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1

Mjelde, R., and J. I. Faleide. "Variation of Icelandic and Hawaiian magmatism: evidence for co-pulsation of mantle plumes?" Marine Geophysical Researches 30, no. 1 (March 2009): 61–72. http://dx.doi.org/10.1007/s11001-009-9066-0.

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2

Nardi, Lauro V. S., Jorge Plá-Cid, Maria de Fátima Bitencourt, and Larissa Z. Stabel. "Geochemistry and petrogenesis of post-collisional ultrapotassic syenites and granites from southernmost Brazil: the Piquiri Syenite Massif." Anais da Academia Brasileira de Ciências 80, no. 2 (June 2008): 353–71. http://dx.doi.org/10.1590/s0001-37652008000200014.

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The Piquiri Syenite Massif, southernmost Brazil, is part of the post-collisional magmatism related to the Neoproterozoic Brasiliano-Pan-African Orogenic Cycle. The massif is about 12 km in diameter and is composed of syenites, granites, monzonitic rocks and lamprophyres. Diopside-phlogopite, diopside-biotite-augite-calcic-amphibole, are the main ferro-magnesian paragenesis in the syenitic rocks. Syenitic and granitic rocks are co-magmatic and related to an ultrapotassic, silica-saturated magmatism. Their trace element patterns indicate a probable mantle source modified by previous, subduction-related metasomatism. The ultrapotassic granites of this massif were produced by fractional crystallization of syenitic magmas, and may be considered as a particular group of hypersolvus and subsolvus A-type granites. Based upon textural, structural and geochemical data most of the syenitic rocks, particularly the fine-grained types, are considered as crystallized liquids, in spite of the abundance of cumulatic layers, schlieren, and compositional banding. Most of the studied samples are metaluminous, with K2O/Na2O ratios higher than 2. The ultrapotassic syenitic and lamprophyric rocks in the Piquiri massif are interpreted to have been produced from enriched mantle sources, OIB-type, like most of the post-collisional shoshonitic, sodic alkaline and high-K tholeiitic magmatism in southernmost Brazil. The source of the ultrapotassic and lamprophyric magmas is probably the same veined mantle, with abundant phlogopite + apatite + amphibole that reflects a previous subduction-related metasomatism.
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3

WU, FU-YUAN, ROGER H. MITCHELL, QIU-LI LI, CHANG ZHANG, and YUE-HENG YANG. "Emplacement age and isotopic composition of the Prairie Lake carbonatite complex, Northwestern Ontario, Canada." Geological Magazine 154, no. 2 (February 12, 2016): 217–36. http://dx.doi.org/10.1017/s0016756815001120.

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AbstractAlkaline rock and carbonatite complexes, including the Prairie Lake complex (NW Ontario), are widely distributed in the Canadian region of the Midcontinent Rift in North America. It has been suggested that these complexes were emplaced during the main stage of rifting magmatism and are related to a mantle plume. The Prairie Lake complex is composed of carbonatite, ijolite and potassic nepheline syenite. Two samples of baddeleyite from the carbonatite yield U–Pb ages of 1157.2±2.3 and 1158.2±3.8 Ma, identical to the age of 1163.6±3.6 Ma obtained for baddeleyite from the ijolite. Apatite from the carbonatite yields the same U–Pb age of ~1160 Ma using TIMS, SIMS and laser ablation techniques. These ages indicate that the various rocks within the complex were synchronously emplaced at about 1160 Ma. The carbonatite, ijolite and syenite have identical Sr, Nd and Hf isotopic compositions with a 87Sr/86Sr ratio of ~0.70254, and positive εNd(t)1160 and εHf(t)1160 values of ~+3.5 and ~+4.6, respectively, indicating that the silicate and carbonatitic rocks are co-genetic and related by simple fractional crystallization from a magma derived from a weakly depleted mantle. These age determinations extend the period of magmatism in the Midcontinent Rift in the Lake Superior area to 1160 Ma, but do not indicate whether the magmatism is associated with passive continental rifting or the initial stages of plume-induced rifting.
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4

NIGAI, Elena. "Udurchukan formation and ayakit complex (Bureya massif, Sikhote-Alin): location, age and geochemistry." Domestic geology, no. 6 (January 28, 2022): 85–99. http://dx.doi.org/10.47765/0869-7175-2021-10033.

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Neogene basalts in the eastern of the Bureya massif and the adjacent Kursk-Komsomolskaya zone of the Sikhote-Alin fold system occur in the seismically and tectonically active area along the Khingan, Amgun and Tanlu-Kharpi deep faults. Analysis of age constraints on the timing of basaltoid magmatism in the Miocene suggests three phases of magmatism in the study areas: Early Miocene (Udurchukan Formation: 22,6–18,6 Ma); Middle Miocene (Ayakit Complex: 14,8–13,0 Ma), and Late Miocene (Ayakit Complex: 10,0–9,3 Ma). Rock studies have found that basalts (Ayakit plateau), basaltic andesites (Udurchukan plateau), and leucitites (Yadasen Island) are enriched in sodium oxides, potassium, titanium, iron, magnesium, and phosphorus. Two samples of alkaline olivine basalts from the Ayakit plateau yielded high KkTe (578,0) and Ag (172,7); elevated Kk in high field-strength Nb (6,2), Ta (3,4) and radioactive Th (2,7), U (2,4). The contents of Co, Ni, Zr, Mo, W, Zn, Sr, Ba, Hg, light and middle REE are 1,1–1,5 times or even higher than the clarke values for mafic rocks. There is a slight deficit of Sb, Cs, Bi, Cu, Li, Sc, Rb, Tm, Yb, Lu (Kk < 0,7). A similar chemical composition of the SASS basalts (Solnechny settlement and Yadasen Island) suggests that they have a common magma source.
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5

Udry, Arya, and James M. D. Day. "1.34 billion-year-old magmatism on Mars evaluated from the co-genetic nakhlite and chassignite meteorites." Geochimica et Cosmochimica Acta 238 (October 2018): 292–315. http://dx.doi.org/10.1016/j.gca.2018.07.006.

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6

Pribavkin, S. V., N. S. Borodina, and M. V. Chervyakovskaya. "Geochemistry of trace elements in rock-forming minerals of gneisses and granites of the Murzinka granite area, Central Urals." МИНЕРАЛОГИЯ (MINERALOGY), no. 3 (October 28, 2020): 74–88. http://dx.doi.org/10.35597/2313-545x-2020-6-3-6.

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Анотація:
The Murzinka granite area (Central Urals), which combines Murzinka granite pluton and underlying rocks of the Murzinka-Adui metamorphic complex, exhibits an evident wetrending geochemical zonation of magmatism with increasing of Rb, Li, Nb and Ta contents and decreasing ba and Sr contents and K/Rb, zr/Hf and Nb/Ta ratios from vein granites of the Yuzhakovo complex to granites of the Vatikha complex and further to granites of the Murzinka complex (Fershtater et al., 2019). To develop the ideas about geochemical zonation of the Murzinka granite magmatism, as well as about the role of gneisses of the Murzinka-Adui metamorphic complex in the formation of granites, we studied the distribution of trace elements in biotite and feldspars of gneisses and granites. Biotite shows an increase in Li, Rb, Cs, Nb, Ga, zn, Mn, Sc, Sn and Tl contents and a decrease in V, Cr, Co, Ni, Y, zr and ba contents from vein biotites of the Yuzhakovo granites to two-mica granites of the Murzinka complex. The composition of feldspars also changes in this direction: plagioclase is enriched in Li, Rb, Cs, be, zn and depleted in Sr, ba, Ga and Pb and K-feldspar is enriched in Rb and depleted in Sr and ba. The varying trace element composition of rock-forming minerals of gneisses and granites is explained by We-trending change in the composition of a crustal protolith, as well as the formation conditions of granites. Figures 6. Tables 4. References 17.
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7

Perna, Maria, Daria Zaccaria, Gianluigi Rosatelli, Francesco Stoppani, Ezio Curti, John Spratt, Emma Humphreys-Williams, et al. "Dissolution-Repackaging of Hellandite-(Ce), Mottanaite-(Ce)/Ferri-Mottanaite-(Ce)." Minerals 11, no. 6 (June 7, 2021): 610. http://dx.doi.org/10.3390/min11060610.

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We investigated hellandite-group mineral phases from the Roman Region, alkali syenite ejecta, by multimethod analyses. They show a complex crystallisation history including co-precipitation of hellandite-(Ce) with brockite, resorption, sub-solidus substitution with mottanaite-(Ce), exsolution of perthite-like ferri-mottanaite-(Ce), overgrowth of an oscillatory-zoned euhedral shell of ferri-mottanaite-(Ce) and late, secondary precipitation of pyrochlore in the cribrose hellandite-(Ce) core. LREE/HREE crossover and a negative Eu anomaly in hellandite-group minerals follows fO2 increase during magma cooling. The distinction among the hellandite-group minerals is based on the element distribution in the M1, M2, M3, M4 and T sites. Additional information on miscibility relationship among the hellandite sensu strictu, tadzhikite, mottanaite, ferri-mottanaite and ciprianiite endmembers derives from molar fraction calculation. We observed that change in composition of hellandite-group minerals mimic the ligands activity in carbothermal-hydrothermal fluids related to carbonatitic magmatism.
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8

Bateman, Paul C. "Aspects of Magmatism: The Nature and Origin of Cordilieran Magmatism . J. Lawford Anderson, Ed. Geological Society of America, Boulder, CO, 1990. xii, 414 pp., illus. $65. Geological Society of America Memoir 174." Science 252, no. 5005 (April 26, 1991): 589–90. http://dx.doi.org/10.1126/science.252.5005.589.b.

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9

Bateman, Paul C. "Aspects of Magmatism: The Nature and Origin of Cordilieran Magmatism . J. Lawford Anderson, Ed. Geological Society of America, Boulder, CO, 1990. xii, 414 pp., illus. $65. Geological Society of America Memoir 174." Science 252, no. 5005 (April 26, 1991): 589–90. http://dx.doi.org/10.1126/science.252.5005.589-b.

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10

Fan, Yunsong, Jinjiang Zhang, Chao Lin, Xiaoxian Wang, and Bo Zhang. "Miocene granitic magmatism constrains the early E-W extension in the Himalayan Orogen: A case study of Kung Co leucogranite." Lithos 398-399 (October 2021): 106295. http://dx.doi.org/10.1016/j.lithos.2021.106295.

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11

Liao, Wen, Bao-Fu Han, Yan Xu, and Ang Li. "Ediacaran initial subduction and Cambrian slab rollback of the Junggar Ocean: New evidence from igneous tectonic blocks and gabbro enclave in Early Palaeozoic accretionary complexes, southern West Junggar, NW China." Geological Magazine 158, no. 10 (May 11, 2021): 1811–29. http://dx.doi.org/10.1017/s0016756821000376.

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AbstractNew zircon U–Pb ages and whole-rock chemical data from four adakitic and two non-adakitic igneous rocks as tectonic blocks in the southern West Junggar accretionary complexes, northwestern China and one gabbro enclave in adakitic block provide further constraints on the initial subduction and following rollback process of the Junggar Ocean as part of southern Palaeo-Asian Ocean. The oldest adakitic monzonite in Tangbale is intruded by the non-adakitic quartz monzonite at 549 Ma, and the youngest adakitic diorite in Tierekehuola formed at 520 Ma. The Ediacaran–Cambrian magmatism show a N-wards younger trend. The high-SiO2 adakitic rocks have high Sr (300–663 ppm) and low Y (6.68–12.2 ppm), with Sr/Y = 40–84 and Mg no. = 46–60, whereas the non-adakitic rocks have high Y (13.2–22.7 ppm) and Yb (2.32–2.92 ppm), with Mg no. = 36–40. The gabbro has high MgO (14.81–15.11 wt%), Co (45–48 ppm), Cr (1120–1360 ppm) and Ni (231–288 ppm), with Mg no. = 72–73. All the samples show similar large-ion lithophile element (LILE) and light rare earth element (LREE) enrichment and Nb, Ta, Ti and varying Zr and Hf depletion, suggesting that they were formed in a subduction-related setting. The adakitic rocks were produced by partial melting of subducted oceanic slab, but the melts were modified by mantle wedge and slab-derived fluids; the non-adakitic rocks were likely derived from partial melts of the middle-lower arc crust; and the gabbro originated from the mantle wedge modified by slab-derived fluids. The magmatism could have been generated during the Ediacaran initial subduction and Cambrian slab rollback of the Junggar Ocean.
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12

Ranta, Jukka-Pekka, Eero Hanski, Holly Stein, Matthew Goode, Timo Mäki, and Atte Taivalkoski. "Kivilompolo Mo mineralization in the Peräpohja belt revisited: Trace element geochemistry and Re-Os dating of molybdenite." Bulletin of the Geological Society of Finland 92, no. 2 (December 15, 2020): 131–50. http://dx.doi.org/10.17741/bgsf/92.2.004.

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The Kivilompolo molybdenite occurrence is located in the northern part of the Peräpoh jabelt, within the lithodemic Ylitornio nappe complex. It is hosted within a deformed porphyritic granite belonging to the pre-orogenic 1.99 Ga Kierovaara suite. The minerali-zation occurs mostly as coarse-grained molybdenite flakes in boudinaged quartz veins, with minor chalcopyrite, pyrite, magnetite, and ilmenite. In this study, we report new geochemical data from the host-rock granite and Re-Os dating results of molybdenite from the mineralization. For the whole-rock geochemistry, the mineralized granite is similar to the Kierovaara suite granites analyzed in previous studies. Also, the ca. 2.0 Ga Re-Os age for molybdenite is equal, within error, to the U-Pb zircon age of the Kierovaara suite granite. In addition, similar molybdenite and uraninite ages have been reported from the Rompas-Rajapalot Au-Co occurrence located 30 km NE of Kivilompolo. We propose that the magmatism at around 2.0 Ga ago initiated the hydrothermal circulation that was responsible for the formation of the molybdenite mineralization at Kivilompolo and the primary uranium mineralization associated with the Rompas-Rajapalot Au-Co occurrence or at least, the magmas provided heating, and in addition potentially saline magmatic fluids and metals from a large, cooling magmatic-hydrothermal system.
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13

Pierosan, Ronaldo, Evandro F. Lima, Lauro V. S. Nardi, Cristina P. de Campos, Artur C. Bastos Neto, José M. T. M. Ferron, and Maurício Prado. "Paleoproterozoic (~1.88Ga) felsic volcanism of the Iricoumé Group in the Pitinga Mining District area, Amazonian Craton, Brazil: insights in ancient volcanic processes from field and petrologic data." Anais da Academia Brasileira de Ciências 83, no. 3 (September 2011): 921–37. http://dx.doi.org/10.1590/s0001-37652011000300012.

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The Iricoumé Group correspond to the most expressive Paleoproterozoic volcanism in the Guyana Shield, Amazonian craton. The volcanics are coeval with Mapuera granitoids, and belong to the Uatumã magmatism. They have U-Pb ages around 1880 Ma, and geochemical signatures of α-type magmas. Iricoumé volcanics consist of porphyritic trachyte to rhyolite, associated to crystal-rich ignimbrites and co-ignimbritic fall tuffs and surges. The amount and morphology of phenocrysts can be useful to distinguish lava (flow and dome) from hypabyssal units. The morphology of ignimbrite crystals allows the distinction between effusive units and ignimbrite, when pyroclasts are obliterated. Co-ignimbritic tuffs are massive, and some show stratifications that suggest deposition by current traction flow. Zircon and apatite saturation temperatures vary from 799°C to 980°C, are in agreement with most temperatures of α-type melts and can be interpreted as minimum liquidus temperature. The viscosities estimation for rhyolitic and trachytic compositions yield values close to experimentally determined melts, and show a typical exponential decay with water addition. The emplacement of Iricoumé volcanics and part of Mapuera granitoids was controlled by ring-faults in an intracratonic environment. A genesis related to the caldera complex setting can be assumed for the Iricoumé-Mapuera volcano-plutonic association in the Pitinga Mining District.
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14

Chu, Tu Minh, Ha Xuan Dinh, and Phuong Nguyen. "Some new research outcomes of wolframite-tin-polymetallic metallization in the Huoi Chun area, Huaphanh province, Lao people’s democratic republic (LPDR)." Journal of Mining and Earth Sciences 61, no. 2 (April 29, 2020): 22–32. http://dx.doi.org/10.46326/jmes.2020.61(2).03.

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The paper focuses on clarifying the characteristics of tungsten, tin - polymetallic ore mineralization in the Huoi Chun area based on applying traditional geological methods, collecting documents, methods of studying ore material composition, and legal statistic. The findings are as follows: Mineral ores were generated mainly by material deposition, crystallization of hydrothermal solution, and filling fracture systems. The main minerals occurred in the study area are tungsten, tin, copper, zinc, bismuth. Tungsten, tin-polymetallic metallization was generated in 3 hydrothermal episodes. The symbiotic wolframite - bismuth mineral symbiosis is a discovery of the authors' collective during the implementation of the National project under Protocol code NDT.35.LA / 17. Sn, Cu, Pb, Zn, As, and Cd - bearing minerals are characterized for the middle episode of metallogeny; whereas W, Co, and Bi- bearing minerals were formed during the third episode of hydrothermal metallogeny. The tungsten, tin - polymetallic mineralization could be related to Mesozoic - Cenozoic intrusive magmatism.
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15

Schandl, Eva S., Michael P. Gorton, and Colin J. Bray. "High-temperature brine in chalcopyrite-rich quartz vein 40 km southwest of Sudbury, Ontario." Canadian Journal of Earth Sciences 48, no. 10 (October 2011): 1369–85. http://dx.doi.org/10.1139/e11-033.

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The Lac Panache (Nipissing) gabbro intrudes Huronian metasediments ca. 40 km southwest of the Sudbury Igneous Complex. The gabbro contains disseminated sulfides and is in contact with a chalcopyrite-rich quartz vein that crystallized from highly saline fluids (46.8 ± 3 equivalent wt.% NaCl) at a minimum temperature of 420 ± 27 °C. Chloride and carbonate inclusions in opened fluid inclusion cavities in the vein suggest that the brine contained dissolved metals (in addition to NaCl), such as Fe, Cu, Mn, and Co. The weakly altered quartz vein postdated regional metamorphism and was probably contemporaneous with the 1.7 Ga felsic magmatism and attendant albite alteration in the area. Cl-rich scapolite in the gabbro and highly saline fluid inclusions in the quartz vein suggest the existence of circulating hot brine throughout the tectonic evolution of the region. The 2.2 Ga old gabbro contains an abundance of Cl-rich scapolite intergrown with pyrrhotite and chalcopyrite that formed during the early hydrothermal (deuteric) alteration of the gabbro.
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16

Andronikov, A. V. "Spinel-garnet Iherzolite nodules from alkaline-ultrabasic rocks of Jetty Peninsula (East Antarctica)." Antarctic Science 2, no. 4 (December 1990): 321–30. http://dx.doi.org/10.1017/s0954102090000451.

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The petrography and mineralogy of Iherzolite nodules from an intrusive body of alkaline-ultrabasic rocks on Jetty Peninsula. The nodules are massive with a porphyritic hypidiomorphic granular texture. The main rock-forming minerals are: olivine, pyroxene, garnet and chrome spinel. The nodules are coarse granular spinel-garnet Iherzolites that are chemically similar to pyrope peridotite from Krezemze, Czechoslovakia, and pyrope-bearing peridotite from alkaline ultrabasites of Yakutia, USSR. The Al2O3 content in enstaties and Ca/(Ca + Mg) ratio in co-existing chrome diopside suggest that equilibrium conditions of the mantle mineral assemblage are: T = 875–900°C, P = 20–24 kbar, conditions typical of the spinel-pyrope facies of the upper mantle. Depths of withdrawal of the inclusions do not exceed 60–75 km. Available age determinations of the intrusive alkaline-ultrabasic rocks (145–150 Ma) suggest that alkaline-ultrabasic magmatism and withdrawal of plutonic nodules were related to rifting which resulted in the breakup of the Gondwana supercontinent in the late Mesozoic.
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17

Peng, Hu, Chaoming Xie, Cai Li, and Zhongyue Zhang. "Provenance and palaeogeographic implications of detrital zircons from the lower Carboniferous Riwanchaka Formation of the central Tibetan Plateau." Geological Magazine 156, no. 12 (July 2, 2019): 2031–42. http://dx.doi.org/10.1017/s0016756819000359.

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AbstractThe Longmu Co–Shuanghu suture zone, which divides the Qiangtang terrane into the northern and southern Qiangtang blocks, is regarded as a key locality in reconstructing the evolutionary history of the Palaeo-Tethys Ocean and the break-up of Gondwana. However, although low-temperature – high-pressure metamorphic rocks and ophiolites have been documented within the Longmu Co–Shuanghu suture zone, it remains unclear whether it is an in situ suture zone and represents the relic of the main Palaeo-Tethys Ocean. The uncertainty stems mainly from the limited systematic studies of the provenance, palaeontological evidence and depositional settings of strata on either side of the Longmu Co–Shuanghu suture zone (i.e. northern and southern Qiangtang blocks). Here we report new detrital zircon U–Pb ages and palaeontological data from Lower Carboniferous strata (Riwanchaka Formation) of the northern Qiangtang block, central Tibet. The Riwanchaka Formation contains warm-climate biota with Cathaysian affinities. Provenance analysis reveals that the formation has detrital zircon spectra similar to those from strata of the Yangtze Plate, and it contains a large proportion of zircons with ages (~360 Ma) similar to the timing of synsedimentary magmatic arc activity, implying an active continental margin setting associated with northward subduction of the Palaeo-Tethyan oceanic lithosphere. Conversely, the Carboniferous–Permian strata from the southern Qiangtang block contain cool-water faunas of Gondwanan affinity and exhibit minimum zircon crystallization ages that are markedly older than their depositional ages, suggesting a passive continental margin setting. The differences in provenance, palaeontological assemblages and depositional settings of the Carboniferous to Permian strata either side of the Longmu Co–Shuanghu suture zone indicate the existence of an ancient ocean between the northern and southern Qiangtang blocks. Combining the new findings with previous studies on high-pressure metamorphic rocks, arc magmatism and ophiolites, we support the interpretation that the Longmu Co–Shuanghu suture zone is an in situ suture zone that represents the main suture of the Palaeo-Tethys Ocean.
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18

Caritat, Patrice de, Brent I. A. McInnes, Alexander T. Walker, Evgeniy Bastrakov, Stephen M. Rowins, and Alexander M. Prent. "The Heavy Mineral Map of Australia: Vision and Pilot Project." Minerals 12, no. 8 (July 28, 2022): 961. http://dx.doi.org/10.3390/min12080961.

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Анотація:
We describe a vision for a national-scale heavy mineral (HM) map generated through automated mineralogical identification and quantification of HMs contained in floodplain sediments from large catchments covering most of Australia. The composition of the sediments reflects the dominant rock types in each catchment, with the generally resistant HMs largely preserving the mineralogical fingerprint of their host protoliths through the weathering-transport-deposition cycle. Heavy mineral presence/absence, absolute and relative abundance, and co-occurrence are metrics useful to map, discover and interpret catchment lithotype(s), geodynamic setting, magmatism, metamorphic grade, alteration and/or mineralization. Underpinning this vision is a pilot project, focusing on a subset from the national sediment sample archive, which is used to demonstrate the feasibility of the larger, national-scale project. We preview a bespoke, cloud-based mineral network analysis (MNA) tool to visualize, explore and discover relationships between HMs as well as between them and geological settings or mineral deposits. We envisage that the Heavy Mineral Map of Australia and MNA tool will contribute significantly to mineral prospectivity analysis and modeling, particularly for technology critical elements and their host minerals, which are central to the global economy transitioning to a more sustainable, lower carbon energy model.
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19

Busby, Cathy, Alison Graettinger, Margarita López Martínez, Sarah Medynski, Tina Niemi, Claire Andrews, Emilie Bowman, et al. "Volcanic record of the arc-to-rift transition onshore of the Guaymas basin in the Santa Rosalía area, Gulf of California, Baja California." Geosphere 16, no. 4 (May 26, 2020): 1012–41. http://dx.doi.org/10.1130/ges02094.1.

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Abstract The Gulf of California is an archetype of continental rupture through transtensional rifting, and exploitation of a thermally weakened arc to produce a rift. Volcanic rocks of central Baja California record the transition from calcalkaline arc magmatism, due to subduction of the Farallon plate (ca. 24–12 Ma), to rift magmatism, related to the opening of the Gulf of California (&lt;12 Ma). In addition, a suite of postsubduction rocks (&lt;12 Ma), referred to as “bajaites,” are enriched in light rare-earth and other incompatible elements (e.g., Ba and Sr). These are further subdivided into high-magnesian andesite (with 50%–58% SiO2 and MgO &gt;4%) and adakite (&gt;56% SiO2 and MgO &lt;3%). The bajaites correlate spatially with a fossil slab imaged under central Baja and are inferred to record postsubduction melting of the slab and subduction-modified mantle by asthenospheric upwelling associated with rifting or slab breakoff. We report on volcanic rocks of all three suites, which surround and underlie the Santa Rosalía sedimentary rift basin. This area represents the western margin of the Guaymas basin, the most magmatically robust segment of the Gulf of California rift, where seafloor spreading occurred in isolation for 3–4 m.y. (starting at 6 Ma) before transtensional pull-apart basins to the north and south ruptured the continental crust. Outcrops of the Santa Rosalía area thus offer the opportunity to understand the magmatic evolution of the Guaymas rift, which has been the focus of numerous oceanographic expeditions. We describe 21 distinct volcanic and hypabyssal map units in the Santa Rosalía area, using field characteristics, petrographic data, and major- and trace-element geochemical data, as well as zircon isotopic data and ten new 40Ar-39Ar ages. Lithofacies include lavas and lava domes, block-and-ash-flow tuffs, ignimbrites, and hypabyssal intrusions (plugs, dikes, and peperites). Calcalkaline volcanic rocks (13.81–10.11 Ma) pass conformably upsection, with no time gap, into volcanic rocks with rift transitional chemistry (9.69–8.84 Ma). The onset of rifting was marked by explosive eruption of silicic ignimbrite (tuff of El Morro), possibly from a caldera, similar to the onset of rifting or accelerated rifting in other parts of the Gulf of California. Epsilon Hf zircon data are consistent with a rift transitional setting for the tuff of El Morro. Arc and rift volcanic rocks were then juxtaposed by normal faults and tilted eastward toward a north-south fault that lay offshore, likely related to the north-south normal faults documented for the early history of the Guaymas basin, prior to the onset of northwest-southeast transtenional faulting. Magmatism in the Santa Rosalía area resumed with emplacement of high-magnesian andesite lavas and intrusions, at 6.06 Ma ± 0.27 Ma, coeval with the onset of seafloor spreading in the Guaymas basin at ca. 6 Ma. The 9.69–8.84 Ma rift transitional volcanic rocks underlying the Santa Rosalía sedimentary basin provide a maximum age on its basal fill. Evaporites in the Santa Rosalía sedimentary basin formed on the margin of the Guaymas basin, where thicker evaporites formed. Overlying coarse-grained clastic sedimentary fill of the Santa Rosalía basin and its stratiform Cu-Co-Zn-Mn sulfides may have accumulated rapidly, coeval with emplacement of 6.06 Ma high-magnesian andesite intrusions and the ca. 6 Ma onset of seafloor spreading in the Guaymas basin.
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20

Omotunde, V. B. "Mineralogy and Geochemistry of Hydrothermally altered Talcose rocks from Ila Orangun-Oyan areas, part of Southwestern Nigeria." Indian Journal of Science and Technology 13, no. 40 (October 31, 2020): 4244–61. http://dx.doi.org/10.17485/ijst/v13i40.1686.

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Background/Objectives: Talcose rocks within Precambrian Basement Complex serve as relics of Archean greenstones. alterations associated with polycyclic-orogenies that affected this complex is studied to understand mineralogical and geochemical alterations. Methods: Five fresh samples of talcose rocks were collected during field mapping. These samples were cut into thin sections to reveal modal mineralogy, altered minerals and degree of alteration of such minerals. Mineral phase identification of the talcose rocks was conducted using X-ray Broker D8 ADVANCE diffractometer while whole rock analysis was carried out using Inductively Coupled Plasma Mass Spectrometry. Findings: Lithological relationship revealed from field evidence showed that the talc bodies occurred in close association with micaceous schist. The mineral assemblage of talc, tremolite, actinolite, chlorite and calcite suggest low grade greenschist metamorphic facies from possible hydrothermal alteration. Geochemical results revealed the following range of concentrations; SiO2 42.19-59.03%; Al2O3 1.1 - 11.8%; Fe2O3 7.64-9.56%; MgO 24.47-26.639%; Ni 594-1207ppm; Co 43.2-113.9ppm; Sn 6-41ppm; V 32-75ppm and Zr 1.3-58.7ppm, and these are typical of talcose rocks. Petrogenetic studies suggest a komatiitic origin with a peridotitic komatiite precursor for the talc-chlorite-tremolite schist. Enrichment in LREE, depletion in HREE and a negative Eu anomaly suggest alteration of the parent magma for the talcose rock and plagioclase fractionation. The trends observed for the LILE, HFSE and REE suggest possible contamination or mixing of crustal and mantle materials during the formation of the protolith. Ni and Co concentrations are higher than average crustal values with implication for ultrabasic to basic magma composition for the komatiitic progenitor and also suggestive of possible mineralisation. Conclusion: Mineralogical examination has revealed a talc-chlorite-tremolite composition for the talcose rocks with peridotitic komatiite precursory while geochemical composition supported ultrabasic magmatism similar to those with the Ilesha schist belt.
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21

Pang, Zhenshan, Fuping Gao, Yangsong Du, Yilun Du, Zhaojian Zong, Jinsong Xie, and Fengpei Xin. "Late Jurassic to Early Cretaceous magmatism in the Xiong’ershan gold district, central China: implications for gold mineralization and geodynamics." Geological Magazine 157, no. 3 (October 9, 2019): 435–57. http://dx.doi.org/10.1017/s0016756819000888.

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AbstractThe Xiong’ershan area is the third largest gold-producing district in China. The Late Jurassic to Early Cretaceous magmatism in the Xiong’ershan area can be divided into two episodes: early (165–150 Ma) and late (138–113 Ma). Laser ablation – inductively coupled plasma – mass spectrometry (LA-ICP-MS) zircon U–Pb dating yields ages of 160.7 ± 0.6 Ma and 127.2 ± 1.0 Ma for the Wuzhangshan and Huashan monzogranites in the Xiong’ershan area, respectively, representing the two magmatic episodes. The Wuzhangshan monzogranites exhibit adakite-like geochemical features (e.g. high Sr/Y ratios, low Yb and Y contents). Their Sr–Nd–Hf isotopic compositions are consistent with those of the amphibolites of the Taihua Group, indicating that the Wuzhangshan monzogranites were formed from partial melting of the Taihua Group metamorphic rocks. Compared to the Wuzhangshan rocks, the Huashan monzogranites have higher MgO, Cr, Co and Ni contents, but lower Sr/Y and Fe3+/Fe2+. All the samples from the Huashan monzogranites plot in the area between the Taihua Group amphibolite rocks and the mantle rocks in the (87Sr/86Sr)t vs εNd(t) and age vs εHf(t) diagrams, suggesting that the Huashan monzogranites were probably generated by mixing of mantle-derived magmas and the Taihua Group metamorphic basement melts. The gold mineralization (136–110 Ma) is coeval with the emplacement of the late-episode magmas, implying that crustal–mantle mixed magma might be a better target for gold mineralization compared to the ancient metamorphic basement melt. The data presented in this study further indicate that the transformation of the lithosphere from thickening to thinning in the Xiong’ershan area probably occurred between ~160 Ma and ~127 Ma, and that the gold mineralization in this area was probably related to lithospheric thinning.
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22

TENG, XUE-MING, M. SANTOSH, and LI TANG. "The Early Cretaceous Shangzhuang layered mafic intrusion and its bearing on decratonization of the North China Craton." Geological Magazine 155, no. 7 (May 22, 2017): 1475–506. http://dx.doi.org/10.1017/s0016756817000371.

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AbstractThe North China Craton (NCC) is one of the classic examples of decratonization through extensive lithospheric destruction during Mesozoic time. Among the various pulses of magmatism associated with cratonic erosion are the rare mafic intrusions in the Yanshan Belt. Here we investigate the Shangzhuang layered intrusion belonging to this suite, which is characterized by compositional layering with troctolite, noritic gabbro and gabbro/gabbroic anorthosite/gabbrodiorite from the bottom to top. The different lithologies of this intrusion exhibit close field relationships, similar chemical patterns and overall identical Lu–Hf isotopes indicating a co-magmatic nature. The fine-grained gabbros occurring near the margin of the intrusion display U–Pb ages similar to those of the other rocks and are considered to represent the composition of the parent magma, characterized by Fe, Mg and Ti enrichment. The magma was sourced from low-degree partial melting of spinel lherzolite sub-continental lithospheric mantle, which had been enriched by crust–mantle interaction and metasomatic fluids derived from the Mongolian oceanic slab subduction beneath the NCC during Late Palaeozoic time. In addition, limited asthenospheric or deeper-mantle materials were also locally mixed with the enriched mantle as the final source component. Our zircon U–Pb data constrain the emplacement age of this intrusion as c. 128–123 Ma in Early Cretaceous time, and correlates with the regional extensional tectonics between c. 135 and 115 Ma in the eastern and central NCC. Mantle upwelling associated with this event resulted in the thermal and chemical erosion of the lithospheric mantle, and emplacement of the parent magma of this layered intrusion.
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23

Gresov, A. I., and A. V. Yatsuk. "Geological Implications for Gas Saturation of Bottom Sediments in Sedimentary Basins in the Southeastern Sector of the East Siberian Sea." Russian Geology and Geophysics 62, no. 2 (February 1, 2021): 157–72. http://dx.doi.org/10.2113/rgg20194075.

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Abstract —We present research results for the geologic structure of the De Long, Aion, and Pegtymel sedimentary basins of the East Siberian Sea. The materials of geological surveys and drilling in their land area and island surroundings, the data obtained from geophysical surveys conducted by Dal’morneftegeofizika, MAGE, and Sevmorgeologiya, and the seismic and deep-drilling data on the U.S. sector of the Chukchi Sea are summarized and analyzed. Pre-Paleozoic strata and the sedimentary cover have been identified throughout the sections of the sedimentary basins, which suggests the existence of a geologic “cover–basement” boundary rather than an arbitrary called “acoustic basement” horizon. The data on the geologic structure and gas saturation of the upper parts of the sedimentary sections were obtained during the study and gas-geochemical testing of core samples and bottom sediments from coastal shallow wells and corers. Gas contained in the rocks and bottom sediments in the study area includes hydrocarbon gases (HCGs) (СН4, С2–С5, and their unsaturated homologues), СО2, Н2, Не, N2, Ar, and, seldom, CO and H2S. The data on gas saturation of bottom sediments and the geochemical parameters of their syngenetic and epigenetic gases are presented. Areas of abnormal saturation of sediments with CO2, СН4, other HCGs, H2, and He (&gt;5, 0.05, 0.001, 0.005, and 0.005 cm3/kg, respectively) have been identified, and maps of the gas saturation patterns in bottom sediments have been compiled. It is established that both gas saturation and distribution are determined mainly by the geologic evolution, tectonics, magmatism, geocryologic conditions, lithologic composition, catagenesis, coal content, bituminosity of sedimentary rocks, and oil and gas potential of the study area.
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24

Kalashnyk, G. A. "Results of geological and geophysical research on the Subotska structure of Ingulskiy megablock of the Ukrainian shield." Мінеральні ресурси України, no. 4 (December 28, 2020): 4–12. http://dx.doi.org/10.31996/mru.2020.4.4-12.

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The article presents the results of diamond prospecting studies in the Subotska structure of the Inhulskyi megablock of Ukrainian Shield. For the results, it is indicated that the Subotska structure is mimicked by crater rocks and in some cases by manifestations of the vent facies with signs of kimberlitic-lamproitic magmatism. The typical local features of manifestations of explosive structures from maar volcanism in Subotska area are determined. The article presents the results of petrographic and mineralogical study of the core material from exploratory wells on the Subotska structure, the results of study of material composition of the clay fraction, X-ray diffraction analysis of the pellet fraction. Data of the X-ray structural analysis of the pellet fraction of samples taken from the core material from exploratory wells on the Subotska structure indicates the obvious mechanical sum, the head folder of such is calciferous montmorilonite, and also saponite, nontronite, hydromica and kaolinit. The availability of the nontronite and saponite is confirmed by the results of electronic-microscopic reports. Also the article presents the results of studying the secondary lithochemical halos of Cr, Ni, Mg, Co, Ti, V, Fe, covering the geochemical spectrum inherent in alkaline-ultrabasic rocks and their weathering crust. These halos are combined with negative gravitational anomalies associated with the explosive structures in the Subotska area. The structural control of the great part of the detected geochemical anomalies, geochemical halos are determined. According to the degree of manifestation of the complex of criteria five potential diamond-prospective structures are discovered on the Subotska area. There were developed recommendations for further research on the Subotska area.
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25

Rezeau, Hervé, Robert Moritz, Jörn-Frederik Wotzlaw, Samvel Hovakimyan, and Rodrik Tayan. "Zircon Petrochronology of the Meghri-Ordubad Pluton, Lesser Caucasus: Fingerprinting Igneous Processes and Implications for the Exploration of Porphyry Cu-Mo Deposits." Economic Geology 114, no. 7 (November 1, 2019): 1365–88. http://dx.doi.org/10.5382/econgeo.4671.

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Abstract The trace element composition of zircon, especially in tandem with U-Pb geochronology, has become a powerful tool for tracing magmatic processes associated with the formation of porphyry copper deposits. However, the use of the redox-sensitive Eu and Ce anomalies as a potential mineral exploration proxy is controversial. This study presents a comprehensive, temporally constrained data set of zircon trace element compositions (n = 645) for three compositionally distinct magmatic series identified in the Meghri-Ordubad pluton, southernmost Lesser Caucasus. The 30 million years of Cenozoic magmatism in the Meghri-Ordubad pluton are associated with several ore-forming pulses leading to the formation of porphyry copper deposits and epithermal-style mineralization. Our zircon geochemical data constrain the thermal and chemical evolution of this complex intrusive suite and allow an evaluation of the usefulness of zircon as a mineral exploration proxy for porphyry copper deposits. Our results combined with Rayleigh fractionation modeling indicate that the trace element composition of zircon (Th/U, Hf, Ti, YbN/DyN, Eu anomalies) is influenced by the composition and the water concentration of the parental magma, as well as by co-crystallizing titanite and apatite. In contrast, the variations of Ce anomalies remain difficult to explain by magmatic processes and could rather be ascribed to relative fluctuations of the redox conditions. In the Meghri-Ordubad pluton, we do not observe any systematic patterns between the trace element composition in zircons and the different ore-forming pulses. This questions the reliability of using the trace element composition in zircon as an exploration mineral proxy, and it rather emphasizes that a good knowledge of the entire magmatic evolution of a metallogenic province is required.
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Debowski, Beatriz Pereira, Guilherme Loriato Potratz, Armando Dias Tavares Júnior, Maria Virgínia Alves Martins, and Mauro Cesar Geraldes. "Age and Origin of the Massangana Intrusive Suite and Associated Mineralizations, in the Rondônia Tin Province: Petrography, U-Pb, and Lu-Hf Isotopes Zircons." Minerals 12, no. 10 (October 16, 2022): 1304. http://dx.doi.org/10.3390/min12101304.

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Rondônia intrusive suites represent the youngest A-type magmatism that occurred in the SW of the Amazon craton, with mineralizations in Sn, Nb, Ta, W, and topaz. Petrological and isotopic studies (U-Pb and Lu-Hf by LA-ICP-MS) allowed the Massangana granite to be subdivided into São Domingos facies (medium to fine biotite-granite), Bom Jardim facies (fine granite), Massangana facies (pyterlites and coarse granites) and Taboca facies (fine granites). The crystallization ages obtained were between 995.7 ± 9.5 Ma to 1026 ± 16 Ma, and the εHf values vary significantly between positive and negative, showing predominantly crustal sources for forming these rocks. Petrographic studies on ore samples indicate the action of co-magmatic hydrothermal fluids enriched in CO2, H2O, and F. These ores are characterized by endogreisens, exogreisens, pegmatites, and quartz veins that are explored in the São Domingos facies area. The endogreisens and exogreisens are formed by topaz-granites and zinnwaldite-granites; the pegmatites are formed by topaz-zinnwaldite-cassiterite-granites; and the veins by cassiterite-sulfides and quartz. The geometries of the mineralized bodies indicate a dome-shaped contact with the host rocks in the magma chamber and can be attributed to residual accumulation. In this sense, the origin of these ores is related to the evolution of intrusive granitic bodies where the terminal phases of the fluid-enriched magma are lodged in the apical portions, and the origin of the mineralized bodies present a biotite-granite, albite-granite, and endogreisens evolution (potassium series), or biotite-granite, alkali-granite and endogreisens (sodic series) and these rocks present TDM ages that indicate a concerning relation to the non-mineralized rocks of Massangana granite.
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27

Chen, Xinglin, Yongjun Shao, Chunkit Lai, and Cheng Wang. "Genesis of the Longmendian Ag–Pb–Zn Deposit in Henan (Central China): Constraints from Fluid Inclusions and H–C–O–S–Pb Isotopes." Geofluids 2020 (July 13, 2020): 1–21. http://dx.doi.org/10.1155/2020/7352821.

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The Longmendian Ag–Pb–Zn deposit is located in the southern margin of the North China Craton, and the mineralization occurs mainly in quartz veins, altered gneissic wallrocks, and minor fault breccias in the Taihua Group. Based on vein crosscutting relations, mineral assemblages, and paragenesis, the mineralization can be divided into three stages: (1) quartz–pyrite, (2) quartz–polymetallic sulfides, and (3) quartz–carbonate–polymetallic sulfides. Wallrock alteration can be divided into three zones, i.e., chlorite–sericite, quartz–carbonate–sericite, and silicate. Fluid inclusions in all Stage 1 to 3 quartz are dominated by vapor-liquid two-phase aqueous type (W-type). Petrographic and microthermometric analyses of the fluid inclusions indicate that the homogenization temperatures of Stages 1, 2, and 3 are 198–332°C, 132–260°C, and 97–166°C, with salinities of 4.0–13.3, 1.1–13.1, and 1.9–7.6 wt% NaCleqv, respectively. The vapor comprises primarily H2O, with some CO2, H2, CO, N2, and CH4. The liquid phase contains Ca2+, Na+, K+, SO42−, Cl−, and F−. The sulfides have δ34S=–1.42 to +2.35‰ and 208Pb/204Pb=37.771 to 38.795, 207Pb/204Pb=15.388 to 15.686, and 206Pb/204Pb=17.660 to 18.101. The H–C–O–S–Pb isotope compositions indicate that the ore-forming materials may have been derived from the Taihua Group and the granitic magma. The fluid boiling and cooling and mixing with meteoric water may have been critical for the Ag–Pb–Zn ore precipitation. Geological and geochemical characteristics of the Longmendian deposit indicate that the deposit is best classified as medium- to low-temperature intermediate-sulfidation (LS/IS) epithermal-type, related to Cretaceous crustal-extension-related granitic magmatism.
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Wilton, Derek H. C., Benoit M. Saumur, Adrian Gordon, and Marie-Claude Williamson. "Enigmatic massive sulphide mineralization in the High Arctic Large Igneous Province, Nunavut, Canada." Canadian Journal of Earth Sciences 56, no. 7 (July 2019): 790–801. http://dx.doi.org/10.1139/cjes-2018-0156.

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Modern mineral exploration strategies should take into account nontraditional metallogenic models for a given geological environment. Here we document the first detailed study of a massive sulphide showing associated with the High Arctic Large Igneous Province (HALIP) and Sverdrup Basin and in fact, only the second example of mineralization described from Axel Heiberg Island, Queen Elizabeth Islands, Canadian Arctic Archipelago. The Between Lake showing (western Axel Heiberg Island) is a small massive sulphide occurrence within scree/talus below a large ridge of gabbro. It was originally described by explorationists as an orthomagmatic sulphide occurrence hosted within a dioritic dyke. New petrographic and mineralogical analyses indicate that the showing consists predominantly of pyrrhotite with lesser pyrite, trace chalcopyrite, and rare sphalerite. No Ni- or Pb-bearing sulphide minerals were detected. Geochemically, the showing contains some Co and Cu, rare Zn, and generally very low Ni contents (<9 ppm). Sulphur isotope ratios of sulphide minerals range from +3.6 to + 6.6‰, somewhat heavier than expected for magmatic-derived S but isotopically lighter than S associated with local evaporite diapirs (+5.8‰ to +12.2‰). Orthomagmatic sulphides hosted in the diorite typically exhibit even lighter isotopic ratios of –3.9‰ to –1.00‰. The data are consistent with potential mafic–siliciclastic volcanogenic massive sulphide mineralization, or the like, the first documented in the HALIP. High heat flow associated with extensive HALIP magmatism was likely the driving force for such mineralization. Mineral prospectivity in Canada’s High Arctic had been predicated upon the potential presence of magmatic Ni – Cu – platinum group element sulphide mineralization. Rather than negating this potential, our findings provide evidence for additional metallogenic potential for this region of Nunavut.
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Swallow, Elliot J., Colin J. N. Wilson, Bruce L. A. Charlier, and John A. Gamble. "The Huckleberry Ridge Tuff, Yellowstone: evacuation of multiple magmatic systems in a complex episodic eruption." Journal of Petrology 60, no. 7 (June 28, 2019): 1371–426. http://dx.doi.org/10.1093/petrology/egz034.

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Abstract The 2·08 Ma, ∼2500 km3 Huckleberry Ridge Tuff (HRT) eruption, Yellowstone, generated two fall deposits and three ignimbrite members (A, B, C), accompanying a ∼95 x 65 km caldera collapse. Field data imply that the pre-A fall deposits took weeks to be erupted, then breaks of weeks to months occurred between members A and B, and years to decades between B and C. We present compositional and isotopic data from single silicic clasts (pumice or fiamme) in the three ignimbrite members, plus new data from co-eruptive mafic components to reconstruct the nature and evacuation history of the HRT crustal magmatic complex. Geochemical data, building on field characteristics, are used to group nine silicic clast types into seven compositional suites (A1-A3; B1; C1-C3) within their respective members A, B and C. Isotopic data are then added to define four magmatic systems that were tapped simultaneously and/or sequentially during the eruption. Systems 1 and 2 fed the initial fall deposits and then vented throughout member A, accompanied by trace amounts of mafic magma. In member A, volumetrically dominant system 1 is represented by a rhyolite suite (A1: 73·0–77·7 wt % SiO2, 450–1680 ppm Ba) plus a distinct low-silica rhyolite suite (A2: 69·2–71·6 wt % SiO2, >2500 ppm Ba). System 2 yielded only a low-Ba, high-silica rhyolite suite (A3: 76·7–77·4 wt % SiO2, ≤250 ppm Ba). Glass compositions in pumices from systems 1 and 2 show clustering, indicative of the same multiple melt-dominant bodies identified in the initial fall deposits and earliest ignimbrite. Member B samples define suite B1 (70·7–77·4 wt % SiO2, 540–3040 ppm Ba) derived from magmatic system 1 (but not 2) that had undergone mixing and reorganisation during the A: B time break, accompanying mafic magma inputs. Mafic scoriae erupted in upper member B cover similar compositions to the member A clasts, but extend over a much broader compositional range. Member C clast compositions reflect major changes during the B: C time break, including rejuvenation of magmatic system 2 (last seen in member A) as suite C3 (75·3–77·2 wt % SiO2, 100–410 ppm Ba), plus the appearance of two new suites with strong crustal signatures. Suite C2 is another rhyolite (74·7–77·6 wt % SiO2, with Ba decreasing with silica from 2840 to 470 ppm) that defines magmatic system 3. Suite C2 also shows clustered glass compositions, suggesting that multiple melt-dominant bodies were a repetitive feature of the HRT magmatic complex. Suite C1, in contrast, is dacite to rhyolite (65·6–75·0 wt % SiO2, with Ba increasing with silica from 750 to 1710 ppm) that defines magmatic system 4. Compositions from magmatic systems 1 and 2 dominantly reflect fractional crystallization, but include partial melting of cumulates related to earlier intrusions of the same mafic magmas as those syn-eruptively vented. Country rock assimilation was limited to minor amounts of a more radiogenic (with respect to Sr) evolved contaminant. In contrast, systems 3 and 4 show similar strongly crustal isotopic compositions (despite their differences in elemental composition) consistent with assimilation of Archean rocks via partial melts derived from cumulates associated with contrasting mafic lineages. System 3 links to the same HRT mafic compositions co-erupted in members A and B. In contrast, system 4 links to olivine tholeiite compositions erupted in the Yellowstone area before, sparsely during, and following the HRT itself. All four magmatic systems were housed beneath the HRT caldera area. Systems 1 and 2 were hosted in Archean crust that had been modified by Cretaceous/Eocene magmatism, whereas systems 3 and 4 were hosted within crust that retained Archean isotopic characteristics. The extreme compositional diversity in the HRT highlights the spatial and temporal complexities that can be associated with large-volume silicic magmatism.
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30

Chen, Xiao-Dong, Bin Li, Chong-Bo Sun, and Hong-Bing Zhou. "Protracted Storage for Calc-Alkaline Andesitic Magma in Magma Chambers: Perspective from the Nageng Andesite, East Kunlun Orogen, NW China." Minerals 11, no. 2 (February 13, 2021): 198. http://dx.doi.org/10.3390/min11020198.

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Calc-alkaline andesitic rocks are a major product of subduction-related magmatism at convergent margins. Where these melts are originated, how long they are stored in the magma chambers, and how they evolved is still a matter of debate. In this study, we present new data of whole-rock elemental and Sr-Nd-Pb isotope compositions, and zircon U-Pb-Th isotopes and trace element contents of Nageng (basaltic-)andesites in the East Kunlun Orogen (NW China). The similar age and whole-rock elemental and Sr-Nd-Pb isotope contents suggest that the Nageng andesite and basaltic andesite are co-magmatic. Their low initial 87Sr/86Sr (0.7084–0.7086) but negative εNd(t) values (−10.61 to −9.49) are consistent with a magma source from the juvenile mafic lower crust, possibly related to the mantle wedge with recycled sediment input. The U-Pb age gap between the zircon core (ca. 248 Ma) and rim (ca. 240 Ma) reveals a protracted magma storage (~8 Myr) prior to the volcanic eruption. When compared to the zircon rims, the zircon cores have higher Ti content and Zr/Hf and Nb/Ta ratios, but lower Hf content and light/heavy rare earth element ratios, which suggests that the parental magma was hotter and less evolved than the basaltic andesite. The plagioclase accumulation likely resulted in Al2O3-enrichment and Fe-depletion, forming the calc-alkaline signature of the Nageng (basaltic-)andesites. The magma temperature, as indicated by the zircon saturation and Ti-in-zircon thermometry, remained low (725–828 °C), and allowed for the magma chamber to survive over ~8 Myr. The decreasing εHf(t) values from zircon core (avg. 0.21, range: −1.28 to 1.32) to rim (avg. −3.68, range: −7.30 to −1.13), together with the presence of some very old xenocrystic zircons (268–856 Ma), suggest that the magma chamber had undergone extensive crustal contamination.
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31

Sutarto, Sutarto, Arifudin Idrus, Agung Harijoko, Lucas Donny Setijadji, Franz Michael Meyer, Sven Sindern, and Sapto Putranto. "Hydrothermal Alteration and Mineralization of the Randu Kuning Porphyry Cu-Au and Intermediate Sulphidation Epithermal Au-Base Metals Deposits in Selogiri, Central Java, Indonesia." Journal of Applied Geology 1, no. 1 (July 26, 2016): 1. http://dx.doi.org/10.22146/jag.26951.

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The Randu Kuning Porphyry Cu-Au prospect area is situated in the Selogiri district, Wonogiri regency, Central Java, Indonesia, about 40 km to the South-East from Solo city, or approximately 70 km east of Yogyakarta city. The Randu Kuning area and its vicinity is a part of the East Java Southern Mountain Zone, mostly occupied by both plutonic and volcanic igneous rocks, volcaniclastic, silisiclastic and carbonate rocks. Magmatism-volcanism products were indicated by the abundant of igneous and volcaniclastic rocks of Mandalika and Semilir Formation. The Alteration zones distribution are generally controlled by the NE–SW and NW–SE trending structures. At least eight types of hydrothermal alteration at the Randu Kuning area and its vicinity had been identified, i.e. magnetite + biotite ± K-feldspar ± chlorite (potassic), chlorite + sericite + magnetite ± actinolite, chlorite + magnetite ± actinolite ± carbonate (inner propylitic), chlorite + epidote ± carbonate (outer propylitic), sericite + quartz + pyrite (phyllic), illite + kaolinite ± smectite (intermediate argillic), illite + kaolinite ± pyrophyllite ± alunite (advanced argillic) and quatz + chlorite (sillisic) zones. The Randu Kuning mineralization at Selogiri is co existing with the porphyry Cu-Au and intermediate sulphidation epithermal Au-base metals. Mineralization in the porphyry environment is mostly associated with the present of quartz-sulphides veins including AB, C, carbonate-sulphides veins (D vein) as well as disseminated sulphides. While in the epithermal prospect, mineralization is particularly associated with pyrite + sphalerite + chalcopyrite + carbonate ± galena veins as well as hydrothermal breccias. The Randu Kuning porphyry prospect has copper gold grade in range at about 0.66–5.7 gr/t Au and 0.04–1.24 % Cu, whereas in the intermediate sulphidation epithermal contain around 0.1–20.8 gr/t Au, 1.2–28.1 gr/t Ag, 0.05–0.9 % Zn, 0.14–0.59 % Pb and 0.01–0.65 % Cu.
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32

Lu, Jia, Chen Zhang, and Dongdong Liu. "Geochronological, Geochemical and Sr-Nd-Hf Isotopic Studies of the A-type Granites and Adakitic Granodiorites in Western Junggar: Petrogenesis and Tectonic Implications." Minerals 10, no. 5 (April 29, 2020): 397. http://dx.doi.org/10.3390/min10050397.

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Late Carboniferous magmatism in the Western Junggar region of the Central Asian Orogenic Belt (CAOB) provides a critical geological record of regional tectonic and geodynamic history. In this study, we determined the zircon U-Pb isotopic compositions, bulk-rock Sr-Nd-Hf isotopic compositions, and major and trace element geochemistry of two granitic bodies in the Western Junggar, with the aim of constraining their emplacement ages, magmatic origin, and geodynamic significance. Radiometric ages indicate that the plutons were emplaced during the Late Carboniferous (322–307 Ma). Plutons in the North Karamay region are characterized by high Sr content (347–362 ppm) and low Y content (15.3–16.7 ppm), yielding relatively high Sr/Y ratios (20.8–23.7). They show consistent Yb (1.68–1.85 ppm), Cr (16–19 ppm), Co (7.5–8.1 ppm) and Ni (5.9–6.6 ppm) content, similar to that of modern adakites. The Hongshan plutons are characterized by high SiO2 (69.95–74.66 wt%), Na2O (3.26–3.64 wt%), and K2O (4.84–5.16 wt%) content, low Al2O3 (12.02–12.84 wt%;) and MgO (0.13–0 18 wt%) content, and low Mg# values (0.16–0.22). This group shows a clear geochemical affinity with A-type granites. All of the studied granitoids have positive εNd(t) (+4.89 to +7.21) and εHf(t) (+7.70 to +13.00) values, with young TDM(Nd) 806–526 Ma) and TDM(Hf) (656–383 Ma) ages, indicating a substantial addition of juvenile material. The adakitic granodiorites in the North Karamay region were likely generated via partial melting of thickened lower crust, while the A-type granites in the Hongshan area may have been derived from the melting of lower-middle crust in an intra-oceanic arc, which consists mainly of oceanic crust. The emplacement of these granitoids represents a regional magmatic “flare up”, which can be explained by the rollback of a subducting slab.
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33

Mills, Andrea, and Hamish Sandeman. "Lithostratigraphy and lithogeochemistry of Ediacaran alkaline basaltic rocks of the Musgravetown Group, Bonavista Peninsula, northeastern Newfoundland, Canada: an extensional volcanogenic basin in the type-Avalon terrane." Atlantic Geology 57 (August 5, 2021): 207–34. http://dx.doi.org/10.4138/atlgeol.2021.010.

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Volcanic rocks of the Ediacaran Musgravetown Group on Bonavista Peninsula, Avalon terrane, Newfoundland, include basal ca. 600 Ma calc-alkaline basalt succeeded by continental tholeiite and alkaline rhyolite of the ca. 592 Ma Plate Cove volcanic belt (Bull Arm Formation), indicating a change from subduction-related to extensionrelated tectonic regimes during that interval. Alkalic basalts on northeastern (Dam Pond area) and southwestern (British Harbour area) Bonavista Peninsula occur below and above, respectively, the ca. 580 Ma glacial Trinity facies. Dam Pond basalt occurs in a structural dome intercalated with and flanked by fine-grained, siliciclastic deposits (Big Head Formation) overlain by Trinity facies. The British Harbour basalt occurs above the Trinity facies, in an upward- coarsening sandstone sequence (Rocky Harbour Formation) overlain by red beds of the Crown Hill Formation (uppermost Musgravetown Group). The Rocky Harbour and Big Head formations are likely stratigraphically interfingered proximal and distal deposits, respectively, derived from erosion of the Bull Arm Formation and older Avalonian assemblages.The Big Head basalts have lower SiO2, Zr, FeOT, P2O5, TiO2 and higher Mg#, Cr, V, Co and Ni contents, and are therefore more primitive than the more FeOT-, TiO2-, and P2O5-rich British Harbour basalts. Large-ionlithophile and rare-earth-element concentrations and ratios indicate that both suites originated from low degree partial melts of deep, weakly garnet-bearing, undepleted asthenospheric peridotite sources, with magma conduits likely focused along regional extensional faults. The protracted and episodic extension-related volcanic activity is consistent with a geodynamic setting that evolved from a mature arc into extensional basins with slowly waning magmatism, possibly involving slab rollback and delamination followed by magmatic underplating. The duration and variation of both volcanism and sedimentation indicate that the Musgravetown Group should be elevated to a Supergroup in order to facilitate future correlation of its constituent parts with other Avalonian basins.
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34

Legostaeva, Yana, Anna Gololobova, and Vladimir Popov. "Geochemical Risks of Diamond Mining in Siberia." Environmental Sciences Proceedings 5, no. 1 (December 7, 2020): 4. http://dx.doi.org/10.3390/iecg2020-08907.

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Geochemical risk is caused by the release of hazardous chemicals to the earth surface. Primary diamond deposits are located in difficult mining and geological conditions. They represent natural geochemical anomalies associated with the mineral composition of rocks and groundwater, which contain a number of impurity elements with high toxic properties (Tl, Di, As, Cd, Hg), and increased concentrations of heavy metals (Cu, Zn, Pb, Ti, V and others). The paper presents the physical-geographical and mining-geological conditions of the diamondiferous region, where three large mining and processing divisions operate: Udachninsky, Aikhalsky and Nyurbinsky. pH, organic matter (humus), total nitrogen, and physical clay were identified in the study samples, by using potentiometric, photoelectric colorimetric, spectrophotometric methods, and pipette method for particle size analysis. Gross and mobile forms of trace elements were determined by atomic absorption and emission spectrometry. The groups of elements were identified that determined the natural and man-made anomalies. The accumulation of Cr, Ni, and Co determines the influence of kimberlite magmatism in general. Cu, Sr, and Li are accumulated in the soils of the Daldyn-Alakit diamond-bearing region. Increased concentrations of Mn and Cu are typical in the soils of the Sredne-Markhinsky diamond-bearing region. An assessment of the ecological and geochemical state of the study areas was carried out according to the indicator of total pollution (Zc), which is the sum of the excess of the concentration coefficients of chemical elements accumulating in anomalies. Areas of pollution and zones of the greatest risk are localized, which occupy up to 75% of the total area of industrial sites. They confined to quarry-dump complexes and to areas of impact of tailing dumps of processing plants.
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35

Sardi, Fernando G., Pablo Grosse, Mamoru Murata, and Rafael Pablo Lozano Fernández. "Internal framework and geochemistry of the Carboniferous Huaco granite pluton, Sierra de Velasco, NW Argentina." Andean Geology 45, no. 2 (March 5, 2018): 229. http://dx.doi.org/10.5027/andgeov45n2-3015.

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The A-type Huaco granite pluton of the Velasco range (Sierras Pampeanas of northwest Argentina) is formed by three coeval granitic facies and contains subordinate coeval-to-late facies, as well as enclaves, dikes and stocks that show different temporal relations, textures and compositions. The dominant facies (Regional Porphyritic Granite; RPG) is a porphyritic two-mica monzo- to syenogranite, with abundant microcline megacrysts up to 12 cm in size. It was emplaced in a dominant extensional setting and has a mainly crustal source but with participation of a mantle-derived component. The RPG transitions towards two coeval and co-genetic granite facies, at its margins (Border Granite; BG) and around Be-pegmatites (Adjacent Porphyritic Granite; APG). These two facies have a finer-grained texture and smaller and less abundant megacrysts. They are also monzo- to syenogranites, but a slight decrease in the biotite/muscovite ratio is observed from the BG to the RPG to the APG. Trace element modeling suggests that the RPG, BG and APG differentiated from the same magma source by fractional crystallization. Temporally older mafic (ME) and felsic (FE) enclaves are common in the pluton. The ME can be considered partially assimilated remnants of a mafic component in the genesis of the RPG, whereas the FE seem to be remnants of premature aplites. Other subordinate rocks intrude the RPG and are, hence, temporally younger: felsic dikes (FD), dioritic dikes (DD) and equiganular granites (EqG) are clearly posterior, whereas coeval-to-late Be-pegmatites (BeP) and orbicular granites (OG) formed during the final stages of crystallization of the pluton. The BeP, OG and FD indicate the presence of abundant water and volatiles. The EqG form small stocks that intrude the RPG and were possibly originated from purely crustal sources. The DD probably correspond to a younger unrelated episode of mafic magmatism.
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36

FLORISBAL, LUANA MOREIRA, LAURO NARDI, MARIA DE FÁTIMA BITENCOURT, and LEANDRO MENEZES BETIOLLO. "Geoquímica das Rochas Máficas Toleíticas da Suíte Pós-Colisional Paulo Lopes, Neoproterozóico do Sul do Brasil." Pesquisas em Geociências 32, no. 2 (December 31, 2005): 69. http://dx.doi.org/10.22456/1807-9806.19547.

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The Paulo Lopes Suite (SPL), composed of the Paulo Lopes Granite (GPL), Garopaba Granitoids (GG) and Silveira Gabbro (GS), is an association of contemporaneous acid and basic rocks, comprising monzo and syenogranites associated to basic dikes, with abundant mafic microgranular enclaves, interpreted as co-mingling products. The contacts between the granitoids and the basic rocks are evidences of coeval and interactive magmas. The Silveira Gabbro occurs in the study area as a main body and several narrow dikes of NNE orientation. Field relations define a chronological order of magmatic events, where the GPL is the first magmatic pulse and, while steel partially crystallized, was intruded by mingled magmas, represented by the GG and the GS. The basic components are medium-grained, equigranular rocks, with subophitic and ophitic textures. The centre of the main body contains medium- to coarse-grained, equigranular rocks, where agglomerates of early-formed clinopyroxene and plagioclase crystals are found. In the chilled margins, they are microporphyritc rocks of aphanitic groundmass, indicative of rapid crystallization. The Silveira Gabbro rocks are composed of labradorite-andesine, orthopyroxene, augite, pigeonite, olivine (occasionally serpentinized), Fe-hornblende and magnesian hornblende, red biotite, magnetite, ilmenite, apatite, and baddeleyite. The composition is tholeiitic, similar to the high-Ti-P basalts of the Serra Geral Formation. Their high contents of K, Rb, Sr and Ba, as well as negative anomalies of Nb and Ta in multielemental diagrams are similar to the ones observed in magmatic rocks from mature arcs or post-collisional environments. The Neoproterozoic basic rocks may be discriminated from the ones belonging to the Cretaceous Serra Geral Formation by their higher contents of alcalis, Cs, U, Th, and by their fractionated REEpatterns, expressed in the La/LuN ratio. The associated granitoids are structural and compositionally compatible with the ones found in post collisional settings, which indicates that the SPL magmatism developed in such environment.
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37

Tan, Jun, Jun-Hao Wei, Shao-Qing Zhao, Yan-Jun Li, Yan Liu, Xiao-Yang Liu, Fei Zhang, Jin-Rong Gan, and Zhi-Hua Wang. "Petrogenesis of Late Triassic high-Mg diorites and associated granitoids with implications for Paleo-Tethys evolution in the northeast Tibetan Plateau." GSA Bulletin 132, no. 5-6 (September 17, 2019): 955–76. http://dx.doi.org/10.1130/b35225.1.

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Abstract Recent research on Paleo-Tethys tectonics has identified a huge late Paleozoic to Mesozoic igneous belt that extends more than 2500 km in the northeast Tibetan Plateau. However, the magma genesis and evolution in this belt remains a subject of considerable debate. This paper presents a combination of zircon U-Pb ages, mineral compositions, major and trace element concentrations, and Sr-Nd-Hf isotopic data for the plutons across the Zhiduo arc belt that marks the site connecting different tectonic-magmatic units. The studied rocks from one quartz diorite, two granodiorite plutons, and their mafic enclaves define a continuous compositional evolution varying from high- to medium-K calc-alkaline gabbroic diorite to granodiorite. Laser ablation–inductively coupled plasma–mass spectroscopy U-Pb analyses of zircons from these three plutonic suites and one mafic enclave yield Late Triassic ages of 222–217 Ma, establishing that the mafic and felsic magmas were nearly coeval. All these rocks are featured by zoned hornblende and plagioclase with Mg- and Ca-rich mantles or oscillatory change in compositions. They exhibit high and variable MgO (up to 4.88–5.66 wt%), Cr, and Ni contents except that one granitoid pluton (Dangjiangrong) possesses high Co (up to 145.0 ppm). They are characterized by subduction-type trace element patterns, with prominent positive Rb, Th, Pb, and K anomalies and negative Ba, Nb, P, and Ti. Together with continuous and heterogeneous Sr-, Nd-, and zircon Hf-isotopic compositions, it suggests that these Late Triassic high-Mg diorites and associated granitoids were generated through magma mixing and fractional crystallization accompanied by chemical exchange. Taking into account the magmatic record from nearby regions, we suggest that double-sided subduction and rollback of the subducting Paleo-Tethys oceanic slab is the main mechanism to generate geochemically-varied magmatism in the northeast Tibetan Plateau, and eventually close the Paleo-Tethys Ocean during much of the Late Triassic.
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38

Halkoaho, Tapio, Marjaana Ahven, O. Tapani Rämö, Janne Hokka, and Hannu Huhma. "Petrography, geochemistry, and geochronology of the Sc-enriched Kiviniemi ferrodiorite intrusion, eastern Finland." Mineralium Deposita 55, no. 8 (January 23, 2020): 1561–80. http://dx.doi.org/10.1007/s00126-020-00952-2.

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Abstract The Kiviniemi mafic intrusion, near the eastern margin of the Paleoproterozoic Central Finland Granitoid Complex, is both spatially and temporally associated with post-kinematic Fe-Ti-P-enriched Svecofennian orogenic mafic magmatism. The main rock types in this small (~ 15 ha) intrusion are garnet-bearing fayalite ferrodiorite, leucoferrodiorite, ferromonzodiorite, and pyroxene diorite. The garnet-bearing fayalite ferrodiorite and leucoferrodiorite contain 50–281 ppm Sc, 275–5600 ppm Zr, and 58–189 ppm Y (n = 42), delineating a mineralized deposit some 2.5 ha in extent. Overall, these rocks show an evolved (iron-enriched) tholeiitic character; low values of Ni (< 20–40 ppm), Cr (< 20 ppm), and Cu (< 20–80 ppm); and high contents of Zn (213–700 ppm). The rock-forming minerals in the ferrodioritic rocks are (ferro)hedenbergite, plagioclase (~ An40), ferropargasite and ferroedenite, almandine garnet, and fayalite (Fo1–4). Accessory minerals include zircon, ilmenite, fluorapatite, biotite, pyrite, pyrrhotite, potassium feldspar, grunerite, and clinoferrosilite. Some relict cumulate textures have been preserved, but primary magmatic features have largely been overprinted by strong recrystallization and corona formation. The main carriers of Sc are amphibole, clinopyroxene, and apatite. The remarkably strong enrichment of Sc in ferromagnesian silicates and apatite, rather than in specific Sc-minerals, implies magmatic enrichment. Post-kinematic mafic intrusions in central Finland constitute a bimodal association with co-existing granitoid counterparts. The Kiviniemi mafic intrusion is associated with a coarse megacrystic granite and the two rock type display mingled contacts, indicative of contemporaneity of the two magmas. This conclusion is in accord with the coincident U-Pb zircon ages for the ferrodiorite, at 1857 ± 2 Ma (multigrain ID-TIMS) and the megacrystic granite, at 1860 ± 7 Ma (single-crystal LA-MC-ICP-MS). The initial εNd value of the ferrodiorite and the granite are + 0.1 and − 2.5, respectively. These Nd isotope compositions probably reflect a chondritic mantle source for the ferrodiorite and suggest incorporation of some Archaean crustal material into the granite in the course of magmatic evolution. The resource estimation calculated for Kiviniemi intrusion by using 40 g/t Sc cut off value is 13.4 Mt of rock with an average grade of 162.7 g/t scandium, 1726 g/t zirconium, and 81 g/t yttrium.
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39

Harry, D. L., and J. C. Bowling. "Inhibiting magmatism on nonvolcanic rifted margins." Geology 27, no. 10 (1999): 895. http://dx.doi.org/10.1130/0091-7613(1999)027<0895:imonrm>2.3.co;2.

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40

Wyman, Derek, and Robert Kerrich. "Mantle plume – volcanic arc interaction: consequences for magmatism, metallogeny, and cratonization in the Abitibi and Wawa subprovinces, CanadaThis article is one of a series of papers published in this Special Issue on the theme Lithoprobe — parameters, processes, and the evolution of a continent." Canadian Journal of Earth Sciences 47, no. 5 (May 2010): 565–89. http://dx.doi.org/10.1139/e09-049.

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The Abitibi and Wawa subprovinces of the southern Superior Province differ in terms of the extent of pre-existing 2750 Ma sialic crust and relationships between mantle plume type (tholeiitic basalt – komatiite) and arc type (tholeiite to calc-alkaline basalt – andesite – dacite – rhyolite) volcanic successions but evolved in close proximity to each other. Isotopic data, evidence from the Kapuskasing uplift, continuation of major structures associated with large gold deposits from the Abitibi into the Wawa subprovince and the related occurrence of diamonds in lamprophyric rocks in both subprovinces point to a common evolution prior to and during orogeny. Differences preserved in supracrustal sequences of the two subprovinces suggest that the main petrogenetic controls on orogenic gold deposits and lamprophyre-hosted diamond deposits lay in the lower crust and upper mantle. Similar processes must also have been active where gold and diamonds are associated on other Archean cratons, such as the Slave and possibly the Kaapvaal craton. Based on evidence preserved in the Abitibi–Wawa orogen, rapid crustal growth at ∼2.7 Ga was linked to the interplay between plate tectonics and mantle plumes. Key indicators in the model developed for the Abitibi–Wawa arc are the co-existence of plume-related rock types, modern-style adakites, major gold deposits, and lamprophyre-hosted diamond occurrences, at least in cases where shoshonitic host magmas can ascend rapidly through the crust. All of these indicators are now identified on the Kaapvaal craton by 3.1 Ga and many recur together in Paleoproterzoic and younger terranes, suggesting a common mechanism for rapid crustal growth through much of Earth’s history. The variety of granitoid types found within the Abitibi–Wawa orogen demonstrates that local tectonic factors, rather than a hotter average upper mantle, were important in controlling the type of magmas formed. Based on the geodynamic history of the subprovince, mantle plume interaction with an existing volcanic arc and the subduction of oceanic plateau crust played an important role in the formation of magmas similar to Cenozoic adakites. Flat subduction beneath a mantle wedge was probably responsible for the generation of the adakites and also promoted diamond stability at shallow depths while enhancing the reservoirs for subsequent orogenic gold deposits. The history of magmatism and mineralization in the Abitibi and Wawa subprovinces precludes an early or gradual development of a cratonic keel, which instead must have coupled with crust during the latest stages of orogeny.
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41

Parsons, Tom, and George A. Thompson. "Does magmatism influence low-angle normal faulting?" Geology 21, no. 3 (1993): 247. http://dx.doi.org/10.1130/0091-7613(1993)021<0247:dmilan>2.3.co;2.

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42

Barresi, Tony, J. L. Nelson, J. Dostal, and R. Friedman. "Evolution of the Hazelton arc near Terrace, British Columbia: stratigraphic, geochronological, and geochemical constraints on a Late Triassic – Early Jurassic arc and Cu–Au porphyry belt." Canadian Journal of Earth Sciences 52, no. 7 (July 2015): 466–94. http://dx.doi.org/10.1139/cjes-2014-0155.

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Understanding the development of island arcs that accreted to the North American craton is critical to deciphering the complex geological history of the Canadian Cordillera. In the case of the Hazelton arc (part of the Stikine terrane, or Stikinia) in northwestern British Columbia, understanding arc evolution also bears on the formation of spatially associated porphyry Cu–Au, epithermal, and volcanogenic massive sulfide deposits. The Hazelton Group is a regionally extensive, long-lived, and exceptionally thick Upper Triassic to Middle Jurassic volcano-sedimentary succession considered to record a successor arc that was built upon the Paleozoic and Triassic Stikine and Stuhini arcs. In central Stikinia, near Terrace, British Columbia, the lower Hazelton Group (Telkwa Formation) comprises three volcanic-intrusive complexes (Mt. Henderson, Mt. O’Brien, and Kitselas) that, at their thickest, constitute almost 16 km of volcanic stratigraphy. Basal Telkwa Formation conglomerates and volcanic rocks were deposited unconformably on Triassic and Paleozoic arc-related basement. New U–Pb zircon ages indicate that volcanism initiated by ca. 204 Ma (latest Triassic). Detrital zircon populations from the basal conglomerate contain abundant 205–233 Ma zircons, derived from regional unroofing of older Triassic intrusions. Eleven kilometres higher in the section, ca. 194 Ma, rhyolites show that arc construction continued for >10 million years. Strata of the Nilkitkwa Formation (upper Hazelton Group) with a U–Pb zircon age of 178.90 ± 0.28 Ma represent waning island-arc volcanism. Telkwa Formation volcanic rocks have bimodal silica concentrations ranging from 48.1 to 62.8 wt.% and 72.3 to 79.0 wt.% and display characteristics of subduction-related magmatism (i.e., calc-alkaline differentiation with low Nb and Ti and high Th concentrations). Mafic to intermediate rocks form a differentiated suite that ranges from high-Al basalt to medium- to high-K andesite. They were derived from hydrous melting of isotopically juvenile spinel lherzolite in the mantle wedge and from subsequent fractional crystallization. Compared to basalts and andesites (εNd = +5 to +5.5), rhyolites have higher positive εNd values (+5.9 to +6.0) and overlapping incompatible element concentrations, indicating that they are not part of the same differentiation suite. Rather, the rhyolites formed from anatexis of arc crust, probably caused by magmatic underplating of the crust. This study documents a temporal and spatial co-occurrence of Hazelton Group volcanic rocks with a belt of economic Cu–Au porphyry deposits (ca. 205–195 Ma) throughout northwestern Stikinia. The coeval relationship is attributed to crustal underplating and intra-arc extension associated with slab rollback during renewed or reconfigured subduction beneath Stikinia, following the demise of the Stuhini arc in the Late Norian.
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43

Skulski, Thomas, Don Francis, and John Ludden. "Arc-transform magmatism in the Wrangell volcanic belt." Geology 19, no. 1 (1991): 11. http://dx.doi.org/10.1130/0091-7613(1991)019<0011:atmitw>2.3.co;2.

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44

Turner, Simon, Mike Sandiford, and John Foden. "Some geodynamic and compositional constraints on "postorogenic" magmatism." Geology 20, no. 10 (1992): 931. http://dx.doi.org/10.1130/0091-7613(1992)020<0931:sgacco>2.3.co;2.

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45

Handke, Michael J., Robert D. Tucker, and Lewis D. Ashwal. "Neoproterozoic continental arc magmatism in west-central Madagascar." Geology 27, no. 4 (1999): 351. http://dx.doi.org/10.1130/0091-7613(1999)027<0351:ncamiw>2.3.co;2.

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46

COOK, R. D., M. L. CRAWFORD, G. I. OMAR, and W. A. CRAWFORD. "Magmatism and deformation, southern Revillagigedo Island, southeastern Alaska." Geological Society of America Bulletin 103, no. 6 (June 1991): 829–41. http://dx.doi.org/10.1130/0016-7606(1991)103<0829:madsri>2.3.co;2.

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47

Bevier, Mary Lou, and Joseph B. Whalen. "Tectonic significance of Silurian magmatism in the Canadian Appalachians." Geology 18, no. 5 (1990): 411. http://dx.doi.org/10.1130/0091-7613(1990)018<0411:tsosmi>2.3.co;2.

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48

Hopper, John R., John C. Mutter, Roger L. Larson, and Carolyn Z. Mutter. "Magmatism and rift margin evolution: Evidence from northwest Australia." Geology 20, no. 9 (1992): 853. http://dx.doi.org/10.1130/0091-7613(1992)020<0853:marmee>2.3.co;2.

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49

Yin, An, Tom Parsons, and George A. Thompson. "Does magmatism influence low-angle normal faulting?: Comment and Reply." Geology 21, no. 10 (1993): 956. http://dx.doi.org/10.1130/0091-7613(1993)021<0956:dmilan>2.3.co;2.

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50

PASLICK, CASSI R., ALEX N. HALLIDAY, GARETH R. DAVIES, KLAUS MEZGER, and B. G. J. UPTON. "Timing of Proterozoic magmatism in the Gardar Province, southern Greenland." Geological Society of America Bulletin 105, no. 2 (February 1993): 272–78. http://dx.doi.org/10.1130/0016-7606(1993)105<0272:topmit>2.3.co;2.

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