Добірка наукової літератури з теми "Dendritic olivine"

Trace element zoning is often used to unravel the crystallization history of phenocrysts in magmatic systems, but interpretation requires quantifying the relative importance of equilibrium versus disequilibrium. Published partition coefficients for phosphorous (P) in olivine vary by more than a factor of ten. After considering kinetic effects, a new equilibrium partition coefficient was extrapolated from a re-examination of natural and experimental systems, indicating that P partition coefficients in olivine are significantly over-estimated. These new partitioning constraints allow us to establish a theoretical P Equilibrium Fractionation Array (PEFA) for mid-ocean ridge basalts (MORBs), revealing that most olivines from MORBs have excess P (2–15 times PEFA) and are thus in disequilibrium. Using an independent case study of natural dendritic olivines, we show that such P enrichments can be explained by diffusion-limited incorporation of P during rapid crystal growth. If growth rate can be related to cooling, the rapid growth rates of olivines have implications for magma system dynamics, such as the size of magma bodies or where crystallization occurs within the body.

Abstract Crystal aggregates in igneous rocks have been variously ascribed to growth processes (e.g., twinning, heterogeneous nucleation, epitaxial growth, dendritic growth), or dynamical processes (e.g., synneusis, accumulation during settling). We tested these hypotheses by quantifying the relative orientation of adjacent crystals using electron backscatter diffraction. Both olivine aggregates from Kīlauea volcano (Hawaiʻi, USA) and chromite aggregates from the Bushveld Complex (South Africa) show diverse attachment geometries inconsistent with growth processes. Near-random attachments in chromite aggregates are consistent with accumulation by settling of individual crystals. Attachment geometries and prominent geochemical differences across grain boundaries in olivine aggregates are indicative of synneusis.

Abstract Many recent studies have investigated the replacive formation of troctolites from mantle protoliths and the compositional evolution of the percolating melt during melt–rock interaction processes. However, strong structural and geochemical constraints for a replacive origin have not yet been established. The Erro–Tobbio impregnated mantle peridotites are primarily associated with a hectometre-size troctolitic body and crosscutting gabbroic dykes, providing a good field control on melt–rock interaction processes and subsequent magmatic intrusions. The troctolitic body exhibits high inner complexity, with a host troctolite (Troctolite A) crosscut by a second generation of troctolitic metre-size pseudo-tabular bodies (Troctolite B). The host Troctolite A is characterized by two different textural types of olivine, corroded deformed millimetre- to centimetre-size olivine and fine-grained rounded undeformed olivine, both embedded in interstitial to poikilitic plagioclase and clinopyroxene. Troctolite A shows melt–rock reaction microstructures indicative of replacive formation after percolation and impregnation of mantle dunites by a reactive melt. The evolution of the texture and crystallographic preferred orientation (CPO) of olivine are correlated and depend on the melt/rock ratio involved in the impregnation process. A low melt/rock ratio allows the preservation of the protolith structure, whereas a high melt/rock ratio leads to the disaggregation of the pre-existing matrix. The mineral compositions in Troctolite A define reactive trends, indicative of the buffering of the melt composition by assimilation of olivine during impregnation. The magmatic Troctolite B bodies are intruded within the pre-existing Troctolite A and are characterized by extreme textural variations of olivine, from decimetre-size dendritic to fine-grained euhedral crystals embedded in poikilitic plagioclase. This textural variability is the result of olivine assimilation during melt–rock reaction and the correlated increase in the degree of undercooling of the percolating melt. In the late gabbroic intrusions, mineral compositions are consistent with the fractional crystallization of melts modified after the reactive crystallization of Troctolites A and B. The Erro–Tobbio troctolitic body has a multi-stage origin, marked by the transition from reactive to fractional crystallization and diffuse to focused melt percolation and intrusion, related to progressive exhumation. During the formation of the troctolitic body, the melt composition was modified and controlled by assimilation and concomitant crystallization reactions occurring at low melt supply. Similar processes have been described in ultraslow-spreading oceanic settings characterized by scarce magmatic activity.

AbstractPyrometallurgical slags from three Cu-Co smelters (Nkana, Mufulira, Chambishi) in the Copperbelt Province, Zambia, were studied from mineralogical and chemical points of view. The slags were enriched in metals and metalloids, mainly Cu (up to 35 wt.%), Co (up to 2.4 wt.%) and As (up to 3650 ppm). The following primary phases were observed in slags: Ca-Fe silicates (clinopyroxene, olivine) and leucite, oxides (spinel-series phases), ubiquitous silicate glass and sulphide/metallic droplets of various sizes. The presence of glass and skeletal/dendritic crystal shapes indicated rapid cooling of the slag melt. Copper and cobalt were found in low concentrations in the majority of silicates (olivine, clinopyroxene) and oxides, substituting for Fe in their structures (up to 7.15 wt.% CoO in olivine, 4.11 wt.% CuO in spinel). Similarly, up to 0.91 wt.% CoO and 6.90 wt.% CuO were observed in the interstitial glass. Nevertheless, the main carriers of these metals in the slags studied were Cu sulphides (digenite, chalcocite, bornite, chalcopyrite), Co-Fe sulphides (cobaltpentlandite), Co-bearing intermetallic phases ((Fe,Co)2As) and alloys. Weathering features corresponding to the presence of secondary metal-bearing phases, such as malachite (Cu2(CO3)(OH)2), brochantite (Cu4SO4(OH)6) and sphaerocobaltite (CoCO3), were observed on the slag surfaces. They indicate that the slags studied are reactive on contact with water/atmosphere and that their environmental stability and release of potentially harmful metals and metalloids must be evaluated further.

Slags from the remote Mota Farun locality above Casaccia (Val Bregaglia, Swiss Alps) have been analyzed with scanning electron microscopy, X-ray powder diffraction and microfocus synchrotron X-ray diffraction to determine mineralogical composition and microstructures. Non-magnetic slag samples are largely composed of euhedral and dendritic iron-rich olivine in a glassy matrix. Locally there are zones with globular inclusions rich in bornite ((Cu5Fe)S4) and locally metallic copper. Some regions display dendritic pentlandite ((Fe,Ni)9S8). Magnetic samples are mainly composed of fayalite (Fe2SiO4) and wüstite (FeO), with minor magnetite (Fe3O4). The mineralogical composition indicates that slags were the product of copper smelting. The slag compositions and morphologies are analogous to slags described from the Oberhalbstein (Graubünden, Switzerland) and the Trentino Alps (Italy) which are attributed to metallurgical exploitations of the Late Bronze Age. While the origin of the ore could not be determined, it may be related to ore deposits of chalcopyrite in greenschists and serpentinites in the vicinity, such as Alp Tgavretga (Septimer Pass) and Val Perossa (Val Bregaglia).

AbstractPartially melted basalts enclosing amygdales which have been completely melted formed at Scawt Hill adjacent to a Tertiary dolerite plug. Melting of the basalts commenced in a clay-rich mesostasis to produce a feldspathic liquid which then crystallized to an assemblage of dendritic olivine, skeletal hypersthene, opaque oxide and Mg-hercynite in a microcrystalline plagioclase matrix. An original mineral assemblage of zeolite, calcite, and saponite-nontronite in the amygdales melted and quenched to a brown glass now containing complexly zoned pyroxenes with plagioclase and opaque oxide. Melting commenced between 700–800°C, reaching a maximum temperature of 1168°C, and was followed by rapid cooling. The assimilation of remelted basalt may alter the course of crystallization of contaminated magmas.

Abstract The c.3·3 Ga Commondale komatiites located south of the Barberton greenstone belt in the Kaapvaal Craton are different from other komatiites, possessing compositional and textural features unique to this occurrence. Unlike almost all other known komatiite occurrences, they are not associated with komatiitic basalts or basalts. The komatiite flows are 0·5–25 m thick and are made up of a marginal zone of spinifex-textured and fine-grained aphyric rocks (low-Mg group) and an inner zone of olivine cumulates (high-Mg group), arranged in such a way to give highly symmetrical compositional profiles for many flows. Olivine is the dominant phase in all rocks, but orthopyroxene occurs as spinifex and elongate laths in the marginal zone. Clinopyroxene and plagioclase are entirely absent. The olivine cumulates formed from Mg-rich magma (36·1% MgO, 6·8% FeO) which caused inflation of the thicker flows. The maximum observed olivine composition in cores (Fo 96·6) is the highest recorded for any komatiite worldwide. The high-Mg magma would have erupted at a temperature close to 1670°C, the highest inferred temperature for an anhydrous terrestrial lava. The marginal zone is enriched in incompatible elements compared with the inner zone and formed by fractionation of the parental melt. However, all rock-types in the marginal zone are depleted in FeO (some as low as 3·5%) which could not have been derived by any primary magmatic process. The marginal zone rocks were modified by assimilation and/or alteration by seawater (or brine) components causing migration of iron and strong enrichment of sodium (up to 1·6 wt % Na2O) and chlorine (up to 2400 ppm). Zirconium has an identical distribution to sodium, with both elements greatly enriched above what would result from fractional crystallization, and may result from speciation of these elements at high temperature followed by post-crystallization alteration. Rare earth elements, Y and Nb have contents commensurate with fractionation of the primitive parental magma. Dendritic-textured olivine-rich rocks with orthopyroxene spinifex spatially and compositionally transitional between the marginal zone and the olivine cumulates resulted from interaction of the high temperature parental magma in the centre of the flows with the fractionated melt at the flow margins. A further manifestation of this association is the development of highly regular fine-scale (5–15 cm) layering (up to 45 layers) of alternating olivine cumulate and spinifex near the base of thick flows. This is overlain by olivine cumulates in which the melt/crystal-mush became arranged into a 3-dimensional network controlled by re-distribution of the trapped melt manifest by a spectacular knobbly texture in outcrop. Over 200 flow units are recognized and detailed chemical and mineralogical studies were carried out on drill cores intersecting 375 m of stratigraphy. The parental magma was highly depleted (in ppm Nb 0·017, Zr 1·18, total REE 1·7 and Gd/YbN=0·3, La/YbN=0·038) and although generally regarded to fall into the rare category of Al-enriched komatiites (AEKs), it is considered that these lavas are a unique class of their own of ultra-depleted komatiites. Relative to other AEKs the Commondale komatiites are both enriched in Al as well as being markedly depleted in Ti (390 ppm), giving rise to the extremely high Al2O3/TiO2 (81). The high temperature and low viscosity of the magma resulted in emplacement processes previously unrecognized in komatiites. The primary melt was derived by melting of mantle peridotite in equilibrium with olivine and orthopyroxene. The initial source was depleted in incompatible elements by small degrees of melting (3–4%) followed by high degrees of partial melting (70%) of the subsequent refractory source at 5 GPa (∼150 km).

Les chondres, constituants principaux des chondrites sont des sphères silicatées ferromagnésiennes d'origine ignée. Ils résultent de la fusion plus ou moins totale de précurseurs solides au cours d'événements brefs de haute température, c'est-à-dire des pics thermiques suivis d'épisodes de refroidissement rapide. Les chondres sont des témoins directs de la formation du système solaire et leurs conditions thermiques (surchauffe, vitesse de refroidissement…) peut apporter des informations sur les contraintes thermiques de formation. Pour cela, des études expérimentales et pétrographiques détaillées ont été réalisées sur des chondres de différentes textures (macro-porphyrique, porphyrique et barré). Pour reproduire la texture macro-porphyrique (peu de grands cristaux d'olivine), le liquide chondritique doit subir un épisode de surchauffe (au-dessus de la température liquidus) afin de réduire la nucléation et, être suivie par un refroidissement lent (quelques °C/h) afin de former les larges olivines présentant les lacunes de cristallisation caractéristiques. Les chondres macro-porphyriques n'ont pas la même histoire thermique que les chondres porphyriques qui ont été initialement moins chauffés (sous leurs températures liquidus). En revanche, les chondres macro-porphyriques et barrés sont issus d'un épisode de surchauffe. Une étude pétrographique et expérimentale sur les textures barrées confirme cette analogie. Les observations réalisées sur les textures barrées ont permis de proposer un modèle 3D de ces objets complexes mais aussi un modèle de formation des chondres barrés où les bordures irrégulières -permettant des interactions gaz/liquide- se forment en même temps que les barres-dendrites muries. Une étude sur le comportement des Terres Rares (REE) entre l'olivine et le liquide a été réalisée lors d'expériences dynamiques à taux de refroidissement (2-1000°C/h) et paliers variables. Un haut taux de cristallisation (composition, tempéra ture de trempe basse, long palier) ou un taux de refroidissement lent favorisent un coefficient de partage bas entre l'olivine et le liquide (Kd). Toutefois, un taux de refroidissement très lent peut entraîner, par retard à la nucléation, des croissances initiales rapides ayant pour conséquence un enrichissement des olivines en REE et un Kdolivine-liquide variable
Chondrules are the main constituents of chondrites and are ferromagnesian silicate spherules of igneous origin. Chondrules result from the more or less complete melting of solid precursors during brief high temperature events, i.e., thermal peaks followed by episodes of rapid cooling. Chondrules are direct witnesses of the formation of the Solar System and the thermal conditions of their formation (superheating, cooling rate, etc.) can provide invaluable information on the formation. In order to provide their constraints, detailed experimental and petrographic studies were carried out on chondrules exhibiting different textures (macro-porphyritic, porphyritic and barred). To reproduce the macro-porphyritic texture (few large olivine crystals), the chondritic liquid must undergo a superheating episode (above the liquidus temperature) in order to reduce the number of nucleation sites and followed by an episode of slow cooling (a few °C/h) to form the large olivines and their peculiar embayments. Thus, the macro-porphyritic chondrules do not have the same thermal history than the porphyritic chondrules which were initially less heated (below their liquidus temperatures). On the other hand, the macro-porphyritic and barred chondrules come from a superheating episode. Petrographic and experimental studies on barred textures confirm this analogy. From the observations on the barred textures, a 3D model is proposed for the formation of these various complex objects. In particular, this model accounts for the formation of barred chondrules, where the irregular borders –due to gas/liquid interactions- are formed at the same time as the bars - ripened dendrites. A study on the behavior of Rare Earth Elements (REE) between olivine and liquid was carried out during dynamic experiments, using different cooling rates (2-1000°C/h) and dwell time (direct quench or long dwell). A high crystallization rate (composition, low quenching temperature, long dw ell) or a slow cooling rate favors a low partition coefficient (Kd) between the olivine and the liquid. In turn, a very slow cooling rate can lead to a delay in nucleation, to fast initial growths resulting in an enrichment of olivines in REE and variable Kdolivine-liquid