively rapid cooling through the amphibole blocking temperature.Metamorphic rocks (amphibolites) from the Lacorne block and the Pontiac Subprovince contain amphiboles with substantially disturbed 40Ar/39Ar release spectra and higher temperature step ages of 2677 ± 6 to 2670 ± 5 Ma, representing the minimum formation age. Fine-grained muscovite and biotite (180–250 μm) from mica schists also have disturbed Ar release patterns, but much younger apparent ages at high-temperature release steps (2581–2523 Ma for muscovite, 2562–2455 Ma for biotite) than the amphiboles.Coarse-grained muscovites from pegmatites associated with syncollision, S-type garnet–muscovite granites (2644 ± 13 Ma) in the Lacorne block and Pontiac Subprpvince show undisturbed or slightly disturbed Ar release spectra and magmatic δ18Oquartz–muscovite = 1.8–3.5‰, with total integrated ages of 2615 ± 10 to 2594 ± 7 Ma (Lacorne) and 2572 ± 6 Ma (Pontiac), respectively, indicating different uplift rates for the two terranes. Amphiboles (~2680 Ma) from metamorphic rocks in the Lacorne block and Pontiac Subprovince and from the Round Lake batholith are disturbed, whereas coarse-grained muscovites from the pegmatites (2644 ± 13 Ma) are relatively undisturbed. This indicates that the disturbance of the amphiboles may have been caused by a thermal event that preceded or was coeval with the emplacement of the garnet–muscovite granite suite, rather than being a grain-size effect.These results are consistent with a model whereby early subduction of oceanic lithosphere beneath the Abitibi SVZ (2740–2680 Ma), and separately under the Pontiac Subprovince, was responsible for syntectonic batholiths and the first thermal event. Collision with the Abitibi SVZ and local underthrusting of the Pontiac Subprovince at about 2670–2630 Ma caused the second major thermal event and partial melting of the underthrust Pontiac-type metasediments to form the garnet–muscovite granites. Later differential uplift exposed the entire Pontiac Subprovince and the Lacorne block as a tectonic window of underthrust Pontiac in the Abitibi SVZ. Resetting of several isotopic systems, including apparent younger ages of gold mineralization, is probably related to this late collisional, tectonothermal overprinting event. Fluid and (or) thermal events at ≥275 °C influenced the Kirkland Lake – Cadillac fault down to 2513 ± 10 Ma, as indicated by a plateau age of postkinematic biotite in the fault. The fault was intermittently reactivated over a period of 440 Ma, from ~2690 Ma to ≤2250 Ma.
38

Boehm, Katharina M., Klaudia F. Kuiper, Bora Uzel, Pieter Z. Vroon, and Jan R. Wijbrans. "Volcanism straddling the Miocene–Pliocene boundary on Patmos and Chiliomodi islands (southeastern Aegean Sea): insights from new 40Ar ∕ 39Ar ages." Geochronology 5, no. 2 (October 11, 2023): 391–403. http://dx.doi.org/10.5194/gchron-5-391-2023.

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Abstract. The island of Patmos, in the eastern Aegean Sea, consists almost entirely of late Miocene to Pliocene volcanic rocks. The magmatism in the Aegean is governed by subduction of the African plate below the Eurasian plate, back-arc extension, slab rollback, slab edge processes and westward extrusion of central Anatolia to the west along the Northern Anatolian Fault into the Aegean domain. The evolution of the Aegean basin is that of a back-arc setting, with a southerly trend in the locus of both convergent tectonics and back-arc stretching, allowing intermittent upwelling of arc, lithospheric and asthenospheric magmas. Here, we present new 40Ar/39Ar age data for Patmos and the nearby small island of Chiliomodi to place this volcanism in a new high-resolution geochronological framework. High-resolution geochronology provides a key to understanding the mechanisms of both the tectonic and magmatic processes that cause the extrusion of magma locally and sheds light on the tectonic evolution of the larger region of the back-arc basin as a whole. The volcanic series on Patmos is alkalic, consistent with a back-arc extensional setting, and ranges from trachybasalt to phonolites, trachytes and rhyolites, with SiO2 ranging from 51.6 wt % to 80.5 wt %, K2O ranging from 2 wt % to 11.8 wt % and extrusion ages ranging from 6.59 ± 0.04 (0.14) Ma to 5.17 ± 0.02 (0.11) Ma. Volcanism on Patmos and adjacent Chiliomodi can be understood as a combination of mantle and crustal tectonic processes including the influence of transform faults and rotational crustal forces that also caused the widening of the southern Aegean basin due to two opposite rotational poles in the east and west and rollback of the subducting slab south of Crete.
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Dokuz, Abdurrahman, Faruk Aydin, and Orhan Karslı. "Postcollisional transition from subduction- to intraplate-type magmatism in the eastern Sakarya zone, Turkey: Indicators of northern Neotethyan slab breakoff." GSA Bulletin 131, no. 9-10 (April 11, 2019): 1623–42. http://dx.doi.org/10.1130/b31993.1.

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Abstract Postcollisional magmatism in the eastern Sakarya zone was recorded by voluminous basic volcanism and repeated plutonism during the early Cenozoic. The temporal and geochemical evolution of these magmatic rocks is important for understanding the possible geodynamic history of the Sakarya zone. Here, we investigated three representative plutons lying between the towns of Çamlıhemşin (Rize) and İspir (Erzurum), Turkey. These are largely composed of medium-K gabbroic diorites (Marselavat Pluton), shoshonitic monzonites (Güllübağ Pluton), and high-K granites (Ayder Pluton). We present whole-rock geochemistry, 40Ar/39Ar geochronology, and Sr, Nd, and Pb isotope analyses from the plutons to constrain the timing of variations in magmatism and source characteristics, and we provide a new approach to the proposed geodynamic models, which are still heavily debated. The 40Ar/39Ar geochronology reveals a cooling sequence from ca. 45 Ma for the Marselavat Pluton through ca. 41 Ma for the Güllübağ Pluton to ca. 40 Ma for the Ayder Pluton. Whole-rock geochemistry and Sr, Nd, Pb isotopes suggest that crustal contamination was not an important factor affecting magma compositions. Although there was no arc-related tectonic setting in the region during the middle Eocene, the Marselavat Pluton shows some subduction affinities, such as moderately negative Nb and Ta anomalies, and slightly positive Pb anomalies. These signatures were possibly inherited from a depleted mantle source that was modified by hydrous fluids released from the oceanic slab during Late Cretaceous subduction. Geochemical traces of the earlier subduction become uncertain in the Güllübağ samples. They display ocean-island basalt–like multi-element profiles and Nb/Ta, Ce/Pb, and La/Ba ratios. All these point to a mantle source in which earlier subduction signatures were hybridized by the addition of asthenospheric melts. Melting of calc-alkaline crustal material, probably emplaced during the first phase of middle Eocene magmatism (Marselavat), led to the formation of granitic plutonism (Ayder Pluton). Our data in conjunction with early Eocene adakite-like rocks show that melt generation, as in the given sequence, was most probably triggered by breakoff of the northern Neotethyan oceanic slab, ∼13 m.y. after the early Maastrichtian collision between the Sakarya zone and Anatolide-Tauride block, and continued until the end of the middle Eocene. A shallow-marine transgression occurred contemporaneously with the middle Eocene magmatism throughout the Sakarya zone. An extension in this magnitude seems unlikely to be the result of orogenic collapse processes only. The main cause of this extension was most probably related to the northward subduction of the southern Neotethys Ocean beneath the Anatolide-Tauride block. The result is a volumetrically larger amount of middle Eocene magmatism than that expected in response to slab breakoff.
40

Leitch, C. H. B., P. van der Heyden, C. I. Godwin, R. L. Armstrong, and J. E. Harakal. "Geochronometry of the Bridge River Camp, southwestern British Columbia." Canadian Journal of Earth Sciences 28, no. 2 (February 1, 1991): 195–208. http://dx.doi.org/10.1139/e91-019.

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Mineralization at the Bralorne mesothermal gold vein deposit is closely related to a suite of early Late Cretaceous to early Tertiary dykes. Premineral albitite dykes (91.4 ± 1.4 Ma by U–Pb on zircons) and postmineral lamprophyre dykes (43.5 ± 1.5 Ma by K–Ar on biotite) set definite age limits on the mineralizing event. A late intra- to post-mineral green hornblende dyke set (85.7 ± 3.0 Ma by K–Ar on hornblende) that forms a transitional series to the albitites may further restrict the age. Thus, mineralization occurred long after emplacement of the host Bralorne intrusions, dated as Early Permian (minimum age of approximately 270 ± 5 Ma by U–Pb on zircons, 284 ± 20 Ma by K–Ar on hornblende, and 40Ar/39Ar plateau at 276 ± 31 Ma). Lithologically similar intrusions 20 km to the north near Gold Bridge are also Early Permian (287 ± 20 Ma by K–Ar on hornblende and 320 ± 80 Ma by a Rb–Sr whole-rock isochron). Geochronology, radiogenic and stable isotopes, and fluid-inclusion studies suggest that there were several pulses of mineralizing activity adjacent to and east of the Coast Plutonic Complex (CPC). Decreasing temperatures and younger age of mineralization with increasing distance from the CPC imply that plutons of the CPC were the main heat source responsible for mineralization. The main pulses were about 90 Ma for mesothermal Au–Ag–As ± W,Mo mineralization at Bralorne near the CPC, ranging outwards to 65 Ma for Ag–Au–Sb–As ± Hg mineralization at the Minto and Congress deposits, to 45 Ma for Ag–Au epithermal mineralization at Blackdome, 100 km east of the CPC.The Bralorne intrusions may have been emplaced below the sea floor in a spreading-ridge oceanic environment, as suggested by the petrology of the intrusive suite, which includes serpentinized ultramafite, hornblende diorite, and soda granite (trondhjemite), typical of an ophiolite association. The chemistry of volcanic rocks mapped as Cadwallader Group, which host these intrusive bodies, is transitional from mid-ocean-ridge basalts to island-arc tholeiite, suggesting a back-arc-basin setting. Gradational contact relations between the hornblende diorite and the volcanic rocks suggest that the diorite intruded its own volcanic products. Intrusive contacts of the diorite with adjacent elongate ultramafic bodies imply that the ultramafic rocks are of Permian or older age and had been structurally emplaced into crustal levels by the time of diorite intrusion. In the Bralorne fault block the Bralorne intrusions appear to cut the adjacent Cadwallader and Bridge River groups, implying an Early Permian or older age for at least parts of these groups. Thus, rocks mapped as Cadwallader Group in the Bralorne area could be distinct from and older than lithologic equivalents exposed elsewhere, although they are similar in terms of their petrology and major- and trace-element chemistry.
41

Petronis, Michael S., John W. Geissman, John S. Oldow, and William C. McIntosh. "Paleomagnetic and 40Ar/39Ar geochronologic data bearing on the structural evolution of the Silver Peak extensional complex, west-central Nevada." GSA Bulletin 114, no. 9 (September 1, 2002): 1108–30. http://dx.doi.org/10.1130/0016-7606(2002)114<1108:paaagd>2.0.co;2.

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Abstract The Silver Peak extensional complex, located in the Silver Peak Range of west- central Nevada, is a displacement-transfer system linking the Furnace Creek–Fish Lake Valley fault system and transcurrent faults of the central Walker Lane. Late Neogene, northwest-directed motion of an upper plate, composed of lower Paleozoic sedimentary rocks and late Tertiary volcanic and volcaniclastic strata, exhumed a lower-plate assemblage of metamorphic tectonites with Proterozoic and Mesozoic protoliths. Paleomagnetic investigation of Miocene–Pliocene pyroclastic and sedimentary rocks of the upper plate and Miocene mafic dikes in the lower plate reveals modest horizontal- axis tilting (northwest-side-up) and vertical-axis rotation (clockwise) within the extensional complex. Eight to ten samples from each of 123 sites were demagnetized; 95 sites yielded interpretable results. Dual- polarity results from one population of mafic dikes in the lower-plate assemblage indicate moderate, northwest-side-up tilting (declination D = 329°, inclination I = 37°, α95 = 4.3°, number N = 30 sites; in situ) (α95 = the confidence limit for the calculated mean direction expressed as an angular radius from the calculated mean direction). Some dikes yield exclusively normal-polarity results that are interpreted to indicate modest clockwise vertical-axis rotation (D = 021°, I = 57°, α95 = 4.3°, N = 19 sites; in situ) concurrent with uplift of the lower-plate rocks, and nine sites yield magnetization directions that are north-directed with positive inclinations of moderate steepness, similar to an expected Miocene field. Late Miocene pyroclastic rocks in the upper plate yield normal-polarity magnetizations suggestive of moderate, clockwise, vertical-axis rotation (D = 032°, I = 53°, α95 = 8.8°, N = 10 sites). The apparent clockwise rotation is unlikely to result from incomplete sampling of the geomagnetic field, because the overall dispersion of the VGP (virtual geomagnetic pole) positions is high for the latitude of the site location. Middle Miocene sedimentary rocks probably were remagnetized shortly after deposition. Of eight 40Ar/39Ar determinations from mafic dikes in the lower plate, five groundmass concentrates yield saddle-shaped age spectra, and one separate provided a plateau date of low confidence. Isochron analysis reveals that all six groundmass concentrates contain excess Ar. If rapid cooling and Ar retention below ∼250 °C are assumed, the preferred age estimate for mafic intrusions is provided by isochron dates and suggests emplacement between 12 and 10.5 Ma. The 40Ar/39Ar age-spectrum data are consistent with existing fission-track cooling and K-Ar isotopic age information from lower-plate granitic rocks and indicate rapid cooling of the lower-plate assemblage from well above 300 °C to 100 °C between 13 and 5 Ma. Rapid cooling may explain the overall distribution of paleomagnetic results from lower-plate intrusions such that the earliest acquired magnetizations reflect both northwest-side-up tilt and clockwise rotation and the younger magnetizations reflect northwest-side-up tilt. Overall, the paleomagnetic data from the Silver Peak extensional complex are interpreted to suggest that vertical-axis rotation of crustal-scale blocks, associated with displacement transfer in the central Walker Lane, may play an integral part in accommodating strain within a continental displacement-transfer system.
42

Wilson, N. S. F., M. Zentilli, P. H. Reynolds, and R. Boric. "Age of mineralization by basinal fluids at the El Soldado manto-type copper deposit, Chile: 40Ar/39Ar geochronology of K-feldspar." Chemical Geology 197, no. 1-4 (June 2003): 161–76. http://dx.doi.org/10.1016/s0009-2541(02)00350-9.

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43

Zhang, Yong, Jing-Gui Sun, Shu-Wen Xing, and Zeng-Jie Zhang. "Geochronology and geochemistry of the Cuihongshan Fe-polymetallic deposit, northeastern China: implications for ore genesis and tectonic setting." Canadian Journal of Earth Sciences 55, no. 5 (May 2018): 475–89. http://dx.doi.org/10.1139/cjes-2017-0178.

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The Lesser Xing’an Range is located in the eastern segment of the Central Asian Orogenic Belt. It hosts an important polymetallic metallogenic belt that contains more than 20 large- to small-scale porphyry Mo, epithermal Au, and skarn Fe-polymetallic deposits. The Cuihongshan Fe-polymetallic deposit is one of the largest polymetallic deposits in northeastern China. To better understand the formation of the Cuihongshan Fe-polymetallic deposit, we investigated the geological characteristics of the Cuihongshan deposit and applied geochemistry and geochronology to constrain the timing of the mineralization, and characteristics of the magmas. Zircon U–Pb dating of the alkali-feldspar granite and monzogranite yielded weighted mean 206Pb/238U ages of 495 ± 1.6 and 203 ± 1 Ma, respectively. Re–Os dating on molybdenite yielded an isochron age of 203.2 ± 1.4 Ma, and 40Ar/39Ar dating on phlogopite yielded an age of 203.4 ± 1.3 Ma. These data suggest that mineralization occurred during the Late Triassic, and is closely related with the monzogranite emplacement. These rocks belong to the high-K calc-alkaline and subalkaline series, are enriched in Rb, U, and Th, are depleted in Nb, Ta, and Ti, and show strong Eu anomalies, implying that they are A-type post-orogenic rocks. The Cuihongshan Fe-polymetallic formation is possibly related to an extensional environment resulting from the final closure of the Paleo-Asian Ocean.
44

Li, Huan, Kotaro Yonezu, Koichiro Watanabe, and Thomas Tindell. "Fluid origin and migration of the Huangshaping W–Mo polymetallic deposit, South China: Geochemistry and 40Ar/39Ar geochronology of hydrothermal K-feldspars." Ore Geology Reviews 86 (June 2017): 117–29. http://dx.doi.org/10.1016/j.oregeorev.2017.02.005.

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45

PROSSER, GIACOMO, MARIO BENTIVENGA, MARINELLA A. LAURENZI, ALFREDO CAGGIANELLI, PIERFRANCESCO DELLINO, and DOMENICO DORONZO. "Late Pliocene volcaniclastic products from Southern Apennines: distal witness of early explosive volcanism in the central Tyrrhenian Sea." Geological Magazine 145, no. 4 (April 11, 2008): 521–36. http://dx.doi.org/10.1017/s0016756808004512.

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AbstractTwo volcaniclastic successions intercalated in Pliocene basinal clays from the Southern Apennines have been analysed to determine their provenance and their relationship with the geodynamic evolution of the Western Mediterranean. The studied deposits are exclusively made up of ashy pyroclasts, dominated by fresh acidic to intermediate glass, mostly in the form of shards, pumice fragments and groundmass fragments with vitrophyric texture. Crystals include Pl, Opx, Cpx, Hbl and rare Bt. Sedimentological features suggest that the volcanic material accumulated near the basin margin by primary fallout processes and was later remobilized by density currents. 40Ar–39Ar geochronology allowed dating of one succession at 2.24±0.06 Ma, corresponding to the Late Pliocene. Composition of the volcaniclastic material is typical of a transitional high-K calc-alkaline series. The age and chemical composition constrain the provenance of the volcaniclastic rocks from the Southern Tyrrhenian domain. Here, volcanic centres were active during Pliocene time, approximately at the northern end of a volcanic arc formed before the opening of the southernmost part of the sea. This paper shows that a detailed study of volcaniclastic products from the southern Apennines and Calabria can be very useful in collecting new pieces of information on the eruption history of the southern Tyrrhenian domain, since they record additional data not available from the study of exposed volcanic edifices.
46

Yang, Jing, De-Wen Zheng, Wen Chen, Brian Hough, Hua-Ning Qiu, Wei-Tao Wang, Ying Wu, and Li Yang. "40Ar/39Ar geochronology of supergene K-bearing sulfate minerals: Cenozoic continental weathering and its paleoclimatic significance in the Tu–Ha Basin, northwestern China." Palaeogeography, Palaeoclimatology, Palaeoecology 445 (March 2016): 83–96. http://dx.doi.org/10.1016/j.palaeo.2016.01.005.

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47

Li, Jian-Wei, and Paulo Vasconcelos. "Cenozoic continental weathering and its implications for the palaeoclimate: evidence from 40Ar/39Ar geochronology of supergene K–Mn oxides in Mt Tabor, central Queensland, Australia." Earth and Planetary Science Letters 200, no. 1-2 (June 2002): 223–39. http://dx.doi.org/10.1016/s0012-821x(02)00594-0.

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48

Olierook, Hugo K. H., Kai Rankenburg, Stanislav Ulrich, Christopher L. Kirkland, Noreen J. Evans, Stephen Brown, Brent I. A. McInnes, et al. "Resolving multiple geological events using in situ Rb–Sr geochronology: implications for metallogenesis at Tropicana, Western Australia." Geochronology 2, no. 2 (October 22, 2020): 283–303. http://dx.doi.org/10.5194/gchron-2-283-2020.

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Abstract. Dating multiple geological events in single samples using thermochronology and geochronology is relatively common, but it is only with the recent advent of triple quadrupole laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) that in situ rubidium–strontium (Rb–Sr) dating has become a more commonly applied and powerful tool to date K-rich or Rb-bearing minerals. Here, we date two generations of mineral assemblages in individual thin sections using the in situ Rb–Sr method. Two distinct mineral assemblages, both probably associated with Au mineralization, are identified in samples from the Tropicana gold mine in the Albany–Fraser Orogen, Western Australia. For Rb–Sr purposes, the key dateable minerals are two generations of biotite as well as additional phengite associated with the younger assemblage. Our results reveal that the first, coarse-grained generation of biotite grains records a minimum age of 2535±18 Ma, coeval with previous 40Ar∕39Ar biotite, rhenium–osmium (Re–Os) pyrite and uranium–lead (U–Pb) rutile results. The second, fine-grained and recrystallized generation of biotite grains record an age of 1207±12 Ma across all samples. Phengite and muscovite yielded broadly similar results at ca. 1.2 Ga, but data are overdispersed for a single coeval population of phengite and show elevated age uncertainties for muscovite. We propose that the ca. 2530 Ma age recorded by various geochronometers represents cooling and exhumation and that the age of ca. 1210 Ma is related to major shearing associated with the regional deformation as part of Stage II of the Albany–Fraser Orogeny. This is the first time that an age of ca. 1210 Ma has been identified in the Tropicana Zone, which may have ramifications for constraining the timing of mineralization in the region. The in situ Rb–Sr technique is currently the only tool capable of resolving both geological events in these rocks.
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Trop, Jeffrey M., Jeff Benowitz, Ronald B. Cole, and Paul O’Sullivan. "Cretaceous to Miocene magmatism, sedimentation, and exhumation within the Alaska Range suture zone: A polyphase reactivated terrane boundary." Geosphere 15, no. 4 (June 26, 2019): 1066–101. http://dx.doi.org/10.1130/ges02014.1.

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AbstractThe Alaska Range suture zone exposes Cretaceous to Quaternary marine and nonmarine sedimentary and volcanic rocks sandwiched between oceanic rocks of the accreted Wrangellia composite terrane to the south and older continental terranes to the north. New U-Pb zircon ages, 40Ar/39Ar, ZHe, and AFT cooling ages, geochemical compositions, and geological field observations from these rocks provide improved constraints on the timing of Cretaceous to Miocene magmatism, sedimentation, and deformation within the collisional suture zone. Our results bear on the unclear displacement history of the seismically active Denali fault, which bisects the suture zone. Newly identified tuffs north of the Denali fault in sedimentary strata of the Cantwell Formation yield ca. 72 to ca. 68 Ma U-Pb zircon ages. Lavas sampled south of the Denali fault yield ca. 69 Ma 40Ar/39Ar ages and geochemical compositions typical of arc assemblages, ranging from basalt-andesite-trachyte, relatively high-K, and high concentrations of incompatible elements attributed to slab contribution (e.g., high Cs, Ba, and Th). The Late Cretaceous lavas and bentonites, together with regionally extensive coeval calc-alkaline plutons, record arc magmatism during contractional deformation and metamorphism within the suture zone. Latest Cretaceous volcanic and sedimentary strata are locally overlain by Eocene Teklanika Formation volcanic rocks with geochemical compositions transitional between arc and intraplate affinity. New detrital-zircon data from the modern Teklanika River indicate peak Teklanika volcanism at ca. 57 Ma, which is also reflected in zircon Pb loss in Cantwell Formation bentonites. Teklanika Formation volcanism may reflect hypothesized slab break-off and a Paleocene–Eocene period of a transform margin configuration. Mafic dike swarms were emplaced along the Denali fault from ca. 38 to ca. 25 Ma based on new 40Ar/39Ar ages. Diking along the Denali fault may have been localized by strike-slip extension following a change in direction of the subducting oceanic plate beneath southern Alaska from N-NE to NW at ca. 46–40 Ma. Diking represents the last recorded episode of significant magmatism in the central and eastern Alaska Range, including along the Denali fault. Two tectonic models may explain emplacement of more primitive and less extensive Eocene–Oligocene magmas: delamination of the Late Cretaceous–Paleocene arc root and/or thickened suture zone lithosphere, or a slab window created during possible Paleocene slab break-off. Fluvial strata exposed just south of the Denali fault in the central Alaska Range record synorogenic sedimentation coeval with diking and inferred strike-slip displacement. Deposition occurred ca. 29 Ma based on palynomorphs and the youngest detrital zircons. U-Pb detrital-zircon geochronology and clast compositional data indicate the fluvial strata were derived from sedimentary and igneous bedrock presently exposed within the Alaska Range, including Cretaceous sources presently exposed on the opposite (north) side of the fault. The provenance data may indicate ∼150 km or more of dextral offset of the ca. 29 Ma strata from inferred sediment sources, but different amounts of slip are feasible.Together, the dike swarms and fluvial strata are interpreted to record Oligocene strike-slip movement along the Denali fault system, coeval with strike-slip basin development along other segments of the fault. Diking and sedimentation occurred just prior to the onset of rapid and persistent exhumation ca. 25 Ma across the Alaska Range. This phase of reactivation of the suture zone is interpreted to reflect the translation along and convergence of southern Alaska across the Denali fault driven by highly coupled flat-slab subduction of the Yakutat microplate, which continues to accrete to the southern margin of Alaska. Furthermore, a change in Pacific plate direction and velocity at ca. 25 Ma created a more convergent regime along the apex of the Denali fault curve, likely contributing to the shutting off of near-fault extension-facilitated arc magmatism along this section of the fault system and increased exhumation rates.
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Yan, Qiaojuan, Zhengle Chen, Zhenju Zhou, Tongyang Zhao, Qiong Han, Jilin Li, Bo Liu, and Wengao Zhang. "Fluid Evolution and Ore Genesis of the Juyuan Tungsten Deposit, Beishan, NW China." Minerals 11, no. 12 (November 24, 2021): 1309. http://dx.doi.org/10.3390/min11121309.

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The newly discovered Juyuan tungsten deposit is hosted in Triassic granite in the Beishan Orogen, NW China. The tungsten mineralization occurred as quartz veins, and the main ore minerals included wolframite and scheelite. The age, origin, and tectonic setting of the Juyuan tungsten deposit, however, remain poorly understood. According to the mineralogical assemblages and crosscutting relationships, three hydrothermal stages can be identified, i.e., the early stage of quartz veins with scheelite and wolframite, the intermediate stage of quartz veinlets with sulfides, and the late stage of carbonate-quartz veinlets with tungsten being mainly introduced in the early stage. Quartz formed in the two earlier stages contained four compositional types of fluid inclusions, i.e., pure CO2, CO2-H2O, daughter mineral-bearing, and NaCl-H2O, but the late-stage quartz only contained the NaCl-H2O inclusions. The inclusions in quartz formed in the early, intermediate, and late stages had total homogenization temperatures of 230–344 °C, 241−295 °C, and 184−234 °C, respectively, with salinities no higher than 7.2 wt.% NaCl equiv (equivalent). Trapping pressures estimated from the CO2-H2O inclusions were 33−256 MPa and 36−214 MPa in the early and intermediate stages, corresponding to mineralization depths of 3–8 km. Fluid boiling and mixing caused rapid precipitation of wolframite, scheelite, and sulfides. Through boiling and inflow of meteoric water, the ore-forming fluid system evolved from CO2-rich to CO2-poor in composition and from magmatic to meteoric, as indicated by decreasing δ18Owater values from early to late stages. The sulfur and lead isotope compositions in the intermediate-stage suggest that the Triassic granite was a significant source of ore metals. The biotite 40Ar/39Ar age from the W-bearing quartz shows that the Juyuan tungsten system was formed at 240.0 ± 1.0 Ma, coeval with the emplacement of granitic rocks at the deposit. Integrating the data obtained from the studies including regional geology, ore geology, biotite Ar-Ar geochronology, fluid inclusion, and C-H-O-S-Pb isotope geochemistry, we conclude that the Juyuan tungsten deposit was a quartz-vein type system that originated from the emplacement of the granites, which was induced by collision between the Tarim and Kazakhstan–Ili plates. A comparison of the characteristics of tungsten mineralization in East Tianshan and Beishan suggests that the Triassic tungsten metallogenic belt in East Tianshan extends to the Beishan orogenic belt and that the west of the orogenic belt also has potential for the discovery of further quartz-vein-type tungsten deposits.

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