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1
Šuica, Sanja, Vesnica Garašić, and Alan B. Woodland. "Petrography and geochemistry of granitoids and related rocks from the pre-Neogene basement of the Slavonia-Srijem Depression (Croatia)." Geologia Croatica 75, no. 1 (February 28, 2022): 129–44. http://dx.doi.org/10.4154/gc.2022.09.
Повний текст джерелаАнотація:
The pre-Neogene basement of the Slavonia-Srijem Depression (eastern Croatia) is composed of various types of igneous, metamorphic and sedimentary rocks. Here we present the petrography and geochemistry of a heterogenous group represented by two types of alkali granite, granite, syenite, rhyolite and orthogneiss. The alkali granite type 1 has an A-type geochemical affinity: a ferroan character, high alkali content, high concentration of rare earth elements (REE3+), Rb, Zr, Nb and Y, and low CaO, MgO, P2O5, Ba, Sr and Eu contents. The syenite has similar characteristics, but displays enrichment in Ba, K, Eu and Zr, which could be a consequence of feldspar and zircon accumulation. The alkali granite type 2 is an A-type granite but differs from the alkali granite type 1 in having lower K2O and Rb, accompanied by higher Na2O and Sr concentrations, possibly resulting from alteration or a different parental magma/evolutionary process. The granite and rhyolite are distinguished from both types of alkali granite by their magnesian character, lower Zr, Nb and Y concentrations, less pronounced Eu negative anomaly, as well as higher Ba, Sr and LREE/HREE. The orthogneiss displays differences in major element chemistry compared to the alkali granite type 1, but has similar trace element and REE patterns. The alkali granites are characterized by Y/Nb<1.2, indicating an ocean island basalt-like source, while the granite originated from melting of a crustal, probably metasedimentary source. The A-type granites could belong to the Late Cretaceous A-type magmatism of the Sava Zone, while the granite is significantly different from the Sava Zone A-type granites as well as the other rocks investigated in this study.
2
Usman, Ediar. "THE GEOCHEMICAL CHARACTERISTIC OF MAJOR ELEMENT OF GRANITOID OF NATUNA, SINGKEP, BANGKA AND SIBOLGA." BULLETIN OF THE MARINE GEOLOGY 30, no. 1 (February 15, 2016): 45. http://dx.doi.org/10.32693/bomg.30.1.2015.74.
Повний текст джерелаАнотація:
A study of geochemical characteristic of major elelemnt of granitoid in Western Indonesia Region was carried out at Natuna, Bangka, Singkep and Sibolga. The SiO2 contents of the granites are 71.16 to 73.02 wt%, 71.77 to 75.56wt% and 71.16 to 73.02wt% at Natuna, Bangka, and Singkep respectively, which are classified as acid magma. While in Sibolga the SiO2 content from 60.27 to 71.44wt%, which is classified as intermediate to acid magma. Based on Harker Diagram, the granites from Natuna, Bangka and Singkep as a co-genetic. In other hand the Sibolga Granite show as a scatter pattern. Granites of Natuna, Bangka and Singkep have the alkaline-total (Na2O + K2O) between 6.03 to 8.51 wt% which are classified as granite and alkali granite regime. K2O content ranges from 3.49 to 5.34 wt% and can be classified as calc-alkaline type. The content of alkaline-total of Sibolga granite between 8.12 to 11.81 wt% and classified as a regime of syenite and granite. The range of K2O is about 5.36 to 6.94wt%, and assumed derived from high-K magma to ultra-potassic types. Granites of Natuna, Bangka and Singkep derived from the plutonic rock types and calc-alkaline magma, while Sibolga granite magma derived from K-high to ultra-potassic as a granite of islands arc. Based on the chemical composition of granite in Western Indonesian Region can be divided into two groups, namely Sibolga granite group is representing the Sumatera Island influenced by tectonic arc system of Sumatera Island. Granites of Bangka and Singkep are representing a granite belt in Western Indonesian Region waters which is influenced by tectonic of back arc.Keywords: magma, geochemical characteristic, major element and Western Indonesian Region Kajian karakteristik geokimia dari unsur utama granitoid di Kawasan Barat Indonesia telah dilakukan di daerah Natuna, Bangka, Singkep dan Sibolga. Kandungan SiO2 granit Natuna antara 71,16 - 73,02%, Bangka antara 71,77 - 75,56%, Singkep antara 72,68 - 76,81% termasuk dalam magma asam. Granit Sibolga memiliki kandungan SiO2 antara 60,27 - 71,44% termasuk dalam magma menengah - asam. Berdasarkan Diagram Harker, granit Natuna, Bangka dan Singkep mempunyai asal kejadian yang sama (ko-genetik), sedangkan granit Sibolga membentuk pola pencar. Granit Natuna, Bangka dan Singkep mengandung total alkalin (K2O+Na2O) antara 6,03 - 8,51% termasuk dalam jenis rejim granit dan alkali granit. Berdasarkan kandungan K2O antara 3,49 - 5,34 %berat, bersifat kalk-alkali. Granit Sibolga mengandung total alkali antara 8,12 - 11,81% termasuk dalam rejim syenit dan granit, dan berdasarkan kandungan K2O antara 5,36 - 6,94% berasal dari jenis magma K-tinggi sampai ultra-potassik. Granit Natuna, Bangka dan Singkep berasal dari jenis batuan beku dalam dan magma kalk-alkalin yang berhubungan dengan penunjaman, sedangkan granit Sibolga berasal dari jenis magma K-tinggi - ultra-potassik sebagai granit busur kepulauan. Berdasarkan komposisi unsur kimia utama, granit di Kawasan Barat Indonesia dapat dibagi dalam dua, yaitu granit Sibolga yang mewakili P. Sumatera, dipengaruhi oleh sistem tektonik busur P. Sumatera. Granit Bangka dan Singkep dapat mewakili suatu jalur granit di perairan Kawasan Barat Indonesia yang dipengaruhi oleh tektonik busur belakang. Kata kunci: jenis magma, karakteristik geokimia, unsur utama, dan Kawasan Barat Indonesia
3
Lee, Byung Choon, Weon-Seo Kee, Uk Hwan Byun, and Sung Won Kim. "Statherian (ca. 1714–1680 Ma) Extension-Related Magmatism and Deformation in the Southwestern Korean Peninsula and Its Geological Significance: Constraints from the Petrological, Structural, Geochemical and Geochronological Studies of Newly Identified Granitoids." Minerals 11, no. 6 (May 24, 2021): 557. http://dx.doi.org/10.3390/min11060557.
Повний текст джерелаАнотація:
In this study, petrological, structural, geochemical, and geochronological analyses of the Statherian alkali feldspar granite and porphyritic alkali feldspar granite in the southwestern part of the Korean Peninsula were conducted to examine petrogenesis of the granitoids and their tectonic setting. Zircon U-Pb dating revealed that the two granites formed around 1.71 Ga and 1.70–1.68 Ga, respectively. The results of the geochemical analyses showed that both of the granites have a high content of K2O, Nb, Ta, and Y, as well as high FeOt/MgO and Ga/Al ratios. Both granites have alkali-calcic characteristics with a ferroan composition, indicating an A-type affinity. Zircon Lu-Hf isotopic compositions yielded negative εHf(t) values (−3.5 to −10.6), indicating a derivation from ancient crustal materials. Both granite types underwent ductile deformation and exhibited a dextral sense of shear with a minor extension component. Based on field relationships and zircon U-Pb dating, it was considered that the deformation event postdated the emplacement of the alkali feldspar granite and terminated soon after the emplacement of the porphyritic alkali feldspar granite in an extensional setting. These data indicated that there were extension-related magmatic activities accompanying ductile deformation in the southwestern part of the Korean Peninsula during 1.71–1.68 Ga. The Statherian extension-related events are well correlated with those in the midwestern part of the Korean and eastern parts of the North China Craton.
4
Semblano, Flávio Robson Dias, Moacir José Buenano Macambira, and Marcelo Lacerda Vasquez. "Petrography, geochemistry and Sm-Nd isotopes of the granites from eastern of the Tapajós Domain, Pará state." Brazilian Journal of Geology 46, no. 4 (December 2016): 509–29. http://dx.doi.org/10.1590/2317-4889201620160059.
Повний текст джерелаАнотація:
ABSTRACT: The Tapajós Domain, located in the southern portion of the Amazonian Craton, is a tectonic domain of the Tapajós-Parima Province, a Paleoproterozoic orogenic belt adjacent to a reworked Archean crust, the Central Amazonian Province. This domain has been interpreted as the product of an assemblage of successive magmatic arcs followed by post-orogenic A-type magmatism formed ca. 1880 Ma-old granites of the Maloquinha Intrusive Suite. The study presented here was carried out in four granitic bodies of this suite (Igarapé Tabuleiro, Dalpaiz, Mamoal and Serra Alta) from the eastern part of the Tapajós Domain, as well as an I-type granite (Igarapé Salustiano) related to the Parauari Intrusive Suite. The A-type granites are syenogranites and monzogranites, and alkali feldspar granites and quartz syenites occur subordinately. These rocks are ferroan, alkalic-calcic to alkalic and dominantly peraluminous, with negative anomalies of Ba, Sr, P and Ti and high rare earth elements (REE) contents with pronounced negative Eu anomaly. This set of features is typical of A-type granites. The Igarapé Salustiano granite encompasses monzogranites and quartz monzonites, which are magnesian, calcic to calc-alkalic, high-K and mainly metaluminous, with high Ba and Sr contents and depleted pattern in high field strength elements (HFSE) and heavy rare earth elements (HREE), characteristic of I-type granites. The source of magma of these A-type granites is similar to post-collisional granites, while the I-type granite keeps syn-collisional signature. Most of the studied granites have εNd (-3.85 to -0.76) and Nd TDM model ages (2.22 to 2.46 Ga) compatible with the Paleoproterozoic crust of the Tapajós Domain. We conclude that the Archean crust source (εNd of -5.01 and Nd TDM of 2.6 Ga) was local for these A-type granites.
5
Jia, Ru-Ya, Guo-Chang Wang, Lin Geng, Zhen-Shan Pang, Hong-Xiang Jia, Zhi-Hui Zhang, Hui Chen, and Zheng Liu. "Petrogenesis of the Early Cretaceous Tiantangshan A-Type Granite, Cathaysia Block, SE China: Implication for the Tin Mineralization." Minerals 9, no. 5 (April 29, 2019): 257. http://dx.doi.org/10.3390/min9050257.
Повний текст джерелаАнотація:
The newly discovered Tiantangshan tin polymetallic deposit is located in the southeast Nanling Range, Cathaysia block, Southeast China. The tin orebodies are mainly hosted in the greisen and the fractured alteration zones of the tufflava and trachydacite. However, the genetic relationship between the hidden alkali-feldspar granite and volcanic rocks and the tin mineralization remains poorly understood. This paper presents SHRIMP zircon U–Pb dating, whole-rock major and trace element analyses, as well as Nd isotopic data of the trachydacite and alkali-feldspar granite. The SHRIMP zircon U–Pb dating of the alkali-feldspar granite and trachydacite yields weight mean 206Pb/238U ages of 138.4 ± 1.2, and 136.2 ± 1.2 Ma, respectively. These granitic rocks have high levels of SiO2 (64.2–75.4 wt%, mostly > 68 wt%), alkalis (K2O + Na2O > 8.3 wt%), REE (except for Eu), HFSE (Zr + Nb + Ce + Y > 350 ppm) and Ga/Al ratios (10,000 × Ga/Al > 2.6), suggesting that they belong to the A-type granite. According to the high Y/Nb and Yb/Ta ratios, they can be further classified into A1 subtype. Their εNd (T) range from −3.8 to −6.5. They were likely generated by the assimilation-fractional crystallization (AFC) of the coeval oceanic island basalts -like basaltic magma. This study suggests that the A1 type granite is also a potential candidate for the exploration of tin deposits.
6
Abdel Gawad, Ahmed E., Hassan Eliwa, Khaled G. Ali, Khalid Alsafi, Mamoru Murata, Masoud S. Salah, and Mohamed Y. Hanfi. "Cancer Risk Assessment and Geochemical Features of Granitoids at Nikeiba, Southeastern Desert, Egypt." Minerals 12, no. 5 (May 13, 2022): 621. http://dx.doi.org/10.3390/min12050621.
Повний текст джерелаАнотація:
Different rock types (syenogranite, alkali feldspar granite and quartz syenite intruded by microgranite dikes and quartz veins) were investigated in the Nikeiba region in Egypt. The main components of the studied intrusive rocks, comprised of granites and quartz syenite, are plagioclase, amphibole, biotite, quartz and K-feldspar in different proportions. Ground gamma ray measurements show that syenogranite, quartz syenite and microgranite dikes have the highest radioactivity (K, eU, eTh and their ratios) in comparison with alkali feldspar granite. Geochemically, syenogranite, alkali feldspar granite and quartz syenite are enriched with large-ion lithophile elements (LILE; Ba, Rb, Sr) and high field-strength elements (HFSE; Y, Zr and Nb), but have decreased Ce, reflecting their alkaline affinity. These rocks reveal calc–alkaline affinity, metaluminous characteristics, A-type granites and post-collision geochemical signatures, which indicates emplacement in within-plate environments under an extensional regime. U and Th are increased in syenogranite and quartz syenite, whereas alkali feldspar granite shows a marked decrease in U and Th. The highest average values of AU (131 ± 49 Bq·kg−1), ATh (164 ± 35) and AK (1402 ± 239) in the syenogranite samples are higher than the recommended worldwide average. The radioactivity levels found in the samples are the result of the alteration of radioactive carrying minerals found inside granite faults. The public’s radioactive risk from the radionuclides found in the investigated granitoid samples is estimated by calculating radiological risks. The excess lifetime cancer (ELCR) values exceed the permissible limit. Therefore, the granitoids are unsuitable for use as infrastructure materials.
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ZHAO, XILIN, YANG JIANG, GUANGFU XING, ZHIHONG CHEN, KAI LIU, MINGGANG YU, and SHENGYAO YU. "A geochemical and geochronological study of the Early Cretaceous, extension-related Honggong ferroan (A-type) granite in southwestern Zhejiang Province, southeast China." Geological Magazine 155, no. 3 (September 27, 2016): 549–67. http://dx.doi.org/10.1017/s0016756816000790.
Повний текст джерелаАнотація:
AbstractThe Honggong pluton is the largest ferroan alkalic (A-type) granite intrusion emplaced along the Jiangshan–Shaoxing fault zone in southwestern Zhejiang Province, and has important implications for understanding the Late Mesozoic tectonic evolution of SE China. U–Pb ages of 138.7 ± 0.8, 134.2 ± 1.1, 128.5 ± 1.5 and 126.1 ± 0.9 Ma were obtained from zircon by laser ablation–inductively coupled plasma–mass spectrometry, indicating that the Honggong pluton formed in the Early Cretaceous. The Honggong pluton has a clear ferroan alkalic (A-type) granite geochemical signature with, for example, high total alkali contents and FeOt/(FeOt+ MgO) values. The Sr–Nd–Hf isotopic compositions suggest that there was juvenile material in the magma source. Geochemical evidence indicates that the pluton was derived through extensive fractionation of melts that contained both asthenospheric mantle and Mesoproterozoic crustal components. These rare granites in southern China were emplaced during five episodes at 235–225, 190, 165–155, 100–90 and 140–120 Ma. The age of the Honggong pluton suggests that localized extension in southwestern Zhejiang Province began as early as ~138 Ma and continued to 126 Ma. This Early Cretaceous extensional event was triggered by localized rollback of the subducting Pacific Plate.
8
Broska, Igor, and Michal Kubiš. "Accessory minerals and evolution of tin-bearing S-type granites in the western segment of the Gemeric Unit (Western Carpathians)." Geologica Carpathica 69, no. 5 (October 1, 2018): 483–97. http://dx.doi.org/10.1515/geoca-2018-0028.
Повний текст джерелаАнотація:
Abstract The S-type accessory mineral assemblage of zircon, monazite-(Ce), fluorapatite and tourmaline in the cupolas of Permian granites of the Gemeric Unit underwent compositional changes and increased variability and volume due to intensive volatile flux. The extended S-type accessory mineral assemblage in the apical parts of the granite resulted in the formation of rare-metal granites from in-situ differentiation and includes abundant tourmaline, zircon, fluorapatite, monazite-(Ce), Nb–Ta–W minerals (Nb–Ta rutile, ferrocolumbite, manganocolumbite, ixiolite, Nb–Ta ferberite, hübnerite), cassiterite, topaz, molybdenite, arsenopyrite and aluminophosphates. The rare-metal granites from cupolas in the western segment of the Gemeric Unit represent the topaz–zinnwaldite granites, albitites and greisens. Zircon in these evolved rare-metal Li–F granite cupolas shows a larger xenotime-(Y) component and heterogeneous morphology compared to zircons from deeper porphyritic biotite granites. The zircon Zr/Hfwt ratio in deeper rooted porphyritic granite varies from 29 to 45, where in the differentiated upper granites an increase in Hf content results in a Zr/Hfwt ratio of 5. The cheralite component in monazite from porphyritic granites usually does not exceed 12 mol. %, however, highly evolved upper rare-metal granites have monazites with 14 to 20 mol. % and sometimes > 40 mol. % of cheralite. In granite cupolas, pure secondary fluorapatite is generated by exsolution of P from P-rich alkali feldspar and high P and F contents may stabilize aluminophosphates. The biotite granites contain scattered schorlitic tourmaline, while textural late-magmatic tourmaline is more alkali deficient with lower Ca content. The differentiated granites contain also nodular and dendritic tourmaline aggregations. The product of crystallization of volatile-enriched granite cupolas are not only variable in their accessory mineral assemblage that captures high field strength elements, but also in numerous veins in country rocks that often contain cassiterite and tourmaline. Volatile flux is documented by the tetrad effect via patterns of chondrite normalized REEs (T1,3 value 1.46). In situ differentiation and tectonic activity caused multiple intrusive events of fluid-rich magmas rich in incompatible elements, resulting in the formation of rare-metal phases in granite roofs. The emplacement of volatile-enriched magmas into upper crustal conditions was followed by deeper rooted porphyritic magma portion undergoing second boiling and re-melting to form porphyritic granite or granite-porphyry during its ascent.
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Imeokparia, E. G. "Geochemical evolution of the Jarawa Younger Granite complex and its related mineralization, northern Nigeria." Geological Magazine 122, no. 2 (March 1985): 163–73. http://dx.doi.org/10.1017/s0016756800031071.
Повний текст джерелаАнотація:
AbstractThe Jarawa Younger Granite complex is composed of high silica alkali granites that were emplaced 161 Ma ago. The granites are characterized by high contents of Rb, Li, F, Sn, Nb, W above normal low-Ca granitic rocks and have typical S-type characteristics that are indicative of a substantial component of crustal melt.Mineralization in the complex is associated with the biotite granite which was emplaced as a sheet-like body at relatively shallow depth and occurs as disseminations and as greisen lodes and veins.Chemical studies of the granites have shown that the biotite granite represents a highly fractionated rock that crystallized from a residual magma from which the hornblende-biotite granite had previously crystallized. However the biotite granite is characterized by steep gradients in some minor and trace elements that apparently indicate that liquid-state differentiation and/or volatile complexing processes made significant contributions to their differentiation. Enrichment of Th, Li, Rb, Sn, W and Nb may be more closely linked to roofward migration of F.
10
Stone, Maurice. "The Tregonning granite: petrogenesis of Li-mica granites in the Cornubian batholith." Mineralogical Magazine 56, no. 383 (June 1992): 141–55. http://dx.doi.org/10.1180/minmag.1992.056.383.01.
Повний текст джерелаАнотація:
AbstractLi-mica (zinnwaldite and/or lepidolite)—topaz—albite granites in the Tregonning—Godolphin pluton and similar rocks in the St. Austell pluton appear to be petrogenetically unrelated to the spatially associated biotite granites. Evidence is provided by lack of development of Li-mica granites at roof zones of biotite granites and markedly different trends and composition fields in bivariate plots such as Li vs. Cs, Rb vs. Sr and Nb vs. Zr. Thus, differentiation of biotite granite magma is unlikely to have generated Li-mica granite magma, as also, on its own, is partial melting of biotite granite or biotiteabsent residual lower crust. However, partial melting of biotite-rich residual rocks involving biotite breakdown could yield a trace alkali- and F-enriched melt, although this would require marked femic mineral, K-feldspar and anorthite fractionation, and Na-enrichment. It is proposed that volatiles derwed from either a mantle source or the crust/mantle interface have aided metasomatism of either residual S-type crust that earlier provided S-type biotite granite magma, or basic (biotite-rich) granitoid, to produce a low-temperature, low-viscosity Li-mica granite melt that rose rapidly in the crust soon after the emplacement of associated biotite granites.
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Akinola, Oluwatoyin O., Azman A. Ghani, and Elvaene James. "Petrography and Geochemical Characterization of a Granite Batholith in Idanre, Southwestern Nigeria." Sains Malaysiana 50, no. 2 (February 28, 2021): 315–26. http://dx.doi.org/10.17576/jsm-2021-5002-04.
Повний текст джерелаАнотація:
Idanre granite batholith in southwestern Nigeria contain three rock types, namely, Older granite undifferentiated (OGu), Older granite porphyritic (OGp) and Older granite fine-grained (OGf). The granitoids intruded into a basement rock of primarily migmatite gneiss. Petrography indicates that quartz, orthoclase, hornblende, and biotite are common to all members while microcline is more prominent in OGp and plagioclase is poorly represented in OGf. Despite minor differences in petrographic features, the granite units generally have similar geochemical relationships. The average SiO2 contents in OGp (70.49%), OGu (68.7%) and OGf (65.8%) are comparable to similar Pan-African suites located in eastern and northern Nigeria. Na2O+K2O-CaO versus SiO2 diagram shows all the granite members are calcic, K2O vs SiO2 plot classify the granites as high-K calcic alkali to shoshonitic. ANK vs ACNK plot indicatesthey are peraluminous. Plot of A/CNK vs SiO2 and K2O vs Na2O diagrams classified the rock as S-type granite. The granitoids are calc-alkaline with elevated Na2O (>2.6%) and Al/(Na2O+CaO) contents (OGu, 2.1-3.4; OGp, 2.4-3.1 and OGf, 2.2-2.9). The tectonic diagram (Rb vs (Y+Nb) indicatesthatthe batholith is Within Plate Granite (WPG.
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Stone, Maurice. "The Lundy granite: a geochemical and petrogenetic comparison with Hercynian and Tertiary granites." Mineralogical Magazine 54, no. 376 (September 1990): 431–46. http://dx.doi.org/10.1180/minmag.1990.054.376.09.
Повний текст джерелаАнотація:
AbstractNew chemical data show that the two main granite types (G1 and G2) cannot be discriminated, but that microgranite sheets/dykes (G3) are significantly different and more evolved, largely as a result of biotite, accessory mineral, and plagioclase fractionation. The Lundy granite is similar to other Tertiary granites of Scotland and Ireland, in age, setting, possible high-temperature mineralogy, relationship to basic magmatism, and REE patterns. These features and a highly evolved chemistry suggest derivation from an unexposed more ‘primitive’ granite that, in turn, had a basaltic parentage. However, similarities with the nearby S-type Hercynian granites, such as high aluminium saturation index (and normative corundum), high trace alkali, Nb, and F contents, low Zr, and high initial Sr ratio suggest a significant crustal component. The problem is resolved by proposing either mixing of silicic magma derived by strong fractionation of basaltic magma with anatectic magma from a pelitic/semi-pelitic crustal source, or fractionation of basaltic magma heavily contaminated by assimilated crustal material. Both origins would yield the high REE contents and fiat REE patterns of a ‘primitive’ granite magma. Fractionation, perhaps of hornblende initially, and later, of biotite and accessory minerals together with feldspars, would produce the small volume of highly fractionated Lundy granite.
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Stone, M., C. S. Exley, and M. C. George. "Compositions of trioctahedral micas in the Cornubian batholith." Mineralogical Magazine 52, no. 365 (April 1988): 175–92. http://dx.doi.org/10.1180/minmag.1988.052.365.04.
Повний текст джерелаАнотація:
AbstractNew major and trace element chemical analyses of trioctahedral micas of the Cornubian batholith emphasize their enrichment in a ‘trace-alkali element’ association (Li, Rb, Cs, F, Nb, Mn) and their deficiency in a ‘femic element’ association (Zr, Ce, Th as well as Mg and Ti) compared with micas from many other granite suites, although there are similarities with some Hercynian granites and with rare metal pegmatites. The new data demonstrate a continuous series from siderophyllite through zinnwaldite to lepidolite, principally as a result of Li-R2+ substitution as indicated by Foster (1960), although a more complete replacement is (Li, Al) = (Fe2+, Fe3+, Ti). It is suggested that the ranges of these micas are based upon the Li content in the unit cell formula and the ratio of Li to R2+, in effect, a compromise between the ranges proposed by Foster (1960) and Rieder (1970). Microprobe analyses lack Li2O, but can be plotted on FeO-SiO2 and FeO-Al2O3-SiO2 diagrams (wt. or atom %) in order to locate compositions within the trioctahedral LiFe micas and to distinguish between lepidolite and muscovite.An examination of 55 new mica analyses shows that hornfels biotites are richer in Mg and that the Cornubian Type A granite (as classifed by Exley and Stone, 1982) micas are richer in Ti and Fe compared with those of Type B granites. Micas from microgranite dykes appear to be poorer in femic elements and richer in trace alkalis and F compared with their Type B granite hosts, consistent with their differentiation from the latter. Mica chemistry is consistent with the magmatic evolution of the A-B-microgranite sequence in the biotite granites, the transformation of Types B to D upon emplacement of E, the derivation of Types E from B by extreme differentiation or metasomatic transformation and mobilization, and the in situ differentiation of Types G from E.
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de Beer, C. H., and P. H. Macey. "Lithostratigraphy of the Mesoproterozoic Windpoort Granite (Spektakel Suite), western Namaqualand, South Africa." South African Journal of Geology 122, no. 2 (June 1, 2019): 249–56. http://dx.doi.org/10.25131/sajg.122.0017.
Повний текст джерелаАнотація:
AbstractThe Windpoort Granite is a porphyritic, leucocratic granite belonging to the Spektakel Suite, a group of late- to post-tectonic granites intruded into the orthogneisses and supracrustal metamorphic rocks in western Namaqualand. Like other granites of this type, it is devoid of penetrative tectonic foliation, at most displaying a magmatic foliation parallel to the boundaries of the intrusion. Its main characteristic setting it apart from other Spektakel Suite granites in western Namaqualand is its tightly packed arrangement of small stubby alkali feldspar phenocrysts. Its U-Pb LA-ICPMS age of 1087 ± 11 Ma agrees with the age of other Spektakel Suite granites showing similar field relationships. It classifies geochemically as a highly potassic monzogranite with more evolved compositions than all other plutons of the Spektakel Suite.
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Daneshvar, Narges, Hossein Azizi, Yoshihiro Asahara, Motohiro Tsuboi, and Mahdi Hosseini. "Rare Earth Elements and Sr Isotope Ratios of Large Apatite Crystals in Ghareh Bagh Mica Mine, NW Iran: Tracing for Petrogenesis and Mineralization." Minerals 10, no. 9 (September 22, 2020): 833. http://dx.doi.org/10.3390/min10090833.
Повний текст джерелаАнотація:
The 320 Ma Ghareh Bagh mica mine is the only active mica mine in northwest Iran, and hosts Mg-bearing biotite (phlogopite) with apatite, epidote, and calcite. Chemical investigation of apatite infers the high abundances of the rare earth elements (REEs up to 5619 ppm), higher ratios of the LREE/HREE ((La/Yb)N = 28.5–36.7)) and high content of Y (236–497 ppm). REE pattern in the apatite and host A-type granite is almost the same. Ghareh Bagh apatite formed from the early magmatic-hydrothermal exsolved fluids at the high temperature from the Ghushchi alkali feldspar granite. The apatite crystals came up as suspension grains and precipitated in the brecciated zone. The early magmatic-hydrothermal fluids settle phlogopite, epidote, chlorite, K-feldspar and albite down in the brecciation zone. Due to the precipitation of these minerals, the late-stage fluids with low contents of Na+, Ca2+ and REE affected the early stage of alteration minerals. The high ratios of 87Sr/86Sr (0.70917 to 0.70950) are more consistent with crustal sources for the apatite large crystals. The same ages (320 Ma) for both brecciated mica veins and host alkali feldspar granites infer the apatite and paragenesis minerals were related to host granite A-type granite in the Ghareh Bagh area.
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Aryanto, Noor C. D., and E. Suparka. "THE PETROLOGY CHARACTERISTIC OF GRANITOID ROCK BASED ON GEOCHEMICAL ANALYSIS OF BAJAU CAPE COAST AND ITS SURROUNDING, WEST KALIMANTAN." BULLETIN OF THE MARINE GEOLOGY 28, no. 1 (February 15, 2016): 13. http://dx.doi.org/10.32693/bomg.28.1.2013.51.
Повний текст джерелаАнотація:
The aim of this study is to identify of petrology characteristic based on geochemical analysis in order to know the granitoid rock type. Administratively, the study area is in the City and District of Singkawang, West Kalimantan Province, at coordinate 108°48'30†- 109°1'30†E and 0°40'30†- 0°54'30†N and, situated ± 145 km to the north of Pontianak City. The outcrop of granitoid along Bajau Cape coast and its surrounding, had been analyzed petrographically and geochemically using AAS method. Based on analysis of five samples show that the ratio mole of Al2O3/(CaO+Na2O +K2O) > 1 ranged between 1.12 and 1.7, while the rest of three samples are moderately aluminous, with a ratio value between 0.5 and 1.0. The ratio between K2O and (K2O+Na2O+CaO) ranges 0.07 to 0.55 (moderate) that forms alkali feldspar normative ranges from 3.8 to 15.89 wt%. This ratio shows that granite alkali feldspar is classified to be calc-alkaline series. Petrographically, this rock is porfiritic texture, hollocrystalline, granular hypodiomorphic and biotite present as phenocryst, yellowish brown, euhedral, thin and platy. The content of oxides element (Na2O and MgO) tend to decrease, whereas of other oxides elements, namely Al2O3, TiO2, K2O, FeO and CaO increased, parallel with the raising of SiO2. Therefore, the Singkawang Granitoid can be grouped as alkali feldspar granite, syeno-granite and quartz monzonite.
Keywords: petrography, geochemstry, major elements, calc-alcaline affinity, granitoid type and Bajau Coast, West Kalimantan.
Penelitian ini bertujuan untuk mengidentifikasi karakteristik petrologi, berdasarkan analisa geokimia sehingga jenis batuan granitoidnya dikenali. Secara administratif, daerah penelitian termasuk ke dalam Kota dan Kabupaten Singkawang, Provinsi Kalimantan Barat, pada koordinat 108°48'30†- 109°1'30†BT and 0°40'30†- 0°54'30†LU dan terletak ± 145 km, arah utara dari Kota Pontianak. Singkapan batuan granitoid sepanjang pantai Tanjung Bajau dan sekitarnya telah dianalisis secara petrografi dan geokimia dengan menggunakan AAS. Berdasarkan 5 contoh yang dianalisa menunjukan perbandingan mol Al2O3/(CaO+Na2O +K2O) > 1, yakni berkisar antara 1,12-1,7, sedangkan 3 contoh sisanya bersifat peraluminus sedang, dengan nilai ratio antara 0.5-1.0. Perbandingan antara K2O dan (K2O+Na2O+CaO) berkisar antara 0,07-0,55 (sedang) yang membentuk alkali normatif feldspar berkisar 3,84 – 15,89% (berat). Perbandingan tersebut menunjukan batuan Granit alkali feldspar yang tergolong dalam seri batuan kalk-alkali. Secara petrografi, batuan tersebut menunjukkan tekstur porfiritik, holokristalin, hipidiomorfik granular dengan biotit hadir sebagai fenokris, coklat kekuningan, euhedral, pipih dan sedikit berlembar. Kandungan unsur oksida (Na2O dan MgO) cenderung mengalami penurunan, sedangkan unsur oksida lainnya, yaitu Al2O3, TiO2, K2O, FeO dan CaO mengalami kenaikan sejalan dengan makin bertambahnya SiO2. Maka dengan demikian Granitoid Singkawang dapat dikelompokan menjadi granit alkali feldspar, syenit-granit dan kuarsa-monsonit.
Kata kunci: Petrografi, geokimia, senyawa utama, afinitas kalk-alkalin, batuan granitoid dan Pantai Bajau, Kalimantan Barat.
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Yu, Xue Feng, Da Peng Li, Hong Kui Li, Shu Xing Wang, and Wei Shan. "Mesozoic Tectonomagmatic Evolution and Gold Metallogeny in Jiaodong Area, East China." Advanced Materials Research 905 (April 2014): 92–95. http://dx.doi.org/10.4028/www.scientific.net/amr.905.92.
Повний текст джерелаАнотація:
There were twice major collision orogenic events in Jiaodong area in Mesozoic period. It showed as three times of magmatic activities and stretching in Jiaodong area. In this paper, based on collecting age datas, referring to the previous classification scheme, a chronological frame pattern of Yanshanian granites had been put forward: Linglong-Kunyushan granite emplacement was in in 160~150Ma; the formation of Guojialing granodiorite was in 130~126Ma; Weideshan granodiorite-granite emplacement was in 120~110Ma; Laoshan A-type miarolitic cavity parlkaline alkali feldspar granite emplacement was in 110~100Ma and represented the end of Yanshan movement. Gold mineralization in three periods in this area had coupled relation with Linglong-Kunyushan granite, Guojialing granodiorite and Weideshan granodiorite-granite. Jiaodong tectonic-magmatic events and gold mineralization were controlled by the interactions among Tethyan tectonic domain, Paleo-ocean tectonic domain and the Pacific tectonic domain.
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Li, Hao-Ran, Ye Qian, Feng-Yue Sun, and Liang Li. "Geochemistry, zircon geochronology, and isotopic systematics of the Zhanbuzhale granites in the East Kunlun, Qinghai Province, northwestern China: implications for the tectonic setting." Canadian Journal of Earth Sciences 57, no. 2 (February 2020): 275–91. http://dx.doi.org/10.1139/cjes-2018-0251.
Повний текст джерелаАнотація:
The Zhanbuzhale region, in the Eastern Kunlun Orogen of northwestern China, is characterized by large volumes of Phanerozoic granitoid rocks and is an ideal region for investigating the tectonic evolution of the Paleo-Tethys system. However, the exact timing of the final closure of the Paleo-Tethys Ocean and initial continental collision remains controversial because of a lack of precise geochronological and detailed geochemical data. In this paper, we report new zircon U–Pb ages and mineralogical, petrographic, and geochemical data for samples of Middle Triassic granodiorite and alkali feldspar granite from the Zhanbuzhale region. The zircon U–Pb ages indicate that the granodiorite and alkali feldspar granite formed at 239 and 236 Ma, respectively. The granodiorites are high-K calc-alkaline, metaluminous, high Sr content, high Sr/Y ratios, low Y content, and show adakite-like affinities. The alkali feldspar granites display high SiO2, extremely low MgO, and low Zr+Nb+Ce+Y contents as well as low Fe2O3t/MgO ratios, showing metaluminous to peraluminous and high-K calc-alkaline features. Geochemical and petrological characteristics of the alkali feldspar granites suggest that they are highly fractionated I-type granites. The granodiorites and alkali feldspar granites have zircon εHf(t) values ranging from –2.26 to –0.18, and from –2.17 to +2.18, respectively. Together with regional geological data, we propose that the Triassic (approximately 239–236 Ma) granitoids were generated during the later stages of northward subduction of the Paleo-Tethys oceanic plate, and that the initial stage of collision between the East Kunlun and the Bayan Har–Songpan Ganzi terrane occurred at approximately 236–227 Ma.
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Sandeman, Hamish A., and John Malpas. "Epizonal I- and A-type granites and associated ash-flow tuffs, Fogo Island, northeast Newfoundland." Canadian Journal of Earth Sciences 32, no. 11 (November 1, 1995): 1835–44. http://dx.doi.org/10.1139/e95-141.
Повний текст джерелаАнотація:
Magmatic activity of Silurian–Devonian age is widespread in the Appalachian–Caledonian Orogen. A marked characteristic of this magmatism is the composite nature of the igneous suites, which range from peridotite to granodiorite in single plutonic bodies. The origin of these suites is still enigmatic, and the assumption that all are the same not proven. Such a suite of intrusive rocks, ranging in composition from minor peridotite to granodiorite, intrudes an openly folded sequence of Silurian volcanogenic sandstones and ash-flow tuffs on Fogo Island, northeast Newfoundland. Two units, the Rogers Cove and Hare Bay microgranites, consist of fine-grained hastingsite granites with spherulitic and flow-banded textures, and exhibit drusy cavities and microfractures that contain the mineral assemblage hastingsitic hornblende + plagioclase + magnetite + zircon. These rocks are characterized by elevated high field strength element contents (e.g., Zr = 74–672 and Y = 21–103 ppm), very high FeO*/MgO ratios (FeO*/MgO = 2.4–93.5), and 10 000 Ga/Al ratios of 1.67–10.52, indicating an A-type granitoid affinity. A third and the most voluminous granitic unit, the Shoal Bay granite, is an alkali-feldspar-phyric, medium-grained, equigranular biotite–hastingsite granite with hastingsite and annitic biotite interstitial to euhedral plagioclase, anhedral quartz, and perthite crystals. The Shoal Bay granite exhibits mineral parageneses similar to the microgranites, but chemical characteristics more typical of calc-alkaline, I-type granitoids. Volcanic–sedimentary sequences spatially associated with the granitic rocks include dense, welded, high-silica, hastingsite-bearing ash-flow tuffs with compositions that suggest they represent erupted equivalents of fractionated end members of the Shoal Bay granite. The rocks making up the Fogo Island batholith have been directly equated with the bimodal, calc-alkaline Mount Peyton batholith of northeast Newfoundland, but the specialized A-type nature of the Fogo granites suggests differing source conditions for the two suites.
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Debowski, Beatriz Pereira, Guilherme Loriato Potratz, Armando Dias Tavares Júnior, Maria Virgínia Alves Martins, and Mauro Cesar Geraldes. "Age and Origin of the Massangana Intrusive Suite and Associated Mineralizations, in the Rondônia Tin Province: Petrography, U-Pb, and Lu-Hf Isotopes Zircons." Minerals 12, no. 10 (October 16, 2022): 1304. http://dx.doi.org/10.3390/min12101304.
Повний текст джерелаАнотація:
Rondônia intrusive suites represent the youngest A-type magmatism that occurred in the SW of the Amazon craton, with mineralizations in Sn, Nb, Ta, W, and topaz. Petrological and isotopic studies (U-Pb and Lu-Hf by LA-ICP-MS) allowed the Massangana granite to be subdivided into São Domingos facies (medium to fine biotite-granite), Bom Jardim facies (fine granite), Massangana facies (pyterlites and coarse granites) and Taboca facies (fine granites). The crystallization ages obtained were between 995.7 ± 9.5 Ma to 1026 ± 16 Ma, and the εHf values vary significantly between positive and negative, showing predominantly crustal sources for forming these rocks. Petrographic studies on ore samples indicate the action of co-magmatic hydrothermal fluids enriched in CO2, H2O, and F. These ores are characterized by endogreisens, exogreisens, pegmatites, and quartz veins that are explored in the São Domingos facies area. The endogreisens and exogreisens are formed by topaz-granites and zinnwaldite-granites; the pegmatites are formed by topaz-zinnwaldite-cassiterite-granites; and the veins by cassiterite-sulfides and quartz. The geometries of the mineralized bodies indicate a dome-shaped contact with the host rocks in the magma chamber and can be attributed to residual accumulation. In this sense, the origin of these ores is related to the evolution of intrusive granitic bodies where the terminal phases of the fluid-enriched magma are lodged in the apical portions, and the origin of the mineralized bodies present a biotite-granite, albite-granite, and endogreisens evolution (potassium series), or biotite-granite, alkali-granite and endogreisens (sodic series) and these rocks present TDM ages that indicate a concerning relation to the non-mineralized rocks of Massangana granite.
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PRADO, MAURÍCIO, JOSÉ TADEU MAXIMINO MIRRAS FERRON, EVANDRO FERNANDES DE LIMA, ARTUR CEZAR BASTOS NETO, VITOR PAULO PEREIRA, ORLANDO RENATO RIGON MINUZZI, and RONALDO PIEROSAN. "Caracterização Petrográfica e Geoquímica da Parte Leste do Granito Europa, Distrito Mineiro de Pitinga, AM." Pesquisas em Geociências 34, no. 1 (June 30, 2007): 77. http://dx.doi.org/10.22456/1807-9806.19464.
Повний текст джерелаАнотація:
The important mineral deposits of the Pitinga Mine, in the Amazonian region are related to A-type granites intruded in the Iricoumé Group. The Europa granite is one of these A-type rocks, intruded in the Iricoumé Group, which is represented by subaerial vulcanoclastic rocks (crystal-rich ignimbrites, thin massive tuffs and siltic tufaceous arenites) and minor hipabissal rhyolites. The volcanic rocks were probably generated in a caldera environment. The Europa granite is an alkali-feldspar peralkaline granite (hipersolvus) without genetic relationship with to the volcanic rocks of the Iricoumé Group, but it could have been generated during the resurgence stages. The petrographic and geochemical data attest that fractional crystallization process was the principal mechanism during the crystallization, which led to the generation of two different granitic facies. The Nb soil anomalies overprinted on the more differentiated facies are related to the astrophillite weathering.
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Abdel Wanees, Nora G., Mohamed M. El-Sayed, Khalil I. Khalil, and Hossam A. Khamis. "Petrogenesis of contrasting magmatic suites in the Abu Kharif area, Northern Eastern Desert, Egypt: implications for Pan-African crustal evolution and tungsten mineralization." Geological Magazine 159, no. 3 (November 30, 2021): 441–67. http://dx.doi.org/10.1017/s0016756821001047.
Повний текст джерелаАнотація:
AbstractThe Abu Kharif area in the Northern Eastern Desert consists of contrasting granitic magma suites: a Cryogenian granodiorite suite (850–635 Ma), an Ediacaran monzogranite suite (635–541 Ma) and a Cambrian alkali riebeckite granite suite (541–485 Ma). Tungsten mineralization occurs within W-bearing quartz veins and a disseminated type confined to the monzogranite.Whole-rock geochemical data classify the granodiorite as a late-orogenic I-type with calc-alkaline affinity, while the monzogranite and alkali riebeckite granite represent respectively a post-orogenic highly fractionated I-type with calc-alkaline affinity and an anorogenic A1-subtype with alkaline affinity. Geochemical modelling indicates that the three intrusions represent separate magmatic pulses where the granodiorite was generated by ∼75 % batch partial melting of an amphibolitic source followed by fractional crystallization of hornblende, biotite, apatite and titanite. The monzogranite was formed by 62 % batch partial melting of the normal ‘non-metasomatized’ Pan-African crust of calc-alkaline granite composition followed by fractional crystallization of plagioclase, biotite, K-feldspar, magnetite, ilmenite, with minor apatite and titanite. The alkali riebeckite granite was generated by 65 % batch partial melting of metasomatized Pan-African granite source followed by fractional crystallization of plagioclase, K-feldspar, amphibole and biotite with minor magnetite, apatite and titanite. In general, the parent magmas of the three intrusions were originally enriched in W, but with different concentrations. This W-enrichment would be caused by magmatic-related hydrothermal volatile-rich fluids and concentrated within the monzogranite.
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Najili, Ahmad, Purnama Sendjaja, Bambang Priadi, Verry Edi Setiawan, and Barry Majeed Hartono. "Petrogenesis of Pre-Tertiary A-Type Granitoid in Jambi Area and its Implications of Rare Earth Element Potential on Main Range Sumatra Belt." Indonesian Journal of Economic Geology 1, no. 1 (December 30, 2021): 49–71. http://dx.doi.org/10.51835/ijeg.2021.1.1.342.
Повний текст джерелаАнотація:
Granitoid rocks are one of the main sources of rare earth elements (REE). This makes granitoid characterization become important in the early stages of REE exploration. Almost all granitoids in Indonesia have been mapped. However, more detailed granitoid studies in Indonesia are still focused on Bangka and Belitung granites (tin belt granite). In contrast to Bangka and Belitung granites, studies related to petrogenesis and granite characteristics on the mainland of Sumatra Island (Sumatra Main Range) are rarely done, such as granitoid in Jambi area. The aim of this study is to determine the characteristics of the Pre-Tertiary granitoids located in the Tigapuluh and Duabelas Mountains, Jambi. The Tanjungjabung Barat granitoid represent the Tigapuluh Mountains area while the Sarolangun granitoid represent the Duabelas Mountains area. These two granitoids interpreted to be Triassic to Jurassic in age. Granitoid characteristics include petrological and geochemical characters. This study also focuses on the petrogenesis of Pre-Tertiary granitoid and its implications for the abundance of REEs. Megascopic observation, petrographic, and geochemical analysis are done in this study. Geochemical analysis was done at the Center of Geological Survey Laboratory, Bandung using the ICP-MS Thermo Icap-Q and XRF ADVANT XP Thermo ARL9900 instruments. Based on megascopic and petrographic observations, both of the granitoids are classified as granite. Geochemically, these two granitoids show the character of A-type granite which is formed in the post-collision environment, and derived from the crustal melting with ferrous alkalic to alkali-calcic peraluminous affinities. This crustal melting happened due to the collision of the Sibumasu Block with Indochina resulting in crustal thickening and crustal melting. The magma then contaminated effectively in the rift environment due to the subduction roll-back of Meso-Tethys in the Late Triassic. Subduction in the West Sumatra also play roles in the genesis and it is shown by the geochemical character of the Sarolangun granitoid. Effective contamination derives the characteristics of A-type granite so that the REE content in both granites are abundant. The abundance of REE is indicated by the presence of the allanite, monazite, apatite, zircon, and titanite. The REE concentration of the Sarolangun granitoid reaches 330 ppm, while the Tanjungjabung Barat granitoid reaches 261 ppm. The REE concentrations of A-type granitoid in Jambi then compared with A-type granitoids from the world and showed relatively the same REE concentrations. The REE concentrations of these granitoids are also higher than the other type granitoids in Indonesia. However, the REE concentrations of Jambi granitoids are similar to the fractionated S-type granite in Bangka. With a recent study showing the presence of A-type granitoid in Sarudik (North Sumatra) and Bukit Batu (South Sumatra), the A-type granitoid in this study indicates the existence of A-type granitoid belt in the Sumatra Main Range. This belt will have a high abundance of REE concentrations and potentially become the source for REE deposits. The author hopes that this study could improve the understanding of tectonic in Sumatra and suggestion for REE exploration in the area.
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Zhu, Xinxiang, Markus B. Raschke, and Yan Liu. "Tourmaline as a Recorder of Ore-Forming Processes in the Xuebaoding W-Sn-Be Deposit, Sichuan Province, China: Evidence from the Chemical Composition of Tourmaline." Minerals 10, no. 5 (May 14, 2020): 438. http://dx.doi.org/10.3390/min10050438.
Повний текст джерелаАнотація:
The Xuebaoding W-Sn-Be deposit located in the Songpan-Ganze Orogenic Belt (Sichuan Province, China) is a hydrothermal deposit with less developed pegmatite stage. The deposit is famous for the coarse-grained crystals of beryl, scheelite, cassiterite, apatite, fluorite, muscovite, and others. The orebody is spatially associated with the Pankou and Pukouling granites hosted in Triassic marbles and schists. The highly fractionated granites are peraluminous, Li-Rb-Cs-rich, and related to W-Sn-Be mineralization. The mineralization can chiefly be classified based on the wallrock and mineral assemblages as muscovite and beryl in granite (Zone I), then beryl, cassiterite and muscovite at the transition from granite to triassic strata (Zone II), and the main mineralized veins composed of an assemblage of beryl, cassiterite, scheelite, fluorite, and apatite hosted in metasedimentary rock units of marble and schist (Zone III). Due to the stability of tourmaline over a wide range of temperature and pressure conditions, its compositional variability can reflect the evolution of the ore-forming fluids. Tourmaline is an important gangue mineral in the Xuebaoding deposit and occurs in the late-magmatic to early-hydrothermal stage, and can thus be used as a proxy for the fluid evolution. Three types of tourmalines can be distinguished: tourmaline disseminations within the granite (type I), tourmaline clusters at the margin of the granite (type II), and tourmalines occurring in the mineralized veins (type III). Based on their chemical composition, both type I and II tourmalines belong to the alkali group and to the dravite-schorl solid solution. Type III tourmaline which is higher in X-site vacancy corresponds to foitite and schorl. It is proposed that the weakly zoned type I tourmalines result from an immiscible boron-rich aqueous fluid in the latest stage of granite crystallization, that the type II tourmalines showing skeletal texture directly formed from the undercooled melts, and that type III tourmalines occurring in the mineralized veins formed directly from the magmatic hydrothermal fluids. Both type I and type II tourmalines show similar compositional variations reflecting the highly fractionated Pankou and Pukouling granites. The higher Ca, Mg, and Fe contents of type III tourmaline are buffered by the composition of the metasedimentary host rocks. The decreasing Na content (<0.8 atoms per formula unit (apfu)) and increasing Fe3+/Fe2+ ratios of all tourmaline samples suggest that they precipitated from oxidized, low-salinity fluids. The decreasing trend of Al content from type I (5.60–6.36 apfu) and type II (6.01–6.43 apfu) to type III (5.58–5.87 apfu) tourmalines, and associated decrease in Na, may be caused by the crystallization of albite and muscovite. The combined petrographic, mineralogical, and chemical characteristics of the three types of tourmalines thus reflect the late-magmatic to early-hydrothermal evolution of the ore-forming fluids, and could be used as a geochemical fingerprint for prospecting W-Sn-Be mineralization in the Xuebaoding district.
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Sun, Zhenjun, Guanghu Liu, Yunsheng Ren, Xi Chen, Xinhao Sun, Chengyang Wang, and Zuowu Li. "Age, Genesis and Tectonic Setting of the Sayashk Tin Deposit in the East Junggar Region: Constraints from Lu–Hf Isotopes, Zircon U–Pb and Molybdenite Re–Os Dating." Minerals 12, no. 9 (August 23, 2022): 1063. http://dx.doi.org/10.3390/min12091063.
Повний текст джерелаАнотація:
The Sayashk tin (Sn) deposit is located within the southern part of the Eastern Junggar orogenic belt in Xinjiang Province and forms part of the Kalamaili alkaline granite belt. There are many Sn polymetallic deposits in the area. To constrain the age, genesis, and tectonic setting of the Sayashk tin deposit in the East Junggar region, we conducted a bulk-rock geochemical analysis of the granite porphyry (SR1) and medium- to fine-grained granite (SR2) hosts of the deposit, LA-ICP-MS zircon U–Pb dating and Lu–Hf isotopic analysis, as well as molybdenite Re–OS dating and combined our results with the metallogenic conditions and other geological characteristics of the deposit. The results show that the Sayashk Sn deposit is indeed spatially, temporally, and genetically closely related to the granite porphyry and medium-fine-grained granite. Both zircon U–Pb ages are 308.2 ± 1.5 Ma and 310.9 ± 1.5 Ma, respectively. The isochron age of molybdenite is 301.4 ± 6.7 Ma, which represents the crystallization age of the granite porphyry and medium-fine-grained granite. Therefore, all of them formed in the late Carboniferous epoch. The medium-fine-grained granites and granite porphyry are characteristically rich in Si and alkali, poor in Ca and Mg, rich in high field-strength elements (HFSE, e.g., Zr, Hf) and Ce, and deficient in Ba, Sr, Eu, P, and Ti. They are typical A-type granites, showing the characteristics of a mixed crustal mantle source. The εHf(t) values of the zircon from the granite porphyry (SR1) range from 10.27 to 16.17 (average 13.71), εHf(t) values of the zircon from the medium-fine-grained granites (SR2) are between 5.72 and 9.21 (average 7.08), and the single model ages (TDM1) and two-stage model ages (TDM2) of the granite porphyry (SR1) fall within the ranges of 319~535 Ma and 339~644 Ma. The single model ages (TDM1) and two-stage model ages (TDM2) of the medium-fine-grained granites (SR2) fall within the ranges of 346~479 Ma and 309~557 Ma. There is little difference between their two-stage model ages and zircon U–Pb ages, indicating that the Sayashk granite may be the product of partial melting of juvenile crustal. Combined with previous research results, the Sayashk Sn deposit formed in a post-collision extensional tectonic setting after the late Carboniferous in the Kalamaili area.
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Qiu, Xiao-Fei, Qiong Xu, Tuo Jiang, Shan-Song Lu, and Long Zhao. "Petrogenesis and tectonic significance of the middle Neoproterozoic highly fractionated A-type granite in the South Qinling block." Geological Magazine 158, no. 10 (May 31, 2021): 1891–910. http://dx.doi.org/10.1017/s001675682100042x.
Повний текст джерелаАнотація:
AbstractThe South Qinling block, a segment of the Yangtze craton involved in the Qinling–Dabie orogen, is critical for understanding the tectonic evolution of eastern China. However, the tectonic setting of the South Qinling block and the northern margin of the Yangtze block during middle Neoproterozoic time has long been the subject of debate, with two distinctly different models (continental rift or volcanic arc) proposed. Here, a comprehensive study of zircon U–Pb geochronology and geochemistry has been carried out on the Chengwan granitic pluton from the Suizao terrane in the South Qinling block. The granites are monzogranite and syenogranite in lithology, and are mainly composed of potash feldspar, quartz, plagioclase and biotite. This suite has long been regarded as a Palaeozoic magmatic pluton, but zircon U–Pb ages of 809 ± 9 Ma and 816 ± 4 Ma are obtained in this study. The granites are metaluminous to strongly peraluminous with high alkali contents, and exhibit highly fractionated features, including high SiO2, low Zr/Hf ratios, rare earth element tetrad effects and enrichment of K and Rb. They show Hf–Nd isotopic decoupling, which may be genetically related to their petrogenetic process. Based on the geochemical features and the positive εHf(t) values of the zircons, it is indicated that the granites may have been derived from partial melting of juvenile tonalitic rocks by biotite breakdown under fluid-absent conditions. The Chengwan granite geochemically belongs to the A2-subtype granites, suggesting that it might have formed in a post-orogenic tectonic setting. The highly fractionated A-type granite in this study may represent extensional collapse shortly after the collisional events in the South Qinling block, and thus indicate a tectonic regime switch, from compression to extension, as early as middle Neoproterozoic time. Integrating our new data with documented magmatic, metamorphic and sedimentary events during middle Neoproterozoic time in the region may support a continental rift model, and argues against arc models.
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Polin, V. F., N. M. Zvereva, A. V. Travin, and A. V. Ponomarchuk. "THE AGE OF GOLD MINERALIZATION IN THE KETKAP-YUNA IGNEOUS PROVINCE, FORMATIONAL TYPES OF GOLD-BEARING COMPLEXES, AND TIME DIFFERENCES IN THE OCCURRENCE OF LATE MESOZOIC MAGMATISM IN DIFFERENT PARTS OF THE ALDAN SHIELD." Tikhookeanskaya Geologiya 41, no. 5 (2022): 3–19. http://dx.doi.org/10.30911/0207-4028-2022-41-5-3-19.
Повний текст джерелаАнотація:
The first 40Ar/39Ar isotopic age data for hydrothermal vein gold mineralization in the late Mesozoic Ketkap-Yuna igneous province of the Aldan shield confirm the correlation between this style of mineralization and the Early Cretaceous sub-alkali magmatism, which was established by geological observations. The combination of geological characteristics and U-Pb data on magmatites enabled us to indirectly determine the age of the highly productive bimetasomatic «massif-skarn» type of mineralization associated with sub-alkali magmatogenic formations of the province. The isotopic dating of magmatites and gold mineralization in the Ketkap-Yuna igneous province and other late Mesozoic igneous provinces of the Aldan shield shows consistency in the ages of ore-bearing magmatites and associated ores. The delay in time of the Late Mesozoic magmatism manifestations in the Ketkap-Yuna igneous province and the associated gold mineralization relative to the intensification of tectonomagmatic processes in the Western and Central Aldan, as well as differences in the correlations of different types of igneous formations in the provinces, are explained by the characteristics of the regional tectonic structure and, as a consequence, the specific nature of the Late Mesozoic magmatism development in different parts of the Aldan shield. Two large areas of the late Mesozoic intensification of tectonomagmatic processes are identified in the Aldan shield that differ both in the time of the onset of polyformational magmatism and the accompanying different-type mineralization, and in the dominant formational type of magmatites: West-Central Aldan, on the one hand, and East Aldan, on the other. The former is characterized by continuous magmatic activity from the Berriasian to the early Albian (≈ 30 Ma) and predominance of the leucitite–alkali-(foid)-syenite formation, and the latter by manifestations of magmatism over a timeframe half of the above period (≈ 15 Ma) and predominance of the subalkaline diorite-granodiorite-granite formation. The termination of the late Mesozoic magmatism in both areas was subsynchronous. A «set» of magmatogenic formations in them is also similar: leucite-alkaline-(foid)-syenite with alkali granites, monzonite (shonkinite)-syenite and subalkaline diorite-granodiorite-granite. The Coniacian–Santonian outbreak of alkali volcano-plutonism during the intensification of tectonomagmatic processes is characteristic of the East Aldan region, which manifested itself in the Ketkap-Yuna igneous province after a long (about 30 Ma) period of amagmatism.
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Qin, Jin-hua, Cui Liu, and Jin-fu Deng. "Geochronology and geochemistry of igneous rocks in the southeastern Lesser Xing’an Range, northeastern China: petrogenesis and implications for the early Mesozoic tectonic evolution." Canadian Journal of Earth Sciences 57, no. 4 (April 2020): 506–23. http://dx.doi.org/10.1139/cjes-2018-0198.
Повний текст джерелаАнотація:
We present systematic U–Pb age data collected by laser ablation multi-collector inductively coupled plasma mass spectrometry, precise geochemical data, and Nd isotope data for igneous rocks from the southeastern Lesser Xing’an Range (SE LXR). The results indicate that the formation ages as follows: Maojiatun alkaline granite, 207.2 ± 0.84 Ma and 204.6 ± 0.93 Ma; Diorite porphyrite, 164.5 ± 0.97 Ma; and Tieli syenogranite, 186.7 ± 1.50 Ma. The alkaline granite has high silicon, potassium, alkali, and FeOT contents; it is enriched in high field strength elements, Zr, Hf, Th, Rb, and U; is depleted in Ba, Sr, Nb, Ta, P, Ti, etc.; and has high ratios of 10000Ga/Al. It shows an A2-type granite affinity. The Tieli alkali-feldspar granite has high total alkali contents and is enriched in high field strength elements and rare earth elements and depleted in Sr, Ba, Ti, and P, and shows varying degrees of alkalinity. Rocks from SE LXR display similar εNd (t) values with corresponding to Nd model ages of 1095 to 813 Ma. The igneous rocks from the SE LXR are proposed to be derived from melting of the Neoproterozoic lower crust and potential magma mixing with ancient crystalline basement. The formation of the Maojiatun alkaline granite occurred in response to a postorogenic event following the closure of the Paleo-Asian Ocean. However, the SE LXR exhibited an extensional back-arc tectonic setting in the Early Jurassic. The Middle Jurassic diorite porphyrite could be related to the temporary stagnation of the westward subduction of the Paleo-Pacific plate.
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Murphy, J. Brendan, Alan J. Anderson, and Doug A. Archibald. "Postorogenic alkali feldspar granite and associated pegmatites in West Avalonia: the petrology of the Neoproterozoic Georgeville Pluton, Antigonish Highlands, Nova Scotia." Canadian Journal of Earth Sciences 35, no. 2 (February 1, 1998): 110–20. http://dx.doi.org/10.1139/e97-099.
Повний текст джерелаАнотація:
The 579.8 ± 2.2 Ma (40Ar-39Ar, muscovite) Georgeville Pluton in mainland Nova Scotia is an epizonal body consisting of alkali feldspar granite and related pegmatite. The pluton intrudes the ca. 619-608 Ma arc-related rocks of the Georgeville Group, which comprises part of West Avalonia, the largest terrane in the Canadian Appalachians. The granite is characterized by above-average SiO2, Th, Nb, Y, and Zr; very low CaO, TiO2, MgO, FeO, and MnO; and most notably by positively sloped rare earth element (REE) profiles generated by extreme light REE depletion. Tectonic discrimination diagrams suggest a within-plate environment, with many, but not all, geochemical and mineralogical features resembling A-type granites. Numerous local and regional geological constraints indicate that the pluton was intruded in a trancurrent setting following the cessation of Neoproterozoic arc-related magmatism along the West Avalonian portion of the Gondwanan continental margin. Geochemical data are consistent with derivation by partial melting of depleted crust or upper mantle followed by extreme fractionation, including REE-rich accessory phases.
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Mao, Chen, Xinbiao Lü, and Chao Chen. "Geochemical Characteristics of A-Type Granite near the Hongyan Cu-Polymetallic Deposit in the Eastern Hegenshan-Heihe Suture Zone, NE China: Implications for Petrogenesis, Mineralization and Tectonic Setting." Minerals 9, no. 5 (May 18, 2019): 309. http://dx.doi.org/10.3390/min9050309.
Повний текст джерелаАнотація:
In the eastern Hegenshan-Heihe suture zone (HHSZ) of NE China, Cu-Au hydrothermal mineralization at the newly discovered Hongyan deposit is associated with the Shanshenfu alkali-feldspar granite (SAFG). Zircon U-Pb dating showed that the inner phase and outer phase of the SAFG were formed at 298.8 ± 1.0 Ma and 298.5 ± 1.0 Ma, respectively. Whole rock geochemistry suggests that the SAFG can be classified as an A-type granite. Halfnium isotopes and trace elements in zircon suggest that the SAFG has high Ti-in-zircon crystallization temperature (721–990 °C), high magmatic oxygen fugacity and largely positive εHf(t) (from +6.0 to +9.9). We proposed that the SAFG was derived from crustal assimilation and fractional crystallization of juvenile crust metasomatized by subducting oceanic crust. The high oxygen fugacity of the SAFG suggests the chalcophile elements (e.g., Cu, Au) remained in the magma as opposed to the magma source. An arc-related juvenile source favors enrichment of Cu and Au in the resulting magma. Combined, these magmatic characteristics suggest Cu ± Au exploration potential for magmatic-hydrothermal mineralization related to the SAFG, and similar bodies along the HHSZ. The results obtained combined with regional geological background suggest that the Permian A-type granites and related mineralization along the HHSZ were formed in a post-collisional slab break-off process.
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Tillberg, Mikael, Olga M. Maskenskaya, Henrik Drake, Johan K. Hogmalm, Curt Broman, Anthony E. Fallick, and Mats E. Åström. "Fractionation of Rare Earth Elements in Greisen and Hydrothermal Veins Related to A-Type Magmatism." Geofluids 2019 (August 22, 2019): 1–20. http://dx.doi.org/10.1155/2019/4523214.
Повний текст джерелаАнотація:
This study focuses on concentrations and fractionation of rare earth elements (REE) in a variety of minerals and bulk materials of hydrothermal greisen and vein mineralization in Paleoproterozoic monzodiorite to granodiorite related to the intrusion of Mesoproterozoic alkali- and fluorine-rich granite. The greisen consists of coarse-grained quartz, muscovite, and fluorite, whereas the veins mainly contain quartz, calcite, epidote, chlorite, and fluorite in order of abundance. A temporal and thus genetic link between the granite and the greisen/veins is established via high spatial resolution in situ Rb-Sr dating, supported by several other isotopic signatures (δ34S, 87Sr/86Sr, δ18O, and δ13C). Fluid-inclusion microthermometry reveals that multiple pulses of moderately to highly saline aqueous to carbonic solutions caused greisenization and vein formation at temperatures above 200–250°C and up to 430°C at the early hydrothermal stage in the veins. Low calculated ∑REE concentration for bulk vein (15 ppm) compared to greisen (75 ppm), country rocks (173–224 ppm), and the intruding granite (320 ppm) points to overall low REE levels in the hydrothermal fluids emanating from the granite. This is explained by efficient REE retention in the granite via incorporation in accessory phosphates, zircon, and fluorite and unfavorable conditions for REE partitioning in fluids at the magmatic and early hydrothermal stages. A noteworthy feature is substantial heavy REE (HREE) enrichment of calcite in the vein system, in contrast to the relatively flat patterns of greisen calcite. The REE fractionation of the vein calcite is explained mainly by fractional crystallization, where the initially precipitated epidote in the veins preferentially incorporates most of the light REE (LREE) pool, leaving a residual fluid enriched in the HREE from which calcite precipitated. Fluorite occurs throughout the system and displays decreasing REE concentrations from granite towards greisen and veins and different fractionation patterns among all these three materials. Taken together, these features confirm efficient REE retention in the early stages of the system and minor control of the REE uptake by mineral-specific partitioning. REE-fractionation patterns and fluid-inclusion data suggest that chloride complexation dominated REE transport during greisenization, whereas carbonate complexation contributed to the HREE enrichment in vein calcite.
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Liverton, T., and D. H. M. Alderton. "Plutonic rocks of the Thirtymile Range, Dorsey Terrane: ultrafractionated tin granites in the Yukon." Canadian Journal of Earth Sciences 31, no. 10 (October 1, 1994): 1557–68. http://dx.doi.org/10.1139/e94-138.
Повний текст джерелаАнотація:
A study of granitoid plutons of the western part of the Dorsey terrane in the southern Yukon has shown that two distinct suites exist on the basis of their mineralogy, chemistry, and metallogeny. Hornblende-rich granodiorite and granodiorite with minor gabbro and diorite form the NW and SW Thirtymile stocks, respectively. These are similar to many calc-alkaline Cordilleran intrusions and are not associated with any mineralization. The Thirtymile and Ork stocks are composed of highly evolved granite that contains hornblende only in the least evolved, volumetrically minor, lithofacies. Biotite granite forms the bulk of the Thirtymile stock, and it displays major- and trace-element trends that correspond to those shown by the adjacent Hake and Seagull batholiths. These latter granites are interpreted to be one magmatic suite, which is associated with F–B-rich skarn tin–tungsten mineralization. The most evolved lithofacies of the Ork and Thirtymile stocks is an alkali-feldspar-rich zinnwaldite–topaz–fluorite leucogranite that has an extremely evolved chemistry (differentiation index up to 99.4 and Rb/Sr ratio > 3000), with trace-element contents normally associated with "A-type" granites. This is interpreted to be the result of ultrafractionation of a halogen-rich residual granitic melt.
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Wei, Chun-Sheng. "207Pb–208Pb decoupling of alkali feldspar from a late Mesozoic A-type granite in eastern China." Mineralogy and Petrology 94, no. 3-4 (May 27, 2008): 209–23. http://dx.doi.org/10.1007/s00710-008-0011-8.
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Kim, Choon-Sik, and Gun-Soo Kim. "Petrogenesis of the early Tertiary A-type Namsan alkali granite in the Kyongsang Basin, Korea." Geosciences Journal 1, no. 2 (June 1997): 99–107. http://dx.doi.org/10.1007/bf02910481.
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Vetrov, Evgeny V., Evgeny A. Pikhutin, and Natalia I. Vetrova. "Geochemical Constraints on Petrogenesis and Tectonics of the Middle Devonian Granitic and Coeval Mafic Magmatism from the Tannuola Terrane (Northern Central Asian Orogenic Belt)." Minerals 12, no. 10 (October 12, 2022): 1282. http://dx.doi.org/10.3390/min12101282.
Повний текст джерелаАнотація:
The Tannuola terrane, located in the northern Central Asian Orogenic Belt, comprises magmatic rocks, attributed to island-arc and collisional settings during the Early Cambrian to the Late Ordovician. However, zircon U-Pb age, geochemical, and Sr-Nd isotopic constraints demonstrate that there was a short episode of peralkaline A-type granite magmatism in the northeast border area of the Tannuola terrane. The obtained zircon U-Pb age of 387.7 ± 3.3 Ma indicates emplacement of the peralkaline A-type granitic rocks in the Middle Devonian (Eifelian–Givetian period boundary). Petrologically, these rocks are mainly composed of riebeckite granites and aplites, which are approximately synchronous with augite-rich dolerites. The granitic rocks are ferroan and calc-alkalic to alkali-calcic in composition. They are characterized by a high content of SiO2, total alkali, Zr, and total REE. Significant depletion of Ba, Sr, P, Ti, and Eu indicates fractionation of plagioclase and/or K-feldspar. The values of εNd(t) in riebeckite granites range from +5.61 to +6.55, and the calculated two-stage model age ranges between 610 and 520 Ma. Coeval dolerites on the chondrite-normalized REE pattern, (Th/Yb)pm–(Nb/Yb)pm, and Th/Yb–Nb/Yb diagrams show compositional affinity between E-MORB and OIB. They are rich in incompatible elements with high HFSE/LREE ratios (Nb/La > 1), indicating that the primary magma originated from the lithospheric mantle metasomatized by asthenosphere-derived melt. Based on these geochemical characteristics, it can be reasonably inferred that the peralkaline A-type granitic rocks, and the coeval mafic rocks, are anorogenic and were emplaced in an extensional tectonic environment despite slightly higher Y/Nb values, which might be caused by a crustal contamination effect. The geochemistry of mafic rocks suggests that the magma originated from the enriched mantle sources. The results of a zircon-saturation thermometer show high initial magma temperatures between 923 and 1184 °C, with an average of 1030 °C, indicating this rock association might be related to a mantle plume beneath the northern Central Asian Orogenic Belt.
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Koesmawardani, W. T., A. Rudyawan, and B. Sapiie. "Granitic Basement Fracture Analogue by Using Integrated Digital Outcrop Model and Fieldwork, at Muaro Silokek, West Sumatra." IOP Conference Series: Earth and Environmental Science 1104, no. 1 (November 1, 2022): 012041. http://dx.doi.org/10.1088/1755-1315/1104/1/012041.
Повний текст джерелаАнотація:
Abstract The study aims to determine fracture characteristics such as orientation, fracture attributes, fracture density distribution, and mineral composition of quartz and feldspar. The study used photogrammetry data to know the distribution and geometry of macro-scale fracture, linear scanline and windows scan data to understand the characteristics of mesoscale fracture attribute, and thin section rocks data from oriented samples to determine petrographic analysis and micro-scale fracture. After analyzing each of these data, analog basement fractured reservoir modeling could be built from integrating the data and modeling parameters based on available fieldwork data. The fault in the research area is represented as a Riedel shear with the orientation direction of NNW-SSE, NE-SW, and ENE-WSW. The fracture density is influenced by its position on the fault and increases in the fault damage zone. The granite type in the study area was divided into three types, namely alkali feldspar granite, syeno granite, and monzogranite. Each granite type has a different response to fractures and shows that the fracture density will increase with the greater quartz and k-feldspar in the fault damage zone. Fracture permeability values are strongly influenced by the geometry of fracture position, fracture aperture, and fracture length. This study produced a new perspective for fractured basement reservoirs, especially for granitic rocks, generally the primary target for basement fracture reservoirs along Sumatra.
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Oyunbat, Sanjsuren. "Petrology and mineralogy of the Ulaan Del Zr-Nb-REE deposit, Lake Zone, Western Mongolia." Mongolian Geoscientist 50 (June 2, 2020): 45–62. http://dx.doi.org/10.5564/mgs.v50i0.1328.
Повний текст джерелаАнотація:
The Ulaan Del deposit is located in the Lake Zone, Western Mongolia. In the area, middle-late Devonian alkali dykes of the Khalzan Complex are hosted in the middle-late Cambrian granodiorite-tonalite of the Togthohiinshil Complex. The alkali dykes of the Khalzan complex comprise medium- to fine-grained syenite, microsyenite, syenite-porphyry and trachyte, trachyrhyolite, and trachyandesite. The dykes are replaced to silica, sericite, albite, fluorite and are brecciated. They crosscut by quartz and quartz-carbonate veinlets. The dykes contain zircon (>0.19% Zr) with a total of rare earth elements oxides >0.1%. The host rocks of the Togtokhiinshil complex are mid-K, metaluminous, I- type granite, depleted in HFSE. Based on geochemical and mineralogical data, economic REE mineralization is concentrated in syenite and syenite porphyry of calc-alkaline high K to shoshonite series of A- type granite, emplaced at within a plate setting. Syenite dykes are enriched in REE. Ore minerals are zircon, apatite, sphene, monazite, xenotime, synchysite, parisite, fluorite and REE complex minerals, pyrite, rutile and limonite. Magmatic, metasomatic and hydrothermal processes significantly contributed to the formation of Zr, Nb, REE and Y mineralization at the Ulaan Del deposit.
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Li, Hong Kui, Yi Fan Li, Lu Yi Li, Chuan Yuan Zhuo, Ke Geng, and Tai Tao Liang. "Discussion about Gold Ores Mineralization of Collision-Type Orogeny in the East of Shandong." Applied Mechanics and Materials 353-356 (August 2013): 1249–62. http://dx.doi.org/10.4028/www.scientific.net/amm.353-356.1249.
Повний текст джерелаАнотація:
The mineralization of collision orogeny is an important part of continental dynamics. For the process of continental dynamics of Shandong, adoption of tectonic facies mapping is main carrier and specific expression form to these researches such as divergence of continental mass, convergence, collision and orogeny. Shandong tectonic facies mapping of 1:500000 scale worked out by author shows that there are two very important events of collision orogeny in Mesozoic this areaIndochina and Yanshan collision orogeny. The Indochina orogeny is mainly characterized as subduction from Yangtze to North China Plates, based on which Sulu high-ultra high pressure zone of metamorphism, syn-orogenic granite and post-orogenic high alkali sinaite are formed. Continental dynamics environment of the Yanshan orogeny derives from transformation from Central Asia-Tethys tectonic domain to marginal-Pacific tectonic domain and subduction of Pacific plates, and it appears as three orogenys and three stretching in the east of Shandong. Magmatic rocks of orogeny related with gold ores can be divided into four combinations as follows: Linglong gneissic granite of the early orogenic period (J3), Guojialing granodiorite-granite of the middle orogenic period (K1), Weideshan diorite-granodiorite-granite of the late orogenic period (K1) and A-type Laoshan geode parlkaline alkali granitesyenogranite of the post orogenic period. For combination of Guojialing granodiorite-granite of the middle orogenic period, SHRIMP U-Pb ages concentrate in 130~126Ma, which are closely related with emplacement of gold ores, and formed ages of gold ores this area concentrate in 115~120Ma, which basically stand for the age of main mineralization period. Polymetallic ores are related with combination of Weideshan diorite-granodiorite-granite of the late orogenic period, and it was also the superimposed mineralization period in the east of Shandong. Tectonics-magma activities and gold ores mineralization are controlled by interaction of three tectonic domains that are tethys, Paleo-Asian Ocean and Pacific. Dynamics background of gold ores this area is transition of tectonic system and lithospheric thinning in Mesozoic, which is related with collision of North China and Yangtze Plates and subduction of Pacific Plates.
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Zhang, Xiang-xin, Yong-feng Gao, and Shi-he Lei. "Petrogenesis of early Permian granitic dykes in the Wulanhuduge area, central Inner Mongolia, North China: constraints from geochronology, geochemistry, and Sr–Nd–Pb isotopes." Canadian Journal of Earth Sciences 57, no. 6 (June 2020): 747–64. http://dx.doi.org/10.1139/cjes-2019-0112.
Повний текст джерелаАнотація:
Early Permian granitic dykes are well developed in the Wulanhuduge area, central Inner Mongolia, North China. In this study, we investigated the petrography, geochronology, and whole-rock geochemistry of the granite porphyry dykes in the Wulanhuduge area. Laser ablation inductively coupled plasma mass spectrometry zircon U–Pb dating yielded 206Pb/238U ages of 289–288 Ma for these granite porphyry dykes, indicating they were emplaced in the early Permian. These granitic dykes are high in silica and alkali contents, and low in total Fe2O3, MgO, CaO, and P2O5 contents. They show enrichment in large-ion lithophile elements such as Rb, Ba, Th, U and K, and depletion in high field strength elements such as Nb, Ta, and Ti, typical of arc-like magma. Their Sr–Nd–Pb isotopic compositions indicate low initial 87Sr/86Sr ratios (0.70306–0.70564), positive εNd(t) values (+3.3 to +3.9), and radiogenic Pb isotopes with (206Pb/204Pb)i of 18.080–18.616, (207Pb/204Pb)i of 15.497–15.555, and (208Pb/204Pb)i of 37.713–38.175. These geochemical data, along with petrological characteristics, suggest that they belong to high K calc-alkaline I-type granites and were generated by the partial melting of the mafic rocks from the pre-existing juvenile arc crust in a post-subduction extensional setting caused by slab breakoff. Therefore, the emplacement of these granite porphyry dykes in the Wulanhuduge area may represent the end stage of the subduction–accretion process in central Inner Mongolia.
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Gallagher, V., P. J. O'Connor, and M. Aftalion. "Intra-Ordovician deformation in southeast Ireland: evidence from the geological setting, geochemical affinities and U—Pb zircon age of the Croghan Kinshelagh granite." Geological Magazine 131, no. 5 (September 1994): 669–84. http://dx.doi.org/10.1017/s0016756800012450.
Повний текст джерелаАнотація:
AbstractThe Croghan Kinshelagh alkali granite intrudes a cleaved volcano-sedimentary sequenceon the border of counties Wicklow and Wexford in southeast Ireland. U-Pb dating of zircons fromthe granite indicate a mid-Caradoc emplacement age of 454 ± 1 Ma. The Duncannon Group hostrocks form the southwestern end of the Avoca Volcanic Belt, a Mid-Ordovician (Caradoc) sequenceof acid and intermediate lavas and volcaniclastics. Dolerite dykes intrude the granite; elsewhere in theregion dolerites are generally associated with volcanic rocks. The main, Dl deformation within theDuncannon Group rocks is manifest as a steep Dl cleavage generally regarded as a product of LateCaledonian regional deformation in southeast Ireland. The Croghan Kinshelagh granite showsstrong geochemical coherence with subalkaline varieties of the Caradoc volcanic rocks; relativelyhigh Th, Y, Nb and REE contents set it apart from any other known granite type in southeastIreland. Together with the geochemical evidence, the age determination of 454 Ma indicates that theCroghan Kinshelagh granite was generated and emplaced during Ordovician volcanism in southeastIreland. Volcanism was closely followed by penetrative deformation and emplacement of the granite.The intra-Ordovician deformation may have been a consequence of closure of the Iapetus Ocean ormore localized events such as accretion on the hanging wall of the subduction zone. The age of theCroghan Kinshelagh granite provides an important datum for Ordovician volcanism and subductionin southeast Ireland.
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RAJESH, H. "Petrogenesis of two granites from the Nilgiri and Madurai blocks, southwestern India: Implications for charnockite–calc-alkaline granite and charnockite–alkali (A-type) granite link in high-grade terrains." Precambrian Research 162, no. 1-2 (April 5, 2008): 180–97. http://dx.doi.org/10.1016/j.precamres.2007.07.023.
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Escarraga, E. A., S. M. Barr, J. B. Murphy, and M. A. Hamilton. "Ordovician A-type plutons in the Antigonish Highlands, Nova Scotia1This article is one of a series of papers published in CJES Special Issue: In honour of Ward Neale on the theme of Appalachian and Grenvillian geology." Canadian Journal of Earth Sciences 49, no. 1 (January 2012): 329–45. http://dx.doi.org/10.1139/e11-026.
Повний текст джерелаАнотація:
Previously unrecognized A-type granitoid and gabbroic rocks cover an area of ∼100 km2 in the central Antigonish Highlands in Avalonian northern mainland Nova Scotia. The granitoid rocks in this suite occur, together with minor gabbro, in separate mappable bodies named the Brora Lake, Haggarts Lake, West Barneys River, McGraths Mountain, and Leadbetter Road plutons and are the focus of this study. They are mainly alkali feldspar granite and quartz syenite with varied texture and modal mineralogy. Close spatial association, gradational contact relations, and magma-mingling relationships suggest that all of these rocks, including the gabbro, are coeval. Hence a U–Pb (zircon) age of 469.4 +/– 0.5 Ma obtained for a quartz syenite sample from the Brora Lake pluton is interpreted to indicate a Middle Ordovician age for all of these granitoid and gabbroic rocks. Most granitic and quartz syenitic samples have hypersolvus texture, characterized by strongly perthitic alkali feldspar, and some also contain interstitial granophyre, both features indicative of shallow emplacement. Mafic minerals include iron-rich calcic and calcic–sodic amphibole, hedenbergite, and in some samples fayalite. Most of the rocks have high concentrations of K, Na, P, Ti, and Fe and are alkalic, with agpaitic indices as high as 0.98. Discrimination diagrams indicate that they are A-type granitoid rocks formed in a within-plate extensional setting. Age correlatives of these A-type granitoid and gabbroic rocks are not yet known elsewhere in Avalonia. The available data suggest that this ca. 470 Ma magmatism occurred while Avalonia was a separate microcontinent in the Rheic Ocean.
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Zhao, Yan, Wenhao Ao, Hong Zhang, Qian Wang, Mingguo Zhai, and Yong Sun. "Latest Paleoproterozoic (ca. 1.8–1.6 Ga) extensional tectonic setting in the Dunhuang terrane, NW China: Evidence from geochronological and geochemical investigations on A-type granite and metamafic rock." Lithosphere 11, no. 6 (October 17, 2019): 834–54. http://dx.doi.org/10.1130/l1114.1.
Повний текст джерелаАнотація:
Abstract Latest Paleoproterozoic (ca. 1.8–1.6 Ga) magmatic rocks outcrop in the Dunhuang terrane, represented by A-type granites and mafic (basaltic) rocks that have metamorphosed into amphibolites. The A-type granites, emplaced at ca. 1.79–1.77 Ga, are geochemically characterized by high Na2O + K2O, Fe2O3T, Zr, Nb, and Ce contents, as well as high Fe2O3T/(Fe2O3T + MgO) and Ga/Al ratios. Furthermore, they have Nb/Ta, Y/Nb, Rb/Nb, and Sc/Nb ratios of 12.10–15.56, 1.45–1.79, 3.52–6.51, and 0.11–0.19, respectively, showing affinity to A2-type granite. The A-type granites have negative εNd(t) values (−5.4 to −4.8) with Neoarchean depleted mantle (TDM2) ages (2591–2494 Ma), corresponding to coupling between εHf(t) values (−4.85 to -0.92) and TDM2 ages (2817–2556 Ma) of zircons. Therefore, the A-type granite pluton was mostly generated by partial melting of Neoarchean tonalitic to granodioritic basement rocks of the Dunhuang Complex in a postcollisional tectonic setting following a late Paleoproterozoic continent-continent collisional event. The metamafic rocks have a protolith age of 1605 ± 45 Ma and metamorphic age of 317 ± 20 Ma, indicating a Paleozoic tectonic event. The metamafic rock samples are geochemically characterized by relatively high alkali (Na2O + K2O = 4.39–4.81 wt%) contents and low Nb/Y (0.63–0.66) ratios, and they show steep rare earth element (REE) patterns with light REE enrichment and insignificant Eu anomalies and Nb-Ta, Zr-Hf, and Ti anomalies, resembling subalkaline oceanic-island basalt affinity. They have positive εNd(t) values (+0.8 to +1.8) close to the chondrite evolutionary line and variable εHf(t) values (-1.09 to +9.06) of zircons. Hence, the protolith of the metamafic rocks may have been produced by magma mixing processes between a depleted mantle source and a metasomatized lithospheric mantle source during the initial rifting stage in an extensional setting, completing the formation of the Precambrian Dunhuang Complex. Considering the ca. 1.85–1.80 Ga regional metamorphism in the Dunhuang terrane, the latest Paleoproterozoic (ca. 1.8–1.6 Ga) A2-type granitic magmatism and mafic magmatism documented the postorogenic to initial rifting processes following the global-scale late Paleoproterozoic collisional event, which is comparable with ca. 1.80–1.67 Ga postcollisional and ca. 1.60–1.53 Ga anorogenic magmatism in the North China craton, but different from that of the Tarim craton.
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Hoang, Nguyen Kim, та Lam Van Phuong. "Petrographical, petrochemical characteristics of Hòn Rồng massif granitoids, Cam Ranh, Khánh Hòa". Science and Technology Development Journal - Natural Sciences 3, № 3 (13 лютого 2020): 195–212. http://dx.doi.org/10.32508/stdjns.v3i3.641.
Повний текст джерелаАнотація:
Hòn Rồng massif granitoid has a high mountainous terrain, with an absolute height of 728 m, relatively equal, slightly extended in the Northwest-Southeast direction, occupying an area of about 29 km2. Petrographical composition is mainly medium - grained biotite granite (phase 2), minor is fine- grained biotite granite (phase 3), vein rocks are aplite granite and pegmatite and a little of xenolith of granodiorite in medium - grained biotite granite. Medium-grained biotite granite: major mineral composition (%): plagioclase (oligoclase) 25–35, quartz 30, orthoclas 25, biotite 5 - 8 and few hornblend; fine-grained granite (%): plagioclase (oligoclase) 30 - 35; quartz 30 - 35; feldspar kali (orthoclase, and microclin) 30, biotite 3 - 5; accessory mineral is zircon, orthite, apatite, sphen, and very little ore minerals (about 2%); epimagmatic minerals including: chlorite, epidot, kaolinite, sericite, carbonate, sausorite-replaced association. Rocks are altered alkalization strongly (albitization and microlinization), and minor are chloritization, epidotization and sericitization. Averaged chemical compositions (%)SiO2: 69.07–72.07; total alkali(K2O+Na2O) 7.35–7.96. Ratio of K2O/Na2O 1.04, low TiO2 (0.24–0.37). Ratios of A/CNK 1.02–1.09, Rb/Sr: 0.27–1.62; Ba/Sr: 1.82–2.56, Ba/Rb: 1.58–7.13; K/Rb: 0.42–0.62; Ca/Sr: 0.21–0.47; the value of Eu anomalies is low. Granite belongs to calc-alkaline, aluminum content is from medium to high; K-Na alkaline series, I-granite type. Granitoid had been formed in plutonic - volcanic arc of subduction-zone. Compared with the granitoid formations in South Vietnam territory, Hòn Rồng massif granitoid belongs to phase 2 (main) and phase 3 (minor) of Đèo Cả complex with late Kreta age.
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Ondrejka, Martin, Pavel Uher, Marián Putiš, Milan Kohút, Igor Broska, Alexander Larionov, Ana-Voica Bojar, and Tomáš Sobocký. "Permian A-type granites of the Western Carpathians and Transdanubian regions: products of the Pangea supercontinent breakup." International Journal of Earth Sciences 110, no. 6 (June 16, 2021): 2133–55. http://dx.doi.org/10.1007/s00531-021-02064-2.
Повний текст джерелаАнотація:
AbstractPermian biotite leucogranites to granite porphyries and rhyolites form small intrusions in several Alpine tectonic units in the Western Carpathians and the Pannonian region (Slovakia and Hungary). Their A-type signature is inferred from main- and trace-element geochemistry, with high K, Rb, Y, REE, Zr, Th, Nb, Fe/Mg and Ga/Al, low Al, Mg, Ca, P, Sr, V and strong negative Eu-anomaly. This geochemical signature is further supported by the mineralogy comprising local hypersolvus alkali feldspars, annitic biotite and the presence and composition of HFSE accessory minerals. The δ18O values measured for zircon (mean value 8.3 ‰ ± 0.36) may be explained by the melting of igneous material of crustal origin and/or mantle basalts which interacted with low-temperature fluids. The in-situ SHRIMP U–Pb isotope dating of zircon from the granites highlights two different periods of magmatic crystallisation and pluton emplacement: the older 281 ± 3 Ma Cisuralian age in the southern part, Velence Hills in the Pannonian region (Transdanubian Unit) and younger Guadalupian ages in the northern part, the West-Carpathian area: 262 ± 4 Ma (Turčok, Gemeric Unit), 267 ± 2 Ma (Hrončok, Veporic Unit) and 264 ± 3 Ma (Upohlav, granitic pebbles in Cretaceous conglomerates of the Pieniny Klippen Belt). The ~ 280 to 260-Ma interval is simultaneous with post-orogenic or anorogenic, rift-related and mainly alkaline (A-type) magmatism on the broader European scale. Our study documents a close relationship between the Permian continental rifting and the Neotethyan Meliatic oceanic basin opening in the Middle Triassic. The A-type granites originated from the partial melting of the ancient lower crustal quartzo-feldspatic rocks with the possible contribution of meta-basic material from the mantle in an extensional tectonic regime consistent with disintegration of the Pangea supercontinent during the Permian–Triassic period.
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Dao, Yan, Feng Li, and Wang Rong. "Geochemistry Characteristics of Cenozioc Alkaline-Rich Intrusions and its Forming Tectonic Setting in Jiudingshan Porphyry Cu-Mo Polymetallic Deposit, West Yunnan." Advanced Materials Research 868 (December 2013): 125–28. http://dx.doi.org/10.4028/www.scientific.net/amr.868.125.
Повний текст джерелаАнотація:
Geochemistry Characteristics of iudingshan Porphyry Cu-Mo Polymetallic Deposit are analyzed in the presented work. The Jiudingshan alkaline-rich porphyry is formed in Cenozoic (from 52 Ma to 29 Ma), being characterized by high potassium, rich alkali and high alumina can be attributed to high K calc alkaline series and shoshonite series, which showing LREE enrichment, HREE depletion, weak negative Eu anomaly (δEu=0.72~1.02, av.=0.86) close to the crust-mantle granite type (δEu=0.83) and mainly is formed in a post-collisional intraplate tectonic setting.
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Archibald, D. B., S. M. Barr, J. B. Murphy, C. E. White, T. G. MacHattie, E. A. Escarraga, M. A. Hamilton, and C. R. M. McFarlane. "Field relationships, petrology, age, and tectonic setting of the Late Cambrian–Ordovician West Barneys River Plutonic Suite, southern Antigonish Highlands, Nova Scotia, Canada." Canadian Journal of Earth Sciences 50, no. 7 (July 2013): 727–45. http://dx.doi.org/10.1139/cjes-2012-0158.
Повний текст джерелаАнотація:
The West Barneys River Plutonic Suite consists of gabbro, syenite-monzonite, alkali-feldspar syenite to quartz alkali-feldspar syenite, and alkali-feldspar granite outcropping in an area of ∼100 km2 in the southern Antigonish Highlands. Magma mixing and mingling textures indicate a comagmatic relationship between some of the mafic and intermediate–felsic lithologies. However, nine U–Pb (zircon) ages, three by thermal ionization mass spectrometry (TIMS) and six by laser-ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS), from the West Barneys River suite and the lithologically similar Cape Porcupine Complex located 60 km to the east range from ca. 495 to 460 Ma, indicating that emplacement occurred over a significant span of time. Intermediate to felsic rocks consist mainly of perthitic K-feldspar and variable amounts of quartz; interstitial granophyre is present in some samples, consistent with shallow emplacement. Mafic phases are Fe-rich amphibole and clinopyroxene, and in some units, fayalite. Intermediate and felsic samples have chemical characteristics of within-plate ferroan A-type granitoid rocks. Gabbroic rocks consist of plagioclase (oligoclase–labradorite) and augite/diopside with less abundant orthopyroxene, olivine, biotite, and ilmenite/magnetite. Their chemical compositions are transitional from tholeiitic to alkalic and characteristic of continental within-plate mafic rocks. The εNd values are similar in gabbroic, syenitic, and granitic samples, ranging between 0.9 and 4.9, consistent with a co-genetic origin for the mafic and intermediate/felsic components of the suite, and derivation from Avalonian subcontinental lithospheric mantle in an extensional environment.
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Tao, Lu, Fa-Bin Pan, Rong Liu, Chong Jin, Bao-Jian Jia, and Xiaobo He. "Petrogenesis of the Cretaceous granitoids in Zhejiang, northeast South China Block and their implications for episodic retreat and roll-back of the Paleo-Pacific Plate." GSA Bulletin 132, no. 7-8 (November 20, 2019): 1514–36. http://dx.doi.org/10.1130/b35426.1.
Повний текст джерелаАнотація:
Abstract Two Cretaceous granitoid belts (i.e., the northwest and southeast belts) have been identified in Zhejiang, northeast South China Block. In this study, seven granitoid plutons from both the two belts were collected for zircon U-Pb dating, whole-rock geochemistry, Sr-Nd isotope, and zircon Hf isotope analyses. Chronologically, the Longyou (132 Ma), Sucun (136 Ma), Shanghekou (131 Ma), and Huangshitan (ca. 126 Ma) plutons from the northwest belt display older magma crystallization age than those of the Xiaoxiong (100 Ma), Zhujiajian (108 Ma), and Qingbang island (108 Ma) plutons from the southeast belt. The Sucun quartz monzonite and the Longyou, Shanghekou, Zhujiajian, and Qingbang island granites therein are fractionated I-type granites (i.e., partial melting of meta-igneous rocks) with relatively moderate-low Zr saturation temperature (723–823 °C) and pronouncedly evolved Nd and Hf isotopic compositions (εNd(t) = –8.17 to –5.67 and εHf(t) = –15.07 to –5.67), indicating that they are derivatives of ancient crustal melt-dominated magmas. The Huangshitan granite shows A-type granitic (i.e., granites that are alkaline and anhydrous and from anorogenic setting) features with high Ga/Al (3.47–5.58), rare earth element (REE) content (271–402 ppm), and Zr saturation temperature (781–889 °C). It holds less enriched Nd and Hf isotopic compositions (εNd(t) = –4.13 to –3.60 and εHf(t) = –5.90 to –2.16) and is attributed to partial melting of mature crustal materials with minor basaltic magma incorporation. The Xiaoxiong (quartz) syenitic porphyry is characterized by moderate SiO2 content (60.68–69.92 wt%), high alkali (9.03–11.66 wt%) and REE contents with fractionated REE pattern [(La/Yb)N = 13.8–26.1]. Its relatively depleted Nd and Hf isotopic compositions (εNd(t) = –3.67 to –3.42 and εHf(t) = –5.76 to –2.25) imply that it could be a derivative of basaltic magma from K-rich metasomatized mantle. Available geochronological data indicate that there were two episodic magmatic pulses at ca. 140–120 Ma and ca. 110–85 Ma associated with the Paleo-Pacific Plate underthrusting beneath the northeast South China Block. Here we put forward an episodic slab retreat and roll-back model to account for generation of these magmatic rocks. Firstly, the subducting Paleo-Pacific slab roll-back initiated at ca. 140 Ma and reached climax at ca. 130–120 Ma, which led to formation of the Longyou, Sucun, and Shanghekou I-type granites and the Huangshitan A-type granite, respectively. Subsequently, a flat slab subduction stage occurred with eastward trench retreat, causing a period of magmatic quiescence from ca. 120 to 110 Ma. The following second slab roll-back started at ca. 110 Ma and reached climax at ca. 100 Ma, giving rise to the earlier Zhujiajian and Qingbang island I-type granites and the later Xiaoxiong (quartz) syenitic porphyry.
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Li, Shan-Shan, Wei Zeng, Huai-Feng Zhang, Lu Wang, Espine Tuyakula Shivute, and Kun-Feng Qiu. "Fractional Crystallization and Partial Melting of the Paleoproterozoic Gneisses and Pegmatite in the Giant Husab Uranium Deposit, Namibia." Minerals 12, no. 3 (March 19, 2022): 379. http://dx.doi.org/10.3390/min12030379.
Повний текст джерелаАнотація:
The giant Husab uranium deposit is located in the Paleoproterozoic Abbabis Metamorphic Complex, which was highly partially melted and metamorphosed during the Damara Orogenic Event. The timing of magma emplacement has been investigated; however, the petrogenesis is unclear. Here we reported petrology, geochemistry, and monazite U-Pb age data from biotite granitic gneisses, syeno-granite, syeno-granitic pegmatites, syeno-granitic gneiss, granitic syenite and biotite quartz monzonites of this complex. Geochemical data suggest that these Paleoproterozoic rocks show high SiO2, Al2O3, and K2O, moderate Na2O, low CaO and Fe2O3, and MgO abundance. The alkali-calcic to alkalic, peraluminous, low Fe-number, depletion in HFSE (Nb-Ta, Ti) and enrichment in LILE (e.g., Rb, Pb) characteristic correspond with I- and S-type granite. Major and trace elements are strongly fractionated with the increase of SiO2, which, together with strongly fractionated LREE patterns and high (La/Yb)N ratios of the biotite granitic gneiss and syeno-granitic gneiss, suggest that the magma was highly evolved and fractionated. Monazite U-Pb data show three metamorphic age groups of 581–535 Ma, 531–522 Ma and 518–484 Ma. The increasing trend of La/Sm and La/Yb with the increase of La, suggest these rocks most likely experienced a partial melting process during the late Palaeozoic metamorphism. We, thus, propose a fractional crystallization model for the generation of the Paleoproterozoic Abbabis Metamorphic Complex basement rock, which was metamorphosed and melted during the late Palaeozoic Damara Orogenic Event and provided the magma sources for primary uranium mineralization.
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Abdel-Rahman, Abdel-Fattah M. "Chlorites in a spectrum of igneous rocks: mineral chemistry and paragenesis." Mineralogical Magazine 59, no. 394 (March 1995): 129–41. http://dx.doi.org/10.1180/minmag.1995.59.394.13.
Повний текст джерелаАнотація:
AbstractThe chlorite data presented are from four igneous complexes covering the compositional spectrum of igneous rocks (gabbro to granite) of orogenic and anorogenic settings. The four igneous complexes are; early orogenic gabbro-diorite-tonalite (D-T) suite, late orogenic granodiorite-adamellite (G-A) suite (both are calc-alkaline suites), high-alumina trondhjemite (TR), and anorogenic peralkaline granite (PGR).Chlorites in these igneous rocks show characteristic compositional fields. The Mg vs Fe plot provides the best discriminant, as data points define three compositionally different groups. Phases in the PGR are Fe-rich, siliceous, interlayered chlorite-smectite (Fe/Mg = 8.6), and differ significantly from those in the calc-alkaline D-T and G-A rocks which are Mg-rich chlorites (Fe/Mg = 0.6–0.8). The X-ray diffraction data for the peralkaline granite samples show superlattice reflections at approximately 31 Å (air-dried) and 34 Å (ethylene glycollated), thus suggesting the presence of an expandable (smectite-like) component in this interlayered (chlorite-smectite) phyllosilicate phase. Chlorites in the peraluminous TR rocks contain Fe/Mg values intermediate between the other two types (Fe/Mg = 1.3). Tetrahedral Al (AlZ) values are remarkably low (0–0.5) in phyllosilicates in the PGR, but vary from 1.9–2.5 in chlorites from the other suites. Yet, these chlorite groups with their generally low AlZ values are distinct from the more stable (type IIb) metamorphic chlorites. Sedimentary chlorites are somewhat similar, in their low AlZ values and metastable structural type, to chlorites in igneous rocks.In the calc-alkaline rocks, chlorite may have been formed at the expense of both biotite [biotite + 3M + 3H2O = chlorite + A], and calcic amphibole [2 Ca-amphibole + 6H2O + 5O2 + 1.8Al = 1 chlorite + 8SiO2 + A], where M = Fe, Mg, Al, and A = K, Na, Ca. The alteration of alkali amphibole in the peralkaline rocks may have produced interlayered chlorite-smectite via this reaction; [1 Na-amphibole + 7H2O + 2.5O2 + M = 1 chlorite-smectite + A]. The presence of such interlayered chlorite-smectite which typically form at low T (150–200°C) suggests that the region was not affected by any major reheating events, which is consistent with the nature of the feldspars.