Дисертації з теми "Hazardous occupations – Case studies"

Over the past 20 years, adult obesity has increased in the United States, especially among the Hispanic/Latino population. In 2010, the Occupational Safety and Health Administration Environmental and Safety News, reported that younger workers, ages 18 to19 years of age, worked in the most high-risk occupations such as agriculture, construction, fishing, and manufacturing. The reported fatality rates for these occupations were 5.6 times greater for Hispanic workers compared to other race/ethnicity groups reported by the Bureau of Labor Statistics in 2013. This study determined whether obesity contributed to workplace injury or mortality in hazardous occupations, using federal, state, and independent national databases. The independent variable was obesity, the dependent variable was injury in hazardous occupations. In addition, age, gender, race/ethnicity, socioeconomic level, educational level, and cultural context were used as mediating variables. The target population included all workers ages 18 to 65 years of age in hazardous occupations. Analysis of databases from NHANES, BRFSS, NIOSH, OSHA, and the BLS was conducted using descriptive statistics for frequency of the mediating variables' relationship to workplace injury. This study highlighted the prevalence of obesity in the Hispanic/Latino population and increased incidence of workplace injury in hazardous occupations, but found no significant relationship between the variables using the BFRSS Web Enabled Analysis Tool for linear regression and cross-tabulation. Establishing a relationship between obesity and increased injury for the Hispanic/Latino population in high-risk occupations for preventative measures will enhance positive social change within this underrepresented population in research.

The potential hazards to the environment and to human health posed by several types of household hazardous wastes (HHW) and waste products are discussed in this paper. This discussion serves to lead into an evaluation of the design and operating parameters of a collection program for these wastes, and the influence that various design parameters may have on the ability of the collection program to remove the wastes from uncontrolled waste stream. A review of existing HHW collection programs and of surveys regarding HHW's is presented. A survey of over 200 households in Vancouver was conducted to determine stored quantities and generation characteristics of specific household hazardous wastes. Respondents were also asked to identify their preferences and concerns regarding the design of a collection program for these wastes. The results were used to estimate the quantities of HHW disposed of annually, and the quantities and profiles of wastes that could be received at a typical depot collection program in the City. Different operating parameters for both depot collection programs and household collection programs were compared. Public willingness to participate in different collection programs was evaluated, and the collection needs of different residential areas was assessed. Significant differences in waste generation and storage practices were indicated to exist between types of dwellings, and between areas of differing economic status. Examples include the result that as many or more apartments residents generated HHW's as did detached dwelling residents, but in significantly smaller quantities, especially for liquid HHW's. Apartment residents also tended to store less HHW than detached dwelling residents. Between upper income and lower income detached dwelling areas, the composition of HHW's was significantly different, with automotive products more prevalent in the lower income area and paints more prevalent in the upper income area. Other differences between dwelling type and income level differentiated areas were also noted. Further observations included the difference in the willingness of respondents to participate in various types of collection programs, and the disposal practices for different waste types. Also, concerns of the respondents with regard to the issue of HHW in general and to each type of collection program in specific were solicited and discussed. Recommendations were made to assist in the design of an effective HHW collection program for the City of Vancouver.
Applied Science, Faculty of
Civil Engineering, Department of
Graduate

The purpose of this mixed methods qualitative case study is to gain a deeper understanding about the factors that contribute to and/or hinder women’s participation in the construction industry by examining women’s experiences within one very industry-specific, male-dominated nontraditional occupation (NTO)—the concrete industry. In this study I utilized a combination of methods including interviews and survey research, as well as case analysis of an organization specifically involved with this population, the Women In Concrete Alliance (WICA). This investigation identifiesd some of the reasons why women’s participation remains low, discusses some of ways that the private, public, and educational sectors have set out to address those shortages, how women working in the field felt feel about those initiatives based upon their experiences, and what systems of support these women draw upon to remain active in a male-dominated profession. As women’s associations within NTOs are one relatively formal potential means of support for women facing occupational isolation, this study also examines different types of organizations to which women working in NTOs belong (e.g. membership, educational, advocacy, trades). I want to know in what ways the organizations benefit members; how the organizations support themselves or are supported financially.

The pharmaceutical industry must worry about managing pharmaceutical waste as it poses a health risk to human beings and its presence in the environment can also contribute to loss of biodiversity. Ngwuluka, Ochekpe, and Odumosu (2011: 11259) state that “Pharmaceuticals, though used to treat and manage diseases, are poisons, which justify the growing concerns about their presence in the environment.” Various forms of pharmaceutical waste exist, Ngwuluka et al. (2011) identified the following forms of pharmaceutical waste: Expired dosage forms, non-reworkable formulations, spilled pharmaceuticals, rejected active pharmaceutical ingredients, expired active pharmaceutical ingredients, and wastewater resulting from the water used for process operations during manufacturing and could come from the water used to clean equipment, pipes and floors, and would contain amongst other materials, chemicals and active pharmaceutical ingredients (APIs). A review on the pharmaceutical industry and the progress they have made in environmental management by generating health, safety and environmental programs, preventing pollution, waste minimization, recycling and reusing materials, investing in projects and facilities to ensure environmental sustainability have been established (Berry & Rondinelli, 2000). Dr. Reddy’s Laboratories is an Indian based pharmaceutical company which imports, markets and sells medicines in South Africa. Dr. Reddy’s has plans to set up a manufacturing plant in South Africa. The purpose of this study is to research waste management practices at Dr. Reddy’s plant in India and to draw parallels between India’s and South Africa’s waste legislation. This is to enable Dr. Reddy’s to review all aspects of its waste management systems, in order to revise where necessary and to improve the overall achievement of its waste management objectives in order to become a more sustainable organisation and to meet South African Waste legislation before setting up a plant in South Africa. 3 ii. Objective of the Evaluation Report The purpose of this research is to evaluate and analyse the development and implementation of a waste management system in a pharmaceutical company, specifically Dr. Reddy’s Laboratories. This is primarily to enable the company to review and analyse all aspects of waste management pertaining to pharmaceutical manufacturing and to revise or improve where necessary to ensure adherence to waste regulations as outlined by government. The following research goals have been also been identified:  To identify and describe waste management practices at Dr. Reddy’s Laboratories, on the inherent assumption by the researcher that the company has a successful waste management strategy that would need to be reviewed to identify areas of improvement before expanding manufacturing facilities into South Africa.  To evaluate, assess and compare similarities and/or differences between the identified South African Legislation for Waste Management with those identified during research conducted at Dr. Reddy’s iii. Importance of the Research Conducted Waste Management is important in that it not only removes from the environment, substances that can be harmful to humans and animals but it also enables an organisation to be more sustainable. According to Seadon (2010: i) “Integrated waste management is considered from a systems’ approach, with a particular emphasis on advancing sustainability”. The study will provide guidance to senior management, shop floor managers and employees who work in Dr. Reddy’s manufacturing plants as well as overall employees at Dr. Reddy’s on how to successfully implement a Waste Management programme to enhance sustainability at the organisation and realise the benefits to the organisation of being more sustainable. Weybrecht (2010) identified the following benefits that companies could gain by adopting sustainable waste management practices: reduced costs, resource preservation, keeping up with legislation, enhanced reputation, business differentiation from competitors, and attraction and retention of quality employees, and customer need satisfaction amongst many other benefits. This research needs to address the gap in analysing waste management practices (with more emphasis on waste treatment, waste minimisation, re-use, recycling and disposal), and implementation and understanding of waste management in the pharmaceutical industry as prior research was done mostly in other chemical industries and not to a large scale in the pharmaceutical industry. South African Waste Legislation, Indian Waste Legislation (as Dr. Reddy’s is based in India), as well as International Pharmaceutical Waste Management Guidelines, and International Pharmaceutical Good Manufacturing Practices provide a framework and benchmark of leading pharmaceutical waste management practices that can guide Dr. Reddy’s Laboratories’ leadership into integrating their waste management practices into their plans of setting up a manufacturing plant in South Africa. 5. Research Methodology This is evaluation research in the form of a case study and the data collection method employed is the conduction of a survey through questionnaires. The evaluation research also involves a document analysis of the organisation’s 2011 and 2012 annual reports, Dr. Reddy’s 2010 Sustainability Report as well as literature compiled by the organisation’s Corporate Communications Division. The research would also include review of existing literature on waste management. v. Structure of Dissertation This dissertation consists of three sections. Section 1: The Evaluation Report The section introduces the research area, provides the objectives of the research, provides contextual background information and describes the rationale for conducting the research. This section further describes Dr. Reddy’s waste management practice as outlined in relevant company documentation; it is also intended to highlight the specific waste management processes that were followed in the formulation and implementation of the waste management strategy. This section further describes the sample and presents the results of the survey, where the results are collated and reviewed in the context of the criteria set in the South African Waste Legislation, Indian Waste Legislation, as well as in International Pharmaceutical Waste Management Guidelines, and International Pharmaceutical Good Manufacturing Practices. The overall findings of this case study suggest that although management at Dr. Reddy’s are satisfied with waste management practices and results achieved at it manufacturing plant, there is however dissatisfaction amongst employees who believe the organisation has not successfully disseminated information and sufficiently trained them on waste management policies, processes and practices. There is therefore a desire amongst employees to be trained and to see the company improve on its waste management processes, this desire is a very important attribute as it indicates that employees at Dr. Reddy understand and are committed to the importance of waste management. Future research should be conducted to measure the legal impact of non-compliance to legislation governing waste management in the pharmaceutical company. Section 2: Literature Review The objective of the literature review is to provide a critical assessment and evaluation of previous research in the field of waste management in general as prior research was done mostly in other industries and not to a large scale in the pharmaceutical industry. The literature review evaluates the key elements of an effective waste management strategy implementation and is followed by a review of literature pertaining to the description of Pharmaceutical waste. Section 3: Research Methodology This section presents a description of how the work in this research was conducted. It presents the research process followed in compiling this case study, represented by the aims and objectives, research methodology and design, data collection techniques and data analysis.

The purpose of this research is to examine the following research question: how has enforcement of Resource Conservation and Recovery Act (RCRA) adapted to the Big Box business system innovation? Additionally, the study explored the possible nature of regulatory choke points that may emerge from the enforcement of RCRA in the Big Box retail system. This study used contingency theory to establish a foundation for analysis of the Big Box business system innovation through identification of structural elements, external influences, and their subsequent interactions associated with the Big Box retail system in terms of environmental compliance with the RCRA enforced by the United States (US) Environmental Protection Agency (EPA). This research employed an embedded comparative case study design using the comparison of two Big Box firms, Walmart Stores, Inc. and Target Corporation, nationally and for the following states with opposing enforcement strategies: Arizona, Kentucky, Missouri, and Texas. The data used was obtained from third-party federal or firm-maintained sources. Findings indicate Walmart adheres to the structural models developed using contingency theory principles and incurs more impacts from regulatory agencies due to the enforcement of RCRA. Furthermore, it was observed that inspections of the firms are not distributed throughout the organizational structural elements by all states. Additionally, the use of different enforcement strategies resulted in the emergence of regulatory choke points by Arizona, Kentucky, and Texas; however, Missouri appears to balance enforcement without causing a regulatory choke point. This research has identified that the enforcement of RCRA has not universally adapted to the demands of the Big Box business system innovation. Agency implications, firm implications, directions for further research, and continued development of a regulatory choke point theory are discussed.

Women’s involvement in collective struggles for environmental quality has surged in recent years, as has research focusing on this phenomenon. Consistent with this research, a feminist lens is useful in revealing a model of community struggle that features women’s activities and strategies to expose environmental insult. I use a case study of community protest in Hermosillo, a city in the Mexican state of Sonora, to feature social networks as a means of politicizing the placement of a toxic waste dump six kilometers outside the city. A feminist perspective reveals these social networks to be more than a way to mobilize resources. It allow us to see the ways in which gender interacts with globalized relations of power, political ecology, and environmental policy, and to validate a creative way in which women can out-maneuver the gendered constraints to political participation. An analysis of how social networks served in this particular struggle suggests that they are an important component in the process through which women gained voice and authored oppositional discourse in contexts where these have been previously denied, and ultimately deconstructed the political authority that sanctioned the dump.

The significance of risk is growing in many Western societies, a phenomenon linked to increasing individualism, personal choice, and outcome uncertainty in multiple spheres of life. Despite being healthier and more physically protected from harm than any previous society, a serious concern for safety and risk control is emerging as a defining characteristic of modern social life. Within the context of a risk-averse society, this thesis investigates the nature and relevance of risk in natural resource recreation and tourism settings. Millions of people every day visit national parks and other protected areas around the world in which natural hazards inhere. Many visitors fail to recognise these hazards, creating moral, legal, and ethical issues for natural resource managers. People travel to national parks anticipating a degree of adventure, to escape routines, and to witness the grandeur of nature. Ironically, the very qualities that attract people to natural areas may also put them at risk. Managers of natural resource tourism and recreation areas in New Zealand are confronted with a paradox born out of visitor demand for nature experiences, a legal obligation to facilitate free access, and a growing social emphasis on health and safety. In particular, this study assesses the risk perceptions of visitors to the Fox and Franz Josef glaciers, popular tourist attractions on the West Coast of New Zealand's South Island, and explores the risk perceptions and beliefs of resource management agency staff. The study also investigates the issue of risk communication at these two sites, and the degree to which existing hazard messages are successful at encouraging appropriate visitor behaviour. Pictorial hazard warning signs are introduced to the sites and their effectiveness evaluated. The findings show that many visitors (especially international visitors) have relatively poor awareness of natural hazards, and behave in ways which potentially compromise physical safety. It is argued that perceptions and behaviour are a consequence of diverse individual and situational factors including limited knowledge of the sites, beliefs about management, poor comprehension of hazard warning signs, and freedom from the normative constraints of everyday life. In contrast to visitors, managers at the glacier sites consider the risks to be significant, and, potentially, severe. It is argued that managers' perceptions of risk are influenced by several important social and site-specific factors, including their own experiences of hazards at the glaciers, perceived legal and moral obligations, the organisational culture, and impressions of high societal expectation concerning safety. The situation is further complicated by the freedom of access principle in national parks, and increasing tourist demand for nature-based experiences. These factors governed beliefs about the subject of risk. This study identifies several dimensions of risk in nature-based recreation and tourism settings. Visitors are at risk of personal accident or injury at certain tourism attractions. Awareness of hazards is limited, visitor behaviour compromises safety, and existing communication strategies are only partially effective. Risk is also apparent in the agency responsible for management of outdoor recreation areas. Site managers perceive a risk in their failure to prevent visitors from harm, whereas senior managers identify risk as primarily financial, legal, and political. Collectively, these factors demonstrate that the phenomenon of risk is increasingly important in the tourism and recreation context, and has the potential to influence significantly both management and experience of protected natural areas in New Zealand.

O Departamento Acadêmico de Química e Biologia da UTFPR- Câmpus Curitiba conta hoje com 30 laboratórios dedicados a atividades de ensino e pesquisa. Atualmente, os resíduos gerados por esses laboratórios são recolhidos e seguem para disposição final. Neste trabalho, foi realizado um levantamento da atual situação da geração de resíduos químicos de laboratório no Departamento. Inicialmente os laboratórios de ensino foram selecionados para execução do trabalho por atenderem maior número de alunos e por suas atividades frequentes, sendo identificados os que atendiam maior número de alunos e onde eram executadas mais aulas práticas. Estudou-se as características dos resíduos gerados nestas aulas, com base nos planos de ensino, acompanhamento de algumas disciplinas durante a execução dos experimentos e registros do almoxarifado. Verificou-se as possibilidades de modificações experimentais, visando a prevenção da geração de resíduos, conforme enunciam os princípios da Química Verde. Desta forma, as disciplinas de Química Inorgânica e Orgânica foram consideradas com boas oportunidades de intervenção. Os roteiros experimentais dessas disciplinas foram estudados, e o inventário dos resíduos gerados por elas apontaram a geração de resíduos perigosos, segundo a NBR 10.004 da ABNT. Elaborou-se cinco novos roteiros de aulas práticas e as modificações metodológicas propostas envolveram a substituição de reagentes que pudessem originar resíduos perigosos contendo bário, chumbo, acetato de etila e clorofórmio. Realizou-se estudo na literatura, de modo a embasar teoricamente as propostas, as quais foram testadas em laboratório. Os testes realizados atingiram os objetivos propostos, comprovando a possibilidade de aplicação das modificações sugeridas. Um dos roteiros modificados foi aplicado em aula prática com o objetivo de verificar sua aplicabilidade e como os alunos receberiam as mudanças. Os alunos executaram e verificaram os fenômenos conforme os objetivos do roteiro, comprovando que o aprendizado não foi prejudicado e que o caráter didático da aula foi mantido. Concluiu-se que é possível executar as aulas práticas das disciplinas citadas prevenindo a geração de resíduos perigosos por meio de técnicas simples e aplicáveis, mantendo-se os objetivos iniciais das aulas práticas e incorporando-se princípios da Química Verde.
The Academic Department of Chemistry and Biology of UTFPR- Campus Curitiba today has 30 laboratories dedicated to teaching and research activities. Currently, waste generated by these laboratories are collected and proceed to final disposal. In this study, we conducted a survey of the current situation of the generation of laboratory chemical waste in the Department. Initially teaching laboratories were selected for execution of work for meeting more students and their frequent activity, were identified that met more students and where they were executed more practical classes. Studied the characteristics of the waste generated in these classes, based on the teaching plans, monitoring of some subjects during the execution of experiments and records the warehouse. There was the possibility of experimental changes, preventing the generation of waste, as set out the principles of green chemistry. Thus, the disciplines of Inorganic and Organic Chemistry were considered with good opportunities for intervention. The experimental manuals of these subjects were studied, and the inventory of the waste generated by them showed the generation of hazardous waste according to NBR 10004 of ABNT. We developed five new routes of practical classes and methodological changes proposed involved the replacement of reagents that could give rise to hazardous waste containing barium, lead, ethyl acetate and chloroform. It was proposed in the literature to explain theoretically proposed, which were tested in the laboratory. The tests met the proposed objectives, proving the applicability of the suggested changes. One of the modified scripts was applied in practical class in order to verify its applicability and how students receive the changes. Students performed and observed phenomena according to the objectives of the roadmap, proving that learning was not harmed and that the didactic nature of the class was held. In conclusion, you can perform the practical lessons of the disciplines mentioned preventing the generation of hazardous waste through simple and applicable techniques, maintaining the initial objectives of the practical classes and incorporating up principles of Green Chemistry.

This work articulates few case empirical studies on some aspects of risk management and occupational health hazards in the context of Indian Industries. Empirical research is research using empirical evidence. It is a way of gaining knowledge by means of direct and indirect observation or experience. The study focuses on five important domains investigating (i) the interrelationships among critical risk factors associated with software engineering project, (ii) risk management for IT outsourcing, (iii) risk management in metropolitan construction project, (iv) health hazard risk management, and (v) appropriate safety measure system selection for improving workers’ safety in an underground coal mining industry. In this research, an ISM approach has been applied to understand the significant interrelationships among the twenty three identified risk factors associated with the software engineering projects. In relation to IT outsourcing project, a hierarchical risk-breakdown structure has been proposed comprising sixty eight risk influencing factors under eleven risk dimensions. A case study has been conducted in a famous IT sector located at the eastern part of India. An improved fuzzy based decision making approach has been proposed for assessing overall IT outsourcing project risks. The degree of risk of identified risk factors have been shown in crisp values rather than the fuzzy numbers. A logical risk categorization framework has been proposed to categorize the risk factors into different risk levels. A unique action requirement plan has been suggested for effectively controlling the risks towards IT outsourcing project success. In the later part, total twenty one occupational health hazards have been identified and assessed their risk extent based on the exposure assessment procedure. Consequently, a constructive control measure plan has been suggested for different health hazards in view of their risk extent level. A novel risk-based decision making framework has been proposed for selecting the appropriate safety measure system in an underground coal mining industry. In addition to this, a case study has been conducted using twenty potential risk factors associated with five risk dimensions for assessing metropolitan construction project risks. Decision-makers’ risk bearing attitude has also been considered in this study. This study also explores the concept of risk matrix for categorizing the risk factors in different risk levels which would provide guidelines towards controlling risks for enhancing the overall project performance. Risk analysis models delignated herein have been case studied in relation to Indian industries. However, the model or hierarchy of various risk dimensions, risk sources; and classification of health hazards can be applicable to appropriate industries all over the globe. Some alteration may incur depending on the geographic situation of coal mining industry in analyzing occupational health hazards and associated risks. The framework for analyzing risks and occupational health hazards based on fuzzy based decision making approach can be applied in industrial context of different countries. Apart from the case studies mentioned above, the work also proposes a risk based decision support framework for selection of safety measure system for underground coal mines. In this case, occupational risks and alternative safety measure systems have been identified through literature survey. This part is a purely a theoretical formulation followed by analysis of assumed data which has not been case studied in reality. The novelty of the proposed framework is to analyze various risk dimensions in software engineering projects, IT Outsourcing, construction projects; also occupational health hazards in underground coal mining industry in a fuzzy based decision making framework. Instead of exploring historical data, survey report of the company; an experienced decision making group has been appointed to provide subjective judgement in regards of likelihood of occurrence and impact of various risks; consequence of exposure, period of exposure, and probability of exposure of various health hazards. Subjective decision making data have been transformed into appropriate fuzzy number sets to quantify overall risks extent. Thus, the proposed framework provides a platform to quantify extent of risk in industrial context.

碩士
國立成功大學
工程管理碩士在職專班
104
Factory fire, explosion, chemical leak accidents have caused considerable casualties and property losses in recent year. Followed by the concept of Prevention is better than relief, this current study aims to provide the disaster prevention strategies for chemical accidents, and indicates how to control the disaster area effectively within the shortest time in order to reduce the impact of hazards. The analyses of the study are based on the reservoir leakage accident of public hazardous materials happened in Xinying, Tainan. The hazard modeling program, ALOHA (Area Location of Hazardous Atmosphere), is used to predict the gas cloud diffusion of toxic chemicals and fire thermal radiation. The outputs of ALOHA (footprint) would be overlaid in Google Earth for investigating the disaster scenario of chemical leakage in its surroundings. The simulation results will help control the actual scene, and understand the possible hazard and severity of the accident area. In addition, it can also be beneficial for relief workers to control the hazard within the limited time, and reduce the impact of the accident. The contributions of the study are twofold: one is to provide a reference for disaster relief units to plan the disaster evacuation by assisting people to the safe refuge and help firefighters to make a correct judgment as well. Besides, the results can be an emergence guide when the factory asks for the external supports according to the leakage severity.

Chromium hydroxide sludge is the end product of the aluminum phosphate coating process used by a truck manufacturer in the Pacific Northwest. This sludge is listed as an (F019) hazardous waste by the Environmental Protection Agency, and must be landfilled in a hazardous waste landfill site. The purpose of this thesis is to evaluate the characteristics of this sludge, and to then recommend suitable methods for handling and disposal. The chemical analysis of the sludge found total chromium to be 5.4% by weight. Industrial hygiene monitoring found the highest concentrations of 0.002 mg/m3 total chromium and 0.00006 mg/m3 hexavalent chromium at the waste treatment plant. The eight hour permissible exposure limit for total chromium is 0.5 mg/m3 and 0.05 mg/m3 for hexavalent chromium. Given the chemical analysis and industrial hygiene monitoring, a management plan is proposed for this truck manufacturer that discusses possible options for handling the (F019) waste, and provides a cost analysis for each of the options. The options that were investigated were onsite treatment, recycling, no change, and delisting. Onsite treatment was not required since the sludge passed the TCLP extraction test. Recycling costs were determined by contacting four recycling firms. Costs were found to be $600/ton and above, which exceeded the current disposal costs of $466/ton. Delisting the sludge from the hazardous waste listing was determined to be the most feasible from a management, cost, and environmental standpoint. Delisting would reduce the costs of handling the waste, would allow a reduction in landfilling costs, and reduce recycling costs. A literature survey provides background information on industrial uses of chromium, health problems associated with chromium, and discusses the regulations that govern disposal of these chromium sludges.
Graduation date: 1991

The paucity of women in senior leadership positions as indicated in the Business Women Association of South Africa 2011 census corroborates that gender equality is still a concerning issue even in the democratic era that we live in. This study explores career developmental experiences of women in senior leadership position in the civil engineering industry. The primary objective was to investigate how these professional women were managing their careers and what career experiences contributed to their ascent to the senior echelons of management. Meaning to the career experiences of these women had been given according to the self-determination theory. By means of purposive selection, seven women at senior management level were selected from both the private and public sectors in the civil engineering industry. Based on the semi-structured interviews conducted, personal documents reviewed and footnotes recorded; it was evident that there were different factors that had facilitated the ascent of these women to senior positions. Their career experiences were also characterised by challenges that subsequently instigated the development of coping strategies and methods. The study has implications for organisations in civil engineering that wish to attract and retain women from generations to come.
Psychology
M.A. (Psychology)

Microbial biodegradation methods of hydrocarbon contaminated soils that can occur through biodegradation, bio augmentation, bio stimulation, and phytoremediation, have gained significant interest in recent years when compared to the conventional methods. The study was designed to explore the influence of petroleum hydrocarbon contamination on physicochemical and microbial characteristics of soils as well as determining the possibility of hydrocarbon biodegradation using biostimulation. The process involved soil characterisation and modification of nitrogen and phosphorus content to stimulate naturally adapting microorganisms. Characterisation process determined that hydrocarbon contamination of Murowa soils introduced hydrophobicity to the naturally wettable sandy loam soils. Naturally adapting microbial species capable of degrading hydrocarbons identified using Direct microscopy, Gram and Melzer’s iodine staining included Pseudomonas, Bacillus, Serratia marcescens, Flavobacterium, Micrococcus, Streptomyces Staphylococcus, Penicillium and yeasts. The N: P nutrient ratio and moisture levels were identified as potential limiting factors and hence experiments focused on manipulation of N: P nutrients to stimulate the identified hydrocarbon degrading organisms (bio stimulation). Hydrocarbons were identified by solvent extraction using hexane and gas chromatography. These included decane, undecane, hexadecanal, 2-ethylcridine, octadecane and 1-iodo. Soils weighing 10kgs with hydrocarbons levels of about 265mg/kg were subjected to eight (8) treatments with seven (7) different combinations of N (6000-12000mgN): P (600- 3000mgP) concentration ranges including the control. Nitrogen The moisture was adjusted and tilling for aeration was done on a weekly basis. Changes in Total Petroleum Hydrocarbon (TPH), C: N: P ratio, microbial mass and pH were evaluated over 111 consecutive days. The optimum N:P ratio was the determined to 2:1 molar ratio in form of 6000mgN:3000mgP. TPH concentration was reduced by 73% from the initial concentration within the first 74 days. Beyond 74 days there were no significant changes in the TPH concentration and this was attributed to the presence of more complex insoluble hydrocarbons which needed more time and an additional bio surfactant to complete mineralization. The conclusion was that a combination of natural attenuation and biostimulation methods can be used to bioremediate Murowa hydrocarbon contaminated soils using the 2:1 molar ratio of what
College of Agriculture and Environmental Sciences
M. Sc. (Environmental Science)

Abstract in English
Incineration is still a widely utilised method for treating healthcare risk waste in the Republic of South Africa. As much as incinerators are needed, the fact that they are still a critical source of hazardous toxic air pollutants that are not easy to manage cannot be disregarded. The Ministry of Environmental Affairs has promulgated a new regulation for General and Hazardous Waste Thermal Treatment. This exceedingly stringent air pollution legislation requires that existing incinerators be modified or redesigned to meet the new air quality standards, or face closure in the event that they fail to comply. The regulation contains strict emission requirements for concentrations of stack gases such as CO2, NO2, NOx, HCl, HF, CO, SO2, as well as TOC and PM. To be certain that emissions are within the standard, incineration facilities are instructed to reduce the acid gas emissions and to have permanent on-line monitoring equipment for stack testing of regulated pollutants. Since the promulgation of the new legislation in April 2015, none of the incinerators in South Africa has been able to achieve the new requirements. This study, based on the quantitative approach, was conducted in search of a cost-effective method of controlling acid gas emissions from incinerators without major adjustments to the plants. During the study, 60 kg of sorbacal Ca(OH)2 was injected into a lime feeder every day. A variable speed drive was used to inject Ca(OH)2 into the furnace continuously at a rate of between 2.5 kg/h and 3.5 kg/h. The temperature was maintained between 850°C and 1200°C with the use of four gas burners. Two manual blowers were utilised to ensure a continuous flow of Ca(OH)2 into the reaction chamber and filtration system. Comparative analysis was done to compare gas emission levels before and after the use of hydrated lime. Descriptive statistics were used to compute the mean, frequency and percentages, while Wilcoxon sign rank test established whether hydrated lime was significant in reducing gaseous emissions or not. Wilcoxon sign rank test showed a statistically significant difference (P<0.05) in the reduction of all gaseous emissions using hydrated lime, except particulate matter where there was a significant increase in emissions. This technology was able to achieve high removal efficiency of 97% for HCl, 86% for HF, 83% for NOx, 87% for SO2 and 74% for NO2. The optimum temperature for SO2 and NOx was 1020°C. For HCl it was between 1190°C and 1200°C, and for NO2 it was between 1120°C and 1200°C. The amount of particulate matter increased along with the concentration of the Ca(OH)2 injections. Ca(OH)2 was found to be cost effective in the controlling and capturing of gaseous emissions. It is recommended that combustion requirements, such as heat, oxygen and turbulence, be considered to reduce the amount of gases generated during the incineration of healthcare risk waste. It is also recommended that electrostatic precipitators be used instead of fabric filters to improve the efficiency of capturing the particulate matter.
Environmental Sciences
M.Sc. (Environmental Science)

The South African Waste Information System (SAWIS) was developed by the Department of Environmental Affairs and Tourism (DEAT) in 2005. This is a system used by government and industry to capture routine data on the tonnages of waste generated, recycled and disposed of in South Africa on a monthly and annual basis. All waste producers and waste management organisations should contribute to this national waste database and should accurately monitor the types and quantities of waste produced and handled. According to DEAT (2006) the need for Data verification is important. DEAT (2006:59) defined the term Data Verification as: "assessing data accuracy, completeness, consistency, availability and internal control practices that serve to determine the overall reliability of the data collected." The aim of the study is to determine a procedure, as well as the nature and extent of internal and external source documents, which could be used in the reconciliation of medical waste quantities from generation to disposal. The key objectives are to determine whether the selected hospitals keep internal records of the quantities of medical waste generated; to reconcile the waste quantities on the internal records with the external records, such as the collection certificates, invoices and waste incineration certificates; to ascertain whether the quantity of medical waste generated is equal to the quantity of waste incinerated and disposed of to determine the ratio factor between the quantity of medical waste before incineration and the quantity of the residue (ashes) after incineration, and to make recommendations on the reconciliation of waste quantities from the point of generation to the point of disposal. The results of the study indicate that the destruction certificate is the proof that the waste that was on-site collected by the service provider has been disposed /treated. Especially as an internal control measure. The health care risk waste (HCRW) management record keeping of quantities of weight as per Hospital A, Hospital B and Hospital C allows the opportunity to analyse the weight per month and per Hospital and per category and to make comparisons. The weakness or the gap however still exist that the waste is not weighed at the point of origin, but at the point where the waste service provider collects the waste onsite. It is from this point onwards that the service level agreement between the hospital and the waste service provider and the document management system and the tracking receipt and the waste collection documents (WCD) becomes relevant and where the quantities of waste per category are for the first time recorded. The hypothesis as stated in Chapter 1 was proven valid. The study concludes that reconciliation and comparison between the collection certificate and the destruction certificate and the monthly invoice is therefore possible, but the risk of mixing of waste and the understating or overstating of waste quantities is still not overcome.
Environmental Sciences
M. Sc. (Environmental management)