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Статті в журналах з теми "Cyclometallates"

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Автор: Grafiati

Опубліковано: 18 травня 2024

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1

Tan, Gui Ping, Hong Bo Fan, and Wai Yeung Wong. "Synthesis and Photophysical Properties of Charged Iridium(III) Cyclometallates Based on Hole-Transporting Carbazole Unit." Applied Mechanics and Materials 633-634 (September 2014): 314–19. http://dx.doi.org/10.4028/www.scientific.net/amm.633-634.314.

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Four novel charged Ir (III) cyclometallates based on 9-phenylcarbazole unit have been developed. By attaching isoquinoline or 5-trifluoromethylpyridine group, the light-emitting properties of the resulting Ir (III) cyclometallates have been improved. Meanwhile, 1,10-phenanthroline or 4,4′-dimethyl-2,2′-bipyridine has been utilized to modify the thermal stability. The four Ir (III) cyclometallates emit yellow light with the highest photoluminescence quantum yields (ΦP) of 0.32 (C4), which is only less than that of the state-of-art complexfac-tris (2-phenylpyridine) iridium (III) [fac-Ir (ppy)3], which showsΦPof 0.40 under the same condition. This inspiring result reveals that the bulky character of CF3group enhances the performance of reported charged Ir (III) cyclometallates and makes them to be potential phosphors in OLED applications.

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2

Téllez, Juan, Albert Gallen, Joaquina Ferrer, Fernando J. Lahoz, Pilar García-Orduña, Antoni Riera, Xavier Verdaguer, Daniel Carmona, and Arnald Grabulosa. "Half-sandwich complexes of Ir(iii), Rh(iii) and Ru(ii) with the MaxPhos ligand: metal centred chirality and cyclometallation." Dalton Transactions 46, no. 45 (2017): 15865–74. http://dx.doi.org/10.1039/c7dt03327c.

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3

Tan, Guiping, Shuming Chen, Chi-Ho Siu, Adam Langlois, Yongfu Qiu, Hongbo Fan, Cheuk-Lam Ho, et al. "Platinum(ii) cyclometallates featuring broad emission bands and their applications in color-tunable OLEDs and high color-rendering WOLEDs." Journal of Materials Chemistry C 4, no. 25 (2016): 6016–26. http://dx.doi.org/10.1039/c6tc01594h.

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Анотація:

Two new phosphorescent platinum(ii) cyclometallates with flexible phenoxy moieties were prepared whose broad excimeric emissive states in the solid state allow the fabrication of high color-rendering two-emitter WOLEDs.

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4

Chakladar, Sukla, Parimal Paul, and Kamalaksha Nag. "Organodipalladium(II) cyclometallates of the schiff base N,N′-diethyl-2,6-dialdiminobenzene." Polyhedron 10, no. 13 (January 1991): 1513–19. http://dx.doi.org/10.1016/s0277-5387(00)86074-x.

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5

Barucki, Hubert, Simon J. Coles, James F. Costello, and Michael B. Hursthouse. "Synthesis and structure of organoantimony (V) cyclometallates: transannular interactions and the barrier to cyclisation." Journal of Organometallic Chemistry 622, no. 1-2 (March 2001): 265–73. http://dx.doi.org/10.1016/s0022-328x(00)00923-2.

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6

lal Pratihar, Jahar, Debprasad Patra, and Surajit Chattopadhyay. "Syntheses, characterization, structure and redox properties of new Rh(III) cyclometallates incorporating azoimine ligands." Journal of Organometallic Chemistry 690, no. 21-22 (November 2005): 4816–21. http://dx.doi.org/10.1016/j.jorganchem.2005.07.076.

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7

Nagaraju, Koppanathi, and Samudranil Pal. "Ruthenium(III) cyclometallates: Regioselective metallation of 1-pyrenyl in 1-pyrenaldehyde 4-R-benzoylhydrazones." Journal of Organometallic Chemistry 737 (August 2013): 7–11. http://dx.doi.org/10.1016/j.jorganchem.2013.03.040.

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8

Babu, G. Narendra, and Samudranil Pal. "Mono- and dinuclear palladium(II) cyclometallates with 4-R-N'-(mesitylidene)benzohydrazides and mono- and diphosphines." Journal of Organometallic Chemistry 805 (March 2016): 19–26. http://dx.doi.org/10.1016/j.jorganchem.2016.01.003.

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9

Narayan Biswas, Achintesh, Purak Das, Sandip Sengupta, Amitava Choudhury, and Pinaki Bandyopadhyay. "C(naphthyl)–H bond activation by rhodium: isolation, characterization and TD-DFT study of the cyclometallates." RSC Advances 1, no. 7 (2011): 1279. http://dx.doi.org/10.1039/c1ra00572c.

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10

Chattopadhyay, Surajit, Chittaranjan Sinha, Partha Basu, and Animesh Chakravorty. "Chemistry of platinum(IV), platinum(II) and palladium(II) cyclometallates of benzylthio- or benzosulphinyl-substituted azobenzenes." Journal of Organometallic Chemistry 414, no. 3 (August 1991): 421–31. http://dx.doi.org/10.1016/0022-328x(91)86340-v.

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11

Sanner, Robert D., Nerine J. Cherepy, Hung Q. Pham, and Victor G. Young. "Phosphorescent heteroleptic iridium(III) cyclometallates: Improved syntheses of acetylacetonate complexes and quantum chemical studies of their excited state properties." Polyhedron 176 (January 2020): 114256. http://dx.doi.org/10.1016/j.poly.2019.114256.

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12

Zucca, Antonio, Giacomo Luigi Petretto, Maria Luisa Cabras, Sergio Stoccoro, Maria Agostina Cinellu, Mario Manassero, and Giovanni Minghetti. "N^N^C platinum(II) and palladium(II) cyclometallates of 6,6′-diphenyl-2,2′-bipyridine, L: Crystal and molecular structure of [Pd(L–H)Cl]." Journal of Organometallic Chemistry 694, no. 23 (November 2009): 3753–61. http://dx.doi.org/10.1016/j.jorganchem.2009.07.034.

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13

Phillips, Ian G., and Peter J. Steel. "Cyclometallated compounds." Journal of Organometallic Chemistry 410, no. 2 (June 1991): 247–55. http://dx.doi.org/10.1016/0022-328x(91)80010-h.

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14

Steel, Peter J. "Cyclometallated compounds." Journal of Organometallic Chemistry 408, no. 3 (May 1991): 395–402. http://dx.doi.org/10.1016/0022-328x(91)83210-u.

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15

Perera, Sarath D. "Syntheses of Au(III) and Au(I) Complexes of 3,4,5,6-Tetraphenyl-2,2´-bipyridine." OUSL Journal 18, no. 1 (September 7, 2023): 85–98. http://dx.doi.org/10.4038/ouslj.v18i1.7600.

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Анотація:

Treatment of the ligand 3,4,5,6-tetraphenyl-2,2´-bipyridine (LH) VIII with HAuCl4 in acetonitrile afforded the cyclometallated square-planar Au(III) complex [LAuCl]ClO4 (7) containing the anionic tridentate (N∧N∧C) ligand, via orthometallation. Treatment of (7) with 4-dimetylaminopyridine (DMAP) and AgClO4 in acetonitrile produced [LAu(DMAP)][ClO4]2 (8), showing the same coordination mode. Analogous complex [LAu(PPh3)][ClO4]2 (9)was prepared by using PPh3 instead of DMAP. Reaction of VIIIwith HAuCl4 at room temperature in aqueous acetonitrileresulted the non-cyclometallated Au(III) complex [(LH)AuCl2]Cl(10), in which VIII is a bidentate (N∧N) ligand. Treatment of VIIIwith the filtrate obtained by mixing [AuCl(PPh3)] and AgO2CCF3 in acetone resulted the non-cyclometallated Au(I) complex[(LH)Au(PPh3)]O2CCF3 (11) having bidentate (N∧N) ligand. Abovecomplexes were adequately characterized by a combination ofelemental analysis, IR, Mass and NMR spectroscopy. The X-raycrystal structures of (7) and (8) were determined.

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16

Slater, Jonathan W., and Jonathan P. Rourke. "Cyclometallated nitrogen heterocycles." Journal of Organometallic Chemistry 688, no. 1-2 (December 2003): 112–20. http://dx.doi.org/10.1016/j.jorganchem.2003.08.038.

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17

O'Keefe, Brendan J., and Peter J. Steel. "Cyclometallated compounds. XV." Acta Crystallographica Section C Crystal Structure Communications 56, no. 12 (December 15, 2000): 1440–41. http://dx.doi.org/10.1107/s0108270100011768.

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18

de Geest, Duncan J., and Peter J. Steel. "Cyclometallated compounds XII. Syntheses of two new doubly-cyclometallated compounds." Inorganic Chemistry Communications 1, no. 9 (September 1998): 358–60. http://dx.doi.org/10.1016/s1387-7003(98)00097-5.

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19

Ionescu, Andreea, Iolinda Aiello, Alessandra Crispini, and Nicolas Godbert. "Thin Film Electrodeposition of Ir(III) Cyclometallated Complexes." Journal of Chemistry 2016 (2016): 1–7. http://dx.doi.org/10.1155/2016/2856973.

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Анотація:

Novel electropolymerizable Ir(III) cyclometallated complexes have been synthesized and characterized. In these complexes the cyclometallated ligands are either 2-phenylpyridineH(PhPy) or benzothiazole-triphenylamineH(BzTh-tpa), while the Ir(III) coordination sphere is completed by a Schiff base substituted with a triphenylamine fragment. A complete electrochemical study has been conducted on all complexes, in order to verify the feasibility of electropolymerization and to elucidate the role of the specific position of the triphenylamine moiety in the molecular structure. Homogeneous thin films of Ir(III) metallopolymers have been successfully obtained through electropolymerization process.

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20

Maity, Ayan, Jonas C. Kölsch, Hanah Na, and Thomas S. Teets. "Room temperature transmetallation from tris(pentafluorophenyl)borane to cyclometallated iridium(iii)." Dalton Transactions 46, no. 35 (2017): 11757–67. http://dx.doi.org/10.1039/c7dt02540h.

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21

Santana, M. D., L. López-Banet, G. Sánchez, J. Pérez, E. Pérez, L. García, J. L. Serrano, and A. Espinosa. "Non-covalent stacking interactions directing the structural and photophysical features of mono- and dinuclear cyclometalated palladium(ii) complexes." Dalton Transactions 45, no. 20 (2016): 8601–13. http://dx.doi.org/10.1039/c5dt04913j.

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22

Solé, Mònica, Cristina Balcells, Margarita Crespo, Josefina Quirante, Josefa Badia, Laura Baldomà, Mercè Font-Bardia, and Marta Cascante. "Synthesis, characterization and biological activity of new cyclometallated platinum(iv) complexes containing a para-tolyl ligand." Dalton Transactions 47, no. 27 (2018): 8956–71. http://dx.doi.org/10.1039/c8dt01124a.

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23

Liguori, Paola Francesca, Mauro Ghedini, Massimo La Deda, Nicolas Godbert, Francesco Parisi, Rita Guzzi, Andreea Ionescu, and Iolinda Aiello. "Electrochromic behaviour of Ir(iii) bis-cyclometalated 1,2-dioxolene tetra-halo complexes: fully reversible catecholate/semiquinone redox switches." Dalton Transactions 49, no. 8 (2020): 2628–35. http://dx.doi.org/10.1039/c9dt04848k.

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24

Williams, Morwen R. M., Benoît Bertrand, David L. Hughes, Zoë A. E. Waller, Claudia Schmidt, Ingo Ott, Maria O’Connell, Mark Searcey, and Manfred Bochmann. "Cyclometallated Au(iii) dithiocarbamate complexes: synthesis, anticancer evaluation and mechanistic studies." Metallomics 10, no. 11 (2018): 1655–66. http://dx.doi.org/10.1039/c8mt00225h.

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25

Shaw, Paul A., Guy J. Clarkson, and Jonathan P. Rourke. "Reversible C–C bond formation at a triply cyclometallated platinum(iv) centre." Chemical Science 8, no. 8 (2017): 5547–58. http://dx.doi.org/10.1039/c7sc01361b.

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26

Damas, Aurelie, Hugo Sesolis, Marie Noelle Rager, Lise Marie Chamoreau, Maria Pia Gullo, Andrea Barbieri та Hani Amouri. "Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties". RSC Adv. 4, № 45 (2014): 23740–48. http://dx.doi.org/10.1039/c4ra01185f.

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27

von Wachenfeldt, Henrik, Alexey V. Polukeev, Nagarajan Loganathan, Filip Paulsen, Philipp Röse, Marion Garreau, Ola F. Wendt, and Daniel Strand. "Cyclometallated gold(iii) aryl-pyridine complexes as efficient catalysts for three-component synthesis of substituted oxazoles." Dalton Transactions 44, no. 12 (2015): 5347–53. http://dx.doi.org/10.1039/c4dt03806a.

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28

Salvadó, Iria, Ilaria Gamba, Javier Montenegro, José Martínez-Costas, Jose Manuel Brea, María Isabel Loza, Miguel Vázquez López, and M. Eugenio Vázquez. "Membrane-disrupting iridium(iii) oligocationic organometallopeptides." Chemical Communications 52, no. 73 (2016): 11008–11. http://dx.doi.org/10.1039/c6cc05537k.

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29

Kumar, George Rajendra, Santosh Kumar Behera, and Pakkirisamy Thilagar. "Room temperature phosphorescent triarylborane functionalized iridium complexes." Dalton Transactions 48, no. 20 (2019): 6817–23. http://dx.doi.org/10.1039/c9dt00590k.

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30

Lázaro, Ariadna, Oriol Serra, Laura Rodríguez, Margarita Crespo, and Mercè Font-Bardia. "Luminescence studies of new [C,N,N′] cyclometallated platinum(ii) and platinum(iv) compounds." New Journal of Chemistry 43, no. 3 (2019): 1247–56. http://dx.doi.org/10.1039/c8nj05492d.

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31

Zheng, Feng, Alan T. Hutton, Cornelia G. C. E. van Sittert, Wilhelmus J. Gerber, and Selwyn F. Mapolie. "Cyclometallated platinum(ii) complexes of benzylidene-2,6-di-isopropylphenylamine containing bidentate phosphines: synthesis, structural properties and reactivity studies." Dalton Transactions 44, no. 4 (2015): 1969–81. http://dx.doi.org/10.1039/c4dt02375g.

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32

Boreham, Elizabeth M., Lucy Jones, Adam N. Swinburne, Mireille Blanchard-Desce, Vincent Hugues, Christine Terryn, Fabien Miomandre, Gilles Lemercier, and Louise S. Natrajan. "A cyclometallated fluorenyl Ir(iii) complex as a potential sensitiser for two-photon excited photodynamic therapy (2PE-PDT)." Dalton Transactions 44, no. 36 (2015): 16127–35. http://dx.doi.org/10.1039/c5dt01855b.

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33

Chen, Qixiang, Sujitraj Sheth, Yuan Zhao, and Qijun Song. "A novel cyclometallated iridium(iii) complex based dual-mode phosphorescent probe for detection of acidity and bovine serum albumin." Analytical Methods 11, no. 23 (2019): 3033–40. http://dx.doi.org/10.1039/c9ay00878k.

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34

Bauer, Emma, Xavier Domingo, Cristina Balcells, Ibrahim H. Polat, Margarita Crespo, Josefina Quirante, Josefa Badía, Laura Baldomà, Mercè Font-Bardia, and Marta Cascante. "Synthesis, characterization and biological activity of new cyclometallated platinum(iv) iodido complexes." Dalton Transactions 46, no. 43 (2017): 14973–87. http://dx.doi.org/10.1039/c7dt03448b.

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35

Kalaiarasi, G., S. Rex Jeya Rajkumar, S. Dharani, Frank R. Fronczek, M. S. A. Muthukumar Nadar, and R. Prabhakaran. "Cyclometallated ruthenium(ii) complexes with 3-acetyl-2[H]-chromene-2-one derived CNS chelating ligand systems: synthesis, X-ray characterization and biological evaluation." New Journal of Chemistry 42, no. 1 (2018): 336–54. http://dx.doi.org/10.1039/c7nj02877f.

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36

Tripathy, Suman Kumar, Umasankar De, Niranjan Dehury, Paltan Laha, Manas Kumar Panda, Hyung Sik Kim, and Srikanta Patra. "Cyclometallated iridium complexes inducing paraptotic cell death like natural products: synthesis, structure and mechanistic aspects." Dalton Transactions 45, no. 38 (2016): 15122–36. http://dx.doi.org/10.1039/c6dt00929h.

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37

Huang, Chao, Guoxia Ran, Yuan Zhao, Chan Wang, and Qijun Song. "Synthesis and application of a water-soluble phosphorescent iridium complex as turn-on sensing material for human serum albumin." Dalton Transactions 47, no. 7 (2018): 2330–36. http://dx.doi.org/10.1039/c7dt04676f.

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38

Kalaiarasi, G., S. Rex Jeya Rajkumar, S. Dharani, J. G. Małecki, and R. Prabhakaran. "An investigation on 3-acetyl-7-methoxy-coumarin Schiff bases and their Ru(ii) metallates with potent antiproliferative activity and enhanced LDH and NO release." RSC Advances 8, no. 3 (2018): 1539–61. http://dx.doi.org/10.1039/c7ra12104k.

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39

Bertrand, B., S. Spreckelmeyer, E. Bodio, F. Cocco, M. Picquet, P. Richard, P. Le Gendre, C. Orvig, M. A. Cinellu, and A. Casini. "Exploring the potential of gold(iii) cyclometallated compounds as cytotoxic agents: variations on the C^N theme." Dalton Transactions 44, no. 26 (2015): 11911–18. http://dx.doi.org/10.1039/c5dt01023c.

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40

Murata, K., K. Saito, S. Kikuchi, M. Akita, and A. Inagaki. "Visible-light-controlled homo- and copolymerization of styrenes by a bichromophoric Ir–Pd catalyst." Chemical Communications 51, no. 26 (2015): 5717–20. http://dx.doi.org/10.1039/c5cc00611b.

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41

Barnett, Harrison J., and Anthony F. Hill. "Benzyne addition to a metal–carbon multiple bond." Dalton Transactions 50, no. 27 (2021): 9383–87. http://dx.doi.org/10.1039/d1dt01402a.

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42

Zhang, Yang, Qun Luo, Wei Zheng, Zhaoying Wang, Yu Lin, Erlong Zhang, Shuang Lü, Junfeng Xiang, Yao Zhao, and Fuyi Wang. "Luminescent cyclometallated platinum(ii) complexes: highly promising EGFR/DNA probes and dual-targeting anticancer agents." Inorganic Chemistry Frontiers 5, no. 2 (2018): 413–24. http://dx.doi.org/10.1039/c7qi00346c.

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43

Tabrizi, Leila, Bachir Zouchoune, and Abdallah Zaiter. "Experimental and theoretical investigation of cyclometallated platinum(ii) complex containing adamantanemethylcyanamide and 1,4-naphthoquinone derivative as ligands: synthesis, characterization, interacting with guanine and cytotoxic activity." RSC Advances 9, no. 1 (2019): 287–300. http://dx.doi.org/10.1039/c8ra08739c.

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44

Gao, Yafei, Qi Chen, Xuebing Leng, and Liang Deng. "Cyclometallation reactions of a three-coordinate cobalt(i) complex bearing a nonsymmetric N-heterocyclic carbene ligand." Dalton Transactions 48, no. 26 (2019): 9676–83. http://dx.doi.org/10.1039/c9dt00731h.

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45

Edwards, Gavin L., David St C. Black, Glen B. Deacon, and Laurence PG Wakelin. "Effect of charge and surface area on the cytotoxicity of cationic metallointercalation reagents." Canadian Journal of Chemistry 83, no. 6-7 (June 1, 2005): 969–79. http://dx.doi.org/10.1139/v05-110.

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Анотація:

Reaction of a series of nitrogen donor ligands (1-phenylpyrazoles, 2-phenylpyridine, benzo[h]quinoline, 1-(2′-pyridyl)indole, 1-phenylindazole, and 2-phenylindazole) with palladium(II) and platinum(II) salts gave complexes where ortho-metallation had occurred resulting in bidentate binding to the metal centres through N and C atoms. These cyclometallated products were isolated as µ-chloro dimers. Subsequent treatment of these µ-chloro dimers with chelating diamines such as 1,2-ethanediamine converted them into 14 cationic (1+) complexes. Analogous coordination mixed ligand complexes (charge 2+) were prepared by reaction of dichloro(1,2-ethanediamine-N,N′)palladium(II) with aromatic diamines such as 2-(1′-pyrazolyl)pyridine, 2,2′-bipyridine, and 1,10-phenanthroline. The complexes exhibited growth inhibitory activity against L1210 mouse leukæmia cells in vitro over a wide concentration range; in general, the cyclometallated complexes were more active than the mixed ligand complexes, although one cyclometallated organoplatinum complex was less active than the mixed ligand analogue. Substitution around the periphery of the aromatic ligands also resulted in increased activity. One complex, derived from 1-(2'-pyridyl)indole, was tested in vivo and showed no significant antitumour inhibition against P388 leukæmia at doses below toxic levels. Key words: anticancer, metallointercalator, cyclometallation, palladium, platinum, cytotoxicity.

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46

Zakis, Janis Mikelis, Tomas Smejkal, and Joanna Wencel-Delord. "Cyclometallated complexes as catalysts for C–H activation and functionalization." Chemical Communications 58, no. 4 (2022): 483–90. http://dx.doi.org/10.1039/d1cc05195d.

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47

Fontani, Mattia, Eleonora Garoni, Alessia Colombo, Claudia Dragonetti, Simona Fantacci, Henri Doucet, Jean-François Soulé, Julien Boixel, Véronique Guerchais та Dominique Roberto. "Novel cyclometallated 5-π-delocalized donor-1,3-di(2-pyridyl)benzene platinum(ii) complexes with good second-order nonlinear optical properties". Dalton Transactions 48, № 1 (2019): 202–8. http://dx.doi.org/10.1039/c8dt03622e.

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48

Zhou, Lihua, Fangfang Wei, Jingjing Xiang, Hongfeng Li, Chunbin Li, Pengfei Zhang, Chuangjun Liu, Ping Gong, Lintao Cai, and Keith Man-Chung Wong. "Enhancing the ROS generation ability of a rhodamine-decorated iridium(iii) complex by ligand regulation for endoplasmic reticulum-targeted photodynamic therapy." Chemical Science 11, no. 44 (2020): 12212–20. http://dx.doi.org/10.1039/d0sc04751a.

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49

Howarth, Ashlee J., Marek B. Majewski, Christopher M. Brown, Francesco Lelj, Michael O. Wolf, and Brian O. Patrick. "Emissive Ir(iii) complexes bearing thienylamido groups on a 1,10-phenanthroline scaffold." Dalton Transactions 44, no. 37 (2015): 16272–79. http://dx.doi.org/10.1039/c5dt02691a.

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Анотація:

Highly emissive cyclometallated Ir(iii) complexes bearing phenanthroline-based ancillary ligands are presented and the effect of tethered thiophene moieties on the photophysical properties is explored.

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50

Abedanzadeh, Sedigheh, Kazem Karami, Mostafa Rahimi, Masoud Edalati, Mozhgan Abedanzadeh, Ali mohammad Tamaddon, Maryam Dehdashti Jahromi, Zahra Amirghofran, Janusz Lipkowski та Krzysztof Lyczko. "Potent cyclometallated Pd(ii) antitumor complexes bearing α-amino acids: synthesis, structural characterization, DNA/BSA binding, cytotoxicity and molecular dynamics simulation". Dalton Transactions 49, № 42 (2020): 14891–907. http://dx.doi.org/10.1039/d0dt02304c.

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Анотація:

Synthesis, characterization, spectroscopic, biological, and molecular modeling studies on the DNA/BSA binding interactions of new cyclometallated Pd(ii) complexes bearing α-amino acids were investigated.

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