Дисертації з теми "Composite de caoutchouc naturel"
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Salaeh, Subhan. "Élaboration des composites et mélanges à base de caoutchouc naturel : relations structure - propriétés." Thesis, Lyon 1, 2014. http://www.theses.fr/2014LYO10141/document.
Повний текст джерелаNatural rubber (NR) and epoxidized natural rubber (ENR) were chosen to study the composites and blends of polymers. The presence of epoxide group caused to improve the mechanical properties in terms of modulus and tensile strength. Furthermore, dielectric spectroscopy revealed that ENR showed conductivity process at low frequency and high temperature. Epoxidized natural rubber containing 50 mol% of epoxide group or ENR-50 exhibited the highest dielectric permittivity and electrical conductivity. Therefore, ENR-50 was then selected to prepare polymer composite filled with barium titanate (BT) and carbon black (CB) particles. The permittivity and conductivity of the composites increased with the volume content of the fillers. The BT/ENR-50 composites reached a high permittivity of 4 8 . 7 for addition of 50 vol% BT. Meanwhile, CB/ENR-50 composite reached percolation threshold at 6. 3 vol% of CB. The phase development and miscibility of poly(vinylidene fluoride) (PVDF)/epoxidixed natural rubber (ENR) blends were then investigated. It was also found that phase structure depended on epoxidation level and blend compositions. The blend exhibited a co-continuous phase morphology in the region of 40 to 60 wt% of ENR-50. Furthermore, the results from dynamic mechanical and dielectric analysis revealed that these blends present a partial miscibility. Finally, the composites based on binary blends of PVDF/ENR-50 containing BT were prepared. The study of the morphologies revealed that BT was dispersed in ENR-50 phase in the case of simple blend. However, the addition of BT after dynamic vulcanization induced localization of BT in PVDF phase and at interface. The highest increment of permittivity can be observed for the composite based on dynamically cured PVDF/ENR-50 (80/20) blend
ศึกษาอิทธิพลของโครงสร้างโมกุลยางธรรมชาติ (NR) และยางธรรมชาติอิพอกไซด์ (ENR) ต่อสมบัติ พบว่าการมีหมู่อิพอกไซด์อยู่ในยาง ENR ทำให้มีการปรับปรุงสมบัติเชิงกล เช่น มอดุลัสและความต้านทานต่อแรงดึง นอกจากนี้สมบัติไดอิเล็กทริกได้แสดงให้เห็นถึงการนำ ไฟฟ้าที่ความถี่ต่ำและอุณหภูมิสูง ยางที่มีหมู่อิพอกไซด์ 50 โมล% (ENR-50) มีค่าการนำไฟฟ้า และค่า permittivity สูงที่สุด ดังนั้นจึงนำยาง ENR-50 ไปใช้ในการเตรียมคอมพอสิตที่ใช้แบเรียม ไททาเนตและเขม่าดำเป็นตัวเติม ซึ่งพบว่าค่า permittivity และค่าการนำไฟฟ้าสูงขึ้นตาม ปริมาณตัวเติมที่ใส่ลงไป ที่ปริมาณ 50%โดยปริมาตรของแบเรียมไททาเนตในยางให้ค่า permittivity สูงถึง 48.7 ในขณะเดียวกันก็พบว่าการเตรียม ENR-50 คอมพอสิตที่ใช้เขม่าดำมี percolation threshold ที่ 6.3 vol% ของเขม่าดำ สำหรับการศึกษาการเปลี่ยนแปลงของสัณฐาน วิทยาและความเข้ากันได้ของพอลิเมอร์เบลนด์ระหว่างพอลิไวนิลลิดีนฟลูออไรด์ (PVDF) กับยาง ENR พบว่า สัณฐานวิทยาของพอลิเมอร์ที่เตรียมได้ขึ้นอยู่กับปริมาณหมู่อิพอกไซด์ในยาง ENR และอัตราส่วนการเบลนด์ อัตราส่วนการเบลนด์ในช่วง 40 ถึง 60% โดยน้ำหนักของยาง ENR- 50 ให้ลักษณะสัณฐานวิทยาแบบวัฏภาคร่วม (co-continuous) นอกจากนี้ผลการทดสอบจาก สมบัติพลวัตเชิงกลและสมบัติไดอิเล็กทริกแสดงให้เห็นถึงความเข้ากันได้บางส่วน (partial miscibility) ท้ายที่สุดนี้ได้เตรียมคอมพอสิตจากพอลิเมอร์เบลนด์ที่เติมแบเรียมไททาเนต สัณฐานวิทยาของคอมโพสิทที่เตรียมได้นั้น พบว่าแบเรียมไททาเนตกระจายตัวในเฟสยางเป็น หลัก อย่างไรก็ตามการเติมแบเรียมไททาเนตหลังจากการวัลคาไนซ์แบบไดนามิกส์ทำให้ แบเรียมไททาเนตกระจายตัวในเฟสพอลิไวนิลลิดีนฟลูออไรด์ (PVDF) และที่ผิวประจัญ (interface) นอกจากนี้คอมพอสิตที่เตรียมจากเทอร์โมพลาสติกวัลคาไนซ์ของ PVDF/ENR 50 ที่ อัตราส่วนการเบลนด์ที่ 80/20 ให้ค่า permittivity ที่สูง
Nozet, Quentin. "Structure et propriétés de matériaux composites obtenus par hétérocoagulation de latex de caoutchouc naturel et de noir de carbone." Electronic Thesis or Diss., Université Paris sciences et lettres, 2020. http://www.theses.fr/2020UPSLS033.
Повний текст джерелаThis thesis investigates the storage hardening of natural rubber and carbon black composites made by heterocoagulation. Heterocoagulation is a process that consists in injecting a carbon black slurry at high speed into a colloidal suspension of natural rubber. We obtain a squishy and highly hydrated material that is subsequently dried and processed using an internal mixer or a mechanical press. The hardening is characterized using various rheological techniques among which torsional rheology and Mooney viscosimetry. Many parameters are investigated: the processing technique, the storage environment, the presence of residual water, temperature, the carbon black content. We define characteristic times of hardening whose temperature dependence indicates that the hardening results from a activated process. The energies of activation are nearly independent of the experimental parameters and compare well to that found in natural rubber. Swelling experiments in good solvent show that hardening is associated with the buildup of an interconnected network of macromolecules. We discuss the origin of this network in relation with the microstructure of natural polyisoprene and the presence of phospholipids and proteins
Schneider, Michael. "Renforcement de polymeres avec des particules composites de latex a base de caoutchouc naturel." Université Louis Pasteur (Strasbourg) (1971-2008), 1995. http://www.theses.fr/1995STR13216.
Повний текст джерелаAgrebi, Fatma. "Étude des propriétés diélectriques, thermiques et vibrationnelles de matériaux nano-composites à base du caoutchouc naturel renforcés par des nano-renforts cellulosiques." Thesis, Amiens, 2018. http://www.theses.fr/2018AMIE0001/document.
Повний текст джерелаNatural rubber isolated from Hevea Brasiliens and reinforced with different percentages of cellulose nano-reinforcements was investigated using three characterization techniques: Differential Scanning Calorimetry analysis, Dielectric Spectroscopy and finally Infrared and Raman Spectroscopy. The aim of the research is to understand the impact of cellulosic nano-reinforcements with different shapes and mass fractions in order to choose the nano-composite with high performance for mechanical applications
Agrebi, Fatma. "Étude des propriétés diélectriques, thermiques et vibrationnelles de matériaux nano-composites à base du caoutchouc naturel renforcés par des nano-renforts cellulosiques." Electronic Thesis or Diss., Amiens, 2018. http://www.theses.fr/2018AMIE0001.
Повний текст джерелаNatural rubber isolated from Hevea Brasiliens and reinforced with different percentages of cellulose nano-reinforcements was investigated using three characterization techniques: Differential Scanning Calorimetry analysis, Dielectric Spectroscopy and finally Infrared and Raman Spectroscopy. The aim of the research is to understand the impact of cellulosic nano-reinforcements with different shapes and mass fractions in order to choose the nano-composite with high performance for mechanical applications
Kampioti, Aikaterini. "Nanocarbon from food waste : dispersions and applications." Thesis, Bordeaux, 2016. http://www.theses.fr/2016BORD0364/document.
Повний текст джерелаThis PhD thesis is focused on the characterization, dispersion and applications of graphitic material (in this manuscript referred as carbon nanopuck (CNP)) that derives from the splitting of biogas and obtained within the framework of the European project “PlasCarb”. This study starts with CNP characterization. Afterwards, well-defined, high concentrated CNP dispersions in water, calibrated insize have been obtained. These dispersions have been used to prepare conductive films and as components of conductive composites with natural rubber. Ultimately, the photoluminescence of CNP dispersed and dissolved in liquid media has been tested. Preliminary tests of these systems exhibit promising blue PL
Longkaew, Khansinee. "Preparation of calcium carbonate particles for application in natural rubber composites." Electronic Thesis or Diss., Le Mans, 2024. https://cyberdoc-int.univ-lemans.fr/Theses/2024/2024LEMA1003.pdf.
Повний текст джерелаThis research aims to synthesize different types and shapes of calcium carbonate (CaCO3) particles at a submicrometric and nanoscale, and investigate their applications as reinforcing fillers for natural rubber (NR) composites. The study was therefore divided into two parts. Firstly, the preparation procedure of CaCO3 particles was based on the solution precipitation method between carbonate ions and calcium ions. The second part focused on investigating the mechanical properties of NR/CaCO3 composites. The first part started with the precipitation of (NH4)2CO3 and CaCl2 dissolved in 50% by weight of sucrose as the aqueous medium. This condition resulted in spherical CaCO3 with particle size of 0.42±0.14 µm with an aspect ratio of about one. When the precipitation reaction occurred in the presence of olive soap, the surface property of the CaCO3 was changed from hydrophilic (water contact angle of 28±2o) to superhydrophobic powders (water contact angle of 163±2o). The typical polymorphic phases of CaCO3 were characterized. The results revealed that both untreated and treated spherical CaCO3 were about 99% of the vaterite polymorph. In the precipitation process using Na2CO3 and CaCl2 aqueous solutions performed at 80±1C, bundle-liked CaCO3 was obtained with an aspect ratio in the range of 8–9. The superhydrophobic bundle-liked CaCO3 was also successfully synthesized by soap treatment. The water contact angle of untreated and treated bundle-liked are 29±2o, and 167±2o, respectively. Furthermore, the spherical CaCO3 dispersed in water at 80C resulted in the fiber-shaped CaCO3 nanoparticles which were achieved via the polymorph transformation from spherical vaterite to long nano-wired aragonite with the highest aspect ratio of 156.9. The untreated fiber CaCO3 was hydrophilic with a water contact angle of 31±1o, while the treated fiber CaCO3 with soap resulted in 165±5o of water contact angle, hence it was superhydrophobic similar to other synthesized CaCO3 polymorphs. The XRD revealed that the untreated and treated bundle-liked and fiber-shaped CaCO3 contained the majority of aragonite followed by vaterite and calcite polymorphs. The second part was carried out to incorporate the prepared CaCO3 (0,5,10,20,40,60 phr) in NR latex. It was found that the CaCO3 polymorphs were stable in the NR latex medium. The mechanical properties of NR/CaCO3 included tensile strength, elongation at break, tear strength, and hardness Shore A. It was found that the tensile strength of NR/CaCO3 composites increased when CaCO3 loading was increased. The tensile strength of NR improved from 22.68±2.22 MPa of neat NR up to 23.94±0.97 MPa when untreated spherical CaCO3 powders (20 phr) were added, and to 25.28±0.80 MPa of treated spherical CaCO3 (20 phr) filled NR. The maximum tensile strength of NR/untreated bundle-liked CaCO3 was 30.59±3.50 MPa at 40 phr of loading while 31.51±1.02 MPa of NR/treated bundle-liked CaCO3 at filler loading 20 phr was obtained. The treated CaCO3-filled NR vulcanizates gave higher tensile strength than the untreated ones. This was caused by better compatibility of filler dispersion between the hydrophobicity of treated CaCO3 and hydrophobic property of NR. As a result, it was found that the NR filled with untreated fiber CaCO3 particle provided the highest tensile strength of 31.66±1.80 MPa at 10 phr of filler loading, over other types of CaCO3. The nanoparticle, large surface area, and high aspect ratio of fiber/ long nano wired of CaCO3 enhanced the interfacial adhesion between CaCO3 and NR matrix which could transfer stress from rubber to filler effectively during stretching. This resulted in the reinforcing efficacy of the fiber CaCO3. In summaroze, the prepared CaCO3 powders have the potential to broaden their application not only as diluents or additives but also as reinforcing agents
Hariwongsanupab, Nuttapong. "Development of green natural rubber composites : Effect of nitrile rubber, fiber surface treatment and carbon black on properties of pineapple leaf fiber reinforced natural rubber composites." Thesis, Mulhouse, 2017. http://www.theses.fr/2017MULH0399/document.
Повний текст джерелаThe effects of nitrile rubber (NBR), fiber surface treatment and carbon black on properties of pineapple leaf fiber-reinforced natural rubber composites (NR/PALF) were studied. The incorporation of NBR and surface treatment of fiber were used to improve the mechanical properties of composites at low deformation, whereas carbon black was used to improve these properties at high deformation. The fiber content was fixed at 10 phr. The composites were prepared using two-roll mill and were cured using compression moulding with keeping the fiber orientation. These composites were characterized using moving die rheometer (MDR), dynamic mechanical thermal analysis (DMTA) and tensile testing. The morphology after cryogenic fracture was observed using scanning electron microscopy (SEM). The effect of NBR from 0 to 20 phr of total rubber content was investigated. NBR is proposed to encase PALF leading to higher stress transfer between matrix and PALF. The method of mixing was also studied. For the fiber surface treatment, propylsilane, allylsilane and silane-69 were treated on the alkali-treated fiber. Treated fibers were characterized using Fourier-Transform infrared spectroscopy (FTIR), x-ray photoelectron spectroscopy (XPS) and SEM. Silane-69 treatment of fiber increased the modulus at low deformation more than the incorporation of NBR of NR/PALF composites due to the chemical crosslinking between rubber and fiber from silane-69 treatment rather than the physical interaction of NR, NBR and fiber. However, reinforcement by fiber reduced the deformation at break. Hence, carbon black was also incorporated into NR/NBR/PALF and NR/surface-treated PALF composites to improve the ultimate properties. By incorporation of carbon black 30 phr in both composites, the mechanical properties of composites were improved and can be controlled at both low and high deformations
Taranamai, Phruedsaporn. "Study of Polymer/Silver-Zeolite Composites For Anti-Microbial Applications." Thesis, Le Mans, 2019. http://www.theses.fr/2019LEMA1021.
Повний текст джерелаThe aim of this work is to prepare antibacterial polymers composites, involving especially poly(lactic acid) (PLA) and epoxidized natural rubber (ENR) in the presence of silver-substituted zeolites (AgZ) as an active ingredient. Herein, the key to control the antibacterial activity of the composites which is the water absorption characteristic was thoroughly studied. In general, the fabrication of antibacterial PLA composites encounters with the problem relating to the poor hydrophilicity of PLA which is the cause of antibacterial ineffectiveness. To enhance the antibacterial activity of the composites, blending with the second polymer having high polarity and flexibility is a promising way to produce the antibacterial AgZ/PLA composite. Herein, epoxidized natural rubber (ENR) was selected to blend with AgZ/PLA composites and the increase in the water absorption percentage could be observed. The morphology as well as the AgZ distribution in the composites were also investigated. The remarkable enhancement of antibacterial activity of ENR/AgZ/PLA composites was observed because more than 98-99% inhibition of S. aureus growth was found. Furthermore, the effects of rubber content and amount of AgZ on the antibacterial activity of the composites were investigated. Moreover, the ENR/AgZ/PLA composites possessed the higher impact resistance compared to neat PLA, suggesting that the improved composites might be a choice in applications at which both antibacterial activity and impact resistance property are of great importance
Daoud, Hajer. "Contribution à l'étude du comportement mécanique et vibratoire des composites biosourcés incorporant des matériaux fonctionnels." Thesis, Le Mans, 2018. http://www.theses.fr/2018LEMA1017/document.
Повний текст джерелаThis thesis focuses on the study of the mechanical and vibration behaviour of a flax fibre reinforced composites with and without an interleaved natural viscoelastic layer. The composite materials have been characterized experimentally using different mechanical and vibrational tests. First, both types of composites were studied using uni-axial tensile and three-points bending tests. Acoustic emission (AE) has been often used for the identification and characterization of micro failure mechanisms in composites. The results showed that these composites have very high specific characteristics. It can be used for applications currently using composites reinforced with synthetic fibres such glass, carbon…. Next, experimental and finite element vibration analyses were carried out on the composites with and without an interleaved natural viscoelastic layer. A good agreement between the two methods was obtained. It has been shown that the viscoelastic layer plays a major role in damping because it has a high level of energy dissipation. Therefore, it improves with a significant way the modal properties of the composite. Finally, nonlinear resonance tests were performed on the composites. It has been shown that the viscoelastic layer generates a nonlinear behaviour in the material. The linear and nonlinear, elastic and dissipative parameters have been calculated to deduce finally that nonlinear parameters are more sensitive to heterogeneities than those derived from linear vibration tests
Tran, Thi Nguyet. "Bio-based elastomeric composites for antibacterial and antifouling applications : methodology for the synthesis and grafting of functionalized oligomers issued from natural rubber." Thesis, Le Mans, 2018. http://www.theses.fr/2018LEMA1024/document.
Повний текст джерелаThis manuscript presents the synthesis of new elastomeric materials based on natural rubber derived building blocks and organic monomers having antifouling and/or antibacterial properties, covalently bound to the polymer network. Original acrylate monomers bearing an organic bioactive moiety (a Guanidinium group or Zosteric acid derivates) were synthesized and co-polymerized with telechelic acrylate oligomers from polyisoprene. No significant leaching of the bioactive monomers occurred and the material resisted to long water immersions. Freestanding films prepared from acrylate oligoisoprenes also showed a weak antibiofouling activity which was drastically increased by integrating the guanidinium and the Zosteric acid monomers. The coatings were active against several strains of pathogenic bacteria among which Pseudomonas aeruginosa, Staphylococcus aureus, Bacillus subtilis and Staphylococcus epidermidis. In order to covalently graft oligoisoprenes to surfaces, new bifunctional oligoisoprenes bearing an alkoxy-silane end moiety were designed and coupled with silicon-containing materials. An alternative approach was followed by prefunctionalizing the surface with amino groups and by covalently grafting oligomers with carbonyl chain-ends. Post-polymerization from the surface free chain-ends resulted in a thick oligoisoprene coating with strong resistance to solvent immersion (water, THF). In this way, we were able to build dense and tethered molecular layers, thin films and thick coatings
Xie, Zhong Jian. "Effet élastocalorique dans le caoutchouc naturel." Thesis, Lyon, 2016. http://www.theses.fr/2016LYSEI025/document.
Повний текст джерелаIn this thesis, we aimed to study the eC effect of natural rubber (NR) and to prove its potential to act as an eC material primarily. The method for improving the eC effect efficiency and fatigue life of NR were also proposed. The eC effect of NR is characterized directly, and interpretation based on the theory of strain-induced crystallization/crystallite (SIC) is proposed. The eC adiabatic temperature change and isothermal entropy change of NR can be up to 9 K and 50 kJ.m-3.K-1 (56 J.kg-1.K-1), which are larger than most of caloric materials. Two coefficients, eC strain coefficient and eC stress coefficient , are defined for evaluating the eC performance at different strains, where is the specific entropy, is the engineering strain, is the temperature and is the stretching stress. It’s found that both coefficients are maximum for a strain around 4.5, indicating that the highest eC performance occurred at middle strain, which is attributed to the occurrence of SIC. To improve the eC performance, it is proposed to apply a pre-strain, so that the low strain regime where eC performance is low can be skipped. Moreover, the large needed deformation can be reduced by the pre-strain and thus the possibility of a compact cooling system designed based on NR is improved. The fatigue property of eC effect of NR is then investigated. The fatigue life at large deformation strain amplitudes (strain of 1-6) is about 800 cycles for the tested NR, which is too short to be used for a cooling system. Decreasing strain amplitude is necessary to extend fatigue life up to requirement of a cooling device. For the same small strain amplitude of 3, the fatigue property is compared at amorphous strain regime (strain of 0-3), onset strain of melting (strain of 2-5) and high strain of SIC (strain of 4-7). It’s found that a larger eC temperature change and a better fatigue property can be obtained at two SIC strain regimes (strain of 2-5 and 4-7) than amorphous strain regime. Especially, the fatigue property at the onset strain of melting (strain of 2-5) is better than that at high strain of SIC (strain of 4-7). A high-cycle fatigue was applied at the strain of 2-5 (most promising strain regime) up to 1.7×105 cycles. It was observed that there is no crack of the sample, as well as a degradation degree of 12% of the eC temperature change. Furthermore, the eC stress coefficient (4.4 K/MPa) at onset strain of melting is larger than that at high strain of SIC (1.6 K/MPa). As a result, the middle strain regime (onset strain regime of melting) can get a higher eC performance, larger temperature change, and better fatigue life, which should be chosen for eC cooling system
Gay, Gérard. "L'allergie immediate au latex naturel." Angers, 1990. http://www.theses.fr/1990ANGE1042.
Повний текст джерелаGros, Alice. "Modélisation de la cristallisation sous tension du caoutchouc naturel." Thesis, Ecole centrale de Nantes, 2016. http://www.theses.fr/2016ECDN0018.
Повний текст джерелаDespite the numerous experimental inverstigations performed over the past century and more intensively in the last fifteen years, strain-induced crystallization taking place in natural rubber still remains hardly understood in its precise mechanisms, leading models to remain phenomenological ones. The present study aims to develop a physicallymotivated model which qualitatively reproduces physical phenomena observed during an uniaxial tensile test. Firstly, the amorphous network is assumed to deform in an equal-force manner, resulting in a representative chain encompassing the inhomogeneity of matter through the chain-length distribution. Secondly, based on classical thermodynamics and on the entangled nature of the polymer network, both crystallization and fusion conditions are established. Moreover the derivation of the equilibrium point of a finite crystallite in a deformed network clarifies the tight relation between deformation and temperature during fusion. Finally, a semi-crystallized chain is defined, accounting for both the inhomogeneity of the amorphous phase and the heterogeneity due to the presence of a crystalline phase. This chain is included in a modified full-network model, initially dedicated to amorphous networks. This work leads to a complete thermo-mechanical constitutive equation which qualitatively reproduces the response of natural rubber in tension, but also to an original interpretative description of strain-induced crystallization
Dong, Shanyan. "Etude de la fatigue du caoutchouc naturel sous sollicitation multiaxiale." Paris, CNAM, 2009. http://www.theses.fr/2009CNAM0678.
Повний текст джерелаRubber is widely used in the industry. One of the major problems encountered in the applications of rubber remains still the prediction of the fatigue life of rubber. Since the components industrial undergo complex loading, we focus our subjects on fatigue of rubber under complex loading in this study. The objectives of this study should include the following points:1) To have a good understanding of the mechanism of multiaxial fatigue of rubber;2) To identify the existing approaches for analyzing the multiaxial fatigue of rubber, and hen develop a new approach;rubber, 3) To evaluate the existing and new approaches according to the test results. In order to accomplish these objectives, three different specimens are adopted. With these specimens we carry out several series of fatigue test under axial and biaxial loading on an INDTRON biaxial fatigue machine. The simulation of the specimens is performed by Finite Element Method. The fatigue lives of rubber are studied according to the test results. The tomography method is used to study the damage inside the rubber during the fatigue process by a medical scanner. Finally, the fatigue crack surfaces are examined by S. E. M
Alousque, Fanny. "Etude de la stabilité colloïdale du latex de caoutchouc naturel." Thesis, Paris 6, 2014. http://www.theses.fr/2014PA066648.
Повний текст джерелаThis work, in collaboration with Michelin for the fabrication of composite materials, deals with the colloidal stability of the latex of natural rubber (NR). The NR latex is a polydisperse colloidal dispersion of a bio-polymer in an aqueous serum. The particles are stabilized by a complex layer of phospholipids and proteins. This dispersion can be coagulated by a physical way (under shearing), or by a physical-chemical way (addition of divalent cations or hydrophobic particles). In this thesis, we studied the coagulation of the NR latex by divalent cations with physical-chemical tools (stability diagrams with different cations, aggregation kinetic of particles, rheological measuremments). Then, the surface of NR particles has been characterized by electrophoresis, firstly in the presence surfactants and secondly depending on the particles size. From the results of the first part we suggest that the coagulation with divalent cations is due to a screening effect because of the increase of ionic strength and that divalent cations can bridge the particles together. This allows keeping them in contact. Adhesion between polymer chains near the surface ensures the irrversible cohesion. In a second time, we saw that the adsorption of surfactants changes the particles surface and the coagulation of NR latex with cations. A small difference of surface charge is observed between the biggest and the smallest NR particles. Finally, a similar behavior has been obtained with a synthetic latex in presence of divalent cations. Our results could be used to develop an industrial process based on this coagulation phenomenon
Caborgan, Rodica. "Contribution à l'analyse expérimentale du comportement thermomécanique du caoutchouc naturel." Phd thesis, Université Montpellier II - Sciences et Techniques du Languedoc, 2011. http://tel.archives-ouvertes.fr/tel-00677252.
Повний текст джерелаPhinyocheep, Pranee. "Synthèse d'élastomères photoréticulables par modification chimique du caoutchouc naturel liquide." Le Mans, 1988. http://cyberdoc.univ-lemans.fr/theses/1998/1988LEMA1019.pdf.
Повний текст джерелаCaborgan, Rodica. "Contribution à l’analyse expérimentale du comportement thermomécanique du caoutchouc naturel." Thesis, Montpellier 2, 2011. http://www.theses.fr/2011MON20203/document.
Повний текст джерелаAn analysis of the thermomechanical behavior of the natural rubber is carried out by combining two quantitative imaging techniques. The digital image correlation of visible images is used to estimate the strain and then the deformation energy whereas infrared images make it possible to estimate, via the heat equation, the amounts of heat involved in the material transformation. The construction of energy balance enables us to determine the relative importance of the dissipative and thermomechanical coupling mechanisms. For low frequency and low extension ratio, the results show the famous thermoelastic inversion effect. From an energy standpoint, a competition between entropic elasticity and stress-induced crystallization/fusion mechanisms is observed for more significant extension ratios. No significant dissipative effect can be detected at low or high loading frequency whereas in each case, a stress-strain hysteresis characterizes the cyclic response of the material
Bennani, Amine. "Elaboration, Comportement et Durée de vie en Fatigue du Caoutchouc Naturel chargé de Silice." Paris, ENMP, 2006. https://pastel.archives-ouvertes.fr/tel-00136825.
Повний текст джерелаNatural rubber has long been reinforced by stiff fillers such as carbon black in order to improve mechanical properties (breaking strength, abrasion, rigidity…). The introduction of silica particles to the library of potential fillers offers new possibilities to further tailor the properties of Natural rubber via blending. Introduce silica instead of carbon black is a challenge in pneumatic industry. Synthetic-based elastomers filled with silica particles decrease in rolling friction of the tires while also retaining a good adherence. The goal of this study is to explore the influence of silica particles one the mechanical behavior, stiffness, strength, hysterisis, fatigue lifetime, of natural rubber. The main purpose is to understand the influence of the morphology of silica (Interaction surfaces between filler with rubber, dispersion with random distribution, chemical activity) on the mechanical behavior and on the fatigue lifetime. Also, Two blends with two different morphology of silica were produced. The both blends were made to obtain similar rheology properties. Experiments investigations were performed to identify the mechanical behavior such as (tension, compression, torsion ,cyclic loading, relaxation tests) and mechanisms of deformation and damage were estimated from uniaxial elongation in combination with in situ SEM micrographs tests. The micro-structure of the blends were studied through SEM observations and uniaxial elongation in combination with in situ X-ray. Theses studies indicate respectively a good dispersion of the filler and a crystallization of soft-segment induced by elongation. Fatigue experimental results with fractographic observations allow to built a new model of lifetime prediction. This model is able to predict the location and orientation of cracks as well as the fatigue lifetime. The life time experiments and numerical tests study shows how the two different silica particles reinforced natural rubber , when subjected to various mechanical loading conditions (uniaxial, hydrostatic, monotonic, cyclic)
Sitthai-Nipithakul, Thirawan. "Etude de la pégosité du caoutchouc naturel réticulé : rôle des composés non-caoutchoutiques." Mulhouse, 2000. http://www.theses.fr/2000MULH0615.
Повний текст джерелаSainte-Beuve, Jerôme. "Le séchage du caoutchouc naturel : facteur de correction de la variabilité ?" Montpellier 2, 1997. http://www.theses.fr/1997MON20229.
Повний текст джерелаBeurrot-Borgarino, Stéphanie. "Cristallisation sous contrainte du caoutchouc naturel en fatigue et sous sollicitation multiaxiale." Phd thesis, Ecole centrale de nantes - ECN, 2012. http://tel.archives-ouvertes.fr/tel-00835499.
Повний текст джерелаBeurrot, Stéphanie. "Cristallisation sous contrainte du caoutchouc naturel en fatigue et sous sollicitation multiaxiale." Ecole Centrale de Nantes, 2012. https://tel.archives-ouvertes.fr/tel-00835499.
Повний текст джерелаNatural rubber is well-known for its excellent mechanical properties in multiaxial fatigue and those are generaly attributed to the ability of the material to crystallize when strained. However, the relationship between strain-induced crystallization and mechanical properties of natural rubber has never been established. The aim of this thesis is therefore to understand the origin of the great multiaxial fatigue properties of carbon black-filled natural rubber, by considering two small scales of study, as opposed to the macroscopic scale generally considered. The first part of this thesis is dedicated to uniaxial crack growth and energy dissipation mechanisms at the cracks and micro-cracks scale ; those mechanisms are determined thanks to original in-situ propagation tests observed with scanning electron microscope. In the second part of the thesis, strain-induced crystallization is studied at the macromolecular scale, in static multaxial deformation on the one hand and in uniaxial fatigue on the other hand, thanks to X-ray diffraction measurements performed at the Soleil synchrotron facility. The characteristics of crystallites, i. E. Their size, orientation, number and lattice parameters, are measured during the different mechanical tests. We observe that in multiaxial deformation, the crystallites are similar in size and have the samei lattice parameters than those nucleated in uniaxial deformation, but their orientation strongly varies with the multiaxiality of the deformation and is not influenced by the loading path. Finally, we show that in uniaxial fatigue, the characteristics of the crystallites evolve with the number of cycles, differently depending on the minimum and maximium stretch ratios reached at each cycle
NA-RANONG, NUCHANAT. "Indice de retention de plasticite du caoutchouc naturel : evolution et facteurs d'influence." Paris 6, 1993. http://www.theses.fr/1993PA066433.
Повний текст джерелаOuardad, Samira. "Approches bio-inspirées du caoutchouc naturel par polymérisation cationique et modification chimique." Thesis, Bordeaux 1, 2011. http://www.theses.fr/2011BOR14465/document.
Повний текст джерелаAlthough synthetic rubbers, including high cis-content polyisoprene (PIP), are used in a broad range ofapplications, they are far from achieving the performances of natural rubber (NR), a 100% 1,4-cis polyisoprenewith very high molar mass. Therefore, NR produced exclusively by hevea (whereas more than 2,500 plant species are known to produce polyterpene-based polymers) is still dominant in many engineering applications since its exceptional properties grants this polymer a strategic resource material which holds a significant marketshare (about 45%).. The only alternative plant species under cultivation, Parthenium argentatum, also calledguayule, produces a latex yielding rubber with properties close to those of hevea rubber, and marketed as “non allergenic natural rubber” but with a higher cost complex extraction processes The NR biosynthesis process isdescribed as a polymerization process involving a series of enzymatic reactions using isopentenyl pyrophosphate(IPP) as elementary building brick. Besides, synthetic PIPs with high cis-content were already produced fromisoprene monomer by Ziegler-Natta, lanthanide-based or anionic-type polymerizations. Currently, no syntheticPIPs mimics the performance of NR, maybe because 100% 1,4-cis PIP could so far not been produced synthetically. A close inspection of the NR biosynthesis process led us to postulate that this latter is consistent with a transferless, stereospecific carbocationic-type polymerization mechanism. We then propose to develop this new bio-inspired cationic-like polymerization approach with the aim to produce polyterpenes and then NR homologues of tailored molar mass and microstructure that could exhibit properties close to natural polyterpenes by using IPP homologues and isoprene as monomers, DMAPP homologues asinitiators and Lewis acids to mimick the divalent cations (Zn2+, Mg2+ or Mn2+) that assist the enzymes during the initiation end activation steps. For the cationic polymerization of isoprene, oligomers with 1,4-trans and cyclized structures were obtained. We also develop new routes to modify polyisoprenes obtained by anionic polymerization in order to establish hydrogen interaction. To this end, different urea groups were grafted and the modified polyisoprene exhibite delastomeric properties close to the one of a non-vulcanized NR obtained by latex coagulation
Auria, Richard. "Contribution à l'étude du caoutchouc naturel : structure interne et transfert d'humidité lors du séchage." Montpellier 2, 1988. http://www.theses.fr/1988MON20133.
Повний текст джерелаGIBAUD, BERTRAND. "Le latex de caoutchouc naturel et sa biocompatbilite (en particulier avec le tissu osseux)." Nantes, 1990. http://www.theses.fr/1990NANT038M.
Повний текст джерелаNikpour, Navid, and Navid Nikpour. "Production and characterization of natural fiber-polymer composites using ground tire rubber as impact modifier." Master's thesis, Université Laval, 2016. http://hdl.handle.net/20.500.11794/26699.
Повний текст джерелаCe travail porte sur la production et la caractérisation de matériaux composites hybrides basés sur un polymère thermoplastique (polyéthylène de haute densité, PEHD), une fibre naturelle (chanvre) et un caoutchouc recyclé provenant de pneus usés (GTR) comme modificateur d'impact. L'addition d'un agent de couplage (polyéthylène maléaté) est également étudiée. Les échantillons sont mélangés par extrusion à double-vis et fabriqués par un moulage en injection. À partir des échantillons obtenus, une caractérisation morphologique et mécanique complète est effectuée. Les résultats montrent que la bonne dispersion est obtenue en raison des bonnes conditions de mélanges sélectionnées et une bonne adhésion interfaciale entre toutes les phases est atteinte en raison de la présence d'anhydride maléique greffée au polyéthylène (MAPE). Enfin, pour des propriétés mécaniques choisies, des modèles de régression non-linéaire sont proposés pour prédire et contrôler les propriétés finales de ces composés par des comparaisons faites sur la base des propriétés de la matrice seule.
This work aims at the production and characterization of hybrid composites based on a thermoplastic polymer (high density polyethylene, HDPE), a natural fiber (hemp) as reinforcement and ground tire rubber (GTR) as an impact modifier. The addition of a coupling agent (maleated polyethylene) is also investigated. The samples are compounded by twin-screw extrusion and produced by injection molding. From the samples obtained, a complete morphological and mechanical characterization is performed. The results show that good dispersion is obtained due to the selected processing conditions and good interfacial adhesion between all the phases is achieved due to the presence of maleic anhydride grafted polyethylene (MAPE). Finally, for selected mechanical properties, nonlinear regression models are proposed to predict and control the final properties of these compounds and comparisons are made based on the neat matrix properties.
This work aims at the production and characterization of hybrid composites based on a thermoplastic polymer (high density polyethylene, HDPE), a natural fiber (hemp) as reinforcement and ground tire rubber (GTR) as an impact modifier. The addition of a coupling agent (maleated polyethylene) is also investigated. The samples are compounded by twin-screw extrusion and produced by injection molding. From the samples obtained, a complete morphological and mechanical characterization is performed. The results show that good dispersion is obtained due to the selected processing conditions and good interfacial adhesion between all the phases is achieved due to the presence of maleic anhydride grafted polyethylene (MAPE). Finally, for selected mechanical properties, nonlinear regression models are proposed to predict and control the final properties of these compounds and comparisons are made based on the neat matrix properties.
Charernjiratragul, Somboon. "Le système productif agricole à base d'hévéaculture dans l'économie thai͏̈landaise du caoutchouc naturel." Montpellier 1, 1991. http://www.theses.fr/1991MON10014.
Повний текст джерелаThis thesis presents a study on the agricultural production system based on rubber cultivation in a small rubber region of songkhla (the highest rubber producing province) in the south of thailand. It is a study on the micro-economic within the farming units, concerning the cropping system, the farming system and the managing system, in relation with the types of planters, which permits us to conceive the socio-economic disparities, at the farm level. With the assistance of this study and the macro-economic studies, in dynamic terms, within the national and international context of natural rubber, one can draw out particular observations through three themes : the capacity, the productivity and the competitiveness, finally permitting formulation of propositions that may more or less touch directly the existing problems
Pire, Myriam. "Caoutchouc naturel époxydé et réticulation par les acides dicarboxyliques : chimie, cinétique et propriétés mécaniques." Phd thesis, Université Pierre et Marie Curie - Paris VI, 2011. http://pastel.archives-ouvertes.fr/pastel-00732940.
Повний текст джерелаBennani, Amine. "Elaboration, comportement et durée de vie en fatigue du caoutchouc naturel renforcé de silice." Phd thesis, École Nationale Supérieure des Mines de Paris, 2006. http://tel.archives-ouvertes.fr/tel-00136825.
Повний текст джерелаCe qui leur confère de meilleures propriétés (résistance à la rupture, abrasion, rigidité...). Actuellement, les charges
renforçantes les plus souvent utilisées sont les noirs de carbone. La substitution de cette charge classique par la silice constitue un challenge dans l'industrie pneumatique. En effet, il est admis que la silice diminue la résistance au roulement des pneus, de matrice synthétique, tout en conservant une bonne adhérence. La particularité de cette étude est d'analyser l'influence du renfort par la silice sur le comportement mécanique en endurance du caoutchouc naturel. Son principal objectif est de comprendre l'influence de la morphologie de la silice (surface développée en interaction avec le caoutchouc, dispersibilité, activité chimique) sur le comportement
mécanique et plus spécialement sur la durée de vie en fatigue du caoutchouc naturel ainsi chargé. L'élaboration de deux matériaux permettant d'établir l'influence de la morphologie de la silice constitue une première étape déterminante du travail. Elle se base sur l'incorporation de deux nuances de silice précipitée dans une matrice de caoutchouc naturel pouvant présenter des propriétés rhéologiques similaires. Les essais de caractérisation mécanique (monotones et cycliques) selon différents types de sollicitation (traction, compression, relaxation, traction cyclique, torsion) ainsi que des essais de traction in situ au MEB permettent d'identifier les mécanismes de déformation, de renfort et d'endommagement présents. L'interprétation des résultats de cette campagne expérimentale est basée sur une caractérisation microstructurale approfondie de l'état de dispersion de la silice ainsi que celui de la cristallisation de la matrice en caoutchouc naturel.. Les résultats des essais de fatigue ainsi que les observations microscopiques des mécanismes de propagation des fissures en fatigue permettent d'établir un critère de durée de vie prenant en compte les modes de sollicitation (traction, compression, et torsion). Celui-ci est capable de prévoir la durée de vie ainsi que le lieu d'amorçage des fissures. Il s'avère que, selon le mode de sollicitation appliqué, les propriétés de dispersion de la silice sont plus ou moins importantes dans le renforcement et l'endurance du caoutchouc naturel chargé de silice.
Ce travail fait donc appel à la physico-chimie, à la mécanique et aux observations microstructurales, en allant de l'élaboration des matériaux jusqu'à la modélisation mécanique du comportement et de la durée de vie.
Pratoto, Adjar. "Établissement d'abaques de dimensionnement de séchoirs à chauffage partiellement solaire pour le caoutchouc naturel." Besançon, 1996. http://www.theses.fr/1996BESA2011.
Повний текст джерелаPortal, Julien. "Mélanges d'élastomères chargés, structure et mise en oeuvre : étude des coupages caoutchouc naturel / polybutadiène." Saint-Etienne, 2008. http://www.theses.fr/2008STET4004.
Повний текст джерелаThe relation between the structure of elastomer blends and their processing is addressed in this project. This work concerns uncured blends of natural rubber and polybutadiene (NR/BR) filled with carbon black (CB). Information on the structure of the filled blends was obtained over the entire composition range. Firstly, the morphology of uncured and unfilled NR/BR blends was described by four experimental procedures. Secondly, the distribution of carbon black in uncured blends could be quantified using differential scanning calorimetry. The processing of filled NR/BR blends was simulated by capillary rheometer to obtain information on die swell and on the onset of flow instabilities. The last part of this study applied the procedures to NR/BR/CB compounds prepared with various mixing conditions. The localization of carbon black indicates that CB has larger affinity for natural rubber than for polybutadiene. This tendency, described by differential scanning calorimetry, is also confirmed by transmission electron microscopy. The second main result of this work is that a balanced distribution of CB between the phases enables a better processing of uncured NR/BR/CB mixtures
Auria, Richard. "Contribution à l'étude du caoutchouc naturel structure interne et transfert d'humidité lors du séchage /." Grenoble 2 : ANRT, 1988. http://catalogue.bnf.fr/ark:/12148/cb376113897.
Повний текст джерелаImbernon, Lucie. "Réticulation non-permanente, chimique ou physique, du caoutchouc naturel époxydé : propriétés dynamiques et recyclage." Thesis, Paris 6, 2015. http://www.theses.fr/2015PA066427/document.
Повний текст джерелаImproving rubber recyclability is a major challenge of today’s society. These materials are usually crosslinked through permanent covalent chemistry, which prevents any further modification of the network structure. The aim of this thesis was to design the recyclability up-stream by using non-permanent chemistry for rubber crosslinking. Epoxidized natural rubber (ENR), chosen as the base rubber, is efficiently crosslinked by reaction of dicarboxylic acids on oxirane rings to form ester bonds. On the one hand, the addition of a transesterification catalyst let foresee the obtaining of vitrimer properties. The advantages of this exchangeable chemistry are shown by comparison to lightly permanently crosslinked rubbers that also show stress relaxation and adhesion properties. On the other hand, using a functionalized diacid with a central disulphide function, a certain degree of reprocessability could be obtained, comparable to what was obtained by conventional sulphur vulcanization. A major advantage of the presented diacid chemistry over vulcanization is the non-toxicity towards the environment. Lastly, by grafting long crystallizable fatty acids onto ENR, we synthesized thermoplastic elastomers. Like diacid-crosslinked ENR (chemical network), these physical networks show strain-induced crystallization measured by X-ray diffraction during cyclic tensile tests
Imbernon, Lucie. "Réticulation non-permanente, chimique ou physique, du caoutchouc naturel époxydé : propriétés dynamiques et recyclage." Electronic Thesis or Diss., Paris 6, 2015. https://accesdistant.sorbonne-universite.fr/login?url=https://theses-intra.sorbonne-universite.fr/2015PA066427.pdf.
Повний текст джерелаImproving rubber recyclability is a major challenge of today’s society. These materials are usually crosslinked through permanent covalent chemistry, which prevents any further modification of the network structure. The aim of this thesis was to design the recyclability up-stream by using non-permanent chemistry for rubber crosslinking. Epoxidized natural rubber (ENR), chosen as the base rubber, is efficiently crosslinked by reaction of dicarboxylic acids on oxirane rings to form ester bonds. On the one hand, the addition of a transesterification catalyst let foresee the obtaining of vitrimer properties. The advantages of this exchangeable chemistry are shown by comparison to lightly permanently crosslinked rubbers that also show stress relaxation and adhesion properties. On the other hand, using a functionalized diacid with a central disulphide function, a certain degree of reprocessability could be obtained, comparable to what was obtained by conventional sulphur vulcanization. A major advantage of the presented diacid chemistry over vulcanization is the non-toxicity towards the environment. Lastly, by grafting long crystallizable fatty acids onto ENR, we synthesized thermoplastic elastomers. Like diacid-crosslinked ENR (chemical network), these physical networks show strain-induced crystallization measured by X-ray diffraction during cyclic tensile tests
Ehabe, Eugène Ejolle. "La structure du caoutchouc naturel : élaboration, évolution au cours de la mastication et prédiction à l'aide du viscosimètre Mooney." Montpellier 2, 2004. http://www.theses.fr/2004MON20017.
Повний текст джерелаRublon, Pierre. "Etude expérimentale multi-échelle de la propagation de fissure de fatique dans le caoutchouc naturel." Ecole centrale de Nantes, 2013. http://www.theses.fr/2013ECDN0003.
Повний текст джерелаThis PhD thesis aims to experimentally characterizethe fatigue crack growth behaviour in natural rubber, and is particularly interested in the neighbourhood of thecrack tip where the well-known phenomenon of straininduced crystallization takes place due to the large strains in this region. The final goal is therefore to explain the outstanding fatigue properties and crack growth resistance of natural rubber which are recognized for a while in literature. On the one hand, fatigue crack growth rate tests are performed to evaluate the influence of various parameters such as the type of elastomer, the carbon-black content and non-relaxing conditions, on the fatigue crack growth resistance. On the other hand, various experimental methods are used at different scales to characterize the fatigue crack tip neighbourhood. First of all, a synchrotron radiation allows us to measure quantitatively the strain-induced crystallization phenomenon at the crack tip using the wide-angle X-ray diffraction method. Moreover, those results are related to strain field measurements obtained by digital image correlation. Besides, an original fatigue experiment performed in a scanning electron microscope enables us to observe in situ the fatigue crack growth mechanisms at the crack tip. Finally, all these experimental results, compared to macroscopic measurements of fatigue crack growth rates in our samples, lead to a discussion about the influence that has the strain-induced crystallization phenomenon on the resistance to fatigue crack growth in natural rubber
Valantin, Chloé. "Compréhension des mécanismes d'endommagement de l'interface textile-caoutchouc." Thesis, Tours, 2014. http://www.theses.fr/2014TOUR4027.
Повний текст джерелаStudied belts undergo complex mechanical stress and thermal variations up to 160°C. To enhance their service life, the interfacial properties between the PA 4, 6 cord, coated with RFL, and the EPDM matrix must be improved. In this study, fatigue tests on belts were stopped after various numbers of cycles in order to characterize the interface between cord and rubber. Electron Microscopy revealed three different mechanisms for mechanical damage: Degradation of the inner cord structure Propagation of fibrillar microcracks at the RFL/rubber interface Appearance of RFL/polyamide microfiber debondings This damage was associated with interfacial hardenings (nanoindentation), viscoelastic properties variations of the structure (DMA) and a decrease in adhesive values (peeling or pulling out). Physicochemical analyses, mainly by Tof-SIMS, enabled to determine interfacial composition and to link its evolution with observed mechanical damage
Rublon, Pierre. "Etude expérimentale multi-échelle de la propagation de fissure de fatigue dans le caoutchouc naturel." Phd thesis, Ecole centrale de nantes - ECN, 2013. http://tel.archives-ouvertes.fr/tel-00904442.
Повний текст джерелаCousin, Bruno. "Séchage du caoutchouc naturel sous forme de granulés ; analyse théorique et expérimentale des processus internes." Montpellier 2, 1990. http://www.theses.fr/1990MON20054.
Повний текст джерелаZhang, Yi. "Identification des gènes impliqués dans la production et la détoxication des espèces activées de l'oxygène chez Hevea brasiliensis et leur caractérisation dans le latex." Thesis, Montpellier, 2018. http://www.theses.fr/2018MONTG004/document.
Повний текст джерелаHevea brasiliensis, a tropical tree, is the main commercial source of nature rubber. The rubber biosynthesis occurs in specialized latex cells of rubber tree. Up 90% dry weight of latex is nature rubber. The milky latex flows out from cut latex cells by tapping rubber tree trunk bark. Rubber exploitation by tapping every several days is very stressful for the bark of rubber tree. To stimulate latex production, ethylene releaser is applied during rubber exploitation in some cases. The stress is increased after hormone stimulation. Reactive oxygen species (ROS) is generated when plant suffers stresses from environment and harvesting activity. Over a certain limit of stress, ROS bursting is motivated in latex cell. A lots of the evidences showed that the ROS lead to the peroxidatic degradation of the unsaturated lipids of the membrane and then to destabilisation and lysis of the organelles. Lysis of the lutoids results in liberation of coagulating factors into latex and coagulation in situ of rubber particles in stressed trees. This serious physiology syndrome is tapping panel dryness (TPD) which is one of main factor limiting rubber production.This PhD aims at identifying ROS production and scavenging genes and their characterizations in latex cell. Firstly, we made a comprehensive bibliography study on ROS production and scavenging genes both in rubber tree and model plant. The NADPH oxidase was considered as the main source of ROS in the stressed trees. ROS scavenging enzymes and antioxidants constituted the ROS scavenging systems in latex. Secondly, based on a genome-wide analysis, 407 genes involved in ROS production and scavenging were identified. Thirdly, based on a transcriptome analysis, 164 redox-related genes were detected expressing in latex of clone SP217 and 161 genes expressing in latex of clone PB260. Fourthly, based on small RNA and degradome analysis, 13 genes were shown to be targeted by 11 microRNAs and 15 genes by 16 phased siRNA in latex. Lastly, this study illustrated specific regulation systems of ROS production and scavenging in latex. HbRBOH2 was identified as the main source gene of ROS in latex. HbCuZnSOD4 might be the most important ROS scavenging gene to detoxify the ROS in latex of TPD tolerant tree
BEN, DHIA AMOR. "Caracterisation, modelisation et calcul d'une structure composite fibres de nylon-resine caoutchouc." Paris 6, 1994. http://www.theses.fr/1994PA066319.
Повний текст джерелаCHALLIOUI, GILLET CAROLE. "Degradation du caoutchouc naturel en phase latex par oxydation controlee. Action du couple phenylhydrazine/oxygene sur un modele des structures polyisopreniques." Le Mans, 1994. http://www.theses.fr/1994LEMA1024.
Повний текст джерелаEiamnipon, Naruepon. "Etude de la dégradation de structures composites en caoutchouc soumises à des chocs." Thesis, Paris, ENMP, 2013. http://www.theses.fr/2013ENMP0099/document.
Повний текст джерелаRoad hazard is a critical problem in tire application. Steel cord-rubber composite such as steel belt is used to reinforce the tire stiffness in architecture of the radial tire. The main function is used to protect penetrations due to foreign objects. In fact, the knowledge of this material is not well-established yet in particular damage mechanisms subjected to impact load. The principal objective of this dissertation is to study high strain rate behaviors, impact behaviors as well as damage mechanisms of the steel cord-rubber composite, allowing us to develop a perforation criterion. The experimental analysis and numerical simulations allow us to thoroughly understand the dynamic behaviors and damage mechanisms for instance high stain rate tensile characterization, drop-weight impact and indentation characterizations, damage observation etc... In order to develop a criterion capable of predicting the perforation of the steel cord-rubber composite, the drop-weight impact tests and indentation tests have been conducted. Finally, we propose the perforation criterion based on analytical approach and its validation for the steel cord-rubber composite
Siqueira, Gustavo Henrique. "Évaluation de la vulnérabilité sismique des ponts routiers au Québec réhabilités avec l'utilisation d'isolateurs en caoutchouc naturel." Thèse, Université de Sherbrooke, 2013. http://hdl.handle.net/11143/6142.
Повний текст джерелаMusigamart, Natedao. "Study of the role of lipids from maturated coagula from Hevea brasiliensis latex on natural rubber behavior in oxidative conditions." Thesis, Montpellier, SupAgro, 2015. http://www.theses.fr/2015NSAM0004/document.
Повний текст джерелаNatural rubber (NR), a derived product from H. brasiliensis latex, is known for its high mechanical properties that are, for some, superior to those of its synthetic counterparts. However, the high degree of unsaturation of poly(cis-1,4-isoprene) makes it susceptible to thermo-oxidation. Fortunately, NR is endowed with non-isoprene components of which some have antioxidant properties. Especially, lipids, the main non-isoprene component retained in NR, have been reported to contain antioxidant substances, especially tocotrienols. It is well known that during the maturation of latex coagula, both NR physical properties and chemical composition are altered, but the complex mechanisms of this alteration are still to be elucidated. In the present work, the evolution of some native antioxidant molecules during maturation was followed in relation with some physical properties. Two experimental conditions of maturation were chosen. The first experiment involved uncontrolled conditions based on traditional unsmoked (USS) or ribbed smoked sheet (RSS) processing, while the second was performed in a dedicated maturation device with full control of environmental factors (relative humidity, temperature and oxygen content) followed by a processing based on that of Technically Specified Rubber (TSR). The evolution of samples during maturation was studied at different scales: bulk properties (P0, P30 and PRI), mesostructure (% gel content, Mw and Mn) and biochemical composition (lipids components). In parallel, in vitro antioxidant activity of NR lipid extracts was also investigated using an optimized DPPH method. Lipid quantity and quality evolved during maturation, especially under aerobic conditions. The total amount of lipid extract decreased, with a release of free fatty acids at early stage of maturation followed by a later decrease, unsaturated fatty acids being the first to disappear. The amount of extractable free γ-tocotrienol did not change much during maturation, while its esterified form was enriched in saturated fatty acids. The antioxidant activity measured in vitro correlated well with free γ-tocotrienol concentration but not with the resistance of rubber to thermo-oxidation assessed by P30 or PRI. Indeed, the in vitro conditions of measurement were far from those occurring inside rubber material. The localization of antioxidants in rubber and especially their physical possibility to interact with the double bonds of poly(cis-1,4-isoprene) or with oxidant species should be further investigated to understand what drives the drop of P30 along maturation time. Non extractable lipids or more polar non-isoprene molecular species (proteins, polyphenols, etc…) could also influence the resistance to thermo-oxidation
Rolere, Sebastien. "Etude des interactions à l'origine de la structure associative du caoutchouc naturel et de leurs influences sur les propriétés rhéologiques." Thesis, Montpellier, 2015. http://www.theses.fr/2015MONTS230.
Повний текст джерелаNatural Rubber (NR) is an elastomer made from Hevea brasiliensis latex. It contains about 94% (w/w) of cis-1,4-polyisoprene and 6% (w/w) of non-isoprene compounds, such as lipids (1.5-3.0%), proteins (~ 2.0%) and minerals (0.2%). These non-isoprene compounds are assumed to be responsible for the associative structure and the outstanding properties of NR. However, substantial variability in NR properties is caused by diverse agronomic conditions (season, clones and tapping system) and by the different manufacturing processes. This PhD thesis is part of the French CANAOPT project, which aims to create new NR grades with reduced and controlled variability for antivibratory applications. This PhD work aims for a better understanding of the origin of the NR gel phase and its influence on rheological properties. The gel phase of NR (or total gel) is composed of a fraction that is insoluble in organic solvent (macrogel), and of microaggregates dispersed in the soluble fraction (microgel). The first component of this PhD research set out to identify the impact of the gel phase on NR properties. To that end, characterization methods were developed in order to investigate the different gel contents, the structures of cis-1,4-polyisoprene chains and microaggregates (SEC-MALS in TBABr mode), and also rheological properties in double-shear solicitation (DMTA) of NR samples. The non-isoprene contents (lipids and proteins) were also investigated using a new characterization method in FT-IR spectroscopy, developed during this PhD work. Correlations between the average molar masses of the macromolecules and the rheological properties of 25 NR samples were highlighted. Finally, a correlation was found between the total gel content and a K' parameter, introduced by the Perez model and graphically determined by the Cole-Cole representation.At the same time, physicochemical characterization of the microgel and the macrogel of NR samples was undertaken. First, a new method was developed in order to extract and study NR microaggregates. The composition, the degree of crosslinking and the rheological properties of macrogels extracted from 11 NR samples were also investigated. It was found that the protein content (5-51% w/w) of the macrogel was clearly correlated to its degree of crosslinking. The macrogel protein content also influenced its rheological properties, which were much greater than those of the corresponding NR and soluble fraction
Panwiriyarat, Wannarat. "Synthèse et étude des propriétés d'un polyuréthane biosourcé obtenu du caoutchouc naturel et du poly(ε-caprolactone)". Phd thesis, Université du Maine, 2012. http://tel.archives-ouvertes.fr/tel-00795875.
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