Добірка наукової літератури з теми "Homolytic cleavage of diborons"
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Статті в журналах з теми "Homolytic cleavage of diborons"
Verma, Piyush Kumar, Naresh Kumar Meher, and K. Geetharani. "Homolytic cleavage of diboron(4) compounds using diazabutadiene derivatives." Chemical Communications 57, no. 64 (2021): 7886–89. http://dx.doi.org/10.1039/d1cc02881b.
Повний текст джерелаWang, Pengfei, Yuli Li, and Guangwei Wang. "Tetrahydroxydiboron-Initiated Atom-Transfer Radical Cyclization." Synthesis 53, no. 19 (April 19, 2021): 3555–63. http://dx.doi.org/10.1055/a-1485-4956.
Повний текст джерелаCao, Levy L., and Douglas W. Stephan. "Homolytic Cleavage Reactions of a Neutral Doubly Base Stabilized Diborane(4)." Organometallics 36, no. 16 (August 9, 2017): 3163–70. http://dx.doi.org/10.1021/acs.organomet.7b00522.
Повний текст джерелаWang, Jiaoyang, Wenrui Zheng, and Yuanyuan Zheng. "Theoretical study on homolytic B–B cleavages of diboron(4) compounds." RSC Adv. 7, no. 78 (2017): 49251–72. http://dx.doi.org/10.1039/c7ra09006d.
Повний текст джерелаTsurugi, Hayato, Kazushi Mashima, Luis C. Misal Castro, and Ibrahim Sultan. "Pyridine-Mediated B–B Bond Activation of (RO)2B–B(OR)2 for Generating Borylpyridine Anions and Pyridine-Stabilized Boryl Radicals as Useful Boryl Reagents in Organic Synthesis." Synthesis 53, no. 18 (April 20, 2021): 3211–26. http://dx.doi.org/10.1055/a-1486-8169.
Повний текст джерелаWeng, Zhiqiang, and Lai Yoong Goh. "Homolytic Cleavage and Aggregation Processes in Cyclopentadienylchromium Chemistry." Accounts of Chemical Research 37, no. 3 (March 2004): 187–99. http://dx.doi.org/10.1021/ar030003r.
Повний текст джерелаDing, Lanlan, Wenrui Zheng, and Yingxing Wang. "Homolytic C–O Cleavage in Phosphates and Sulfonates." Journal of Physical Chemistry A 119, no. 14 (March 27, 2015): 3488–99. http://dx.doi.org/10.1021/acs.jpca.5b00569.
Повний текст джерелаKampmeier, Jack A. "Regioselectivity in the Homolytic Cleavage of S-Adenosylmethionine." Biochemistry 49, no. 51 (December 28, 2010): 10770–72. http://dx.doi.org/10.1021/bi101509u.
Повний текст джерелаNome, Faruk, Marcos Caroli Rezende, Claudia Maria Sabóia, and Arlindo Clemente Da Silva. "Kinetics of the thermolysis of para-substituted benzylcobalamins and derivatives." Canadian Journal of Chemistry 65, no. 9 (September 1, 1987): 2095–99. http://dx.doi.org/10.1139/v87-347.
Повний текст джерелаBajaj, Ashima, Rishu Khurana, and Md Ehesan Ali. "Quantum interference and spin filtering effects in photo-responsive single molecule devices." Journal of Materials Chemistry C 9, no. 34 (2021): 11242–51. http://dx.doi.org/10.1039/d1tc02200h.
Повний текст джерелаДисертації з теми "Homolytic cleavage of diborons"
Verma, Piyush Kumar. "Cobalt-nhc Complexes and Diazabutadienes in Activation of Mono/Diboron Compounds and Their Application in C-b Coupling Reactions." Thesis, 2021. https://etd.iisc.ac.in/handle/2005/5241.
Повний текст джерелаWu, Yi-Wen, and 吳翌彣. "The Study of Electronic Structures of Five-coordinate Saddled Iron(III) Porphyrin Radical Cation and O-O Bond Homolytic Cleavage of (OETPP)FeIIIO(H)OtBu." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/n6af3q.
Повний текст джерела國立中興大學
化學系所
106
In this study, paramagnetic NMR spectroscopy, X-ray diffraction, magnetic susceptibility and DFT calculation are employed to elucidate the strong bonding interaction between iron(III) dx2-y2 and porphyrin a2u orbitals of [Fe(OMTPP∙)Cl]SbCl6 and [Fe(OETPP∙)Cl]SbCl6. Their crystal structures clearly indicate that their saddle deformations are increased compared to those prior to oxidations. Their 1H NMR data present the S = 2 states for such one-electron oxidation states, and demonstrate that their structures in solutions remain strong saddle deformations. In light of 1H NMR spectroscopy of [Fe(TPP∙)Cl]SbCl6 resembling to the above cases, we postulate that the ring structure of [Fe(TPP∙)Cl]+ may possess strongly saddle to have great bonding interaction between iron(III) dx2-y2 and porphyrin a2u orbitals. In the DFT calculations, the degrees of phenyl ring rotation and saddled deformation will also affect their NMR spectra. In another topic, we observe O-O bond homolytic cleavage of (OETPP)FeIIIO(H)OtBu formed in the reaction of Fe(OETPP)ClO4 with TBHP and its activation parameters (ΔH≠ = 47(2) kJ mol-1, ΔS≠ = 83(9)J mol-1K-1) is measured by low-temperature UV-vis spectral data. The corresponding one-electron oxidation product is identified as [Fe(OETPP∙)OH]+, which is an isoelectronic structure as oxoiron(IV) porphyrin, by UV-vis, NMR spectroscopy and ESI-MS spectrometry. According to the experiments of NMR and ESI-MS, we also find that ·OtBu radical will convert Fe(OETPP)ClO4 to [Fe(OETPP∙)OtBu]+. Furthermore, these related iron(III) porphyrin radical cations can be carried out one more electron oxidation to isoporphyrins, an isoelectronic structure as Compound I. These iron(III) saddled isoporphyrins are shown to be reactive for highly selective chlorination of cyclohexene.
Mala, Deep. "Chemistry of Ru(II) Complexes Bearing N-heterocyclic Carbene, Hydride, and Dihydrogen Ligands : Synthesis, Mechanistic Insights, and Applications." Thesis, 2016. http://etd.iisc.ac.in/handle/2005/4162.
Повний текст джерелаЧастини книг з теми "Homolytic cleavage of diborons"
James, B. R., and M. T. Ashby. "Homolytic Cleavage to Give Metal-Hydrides." In Inorganic Reactions and Methods, 66–71. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch29.
Повний текст джерелаKühn, F. E., C. C. Romäo, and W. A. Herrmann. "Homolytic Cleavage." In Compounds of Groups 7-3 (Mn..., Cr..., V..., Ti..., Sc..., La..., Ac...), 1. Georg Thieme Verlag KG, 2003. http://dx.doi.org/10.1055/sos-sd-002-00209.
Повний текст джерела"Oxidative Degradation." In Organic Chemistry of Drug Degradation, 48–109. The Royal Society of Chemistry, 2012. http://dx.doi.org/10.1039/bk9781849734219-00048.
Повний текст джерела"S-Adenosyl Methionine: One Electron and Two Electron Reaction Manifolds in Biosyntheses." In Natural Product Biosynthesis: Chemical Logic and Enzymatic Machinery, 524–68. The Royal Society of Chemistry, 2017. http://dx.doi.org/10.1039/bk9781788010764-00524.
Повний текст джерела"Energy of a Homolytic Cleavage of Communication OH in Replaced 2,6-di-tert.Butylphenols." In Chemistry and Physics of Complex Materials, 225–34. Apple Academic Press, 2013. http://dx.doi.org/10.1201/b16302-13.
Повний текст джерела"Carbon-based Radicals in C–C Bond Formations in Natural Products." In Natural Product Biosynthesis: Chemical Logic and Enzymatic Machinery, 456–522. The Royal Society of Chemistry, 2017. http://dx.doi.org/10.1039/bk9781788010764-00456.
Повний текст джерелаKlärner, F. G., M. K. Diedrich, G. Dierkes, and J. S. Gehrke. "Organic Reactions at High Pressure: the Effect of Pressure on cyclizations and Homolytic Bond Cleavage." In High Pressure Food Science, Bioscience and Chemistry, 3–11. Elsevier, 1998. http://dx.doi.org/10.1533/9781845698379.1.3.
Повний текст джерела"Carbon Radicals." In The Chemical Biology of Carbon, 402–37. The Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781839169502-00402.
Повний текст джерелаMartinho Simões, José A., and Manuel Minas da Piedade. "Electrochemical Measurements." In Molecular Energetics. Oxford University Press, 2008. http://dx.doi.org/10.1093/oso/9780195133196.003.0020.
Повний текст джерелаFrey, Perry A., and Adrian D. Hegeman. "Decarboxylation and Carboxylation." In Enzymatic Reaction Mechanisms. Oxford University Press, 2007. http://dx.doi.org/10.1093/oso/9780195122589.003.0012.
Повний текст джерелаТези доповідей конференцій з теми "Homolytic cleavage of diborons"
Jeremić, Svetlana R., Jelena R. Đorović Jovanović, Marijana S. Stanojević Pirković, and Zoran S. Marković. "THERMODYNAMICALLY INVESTIGATIONS OF FREE RADICAL SCAVENGER POTENCY OF 1,2,4-TRIHYDROXYTHIOXANTHONE." In 1st INTERNATIONAL Conference on Chemo and BioInformatics. Institute for Information Technologies, University of Kragujevac, 2021. http://dx.doi.org/10.46793/iccbi21.414j.
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