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Статті в журналах з теми "Biomass derivatives"

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Автор: Grafiati

Опубліковано: 14 березня 2023

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1

Ge, Shaokui, Ming Xu, Gerald L. Anderson, and Raymond I. Carruthers. "Estimating Yellow Starthistle (Centaurea solstitialis) Leaf Area Index and Aboveground Biomass with the Use of Hyperspectral Data." Weed Science 55, no. 6 (December 2007): 671–78. http://dx.doi.org/10.1614/ws-06-212.1.

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Hyperspectral remote-sensed data were obtained via a Compact Airborne Spectrographic Imager-II (CASI-II) and used to estimate leaf-area index (LAI) and aboveground biomass of a highly invasive weed species, yellow starthistle (YST). In parallel, 34 ground-based field plots were used to measure aboveground biomass and LAI to develop and validate hyperspectral-based models for estimating these measures remotely. Derivatives of individual hyperspectral bands improved the correlations between imaged data and actual on-site measurements. Six derivative-based normalized difference vegetation indices (DNDVI) were developed; three of them were superior to the commonly used normalized difference vegetation index (NDVI) in estimating aboveground biomass of YST, but did not improve estimates of LAI. The locally integrated derivatives-based vegetation indices (LDVI) from adjacent bands within three different spectral regions (the blue, red, and green reflectance ranges) were used to enhance absorption characteristics. Three LDVIs outperformed NDVI in estimating LAI, but not biomass. Multiple regression models were developed to improve the estimation of LAI and aboveground biomass of YST, and explained 75% and 53% of the variance in biomass and LAI, respectively, based on validation assessments with actual ground measurements.

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2

Dutta, Saikat, Linglin Wu, and Mark Mascal. "Production of 5-(chloromethyl)furan-2-carbonyl chloride and furan-2,5-dicarbonyl chloride from biomass-derived 5-(chloromethyl)furfural (CMF)." Green Chemistry 17, no. 7 (2015): 3737–39. http://dx.doi.org/10.1039/c5gc00936g.

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Biomass-derived CMF is oxidized to the acid chloride CMFCC in a single step using inexpensive t-butyl hypochlorite. Likewise, DFF, also a CMF derivative, is oxidized directly to the diacid chloride FDCC. The products are platforms for a variety of chemical derivatives of carbohydrates.

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3

de Assis, Geovânia C., Igor M. A. Silva, Tiago G. dos Santos, Thatiane V. dos Santos, Mario R. Meneghetti, and Simoni M. P. Meneghetti. "Photocatalytic processes for biomass conversion." Catalysis Science & Technology 11, no. 7 (2021): 2354–60. http://dx.doi.org/10.1039/d0cy02358b.

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4

Lu, Xihong, Shilei Xie, Hao Yang, Yexiang Tong, and Hongbing Ji. "Photoelectrochemical hydrogen production from biomass derivatives and water." Chem. Soc. Rev. 43, no. 22 (2014): 7581–93. http://dx.doi.org/10.1039/c3cs60392j.

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5

Cottet, Celeste, Yuly A. Ramirez-Tapias, Juan F. Delgado, Orlando de la Osa, Andrés G. Salvay, and Mercedes A. Peltzer. "Biobased Materials from Microbial Biomass and Its Derivatives." Materials 13, no. 6 (March 11, 2020): 1263. http://dx.doi.org/10.3390/ma13061263.

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There is a strong public concern about plastic waste, which promotes the development of new biobased materials. The benefit of using microbial biomass for new developments is that it is a completely renewable source of polymers, which is not limited to climate conditions or may cause deforestation, as biopolymers come from vegetal biomass. The present review is focused on the use of microbial biomass and its derivatives as sources of biopolymers to form new materials. Yeast and fungal biomass are low-cost and abundant sources of biopolymers with high promising properties for the development of biodegradable materials, while milk and water kefir grains, composed by kefiran and dextran, respectively, produce films with very good optical and mechanical properties. The reasons for considering microbial cellulose as an attractive biobased material are the conformational structure and enhanced properties compared to plant cellulose. Kombucha tea, a probiotic fermented sparkling beverage, produces a floating membrane that has been identified as bacterial cellulose as a side stream during this fermentation. The results shown in this review demonstrated the good performance of microbial biomass to form new materials, with enhanced functional properties for different applications.

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6

Lund, Torben, Henning Lund, and Jyoti Chattopadhyaya. "Electrochemical Reduction of Furan Derivatives Derived from Biomass." Acta Chemica Scandinavica 39b (1985): 429–35. http://dx.doi.org/10.3891/acta.chem.scand.39b-0429.

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7

Zhao, Li, Niki Baccile, Silvia Gross, Yuanjian Zhang, Wei Wei, Yuhan Sun, Markus Antonietti, and Maria-Magdalena Titirici. "Sustainable nitrogen-doped carbonaceous materials from biomass derivatives." Carbon 48, no. 13 (November 2010): 3778–87. http://dx.doi.org/10.1016/j.carbon.2010.06.040.

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8

ONDA, Ayumu, Shuhei OGO, and Kazumichi YANAGISAWA. "Catalytic Conversions of Biomass Derivatives Over Apatite Compounds." Hyomen Kagaku 32, no. 6 (2011): 387–92. http://dx.doi.org/10.1380/jsssj.32.387.

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9

Umerzakova, M. B., B. K. Donenov, R. B. Sarieva, and Zh N. Kainarbaeva. "PREPARATION OF SULPHATED FATTY ACID DERIVATIVES OF SPIRULINA OIL." Chemical Journal of Kazakhstan 73, no. 1 (March 14, 2021): 34–42. http://dx.doi.org/10.51580/2021-1/2710-1185.03.

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A new sulfonated derivative of Spirulina oil fatty acids was obtained in the work.This derivative is obtained from dry biomass of microalgae in several stages: extraction of lipids from dry biomass, lipid methylation, amination of the formed methyl esters of Spirulina fatty acids, modification of amide with maleic anhydrideand subsequent reaction of the synthesized monoester with sodium bisulfate. The conditions for all stages of the synthesis of the sulfonated derivative were optimized.The initial compounds and reaction products were identified by IR spectroscopy.

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10

Liu, Xiaoqing, Xiaoguang Duan, Wei Wei, Shaobin Wang, and Bing-Jie Ni. "Photocatalytic conversion of lignocellulosic biomass to valuable products." Green Chemistry 21, no. 16 (2019): 4266–89. http://dx.doi.org/10.1039/c9gc01728c.

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11

Lipcius, R. N., D. B. Eggleston, D. L. Miller, and T. C. Luhrs. "The habitat-survival function for Caribbean spiny lobster: an inverted size effect and non-linearity in mixed algal and seagrass habitats." Marine and Freshwater Research 49, no. 8 (1998): 807. http://dx.doi.org/10.1071/mf97094.

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The habitat-survival function (HSF) defines changes in survival relative to habitat structure; forms include linear, hyperbolic and sigmoid (threshold) curves, whose consequences on predator–prey dynamics are illustrated by their first derivatives. Survival of two juvenile size classes of Caribbean spiny lobster was evaluated as a function of plant biomass in tethering experiments in mixed algal and seagrass patches adjacent to Bahía de la Ascensión, Mexico, which serves as nursery habitat. The HSF was hyperbolic for algal biomass; even modest increases of algal biomass significantly enhanced lobster survival. The rate of change in survival as a function of algal biomass (i.e. an approximation of the first derivative) was greatest at low-to-moderate levels of habitat structure. Hence, survival in these microhabitats is either low or rapidly changing with alterations in habitat structure, and they should be avoided by juveniles. Seagrass biomass did not significantly influence survival, although its levels were relatively low. Smaller juveniles had significantly higher survival rates than larger juveniles, probably because of the limited availability of appropriately scaled refugia for larger juveniles; large juveniles may display an ontogenetic shift from these habitats to coral reefs because of elevated predation risk as they grow.

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12

Liu, Jie, Yanjun Li, and Zhichao Lou. "Recent Advancements in MOF/Biomass and Bio-MOF Multifunctional Materials: A Review." Sustainability 14, no. 10 (May 10, 2022): 5768. http://dx.doi.org/10.3390/su14105768.

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Metal–organic frameworks (MOFs) and their derivatives have delivered perfect answers in detection, separation, solving water and electromagnetic pollution and improving catalysis and energy storage efficiency due to their advantages including their highly tunable porosity, structure and versatility. Recently, MOF/biomass, bio-MOFs and their derivatives have gradually become a shining star in the MOF family due to the improvement in the application performance of MOFs using biomass and biomolecules. However, current studies lack a systematic summary of the synthesis and advancements of MOF/biomass, bio-MOFs and their derivatives. In this review, we describe their research progress in detail from the following two aspects: (1) synthesis of MOF/biomass using biomass as a template to achieve good dispersion and connectivity at the same time; (2) preparing bio-MOFs by replacing traditional organic linkers with biomolecules to enhance the connection stability between metal ions/clusters and ligands and avoid the formation of toxic by-products. This enables MOFs to possess additional unique advantages, such as improved biocompatibility and mechanical strength, ideal reusability and stability and lower production costs. Most importantly, this is a further step towards green and sustainable development. Additionally, we showcase some typical application examples to show their great potential, including in the fields of environmental remediation, energy storage and electromagnetic wave absorption.

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13

Oliveira, Luiz, Márcio Pereira, Ana Pacheli Heitman, José Filho, Cinthia Oliveira, and Maria Ziolek. "Niobium: The Focus on Catalytic Application in the Conversion of Biomass and Biomass Derivatives." Molecules 28, no. 4 (February 4, 2023): 1527. http://dx.doi.org/10.3390/molecules28041527.

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The world scenario regarding consumption and demand for products based on fossil fuels has demonstrated the imperative need to develop new technologies capable of using renewable resources. In this context, the use of biomass to obtain chemical intermediates and fuels has emerged as an important area of research in recent years, since it is a renewable source of carbon in great abundance. It has the benefit of not contributing to the additional emission of greenhouse gases since the CO2 released during the energy conversion process is consumed by it through photosynthesis. In the presented review, the authors provide an update of the literature in the field of biomass transformation with the use of niobium-containing catalysts, emphasizing the versatility of niobium compounds for the conversion of different types of biomass.

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14

Liu, Xinxin, Qixuan Lin, Yuhuan Yan, Feng Peng, Runcang Sun, and Junli Ren. "Hemicellulose from Plant Biomass in Medical and Pharmaceutical Application: A Critical Review." Current Medicinal Chemistry 26, no. 14 (July 24, 2019): 2430–55. http://dx.doi.org/10.2174/0929867324666170705113657.

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Background:Due to the non-toxicity, abundance and biodegradability, recently more and more attention has been focused on the exploration of hemicellulose as the potential substrate for the production of liquid fuels and other value-added chemicals and materials in different fields. This review aims to summarize the current knowledge on the promising application of nature hemicellulose and its derivative products including its degradation products, its new derivatives and hemicellulosebased medical biodegradable materials in the medical and pharmaceutical field, especially for inmmune regulation, bacteria inhibition, drug release, anti-caries, scaffold materials and anti-tumor.Methods:We searched the related papers about the medical and pharmaceutical application of hemicellulose and its derivative products, and summarized their preparation methods, properties and use effects.Results:Two hundred and twenty-seven papers were included in this review. Forty-seven papers introduced the extraction and application in immune regulation of nature hemicellulose, such as xylan, mannan, xyloglucan (XG) and β-glucan. Seventy-seven papers mentioned the preparation and application of degradation products of hemicellulose for adjusting intestinal function, maintaining blood glucose levels, enhancing the immunity and alleviating human fatigue fields such as xylooligosaccharides, xylitol, xylose, arabinose, etc. The preparation of hemicellulose derivatives were described in thirty-two papers such as hemicellulose esters, hemicellulose ethers and their effects on anticoagulants, adsorption of creatinine, the addition of immune cells and the inhibition of harmful bacteria. Finally, the preparations of hemicellulose-based materials such as hydrogels and membrane for the field of drug release, cell immobilization, cancer therapy and wound dressings were presented using fifty-five papers.Conclusion:The structure of hemicellulose-based products has the significant impact on properties and the use effect for the immunity, and treating various diseases of human. However, some efforts should be made to explore and improve the properties of hemicellulose-based products and design the new materials to broaden hemicellulose applications.

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15

Roylance, John J., and Kyoung-Shin Choi. "Electrochemical reductive amination of furfural-based biomass intermediates." Green Chemistry 18, no. 20 (2016): 5412–17. http://dx.doi.org/10.1039/c6gc01541g.

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16

Ventura, Sónia P. M., Paulo de Morais, Jaime A. S. Coelho, Tânia Sintra, João A. P. Coutinho, and Carlos A. M. Afonso. "Evaluating the toxicity of biomass derived platform chemicals." Green Chemistry 18, no. 17 (2016): 4733–42. http://dx.doi.org/10.1039/c6gc01211f.

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17

Jardine, Anwar, and Shakeela Sayed. "Valorisation of chitinous biomass for antimicrobial applications." Pure and Applied Chemistry 90, no. 2 (February 23, 2018): 293–304. http://dx.doi.org/10.1515/pac-2017-0707.

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Abstract The chitin and chitosan market worldwide has shown tremendous growth, propelled by the expansion in the application domain. The market volume is projected to be more than 155 thousand metric tons by the year 2022. The global market for chitin and chitosan derivatives is expected to reach $4.2 billion by 2021 up from $2.0 billion in 2016 at a compound annual growth rate (CAGR) of 15.4%, from 2016 to 2021. Among chitin derivatives, chitosan is projected to offer the highest growth potential. The demand for a reliable source of high quality chitosan is rapidly increasing as new value added products enter the market. At the same time the growth of value added chitosan based products are limited by the availability of a sustainable supply chain. Antimicrobial properties are of special interest in the packaging, cosmetic, food and biomedical sector. Most of the latter applications warrants high-volume and low cost materials. However, the process chemistry for bulk chitosan manufacturing is currently not very environmentally friendly. Green technologies for chitosan modification have increased in recent years and now face the challenge of economic viability. In this review the status of antimicrobial chitosan derivatives will be reported with a critical review of the chemical technologies that would mitigate the commercialisation of these biopolymers in the antimicrobial biopolymer market sector. The amount of publications per annum has increased exponentially and the lack of global standardised antimicrobial test protocols make it rather challenging to properly evaluate the relative efficacy of these polymers.

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18

Liu, Xiaofang, Dayong Yu, Hangyu Luo, Can Li, and Hu Li. "Efficient Reaction Systems for Lignocellulosic Biomass Conversion to Furan Derivatives: A Minireview." Polymers 14, no. 17 (September 4, 2022): 3671. http://dx.doi.org/10.3390/polym14173671.

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Lignocellulosic biomass as abundant, renewable, and sustainable carbon feedstock is an alternative to relieve the dependence on fossil fuels and satisfy the demands of chemicals and materials. Conversions of lignocellulosic biomass to high-value-added chemicals have drawn much attention recently due to the high availability of sustainable ways. This minireview surveys the recent trends in lignocellulosic biomass conversion into furan derivatives based on the following systems: (1) ionic liquids, (2) deep eutectic solvents, and (3) biphasic systems. Moreover, the current challenges and future perspectives in the development of efficient routes for lignocellulosic biomass conversion are provided.

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19

Xu, Benjing, Ziting Du, Jinhang Dai, Ronghe Yang, Delong Yang, Xingxing Gu, Ning Li, and Fukun Li. "Progress in Catalytic Conversion of Renewable Chitin Biomass to Furan-Derived Platform Compounds." Catalysts 12, no. 6 (June 14, 2022): 653. http://dx.doi.org/10.3390/catal12060653.

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Chitin is one of the most abundant biopolymers on Earth but under-utilized. The effective conversion of chitin biomass to useful chemicals is a promising strategy to make full use of chitin. Among chitin-derived compounds, some furan derivatives, typically 5-hydroxymethylfurfural and 3-acetamido-5-acetylfuran, have shown great potential as platform compounds in future industries. In this review, different catalytic systems for the synthesis of nitrogen-free 5-hydroxymethylfurfural and nitrogen-containing 3-acetamido-5-acetylfuran from chitin or its derivatives are summarized comparatively. Some efficient technologies for enhancing chitin biomass conversion have been introduced. Last but not least, future challenges are discussed to enable the production of valuable compounds from chitin biomass via greener processes.

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20

Skała, Ewa, Agnieszka Kicel, Monika A. Olszewska, Anna K. Kiss, and Halina Wysokińska. "Establishment of Hairy Root Cultures ofRhaponticum carthamoides(Willd.) Iljin for the Production of Biomass and Caffeic Acid Derivatives." BioMed Research International 2015 (2015): 1–11. http://dx.doi.org/10.1155/2015/181098.

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The aim of the study was to obtain transformed roots ofRhaponticum carthamoidesand evaluate their phytochemical profile. Hairy roots were induced from leaf explants by the transformation ofAgrobacterium rhizogenesstrains A4 and ATCC 15834. The best response (43%) was achieved by infection with A4 strain. The effects of different liquid media (WPM, B5, SH) with full and half-strength concentrations of macro- and micronutrients on biomass accumulation of the best grown hairy root line (RC3) at two different lighting conditions (light or dark) were investigated. The highest biomass (93 g L−1of the fresh weight after 35 days) was obtained in WPM medium under periodic light. UPLC-PDA-ESI-MS3and HPLC-PDA analyses of 80% aqueous methanol extracts from the obtained hairy roots revealed the presence of eleven caffeoylquinic acids and their derivatives and five flavonoid glycosides. The production of caffeoylquinic acids and their derivatives was elevated in hairy roots grown in the light. Only light-grown hairy roots demonstrated the capability for the biosynthesis of such flavonoid glycosides as quercetagetin, quercetin, luteolin, and patuletin hexosides. Chlorogenic acid, 3,5-di-O-caffeoylquinic acid and a tentatively identified tricaffeoylquinic acid derivative were detected as the major compounds present in the transformed roots.

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21

Yun, Yang Sik, Claudia E. Berdugo-Díaz, and David W. Flaherty. "Advances in Understanding the Selective Hydrogenolysis of Biomass Derivatives." ACS Catalysis 11, no. 17 (August 23, 2021): 11193–232. http://dx.doi.org/10.1021/acscatal.1c02866.

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22

TOGO, Azusa, Yukiko ENOMOTO, Akio TAKEMURA, and Tadahisa IWATA. "Synthesis of Biomass-based Adhesives Derived fromDextran Ester Derivatives." Journal of The Adhesion Society of Japan 55, no. 9 (September 1, 2019): 315–22. http://dx.doi.org/10.11618/adhesion.55.315.

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23

Andérez-Fernández, M., E. Pérez, A. Martín, and M. D. Bermejo. "Hydrothermal CO 2 reduction using biomass derivatives as reductants." Journal of Supercritical Fluids 133 (March 2018): 658–64. http://dx.doi.org/10.1016/j.supflu.2017.10.010.

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24

Silva, Ana L. R., Ana C. M. O. Lima, and Maria D. M. C. Ribeiro da Silva. "Energetic characterization of indanone derivatives involved in biomass degradation." Journal of Thermal Analysis and Calorimetry 134, no. 2 (July 16, 2018): 1267–76. http://dx.doi.org/10.1007/s10973-018-7533-z.

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25

Shimura, Katsuya, and Hisao Yoshida. "Heterogeneous photocatalytic hydrogen production from water and biomass derivatives." Energy & Environmental Science 4, no. 7 (2011): 2467. http://dx.doi.org/10.1039/c1ee01120k.

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26

Gartz, Jochen. "Extraction and analysis of indole derivatives from fungal biomass." Journal of Basic Microbiology 34, no. 1 (1994): 17–22. http://dx.doi.org/10.1002/jobm.3620340104.

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27

Lin, Zhexi, Rui Chen, Zhenping Qu, and Jingguang G. Chen. "Hydrodeoxygenation of biomass-derived oxygenates over metal carbides: from model surfaces to powder catalysts." Green Chemistry 20, no. 12 (2018): 2679–96. http://dx.doi.org/10.1039/c8gc00239h.

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28

Liguori, Francesca, Carmen Moreno-Marrodan, and Pierluigi Barbaro. "Biomass-derived chemical substitutes for bisphenol A: recent advancements in catalytic synthesis." Chemical Society Reviews 49, no. 17 (2020): 6329–63. http://dx.doi.org/10.1039/d0cs00179a.

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29

Rojas-Buzo, Sergio, Pilar García-García, and Avelino Corma. "Hf-based metal–organic frameworks as acid–base catalysts for the transformation of biomass-derived furanic compounds into chemicals." Green Chemistry 20, no. 13 (2018): 3081–91. http://dx.doi.org/10.1039/c8gc00806j.

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30

Li, Wenjing, Pengxiang Ge, Mindong Chen, Jiajie Tang, Maoyu Cao, Yan Cui, Kun Hu, and Dongyang Nie. "Tracers from Biomass Burning Emissions and Identification of Biomass Burning." Atmosphere 12, no. 11 (October 26, 2021): 1401. http://dx.doi.org/10.3390/atmos12111401.

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Анотація:

The major organic compositions from biomass burning emissions are monosaccharide derivatives from the breakdown of cellulose, generally accompanied by small amounts of straight-chain, aliphatic, oxygenated compounds, and terpenoids from vegetation waxes, resins/gums, and other biopolymers. Levoglucosan from cellulose can be utilized as a specific or general indicator for biomass combustion emissions in aerosol samples. There are other important compounds, such as dehydroabietic acid, syringaldehyde, syringic acid, vanillic acid, vanillin, homovanillic acid, 4-hydroxybenzoic acid, and p-coumaric acid, which are additional key indicators of biomass burning. In this review, we will address these tracers from different types of biomass burning and the methods used to identify the sources in ambient aerosols. First, the methods of inferring biomass burning types by the ratio method are summarized, including levoglucosan/mannose, syringic acid/vanillic acid, levolgucosan/K+, vanillic acid/4-hydroxybenzoic acid, levoglucosan/OC, and levoglucosan/EC to infer the sources of biomass burning, such as crop residual burning, wheat burning, leaf burning, peatland fire, and forest fire in Asia. Second, we present the source tracer ratio methods that determine the biomass combustion types and their contributions. Finally, we introduce the PCA (Principal component analysis) and PMF (Positive matrix factor) methods to identify the type of biomass burning and its contributions according to emission factors of different species in various plants such as softwood, hardwood, and grass.

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31

Aellig, Christof, Florian Jenny, David Scholz, Patrick Wolf, Isabella Giovinazzo, Fabian Kollhoff, and Ive Hermans. "Combined 1,4-butanediol lactonization and transfer hydrogenation/hydrogenolysis of furfural-derivatives under continuous flow conditions." Catal. Sci. Technol. 4, no. 8 (2014): 2326–31. http://dx.doi.org/10.1039/c4cy00213j.

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32

Wang, Jianjian, Xiaohui Liu, Bicheng Hu, Guanzhong Lu, and Yanqin Wang. "Efficient catalytic conversion of lignocellulosic biomass into renewable liquid biofuels via furan derivatives." RSC Adv. 4, no. 59 (2014): 31101–7. http://dx.doi.org/10.1039/c4ra04900d.

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33

Dai, Xingchao, Xinjiang Cui, Hangkong Yuan, Youquan Deng, and Feng Shi. "Cooperative transformation of nitroarenes and biomass-based alcohols catalyzed by CuNiAlOx." RSC Advances 5, no. 11 (2015): 7970–75. http://dx.doi.org/10.1039/c4ra16081a.

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34

Muzzio, Michelle, Chao Yu, Honghong Lin, Typher Yom, Dilek A. Boga, Zheng Xi, Na Li, et al. "Reductive amination of ethyl levulinate to pyrrolidones over AuPd nanoparticles at ambient hydrogen pressure." Green Chemistry 21, no. 8 (2019): 1895–99. http://dx.doi.org/10.1039/c9gc00396g.

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35

Pang, Jie, Wenfeng Zhang, Jinliang Zhang, Gaoping Cao, Minfang Han, and Yusheng Yang. "Facile and sustainable synthesis of sodium lignosulfonate derived hierarchical porous carbons for supercapacitors with high volumetric energy densities." Green Chemistry 19, no. 16 (2017): 3916–26. http://dx.doi.org/10.1039/c7gc01434a.

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36

Nardi, M., P. Costanzo, A. De Nino, M. L. Di Gioia, F. Olivito, G. Sindona, and A. Procopio. "Water excellent solvent for the synthesis of bifunctionalized cyclopentenones from furfural." Green Chemistry 19, no. 22 (2017): 5403–11. http://dx.doi.org/10.1039/c7gc02303k.

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37

Cong, Hanyu, Haibo Yuan, Zekun Tao, Hanlin Bao, Zheming Zhang, Yi Jiang, Di Huang, Hongling Liu, and Tengfei Wang. "Recent Advances in Catalytic Conversion of Biomass to 2,5-Furandicarboxylic Acid." Catalysts 11, no. 9 (September 16, 2021): 1113. http://dx.doi.org/10.3390/catal11091113.

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Анотація:

Converting biomass into high value-added compounds has attracted great attention for solving fossil fuel consumption and global warming. 5-Hydroxymethylfurfural (HMF) has been considered as a versatile biomass-derived building block that can be used to synthesize a variety of sustainable fuels and chemicals. Among these derivatives, 2,5-furandicarboxylic acid (FDCA) is a desirable alternative to petroleum-derived terephthalic acid for the synthesis of biodegradable polyesters. Herein, to fully understand the current development of the catalytic conversion of biomass to FDCA, a comprehensive review of the catalytic conversion of cellulose biomass to HMF and the oxidation of HMF to FDCA is presented. Moreover, future research directions and general trends of using biomass for FDCA production are also proposed.

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38

Wang, Keping, Mei Wu, Yixuan Liu, Ying Yang, and Hu Li. "Magnetic solid sulfonic acid-enabled direct catalytic production of biomass-derived N-substituted pyrroles." New Journal of Chemistry 46, no. 11 (2022): 5312–20. http://dx.doi.org/10.1039/d1nj05828b.

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39

Galkin, Konstantin, Fedor Kucherov, Oleg Markov, Ksenia Egorova, Alexandra Posvyatenko, and Valentine Ananikov. "Facile Chemical Access to Biologically Active Norcantharidin Derivatives from Biomass." Molecules 22, no. 12 (December 12, 2017): 2210. http://dx.doi.org/10.3390/molecules22122210.

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40

Baudouin, David, Hang Xiang, and Frédéric Vogel. "On the selective desulphurization of biomass derivatives in supercritical water." Biomass and Bioenergy 164 (September 2022): 106529. http://dx.doi.org/10.1016/j.biombioe.2022.106529.

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41

Zhao, Wenfeng, Sebastian Meier, Song Yang, and Anders Riisager. "Ammonia borane enabled upgrading of biomass derivatives at room temperature." Green Chemistry 22, no. 18 (2020): 5972–77. http://dx.doi.org/10.1039/d0gc02372h.

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An efficient catalyst-free system composed of ammonia borane in water or alcohol was developed to selectively convert biomass-derived feedstock into four value-added products under extremely mild conditions.

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42

Lu, Xihong, Shilei Xie, Hao Yang, Yexiang Tong, and Hongbing Ji. "ChemInform Abstract: Photoelectrochemical Hydrogen Production from Biomass Derivatives and Water." ChemInform 46, no. 3 (December 22, 2014): no. http://dx.doi.org/10.1002/chin.201503289.

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43

Xu, Wenjie, Qineng Xia, Yu Zhang, Yong Guo, Yanqin Wang, and Guanzhong Lu. "Effective Production of Octane from Biomass Derivatives under Mild Conditions." ChemSusChem 4, no. 12 (November 2, 2011): 1758–61. http://dx.doi.org/10.1002/cssc.201100361.

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44

Karmee, Sanjib Kumar. "Lipase catalyzed synthesis of ester-based surfactants from biomass derivatives." Biofuels, Bioproducts and Biorefining 2, no. 2 (2008): 144–54. http://dx.doi.org/10.1002/bbb.60.

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45

Abdel-Lateff, Ahmed. "Bioproduction of Sorbicillin Derivatives from Marine Trichoderma sp." Zeitschrift für Naturforschung C 63, no. 9-10 (October 1, 2008): 631–35. http://dx.doi.org/10.1515/znc-2008-9-1002.

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The variability of sorbicillin derivatives production by marine Trichoderma sp., isolated from the sponge Agelas dispar J., was studied using six different culture media to find a good medium for biomass production, particularly of trichodimerol, bislongiquinolide and bisvertinol. A simple and rapid convenient method for identification, quantification and validation of the sorbicillin derivatives in ethyl acetate extracts has been applied by using RPHPLC coupled with diode array detection.

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46

Lin, Tang-Huang, Si-Chee Tsay, Wei-Hung Lien, Neng-Huei Lin, and Ta-Chih Hsiao. "Spectral Derivatives of Optical Depth for Partitioning Aerosol Type and Loading." Remote Sensing 13, no. 8 (April 16, 2021): 1544. http://dx.doi.org/10.3390/rs13081544.

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Quantifying aerosol compositions (e.g., type, loading) from remotely sensed measurements by spaceborne, suborbital and ground-based platforms is a challenging task. In this study, the first and second-order spectral derivatives of aerosol optical depth (AOD) with respect to wavelength are explored to determine the partitions of the major components of aerosols based on the spectral dependence of their particle optical size and complex refractive index. With theoretical simulations from the Second Simulation of a Satellite Signal in the Solar Spectrum (6S) model, AOD spectral derivatives are characterized for collective models of aerosol types, such as mineral dust (DS) particles, biomass-burning (BB) aerosols and anthropogenic pollutants (AP), as well as stretching out to the mixtures among them. Based on the intrinsic values from normalized spectral derivatives, referenced as the Normalized Derivative Aerosol Index (NDAI), a unique pattern is clearly exhibited for bounding the major aerosol components; in turn, fractions of the total AOD (fAOD) for major aerosol components can be extracted. The subtlety of this NDAI method is examined by using measurements of typical aerosol cases identified carefully by the ground-based Aerosol Robotic Network (AERONET) sun–sky spectroradiometer. The results may be highly practicable for quantifying fAOD among mixed-type aerosols by means of the normalized AOD spectral derivatives.

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47

Kozlov, Kirill S., Leonid V. Romashov, and Valentine P. Ananikov. "A tunable precious metal-free system for selective oxidative esterification of biobased 5-(hydroxymethyl)furfural." Green Chemistry 21, no. 12 (2019): 3464–68. http://dx.doi.org/10.1039/c9gc00840c.

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48

Ventura, Maria, Marcelo E. Domine, and Marvin Chávez-Sifontes. "Catalytic Processes For Lignin Valorization into Fuels and Chemicals (Aromatics)." Current Catalysis 8, no. 1 (June 21, 2019): 20–40. http://dx.doi.org/10.2174/2211544708666190124112830.

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Valorization of lignocellulosic biomass becomes a sustainable alternative against the constant depletion and environmental problems of fossil sources necessary for the production of chemicals and fuels. In this context, a wide range of renewable raw materials can be obtained from lignocellulosic biomass in both polymeric (i.e. cellulose, starch, lignin) and monomeric (i.e. sugars, polyols, phenols) forms. Lignin and its derivatives are interesting platform chemicals for industry, although mainly due to its refractory characteristics its use has been less considered compared to other biomass fractions. To take advantage of the potentialities of lignin, it is necessary to isolate it from the cellulose/ hemicellulosic fraction, and then apply depolymerization processes; the overcoming of technical limitations being a current issue of growing interest for many research groups. In this review, significant data related to the structural characteristics of different types of commercial lignins are presented, also including extraction and isolation processes from biomass, and industrial feedstocks obtained as residues from paper industry under different treatments. The review mainly focuses on the different depolymerization processes (hydrolysis, hydrogenolysis, hydrodeoxygenation, pyrolysis) up to now developed and investigated analyzing the different hydrocarbons and aromatic derivatives obtained in each case, as well as the interesting reactions some of them may undergo. Special emphasis is done on the development of new catalysts and catalytic processes for the efficient production of fuels and chemicals from lignin. The possibilities of applications for lignin and its derivatives in new industrial processes and their integration into the biorefinery of the future are also assessed.

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49

Chen, Hongyan, Jiajing Zhou, Fuyuan Guo, Yaqian Wang, Yue Chen, Yan Liang, Yunlong Xu, and Huang Zhang. "High-performance Zn2SnO4 anodes enabled by MOF-derived MnO decoration and carbon confinement for lithium-ion batteries." CrystEngComm 23, no. 13 (2021): 2590–98. http://dx.doi.org/10.1039/d1ce00084e.

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50

Liu, Jinrong, Lei Xie, Zhe Wang, Shanjun Mao, Yutong Gong, and Yong Wang. "Biomass-derived ordered mesoporous carbon nano-ellipsoid encapsulated metal nanoparticles inside: ideal nanoreactors for shape-selective catalysis." Chemical Communications 56, no. 2 (2020): 229–32. http://dx.doi.org/10.1039/c9cc08066j.

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Ordered mesoporous nano-ellipsoids were synthesized by hydrothermal carbonization of biomass derivatives. Their multifunctional features have been demonstrated and the ability of encapsulating metal nanoparticles (NPs) is presented.

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