Дисертації з теми "Bivalent metal ion batteries"
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David, Lamuel Abraham. "Van der Waals sheets for rechargeable metal-ion batteries." Diss., Kansas State University, 2015. http://hdl.handle.net/2097/32796.
Повний текст джерелаDepartment of Mechanical and Nuclear Engineering
Gurpreet Singh
The inevitable depletion of fossil fuels and related environmental issues has led to exploration of alternative energy sources and storage technologies. Among various energy storage technologies, rechargeable metal-ion batteries (MIB) are at the forefront. One dominant factor affecting the performance of MIB is the choice of electrode material. This thesis reports synthesis of paper like electrodes composed for three representative layered materials (van der Waals sheets) namely reduced graphene oxide (rGO), molybdenum disulfide (MoS₂) and hexagonal boron nitride (BN) and their use as a flexible negative electrode for Li and Na-ion batteries. Additionally, layered or sandwiched structures of vdW sheets with precursor-derived ceramics (PDCs) were explored as high C-rate electrode materials. Electrochemical performance of rGO paper electrodes depended upon its reduction temperature, with maximum Li charge capacity of 325 mAh.g⁻¹ observed for specimen annealed at 900°C. However, a sharp decline in Na charge capacity was noted for rGO annealed above 500 °C. More importantly, annealing of GO in NH₃ at 500 °C showed negligible cyclability for Na-ions while there was improvement in electrode's Li-ion cycling performance. This is due to increased level of ordering in graphene sheets and decreased interlayer spacing with increasing annealing temperatures in Ar or reduction at moderate temperatures in NH₃. Further enhancement in rGO electrodes was achieved by interfacing exfoliated MoS₂ with rGO in 8:2 wt. ratios. Such papers showed good Na cycling ability with charge capacity of approx. 225.mAh.g⁻¹ and coulombic efficiency reaching 99%. Composite paper electrode of rGO and silicon oxycarbide SiOC (a type of PDC) was tested as high power-high energy anode material. Owing to this unique structure, the SiOC/rGO composite electrode exhibited stable Li-ion charge capacity of 543.mAh.g⁻¹ at 2400 mA.g⁻¹ with nearly 100% average cycling efficiency. Further, mechanical characterization of composite papers revealed difference in fracture mechanism between rGO and 60SiOC composite freestanding paper. This work demonstrates the first high power density silicon based PDC/rGO composite with high cyclic stability. Composite paper electrodes of exfoliated MoS₂ sheets and silicon carbonitride (another type of PDC material) were prepared by chemical interfacing of MoS₂ with polysilazane followed by pyrolysis . Microscopic and spectroscopic techniques confirmed ceramization of polymer to ceramic phase on surfaces on MoS₂. The electrode showed classical three-phase behavior characteristics of a conversion reaction. Excellent C-rate performance and Li capacity of 530 mAh.g⁻¹ which is approximately 3 times higher than bulk MoS₂ was observed. Composite papers of BN sheets with SiCN (SiCN/BN) showed improved electrical conductivity, high-temperature oxidation resistance (at 1000 °C), and high electrochemical activity (~517 mAh g⁻¹ at 100 mA g⁻¹) toward Li-ions generally not observed in SiCN or B-doped SiCN. Chemical characterization of the composite suggests increased free-carbon content in the SiCN phase, which may have exceeded the percolation limit, leading to the improved conductivity and Li-reversible capacity. The novel approach to synthesis of van der Waals sheets and its PDC composites along with battery cyclic performance testing offers a starting point to further explore the cyclic performance of other van der Waals sheets functionalized with various other PDC chemistries.
Li, Xianji. "Metal nitrides as negative electrode materials for sodium-ion batteries." Thesis, University of Southampton, 2015. https://eprints.soton.ac.uk/374787/.
Повний текст джерелаNose, Masafumi. "Studies on Sodium-containing Transition Metal Phosphates for Sodium-ion Batteries." 京都大学 (Kyoto University), 2016. http://hdl.handle.net/2433/215565.
Повний текст джерелаLubke, Mechthild. "Nano-sized transition metal oxide negative electrode materials for lithium-ion batteries." Thesis, University College London (University of London), 2018. http://discovery.ucl.ac.uk/10044227/.
Повний текст джерелаBudak, Öznil [Verfasser]. "Metal oxide / carbon hybrid anode materials for lithium-ion batteries / Öznil Budak." Saarbrücken : Saarländische Universitäts- und Landesbibliothek, 2020. http://d-nb.info/1232726214/34.
Повний текст джерелаAlwast, Dorothea [Verfasser]. "Electrochemical Model Studies on Metal-air and Lithium-ion Batteries / Dorothea Alwast." Ulm : Universität Ulm, 2021. http://d-nb.info/1237750822/34.
Повний текст джерелаBerti, Nicola. "MgH2-TiH2 hydrides as negative electrodesof Li-ion batteries." Thesis, Paris Est, 2017. http://www.theses.fr/2017PESC1029/document.
Повний текст джерелаToday, lithium-ion batteries are widely used as power supplies in portable electronics such as laptops, smartphones and cameras. However, new applications such as full electric vehicles and energy storage stationary systems require enhanced battery performances. In particular, novel electrode materials with higher energy density are needed.MgH2 and TiH2 hydrides and mixtures of them have high electrochemical capacity (> 1 Ah/g). They have been studied as negative electrode materials in Li-ion batteries. The conversion reaction of lithium with these hydrides and the related microstructural changes have been deeply investigated to gain a better understanding of reaction mechanisms and their reversibility. The electrochemical properties of MgH2 thin films and MgH2+TiH2 composite powders have been evaluated using both liquid organic and solid (LiBH4) electrolytes. Reversible capacity and cycle-life are found to strongly depend on both molar ratio between the hydrides and cycling conditions. Mass transport and density of interfaces within the electrode are identified as the main factors affecting the reversibility of the conversion reaction
Henriques, Alexandra J. "Nano-Confined Metal Oxide in Carbon Nanotube Composite Electrodes for Lithium Ion Batteries." FIU Digital Commons, 2017. http://digitalcommons.fiu.edu/etd/3169.
Повний текст джерелаTsukamoto, Hisashi. "Synthesis and electrochemical studies of lithium transition metal oxides for lithium-ion batteries." Thesis, University of Aberdeen, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.327428.
Повний текст джерелаMartin, Andréa Joris Quentin. "Nano-sized Transition Metal Fluorides as Positive Electrode Materials for Alkali-Ion Batteries." Doctoral thesis, Humboldt-Universität zu Berlin, 2020. http://dx.doi.org/10.18452/21619.
Повний текст джерелаMetal fluoride compounds appear as very appealing candidates for the next generation of alkali-ion battery cathodes. However, many drawbacks prevent this family of compounds to be applicable to storage systems. Metal fluorides demonstrate a high insulating character, and the mechanisms involved during the discharge/charge processes atom engender large volume changes and a drastic reorganization of the material, which induces poor reversibility. In order to answer these problematics, the present thesis reports the elaboration of innovative synthesis routes for transition metal fluoride compounds and the application of these fluoride materials in alkali-ion battery systems. In a first part, MFx compounds (M = Co, Fe; x = 2 or 3) are studied. Those compounds exhibit high initial capacity but very poor cyclability and low C-rate capabilities. Ex-situ X-ray diffraction and transmission electron microscopy demonstrate that the low reversibility of the processes is mainly due to the conversion reaction occurring during their discharge/charge. In the second part, the syntheses of transition metal fluoride perovskites are reported, as well as their electrochemical properties. NaFeF3 demonstrates excellent performances and reversibility. The study of the mechanisms occurring during its charge/discharge processes towards different alkali systems by ex-situ and operando X-ray diffraction reveals that its crystalline framework is maintained along the cycles, resulting in high reversibility and excellent C-rate performance. This retention of the crystal framework is possible by an electrochemical stabilization of a cubic conformation of FeF3, which is usually only observable at high temperature (400 °C), and can be explained by lower reorganizations within the crystal framework. Similar electrochemical properties could be observed for KFeF3 and NH4FeF3, where ammonium ions are reported for the first time as a charge carrier in alkali-ion systems.
Dall'Agnese, Yohan. "Study of early transition metal carbides for energy storage applications." Thesis, Toulouse 3, 2016. http://www.theses.fr/2016TOU30025/document.
Повний текст джерелаAn increase in energy and power densities is needed to match the growing energy storage demands linked with the development of renewable energy production and portable electronics. Several energy storage technologies exist including lithium ion batteries, sodium ion batteries, fuel cells and electrochemical capacitors. These systems are complementary to each other. For example, electrochemical capacitors (ECs) can deliver high power densities whereas batteries are used for high energy densities applications. The first objective of this work is to investigate the electrochemical performances of a new family of 2-D material called MXene and propose new solutions to tackle the energy storage concern. To achieve this goal, several directions have been explored. The first part of the research focuses on MXene behavior as electrode material for electrochemical capacitors in aqueous electrolytes. The next part starts with sodium-ion batteries, and a new hybrid system of sodium ion capacitor is proposed. The last part is the study of MXene electrodes for supercapacitors is organic electrolytes. The energy storage mechanisms are thoroughly investigated. Different characterization techniques were used in this work, such as cyclic voltammetry, galvanostatic charge-discharge, electrochemical impedance spectroscopy, scanning electron microscopy and X-ray diffraction
Wang, Miaojun. "Energetics of lithium transition metal oxides applied as cathode materials in lithium ion batteries /." For electronic version search Digital dissertations database. Restricted to UC campuses. Access is free to UC campus dissertations, 2005. http://uclibs.org/PID/11984.
Повний текст джерелаLimthongkul, Pimpa 1975. "Phase transformations and microstructural design of lithiated metal anodes for lithium-ion rechargeable batteries." Thesis, Massachusetts Institute of Technology, 2002. http://hdl.handle.net/1721.1/8443.
Повний текст джерелаIncludes bibliographical references.
There has been great recent interest in lithium storage at the anode of Li-ion rechargeable battery by alloying with metals such as Al, Sn, and Sb, or metalloids such as Si, as an alternative to the intercalation of graphite. This is due to the intrinsically high gravimetric and volumetric energy densities of this type of anodes (can be over an order of magnitude of that of graphite). However, the Achilles' heel of these Li-Me alloys has been the poor cyclability, attributed to mechanical failure resulting from the large volume changes accompanying alloying. Me-oxides, explored as candidates for anode materials because of their higher cyclability relative to pure Me, suffer from the problem of first cycle irreversibility. In both these types of systems, much experimental and empirical data have been provided in the literature on a largely comparative basis (i.e. investigations comparing the anode behavior of some new material with older candidates). It is the belief of the author that, in order to successfully proceed with the development of better anode materials, and the subsequent design and production of batteries with better intrinsic energy densities, a fundamental understanding of the relationship between the science and engineering of anode materials must be achieved, via a systematic and quantitative investigation of a variety of materials under a number of experimental conditions. In this thesis, the effects of composition and processing on microstructure and subsequent electrochemical behavior of anodes for Li-ion rechargeable batteries were investigated, using a number of approaches.
(cont.) First, partial reduction of mixed oxides including Sb-V-O, Sb-Mn-O, Ag-V-O, Ag-Mn-O and Sn-Ti-O, was explored as a method to produce anode materials with high cyclability relative to pure metal anodes, and decreased first cycle irreversibility relative to previously produced metal-oxides. The highest cyclability was achieved with anode materials where the more noble metal of the mixed oxide was reduced internally, producing nanoscale active particles which were passivated by an inactive matrix. Second, a systematic study of various metal anode materials, including Si, Sn, Al, Sb and Ag, of different starting particle sizes was undertaken, in order to better understand the micromechanical mechanisms leading to poor cyclability in these pure metals. SEM of these materials revealed fracture in particles of > 1 pm after a single discharge/charge cycle, consistent with literature models which predict such fracture due to volumetric strains upon lithiation. However, TEM of these materials revealed a nanocrystalline structure after one cycle that in some metals was mixed with an amorphous phase. STEM of anode materials after 50 cycles revealed a dissociation of this nanostructure into nanoparticles, suggesting a failure mechanism other than volumetric strains, such as chemical attack. Finally, the appearance of the amorphous phase was investigated in lithiated Si, Sn, Ag and Al metal anode systems. A new mechanism, electrochemically-induced solid-state amorphization was proposed and explored via experiments using calibrated XRD and TEM. Experimental observations of these various Me systems subjected to different degrees of lithiation supported such phenomenon...
by Pimpa Limthongkul.
Ph.D.
Arayamparambil, Jeethu Jiju. "Metal carbodiimides and cyanamides, a new family of electrode materials for Li-ion batteries." Thesis, Montpellier, 2019. http://www.theses.fr/2019MONTS066.
Повний текст джерелаLi-ion batteries are currently the most common choice for all portable electronic devices but also for hybrid electric vehicles and renewable energy sectors. At present, graphite is routinely employed as the anode material for Li-ion-batteries due to its excellent attributes such as long cycle life, abundance, and relatively cost effective. However, the disadvantages of graphitic anode include low energy density and safety concerns. As a consequence, alternative cost effective anode materials with high energy density and long cycle life have been widely explored. Among this transition metal based compounds are an exciting and reasonable alternative for graphite owing to their high specific capacity. Compounds with the formula MX where M is a divalent metal and X = O, S, PO4, and CO3 have been reported to be electrochemically active at average voltages around 1 volts. In spite of their high theoretical specific capacities, high irreversible capacity in the first lithiation and the weak cycling life prevent the practical use of these materials. Since 2015, the possibility of using transition metal carbodiimides (MNCN, with M = Fe, Mn, Co, Cu, Zn, Ni) have been reported, and some of them have shown promising electrochemical performance as anode materials for both Li and Na ion batteries. Like all divalent metal based electrode materials, carbodiimides have been found to suffer from high initial irreversible capacity and high operating voltage, however they show a better cycle life. The application of transition metal carbodiimides in the field of energy storage (and conversion) is still in its early stages and despite progress in electrochemical evaluation much remains to be done in order to establish the reaction mechanisms that govern the reported promising performances. Besides the transition metal carbodiimides there are still many other inorganic cyanamides and carbodiimides materials to explore. Therefore the main targets of this PhD work are (i) to assess the properties of new carbodiimides/cyanamides as electrode materials for LiBs and (ii) to establish their electrochemical reaction mechanisms via advanced operando techniques and DFT calculations. Concerning the electrochemical performance, Cr2(NCN)3 turned out to be by the far the best carbodiimide anode material with stable specific capacity of more than 600 mAh.g-1 for more than 900 cycles at 2C rate. CoNCN and FeNCN have also shown excellent electrochemical properties since they can sustain a specific capacity higher than 500 mAh.g-1 for more than 100 cycles at 2C rate. Poor performance was observed for PbNCN, Ag2NCN and ZnNCN since the practical capacities are well below the theoretical ones. These phase show also fast capacity fading during the first 20 cycles. These three performance categories correlate well with the three different reaction mechanisms established for the investigated phases. Up to now, three types of reaction mechanism have been identified including (i) Combined intercalation and conversion processes in the case of Cr2(NCN)3 as evidenced by both theoretical and experimental methods, (ii) pure conversion reaction in the case of CoNCN and finally (iii) a combined conversion and alloying mechanism in the case of Pb, Zn and Ag compounds. It is worth noting that whatever the reaction pathway, all the carbodiimide/cyanamide anode materials face the limitation of a significantly low coulombic efficiency during the first cycles. To overcome this obstacle, much effort is needed to clarify the nature and the role of SEI in the overall performance of this family of materials. The promising results reported in this work do not probably yet meet the standards needed to take carbodiimides/cyanamides into the practical applications, but they clearly evidence the rich possibilities offered by this young family of molecular inorganic materials
Thanaweera, Achchige Dumindu P. "Design and characterisation of layered transition metal oxide cathode materials for Na-ion batteries." Thesis, Queensland University of Technology, 2022. https://eprints.qut.edu.au/228445/1/Dumindu_Thanaweera%20Achchige_Thesis.pdf.
Повний текст джерелаLINGUA, GABRIELE. "Newly designed single-ion conducting polymer electrolytes enabling advanced Li-metal solid-state batteries." Doctoral thesis, Politecnico di Torino, 2022. http://hdl.handle.net/11583/2969103.
Повний текст джерелаWang, Luyuan Paul. "Matériaux à hautes performance à base d'oxydes métalliques pour applications de stockage de l'énergie." Thesis, Université Grenoble Alpes (ComUE), 2017. http://www.theses.fr/2017GREAI031/document.
Повний текст джерелаThe heart of battery technology lies primarily in the electrode material, which is fundamental to how much charge can be stored and how long the battery can be cycled. Tin dioxide (SnO₂) has received tremendous attention as an anode material in both Li-ion (LIB) and Na-ion (NIB) batteries, owing to benefits such as high specific capacity and rate capability. However, large volume expansion accompanying charging/discharging process results in poor cycleability that hinders the utilization of SnO₂ in commercial batteries. To this end, engineering solutions to surmount the limitations facing SnO₂ as an anode in LIB/NIB will be presented in this thesis. The initial part of the thesis focuses on producing SnO₂ and rGO (reduced graphene oxide)/SnO₂ through laser pyrolysis and its application as an anode. The following segment studies the effect of nitrogen doping, where it was found to have a positive effect on SnO₂ in LIB, but a detrimental effect in NIB. The final part of the thesis investigates the effect of matrix engineering through the production of a ZnSnO₃ compound. Finally, the obtained results will be compared and to understand the implications that they may possess
Maisuradze, Mariam. "Synthesis and Characterization of Double Metal Hexacyanoferrates." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2020. http://amslaurea.unibo.it/21014/.
Повний текст джерелаCourtney, Ian Anthony. "The physics and chemistry of metal oxide composites as anode materials for lithium-ion batteries." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape9/PQDD_0021/NQ49253.pdf.
Повний текст джерелаSgarbi, Stabellini Francesca. "Synthesis and surface characterization of metal (Mn, Ti) hexacyanoferrate electrodes." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2021. http://amslaurea.unibo.it/24378/.
Повний текст джерелаOhira, Koji. "Systematic survey of phosphate materials for lithium-ion batteries by first principle calculations." Master's thesis, 京都大学 (Kyoto University), 2013. http://hdl.handle.net/2433/180500.
Повний текст джерелаMoore, Charles J. (Charles Jacob). "Ab initio screening of lithium diffusion rates in transition metal oxide cathodes for lithium ion batteries." Thesis, Massachusetts Institute of Technology, 2012. http://hdl.handle.net/1721.1/79562.
Повний текст джерелаCataloged from PDF version of thesis.
Includes bibliographical references (p. 57-62).
A screening metric for diffusion limitations in lithium ion battery cathodes is derived using transition state theory and common materials properties. The metric relies on net activation barrier for lithium diffusion. Several cathode materials are screened using this approach: [beta]'-LiFePO4, hexagonal LiMnBO3, monoclinic LiMnBO3, Li 3Mn(CO3)(PO4), and Li9V3 (P2O7)3(PO4) 2. The activation barriers for the materials are determined using a combined approach. First, an empirical potential model is used to identify the lithium diffusion topology. Second, density functional theory is used to determine migration barriers. The accuracy of the empirical potential diffusion topologies, the density functional theory migration barriers, and the overall screening metric are compared against experimental evidence to validate the methodology. The accuracy of the empirical potential model is also evaluated against the density functional theory migration barriers.
by Charles J. Moore.
S.M.
Mohamed, Zakiah. "Relationships Among Structure, Magnetism and State of Charge in Positive Electrode Materials for Metal-Ion Batteries." Thesis, The University of Sydney, 2015. http://hdl.handle.net/2123/14438.
Повний текст джерелаCognet, Marine. "Elaboration de matériaux hybrides pour le stockage de l’énergie et le recyclage de batteries Li-Ion." Thesis, Montpellier, 2019. http://www.theses.fr/2019MONTS064.
Повний текст джерелаEnergy storage is one of the biggest challenges for next decades and a key player for the energy transition. The management of renewable energy production requires more efficient and easily recyclable electrochemical energy storage devices for the eco-responsible development of those technologies.During this PhD thesis, MOFs were used as electrode material but also as a tool for recycling of Li-ion batteries. Three differents MOFs, based on phosphonate, sulfonate or carboxylate ligands, have been developed with different transition metals (Fe, Ni, Mn and Co). Promising electrochemical properties have been observed and post-cycling analysis allowed enlightening the advantages of MOFs as electrode materials. Finally, a recycling method have been developed by the selective precipitation of metals as MOFs in real Li-ion battery waste solutions. The formation of high valuable materials could be one way to close the life circle of batteries economically
Vijayakumar, V. "Preparation, characterization and application of proton, lithium and zinc-ion conducting polymer electrolytes for supercapacitors, lithium- and zinc-metal batteries." Thesis(Ph.D.), CSIR-National Chemical Laboratory, 2021. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/5972.
Повний текст джерелаUniversity Grants Commissions (UGC), India CSIR, India
AcSIR
Purushothaman, Bushan K. "DEVELOPMENT OF BATTERIES FOR IMPLANTABLE APPLICATIONS." Case Western Reserve University School of Graduate Studies / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=case1151609663.
Повний текст джерелаMartin, Andréa Joris Quentin [Verfasser]. "Nano-sized Transition Metal Fluorides as Positive Electrode Materials for Alkali-Ion Batteries / Andréa Joris Quentin Martin." Berlin : Humboldt-Universität zu Berlin, 2020. http://d-nb.info/1220690406/34.
Повний текст джерелаGao, Shuang. "INVESTIGATION OF TRANSITION-METAL IONS IN THE NICKEL-RICH LAYERED POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES." UKnowledge, 2019. https://uknowledge.uky.edu/cme_etds/100.
Повний текст джерелаInamoto, Jun-ichi, and Junichi Inamoto. "Electrochemical Characterization of Surface-State of Positive Thin-Film Electrodes in Lithium-Ion Batteries." Kyoto University, 2017. http://hdl.handle.net/2433/226784.
Повний текст джерелаZhao, Zijian [Verfasser], and H. [Akademischer Betreuer] Ehrenberg. "Study of Ternary Transition Metal Oxides as Conversion Anodes in Li-Ion Batteries / Zijian Zhao ; Betreuer: H. Ehrenberg." Karlsruhe : KIT-Bibliothek, 2019. http://d-nb.info/1199459917/34.
Повний текст джерелаBaur, Christian [Verfasser]. "Li-rich disordered rock salt transition metal oxyfluorides as novel cathode materials in lithium-ion batteries / Christian Baur." Ulm : Universität Ulm, 2020. http://d-nb.info/1219577693/34.
Повний текст джерелаGosselink, Denise. "Study of Transition Metal Phosphides as Anode Materials for Lithium-ion Batteries: Phase Transitions and the Role of the Anionic Network." Thesis, University of Waterloo, 2006. http://hdl.handle.net/10012/2958.
Повний текст джерелаTian, Guiying [Verfasser], and H. [Akademischer Betreuer] Ehrenberg. "Study on lithium ion migration in the composite solid electrolyte for lithium metal batteries / Guiying Tian ; Betreuer: H. Ehrenberg." Karlsruhe : KIT-Bibliothek, 2019. http://d-nb.info/1177147157/34.
Повний текст джерелаNilsson, Viktor. "Highly Concentrated Electrolytes for Lithium Batteries : From fundamentals to cell tests." Licentiate thesis, Chalmers University of Technology, 2018. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-351339.
Повний текст джерелаElektrolyten är en fundamental del av ett litiumbatteri som starkt påverkar livslängden och säkerheten. Den måste utstå svåra förhållanden, inte minst vid gränsytan mot elektroderna. Dagens kommersiella elektrolyter är baserade på 1 M LiPF 6 i en blandning av organiska lösningsmedel. De balanserar kraven på elektrokemisk stabilitet och jonledningsförmåga, men de är lättflyktiga och bryts ned när de används vid temperaturer över ca. 70°C. Saltet skulle kunna bytas ut mot t.ex. LiTFSI, vilket ökar värmetåligheten avsevärt, men istället uppstår problem med korrosion på den strömsamlare av aluminium som används för katoden. Genom att byta ut grafitanoden i ett Li-jonbatteri mot en folie av litiummetall kan man öka energitätheten, men då litium pläteras bildas ständigt nya Li-ytor som kan reagera med elektrolyten. Detta leder till en låg coulombisk effektivitet genom nedbrytning av både Li och elektrolyt. Högkoncentrerade elektrolyter har en mycket hög saltkoncentration, ofta över 4 M, och har lags fram som en möjlig lösning på många av de problem som plågar denna och nästa generations batterier. Dessa elektrolyter har en annorlunda lösningsstruktur, sådan att alla lösningsmedelsmolekyler koordinerar till katjoner – vilket leder till att de blir mindre lättflyktiga, får en ökad täthet av laddningsbärare, och en ökad elektrokemisk stabilitet. Samtidigt får de en högre viskositet och lägre jonledningsförmåga. Här har två angreppssätt för högkoncentrerade elektrolyter utvärderats. I det första har acetonitril, som har begränsad elektrokemisk stabilitet och ett högt ångtryck, blandats med LiTFSI för en uppsättning av elektrolyter med varierande koncentration. Dessa har testats i Li-jonbatterier och i synnerhet den passiverande ytan på grafitelektroder har undersökts med både röntgen-fotoelektronspektroskopi (XPS) och elektrokemiska metoder. En markant förbättring av den elektrokemiska stabiliteten observeras, men de inneboende bristerna hos elektrolyten kan inte kompenseras fullständigt, vilket skapar tvivel på hur väl detta kan fungera i en kommersiell cell. Med det andra angreppssättet har hög saltkoncentration nyttjats för sänka smältpunkten för en elektrolyt baserad på etylenkarbonat, som annars inte kan används som enda lösningsmedel. Dessa elektrolyter har testats för användning i Limetall-batterier genom långtidstest, mätning av den coulombiska effektiviteten och analys av deponerade Li-ytor med svepelektronmikroskop. Resultaten är lovande, med över 250 cykler på 0.5 mAh/cm2 och en effektivitet på över 94%, men framförallt observeras en mycket jämnare deponerad Li-yta, vilket kan möjliggöra säker cykling av Li-metall-batterier. Ett logiskt nästa steg är studier av Liytan med t.ex. XPS för att utröna vad som skiljer den från ytan som bildats i en 1 M referenselektrolyt.
聖, 橋上, and Satoshi Hashigami. "Studies on degradation factors and their mitigation methods of cathode materials for advanced lithium-ion batteries." Thesis, https://doors.doshisha.ac.jp/opac/opac_link/bibid/BB13106330/?lang=0, 2019. https://doors.doshisha.ac.jp/opac/opac_link/bibid/BB13106330/?lang=0.
Повний текст джерелаThe development of energy storage technologies using batteries has attracted much attention to introduce the renewable energy. If we can achieve 250 Wh kg-1 with the advanced LIBs based on the principle of LIB, we can lower the cost of the total energy storage systems while ensuring the safety, and hence the advanced LIBs will accelerate the world-wide spread of large-scale power storage systems. In this thesis, the author focused surface modification of lithium-rich layered ternary transition metal oxide and high-nickel layered ternary transition metal oxide cathode particles with oxides as mitigation methods for capacity fading.
博士(工学)
Doctor of Philosophy in Engineering
同志社大学
Doshisha University
Combelles, Cécil. "Modélisation ab-initio Appliquée à la Conception de Nouvelles Batteries Li-Ion." Phd thesis, Université Montpellier II - Sciences et Techniques du Languedoc, 2009. http://tel.archives-ouvertes.fr/tel-00421182.
Повний текст джерелаLi, Chengping [Verfasser], and H. [Akademischer Betreuer] Ehrenberg. "Investigation of Metal Oxides/Sulfides as Negative Electrode Materials for Li-ion and Beyond-Li Batteries / Chengping Li ; Betreuer: H. Ehrenberg." Karlsruhe : KIT-Bibliothek, 2021. http://d-nb.info/1227451296/34.
Повний текст джерелаDe, Villiers Daniel. "The application of new generation batteries in old tactical radios / D. de Villiers." Thesis, North-West University, 2007. http://hdl.handle.net/10394/738.
Повний текст джерелаThesis (M.Ing. (Electronical Engineering))--North-West University, Potchefstroom Campus, 2008.
Lyness, Christopher. "Novel lithium-ion host materials for electrode applications." Thesis, University of St Andrews, 2011. http://hdl.handle.net/10023/1921.
Повний текст джерелаLiu, Xinye. "Binary metal organic framework derived hierarchical hollow Ni3S2/Co9S8/N-doped carbon composite with superior sodium storage performance." University of Akron / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=akron1489784678856585.
Повний текст джерелаMANCINI, Marilena. "Improved anodic materials for lithium-ion batteries: surface modification by metal deposition and electrochemical characterization of oxidized graphite and titanium dioxide electrodes." Doctoral thesis, Università degli Studi di Camerino, 2009. http://hdl.handle.net/11581/401752.
Повний текст джерелаGiesecke, Marianne. "Characterizing ions in solution by NMR methods." Doctoral thesis, KTH, Tillämpad fysikalisk kemi, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-149552.
Повний текст джерелаQC 20140825
Zhang, Yirui S. M. Massachusetts Institute of Technology. "Understanding the pathway and mechanism of electrolyte decomposition on metal oxide surfaces in Li-ion batteries by in situ Fourier Transform Infrared Spectroscopy." Thesis, Massachusetts Institute of Technology, 2019. https://hdl.handle.net/1721.1/122227.
Повний текст джерелаCataloged from PDF version of thesis.
Includes bibliographical references (pages 69-75).
Understanding (electro)chemical reactions at the electrode-electrolyte interface (EEI) is crucial to promote the cycle life of lithium-ion batteries. In situ studies of EEI can provide new insights into reaction intermediates and soluble species not accessible by ex situ characterization of electrode surfaces. In this study, we developed an in situ Fourier Transform infrared spectroscopy (FTIR) method to investigate the (electro)chemical reactions at the interface between the electrolyte and composite positive electrode surface during charging. While ethyl methyl carbonate (EMC) and ethylene carbonate (EC) were stable against (electro)chemical oxidation on Pt up to 4.8 VL, dehydrogenation of both carbonates on the surface of LiNio.8Cooa.Mno.l02 (NMC81 1) electrodes was revealed by in situ FTIR spectra and density functional theory (DFT). Both solvents can dehydrogenate and form de-H EC and de-H EMC, respectively, with carbon atom binding to lattice oxygen and sticking on surface. De-H EC can further remove another hydrogen atom to form vinylene carbonate (VC) or bind together to form oligomers, both of which are soluble and hard to be accessed through ex-situ methods. In situ FTIR method successfully tracked detailed pathways of solvent decomposition on oxide surface, and electrochemical impedance spectroscopy (EIS) further confirmed the formation of a passivating layer from solvent decomposition on the surface. The impedance growth is oxide and solvation structure-dependent and it accounts for battery degrading. We finally proposed and verified multiple strategies to further improve the cycling stability of high-energy density positive electrode in Li-ion batteries.
by Yirui Zhang.
S.M.
S.M. Massachusetts Institute of Technology, Department of Mechanical Engineering
Popa, Andreia Ioana. "Electrochemistry and magnetism of lithium doped transition metal oxides." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-26029.
Повний текст джерелаPopa, Andreia Ioana. "Electrochemistry and magnetism of lithium doped transition metal oxides." Doctoral thesis, Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden, 2009. https://tud.qucosa.de/id/qucosa%3A25180.
Повний текст джерелаGao, Suning [Verfasser], Rudolf [Gutachter] Holze, Rudolf [Akademischer Betreuer] Holze, and Qunting [Gutachter] Qu. "Layered transition metal sulfide- based negative electrode materials for lithium and sodium ion batteries and their mechanistic studies / Suning Gao ; Gutachter: Rudolf Holze, Qunting Qu ; Betreuer: Rudolf Holze." Chemnitz : Technische Universität Chemnitz, 2020. http://d-nb.info/1219910309/34.
Повний текст джерелаBani, Hashemi Amir [Verfasser], Mantia Fabio [Akademischer Betreuer] La, Mantia Fabio [Gutachter] La, and Mauro [Gutachter] Pasta. "Electrochemical and morphological characterization of the Interface at negative electrodes in aqueous metal-ion batteries "Gas Evolution & electrodepostion Efficiency" / Amir Bani Hashemi ; Gutachter: Fabio La Mantia, Mauro Pasta ; Betreuer: Fabio La Mantia." Bremen : Staats- und Universitätsbibliothek Bremen, 2018. http://d-nb.info/1154925978/34.
Повний текст джерелаBhatti, Asif Iqbal. "Calculs ab-initio et simulations atomistiques des propriétés thermodynamiques et cinétiques de complexes de métaux de transition utilisés comme batteries." Thesis, Université Grenoble Alpes (ComUE), 2018. http://www.theses.fr/2018GREAI092/document.
Повний текст джерелаAbstract Standard redox potentials for mono and bi-nuclear transition metal (TM) complexes left[Mleft(dmbpyright)_{3}right]^{n+}nCi^{-}, have been investigated using First Principles Calculation. Three metal centers are investigated: Fe, Ru, and Cu. Our modeling is validated on mono-nuclear compounds. This approach consists in determining the best small polymer (bi-nuclear) made out of these monomers for a battery application. For that, we varied the three available degrees of freedom i.e., the nature of the central TM atom (Fe, Ru, and Cu), counter-ions Ci=PF_{6}^{-}, TFSI^{-} and ClO_{4}^{-} in interaction with the polymer, and the alkyl chain -left(CH_{2}right)_{n}- of length n that connects both mono-nuclear in the bi-nuclear compound. The Iron compound with -left(CH_{2}right)_{n=6}- is found to be the best candidate. The left[Culeft(dmbpyright)_{2}right]^{n+}nCi^{-} complex shows too much structure deformation upon loading, making it less reliable for cathode material. Moreover, we studied two XC functional, PBE and PBE0 and found, for three complexes PBE approximation retains the ligand field picture whereas PBE0 functional induces an exaggerated and unexpected band dispersion by dissolving the ligand field picture expected for the octahedral environment of the TM in the studied complexes. These findings validate that hybrid functional for which it was designed to localize and cancel self-interaction error does not work for all system. More particularly, the PBE0 approximation fails to model the three complexes (Fe, Ru, and Cu) in functional conditions (in the field made by the counter-ions).Abstract Further, we have developed an atomistic potential relying on the Force Field scheme for the Iron complex in order to study the dynamical properties of this compound at larger simulation scale (3D reticulated polymerization made of our Fe complex monomers). We made an intensive use of our DFT data (energies, geometries, spin-state configurations and calculated vibrational properties) to develop the required parameters entering the model. Moreover, computational techniques (written python language) were developed specifically to create a 3D structure of transition metal complexes satisfying the condition to be fully reticulated. Bounding conditions had to be designed and a procedure aiming at fixing reliable and physical effective charges on each atom of the simulation cell (compatible with DFT results) were developed. Our first simulations have been attached to calculate the diffusion coefficients of the counter-ions in both the fully loaded and unloaded states. A more ambitious and realistic calculation aims at investigating the paths of the counter-ions when one single center starts to be loaded in an unloaded environment.Abstract Keyword: Polymer, Electrochemistry, Li-ion Battery, DFT, Force Field development, 3D structure, Atomistic modeling
Adam, Robert. "Phasenumwandlungen und Änderungen der Mikrostruktur in Konversionselektroden für Lithium-Ionen-Batterien basierend auf 3d-Übergangsmetalloxiden." TU Bergakademie Freiberg, 2020. https://tubaf.qucosa.de/id/qucosa%3A75540.
Повний текст джерелаVenkatesha, Akshatha. "Structural and Electrochemical Investigations of Monovalent and Divalent Aqueous Rechargeable Batteries." Thesis, 2023. https://etd.iisc.ac.in/handle/2005/6205.
Повний текст джерелаUGC, DST