Дисертації з теми "Interface conductivity"
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Karayacoubian, Paul. "Effective Thermal Conductivity of Composite Fluidic Thermal Interface Materials." Thesis, University of Waterloo, 2006. http://hdl.handle.net/10012/2881.
Повний текст джерелаThe following study presents the application of two simple theorems for establishing bounds on the effective thermal conductivity of such inhomogeneous media. These theorems are applied to the development of models which are the geometric means of the upper and lower bounds for effective thermal conductivity of base fluids into which are suspended particles of various geometries.
Numerical work indicates that the models show generally good agreement for the various geometric dispersions, in particular for particles with low to moderate aspect ratios. The numerical results approach the lower bound as the conductivity ratio is increased. An important observation is that orienting the particles in the direction of heat flow leads to substantial enhancment in the thermal conductivity of the base fluid. Clustering leads to a small enhancement in effective thermal conductivity beyond that which is predicted for systems composed of regular arrays of particles. Although significant enhancement is possible if the clusters are large, in reality, clustering to the extent that solid agglomerates span large distances is unlikely since such clusters would settle out of the fluid.
In addition, experimental work available in the literature indicates that the agreement between the selected experimental data and the geometric mean of the upper and lower bounds for a sphere in a unit cell are in excellent agreement, even for particles which are irregular in shape.
Russell, Carissa Don. "INTERFACIAL THERMAL CONDUCTIVITY USING MULTIWALL CARBON NANOTUBES." UKnowledge, 2010. http://uknowledge.uky.edu/gradschool_theses/30.
Повний текст джерелаCarvallo, Pecci Andrés Nicolás. "Modèle biophysique pour la mesure de la conductivité cérébrale et apport diagnostique." Thesis, Rennes 1, 2018. http://www.theses.fr/2018REN1S039/document.
Повний текст джерелаWe aimed at providing an accurate estimation of human brain tissue electrical conductivity in clinico, using local, low-intensity pulsed stimulation. Methods: Using the quasi-static approximation of Maxwell equations, we derived an analytical model of the electric field generated by intracerebral stereotactic-EEG (SEEG) electrodes. We coupled this electric field model with a model of the electrode-electrolyte interface to provide an explicit, analytical expression of brain tissue conductivity based on the recorded brain tissue response to pulse stimulation. Results: We validated our biophysical model using: i) saline solutions calibrated in electrical conductivity, ii) rat brain tissue, and iii) electrophysiological data recorded in clinico from two epileptic patients during SEEG. Conclusion: This new model-based method offers a fast and reliable estimation of brain tissue electrical conductivity by accounting for contributions from the electrode-electrolyte interface. Significance: This method outperforms standard bioimpedance measurements since it provides absolute (as opposed to relative) changes in brain tissue conductivity. Application for diagnosis is envisioned since conductivity values strongly differ when estimated in the healthy vs. hyperexcitable brain tissue
Plattier-Boné, Julien. "Structuration des charges dans des mélanges de polymères immiscibles." Phd thesis, Université du Maine, 2013. http://tel.archives-ouvertes.fr/tel-00839195.
Повний текст джерелаRaghavan, Vasudevan. "Effect of Interface, Density and Height of Carbon Nanotube Arrays on Their Thermal Conductivity: An Experimental Study." University of Cincinnati / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1289236348.
Повний текст джерелаMustapha, Lateef Abimbola, and Lateef Abimbola Mustapha. "Thermo-Mechanical Characterization and Interfacial Thermal Resistance Studies of Chemically Modified Carbon Nanotube Thermal Interface Material - Experimental and Mechanistic Approaches." Diss., The University of Arizona, 2017. http://hdl.handle.net/10150/625379.
Повний текст джерелаLe, Poul Nicolas. "Charge transfer at the high-temperature superconductor/liquid electrolyte interface." Thesis, University of Exeter, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.391279.
Повний текст джерелаAdhikari, Amit. "Polymer Matrix Composite: Thermally Conductive GreasesPreparation and Characterization." University of Akron / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=akron1556282222035491.
Повний текст джерелаVasquez, Cristal Jeanette. "Oxide-coated vertically aligned carbon nanotube forests as thermal interface materials." Thesis, Georgia Institute of Technology, 2014. http://hdl.handle.net/1853/52237.
Повний текст джерелаCarrillo-Avila, Eugenio. "Modélisation des transferts hydriques dans le système sol-plante-atmosphère : application à la plaine de la Bièvre (Isère)." Université Joseph Fourier (Grenoble), 1995. http://www.theses.fr/1995GRE10026.
Повний текст джерелаMartin, Joshua. "Methods of thermoelectric enhancement in silicon-germanium alloy type I clathrates and in nanostructured lead chalcogenides." [Tampa, Fla] : University of South Florida, 2008. http://purl.fcla.edu/usf/dc/et/SFE0002448.
Повний текст джерелаSellak, Radouane. "Elaboration et caractérisation d'une résine thermodurcissable conductrice." Phd thesis, Université du Maine, 2013. http://tel.archives-ouvertes.fr/tel-00949522.
Повний текст джерелаJeancolas, Antoine. "Étude expérimentale et modélisation micromécanique du comportement de composites hybrides : optimisation de la conductivité thermique." Thesis, Université de Lorraine, 2018. http://www.theses.fr/2018LORR0285/document.
Повний текст джерелаThe increase of electronic components in the integrated circuits and the required electrical power set the question of the dissipation of the heat generated. The electrical box must favor the heat dissipation while maintaining electrical insulation. The solution chosen to transfer the heat is to develop composite materials whose reinforcements by their structure will improve the thermal conductivity. Polymer-based composite materials were chosen for their building ability. Thermal conductivity and electrical insulation are insured by ceramic reinforcements. The homogenization methods allow to improve the composites’ design according to the properties of their constituents, their geometry and their distribution. They thus provide an optimized formulation of materials satisfying the characteristics emanating from the industrial partner (‘Institut de Soudure’). The expected thermal conductivity of the composites imposes a high volume fraction of reinforcements to counterbalance the insulating polymer matrix. Homogenization methods have been developed to provide predictions of effective thermal conductivity for high (greater than 20%) reinforcement rates and high thermal conductivity contrasts. The presence of an interphase resulting from strong physico-chemical incompatibilities between the components must also be modeled
Messaadi, Saci. "Modélisation électrique de couches ou de fils minces métalliques : Effet thermique d'interface verre-couche amorphe." Nancy 1, 1987. http://www.theses.fr/1987NAN10048.
Повний текст джерелаZacarias, Domingues Fernandes Rosana. "Propriétés électriques et électrochimiques de zircones fortement dopées et étude de jonctions ioniques." Grenoble INPG, 1988. http://www.theses.fr/1988INPG0072.
Повний текст джерелаShukla, Nitin. "Heat Transport across Dissimilar Materials." Diss., Virginia Tech, 2009. http://hdl.handle.net/10919/27820.
Повний текст джерелаPh. D.
Dudda, Bruna. "Surface and interface states investigated in Si based thin films for photovoltaic applications." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2017. http://amslaurea.unibo.it/13656/.
Повний текст джерелаHamrat, Sonia. "Etude des échanges thermiques et conception d’un système de refroidissement pour le système de lecture du trajectographe SciFi de LHCb." Thesis, Université Clermont Auvergne (2017-2020), 2017. http://www.theses.fr/2017CLFAC104/document.
Повний текст джерелаIn the context of the evolution of the biggest circular accelerator of particles «LHC», an important program of upgrade on all the detectors which establishes itself was thrown. Among them, we find the upgrade of the detector LHCb which includes the complete replacement of several sub-detectors. The frequency of high reading of 40MHz, an unprecedented in an experiment of physical appearance of particles, and the environment of severe radiation bound to the increase of the intensity of the LHC, are the main challenges by the new sub-detectors. The work presented in this manuscript, described as a small part of the evolution of the LHCb detector. The development and the construction of a new wide-scale tracker, based on a new technology with scintillating fiber «SciFi», read with photomultipliers to the silicon «SiPM», is one of the key projects of the LHCb upgrade program. The first part, consists in studying the thermal exchanges and designing a cooling system for every Read-Out Box «ROB» which contains two electronic front-end « FE », and which allow to read the data of the detector. The latter has a thermal dissipation about 110W. To ensure the smooth running of electronic components, it is compulsory to set up a cooler. Important constraints are taken into account in this study, the first one represents the space limited compared to the need for the cooling system, the electronic interfaces and mechanical, the second concerns the SiPM. Connected with the electronics by flexible cables, they are located near the electronics «FE» and their temperature of operation is perfectly settled around -40 ° C. Works of digital simulations on the software FloTHERM and ANSYS were led on the experimental bench realized within the laboratory, and which allowed us to determine the best adapted solution of cooling. This study also showed to us that he is more than necessity to integrate thermal interfaces «IT» such as thermal pastas to assure a better transfer of heat between electronic components and cooler. The second part, represents an in-depth study on the thermal interfaces which are a delicate point of transfer of heat, because they can have dozens percent of the global thermal resistance. To guarantee an adequate and sustainable use of these materials, several parameters were verified, in particular hardness, consistency (no production of fat or oil) and the thermal conductivity, thanks to a bench of measures adapted according to the method normalized ASTM D5470, with this bench we could measure the flow of heat through the tested thermal interface sample and which is generated by a hot source and a cold source that are mounted at the ends of our bench.With the installation CHARME (CERN) and PAVIRMA (Cézeaux), a series of measure of irradiations at the neutrons and the X-rays are also made, correspond-ing to the environment in which they will be exposed in the experience, on one side to identify the damages and the possible changes on the thermal resistances by the analysis of the thermal impedance, the other one to identify the thermal interface which suits best our application and which allows to assure an excellent thermal exchange and thus a good cooling of the frontal electronics within the trajectographe of the detector LHCb
Lincot, Daniel. "Contribution à l'étude des phénomènes de surface en électrochimie des semiconducteurs : l'interface tellurure de cadmium / électrolyte aqueux." Paris 6, 1986. http://www.theses.fr/1986PA066269.
Повний текст джерелаYao, N'guessan Alfred. "Contribution a l'etude des jonctions gaas-electrolyte aqueux et non aqueux : formation de l'interface et cinetique de transfert de charges." Paris 7, 1987. http://www.theses.fr/1987PA077174.
Повний текст джерелаGuillet, Stéphane. "Etude des propriétés électroniques des interfaces Ag/Si(100) et Cu/Si(100)." Grenoble 1, 1993. http://www.theses.fr/1993GRE10065.
Повний текст джерелаOusten, Jean-Pierre. "Etude du comportement au vieillissement des interfaces thermiques pour modules électroniques de puissance dédiés à des applications transports." Phd thesis, École normale supérieure de Cachan - ENS Cachan, 2013. http://tel.archives-ouvertes.fr/tel-00910948.
Повний текст джерелаGupta, Mohit Kumar. "Design of Thermal Barrier Coatings : A modelling approach." Doctoral thesis, Högskolan Väst, Avd för maskinteknik, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:hv:diva-7181.
Повний текст джерелаAfsari, Mamaghani Sepideh. "The Formation of Two Dimensional Supramolecular Structures and Their Use in Studying Charge Transport at the Single Molecule Level at the Liquid-Solid Interface." Diss., Temple University Libraries, 2015. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/350915.
Повний текст джерелаPh.D.
Understanding charge transport through molecular junctions and factors affecting the conductivity at the single molecule level is the first step in designing functional electronic devices using individual molecules. A variety of methods have been developed to fabricate metal-molecule-metal junctions in order to evaluate Single Molecule Conductance (SMC). Single molecule junctions usually are formed by wiring a molecule between two metal electrodes via anchoring groups that provide efficient electronic coupling and bind the organic molecular backbone to the metal electrodes. We demonstrated a novel strategy to fabricate single molecule junctions by employing the stabilization provided by the long range ordered structure of the molecules on the surface. The templates formed by the ordered molecular adlayer immobilize the molecule on the electrode surface and facilitate conductance measurements of single molecule junctions with controlled molecular orientation. This strategy enables the construction of orientation-controlled single molecule junctions, with molecules lacking proper anchoring groups that cannot be formed via conventional SMC methods. Utilizing Scanning Tunneling Microscopy (STM) imaging and STM break junction (STM-BJ) techniques combined, we employed the molecular assembly of mesitylene to create highly conductive molecular junctions with controlled orientation of benzene ring perpendicular to the STM tip as the electrode. The long range ordered structure of mesitylene molecules imaged using STM, supports the hypothesis that mesitylene is initially adsorbed on the Au(111) with the benzene ring lying flat on the surface and perpendicular to the Au tip. Thus, long range ordered structure of mesitylene facilitates formation of Au-π-Au junctions. Mesitylene molecules do not have standard anchoring groups providing enough contact to the gold electrode and the only assumable geometry for the molecules in the junction is via direct contact between Au and the π system of the benzene ring in mesitylene. SMC measurements for Au/mesitylene/Au junctions results in a molecular conductance value around 0.125Go, two orders of magnitude higher than the measured conductance of a benzene ring connected via anchoring groups. We attributed this conductance peak to charge transport perpendicular to the benzene ring due to direct coupling between the π system and the gold electrode that happens in planar orientation. The conductance we measured for planar orientation of benzene ring is two order of magnitude larger than conductance of junctions formed with benzene derivatives with conventional linkers. Thus, altering the orientation of a single benzene-containing molecule between the two electrodes from planar orientation to the upright attached via the linkers, results in altering the conductivity in a large order. Based on these findings, by utilizing STM imaging and STM-BJ in an electrochemical environment including potential induced self-assembly formation of terephthalic acid, we designed an electrochemical single molecule switch. Terephthalic acid forms large domains of ordered structure on negatively charged Au(111) surface under negative electrochemical surface potentials with the benzene ring lying flat on the surface due to hydrogen bonding between carboxylic acid groups of neighboring molecules. Formation of long range ordered structure facilitates direct contact between the π system of the benzene ring and the gold electrodes resulting in the conductance peak. On positively charged Au(111), deprotonation of carboxylic acid groups leads to absence of long range ordered structure of molecules with planar orientation and absence of the conductance peak. In this case alternating the surface (electrode) potential from negative to positive charge densities induces a transition in the adlayer structure on the surface and switches conductance value. Hence, electrochemical surface potential can, in principle, be employed as an external stimulus to switch single molecule arrangement on the surface and the conductance in the junction. The observation of conductance switching due to molecule’s arrangement in the junction lead to the hypothesis that for any benzene derivative, an orientation-dependent conductance in the junction due to the contact geometry (i.e. electrode-anchoring groups versus direct electrode-π contact) should be expected. Conventional techniques in fabricating single molecule junctions enable accessing charge transport along only one direction, i.e., between two anchoring groups. However, molecules such as benzene derivatives are anisotropic objects and we are able to measure an orientation-dependent conductance. In order to systematically study anisotropic conductivity at single molecule level, we need to measure the conductance in different and well-controlled orientations of single molecules in the junction. We employed the same EC-STM-BJ set up for SMC measurements and utilize electrochemical potential of the substrate (electrode) as the tuning source to variate the orientation of the single molecule in the junction. We investigated single molecule conductance of the benzene rings with carboxylic acid functional groups in two orientations: one with the benzene ring bridging between two electrodes using carboxylic acids as anchoring groups (upright); and one with the molecule lying flat on the substrate perpendicular to the STM tip (planar). Physisorption of these species on the Au (111) single crystal electrode surface at negative electrochemical potentials results in an ordered structure with the benzene ring in a planar orientation. Positive electrochemical potentials cause formation of the ordered structure with molecules standing upright due to coordination of a deprotonated carboxyl groups to the electrode surface. Thus, formation of the single molecule junction and consequently conductivity measurements is facilitated in two directions for the same molecule and anisotropic conductivity can be studied. In engineering well-ordered two-dimensional (2-D) molecular structures with controlled assembly of molecular species, pH can be employed as another tuning source for the molecular structures and adsorption in experiments conducted in aqueous solutions. Based on simple chemical principles, amine (NH2) groups are hydrogen bond acceptors and donors. Amines are soluble in water and protonation results in protonated (NH3+) and unprotonated (NH2) amine groups in acidic and moderately acidic/neutral solutions, respectively. Thus, amines are suitable molecular building blocks for fabricating 2-D supramolecular structures where pH is employed as a knob to manipulate intermolecular hydrogen bonding leading to phase transitions. We investigated pH induced structural changes in the 1,3,5–triaminobenzene (TAB) monolayer and the formation/disruption of hydrogen bonds between neighboring molecules. Our STM images indicate that in the concentrated acidic solution, the protonated amine groups of TAB are not able to form H-bonds and long range ordered structure of TAB does not form on the Au(111) surface. However, in moderately acidic solution (pH ~ 5.5) at room temperature, protonation on the ring carbon atom generates species capable of forming H-bonds leading to the formation of the long range ordered structures of TAB molecules. Utilizing EC-STM set up, we investigated the controllable fabrication of a TAB 2-D supramolecular structure based on amine-amine hydrogen bonding and effect of pH in formation of ordered/disordered TAB network.
Temple University--Theses
Bouhki, Mohamed. "Amorphisation par réaction à l'état solide dans les multicouches NI/TI." Nancy 1, 1993. http://www.theses.fr/1993NAN10005.
Повний текст джерелаZhang, Rongwei. "Novel conductive adhesives for electronic packaging applications: a way towards economical, highly conductive, low temperature and flexible interconnects." Diss., Georgia Institute of Technology, 2011. http://hdl.handle.net/1853/39548.
Повний текст джерелаChen, Peixuan. "Thermal transport through SiGe superlattices." Doctoral thesis, Universitätsbibliothek Chemnitz, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-159170.
Повний текст джерелаVerständnis des thermischen Transport auf Nanoskala ist sowohl grundlegend für die Entwicklung nanostrukturierter Materialien, als auch für Temperaturkontrolle in nanoelektronischen Bauteilen. Diese Dissertation widmet sich der Erforschung des thermischen Transports durch SiGe basierenden Übergittern. Variationen, der Si(Ge) Schichtdicken, wurden zur systematischen Untersuchung der Normalkomponente zur Wachstumsrichtung der Wärmeleitfähigkeit, von SiGe Übergittern, genutzt. Die Beobachtung des additiven Charakters, des thermischen Widerstands, der SiGe Schichten, mit oder ohne Inselwachstum, ermöglicht die Erstellung von Strukturen mit bestimmter Wärmeleitfähigkeiten durch die Variation der Schichtdicken bis zu einer Minimaldistanz zweier Schichtübergänge von ~1.5nm. Die Ge Segregation führt zu einer Vermischung, von Si und Ge, welche eine essentielle Rolle zur diffusen Phononenstreuung spielt. Unsere Untersuchungen, von planaren Übergittern und Übergittern mit variabler Inseldichte, zeigen, dass Inseln und planare Schichten zu einer vergleichbaren Reduktion, der Wärmeleitfähigkeit, führen. Diese Beobachtung lässt sich, sowohl auf die flache Morphologie als auch die Abplattung der SiGe Inseln, aufgrund der Überwachsung mit Si, zurückführen. Die Experimente zeigen außerdem, dass sich der Barriereneffekt, der Schichtgrenzen, durch Reduktion der Schichtabstände und durch verstärkte Vermischung im Bereich der Schichtgrenzen, durch Erhitzung, eliminieren lässt. Die präsentierten Messungen sind sowohl, für die Entwicklung jener Bauteile, die eine Optimierung des thermischen Transports oder Temperaturmanagment erfordern, als auch von thermoelektrischen Matieralien und Bauteilen, basierend auf Übergittern, relevant
Yao, Yulong. "THERMAL CONDUCTIVITIES OF ORGANIC SEMICONDUCTORS." UKnowledge, 2017. http://uknowledge.uky.edu/physastron_etds/48.
Повний текст джерелаTyagi, Sidhanth. "Objects interacting with a solidification front." Electronic Thesis or Diss., Université Paris sciences et lettres, 2020. http://www.theses.fr/2020UPSLS025.
Повний текст джерелаThe interaction of solidification fronts with objects (droplets, bubbles, particles, or biological cells) is a common phenomenon encountered in a plethora of situations, ranging from industrial to natural occurrences, such as the formation ofsea ice, growth of single crystals, metallurgy, cryobiology, food science, and filtration or water purification. The process,though well-known, is complex and an unambiguous quantification of the mechanisms in situ is yet to be developed. Theobjects (soft or hard) can have diverse outcomes owing to their confrontation with an advancing solid-liquid interface. Thefront can engulf the object, trapping it into the growing crystal, or the front can repel the object, pushing it ahead of itself.The consequences of this interaction impacts the final microstructure and hence, determines the structural as well asfunctional properties of the solidified material. Furthermore, many of these phenomena occur in the presence of solutes(or impurities), which can segregate at the interface during the growth of a solid. In this study, we analyse the interactionof spherical soft objects (droplets and bubbles) and rigid particles with an approaching ice-water interface. Our customcryo-confocal microscopy setup enables a rapid imaging of the growth of ice crystals, the liquid phase, and the dynamicsof objects encountering the solidification front. We depict the impact of solute (or impurity) concentration and their influence on the interface geometry, object dynamics, and the solidified microstructure. We explore several important aspectsof multiple particle interactions in realistic systems and discuss the consequences of particle redistribution in comparisonto the ideal systems considered by the past physical models. Our results demonstrate how an increasing concentration ofsolute in the bulk liquid and their subsequent segregation can dramatically alter the predicted nature of object-front interactions and the solidification microstructures. We suggest that the freezing of suspensions using cryo-confocal microscopymay serve as an analogue for studying the in situ interaction of foreign objects with a moving solid-liquid interface
Allongue, Philippe. "Etude de l'interface gaas/electrolyte : apport des mesures de photocapacite et des modifications de surface par depot electrolytique de metaux." Paris 6, 1988. http://www.theses.fr/1988PA066017.
Повний текст джерелаKadiroglu, Umut. "Polymer electrolyte/electrode interfaces." Thesis, University of Southampton, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302347.
Повний текст джерелаChen, Peixuan. "Thermal transport through SiGe superlattices." Doctoral thesis, Universitätsverlag der Technischen Universität Chemnitz, 2014. https://monarch.qucosa.de/id/qucosa%3A20177.
Повний текст джерелаVerständnis des thermischen Transport auf Nanoskala ist sowohl grundlegend für die Entwicklung nanostrukturierter Materialien, als auch für Temperaturkontrolle in nanoelektronischen Bauteilen. Diese Dissertation widmet sich der Erforschung des thermischen Transports durch SiGe basierenden Übergittern. Variationen, der Si(Ge) Schichtdicken, wurden zur systematischen Untersuchung der Normalkomponente zur Wachstumsrichtung der Wärmeleitfähigkeit, von SiGe Übergittern, genutzt. Die Beobachtung des additiven Charakters, des thermischen Widerstands, der SiGe Schichten, mit oder ohne Inselwachstum, ermöglicht die Erstellung von Strukturen mit bestimmter Wärmeleitfähigkeiten durch die Variation der Schichtdicken bis zu einer Minimaldistanz zweier Schichtübergänge von ~1.5nm. Die Ge Segregation führt zu einer Vermischung, von Si und Ge, welche eine essentielle Rolle zur diffusen Phononenstreuung spielt. Unsere Untersuchungen, von planaren Übergittern und Übergittern mit variabler Inseldichte, zeigen, dass Inseln und planare Schichten zu einer vergleichbaren Reduktion, der Wärmeleitfähigkeit, führen. Diese Beobachtung lässt sich, sowohl auf die flache Morphologie als auch die Abplattung der SiGe Inseln, aufgrund der Überwachsung mit Si, zurückführen. Die Experimente zeigen außerdem, dass sich der Barriereneffekt, der Schichtgrenzen, durch Reduktion der Schichtabstände und durch verstärkte Vermischung im Bereich der Schichtgrenzen, durch Erhitzung, eliminieren lässt. Die präsentierten Messungen sind sowohl, für die Entwicklung jener Bauteile, die eine Optimierung des thermischen Transports oder Temperaturmanagment erfordern, als auch von thermoelektrischen Matieralien und Bauteilen, basierend auf Übergittern, relevant.
Wang, Yifeng, Kyu Hyoung Lee, Hiromichi Ohta, and Kunihito Koumoto. "Thermoelectric properties of electron doped SrO(SrTiO3)n (n=1,2) ceramics." American Institite of Physics, 2009. http://hdl.handle.net/2237/12629.
Повний текст джерелаOuellette, Daniel Gerald. "Dynamical conductivity of strongly correlated electron systems at oxide interfaces." Thesis, University of California, Santa Barbara, 2014. http://pqdtopen.proquest.com/#viewpdf?dispub=3602181.
Повний текст джерелаThe Mott metal-insulator transition (MIT) in transition-metal complex oxides results from strong electron-electron interactions and is accompanied by a rich spectrum of phenomena, including magnetic, charge, and orbital ordering, superconductivity, structural distortions, polarons, and very high-density 2-dimensional interface electron liquids. Recent advances in oxide heteroepitaxy allow interface control as a promising new approach to tuning the exotic properties of materials near the quantum critical point, with potential application to technologies including phase-change electronics, high power transistors, and sensors. The dynamical conductivity of oxide heterostructures is measured using a combination of terahertz time-domain spectroscopy, Fourier transform infrared spectroscopy, and dc magnetotransport. The rare-earth nickelates RNiO3 (R = La, Nd...) exhibit a temperature and bandwidth controlled MIT in bulk. Measurements of the Drude response in epitaxial thin films provide quantification of the strain-dependent mass enhancement in the metallic phase due to strong correlations. Reduction of LaNiO 3 film thickness leads to additional mass renormalization attributed to structural distortions at the heteroepitaxial interface, and an MIT is observed depending on the interfacing materials in coherent perovskite heterostructures. The rare-earth titanates RTiO3 exhibit a bandwidth and band filling controlled Mott MIT. Furthermore, the heterointerface between Mott insulating GdTiO3 and band insulating SrTiO3 exhibits a 2-dimensional itinerant electron liquid, with extremely high sheet densities of 3 × 1014 cm-2. The dynamical conductivity of the interface electrons is analyzed in terms of subband-dependent electron mobility and the established large polaron dynamics in bulk SrTiO3. Additional confinement of the electron liquids is achieved by decreasing the SrTiO3 layer thickness, with attendant increase in the dynamical mass. Taking the confinement to its extreme limit, a single (GdO) + plane in Mott insulating GdTiO3 is replaced with a (SrO) 0 plane. This is equivalent to "delta-doping" the Mott insulator with an extremely high density sheet of holes. The transport and absorption in the resulting two-dimensional insulator are consistent with a simple model of small polaron hopping. A comparison is made to similar features in the conductivity of randomly doped Sr1-xGdxTiO3 films.
Theys, Bertrand. "Photoelectrochimie du seleniure d'indium." Paris 7, 1987. http://www.theses.fr/1987PA077165.
Повний текст джерелаKlittich, Mena R. "Surface Interactions with Hierarchical Nanostructures: From Gecko Adhesion to Thermal Behavior." University of Akron / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=akron1499440265902425.
Повний текст джерелаGamon, Jacinthe. "Dopage et interfaces optimisés de semiconducteurs : étude de deux systèmes complémentaires BiCuOS et ZnO." Thesis, Paris 6, 2017. http://www.theses.fr/2017PA066164.
Повний текст джерелаThe emerging domain of printed electronics requires new cheap and non-toxic materials for applications such as logic devices, sensors, displays, thermoelectric and photovoltaic devices. It also requires optimizing the conduction in granular semiconductors. BiCuOS has been identified as a promising p-type semiconductor for such applications. However, its high copper under-stoichiometry, induces an important p-type doping, which is detrimental for its use as a photovoltaic absorber. Moreover, like all chalcogenide based materials, it shows a poor chemical stability during sintering, thermal treatment necessary to enhance transport properties. In order to optimize its properties, solutions must be found i) to control the doping content, ii) to obtain good charge carrier mobilities in thin films. On the one hand, we have explored different kinds of substitutions such as iodine for sulfur or silver for copper, which successfully enabled to strongly reduce the charge carrier density. On the other hand, we have studied the effect of grafting conjugated molecules (terephthalic acid and polythiophene derivatives) onto the surface of a model n-type semiconductor (ZnO) to study their effect on the intergranular transport. Electronic transfer improvement occurs by transfer though a lowered energy barrier formed by the LUMO of the molecules. The formulation of optimized inks using these molecules as additives allowed the thin film deposition of p-n diodes formed with ZnO/BiCuOS. Although no photovoltaic effect has been detected yet, the p-n junctions showed high nonlinear properties and are strongly photosensitive. With this work, we have participated to the elaboration of new sulfides and hybrid interfaces systems for the improvement of semiconductor devices. The development of such hybrid electronic devices through soft chemistry method is a valuable step towards the commercialization of sustainable technologies
Batkam, Hemo Serge. "Thermique multidomaines en simulation numérique du remplissage 3D." Paris, ENMP, 2002. http://www.theses.fr/2002ENMP0001.
Повний текст джерелаSolving the thermal problem is a key point for the numerical simulation of injection molding. The main causes of the numerical difficulties encountered by classical Galerkin techniques are the specific characters of molten polymers: high energy dissipation, low thermal conductivity, thermal shocks at the mold wall, thermal dependence of rheology. In this contribution, we have developed a space-time finite element method to solve the heat equation. A discontinuous Galerkin technique using P0/P0+ elements is proposed for the steady problem. The transient problem is treated with a discontinuous high order finite element in time method. The so-built scheme is local and easy to implement. It reveals good properties of stability, robustness and speed. Its appears to be efficient both for convection dominant and diffusion dominant equations, and is therefore suitable for injection molding process. Another difficulty when modelling the thermal exchanges in the polymer is to define accurate boundary conditions at the cavity frontier. We have investigated a numerical scheme which allows to couple the computations in the polymer with thermal computations in domains surrounding the cavity (multidomain approach). This scheme does not require coincident meshes between the domains. A specific processing at the interfaces guarantees natural thermal exchanges between two domains in contact, with no regard of any particular heat exchange coefficient specified at the interface. All the proposed methods have been validated through analytic examples, then integrated to the thermal solver of REM3D® software. Several examples of complex 3D mold filling, including thermomechanical coupling in the cavity, and possibly thermal coupling in the mold or in inserts (overmolding injection process) are given
Alaili, Kamal. "Transport de chaleur dans les nano-couches minces excitées par une source laser d'intensité modulée." Thesis, Poitiers, 2019. http://www.theses.fr/2019POIT2314.
Повний текст джерелаThis work, separated into two main parts, deals with the study of heat transport in nano-layers excited by a laser beam with modulated intensity. In the first part, we exploit the analytical solution of the phonon Boltzmann transport equation to describe the variations of temperature and heat flux in thin dielectric films excited by a laser beam of modulated intensity. This last solution allows us to model the behavior of the interface thermal resistance (ITR) between two dielectric layers according to the nature of the phonon transport regime and the modulation frequency. In the steady state regime, we show that this interface resistance has a non-intrinsic and asymmetric character with regard to the two layers properties. In addition, it becomes very important when the phonon transport regime is ballistic. Our results are in good agreement with the DMM in the ballistic regime, while they differ by about 16% in the diffusive regime. However, in the dynamical regime, we mainly show that in the diffusive regime, the ITR reaches a maximum at a characteristic modulation frequency. The expression of this characteristic frequency can thus be used to determine the dominant phonons mean free path and relaxation time through the comparison of the theoretical model and the experimental data. In the second part, we propose three different ways to extract simultaneously the thermal diffusivity and conductivity of a finite layer based on the Fourier heat equation. The idea is to use the exact expression of the temperature profile at the front surface of the thin layer when the latter is excited by a periodic heat flux, while the rear surface can be maintained at one of three different types of boundary conditions: modulated periodic heat flux, modulated temperature, or constant temperature. We determine the expressions of the modulation frequencies at which the front surface temperature reaches its first maximum and first minimum. The combination of these characteristic frequencies with the ratio between the first maximum and the first minimum of the temperature, thus leads to the determination of the diffusivity and thermal conductivity
Verdier, Maxime. "Effet de l’orientation et de l’état des surfaces/interfaces sur les propriétés thermiques des semi-conducteurs nano-structurés." Thesis, Université de Lorraine, 2018. http://www.theses.fr/2018LORR0138/document.
Повний текст джерелаThis study deals with heat transport in crystalline nanostructured silicon and the impact of amorphization. The thermal conductivity of various nanostructures is computed with two numerical methods: Molecular Dynamics and Monte Carlo resolution of the Boltzmann transport equation. First, materials with spherical nanopores are investigated and the importance of the surface density is highlighted. Then, nanofilms with periodic cylindrical pores, often called phononic crystals, are studied. The density of states computed with Molecular Dynamics does not show major modifications of the heat carriers (phonons) properties. However, results show that the surfaces orientation, the pore distribution and the existence of native oxide or amorphous layers may have an important impact on the thermal conductivity. Then, heat transport in nanowires is studied, in particular the radial evolution of the thermal conductivity. The latter one is maximum at the center of the nanowire and decreases when approaching the nanowire surface. Structures made from interconnected nanowires, called nanowire networks, are also studied; they have an extremely low thermal conductivity. Finally, the impact of the roughness and amorphization of the surfaces on thermal transport is analyzed for different types of nanostructures. The two latter phenomena contribute strongly to the reduction of the thermal conductivity, which can reach very low values while keeping an important crystalline fraction.It opens new perspectives for the control of this property with material designing
Gabouze, Noureddine. "Etude photoelectrochimique de gaas(n) et si(n) en milieu non aqueux ch::(3)oh et ch::(3)cn : etude et realisation de cellules photoelectrochimiques minces." Paris 6, 1988. http://www.theses.fr/1988PA066242.
Повний текст джерелаChauhan, Vinay Singh. "Impact of Nanoscale Defects on Thermal Transport in Materials." The Ohio State University, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=osu1586440154974469.
Повний текст джерелаStreb, Fabian. "Novel materials for heat dissipation in semiconductor technologies." Eigenverlag, 2018. https://monarch.qucosa.de/id/qucosa%3A23536.
Повний текст джерелаWärmemanagement ist eine große Herausforderung sowohl für aktuelle als auch für zukünftige Halbleiterprodukte. Speziell die nächste Produktgeneration mit SiC oder GaN Chips benötigen neue Entwärmungskonzepte, um ihr volles Potential bezüglich höherer Stromstärken zu entfalten. In dieser Arbeit wurden vier neuartige Konzepte erforscht: Diamant basierte Substrate, Phasen-Wechsel-Materialien, Cu-Graphene Kompositschichten und anisotrope Entwärmung. Es zeigte sich, dass anisotrope Entwärmung das vielversprechendste Konzept ist. Als Demonstrator wurde eine Bodenplatte mit thermisch pyrolytischen Graphiteinleger für ein Leistungsmodul gefertigt. Sie zeigt eine lokale Erhöhung der Entwärmung von 30 %. Weiter ist der thermische Kontakt zwischen Bauteil und Kühler sehr wichtig. Verschiedene Charakterisierungsmethoden für thermische Schnittstellen-Materialien wurden verglichen. Dieser Vergleich zeigt, dass eine Kombination verschiedener Methoden notwendig ist, um ein vollständiges Bild über die Leistungsfähigkeit solcher Materialien zu gewinnen. Eine neue Messmethode wurde entwickelt, um die thermische Kontakt-Leitfähigkeit zu messen. Diese neue Methode ermöglicht es, die beste Wärmeleitpaste für eine vorgegebene Kombination aus Produkt und Kühleroberfläche zu identifizieren.
Daniels-Hafer, Carrie Lynn. "Electrochemical tuning of charge transport at inorganic semiconductor doped conjugated polymer interfaces through manipulation of electrochemical potential /." view abstract or download file of text, 2004.
Знайти повний текст джерелаTypescript. Includes vita and abstract. Includes bibliographical references (leaves 185-196). Also available for download via the World Wide Web; free to University of Oregon users.
Glacet, Jean-Yves. "Proprietes electroniques des intefaces si : :(3)n::(4)/si et sin::(x)/gainas." Toulouse, INSA, 1986. http://www.theses.fr/1986ISAT0034.
Повний текст джерелаMartin, Justin J. "Construction of self-assembled inorganic interfaces as a method for tuning conducting polymer thin film sheet conductivity." Diss., Online access via UMI:, 2007.
Знайти повний текст джерелаDerouiche, Abdelouahed. "Contribution à l'étude des microémulsions comme agents de transfert : application au transport d'ions métalliques et mécanismes des transferts liquide-liquide." Nancy 1, 1990. http://www.theses.fr/1990NAN10427.
Повний текст джерелаGourba, Emmanuel. "Elaboration et caractérisation physicochimique et électrochimique de couches minces de YSZ et de CGO en vue de leur utilisation comme électrolyte des piles à combustible à oxyde solide." Paris 6, 2004. http://www.theses.fr/2004PA066138.
Повний текст джерелаSettembre, Antonio. "Failure analysis of HVDC cable joint interfaces." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2021. http://amslaurea.unibo.it/24677/.
Повний текст джерелаSahli, Salah. "Etude du comportement electrique de films minces de gaas amorphes ou polycristallins elabores par depots en phase vapeur ou par plasma a partir d'organometalliques." Toulouse 3, 1986. http://www.theses.fr/1986TOU30049.
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