Добірка наукової літератури з теми "5-chloromethyl furfural"

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Статті в журналах з теми "5-chloromethyl furfural"

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Bizet, Boris, Christian H. Hornung, Thomas M. Kohl, and John Tsanaktsidis. "Synthesis of Imines and Amines from Furfurals Using Continuous Flow Processing." Australian Journal of Chemistry 70, no. 10 (2017): 1069. http://dx.doi.org/10.1071/ch17036.

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Анотація:
A simple procedure for the condensation of the bio-derived furfurals, 5-(methyl)furfural (MF) and 5-(chloromethyl)furfural (CMF), with primary amines is described herein. The experiments were conducted in both batch and flow conditions, with reaction times as short as 60 s. Moderately high temperatures were demonstrated to be suitable for the condensation reaction of MF in a few minutes whereas milder conditions and longer reaction times were necessary for CMF. Under these conditions the amine did not react with the methyl-chlorine group, leaving a very reactive site after condensation.
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Kohl, T. M., B. Bizet, P. Kevan, C. Sellwood, J. Tsanaktsidis, and C. H. Hornung. "Efficient synthesis of 5-(chloromethyl)furfural (CMF) from high fructose corn syrup (HFCS) using continuous flow processing." Reaction Chemistry & Engineering 2, no. 4 (2017): 541–49. http://dx.doi.org/10.1039/c7re00039a.

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Zuo, Miao, Zheng Li, Yetao Jiang, Xing Tang, Xianhai Zeng, Yong Sun, and Lu Lin. "Correction: Green catalytic conversion of bio-based sugars to 5-chloromethyl furfural in deep eutectic solvent, catalyzed by metal chlorides." RSC Advances 6, no. 40 (2016): 33492. http://dx.doi.org/10.1039/c6ra90032a.

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Mascal, Mark, and Saikat Dutta. "Synthesis of ranitidine (Zantac) from cellulose-derived 5-(chloromethyl)furfural." Green Chemistry 13, no. 11 (2011): 3101. http://dx.doi.org/10.1039/c1gc15537g.

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Dutta, Saikat, and Mark Mascal. "Novel Pathways to 2,5-Dimethylfuran via Biomass-Derived 5-(Chloromethyl)furfural." ChemSusChem 7, no. 11 (September 5, 2014): 3028–30. http://dx.doi.org/10.1002/cssc.201402702.

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Mascal, Mark, and Edward B Nikitin. "Dramatic Advancements in the Saccharide to 5-(Chloromethyl)furfural Conversion Reaction." ChemSusChem 2, no. 9 (September 21, 2009): 859–61. http://dx.doi.org/10.1002/cssc.200900136.

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Bhat, Navya Subray, Nivedha Vinod, Sharath Bandibairanahalli Onkarappa, and Saikat Dutta. "Hydrochloric acid-catalyzed coproduction of furfural and 5-(chloromethyl)furfural assisted by a phase transfer catalyst." Carbohydrate Research 496 (October 2020): 108105. http://dx.doi.org/10.1016/j.carres.2020.108105.

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Dutta, Saikat, Linglin Wu, and Mark Mascal. "Production of 5-(chloromethyl)furan-2-carbonyl chloride and furan-2,5-dicarbonyl chloride from biomass-derived 5-(chloromethyl)furfural (CMF)." Green Chemistry 17, no. 7 (2015): 3737–39. http://dx.doi.org/10.1039/c5gc00936g.

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Анотація:
Biomass-derived CMF is oxidized to the acid chloride CMFCC in a single step using inexpensive t-butyl hypochlorite. Likewise, DFF, also a CMF derivative, is oxidized directly to the diacid chloride FDCC. The products are platforms for a variety of chemical derivatives of carbohydrates.
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Mascal, Mark. "5-(Chloromethyl)furfural (CMF): A Platform for Transforming Cellulose into Commercial Products." ACS Sustainable Chemistry & Engineering 7, no. 6 (March 5, 2019): 5588–601. http://dx.doi.org/10.1021/acssuschemeng.8b06553.

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Salim, Kunnummal Mangott Muhammed, Aranhikkal Shamsiya, and Bahulayan Damodaran. "Green Synthesis of Fluorescent Peptidomimetic Triazoles from Biomass-Derived 5-(Chloromethyl)furfural." ChemistrySelect 3, no. 39 (October 24, 2018): 11141–46. http://dx.doi.org/10.1002/slct.201802310.

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Дисертації з теми "5-chloromethyl furfural"

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Howard, Joshua M. "Catalytic conversion of sugar manufacturing by-products to 5-(chloromethyl) furfural and 5-(hydroxymethyl) furural." Thesis, Queensland University of Technology, 2017. https://eprints.qut.edu.au/107143/2/Joshua_Howard_Thesis.pdf.

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Анотація:
This thesis is a contribution to the development of catalytic processes for the production of platform chemicals from agricultural residues. It examined catalytic processes for the production of chloromethylfurfural and hydroxymethylfurfural from sugar cane bagasse and molasses. These chemicals can be used for the production of fuels, pharmaceuticals and polymers.
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Тези доповідей конференцій з теми "5-chloromethyl furfural"

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Schael, Frank, Krishna Nigam, and Patrick Rojahn. "Green engineering approach with microstructured coiled flow inverter for CMF and HMF continuous flow synthesis." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/ikvz3189.

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Анотація:
Since the first publication of the 12 green engineering principles by Anastas and coworkers in 2003 a considerable body of literature developed the idea and its systematic application further. Nowadays several chemical process assessment tools include green engineering principles. This talk gives an overview on the status of green engineering in process assessment and presents a process development example following green engineering principles such as employment of renewable rather than depleting feedstocks and maximization of mass, energy, space and time efficiency among others. In particular, investigations of the technical synthesis of 5-(hydroxymethyl)furfural HMF and 5-(chloromethyl) furfural CMF from sugars and sugar containing waste streams is presented. HMF and CMF attracted a lot of attention in recent literature as potential candidates for new platform chemicals. However, mainly studies of batch processes are so far available. In continuation of earlier investigations process development for a continuous flow synthesis of HMF and CMF is performed by means of a reactive extraction which allows to beneficially combine separation and reaction unit operations in a single processing step. A coiled flow inverter reactor concept with reactor diameters on the scale of millimeter and submillimeter is used. The hydrodynamic properties of the reactor concept in conjunction with small reactor diameters assure efficient heat and mass transfer, narrow residence time distribution and improved safety when compared to regular batch processes. The continuous flow approach allows more easy adaption to changing processing demands and better process control. In systematic investigations environmentally benign extraction solvents, reaction temperature, initial sugar concentrations, and reactor geometry is varied. Kinetic details as well as the influence of flow regimes of the two-phase mixture and hydrodynamic aspects of the reactor operation are elucidated. This information is of relevance for optimization for a later scale-up of the process in line with green engineering principles.
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