Статті в журналах: "Carbon-Dot Based Hybrid Nanomaterials"

1

Her, Shiuh-Chuan, and Yuan-Ming Liang. "Carbon-Based Nanomaterials Thin Film Deposited on a Flexible Substrate for Strain Sensing Application." Sensors 22, no. 13 (July 4, 2022): 5039. http://dx.doi.org/10.3390/s22135039.

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Hybrid nanomaterial film consisting of multi-walled carbon nanotubes (MWCNT) and graphene nanoplatelet (GNP) were deposited on a highly flexible polyimide (PI) substrate using spray gun. The hybridization between 2-D GNP and 1-D MWCNT reduces stacking among the nanomaterials and produces a thin film with a porous structure. Carbon-based nanomaterials of MWCNT and GNP with high electrical conductivity can be employed to detect the deformation and damage for structural health monitoring. The strain sensing capability of carbon-based hybrid nanomaterial film was evaluated by its piezoresistive behavior, which correlates the change of electrical resistance with the applied strain through a tensile test. The effects of weight ratio between MWCNT and GNP and the total amount of hybrid nanomaterials on the strain sensitivity of the nanomaterial thin film were investigated. Experimental results showed that both the electrical conductivity and strain sensitivity of the hybrid nanomaterial film increased with the increase of the GNP contents. The gauge factor used to characterize the strain sensitivity of the nanomaterial film increased from 7.75 to 24 as the GNP weight ratio increased from 0 wt.% to 100 wt.%. In this work, a simple, low cost, and easy to implement deposition process was proposed to prepare a highly flexible nanomaterial film. A high strain sensitivity with gauge factor of 24 was achieved for the nanomaterial thin film.

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2

Kumar, Vijay Bhooshan, Amit Kumar Sahu, and Kota Bhanu Sankara Rao. "Development of Doped Carbon Quantum Dot-Based Nanomaterials for Lubricant Additive Applications." Lubricants 10, no. 7 (July 7, 2022): 144. http://dx.doi.org/10.3390/lubricants10070144.

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The development of advanced lubricants is essential for the pursuit of energy efficiency and sustainable development. In order to improve the properties of lubricating fluids, high-performance lubricating additives are required. In recent research studies, carbon nanomaterials such as fullerenes, carbon nanotubes, and graphene have been examined as lubricating additives to water or oil. Lubricating oils are well known for the presence of additives, especially friction-reducers and anti-wear additives. As part of this work, we have studied the advancement in the research and development of carbon dot (CD)-based lubricant additives by presenting a number of several applications of CD-based additives. We have also highlighted the friction-reducing properties and anti-wear properties of CDs and their lubrication mechanism along with some challenges and future perspectives of CDs as an additive. CDs are carbon nanomaterials that are synthesized from single-atom-thick sheets containing a large number of oxygen-containing functional groups; they have gained increasing attention as friction-reducing and antiwear additives. CDs have gradually been revealed to have exceptional tribological properties, particularly acting as additives to lubricating base oils. In our final section, we discuss the main challenges, future research directions, and a number of suggestions for a complete functionalized or hybrid doped CD-based material.

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3

Semchuk, O. Yu, T. Gatti, and S. Osella. "Carbon based hybrid nanomaterials: overview and challenges ahead." SURFACE 14(29) (December 30, 2022): 78–94. http://dx.doi.org/10.15407/surface.2022.14.078.

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In recent years, many new materials have been developed and prepared to improve the performance of light-harvesting technologies and to develop new and attractive applications. The problem of stability of long-term operation of various optoelectronic devices based on organic materials, both conjugated polymers and small molecules of organic semiconductors (SMOSs), is becoming relevant now. One way to solve this problem is to use carbon nanostructures, such as carbon nanotubes and a large family of graphene-based materials, which have enhanced stability, in carefully designed nanohybrid or nanocomposite architectures that can be integrated into photosensitive layers and where their potential is not yet know fully disclosed. Recently, a new trend has been seen in this direction - the use of nanoscale materials for, first of all, the conversion of light into electricity. The main goal of this approach is to rationally design stable and highly efficient carbon-based hybrid nanomaterials for optoelectrical applications, namely light harvesting/electricity conversion, which can be implemented in real optoelectrical devices. In this review, we will discuss the theoretical and experimental foundations of the hybridization of carbon nanostructures (CNSs) with other materials to reveal new optoelectronic properties and provide an overview of existing examples in the literature that will predict interesting future perspectives for use in future devices.

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4

Howlader, Ashraful Hossain, Feng Li, and Rongkun Zheng. "Carbon Nanomaterials for Halide Perovskites‐Based Hybrid Photodetectors." Advanced Materials Technologies 5, no. 12 (October 7, 2020): 2000643. http://dx.doi.org/10.1002/admt.202000643.

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5

Plachá, Daniela, Alexandra Muñoz-Bonilla, Kateřina Škrlová, Coro Echeverria, Alberto Chiloeches, Martin Petr, Khalid Lafdi, and Marta Fernández-García. "Antibacterial Character of Cationic Polymers Attached to Carbon-Based Nanomaterials." Nanomaterials 10, no. 6 (June 22, 2020): 1218. http://dx.doi.org/10.3390/nano10061218.

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The preparation of hybrid polymeric systems based on carbon derivatives with a cationic polymer is described. The polymer used is a copolymer of a quaternizable methacrylic monomer with another dopamine-based monomer capable of anchoring to carbon compounds. Graphene oxide and graphene as well as hybrid polymeric systems were widely characterized by infrared, Raman and photoemission X-ray spectroscopies, electron scanning microscopy, zeta potential and thermal degradation. These allowed confirming the attachment of copolymer onto carbonaceous materials. Besides, the antimicrobial activity of hybrid polymeric systems was tested against Gram positive Staphylococcus aureus and Staphylococcus epidermidis and Gram negative Escherichia coli and Pseudomonas aeruginosa bacteria. The results showed the antibacterial character of these hybrid systems.

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6

Li, Haiqing, Sing I. Song, Ga Young Song, and Il Kim. "Non-Covalently Functionalized Carbon Nanostructures for Synthesizing Carbon-Based Hybrid Nanomaterials." Journal of Nanoscience and Nanotechnology 14, no. 2 (February 1, 2014): 1425–40. http://dx.doi.org/10.1166/jnn.2014.9048.

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7

Barrejón, Myriam, Luis M. Arellano, Francis D'Souza, and Fernando Langa. "Bidirectional charge-transfer behavior in carbon-based hybrid nanomaterials." Nanoscale 11, no. 32 (2019): 14978–92. http://dx.doi.org/10.1039/c9nr04388h.

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This review highlights construction and study of molecular and supramolecular donor–acceptor constructs derived by linking photosensitizers to various nanocarbons in governing directional electron transfer.

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8

Laurila, Tomi, Sami Sainio, and Miguel A. Caro. "Hybrid carbon based nanomaterials for electrochemical detection of biomolecules." Progress in Materials Science 88 (July 2017): 499–594. http://dx.doi.org/10.1016/j.pmatsci.2017.04.012.

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9

Awan, Muhammad Maqbool Sadiq, Parviz Soroushian, Arshad Ali, and Muhammad Yousaf Saqid Awan. "High-Performance Cementitious Matrix using Carbon Nanofibers." Indonesian Journal of Science and Technology 2, no. 1 (April 1, 2017): 57. http://dx.doi.org/10.17509/ijost.v2i1.5989.

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Graphite nanomaterials would realize their reinforcement potential within cement-based materials when they are thoroughly dispersed and effectively bonded to cement hydrates. Thorough dispersion of graphite nanomaterials in the fresh cementitious matrix encounters challenges associated with the hydrophobic nature of nanomaterial surfaces and their strong tendency towards agglomeration via attractive van der Waals forces. Effective interfacial interactions with cement hydrates are further challenged by the relatively inert nature of nanomaterial surfaces. An experimental program was conducted with the objective of effectively utilizing both acid-oxidized and pristine carbon nanofibers towards reinforcement of high-performance cementitious pastes. Hybrid reinforcement systems comprising optimum volume fraction of carbon nanofibers and micro-scale fibers were also evaluated in cementitious matrices. The improvements in nanofiber dispersion and interfacial interactions resulting from acid-oxidation and use of proper dispersion techniques were found to bring about significant gains in the engineering properties of high-performance cementitious materials.

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10

Wang, Zhuqing, Shasha Wu, Jian Wang, Along Yu, and Gang Wei. "Carbon Nanofiber-Based Functional Nanomaterials for Sensor Applications." Nanomaterials 9, no. 7 (July 22, 2019): 1045. http://dx.doi.org/10.3390/nano9071045.

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Carbon nanofibers (CNFs) exhibit great potentials in the fields of materials science, biomedicine, tissue engineering, catalysis, energy, environmental science, and analytical science due to their unique physical and chemical properties. Usually, CNFs with flat, mesoporous, and porous surfaces can be synthesized by chemical vapor deposition and electrospinning techniques with subsequent chemical treatment. Meanwhile, the surfaces of CNFs are easy to modify with various materials to extend the applications of CNF-based hybrid nanomaterials in multiple fields. In this review, we focus on the design, synthesis, and sensor applications of CNF-based functional nanomaterials. The fabrication strategies of CNF-based functional nanomaterials by adding metallic nanoparticles (NPs), metal oxide NPs, alloy, silica, polymers, and others into CNFs are introduced and discussed. In addition, the sensor applications of CNF-based nanomaterials for detecting gas, strain, pressure, small molecule, and biomacromolecules are demonstrated in detail. This work will be beneficial for the readers to understand the strategies for fabricating various CNF-based nanomaterials, and explore new applications in energy, catalysis, and environmental science.

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11

Vejpravová, Jana. "Mixed sp2–sp3 Nanocarbon Materials: A Status Quo Review." Nanomaterials 11, no. 10 (September 22, 2021): 2469. http://dx.doi.org/10.3390/nano11102469.

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Carbon nanomaterials with a different character of the chemical bond—graphene (sp2) and nanodiamond (sp3)—are the building bricks for a new class of all-carbon hybrid nanomaterials, where the two different carbon networks with sp3 and sp2 hybridization coexist, interacting and even transforming into one another. The extraordinary physiochemical properties defined by the unique electronic band structure of the two border nanoallotropes ensure the immense application potential and versatility of these all-carbon nanomaterials. The review summarizes the status quo of sp2 – sp3 nanomaterials, including graphene/graphene-oxide—nanodiamond composites and hybrids, graphene/graphene-oxide—diamond heterojunctions, and other sp2–sp3 nanocarbon hybrids for sensing, electronic, and other emergent applications. Novel sp2–sp3 transitional nanocarbon phases and architectures are also discussed. Furthermore, the two-way sp2 (graphene) to sp3 (diamond surface and nanodiamond) transformations at the nanoscale, essential for innovative fabrication, and stability and chemical reactivity assessment are discussed based on extensive theoretical, computational and experimental studies.

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12

Liang, Pan, Linshen Mao, Yanli Dong, Zhenwen Zhao, Qin Sun, Maryam Mazhar, Yining Ma, Sijin Yang, and Wei Ren. "Design and Application of Near-Infrared Nanomaterial-Liposome Hybrid Nanocarriers for Cancer Photothermal Therapy." Pharmaceutics 13, no. 12 (December 3, 2021): 2070. http://dx.doi.org/10.3390/pharmaceutics13122070.

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Liposomes are attractive carriers for targeted and controlled drug delivery receiving increasing attention in cancer photothermal therapy. However, the field of creating near-infrared nanomaterial-liposome hybrid nanocarriers (NIRN-Lips) is relatively little understood. The hybrid nanocarriers combine the dual superiority of nanomaterials and liposomes, with more stable particles, enhanced photoluminescence, higher tumor permeability, better tumor-targeted drug delivery, stimulus-responsive drug release, and thus exhibiting better anti-tumor efficacy. Herein, this review covers the liposomes supported various types of near-infrared nanomaterials, including gold-based nanomaterials, carbon-based nanomaterials, and semiconductor quantum dots. Specifically, the NIRN-Lips are described in terms of their feature, synthesis, and drug-release mechanism. The design considerations of NIRN-Lips are highlighted. Further, we briefly introduced the photothermal conversion mechanism of NIRNs and the cell death mechanism induced by photothermal therapy. Subsequently, we provided a brief conclusion of NIRNs-Lips applied in cancer photothermal therapy. Finally, we discussed a synopsis of associated challenges and future perspectives for the applications of NIRN-Lips in cancer photothermal therapy.

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13

Ozkan, Sveta Zhiraslanovna, Aleksandr Ivanovich Kostev, Galina Petrovna Karpacheva, Petr Aleksandrovich Chernavskii, Andrey Aleksandrovich Vasilev, and Dmitriy Gennad’evich Muratov. "Hybrid Electromagnetic Nanomaterials Based on Polydiphenylamine-2-carboxylic Acid." Polymers 12, no. 7 (July 15, 2020): 1568. http://dx.doi.org/10.3390/polym12071568.

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Hybrid ternary nanomaterials based on conjugated polymer polydiphenylamine-2-carboxylic acid (PDPAC) (poly-N-phenylanthranilic acid), Fe3O4 nanoparticles and single-walled carbon nanotubes (SWCNT) were prepared for the first time. Polymer–metal–carbon Fe3O4/SWCNT/PDPAC nanocomposites were synthesized via in situ oxidative polymerization of diphenylamine-2-carboxylic acid (DPAC) by two different ways: in an acidic medium and in the interfacial process in an alkaline medium. In an alkaline medium (pH 11.4), the entire process of Fe3O4/SWCNT/PDPAC-1 synthesis was carried out in one reaction vessel without intermediate stages of product extraction and purification. In an acidic medium (pH 0.3), to prepare the Fe3O4/SWCNT/PDPAC-2 nanocomposites, prefabricated magnetite nanoparticles were deposited on the surface of obtained SWCNT/PDPAC-2. The phase composition of the nanocomposites does not depend on the synthesis reaction medium pH. The influence of the reaction medium pH on the structure, morphology, thermal, magnetic, and electrical properties of the obtained ternary nanocomposites was studied.

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14

Patila, Michaela, Panagiotis E. Athanasiou, Lampros Kortessis, Georgia Potsi, Antonios Kouloumpis, Dimitrios Gournis, and Haralambos Stamatis. "Immobilization of Laccase on Hybrid Super-Structured Nanomaterials for the Decolorization of Phenolic Dyes." Processes 10, no. 2 (January 26, 2022): 233. http://dx.doi.org/10.3390/pr10020233.

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In the present work, hybrid super-structured nanomaterials were synthesized by the combination of smectite nanoclays with various carbon-based nanomaterials (graphene oxide, carbon nanotubes and adamantylamine) and were used as nanosupports for the covalent and non-covalent immobilization of laccase from Trametes versicolor (TvL). TvL was successfully immobilized on these hybrid nanomaterials, achieving high immobilization yields (up to 85%), while its conformation remained unaltered upon immobilization. The apparent kinetic constants Vmax and Km of the immobilized enzymes strongly depended on the immobilization procedure and the composition of hybrid nanomaterials. Immobilized TvL preserved up to 50% of its initial activity after 24 h of incubation at 60 °C, while free enzyme was totally deactivated. The TvL-hybrid nanomaterials bioconjugates were efficiently applied for the degradation of various synthetic dyes, exhibiting excellent decolorization capacity, as well as high reusability (up to 11 successive catalytic cycles), providing insights into the use of these bionanoconjugates on applications with environmental, and industrial interest.

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15

David, Madalina Elena, Rodica-Mariana Ion, Ramona Marina Grigorescu, Lorena Iancu, Alina Maria Holban, Adrian Ionut Nicoara, Elvira Alexandrescu, et al. "Hybrid Materials Based on Multi-Walled Carbon Nanotubes and Nanoparticles with Antimicrobial Properties." Nanomaterials 11, no. 6 (May 27, 2021): 1415. http://dx.doi.org/10.3390/nano11061415.

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In this study, multi-walled carbon nanotubes (MWCNTs) were decorated with different types of nanoparticles (NPs) in order to obtain hybrid materials with improved antimicrobial activity. Structural and morphological analysis, such as Fourier transformed infrared spectroscopy, Raman spectroscopy, X-ray diffraction, transmission electron microscopy, environmental scanning electron microscopy/energy-dispersive X-ray spectroscopy and the Brunauer–Emmett–Teller technique were used in order to investigate the decoration of the nanotubes with NPs. Analysis of the decorated nanotubes showed a narrow size distribution of NPs, 7–13 nm for the nanotubes decorated with zinc oxide (ZnO) NPs, 15–33 nm for the nanotubes decorated with silver (Ag) NPs and 20–35 nm for the nanotubes decorated with hydroxyapatite (HAp) NPs, respectively. The dispersion in water of the obtained nanomaterials was improved for all the decorated MWCNTs, as revealed by the relative absorbance variation in time of the water-dispersed nanomaterials. The obtained nanomaterials showed a good antimicrobial activity; however, the presence of the NPs on the surface of MWCNTs improved the nanocomposites’ activity. The presence of ZnO and Ag nanoparticles enhanced the antimicrobial properties of the material, in clinically relevant microbial strains. Our data proves that such composite nanomaterials are efficient antimicrobial agents, suitable for the therapy of severe infection and biofilms.

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16

Batool, Razia, Amina Rhouati, Mian Hasnain Nawaz, Akhtar Hayat, and Jean Louis Marty. "A Review of the Construction of Nano-Hybrids for Electrochemical Biosensing of Glucose." Biosensors 9, no. 1 (March 25, 2019): 46. http://dx.doi.org/10.3390/bios9010046.

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Continuous progress in the domain of nano and material science has led to modulation ofthe properties of nanomaterials in a controlled and desired fashion. In this sense, nanomaterials,including carbon-based materials, metals and metal oxides, and composite/hybrid materials haveattracted extensive interest with regard to the construction of electrochemical biosensors. Themodification of a working electrode with a combination of two or three nanomaterials in the formof nano-composite/nano-hybrids has revealed good results with very good reproducibility, stability,and improved sensitivity. This review paper is focused on discussing the possible constructs ofnano-hybrids and their subsequent use in the construction of electrochemical glucose biosensors.

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17

Tan, Qiaoyin, Cuicui Wu, Lei Li, Weide Shao, and Min Luo. "Nanomaterial-Based Prosthetic Limbs for Disability Mobility Assistance: A Review of Recent Advances." Journal of Nanomaterials 2022 (March 31, 2022): 1–10. http://dx.doi.org/10.1155/2022/3425297.

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The emergence of new hybrid nanomaterial has enabled prosthetic devices to have more performance and significantly improved the quality of life of the disabled. Due to the biosensing properties of prosthetic limbs made of nanomaterials, a large number of nanocomposites have been designed, developed, and evaluated for various prosthetic limbs, such as e-skin, e-skin’s neurotactility sensing, human prosthetic interface tissue engineering, bones, and biosensors. Nano-based materials are also considered to be the new generation of scientific and technological materials for the preparation of various prosthetic devices for the disabled, which can effectively improve the sense of use of the disabled and achieve functional diversity. The study described various nanomaterials for prosthetic devices, and introduced some basic components of nanocomposites; their applications are in three areas, such as bone, skin, and nerve, and evaluated and summarized the advantages of these applications. The results show that (1) carbon-based nanomaterials as neural materials have been studied most deeply. Due to that strong stability of the carbon-based material and the simple transmission mechanism, the cost can be controlled in manufacturing the artificial limb. Materials with human-computer interaction function are the research focus in the future. (2) Skin nanomaterials are mainly composite materials, generally containing metal- and carbon-based materials. Ionic gels, ionic liquids, hydrogels, and elastomers have become the focus of attention due to the sensitivity, multimodal, and memory properties of their materials. (3) Outstanding nanomaterials for bone are fibrous materials, metallic synthetic materials, and composite materials, with extremely high hardness, weight, and toughness. Of the skeletal materials, the choice of prosthetic socket material is the most important and is typically based on fiber laminate composites. Some of these materials make sensors for durability and performance that can be used for large-scale clinical testing.

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18

Danial, Wan Hazman, Nur Fathanah Md Bahri, and Zaiton Abdul Majid. "Preparation, Marriage Chemistry and Applications of Graphene Quantum Dots–Nanocellulose Composite: A Brief Review." Molecules 26, no. 20 (October 12, 2021): 6158. http://dx.doi.org/10.3390/molecules26206158.

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Graphene quantum dots (GQDs) are zero-dimensional carbon-based materials, while nanocellulose is a nanomaterial that can be derived from naturally occurring cellulose polymers or renewable biomass resources. The unique geometrical, biocompatible and biodegradable properties of both these remarkable nanomaterials have caught the attention of the scientific community in terms of fundamental research aimed at advancing technology. This study reviews the preparation, marriage chemistry and applications of GQDs–nanocellulose composites. The preparation of these composites can be achieved via rapid and simple solution mixing containing known concentration of nanomaterial with a pre-defined composition ratio in a neutral pH medium. They can also be incorporated into other matrices or drop-casted onto substrates, depending on the intended application. Additionally, combining GQDs and nanocellulose has proven to impart new hybrid nanomaterials with excellent performance as well as surface functionality and, therefore, a plethora of applications. Potential applications for GQDs–nanocellulose composites include sensing or, for analytical purposes, injectable 3D printing materials, supercapacitors and light-emitting diodes. This review unlocks windows of research opportunities for GQDs–nanocellulose composites and pave the way for the synthesis and application of more innovative hybrid nanomaterials.

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19

López-Naranjo, Edgar J., Luis J. González-Ortiz, Luis M. Apátiga, Eric M. Rivera-Muñoz, and Alejandro Manzano-Ramírez. "Transparent Electrodes: A Review of the Use of Carbon-Based Nanomaterials." Journal of Nanomaterials 2016 (2016): 1–12. http://dx.doi.org/10.1155/2016/4928365.

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Transparent conducting electrodes (TCE) are extensively applied in a great range of optoelectronic and photovoltaic equipment (e.g., solar cells, touch panels, and flexible devices). Carbon-based nanomaterials are considered as suitable replacements to substitute traditional materials to manufacture TCE due to their remarkable characteristics, for example, high optical transmittance and outstanding electrical properties. In comparison with traditional indium tin oxide electrodes, carbon-based electrodes show good mechanical properties, chemical stability, and low cost. Nevertheless, major issues related to the development of good quality manufacture methods to produce carbon-based nanomaterials have to be overcome to meet massive market requirements. Hence, the development of alternative TCE materials as well as appropriate large production techniques that meet the requirements of a proper sheet resistance along with a high optical transparency is a priority. Therefore, in this work, we summarize and discuss novel production and synthesis methods, chemical treatments, and hybrid materials developed to satisfy the worldwide request for carbon-based nanomaterials.

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20

Garoz-Ruiz, Jesus, David Ibañez, Edna C. Romero, Virginia Ruiz, Aranzazu Heras, and Alvaro Colina. "Optically transparent electrodes for spectroelectrochemistry fabricated with graphene nanoplatelets and single-walled carbon nanotubes." RSC Advances 6, no. 37 (2016): 31431–39. http://dx.doi.org/10.1039/c6ra04116g.

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Lee, Jin Ah, Won Jun Lee, Joonwon Lim, and Sang Ouk Kim. "N-Dopant-Mediated Growth of Metal Oxide Nanoparticles on Carbon Nanotubes." Nanomaterials 11, no. 8 (July 22, 2021): 1882. http://dx.doi.org/10.3390/nano11081882.

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Metal oxide nanoparticles supported on heteroatom-doped graphitic surfaces have been pursued for several decades for a wide spectrum of applications. Despite extensive research on functional metal oxide nanoparticle/doped carbon nanomaterial hybrids, the role of the heteroatom dopant in the hybridization process of doped carbon nanomaterials has been overlooked. Here, the direct growth of MnOx and RuOx nanoparticles in nitrogen (N)-doped sites of carbon nanotubes (NCNTs) is presented. The quaternary nitrogen (NQ) sites of CNTs actively participate in the nucleation and growth of the metal nanoparticles. The evenly distributed NQ nucleation sites mediate the generation of uniformly dispersed <10 nm diameter MnOx and RuOx nanoparticles, directly decorated on NCNT surfaces. The electrochemical performance of the resultant hybridized materials was evaluated using cyclic voltammetry. This novel hybridization method using the dopant-mediated nucleation and growth of metal oxides suggests ways that heteroatom dopants can be utilized to optimize the structure, interface and corresponding properties of graphitic carbon-based hybrid materials.

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22

Innocenzi, Plinio, Luca Malfatti, and Davide Carboni. "Graphene and carbon nanodots in mesoporous materials: an interactive platform for functional applications." Nanoscale 7, no. 30 (2015): 12759–72. http://dx.doi.org/10.1039/c5nr03773e.

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23

Ramalingame, Rajarajan, Jose Roberto Bautista-Quijano, Danrlei de Farias Alves, and Olfa Kanoun. "Temperature Self-Compensated Strain Sensors based on MWCNT-Graphene Hybrid Nanocomposite." Journal of Composites Science 3, no. 4 (November 7, 2019): 96. http://dx.doi.org/10.3390/jcs3040096.

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Sensors based on carbon nanomaterials are gaining importance due to their tunable properties and their potentially outstanding sensing performance. Despite their advantages, carbon-based nanomaterial sensors are prone to cross-sensitivities with environmental factors like temperature. Thus, to reduce the temperature influence on the sensing material, compensation and correction procedures are usually considered. These methods may require the use of additional sensors which can themselves be subject to residual errors. Hence, a more promising approach consists of synthesizing a material that is capable of self-compensating for the influence of temperature. In this study, a hybrid nanocomposite based on multi-walled carbon nanotubes (MWCNT) and graphene is proposed, which can compensate, by itself, for the influence of temperature on the material conductivity. The hybrid nanocomposite material uses the different temperature behavior of MWCNTs, which have a negative temperature coefficient, and graphene, which has a positive temperature coefficient. The influence of the material ratio and dispersion quality are investigated in this work. Material composition and dispersion quality are analyzed using Raman spectroscopy and scanning electron microscopy (SEM). A composition of 70% graphene and 30% MWCNT exhibits a nearly temperature-independent hybrid nanocomposite with a sensitivity of 0.022 Ω/°C, corresponding to a resistance change of ~1.2 Ω for a temperature range of 25 to 80 °C. Additionally, a simple investigation of the strain sensing behavior of the hybrid material is also presented. The hybrid nanocomposite-based, thin-film strain sensor exhibits good stability over 100 cycles and a significantly high gauge factor, i.e., 16.21.

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Litvin, Aleksandr P., Anton A. Babaev, Peter S. Parfenov, Aliaksei Dubavik, Sergei A. Cherevkov, Mikhail A. Baranov, Kirill V. Bogdanov, et al. "Ligand-Assisted Formation of Graphene/Quantum Dot Monolayers with Improved Morphological and Electrical Properties." Nanomaterials 10, no. 4 (April 11, 2020): 723. http://dx.doi.org/10.3390/nano10040723.

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Hybrid nanomaterials based on graphene and PbS quantum dots (QDs) have demonstrated promising applications in optoelectronics. However, the formation of high-quality large-area hybrid films remains technologically challenging. Here, we demonstrate that ligand-assisted self-organization of covalently bonded PbS QDs and reduced graphene oxide (rGO) can be utilized for the formation of highly uniform monolayers. After the post-deposition ligand exchange, these films demonstrated high conductivity and photoresponse. The obtained films demonstrate a remarkable improvement in morphology and charge transport compared to those obtained by the spin-coating method. It is expected that these materials might find a range of applications in photovoltaics and optoelectronics.

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Овчинников, Е. В., В. М. Хвисевич, Н. М. Чекан, А. И. Веремейчик, Е. И. Эйсымонт та Г. А. Костюкович. "СМАЗОЧНЫЕ МАТЕРИАЛЫ НА ОСНОВЕ ПОЛЯРНЫХ И НЕПОЛЯРНЫХ ЖИДКОСТЕЙ, МОДИФИЦИРОВАННЫХ ГИБРИДНЫМИ УГЛЕРОДНЫМИ НАНОМАТЕРИАЛАМИ". Vestnik of Brest State Technical University. Civil Engineering and Architecture, № 2 - 2021 (29 червня 2021): 58–62. http://dx.doi.org/10.36773/1818-1212-2021-125-2-58-62.

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26

Knauss, Steven J., Samuel A. Brennan, and Mark A. Atwater. "In-Situ Formation of Carbon Nanofiber Hybrid Architectures for Functional Devices." MRS Advances 4, no. 33-34 (2019): 1869–75. http://dx.doi.org/10.1557/adv.2019.312.

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AbstractCarbon nanomaterials are consistently providing new excitement over their properties and potential applications, but many of these material have yet to fully live up to their expectations commercially. The barrier to adoption often exists as a result of complex processing, fragility of the as-produced material, or difficulty scaling beyond laboratory quantities. This work provides a new approach for utilizing fibrous carbon nanomaterials to advance the technology toward new applications and industrial utility. This is accomplished by creating tailored device architectures through in-situ integration of activated carbon powder using carbon nanofiber deposition. The resulting hybrid materials and components can serve in diverse applications, with each instance able to be fine-tuned through a combination of processing parameters. The applications of such materials are anticipated to directly serve current carbon-based technology in filtration, energy storage and delivery, and thermal management, but the concepts are not limited to current carbon applications.

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Kveton, Filip, Anna Blsakova, Peter Kasak, and Jan Tkac. "Glycan Nanobiosensors." Nanomaterials 10, no. 7 (July 19, 2020): 1406. http://dx.doi.org/10.3390/nano10071406.

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This review paper comprehensively summarizes advances made in the design of glycan nanobiosensors using diverse forms of nanomaterials. In particular, the paper covers the application of gold nanoparticles, quantum dots, magnetic nanoparticles, carbon nanoparticles, hybrid types of nanoparticles, proteins as nanoscaffolds and various nanoscale-based approaches to designing such nanoscale probes. The article covers innovative immobilization strategies for the conjugation of glycans on nanoparticles. Summaries of the detection schemes applied, the analytes detected and the key operational characteristics of such nanobiosensors are provided in the form of tables for each particular type of nanomaterial.

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Ozkan, Sveta, Valeriy Petrov, Andrey Vasilev, Petr Chernavskii, Mikhail Efimov, Dmitriy Muratov, Galina Pankina, and Galina Karpacheva. "Formation Features of Polymer–Metal–Carbon Ternary Electromagnetic Nanocomposites Based on Polyphenoxazine." Polymers 15, no. 13 (June 29, 2023): 2894. http://dx.doi.org/10.3390/polym15132894.

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Novel ternary hybrid polyphenoxazine (PPOA)-derived nanocomposites involving Co-Fe particles and single-walled (SWCNTs) or multi-walled (MWCNTs) carbon nanotubes were prepared and investigated. An efficient one-pot method employing infrared (IR) heating enabled the formation of Co-Fe/CNT/PPOA nanocomposites. During this, the dehydrogenation of phenoxazine (POA) units led to the simultaneous reduction of metals by released hydrogen, yielding bimetallic Co-Fe particles with a size range from the nanoscale (5–30 nm) to the microscale (400–1400 nm). The synthesized Co-Fe/CNT/PPOA nanomaterials exhibited impressive thermal stability, demonstrating a half-weight loss at 640 °C and 563 °C in air for Co-Fe/SWCNT/PPOA and Co-Fe/MWCNT/PPOA, respectively. Although a slightly broader range of saturation magnetization values was obtained using MWCNTs, it was found that the type of carbon nanotube, whether an SWCNT (22.14–41.82 emu/g) or an MWCNT (20.93–44.33 emu/g), did not considerably affect the magnetic characteristics of the resulting nanomaterial. By contrast, saturation magnetization escalated with an increasing concentration of both cobalt and iron. These nanocomposites demonstrated a weak dependence of electrical conductivity on frequency. It is shown that the conductivity value for hybrid nanocomposites is higher compared to single-polymer materials and becomes higher with increasing CNT content.

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Kim, Hoejin, Mohammad Arif Ishtiaque Shuvo, Hasanul Karim, Juan C. Noveron, Tzu-liang Tseng, and Yirong Lin. "Synthesis and characterization of CeO2 nanoparticles on porous carbon for Li-ion battery." MRS Advances 2, no. 54 (2017): 3299–307. http://dx.doi.org/10.1557/adv.2017.443.

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ABSTRACTCarbon based materials have long been investigated as anodes for lithium ion batteries. Among these materials, porous carbon holds several advantages such as high stability, high specific surface area, and excellent cycling capability. To further enhance the energy storage performance, ceramic nanomaterials have been combined with carbon based materials as hybrid anodes for enhanced specific capacity. The use of metal oxide ceramic nanomaterials could enhance the surface electrochemical reactivity thus leads to the increasing of capacity retention at higher number of cycles. In this research, we synthesized ceria (CeO2) nano-particles on porous carbon to form inorganic-organic hybrid composites as an anode material for Li-ion battery. The high redox potential of ceria is expected to increase the specific capacity and energy density of the system. The electrochemical performance was determined by a battery analyzer. It is observed that the specific capacity could be improved by 77% using hybrid composites anode. The material morphology, crystal structure, and thermal stability were characterized by Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-Ray Diffraction (XRD), and Thermogravimetric Analysis (TGA).

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Szabó, Tibor, Róbert Janovics, Marianna Túri, István Futó, István Papp, Mihály Braun, Krisztián Németh, et al. "Isotope Analytical Characterization of Carbon-Based Nanocomposites." Radiocarbon 60, no. 4 (August 2018): 1101–14. http://dx.doi.org/10.1017/rdc.2018.63.

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ABSTRACTCarbon-based nanomaterials of different dimensions (1–3D, tubes, bundles, films, papers and sponges, graphene sheets) have been created and their characteristic properties have been discussed intensively in the literature. Due to their unique advantageous, tunable properties these materials became promising candidates in new generations of applications in many research laboratories and, recently, in industries as well. Protein-based bio-nanocomposites are referred to as materials of the future, which may serve as conceptual revolution in the development of integrated optical devices, e.g. optical switches, microimaging systems, sensors, telecommunication technologies or energy harvesting and biosensor applications. In our experiments, we designed various carbon-based nanomaterials either doped or not doped with nitrogen or sulfur during catalytic chemical vapor deposition synthesis. Radio- and isotope analytical studies have shown that the used starting materials, precursors and carriers have a strong influence on the geometry and physico-/chemical characteristics of the carbon nanotubes produced. After determining the 14C isotope constitution 53 m/m% balance was found in the reaction center protein/carbon nanotubes complex in a sensitive way that was prepared in our laboratory. The result is essential in determining the yield of conversion of light energy to chemical potential in this bio-hybrid system.

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Fotiadou, Renia, Michaela Patila, Mohamed Amen Hammami, Apostolos Enotiadis, Dimitrios Moschovas, Kyriaki Tsirka, Konstantinos Spyrou, et al. "Development of Effective Lipase-Hybrid Nanoflowers Enriched with Carbon and Magnetic Nanomaterials for Biocatalytic Transformations." Nanomaterials 9, no. 6 (May 28, 2019): 808. http://dx.doi.org/10.3390/nano9060808.

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In the present study, hybrid nanoflowers (HNFs) based on copper (II) or manganese (II) ions were prepared by a simple method and used as nanosupports for the development of effective nanobiocatalysts through the immobilization of lipase B from Pseudozyma antarctica. The hybrid nanobiocatalysts were characterized by various techniques including scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS), X-ray diffraction (XRD), Raman spectroscopy, and Fourier transform infrared spectroscopy (FTIR). The effect of the addition of carbon-based nanomaterials, namely graphene oxide and carbon nanotubes, as well as magnetic nanoparticles such as maghemite, on the structure, catalytic activity, and operational stability of the hybrid nanobiocatalysts was also investigated. In all cases, the addition of nanomaterials during the preparation of HNFs increased the catalytic activity and the operational stability of the immobilized biocatalyst. Lipase-based magnetic nanoflowers were effectively applied for the synthesis of tyrosol esters in non-aqueous media, such as organic solvents, ionic liquids, and environmental friendly deep eutectic solvents. In such media, the immobilized lipase preserved almost 100% of its initial activity after eight successive catalytic cycles, indicating that these hybrid magnetic nanoflowers can be applied for the development of efficient nanobiocatalytic systems.

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Samantaray, Manas R., Abhay Kumar Mondal, Govindhasamy Murugadoss, Sudhagar Pitchaimuthu, Santanu Das, Raihana Bahru, and Mohd Ambri Mohamed. "Synergetic Effects of Hybrid Carbon Nanostructured Counter Electrodes for Dye-Sensitized Solar Cells: A Review." Materials 13, no. 12 (June 19, 2020): 2779. http://dx.doi.org/10.3390/ma13122779.

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This article provides an overview of the structural and physicochemical properties of stable carbon-based nanomaterials and their applications as counter electrodes (CEs) in dye-sensitized solar cells (DSSCs). The research community has long sought to harvest highly efficient third-generation DSSCs by developing carbon-based CEs, which are among the most important components of DSSCs. Since the initial introduction of DSSCs, Pt-based electrodes have been commonly used as CEs owing to their high-electrocatalytic activities, thus, accelerating the redox couple at the electrode/electrolyte interface to complete the circuit. However, Pt-based electrodes have several limitations due to their cost, abundance, complicated facility, and low corrosion resistance in a liquid electrolyte, which further restricts the large-area applications of DSSCs. Although carbon-based nanostructures showed the best potential to replace Pt-CE of DSSC, several new properties and characteristics of carbon-CE have been reported for future enhancements in this field. In this review, we discuss the detailed synthesis, properties, and performances of various carbonaceous materials proposed for DSSC-CE. These nano-carbon materials include carbon nanoparticles, activated carbon, carbon nanofibers, carbon nanotube, two-dimensional graphene, and hybrid carbon material composites. Among the CE materials currently available, carbon-carbon hybridized electrodes show the best performance efficiency (up to 10.05%) with a high fill factor (83%). Indeed, up to 8.23% improvements in cell efficiency may be achieved by a carbon-metal hybrid material under sun condition. This review then provides guidance on how to choose appropriate carbon nanomaterials to improve the performance of CEs used in DSSCs.

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Dăscălescu, Dorin, and Constantin Apetrei. "Nanomaterials Based Electrochemical Sensors for Serotonin Detection: A Review." Chemosensors 9, no. 1 (January 14, 2021): 14. http://dx.doi.org/10.3390/chemosensors9010014.

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The present review deals with the recent progress made in the field of the electrochemical detection of serotonin by means of electrochemical sensors based on various nanomaterials incorporated in the sensitive element. Due to the unique chemical and physical properties of these nanomaterials, it was possible to develop sensitive electrochemical sensors with excellent analytical performances, useful in the practice. The main electrochemical sensors used in serotonin detection are based on carbon electrodes modified with carbon nanotubes and various materials, such as benzofuran, polyalizarin red-S, poly(L-arginine), Nafion/Ni(OH)2, or graphene oxide, incorporating silver-silver selenite nanoparticles, as well as screen-printed electrodes modified with zinc oxide or aluminium oxide. Also, the review describes the nanocomposite sensors based on conductive polymers, tin oxide-tin sulphide, silver/polypyrole/copper oxide or a hybrid structure of cerium oxide-gold oxide nanofibers together with ruthenium oxide nanowires. The presentation focused on describing the sensitive materials, characterizing the sensors, the detection techniques, electroanalytical properties, validation and use of sensors in lab practice.

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Lopes, Paulo E., Duarte Moura, Loic Hilliou, Beate Krause, Petra Pötschke, Hugo Figueiredo, Ricardo Alves, Emmanuel Lepleux, Louis Pacheco, and Maria C. Paiva. "Mixed Carbon Nanomaterial/Epoxy Resin for Electrically Conductive Adhesives." Journal of Composites Science 4, no. 3 (August 1, 2020): 105. http://dx.doi.org/10.3390/jcs4030105.

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The increasing complexity of printed circuit boards (PCBs) due to miniaturization, increased the density of electronic components, and demanding thermal management during the assembly triggered the research of innovative solder pastes and electrically conductive adhesives (ECAs). Current commercial ECAs are typically based on epoxy matrices with a high load (>60%) of silver particles, generally in the form of microflakes. The present work reports the production of ECAs based on epoxy/carbon nanomaterials using carbon nanotubes (single and multi-walled) and exfoliated graphite, as well as hybrid compositions, within a range of concentrations. The composites were tested for morphology (dispersion of the conductive nanomaterials), electrical and thermal conductivity, rheological characteristics and deposition on a test PCB. Finally, the ECA’s shelf life was assessed by mixing all the components and conductive nanomaterials, and evaluating the cure of the resin before and after freezing for a time range up to nine months. The ECAs produced could be stored at −18 °C without affecting the cure reaction.

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35

Yang, Yunpeng, Huanlei Wang, Wei Liu, Jing Shi, Guanghe Dong, Hao Zhang, Dong Li, and Gaofei Lu. "Polymer salt-derived carbon-based nanomaterials for high-performance hybrid Li-ion capacitors." Journal of Materials Science 54, no. 10 (February 13, 2019): 7811–22. http://dx.doi.org/10.1007/s10853-019-03423-w.

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36

Mehdipoor, Ebrahim, Mohsen Adeli, Masoumeh Bavadi, Pezhman Sasanpour, and Bizhan Rashidian. "A possible anticancer drug delivery system based on carbon nanotube–dendrimer hybrid nanomaterials." Journal of Materials Chemistry 21, no. 39 (2011): 15456. http://dx.doi.org/10.1039/c1jm13254g.

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37

Li, Zhenhui, Ke Xu, and Fanan Wei. "Recent progress in photodetectors based on low-dimensional nanomaterials." Nanotechnology Reviews 7, no. 5 (October 25, 2018): 393–411. http://dx.doi.org/10.1515/ntrev-2018-0084.

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Abstract Photodetectors (PDs) have great potential in applications of imaging, telecommunication, and biological sensing. In this article, state-of-the-art achievements on typical low-dimensional nanostructured PDs and hybrid PDs are reviewed. In the 2D nanostructured PDs part, 2D transition metal dichalcogenides have a natural gap, which promise high sensitivity of photodetection. Graphene and black phosphorus can also stand for 2D nanostructured PDs due to their broadband absorption and tunable direct bandgap, respectively. In the 1D nanostructured PDs part, owing to its high photoconductive characteristic, ZnO nanowire film is a promising material for ultraviolet PDs. Carbon nanotubes show potential in infrared (IR) detection due to its unique physical properties. In the 0D nanostructured PDs part, lead sulfide has a small bandgap and large Bohr exciton radius, which collectively give it a wide spectral tunability in the IR. In the hybrid PDs part, electrical and chemical doping is applied to combine different nanomaterials to realize PDs with high performance. In each part, the present situation and major challenges are overviewed. Then, the evolutions of the methods to overcome these challenges and the tremendous research breakthroughs are demonstrated. At last, future directions that could improve the performance of PDs are discussed.

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Karthik, Kannan, Devi Radhika, D. Gnanasangeetha, K. Gurushankar, and Md Enamul Hoque. "Two-dimensional based hybrid materials for photocatalytic conversion of carbon dioxide into hydrocarbon fuels: A mini review." Physics and Chemistry of Solid State 22, no. 1 (March 13, 2021): 132–40. http://dx.doi.org/10.15330/pcss.22.1.132-140.

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Carbon dioxide conversion to chemicals and fuels based on two-dimensional based hybrid materials will present a thorough discussion of the physics, chemistry, and electrochemical science behind the new and important area of materials science, energy, and environmental sustainability. The tremendous opportunities for two-dimensional based hybrid materials in the photocatalytic carbon dioxide conversion field come up from their huge number of applications. In the carbon dioxide conversion field, nanostructured metal oxide with a two-dimensional material composite system must meet assured design and functional criteria, as well as electrical and mechanical properties. The whole content of the proposed review is anticipated to build on what has been learned in elementary courses about synthesizing two-dimensional nanomaterials, metal oxide with composites, carbon dioxide conversion requirements, uses of two-dimensional materials with nanocomposites in carbon dioxide conversion as well as fuels and the major mechanisms involved during each application. The impact of hybrid materials and synergistic composite mixtures which are used extensively or show promising outcomes in the photocatalytic carbon dioxide conversion field will also be discussed.

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Yu, Wen Xiu, Su Jie Qin, Zuo Ping Xiong, Zhong Qiang Ren, Xue Wen Wang, and Ting Zhang. "Controllable Fabrication of Flexible Multi-Walled Carbon Nanotubes/Reduced Graphene Oxide Hybrid Ultrathin Films." Applied Mechanics and Materials 748 (April 2015): 175–78. http://dx.doi.org/10.4028/www.scientific.net/amm.748.175.

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Multi-walled carbon nanotubes/reduced graphene oxide (MWCNT/rGO) hybrid films have attracted increasing massive attention due to their unique advantages such as high conductivity, superior mechanical property and thermal properties. In this work, a novel, facile and low cost method was developed to fabricate the MWCNT/rGO flexible ultrathin hybrid films with the thickness of about 55 nm. These hybrid films can be fabricated repeatedly through layer-by-layer exfoliation on the surface of liquids, and transferred to various substrates. The devices based on MWCNT/rGO hybrid films offer a unique platform for integrating carbon nanomaterials for advanced electronics, energy, and sensor applications.

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Selvaraj, Senthil Kumaran, Rathan Ramesh, Tharun M. V. Narendhra, Ishan Nilesh Agarwal, Utkarsh Chadha, Velmurugan Paramasivam, and Ponnusamy Palanisamy. "New Developments in Carbon-Based Nanomaterials for Automotive Brake Pad Applications and Future Challenges." Journal of Nanomaterials 2021 (November 22, 2021): 1–24. http://dx.doi.org/10.1155/2021/6787435.

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The proper functioning of automotive brake pads is of utmost importance to ensure the safety of passengers. Therefore, brake pad materials must be chosen with utmost precision and care to ensure their optimal functioning for long durations. Through a thorough literature review, it is found that the materials used currently for this purpose pose multiple discrepancies. Therefore, it is imperative to shift our focus towards nanomaterials, as they are one of the essential novel materials in this field. This study discusses the multiple constituents used in commercial brake pads, their role in improving and stabilizing their operation, and their desired properties to achieve optimal functioning. Parallelly, this study also reviews some of the potential organic and carbon nanomaterials that could prove to provide tough competition to currently utilized materials for brake pad applications. From this review, the major future commercial brake pad materials obtained include the likes of banana peel powder, crab shell powder, coconut fibers, stark corn fibers, metal oxide composites, metal nitride composites, multiwalled carbon nanotubes, and hybrid nanocomposites. These materials are studied on the basis of their performance under high-frictional force applications and analyzed by considering their mechanical, chemical, thermal, and tribological properties. Carbon nanotube-based composites showed improved tribological and braking performances making them more attractive than the materials in commercially available brake pads. In addition to these, the effects of usage of such nanomaterials on the environment and health are reviewed, in order to understand the feasibility of utilization of nanomaterials in automotive brake pad applications. From this analysis, this work suggests that there are a variety of nanomaterials that prove to be capable of automotive brake pad applications and, with further research and technological developments, would prove to be an asset to the automotive brake pad industry.

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Del Sole, Regina, Chiara Lo Porto, Sara Lotito, Chiara Ingrosso, Roberto Comparelli, Maria Lucia Curri, Gianni Barucca, Francesco Fracassi, Fabio Palumbo, and Antonella Milella. "Atmospheric Pressure Plasma Deposition of Hybrid Nanocomposite Coatings Containing TiO2 and Carbon-Based Nanomaterials." Molecules 28, no. 13 (June 30, 2023): 5131. http://dx.doi.org/10.3390/molecules28135131.

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Among the different applications of TiO2, its use for the photocatalytic abatement of organic pollutants has been demonstrated particularly relevant. However, the wide band gap (3.2 eV), which requires UV irradiation for activation, and the fast electron-hole recombination rate of this n-type semiconductor limit its photocatalytic performance. A strategy to overcome these limitations relies on the realization of a nanocomposite that combines TiO2 nanoparticles with carbon-based nanomaterials, such as rGO (reduced graphene oxide) and fullerene (C60). On the other hand, the design and realization of coatings formed of such TiO2-based nanocomposite coatings are essential to make them suitable for their technological applications, including those in the environmental field. In this work, aerosol-assisted atmospheric pressure plasma deposition of nanocomposite coatings containing both TiO2 nanoparticles and carbon-based nanomaterials, as rGO or C60, in a siloxane matrix is reported. The chemical composition and morphology of the deposited films were investigated for the different types of prepared nanocomposites by means of FT-IR, FEG-SEM, and TEM analyses. The photocatalytic activity of the nanocomposite coatings was evaluated through monitoring the photodegradation of methylene blue (MB) as a model organic pollutant. Results demonstrate that the nanocomposite coatings embedding rGO or C60 show enhanced photocatalytic performance with respect to the TiO2 counterpart. In particular, TiO2/C60 nanocomposites allow to achieve 85% MB degradation upon 180 min of UV irradiation.

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Ozkan, Sveta Zhiraslanovna, Galina Petrovna Karpacheva, Aleksandr Ivanovich Kostev, and Galina Nikolaevna Bondarenko. "Formation Features of Hybrid Nanocomposites Based on Polydiphenylamine-2-Carboxylic Acid and Single-Walled Carbon Nanotubes." Polymers 11, no. 7 (July 13, 2019): 1181. http://dx.doi.org/10.3390/polym11071181.

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Hybrid nanocomposites based on electroactive polydiphenylamine-2-carboxylic acid (PDPAC) and single-walled carbon nanotubes (SWCNTs) were obtained for the first time. Polymer-carbon nanomaterials were synthesized via in situ oxidative polymerization of diphenylamine-2-carboxylic acid (DPAC) in the presence of SWCNTs by two different ways. Hybrid SWCNT/PDPAC nanocomposites were prepared both in an acidic medium and in the heterophase system in an alkaline medium. In the heterophase system, the monomer and the SWCNTs are in the organic phase (chloroform) and the oxidant (ammonium persulfate) is in an aqueous solution of ammonium hydroxide. The chemical structure, as well as the electrical and thermal properties of the developed SWCNT/PDPAC nanocomposite materials were investigated.

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Ortega-Nieto, Clara, Noelia Losada-Garcia, Doina Prodan, Gabriel Furtos, and Jose M. Palomo. "Recent Advances on the Design and Applications of Antimicrobial Nanomaterials." Nanomaterials 13, no. 17 (August 24, 2023): 2406. http://dx.doi.org/10.3390/nano13172406.

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Present worldwide difficulties in healthcare and the environment have motivated the investigation and research of novel materials in an effort to find novel techniques to address the current challenges and requirements. In particular, the use of nanomaterials has demonstrated a significant promise in the fight against bacterial infections and the problem of antibiotic resistance. Metal nanoparticles and carbon-based nanomaterials in particular have been highlighted for their exceptional abilities to inhibit many types of bacteria and pathogens. In order for these materials to be as effective as possible, synthetic techniques are crucial. Therefore, in this review article, we highlight some recent developments in the design and synthesis of various nanomaterials, including metal nanoparticles (e.g., Ag, Zn, or Cu), metal hybrid nanomaterials, and the synthesis of multi-metallic hybrid nanostructured materials. Following that, examples of these materials’ applications in antimicrobial performance targeted at eradicating multi-drug resistant bacteria, material protection such as microbiologically influenced corrosion (MIC), or additives in construction materials have been described.

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Lim, Seung, Juyoung Moon, Uoon Baek, Jae Lee, Youngjin Chae, and Jung Park. "Shape-Controlled TiO2 Nanomaterials-Based Hybrid Solid-State Electrolytes for Solar Energy Conversion with a Mesoporous Carbon Electrocatalyst." Nanomaterials 11, no. 4 (April 3, 2021): 913. http://dx.doi.org/10.3390/nano11040913.

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One-dimensional (1D) titanium dioxide (TiO2) is prepared by hydrothermal method and incorporated as nanofiller into a hybrid polymer matrix of polyethylene glycol (PEG) and employed as a solid-electrolyte in dye-sensitized solar cells (DSSCs). Mesoporous carbon electrocatalyst with a high surface area is obtained by the carbonization of the PVDC-g-POEM double comb copolymer. The 1D TiO2 nanofiller is found to increase the photoelectrochemical performance. As a result, for the mesoporous carbon-based DSSCs, 1D TiO2 hybrid solid-state electrolyte yielded the highest efficiencies, with 6.1% under 1 sun illumination, in comparison with the efficiencies of 3.9% for quasi solid-state electrolyte and 4.8% for commercial TiO2 hybrid solid-state electrolyte, respectively. The excellent photovoltaic performance is attributed to the improved ion diffusion, scattering effect, effective path for redox couple transfer, and sufficient penetration of 1D TiO2 hybrid solid-state electrolyte into the electrode, which results in improved light-harvesting, enhanced electron transport, decreased charge recombination, and decreased resistance at the electrode/electrolyte interface.

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Cohen-Karni, Tzahi. "(Invited) Multi-Modality Input/Output Interfaces with Tissue and Cells Using Nanocarbons." ECS Meeting Abstracts MA2022-01, no. 8 (July 7, 2022): 705. http://dx.doi.org/10.1149/ma2022-018705mtgabs.

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My team’s efforts are focused on three major thrusts: (i) synthesis and in depth mechanistic investigation of the unique emergent optical, thermal, electrical and electrochemical properties of novel hybrid-nanomaterials and nanomaterials topologies composed on one-dimensional and two-dimensional building blocks, (ii) application and characterization of hybrid-nanomaterials interfaces with cells and tissue, and (iii) development and engineering of nanomaterials-based platforms to interrogate and affect the electrical properties of tissue and cells such as cardiomyocytes, and neurons, with a specific focus to understand electrical signal transduction in complex 3D cellular assemblies. Major questions we strive to answer are: Can we make materials and platforms that are tailored to allow seamless and stable integration with cells and tissue enabling sensing and actuation? Can hybrid-nanomaterials allow new insights about biological processes, e.g., tissue development and disease progression? In this talk I will describe our recent efforts in tackling these challenges. Our highly flexible bottom-up nanomaterials synthesis capabilities allow us to form unique hybrid-nanomaterials that can be used in various input/output bioelectrical interfaces, i.e., bioelectrical platforms for chemical and physical sensing and actuation. We developed a breakthrough bioelectrical interface, a 3D self-rolled biosensor arrays (3D-SR-BAs) of either active field effect transistors or passive microelectrodes to measure both cardiac and neural spheroids electrophysiology in 3D. This approach enables electrophysiological investigation and monitoring of the complex signal transduction in 3D cellular assemblies toward an organ-on-an-electronic-chip (organ-on-e-chip) platform for tissue maturation investigations and development of drugs for disease treatment. Utilizing graphene, a two-dimensional (2D) atomically thin carbon allotrope, we demonstrated a new technique to simultaneously record the intracellular electrical activity of multiple excitable cells with ultra-microelectrodes that can be as small as the size as an axon ca. 2µm in size. The outstanding electrochemical properties of our hybrid-nanomaterials allowed us to develop electrical sensors and actuators, e.g., sensors to explore the brain chemistry and sensors/actuators that are deployed in a large volumetric muscle loss animal model. Finally, using the unique optical properties of nanocarbons, e.g., graphene-based hybrid-nanomaterials and 2D nanocarbides (MXene), we have formed remote, non-genetic bioelectrical interfaces with excitable cells and modulated cellular and network activity with high precision and low needed energy. In summary, the exceptional synthetic control and flexible assembly of nanomaterials provide powerful tools for fundamental studies and applications in life science and potentially seamlessly merge nanomaterials-based platforms with cells, fusing nonliving and living systems together.

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46

Tessaro, Leticia, Adriano Aquino, Paloma de Almeida Rodrigues, Nirav Joshi, Rafaela Gomes Ferrari, and Carlos Adam Conte-Junior. "Nucleic Acid-Based Nanobiosensor (NAB) Used for Salmonella Detection in Foods: A Systematic Review." Nanomaterials 12, no. 5 (February 28, 2022): 821. http://dx.doi.org/10.3390/nano12050821.

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Salmonella bacteria is a foodborne pathogen found mainly in food products causing severe symptoms in the individual, such as diarrhea, fever, and abdominal cramps after consuming the infected food, which can be fatal in some severe cases. Rapid and selective methods to detect Salmonella bacteria can prevent outbreaks when ingesting contaminated food. Nanobiosensors are a highly sensitive, simple, faster, and lower cost method for the rapid detection of Salmonella, an alternative to conventional enzyme-linked immunosorbent assay (ELISA) and polymerase chain reaction (PCR) techniques. This study systematically searched and analyzed literature data related to nucleic acid-based nanobiosensors (NABs) with nanomaterials to detect Salmonella in food, retrieved from three databases, published between 2010 and 2021. We extracted data and critically analyzed the effect of nanomaterial functionalized with aptamer or DNA at the limit of detection (LOD). Among the nanomaterials, gold nanoparticles (AuNPs) were the most used nanomaterial in studies due to their unique optical properties of the metal, followed by magnetic nanoparticles (MNPs) of Fe3O4, copper nanoparticles (CuNPs), and also hybrid nanomaterials multiwalled carbon nanotubes (c-MWCNT/AuNP), QD/UCNP-MB (quantum dotes upconverting nanoparticle of magnetic beads), and cadmium telluride quantum dots (CdTe QDs@MNPs) showed excellent LOD values. The transducers used for detection also varied from electrochemical, fluorescent, surface-enhanced Raman spectroscopy (SERS), RAMAN spectroscopy, and mainly colorimetric due to the possibility of visualizing the detection result with the naked eye. Furthermore, we show the magnetic separation system capable of detecting the target amplification of the genetic material. Finally, we present perspectives, future research, and opportunities to use point-of-care (POC) diagnostic devices as a faster and lower cost approach for detecting Salmonella in food as they prove to be viable for resource-constrained environments such as field-based or economically limited conditions.

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Tangthana-umrung, Kanokporn, Xiaomeng Zhang, and Matthieu Gresil. "Synergistic toughening on hybrid epoxy nanocomposites by introducing engineering thermoplastic and carbon-based nanomaterials." Polymer 245 (April 2022): 124703. http://dx.doi.org/10.1016/j.polymer.2022.124703.

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Zeng, Yao, Xia Luo, Kejing Yu, and Kun Qian. "EMI shielding performance of phenolic-based carbon foam modified with GO/SiO2 hybrid nanomaterials." Chemical Physics Letters 715 (January 2019): 166–72. http://dx.doi.org/10.1016/j.cplett.2018.11.040.

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Bojarska, Zuzanna, Marta Mazurkiewicz-Pawlicka, Stanisław Gierlotka, and Łukasz Makowski. "Production and Properties of Molybdenum Disulfide/Graphene Oxide Hybrid Nanostructures for Catalytic Applications." Nanomaterials 10, no. 9 (September 17, 2020): 1865. http://dx.doi.org/10.3390/nano10091865.

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Анотація:

Molybdenum disulfide (MoS2) can be an excellent candidate for being combined with carbon nanomaterials to obtain new hybrid nanostructures with outstanding properties, including higher catalytic activity. The aim of the conducted research was to develop the novel production method of hybrid nanostructures formed from MoS2 and graphene oxide (GO). The nanostructures were synthesized in different weight ratios and in two types of reactors (i.e., impinging jet and semi-batch reactors). Physicochemical analysis of the obtained materials was carried out, using various analytical techniques: particle size distribution (PSD), thermogravimetric analysis (TGA), FT-IR spectroscopy, X-ray diffraction (XRD), and scanning electron microscopy (SEM). Due to the potential application of materials based on MoS2 as the catalyst for hydrogen evolution reaction, linear sweep voltammetry (LSV) of the commercial MoS2, synthesized MoS2 and the obtained hybrid nanostructures was performed using a three-electrode system. The results show that the developed synthesis of hybrid MoS2/GO nanostructures in continuous reactors is a novel and facile method for obtaining products with desired properties. The hybrid nanostructures have shown better electrochemical properties and higher onset potentials compared to MoS2 nanoparticles. The results indicate that the addition of carbon nanomaterials during the synthesis improves the activity and stability of the MoS2 nanoparticles.

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Babanli, Mustafa, and Yusif Tanriverdiyev. "RESEARCH OF Al AND Mg MATRİX HYBRİD LAMİNATED COMPOSİTE MATERİALS." ETM - Equipment, Technologies, Materials 05, no. 01 (January 20, 2021): 11–15. http://dx.doi.org/10.36962/etm0501202011.

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The main purpose of this research is to select suitable matrices and fillers for the preparation of composites that meet modern requirements to meet the needs of a rapidly growing industry. Studies in various databases have shown that metal-matrix hybrid laminated composite materials, mainly aluminum and magnesium alloy plates, are used as matrix materials, while carbon-based nanomaterials are used as fillers. Keywords: composition, matrix, aluminum, magnesium.

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