Добірка наукової літератури з теми "Homolytic Cleavage"
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Статті в журналах з теми "Homolytic Cleavage"
Verma, Piyush Kumar, Naresh Kumar Meher, and K. Geetharani. "Homolytic cleavage of diboron(4) compounds using diazabutadiene derivatives." Chemical Communications 57, no. 64 (2021): 7886–89. http://dx.doi.org/10.1039/d1cc02881b.
Повний текст джерелаNome, Faruk, Marcos Caroli Rezende, Claudia Maria Sabóia, and Arlindo Clemente Da Silva. "Kinetics of the thermolysis of para-substituted benzylcobalamins and derivatives." Canadian Journal of Chemistry 65, no. 9 (September 1, 1987): 2095–99. http://dx.doi.org/10.1139/v87-347.
Повний текст джерелаBajaj, Ashima, Rishu Khurana, and Md Ehesan Ali. "Quantum interference and spin filtering effects in photo-responsive single molecule devices." Journal of Materials Chemistry C 9, no. 34 (2021): 11242–51. http://dx.doi.org/10.1039/d1tc02200h.
Повний текст джерелаLi, Yan, Kartik Chandra Mondal, Peter Stollberg, Hongping Zhu, Herbert W. Roesky, Regine Herbst-Irmer, Dietmar Stalke, and Heike Fliegl. "Unusual formation of a N-heterocyclic germylene via homolytic cleavage of a C–C bond." Chem. Commun. 50, no. 25 (2014): 3356–58. http://dx.doi.org/10.1039/c4cc00251b.
Повний текст джерелаSiegel, Marshall M., and Norman B. Colthup. "Molecular Orbital Study of Remote Charge Site Decompositions in the Collision-Induced Decomposition Mass Spectra of Fatty Acid Carboxylate Anions." Applied Spectroscopy 42, no. 7 (September 1988): 1214–21. http://dx.doi.org/10.1366/0003702884429887.
Повний текст джерелаHosseini, Seyedeh Nargess, Jeffrey R. Johnston, and F. G. West. "Evidence for heterolytic cleavage of a cyclic oxonium ylide: implications for the mechanism of the Stevens [1,2]-shift." Chemical Communications 53, no. 94 (2017): 12654–56. http://dx.doi.org/10.1039/c7cc07716e.
Повний текст джерелаHou, Bo, David Benito-Alifonso, Richard Webster, David Cherns, M. Carmen Galan, and David J. Fermín. "Rapid phosphine-free synthesis of CdSe quantum dots: promoting the generation of Se precursors using a radical initiator." J. Mater. Chem. A 2, no. 19 (2014): 6879–86. http://dx.doi.org/10.1039/c4ta00285g.
Повний текст джерелаShu, Xing-Zhong, and Xiaobo Pang. "Titanium: A Unique Metal for Radical Dehydroxylative Functionalization of Alcohols." Synlett 32, no. 13 (March 4, 2021): 1269–74. http://dx.doi.org/10.1055/a-1406-0484.
Повний текст джерелаTang, Wai-Kit, Chun-Ping Leong, Qiang Hao та Chi-Kit Siu. "Theoretical examination of competitive β-radical-induced cleavages of N–Cα and Cα–C bonds of peptides". Canadian Journal of Chemistry 93, № 12 (грудень 2015): 1355–62. http://dx.doi.org/10.1139/cjc-2015-0208.
Повний текст джерелаLIU, MIN HSIEN, and GEN FA ZHENG. "COMPUTATIONAL STUDY OF UNIMOLECULAR DECOMPOSITION MECHANISM OF RDX EXPLOSIVE." Journal of Theoretical and Computational Chemistry 06, no. 02 (June 2007): 341–51. http://dx.doi.org/10.1142/s0219633607002952.
Повний текст джерелаДисертації з теми "Homolytic Cleavage"
Wu, Yi-Wen, and 吳翌彣. "The Study of Electronic Structures of Five-coordinate Saddled Iron(III) Porphyrin Radical Cation and O-O Bond Homolytic Cleavage of (OETPP)FeIIIO(H)OtBu." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/n6af3q.
Повний текст джерела國立中興大學
化學系所
106
In this study, paramagnetic NMR spectroscopy, X-ray diffraction, magnetic susceptibility and DFT calculation are employed to elucidate the strong bonding interaction between iron(III) dx2-y2 and porphyrin a2u orbitals of [Fe(OMTPP∙)Cl]SbCl6 and [Fe(OETPP∙)Cl]SbCl6. Their crystal structures clearly indicate that their saddle deformations are increased compared to those prior to oxidations. Their 1H NMR data present the S = 2 states for such one-electron oxidation states, and demonstrate that their structures in solutions remain strong saddle deformations. In light of 1H NMR spectroscopy of [Fe(TPP∙)Cl]SbCl6 resembling to the above cases, we postulate that the ring structure of [Fe(TPP∙)Cl]+ may possess strongly saddle to have great bonding interaction between iron(III) dx2-y2 and porphyrin a2u orbitals. In the DFT calculations, the degrees of phenyl ring rotation and saddled deformation will also affect their NMR spectra. In another topic, we observe O-O bond homolytic cleavage of (OETPP)FeIIIO(H)OtBu formed in the reaction of Fe(OETPP)ClO4 with TBHP and its activation parameters (ΔH≠ = 47(2) kJ mol-1, ΔS≠ = 83(9)J mol-1K-1) is measured by low-temperature UV-vis spectral data. The corresponding one-electron oxidation product is identified as [Fe(OETPP∙)OH]+, which is an isoelectronic structure as oxoiron(IV) porphyrin, by UV-vis, NMR spectroscopy and ESI-MS spectrometry. According to the experiments of NMR and ESI-MS, we also find that ·OtBu radical will convert Fe(OETPP)ClO4 to [Fe(OETPP∙)OtBu]+. Furthermore, these related iron(III) porphyrin radical cations can be carried out one more electron oxidation to isoporphyrins, an isoelectronic structure as Compound I. These iron(III) saddled isoporphyrins are shown to be reactive for highly selective chlorination of cyclohexene.
Verma, Piyush Kumar. "Cobalt-nhc Complexes and Diazabutadienes in Activation of Mono/Diboron Compounds and Their Application in C-b Coupling Reactions." Thesis, 2021. https://etd.iisc.ac.in/handle/2005/5241.
Повний текст джерелаMala, Deep. "Chemistry of Ru(II) Complexes Bearing N-heterocyclic Carbene, Hydride, and Dihydrogen Ligands : Synthesis, Mechanistic Insights, and Applications." Thesis, 2016. http://etd.iisc.ac.in/handle/2005/4162.
Повний текст джерелаЧастини книг з теми "Homolytic Cleavage"
James, B. R., and M. T. Ashby. "Homolytic Cleavage to Give Metal-Hydrides." In Inorganic Reactions and Methods, 66–71. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch29.
Повний текст джерелаKühn, F. E., C. C. Romäo, and W. A. Herrmann. "Homolytic Cleavage." In Compounds of Groups 7-3 (Mn..., Cr..., V..., Ti..., Sc..., La..., Ac...), 1. Georg Thieme Verlag KG, 2003. http://dx.doi.org/10.1055/sos-sd-002-00209.
Повний текст джерела"Oxidative Degradation." In Organic Chemistry of Drug Degradation, 48–109. The Royal Society of Chemistry, 2012. http://dx.doi.org/10.1039/bk9781849734219-00048.
Повний текст джерела"S-Adenosyl Methionine: One Electron and Two Electron Reaction Manifolds in Biosyntheses." In Natural Product Biosynthesis: Chemical Logic and Enzymatic Machinery, 524–68. The Royal Society of Chemistry, 2017. http://dx.doi.org/10.1039/bk9781788010764-00524.
Повний текст джерела"Carbon Radicals." In The Chemical Biology of Carbon, 402–37. The Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781839169502-00402.
Повний текст джерела"Carbon-based Radicals in C–C Bond Formations in Natural Products." In Natural Product Biosynthesis: Chemical Logic and Enzymatic Machinery, 456–522. The Royal Society of Chemistry, 2017. http://dx.doi.org/10.1039/bk9781788010764-00456.
Повний текст джерела"Energy of a Homolytic Cleavage of Communication OH in Replaced 2,6-di-tert.Butylphenols." In Chemistry and Physics of Complex Materials, 225–34. Apple Academic Press, 2013. http://dx.doi.org/10.1201/b16302-13.
Повний текст джерелаMartinho Simões, José A., and Manuel Minas da Piedade. "Electrochemical Measurements." In Molecular Energetics. Oxford University Press, 2008. http://dx.doi.org/10.1093/oso/9780195133196.003.0020.
Повний текст джерелаKlärner, F. G., M. K. Diedrich, G. Dierkes, and J. S. Gehrke. "Organic Reactions at High Pressure: the Effect of Pressure on cyclizations and Homolytic Bond Cleavage." In High Pressure Food Science, Bioscience and Chemistry, 3–11. Elsevier, 1998. http://dx.doi.org/10.1533/9781845698379.1.3.
Повний текст джерелаFrey, Perry A., and Adrian D. Hegeman. "Decarboxylation and Carboxylation." In Enzymatic Reaction Mechanisms. Oxford University Press, 2007. http://dx.doi.org/10.1093/oso/9780195122589.003.0012.
Повний текст джерелаТези доповідей конференцій з теми "Homolytic Cleavage"
Jeremić, Svetlana R., Jelena R. Đorović Jovanović, Marijana S. Stanojević Pirković, and Zoran S. Marković. "THERMODYNAMICALLY INVESTIGATIONS OF FREE RADICAL SCAVENGER POTENCY OF 1,2,4-TRIHYDROXYTHIOXANTHONE." In 1st INTERNATIONAL Conference on Chemo and BioInformatics. Institute for Information Technologies, University of Kragujevac, 2021. http://dx.doi.org/10.46793/iccbi21.414j.
Повний текст джерела