Готові списки джерел за темами / Ion Conducting Polymer Electrolytes

Добірка наукової літератури з теми "Ion Conducting Polymer Electrolytes"

Автор: Grafiati
Опубліковано: 7 вересня 2023

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Статті в журналах з теми "Ion Conducting Polymer Electrolytes"

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Kohl, Paul, Mrinmay Mandal, Mengjie Chen, Habin Park, and Parin Shah. "(Invited) Anion Conducting Solid Polymer Ionomers Electrolytes for Fuel Cells and Electrolyzers." ECS Meeting Abstracts MA2022-02, no. 46 (October 9, 2022): 1718. http://dx.doi.org/10.1149/ma2022-02461718mtgabs.

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Ion conducting polymer electrolytes provide an enabling technology for the creation of low temperature fuel cells, hydrogen producing water electrolyzers, and flow batteries. The critical parameters of solid polymer electrolytes include ionic conductivity, ion selectivity, chemical resistance and dimensional stability in the presence of excess water. High pH operation using anion conductive polymer electrolytes has several potential advantages over acid-based polymer devices including low-cost catalysts, hydrocarbon (non-perfluorinated) polymer, and low cost cell components. However, the identification and synthesis of stable, hydroxide conducting solid polymer electrolytes has been elusive. In this study, a family of hydroxide conducting, poly(norbornene) solid polymer electrolytes were synthesized and used in high-performance, durable membrane electrode assemblies for fuel cells and electrolyzers. In addition to membranes, covalently bonded, self-adherent, hydroxide conducting ionomers were used to form high-performance, durable membrane electrode assembly for water electrolysis. Electrodes made by grind-spray method were compared to electrodes prepared by the solvent-cast method. The self-adhesive ionomers and membranes are based on hydroxide conducting poly(norbornene) polymers. The effect of porous transport layer material and porosity was examined. High performance electrolysis with very low degradation rates was achieved using stainless steel and nickel porous transport layers.
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Watanabe, Masayoshi. "Ion Conducting Polymers Polymer Electrolytes." Kobunshi 42, no. 8 (1993): 702–5. http://dx.doi.org/10.1295/kobunshi.42.702.

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Scrosati, Bruno. "Ion-conducting polymer electrolytes." Philosophical Magazine B 59, no. 1 (January 1989): 151–60. http://dx.doi.org/10.1080/13642818908208454.

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Ghorbanzade, Pedram, Laura C. Loaiza, and Patrik Johansson. "Plasticized and salt-doped single-ion conducting polymer electrolytes for lithium batteries." RSC Advances 12, no. 28 (2022): 18164–67. http://dx.doi.org/10.1039/d2ra03249j.

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Lee, Kyoung-Jin, Eun-Jeong Yi, Gangsanin Kim, and Haejin Hwang. "Synthesis of Ceramic/Polymer Nanocomposite Electrolytes for All-Solid-State Batteries." Journal of Nanoscience and Nanotechnology 20, no. 7 (July 1, 2020): 4494–97. http://dx.doi.org/10.1166/jnn.2020.17562.

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Lithium-ion conducting nanocomposite solid electrolytes were synthesized from polyethylene oxide (PEO), poly(methyl methacrylate) (PMMA), LiClO4, and Li1.3Al0.3Ti1.7(PO4)3 (LATP) ceramic particles. The synthesized nanocomposite electrolyte consisted of LATP particles and an amorphous polymer. LATP particles were homogeneously distributed in the polymer matrix. The nanocomposite electrolytes were flexible and self-standing. The lithium-ion conductivity of the nanocomposite electrolyte was almost an order of magnitude higher than that of the PEO/PMMA solid polymer electrolyte.
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Hoffman, Zach J., Alec S. Ho, Saheli Chakraborty, and Nitash P. Balsara. "Limiting Current Density in Single-Ion-Conducting and Conventional Block Copolymer Electrolytes." Journal of The Electrochemical Society 169, no. 4 (April 1, 2022): 043502. http://dx.doi.org/10.1149/1945-7111/ac613b.

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The limiting current density of a conventional polymer electrolyte (PS-PEO/LiTFSI) and a single-ion-conducting polymer electrolyte (PSLiTFSI-PEO) was measured using a new approach based on the fitted slopes of the potential obtained from lithium-polymer-lithium symmetric cells at a constant current density. The results of this method were consistent with those of an alternative framework for identifying the limiting current density taken from the literature. We found the limiting current density of the conventional electrolyte is inversely proportional to electrolyte thickness as expected from theory. The limiting current density of the single-ion-conducting electrolyte was found to be independent of thickness. There are no theories that address the dependence of the limiting current density on thickness for single-ion-conducting electrolytes.
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Ogata, N., K. Sanui, M. Rikukawa, S. Yamada, and M. Watanabe. "Super ion conducting polymers for solid polymer electrolytes." Synthetic Metals 69, no. 1-3 (March 1995): 521–24. http://dx.doi.org/10.1016/0379-6779(94)02553-b.

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K Manjula, K. Manjula, and V. John Reddy. "Na+ Ion Conducting Nano-Composite Solid Polymer Electrolyte – Application to Electrochemical Cell." Oriental Journal Of Chemistry 38, no. 5 (October 31, 2022): 1204–8. http://dx.doi.org/10.13005/ojc/380515.

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Various concentrations of Multi Walled Carbon Nanotubes (MCNT) fillers dispersed PVDF- HFP: NaClO4 nanocomposite polymer electrolytes (NPE) were prepared by solution casting technique. The dispersion of MCNT nano fillers raised the accessibility of more ions for attaining the highest conductivity. Electrical conductivity, Ohmic resistance (RΩ), Polarisation resistanace (Rp), and Warburg impedance (W) were studied using electrochemical impedance spectroscopy (EIS), which revealed ion transport mechanics in the polymer electrolytes. The best ionic conductivity is found to be 8.46 × 10-3 Scm-1 for the 7 wt.% dispersed MCNT Nanocomposite Solid Polymer electrolyte among all polymer electrolyte samples. Electrochemical cell was made by PVDF-HFP:NaClO4 : MCNT polymer electrolyte and exhibited 1.95 V open circuit voltage and 2.5 mA short circuit current, respectively.
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Zhang, Heng, Chunmei Li, Michal Piszcz, Estibaliz Coya, Teofilo Rojo, Lide M. Rodriguez-Martinez, Michel Armand, and Zhibin Zhou. "Single lithium-ion conducting solid polymer electrolytes: advances and perspectives." Chemical Society Reviews 46, no. 3 (2017): 797–815. http://dx.doi.org/10.1039/c6cs00491a.

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Single lithium-ion conducting solid polymer electrolytes (SLIC-SPEs), with a high lithium-ion transference number, the absence of the detrimental effect of anion polarization, and low dendrite growth rate, could be an excellent choice of safe electrolyte materials for lithium batteries in the future.
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Leena Chandra, Manuel Victor, Shunmugavel Karthikeyan, Subramanian Selvasekarapandian, Manavalan Premalatha, and Sampath Monisha. "Study of PVAc-PMMA-LiCl polymer blend electrolyte and the effect of plasticizer ethylene carbonate and nanofiller titania on PVAc-PMMA-LiCl polymer blend electrolyte." Journal of Polymer Engineering 37, no. 6 (July 26, 2017): 617–31. http://dx.doi.org/10.1515/polyeng-2016-0145.

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Abstract lithium ion conducting polymer electrolyte is one of the essential components of modern rechargeable lithium batteries because of its good interfacial contact with electrodes and effective mechanical properties. A solid lithium ion conducting polymer blend electrolyte is prepared using poly (vinyl acetate) (PVAc) and poly (methyl methacrylate) (PMMA) polymers with different molecular weight percentages (wt%) of lithium chloride (LiCl) by the solution casting technique with tetrahydrofuran as a solvent. The polymer electrolytes were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), Thermogravimetry (TG), AC impedance spectroscopy and ionic transport measurements. XRD and FTIR studies confirm the amorphous nature of the polymer electrolyte and the complexation of salt with polymer. The thermal behavior of polymer electrolytes has been studied from DSC and TG. The highest conductivity obtained using AC impedance spectroscopy is 1.03×10−5 Scm−1 at 303 K for 70 wt%PVAc:30 wt%PMMA:0.8 wt% of LiCl polymer-salt complex. The plasticizer ethylene carbonate (EC) and nanofiller titania (TiO2) were added to the optimized high conducting blend polymer electrolyte. An enhancement in conductivity by one order of magnitude was observed for the plasticized 70 wt%PVAc-30 wt%PMMA-0.8 wt% LiCl polymer electrolyte at ambient temperature. The ionic conductivity value obtained using AC impedance spectroscopy for the plasticized 70 wt%PVAc-30 wt%PMMA-0.8 wt% LiCl polymer electrolyte was 1.03×10−4 Scm−1. The highest conductivity obtained for 70 wt%PVAc-30 wt%PMMA-0.8% LiCl-6 mg TiO2 was 4.45×10−4 Scm−1. Dielectric properties of polymer films are studied and discussed. The electrochemical stability of 1.69 V and 2.69 V was obtained for 70 wt%PVAc-30 wt%PMMA-0.8% LiCl and 70 wt%PVAc-30 wt%PMMA-0.8% LiCl-6 mg TiO2 polymer electrolytes, respectively, using linear sweep voltammetry. The value of Li+ ion transference number was estimated by the DC polarization method and was found to be 0.99 for the highest conducting 70 wt%PVAc-30 wt%PMMA-0.8 wt% LiCl-6 mg TiO2 nanocomposite polymer electrolyte.
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Дисертації з теми "Ion Conducting Polymer Electrolytes"

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Willgert, Markus. "Solid Polymer Lithium-Ion Conducting Electrolytes for Structural Batteries." Doctoral thesis, KTH, Ytbehandlingsteknik, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-144169.

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This work comprises the manufacture and characterization of solid polymer lithium ion conducting electrolytes for structural batteries. In the study, polymer films are produced in situ via a rapid versatile UV irradiation polymerization route, in which ethylene oxide methacrylates are polymerized into thermoset networks. In the first part of the study, the simplicity and efficiency of this manufacturing route is emphasized. Polymer electrolytes are pro-duced with an ionic conductivity ranging from 5.8×10-10 S cm-1 up to 1.5×10-6 S cm-1, and a storage modulus of up to 2 GPa at 20°C. In the sec-ond part, the effect of the lithium salt content is studied, both for tightly crosslinked systems with a glass transition temperature (Tg) above room temperature but also for sparsely crosslinked system with a Tg below. It is shown that for these systems, there is a threshold amount of 4% lithium salt by weight, above which the ion conducting ability is not affected to a larger extent when the salt content is increased further. It is also shown that the influence of the salt content on the ionic conductivity is similar within both systems. However, the Tg is more affected by the addition of lithium salt for the loosely crosslinked system, and since the Tg is the main affecting parame-ter of the conductivity, the salt content plays a larger role here. In the third part of the study, a thiol functional compound is added via thiol-ene chemistry to create thio-ether segments in the polymer network. This is done in order to expand the toolbox of possible building blocks usable in the design of structural electrolytes. It is shown that solid polymer electrolytes of more homogeneous networks with a narrower glass transition region can be produced this way, and that they have the ability to function as an electrolyte. Finally, the abilities of reinforcing the electrolytes by nano fibrilar cellulose are investigated, by means to improve the mechanical properties without decreasing the ionic conductivity at any larger extent. These composites show conductivity values close to 10-4 S cm-1 and a storage modulus around 400 MPa at 25 °C.

QC 20140410

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Willgert, Markus. "Solid Polymer Lithium-ion Conducting Electrolytes for Structural Batteries." Licentiate thesis, KTH, Ytbehandlingsteknik, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-107182.

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LINGUA, GABRIELE. "Newly designed single-ion conducting polymer electrolytes enabling advanced Li-metal solid-state batteries." Doctoral thesis, Politecnico di Torino, 2022. http://hdl.handle.net/11583/2969103.

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Best, Adam Samuel 1976. "Lithium-ion conducting electrolytes for use in lithium battery applications." Monash University, School of Physics and Materials Engineering, 2001. http://arrow.monash.edu.au/hdl/1959.1/9240.

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Shen, Kuan-Hsuan. "Modeling ion conduction through salt-doped polymers: Morphology, ion solvation, and ion correlations." The Ohio State University, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=osu1595422569403378.

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Guo, Jiao. "Development of Ion Conductive Polymer Gel Electrolytes and Their Electrochemical and Electromechanical Behavior Studies." University of Akron / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=akron1279140041.

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Álvarez, Daniel Jardón. "Study of advanced ion conducting polymers by relaxation, diffusion and spectroscopy NMR methods." Universidade de São Paulo, 2016. http://www.teses.usp.br/teses/disponiveis/18/18158/tde-19102016-114611/.

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Анотація:
Advances on secondary lithium ion batteries imply the use of solid polymer electrolytes, which represent a promising solution to improve safety issues in high energy density batteries. Through dissolution of lithium salts into a polymeric host, such as poly(ethylene oxide) (PEO), ion conducting polymers are obtained. The Li+ ions will be localized in the proximity of the oxygen atoms in the PEO chains and thus, their motion strongly correlated with the segmental reorientation of the polymer. Nuclear magnetic resonance (NMR) spectroscopy, translational diffusion coefficients and transverse relaxation times (T2) contribute to the understanding of the involved structures and the ongoing dynamical processes in ionic conductivity. Nuclei with different motional freedom can present different T2 times. T2xT2 exchange experiments enable studying exchange processes between nuclei from different motional regimes. In this work, three different ion conducting polymers were studied. First, PEG was doped with different amounts of LiClO4. 7Li NMR relaxometry measurements were done to study dynamical behavior of the lithium ions in the amorphous phase. All samples presented two lithium types with clearly differentiated T2 times, indicating the presence of two regions with different dynamics. The mobility and consequently the T2 times, increases with temperature. It was observed, that the doping ratio strongly influences the dynamics of the lithium ions, as the amount of crystalline PEG is reduced while increasing the polarity of the sample. A local maximum of the mobility was observed for y = 8. With the T2xT2 exchange experiments exchange rates between both lithium sites were quantified. Second, the triblock copolymer PS-PEO-PS doped with LiTFSI was studied with high resolution solid state NMR techniques as well as with 7Li relaxometry measurements. T1ρ and spin diffusion measurements gave insight on the influence of the doping and the PS/PEO ratio on the mobility of the different segments and on interdomain distances of the lamellar phases. Third, multiple quantum diffusion measurements were applied on poly(ethylene glycol) distearate (PEGD) doped with LiClO4. Therefore, triple quantum states of the 3/2 nucleus 7Li were excited. After optimizing the experimental procedure, it was possible to obtain reliable diffusion coefficients using triple quantum states.
O avanço da tecnologia em baterias secundárias de íons lítio envolve o uso de polímeros condutores iônicos como eletrólitos, os quais representam uma solução promissora para obter baterias de maior densidade de energia e segurança. Polímeros condutores são formados através da dissolução de sais de lítio em uma matriz polimérica, como o poli(óxido de etileno) (PEO). Os íons de lítio estão localizados próximos aos oxigênios do PEO, de tal forma que seu movimento está correlacionado com a reorientação das cadeias poliméricas. Espectroscopia por Ressonância magnética nuclear (RMN), junto com medidas de difusão translacional e tempos de relaxação transversal (T2) contribuem para elucidar as estruturas e os processos dinâmicos envolvidos na condutividade iônica. Núcleos com diferente liberdade de movimentação podem ter tempos de T2 diferentes. Experimentos de T2xT2 permitem correlacionar sítios de diferentes propriedades dinâmicas. Neste trabalho, três diferentes polímeros condutores iônicos foram estudados. Primeiro, PEG foi dopado com LiClO4. As propriedades dinâmicas dos íons lítio na fase amorfa foram estudadas com medidas de relaxometria por RMN do núcleo 7Li. Todas as razões de dopagem apresentaram dois T2 diferentes, indicando dos tipos de lítio com dinâmica diferente. A mobilidade, e consequentemente os tempos T2 aumentam com aumento da temperatura. Foi identificado que a dopagem fortemente influencia a dinâmica dos íons lítio, devido à redução da fase cristalina PEG e o aumento da polaridade na amostra. Um máximo local da mobilidade foi observado para y = 8. Com o experimento T2xT2 foram quantificadas as rações de troca entre os dois tipos de lítio. Segundo, o copolímero tribloco PS-PEO-PS dopado com LiTFSI foi analisado através de técnicas de RMN de estado sólido de alta resolução assim como através de medidas de relaxação de 7Li. Medidas de T1ρ e difusão de spin mostraram a influência da dopagem e da razão PS/PEO na mobilidade dos diferentes segmentos e nas distâncias interdomínio das fases lamelares. Terceiro, medidas de difusão através de estados de múltiplos quanta foram feitas em diesterato de polietileno glicol (PEGD) dopado com LiClO4. Estados de triplo quantum foram criados no núcleo 7Li, spin 3/2. Após garantir a eficiência das ferramentas desenvolvidas, foi possível obter coeficientes de difusão confiáveis.
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Guha, Thakurta Soma. "Anhydrous State Proton and Lithium Ion Conducting Solid Polymer Electrolytes Based on Sulfonated Bisphenol-A-Poly(Arylene Ethers)." University of Akron / OhioLINK, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=akron1239911460.

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Spence, Graham Harvey. "New polymer and gel electrolytes for potential application in smart windows." Thesis, Heriot-Watt University, 1998. http://hdl.handle.net/10399/614.

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Vijayakumar, V. "Preparation, characterization and application of proton, lithium and zinc-ion conducting polymer electrolytes for supercapacitors, lithium- and zinc-metal batteries." Thesis(Ph.D.), CSIR-National Chemical Laboratory, 2021. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/5972.

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The use of liquid electrolytes in energy storage devices are associated with several constraints pertaining to safety. Polymer electrolytes are suitable candidates to overcome several problems associated with free-flowing liquid electrolytes. The current thesis deals with the development of proton, lithium, and zinc conducting gel polymer electrolytes for electrochemical energy storage devices such as supercapacitors, lithium-metal batteries, and zinc-metal batteries. Special emphasis is given to the improvement of electrode|electrolyte interface in polymer electrolyte-based energy storage devices by the ultraviolet-light-induced in situ processing strategy. Ultimately, the prospects of employing polymer electrolytes as an alternative to liquid electrolytes in energy storage devices is revisited in this dissertation through four dedicated working chapters.
University Grants Commissions (UGC), India CSIR, India
AcSIR
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Книги з теми "Ion Conducting Polymer Electrolytes"

1

Rubinson, Judith F., and Harry B. Mark, eds. Conducting Polymers and Polymer Electrolytes. Washington, DC: American Chemical Society, 2002. http://dx.doi.org/10.1021/bk-2003-0832.

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2

Jinli, Qiao, and Okada Tatsuhiro, eds. Hydrocarbon polymer electrolytes for fuel cell applications. Hauppauge, N.Y: Nova Science Publishers, 2008.

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3

Tatsuhiro, Okada, Saitō Morihiro, and Hayamizu Kikuko, eds. Perfluorinated polymer electrolyte membranes for fuel cells. New York: Nova Science Publishers, 2008.

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4

Saad, Alshreif A. Development of a novel conducting polymer modified electrode for ion extraction. Leicester: De Montfort University, 1999.

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5

F, Rubinson Judith, Mark Harry B, American Chemical Society. Division of Colloid and Surface Chemistry, and American Chemical Society Meeting, eds. Conducting polymers and polymer electrolytes: From biology to photovoltaics. Washington, D.C: American Chemical Society, 2002.

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Conducting Polymers and Polymer Electrolytes: From Biology to Photovoltaics (Acs Symposium Series). An American Chemical Society Publication, 2002.

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7

Mehrer, Helmut. Progress in Thermodynamics, Diffusion, Ion and Proton Transport of Ionic Compounds and Ion-Conducting Polymer Films. Trans Tech Publications, Limited, 2016.

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Progress in Thermodynamics, Diffusion, Ion and Proton Transport of Ionic Compounds and Ion-Conducting Polymer Films. Trans Tech Publications, Limited, 2016.

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9

Writer, Beta. Lithium-Ion Batteries: A Machine-Generated Summary of Current Research. Springer, 2019.

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Частини книг з теми "Ion Conducting Polymer Electrolytes"

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Chandra, Angesh, Alok Bhatt, and Archana Chandra. "Synthesis and Ion Transport Studies of K+ Ion Conducting Nanocomposite Polymer Electrolytes." In Trends and Applications in Advanced Polymeric Materials, 207–18. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2017. http://dx.doi.org/10.1002/9781119364795.ch11.

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Kim, Seok, Sung Goo Lee, and Soo Jin Park. "Ion Conducting Behaviors of Polymeric Composite Electrolytes Containing Mesoporous Silicates." In Solid State Phenomena, 51–54. Stafa: Trans Tech Publications Ltd., 2007. http://dx.doi.org/10.4028/3-908451-27-2.51.

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Brylev, O., M. Duclot, F. Alloin, J. Y. Sanchez, and J. L. Souquet. "Single Conductive Polymer Electrolytes: From Pressure Conductivity Measurements to Transport Mechanism." In Materials for Lithium-Ion Batteries, 517–20. Dordrecht: Springer Netherlands, 2000. http://dx.doi.org/10.1007/978-94-011-4333-2_32.

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Mallikarjun, A., M. Sangeetha, Maheshwar Reddy Mettu, M. Vikranth Reddy, M. Jaipal Reddy, J. Siva Kumar, and T. Sreekanth. "Morphological, Spectroscopic, Structural and Electrical Properties of $${\text{Mg}}^{ + 2}$$ Ion Conducting PMMA: PVDF-HFP Blend Polymer Electrolytes." In Advances in Sustainability Science and Technology, 401–16. Singapore: Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-16-4321-7_34.

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Tominaga, Yoichi. "A New Class of Ion-Conductive Polymer Electrolytes: CO2/Epoxide Alternating Copolymers With Lithium Salts." In Synthesis and Applications of Copolymers, 215–38. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118860168.ch8.

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Tsuchida, E. "Polymeric Solid Electrolyte and Ion-Conduction." In Progress in Pacific Polymer Science, 153–63. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-642-84115-6_20.

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Scrosati, Bruno. "Lithium Polymer Electrolytes." In Advances in Lithium-Ion Batteries, 251–66. Boston, MA: Springer US, 2002. http://dx.doi.org/10.1007/0-306-47508-1_9.

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Hartnig, Christoph, and Michael Schmidt. "Electrolytes and conducting salts." In Lithium-Ion Batteries: Basics and Applications, 59–74. Berlin, Heidelberg: Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-53071-9_6.

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Sakai, Yoshiro. "Ion Conducting Polymer Sensors." In Polymer Sensors and Actuators, 1–13. Berlin, Heidelberg: Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/978-3-662-04068-3_1.

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Rost, A., J. Schilm, M. Kusnezoff, and A. Michaelis. "Li-Ion Conducting Solid Electrolytes." In Ceramic Materials for Energy Applications III, 25–32. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118807934.ch3.

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Тези доповідей конференцій з теми "Ion Conducting Polymer Electrolytes"

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Ogata, N., K. Sanui, M. Rikukawa, S. Yamada, and M. Watanabe. "Super ion conducting polymers for solid polymer electrolytes." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835672.

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Hashmi, S. A., H. M. Upadhyaya, and Awalendra K. Thakur. "SODIUM ION CONDUCTING COMPOSITE POLYMER ELECTROLYTES FOR BATTERY APPLICATIONS." In Proceedings of the 7th Asian Conference. WORLD SCIENTIFIC, 2000. http://dx.doi.org/10.1142/9789812791979_0072.

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Rajendran, S., Chithra M. Mathew, T. Marimuthu, and K. Kesavan. "Li ion conducting gel polymer electrolytes based on Poly(vinyl acetate)." In PROCEEDING OF INTERNATIONAL CONFERENCE ON RECENT TRENDS IN APPLIED PHYSICS AND MATERIAL SCIENCE: RAM 2013. AIP, 2013. http://dx.doi.org/10.1063/1.4810457.

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Venugopal, Vinithra, Hao Zhang, and Vishnu-Baba Sundaresan. "A Chemo-Mechanical Constitutive Model for Conducting Polymers." In ASME 2013 Conference on Smart Materials, Adaptive Structures and Intelligent Systems. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/smasis2013-3218.

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Conducting polymers undergo volumetric expansion through redox-mediated ion exchange with its electrolytic environment. The ion transport processes resulting from an applied electrical field controls the conformational relaxation in conducting polymer and regulates the generated stress and strain. In the last two decades, significant contributions from various groups have resulted in methods to fabricate, model and characterize the mechanical response of conducting polymer actuators in bending mode. An alternating electrical field applied to the polymer electrolyte interface produces the mechanical response in the polymer. The electrical energy applied to the polymer is used by the electrochemical reaction in the polymer backbone, for ion transport at the electrolyte-polymer interface and for conformational changes to the polymer. Due to the advances in polymer synthesis, there are multitudes of polymer-dopant combinations used to design an actuator. Over the last decade, polypyrrole (PPy) has evolved to be the most common conducting polymer actuator. Thin sheets of polymer are electrodeposited on to a substrate, doped with dodecylbezenesulfonate (DBS-) and microfabricated into a hermetic, air operated cantilever actuator. The electrical energy applied across the thickness of the polymer is expended by the electrochemical interactions at the polymer-electrolyte interface, ion transport and electrostatic interactions of the backbone. The widely adopted model for designing actuators is the electrochemically stimulated conformational relaxation (ESCR) model. Despite these advances, there have been very few investigations into the development of a constitutive model for conducting polymers that represent the input-output relation for chemoelectromechanical energy conversion. On one hand, dynamic models of conducting polymers use multiphysics-based non-linear models that are computationally intensive and not scalable for complicated geometries. On the other, empirical models that represent the chemomechanical coupling in conducting polymers present an over-simplified approach and lack the scientific rigor in predicting the mechanical response. In order to address these limitations and to develop a constitutive model for conducting polymers, its coupled chemomechanical response and material degradation with time, we have developed a constitutive model for polypyrrole-based conducting polymer actuator. The constitutive model is applied to a micron-scale conducting polymer actuator and coupling coefficients are expressed using a mechanistic representation of coupling in polypyrrole (dodecylbenzenesulfonate) [PPy(DBS)].
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Isa, K. B. Md, L. Othman, D. Hambali, Z. Zainuddin, and Z. Osman. "Na-ion conducting gel polymer electrolytes based on polyvinylidenefluoride-co-hexafluoropropylene with sodium trifluoromethane-sulfonate." In GREEN DESIGN AND MANUFACTURE: ADVANCED AND EMERGING APPLICATIONS: Proceedings of the 4th International Conference on Green Design and Manufacture 2018. Author(s), 2018. http://dx.doi.org/10.1063/1.5066869.

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Northcutt, Robert, Vishnu-Baba Sundaresan, Sergio Salinas, and Hao Zhang. "Polypyrrole Bridge as a Support for Alamethicin-Reconstituted Planar Bilayer Lipid Membranes." In ASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems. ASMEDC, 2011. http://dx.doi.org/10.1115/smasis2011-5015.

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Conducting polymer actuators and sensors utilize electrochemical reactions and associated ion transport at the polymer-electrolyte interface for their engineering function. Similarly, a bioderived active material utilizes ion transport through a protein and across a bilayer lipid membrane for sensing and actuation functions. Inspired by the similarity in ion transport process in a bilayer lipid membrane (BLM) and conducting polymers, we propose to build an integrated ionic device in which the ion transport through the protein in the bilayer lipid membrane regulates the electrolytic and mechanical properties of the conducting polymer. This article demonstrates the fabrication and characterization of a DPhPC planar BLM reconstituted with alamethicin and supported on a polypyrrole bridge measuring 100 μm × 500 μm and formed across micro-fabricated gold pads. The assembly is supported on silicon dioxide coated wafers and packaged into an electronic-ionic package for electrochemical characterization. The various ionic components in the integrated ionic device are characterized using electrical impedance spectroscopy (EIS), cyclic voltammetry (CV), and chronoamperometry (CA) measurements. The results from our experimental studies demonstrate the procedure to fabricate a rugged electro active polymer supported BLM that will serve as a platform for chemical, bioelectrical sensing and VOC detection.
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BRAHMANANDHAN, G. M., J. MALATHI, M. HEMA, G. HIRANKUMAR, D. KHANNA, D. ARUN KUMAR, and S. SELVASEKARAPANDIAN. "STUDY OF Na+ ION CONDUCTION IN PVA-NaSCN SOLID POLYMER ELECTROLYTES." In Proceedings of the 10th Asian Conference. WORLD SCIENTIFIC, 2006. http://dx.doi.org/10.1142/9789812773104_0077.

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Gohel, Khushbu, and D. K. Kanchan. "Conductivity and dielectric behavior of lithium ion conducting gel polymer electrolyte." In NATIONAL CONFERENCE ON ADVANCED MATERIALS AND NANOTECHNOLOGY - 2018: AMN-2018. Author(s), 2018. http://dx.doi.org/10.1063/1.5052103.

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Harshlata, Kuldeep Mishra, and D. K. Rai. "Sodium ion conducting polymer electrolyte membrane prepared by phase inversion technique." In DAE SOLID STATE PHYSICS SYMPOSIUM 2017. Author(s), 2018. http://dx.doi.org/10.1063/1.5029181.

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Duncan, Andrew J., Timothy E. Long, and Donald J. Leo. "Design for Optimized Electromechanical Transduction in Ionic Polymer Transducers Fabricated With Architecturally Controlled Ionomers." In ASME 2009 Conference on Smart Materials, Adaptive Structures and Intelligent Systems. ASMEDC, 2009. http://dx.doi.org/10.1115/smasis2009-1373.

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Ionic polymer transducers (IPT) are devices composed of ionomeric membranes, high surface area electrodes, and ion-conducting electrolytes that are capable of electromechanical transduction. This study aims to optimize the interactions between all three of these components to design a high performance IPT with novel ionomers. Equivalent circuit modeling of impedance data allowed for estimations of IPT capacitance due to changes in the compositions of the electrodes. Various methods for control of electrolyte uptake resulted in a range of ionic conductivity when combined with novel ionomers that vary in polymer backbone architecture and charge content. Although the ionic liquid was found to dominate the magnitude of the conductivity, the pathway for uptake was significant in determination of the overall maximum values. Combination of these optimized parameters for capacitance and ionic conductivity identified design criteria for potentially high performance IPTs to investigate the benefits of these novel ionomers in electroactive devices.
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Звіти організацій з теми "Ion Conducting Polymer Electrolytes"

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Arnold, John. Supramolecular Engineering of New Lithium Ion Conducting Polymer Electrolytes. Fort Belvoir, VA: Defense Technical Information Center, January 2001. http://dx.doi.org/10.21236/ada431777.

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Feld, William A., and Denise M. Weimers. Single Lithium Ion Conducting Polymer Electrolyte. Fort Belvoir, VA: Defense Technical Information Center, May 1998. http://dx.doi.org/10.21236/ada353668.

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Feld, William A. Aerospace Power Scholarly Research Program. Delivery Order 0007: Single Lithium Ion Conducting Polymer Electrolyte. Fort Belvoir, VA: Defense Technical Information Center, December 2005. http://dx.doi.org/10.21236/ada444661.

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Pintauro, Peter. High-Performance Li-Ion Battery Anodes from Electrospun Nanoparticle/Conducting Polymer Nanofibers. Office of Scientific and Technical Information (OSTI), March 2020. http://dx.doi.org/10.2172/1603318.

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Shriver, D. F., and M. A. Ratner. Mixed ionic-electronic conduction and percolation in polymer electrolyte metal oxide composites. Final report. Office of Scientific and Technical Information (OSTI), June 1997. http://dx.doi.org/10.2172/491618.

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Greenbaum, Steven G. Lithium Ion Transport Across and Between Phase Boundaries in Heterogeneous Polymer Electrolytes, Based on PVdF. Fort Belvoir, VA: Defense Technical Information Center, February 1998. http://dx.doi.org/10.21236/ada344887.

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