Дисертації з теми "CNF catalyst"
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Hou, Guangfeng. "Substrate Patterning by Nanomachining for Controlled Carbon Nanotube Growth." University of Cincinnati / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1407410214.
Повний текст джерелаHermann, Sascha. "Growth of carbon nanotubes on different support/catalyst systems for advanced interconnects in integrated circuits." Doctoral thesis, Universitätsbibliothek Chemnitz, 2011. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-78189.
Повний текст джерелаAufgrund der kontinuierlichen Verkleinerung von Strukturen in extrem hoch integrierten (engl. Ultra-Large Scale Integration − ULSI) Schaltkreisen werden die Anforderungen an die Materialien und die Technologie in naher Zukunft dramatisch ansteigen. Besonders im Leitbahnsystem sind neue Materialien und Konzepte gefragt. Kohlenstoffnanoröhren (engl. Carbon Nanotubes − CNT) stellen hierbei ein vielversprechendes Material dar, um teilweise oder sogar vollständig metallische Leitbahnen zu ersetzen. Die vorliegende Arbeit liefert einen Beitrag zur CNT-Wachstumskontrolle mit der thermischen Gasphasenabscheidung (engl. Chemical Vapor Deposition − CVD) sowie der Integration von CNTs als vertikale Leitungsverbindungen (Via) in ULSI-Schaltkreisen. Verschiedene Untergrund/Katalysator-Systeme werden in Prozessen zur Katalysatorvorbehandlung sowie zum CNT-Wachstum betrachtet. Die Untersuchungen richten sich insbesondere auf die Katalysatorformierung und die Wechselwirkungen an den Grenzflächen. Diese werden mit dem CNT-Wachstum in Verbindung gebracht. Für Untersuchungen von Grenzflächeninteraktionen, Schichtstruktur, Zusammensetzung sowie CNT-Wachstumscharakteristik werden Analysen mit AFM, REM, TEM, XRD, XPS und Raman-Spektroskopie genutzt. Zunächst werden Voruntersuchungen an dem gut bekannten System SiO2/Ni zur Nanopartikelformierung und CNTWachstum vorgestellt. Dieses System ist gekennzeichnet durch eine schwache Wechselwirkung zwischen Untergrund und Katalysator sowie ungerichtetem Wachstum von mehrwandigen CNTs (MWCNTs). Im Gegensatz dazu hat bei dem System Ta/Ni eine starke Interaktion an der Grenzfläche eine Katalysatornanopartikelbenetzung und vertikales MWCNT-Wachstum zur Folge. Für das W/Ni-System gelten ebenfalls starke Interaktionen an der Grenzfläche. Bei diesem System wird allerdings eine Stranski-Krastanov-Schichtformierung des Katalysators und eine vollständige Unterbindung von CNT-Wachstum erreicht. Bei dem System SiO2/Cr/Ni agieren Cr und Ni als Bi- Katalysatorsystem. Dies führt zu einer neuartigen Nanostruktur, die als Zwischenschicht-CNT (engl. Interlayer Carbon Nanotubes − ICNTs) Struktur definiert wird. Die Schichten sind durch eine gute Qualität von gerichteten MWCNTs charakterisiert, die aus einer geschlossenen, sehr glatten und von den CNTs getragenen Cr/Ni-Schicht herauswachsen. Darüber hinaus bietet die Struktur neue Möglichkeiten für die Integration von CNTs in verschiedene elektronische Anwendungen. Auf der Grundlage der vorgestellten Manipulationsmöglichkeiten von CNT-Wachstum wurde eine Integrationstechnologie für CNTs in Vias abgeleitet. Der Ansatz ist eine oberflächeninduzierte selektive CVD von vertikal gerichteten MWCNTs in Via-Strukturen. Diese Technologie wird mit der Herstellung von einem Via-Testvehikel und dem selektiven CNT-Wachstum in Vias auf 4 Zoll Wafern demonstriert. Um das Widerstandsproblem von CNT-Vias, verursacht durch eine zu niedrige CNT-Dichte, zu reduzieren, wird eine Technologieerweiterung vorgeschlagen. Der Ansatz geht von einer CNT/Metall-Heterostruktur aus, bei der das Metall mit Hilfe der Atomlagenabscheidung (engl. Atomic Layer Deposition − ALD) implementiert wird. Es werden erste Ergebnisse zur CNT-Beschichtung mit reduzierbaren Kupferoxidnanopartikeln vorgestellt und diskutiert
Zhang, Qiang. "Probing the Active Site of CNx Catalysts for the Oxygen Reduction Reaction in Acidic Media: A First-Principles Study." The Ohio State University, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=osu1531312924087566.
Повний текст джерелаAcosta, Roberto I. "Ostwald Ripening of Iron (Fe) Catalyst Nanoparticles on Aluminum Oxide Surfaces (Al2O3) for the Growth of Carbon Nanotubes." Wright State University / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=wright1263485314.
Повний текст джерелаBiddinger, Elizabeth Joyce. "Nitrogen-Containing Carbon Nanofibers as Non-Noble Metal Cathode Catalysts in PEM and Direct Methanol Fuel Cells." The Ohio State University, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=osu1274389015.
Повний текст джерелаLinck, Nicholas W. "PRECISE CONTROL OF CARBON NANOTUBE MEMBRANE STRUCTURE FOR ENZYME MIMETIC CATALYSIS." UKnowledge, 2014. http://uknowledge.uky.edu/cme_etds/35.
Повний текст джерелаRautio, A. R. (Anne-Riikka). "On the stability of carbon nanotube and titania nanowire based catalyst materials:from synthesis to applications." Doctoral thesis, Oulun yliopisto, 2016. http://urn.fi/urn:isbn:9789526211060.
Повний текст джерелаTiivistelmä Katalyyttitukimateriaalin pilaantuminen ja katalyyttinanopartikkelien sintrautuminen johtavat siihen, että muuntajissa ja sensoreissa käytettävät katalyyttiset materiaalit eivät enää toimi, mikä voi aiheuttaa sekä vakavia taloudellisia haittoja että ympäristöhaittoja. Tämän vuoksi kehitetään uusia kestävämpiä katalyyttimateriaaleja. Tässä väitöskirjassa tutkittiin yksiulotteisia nanomateriaaleja, kuten hiilinanoputkia sekä titaanidioksidinanojohtimia ja verrattiin niiden rakenteellista ja toiminnallista stabiiliutta perinteisiin nollaulotteisiin vastineisiin. Erilaisten katalyyttinanomateriaalien ja tukimateriaalien yhdistelmien ikääntymistä arvioitiin röntgendiffraktion, läpäisyelektronimikroskopian ja energiadispersiivisen röntgenanalyysin avulla yli 70 erilaisesta näytteestä. Vaikka hiilinanoputket osoittautuivat termisesti stabiileimmaksi hiilipohjaiseksi tukimateriaaliksi metallinanopartikkeleille, ne ovat kuten kaikki hiilimateriaalit, metallioksiditukimateriaaleja herkempiä korkeille lämpötiloille. Hiilinanoputkipohjaiset katalyytit voivat deaktivoitua katalyyttisen hapettumisen tai kaasuuntumisen vuoksi jo kohtalaisissa lämpötiloissa. Lisäksi elektronisäteellä säteilytetyt nanopartikkelit tai pintavirheitä sisältävät hiilinanoputkipohjaiset katalyytit olivat tutkituista nanomateriaaleista herkimpiä muodostamaan nanorakenteita (koloja, kanavia). Valmistettuja nanokomposiitteja käytettiin onnistuneesti kolmessa eri sovelluksessa: i) vedyn valmistuksessa etanolista höyryreformointireaktiolla, ii) hienokemikaalien valmistuksessa sitraalin hydrauksella sekä iii) elektrodimateriaalina EDLC-kondensaattorissa. Sekä hiilinanoputki- sekä TiO₂-nanojohdinpohjaiset nanomateriaalit toimivat testatuissa katalyyttisissa reaktioissa (etanolin reformointi sekä sitraalin hydraus) paremmin kuin niiden perinteiset vastineet. Lisäksi superkondensaattorin ominaiskapasitanssia onnistuttiin nostamaan lisäämällä hiilinanoputkipohjaisen elektrodin ominaispinta-alaa katalyyttisella hapetusreaktiolla
Vijwani, Hema. "Hierarchical Porous Structures with Aligned Carbon Nanotubes as Efficient Adsorbents and Metal-Catalyst Supports." Wright State University / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=wright1433350549.
Повний текст джерелаDemir-kivrak, Hilal. "Synthesis And Characterization Of Ethanol Electro-oxidation Catalysis." Phd thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/12613887/index.pdf.
Повний текст джерелаner Co-supervisor : Dr. Sadig Kuliyev October 2010, 196 pages In this study, the role of defects, the role of Sn in relation to defects, and the role of oxide phase of tin in ethanol electro-oxidation reaction were investigated. Firstly, adsorption calorimetry measurements were conducted on monometallic (1%Pt, 2%Pt, and 5%Pt) and bi-metallic (5% Pt-Sn) &gamma
-Al2O3 supported Pt catalysts. It was observed that while saturation coverage values decreased, intermediate heats remained same for Pt-Sn catalysts by the increasing amount of tin. The effect of particle size was investigated on Pt/C (pH=5), Pt/C (pH=11) catalysts at different scan rates. At high scan rates (quite above diffusion limitations), current per site activities were nearly the same for 20% Pt/C (E-Tek), Pt/C (pH=11), and Pt/C (pH=5) catalysts, which explained as electro-oxidation reaction takes place at the defects sites. Furthermore, the effect of support on ethanol electro-oxidation was investigated on CNT supported Pt catalyst. Results indicate that only the metal v dispersions improved ethanol electro-oxidation reaction and support did not have any effect on ethanol electro-oxidation reaction. Results on the 20% Pt-Sn/C (15:1 to 1:1 Pt: Sn atomic ratios) and 20% Pt-SnO2/C (6:1 and 1:1) catalysts indicated that ethanol electro-oxidation activity increased by increasing tin amount. For 20% Pt-Sn/C catalysts, Pt-Sn (6:1)/C indicated best activity. On the other hand, 20% Pt-SnO2 (6:1)/C catalyst was better than Pt-Sn (6:1)/C in terms of ethanol electro-oxidation activity due to the fact that there was low contact between Pt and tin oxide particles.
Pap, A. E. (Andrea Edit). "Investigation of pristine and oxidized porous silicon." Doctoral thesis, University of Oulu, 2005. http://urn.fi/urn:isbn:9514277759.
Повний текст джерелаMartins, Daniele Moreira. "Ação Antioxidante e Neuroprotetora de Derivados Pirazolínicos Inéditos." Universidade Federal de Santa Maria, 2008. http://repositorio.ufsm.br/handle/1/8944.
Повний текст джерелаOxidative stress is involved in several neurodegenerative diseases, such as Alzheimer's disease, Parkinson's disease and amyotrophic lateral sclerosis. Oxidative stress seems to be involved in the pathology of dementia/amnesia. It has been suggested that oxidative stress impairs the muscarinic cholinergic system triggering Alzheimer's disease. The muscarinic antagonist scopolamine has been used to induce amnesia in animals. This experimental model has been used in screening anti-amnesic drugs that could be useful for the treatment of dementia. The aim of this study was to evaluate the possible in vitro antioxidant effect of a series of pyrazoline derivatives newly synthesized: (1) 5-hydroxy-3-methyl-5-trifluoromethyl-4,5-dihydro-1H-carbaldehyde-pyrazole, (2) 5-hydroxy-3-methyl-5- trifluoromethyl-4,5-dihydro-1H-1-acetyl-pyrazole, (3) 5-hydroxy-3-methyl-5-trifluoromethyl-4,5-dihydro-1H-carboxyamide-pyrazole, (4) 5-hydroxy-3-methyl-5-trifluoromethyl-4,5-dihydro-1H-1-benzoyl-pyrazole, (5) 5-hydroxy-3-methyl-5-trifluoromethyl-4,5-dihydro-1H-1-(2- hydroxybenzoyl)-pyrazole and (6) 5-hydroxy-3-methyl-5-trifluoromethyl-4,5-dihydro-1H-1-(4-methoxybenzoyl)-pyrazole. Besides, considering the possible involvement of oxidative stress in dementia, the compound that was the most effective in vitro was assessed concerning to its ability to prevent the memory deficit and oxidative stress in a scopolamine-induced amnesia model. Compound (5) had the highest antioxidant capacity in vitro, since it reduced lipid peroxidation (TBARS) basal and stimulated by the pro-oxidants iron, hydrogen peroxide and sodium nitroprusside, having significant effects from 15 μM onwards (p<0.05). Compound (5) also protected against hydrogen peroxide-induced glutathione oxidation, with a significant effect at the concentration of 150 μM (p<0.05). This compound also had the highest total antioxidant activity, demonstrated by its ability to remove the radical 1,1-dyphenyl-2-pycrylhydrazyl (DPPH). Compounds (1) and (4) also reduced lipid peroxidation basal and stimulated by iron and sodium nitroprusside, having significant effects from 15 μM onwards (p<0.05). Compound (2) had the highest ability to reduce iron (p<0.05). Scopolamine administration 30 min before training session resulted in shorter latency to step-down during the test session of the inhibitory avoidance task (p<0.05). Pretreatment with pyrazole compound (5) had no effect per se on the step-down latency. However, pretreatment with compound (5) (100 μmol/kg) 30 min before scopolamine did prevent the amnesic effect of scopolamine (p<0.05). No significant effect of scopolamine or pyrazole treatment was observed on any of the oxidative stress markers evaluated (thiobarbituric acid reactive substances, non-protein sulfhydrylic groups content and activity of enzymes superoxide dismutase and catalase) suggesting that the protective effect of compound (5) was not related to a possible antioxidant activity. Results revealed that pyrazole compound (5) has in vitro antioxidant activity as well as neuroprotective activity in a model of amnesia. These findings suggest that compound (5) could be a promising drug for the treatment of Alzheimer´s disease. However, further studies are needed to elucidate the mechanisms involved in the antiamnesic effect of this compound, as well as its effect on other dementia models.
O estresse oxidativo está envolvido em diversas doenças neurodegenerativas importantes, tais como a doença de Alzheimer, a doença de Parkinson e a esclerose lateral amiotrófica. O estresse oxidativo parece estar envolvido na patologia da demência/amnésia, tendo sido sugerido que as alterações cerebrais decorrentes deste causam danos ao sistema colinérgico muscarínico e que desta forma desencadeiam a doença de Alzheimer. A escopolamina, um antagonista muscarínico, tem sido usado para induzir amnésia em animais, em um modelo experimental para a triagem de drogas que poderiam ser úteis no tratamento da demência. O principal objetivo deste estudo foi avaliar o possível efeito antioxidante in vitro de uma série de derivados pirazolínicos recém sintetizados: (1) 5-hidroxi-3-metil-5-trifluorometil-4,5-diidro-1H-carbaldeido-pirazol, (2) 5-hidroxi-3-metil-5- trifluorometil-4,5-diidro-1H-1-acetil-pirazol, (3) 5-hidroxi-3-metil-5-trifluorometil-4,5-diidro-1Hcarboxiamida- pirazol, (4) 5-hidroxi-3-metil-5-trifluorometil-4,5-diidro-1H-1-benzoil-pirazol, (5) 5-hidroxi-3-metil-5-trifluorometil-4,5-diidro-1H-1-(2-hidroxibenzoil)-pirazol e (6) 5-hidroxi-3-metil-5-trifluorometil-4,5-diidro-1H-1-(4-methoxibenzoil)-pirazol. Além disso, considerando o possível envolvimento do estresse oxidativo na demência, foi avaliada a capacidade do composto mais efetivo in vitro, em prevenir o déficit de memória e o estresse oxidativo em um modelo de amnésia induzida por escopolamina. O derivado pirazolínico (5) apresentou maior capacidade antioxidante in vitro, pois foi o mais efetivo para reduzir a lipoperoxidação (TBARS) basal e induzida pelos pró-oxidantes ferro, peróxido de hidrogênio e nitroprussiato de sódio, tendo efeitos significativos a partir de 15 μM (p<0,05). O composto (5) também protegeu a glutationa da oxidação induzida por peróxido de hidrogênio, tendo efeito significativo na concentração de 150 μM (p<0,05). Este composto também foi o que teve maior atividade antioxidante total, demonstrada pela sua capacidade de remover o radical 1,1-difenil-2-picrilhidrazil (DPPH). Os compostos (1) e (4) também reduziram a lipoperoxidação basal e induzida por ferro e nitroprussiato de sódio, tendo efeitos significativos a partir de 15 μM (p<0,05). O composto (2) apresentou a maior capacidade de redução de ferro (p<0,05). A administração de escopolamina 30 min antes do treino provocou amnésia, medida como a redução na latência para descer da plataforma no teste de esquiva inibitória (p<0.05). O pré-tratamento com o composto (5) 30 min antes da escopolamina não apresentou efeito per se na latência, mas preveniu o efeito amnésico da escopolamina, na dose de 100 μmol/kg (p<0.05). Não foi observado efeito significativo da escopolamina ou do composto (5) em qualquer dos marcadores de estresse oxidativo avaliados (substâncias reativas ao ácido tiobarbitúrico, grupos tiólicos não protéicos e atividade das enzimas superóxido dismutase e catalase), sugerindo que o efeito protetor do composto (5) não está relacionado à sua atividade antioxidante. Os resultados obtidos demonstram que o composto (5) apresenta atividade antioxidante in vitro e neuroprotetora em um modelo de amnésia, sugerindo que este composto pode ser promissor para o tratamento da doença de Alzheimer. No entanto, outros estudos são necessários para elucidar os mecanismos envolvidos na ação anti-amnésica deste composto, bem como o seu efeito em outros modelos de demência.
Griffiths, Owen Glyn. "Environmental life cycle assessment of engineered nanomaterials in carbon capture and utilisation processes." Thesis, University of Bath, 2014. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.629663.
Повний текст джерелаBulmer, John Simmons. "Temperature and Frequency Dependent Conduction Mechanisms Within Bulk Carbon Nanotube Materials." Wright State University / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=wright1290546481.
Повний текст джерелаZhong, Shifa. "Permanganate Reaction Kinetics and Mechanisms and Machine Learning Application in Oxidative Water Treatment." Case Western Reserve University School of Graduate Studies / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=case1618686803768471.
Повний текст джерелаMoya, Arthur Ndumiso. "Fly ash catalysed synthesis of CNFs for use in a photocatalytic CNF-TiO2 hybrid." Thesis, 2016. http://hdl.handle.net/10539/21237.
Повний текст джерелаThis study has explored the CVD synthesis of carbon nanofibres (CNFs) using Eskom’s waste coal fly ash as a catalyst with acetylene and hydrogen as the carbon source and carrier gas, respectively. In the process, a possible growth mechanism for these carbon nanofibres was sought. CNFs were successfully synthesised from fly ash and were found to have an average diameter of 22±7 nm. The growth mechanism of these CNFs was studied using EDS, TEM and laser Raman spectroscopy. It was observed that CNFs grew via root growth on spherical particles of fly ash and by tip growth on irregular-shaped metal oxide agglomerates. Both of these were found, through EDS analysis, to be Fe-rich. CNFs were functionalised between 2-12 h under reflux at 110 °C using a 3:1 (v/v) combination of HNO3 and H2SO4 in order to introduce functional groups onto their surfaces to act as anchors for hydrophilic reactants. The functionalisation of these CNFs was studied using TEM, laser Raman spectroscopy, ATR-FTIR spectroscopy, PXRD, BET, XRF and TGA. ATR-FTIR spectroscopy showed that some carbonyl functional groups were present on the surfaces of these CNFs after functionalisation. The functionalised CNFs (fCNFs) were then treated using a simple hydrothermal method to deposit 10% (m/m) of TiO2 nanoparticles onto their surface. This hydrothermal method employed the drop-wise addition of TiCl4 to a cold water-fCNFs mixture, which was then refluxed at 115 °C for 2-12 h. Laser Raman spectroscopy confirmed the presence of both TiO2 (phase pure anatase) and CNFs. ATR-FTIR spectroscopy provisionally revealed the presence of covalent Ti-O-C bonds. Studies where the duration of exposure to TiCl4 and the functionalisation time of CNFs were examined showed that the particle size and agglomeration of the TiO2 nanoparticles did not affect the surface area of the CNF-TiO2 hybrids significantly. However, CNF-TiO2 hybrids which were shown by TGA to have high fly ash content were observed to have low surface areas. fCNFs functionalised at 2 h had the highest surface area, at all fixed durations of exposure to TiCl4 by comparison with fCNFs which had been functionalised for longer periods.
GR2016
Ko, Yi-Ann, and 柯苡安. "Hydrogenation of p-CNB over gold catalysts." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/78022445440135722588.
Повний текст джерела國立中央大學
化學工程與材料工程研究所
98
Nanosized gold catalyst has been reported to be a good catalyst for the liquid phase hydrogenation reactions due to their excellent activity and selectivity. In this research, two investigations were carried out on the gold catalyst: the affection of cobalt oxides and palladium to gold catalysts. A series of Au catalysts supported on CoOx-TiO2 with various Co contents were prepared. CoOx-TiO2 support was prepared by incipient-wetness impregnation with aqueous solution of Co(NO3)2 on TiO2. Gold catalysts were prepared by deposition-precipitation method (DP) with 1 wt. % Au loading. The molar rations of Co to Ti were 0, 1/99, 6/94, 1/9, 2/8, 3/7 and 1.0, respectively. The catalysts were denoted as Au/CoOx-TiO2 (m), where m represented the atomic ratio of Co/Ti. Palladium was added as a second metal on TiO2 which were prepared by impregnation with aqueous solution of Pd(NO3)2. Gold catalysts were prepared by deposition-precipitation method (DP) with 1 wt. % Au loading. After preparation, the catalysts were reduced under H2 at 423oC for 2h and reduced by sodium borohydride in the methanolic solution (50/50 methanol/water) at 298K under vigorous stirring and used nitrogen stream to remove air. These catalysts were characterized by inductively-coupled-plasma-mass spectrometry (ICP-MS), X–ray diffraction (XRD), transmission electron microscopy(TEM), high resolution transmission electron microscopy(HR-TEM), X-ray photoelectron spectroscopy(XPS) and temperature programmed reduction (TPR). The catalytic properties of gold based catalysts were studied on hydrogenation of p–chloronitrobenzene (p-CNB). The conditions for hydrogenation reaction were 1.2 MPa H2 pressure, 353 K reaction temperature and 500 rpm stirring speed. Methanol was used as the solvent, the concentration of p-CNB was 0.2 M (2.54g p–CNB in 80 ml methanol) and the amount of gold based catalyst was 0.5g. The cobalt oxide in Au/CoOx-TiO2 plays the role of a textural promoter, prevents from sintering of gold particle, increased active sites, and then enhanced catalytic activity. Cobalt not only good in steric effect, but also be an electronic promoter, which donated partial electronic to Au. Au/CoOx-TiO2 (1:9) exhibited the highest activity among the series of Au/CoOx-TiO2. The Au-Pd/TiO2 catalyst which reduced by NaBH4 could reached 100% conversion at 180 min reaction time. The results showed that NaBH4 reduction could prevent Au0 from being oxidized, increased the active site. It could be concluded that suitable cobalt amount shows the best performance, and palladium could promote the conversion effectively.
Alghyamah, Abdulaziz. "Comparison Between CEF and HT-TGIC of Polyolefins Made by Ziegler-Natta and Metallocene Catalysts." Thesis, 2012. http://hdl.handle.net/10012/7130.
Повний текст джерелаAlkhazaal, Abdulaal. "Characterization of Ethylene/α-Olefin Copolymers Made with a Single-Site Catalyst Using Crystallization Elution Fractionation". Thesis, 2011. http://hdl.handle.net/10012/6132.
Повний текст джерелаWang, Tzu-Hao, and 王祖皓. "Preparation of Au-Pd/SiO2 catalyst with egg-shell structure and its application in p-CNB hydrogenation reaction." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/6gy93a.
Повний текст джерела國立中央大學
化學工程與材料工程學系
105
Nano-palladium catalyst has been reported to have high activity for hydrogenation reaction but selectivity of main product, p-chloroaniline (p-CAN), was low. In this study, gold-palladium bimetals were loaded on spherical silica to form the egg-shell catalyst and used different ratio of Au/Pd metal on silica to carry out the p-CNB hydrogenation reaction. All the catalysts were characterized by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS). The condition of hydrogenation reaction was room temperature as reaction temperature, 0.55MPa as H2 partial pressure and at 300 rpm stirring rate. The average particle size of Pd-Au/SiO2 fresh catalyst was smaller than that of Pd/SiO2 and the active metals were highly dispersed on SiO2 support surface. In the early stage of reaction, metals still maintained high dispersion. The main reason is adding gold as promoter can prevent metals from agglomeration and dispread Pd to single active site. However, after long time on the stream, metals agglomeration on silica surface and larger particle size were observed and resulted in decrease in active metals and lead to deactivation. Besides, the activity of catalyst was significantly decreased but selectivity of p-CAN was not obvious change in p-CNB hydrogenation reaction. Therefore, metals composition was not serious change after the reaction.
Arrigo, Rosa [Verfasser]. "Nitrogen functionalization of CNFs and application in heterogeneous catalysis / vorgelegt von Rosa Arrigo." 2009. http://d-nb.info/998923192/34.
Повний текст джерелаCheemalapati, Surya Venkata Sekhar. "The effect of catalyst properties on the synthesis of carbon nanotubes by plasma enhanced chemical vapor deposition." Thesis, 2012. http://hdl.handle.net/1957/35803.
Повний текст джерелаGraduation date: 2013
Shen, Wei-Ting, and 沈韋廷. "Efficient catalysis of Sonogashira reaction by a novel palladium complex with a triptycene incorporated CNC pincer bis-carbene ligands." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/9kjm39.
Повний текст джерела國立東華大學
化學系
100
N-Heterocyclic Carbenes (NHCs) was a stable carbene, which was strong σ-donor character and considered to be of low toxicity. Triptycene was a very rigid structure, and we used triptycene as a ligand to synthesize the stable NHCs 1、2, and make it becomes a palladium (Pd) complex then into use of cross-coupling reactions. We found the ligands 1-di (1) and 2-di (2) are active catalytic ligands which can giving the good results to react with aryl halides and heterocyclic halides then catalyzed the Sonogashira reaction with aryl alkynes . Under different conditions, the ideal yield could up to 99%. We also test the catalytic recycling of 1, and it can be used in 3 to 5 times in different conditions.