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1

Denninger, U., J. J. Schneider, G. Wilke, R. Goddard, R. Krömer e C. Krüger. "Transition metal complexes". Journal of Organometallic Chemistry 459, n.º 1-2 (outubro de 1993): 349–57. http://dx.doi.org/10.1016/0022-328x(93)86088-y.

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2

Reinholdt, Anders, e Jesper Bendix. "Transition Metal Carbide Complexes". Chemical Reviews 122, n.º 1 (19 de novembro de 2021): 830–902. http://dx.doi.org/10.1021/acs.chemrev.1c00404.

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3

Zhou, Wei, Wen-Jie Pan, Jie Chen, Min Zhang, Jin-Hong Lin, Weiguo Cao e Ji-Chang Xiao. "Transition-metal difluorocarbene complexes". Chemical Communications 57, n.º 74 (2021): 9316–29. http://dx.doi.org/10.1039/d1cc04029d.

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4

Braunschweig, Holger, Rian D. Dewhurst e Viktoria H. Gessner. "Transition metal borylene complexes". Chemical Society Reviews 42, n.º 8 (2013): 3197. http://dx.doi.org/10.1039/c3cs35510a.

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5

Starodub, Vladimir A., e T. N. Starodub. "Isotrithionedithiolate transition metal complexes". Russian Chemical Reviews 80, n.º 9 (30 de setembro de 2011): 829–53. http://dx.doi.org/10.1070/rc2011v080n09abeh004199.

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6

Ziessel, Raymond, Muriel Hissler, Abdelkrim El-ghayoury e Anthony Harriman. "Multifunctional transition metal complexes". Coordination Chemistry Reviews 178-180 (dezembro de 1998): 1251–98. http://dx.doi.org/10.1016/s0010-8545(98)00060-5.

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7

Brothers, Penelope J., e Warren R. Roper. "Transition-metal dihalocarbene complexes". Chemical Reviews 88, n.º 7 (novembro de 1988): 1293–326. http://dx.doi.org/10.1021/cr00089a014.

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8

Cundari, Thomas R. "Transition metal imido complexes". Journal of the American Chemical Society 114, n.º 20 (setembro de 1992): 7879–88. http://dx.doi.org/10.1021/ja00046a037.

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9

Hall, Chris, e Robin N. Perutz. "Transition Metal Alkane Complexes†". Chemical Reviews 96, n.º 8 (janeiro de 1996): 3125–46. http://dx.doi.org/10.1021/cr9502615.

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10

Werner, H., D. Schneider e M. Schulz. "Vinylidene transition-metal complexes". Journal of Organometallic Chemistry 451, n.º 1-2 (junho de 1993): 175–82. http://dx.doi.org/10.1016/0022-328x(93)83024-p.

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11

Lappert, M. F. "Transition Metal Carbyne Complexes". Journal of Organometallic Chemistry 461, n.º 1-2 (novembro de 1993): C7—C8. http://dx.doi.org/10.1016/0022-328x(93)83302-c.

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12

B�tiu, C., I. Panea, L. Ghizdavu, L. David e S. Ghizdavu Pellascio. "Divalent transition metal complexes". Journal of Thermal Analysis and Calorimetry 79, n.º 1 (janeiro de 2005): 129–34. http://dx.doi.org/10.1007/s10973-004-0573-6.

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13

Kalt, Dominique, e Ulrich Schubert. "Transition metal silyl complexes." Inorganica Chimica Acta 306, n.º 2 (agosto de 2000): 211–14. http://dx.doi.org/10.1016/s0020-1693(00)00175-4.

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14

Barron, Andrew R., e Geoffrey Wilkinson. "Transition-metal aluminohydride complexes". Polyhedron 5, n.º 12 (janeiro de 1986): 1897–915. http://dx.doi.org/10.1016/s0277-5387(00)87113-2.

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15

Hitchcock, Peter B., Michael F. Lappert e Michael J. McGeary. "Dimetallostannylene-transition-metal complexes". Organometallics 9, n.º 3 (março de 1990): 884–86. http://dx.doi.org/10.1021/om00117a064.

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16

de Azevedo, Cristina G., e K. Peter C. Vollhardt. "Oligocyclopentadienyl Transition Metal Complexes". Synlett 2002, n.º 07 (2002): 1019–42. http://dx.doi.org/10.1055/s-2002-32572.

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17

Brisdon, Brian J., e Richard A. Walton. "Transition metal butadienyl complexes". Polyhedron 14, n.º 10 (maio de 1995): 1259–76. http://dx.doi.org/10.1016/0277-5387(95)00060-6.

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18

Hlatky, Gregory G., e Robert H. Crabtree. "Transition-metal polyhydride complexes". Coordination Chemistry Reviews 65 (julho de 1985): 1–48. http://dx.doi.org/10.1016/0010-8545(85)85020-7.

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19

Werner, H., J. Wolf, F. J. G. Alonso, M. L. Ziegler e O. Serhadli. "Vinylidene transition-metal complexes". Journal of Organometallic Chemistry 336, n.º 3 (dezembro de 1987): 397–411. http://dx.doi.org/10.1016/0022-328x(87)85200-2.

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20

Knorr, Michael, e Ulrich Schubert. "Transition-metal silyl complexes". Journal of Organometallic Chemistry 365, n.º 1-2 (abril de 1989): 151–61. http://dx.doi.org/10.1016/0022-328x(89)87175-x.

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21

Schubert, U. "Transition-metal silyl complexes". Transition Metal Chemistry 16, n.º 1 (fevereiro de 1991): 136–44. http://dx.doi.org/10.1007/bf01127889.

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22

Stevens, Raymond C., John S. Ricci, Thomas F. Koetzle e Wolfgang A. Herrmann. "Transition metal methylene complexes". Journal of Organometallic Chemistry 412, n.º 3 (julho de 1991): 425–34. http://dx.doi.org/10.1016/0022-328x(91)86087-7.

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23

Bysewski, Oliver, Maria Sittig, Andreas Winter, Benjamin Dietzek-Ivanšić e Ulrich S. Schubert. "Photobasic transition-metal complexes". Coordination Chemistry Reviews 498 (janeiro de 2024): 215441. http://dx.doi.org/10.1016/j.ccr.2023.215441.

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24

Sydora, Orson L. "Transition metal benzoate complexes". Polyhedron 252 (abril de 2024): 116854. http://dx.doi.org/10.1016/j.poly.2024.116854.

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25

Mantri, S., H. C. Pradhan, T. Maharana e A. K. Sutar. "Schiff Base Transition Metal Complexes for ROP of L-Lactide". International Journal of Chemical Engineering and Applications 8, n.º 2 (abril de 2017): 122–26. http://dx.doi.org/10.18178/ijcea.2017.8.2.642.

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26

Gerasimov, O. V., e Valentin N. Parmon. "Photocatalysis by transition metal complexes". Russian Chemical Reviews 61, n.º 2 (28 de fevereiro de 1992): 154–67. http://dx.doi.org/10.1070/rc1992v061n02abeh000937.

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27

Brunner, Henri, Jürgen Klankermayer e Manfred Zabel. "Optically active transition-metal complexes". Journal of Organometallic Chemistry 601, n.º 2 (abril de 2000): 211–19. http://dx.doi.org/10.1016/s0022-328x(00)00064-4.

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28

Winkelmann, Ole, Christian Näther e Ulrich Lüning. "Bimacrocyclic NHC transition metal complexes". Journal of Organometallic Chemistry 693, n.º 6 (março de 2008): 923–32. http://dx.doi.org/10.1016/j.jorganchem.2007.11.064.

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29

Xu, Wei, Jonathon P. Rourke, Jagadese J. Vittal e Richard J. Puddephatt. "Transition Metal Rimmed-Calixresorcinarene Complexes". Inorganic Chemistry 34, n.º 1 (janeiro de 1995): 323–29. http://dx.doi.org/10.1021/ic00105a050.

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30

Frohnapfel, David S., e Joseph L. Templeton. "Transition metal η2-vinyl complexes". Coordination Chemistry Reviews 206-207 (setembro de 2000): 199–235. http://dx.doi.org/10.1016/s0010-8545(00)00269-1.

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31

Matos, Robson M., e Carlos A. L. Filgueiras. "Transition metal complexes of thioalcanamines". Transition Metal Chemistry 15, n.º 4 (agosto de 1990): 297–99. http://dx.doi.org/10.1007/bf01061938.

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32

Brunner, H., A. Köllnberger, T. Burgemeister e M. Zabel. "Optically active transition metal complexes". Polyhedron 19, n.º 12 (junho de 2000): 1519–26. http://dx.doi.org/10.1016/s0277-5387(00)00416-2.

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33

González-Maupoey, Marta, Vanessa Tabernero e Tomás Cuenca. "Early transition metal fulvalene complexes". Coordination Chemistry Reviews 253, n.º 13-14 (julho de 2009): 1854–81. http://dx.doi.org/10.1016/j.ccr.2009.02.013.

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34

Busetto, Luigi, Peter M. Maitlis e Valerio Zanotti. "Bridging vinylalkylidene transition metal complexes". Coordination Chemistry Reviews 254, n.º 5-6 (março de 2010): 470–86. http://dx.doi.org/10.1016/j.ccr.2009.07.022.

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35

Feltham, R. D. "Transition metal complexes of NOx". Pure and Applied Chemistry 61, n.º 5 (1 de janeiro de 1989): 943–46. http://dx.doi.org/10.1351/pac198961050943.

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36

Taw, Felicia L., Brian L. Scott e Jaqueline L. Kiplinger. "Early Transition-Metal Perfluoroalkyl Complexes". Journal of the American Chemical Society 125, n.º 48 (dezembro de 2003): 14712–13. http://dx.doi.org/10.1021/ja038527+.

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37

Meier, K. "Photopolymerization with transition metal complexes". Coordination Chemistry Reviews 111 (dezembro de 1991): 97–110. http://dx.doi.org/10.1016/0010-8545(91)84014-v.

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38

PANDEY, K. "Transition metal–σ-borane complexes". Coordination Chemistry Reviews 253, n.º 1-2 (janeiro de 2009): 37–55. http://dx.doi.org/10.1016/j.ccr.2007.11.026.

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39

Salzer, A., H. Schmalle, R. Stauber e S. Streiff. "Optically active transition-metal complexes". Journal of Organometallic Chemistry 408, n.º 3 (maio de 1991): 403–24. http://dx.doi.org/10.1016/0022-328x(91)83211-l.

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40

Nishiyama, Hisao, Henri Brunner e Peter G. Jones. "Optically active transition metal complexes". Journal of Organometallic Chemistry 405, n.º 2 (março de 1991): 247–55. http://dx.doi.org/10.1016/0022-328x(91)86278-x.

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41

Braunschweig, Holger. "Transition Metal Complexes of Boron". Angewandte Chemie International Edition 37, n.º 13-14 (3 de agosto de 1998): 1786–801. http://dx.doi.org/10.1002/(sici)1521-3773(19980803)37:13/14<1786::aid-anie1786>3.0.co;2-c.

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42

Jagirdar, Balaji R. "Transition metal complexes and catalysis". Resonance 4, n.º 9 (setembro de 1999): 63–81. http://dx.doi.org/10.1007/bf02834234.

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43

Barrera, Heribert, Joan Sola e Josef M. Vi�as. "Transition metal complexes of ?-mercaptoalkylpiperidines". Transition Metal Chemistry 10, n.º 6 (junho de 1985): 233–35. http://dx.doi.org/10.1007/bf00692635.

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44

Richers, Casseday P., Jeffery A. Bertke e Thomas B. Rauchfuss. "Syntheses of transition metal methoxysiloxides". Dalton Transactions 46, n.º 27 (2017): 8756–62. http://dx.doi.org/10.1039/c6dt04205h.

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45

Prananto, Yuniar P., Aron Urbatsch, Boujemaa Moubaraki, Keith S. Murray, David R. Turner, Glen B. Deacon e Stuart R. Batten. "Transition Metal Thiocyanate Complexes of Picolylcyanoacetamides". Australian Journal of Chemistry 70, n.º 5 (2017): 516. http://dx.doi.org/10.1071/ch16648.

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A variety of transition metal complexes involving picolylcyanoacetamides (pica = NCCH2CONH-R; R = 2-picolyl- (2pica), 3-picolyl- (3pica), 4-picolyl- (4pica)) and thiocyanate have been synthesised and their solid-state structures have been determined. The complexes were all obtained from reactions between the corresponding metals salts and pica ligands with sodium thiocyanate under ambient conditions. Both 3pica and 4pica coordinate to the metal solely through the nitrogen atom of the picolyl group and form discrete tetrahedral [M(NCS)2(pica)2] (3pica; M = Mn, Zn; 4pica; M = Co) and octahedral [M(NCS)2(3pica)4] (M = Co, Fe, Ni) complexes. In addition, one-dimensional N,S-thiocyanate-bridged coordination polymers poly-[M(µ-NCS)2(pica)2] (3pica; M = Cd; 4pica; M = Co, Cd) were obtained. The ligand 2pica gave the discrete octahedral complexes [Co(NCS)2(2pica)2] and [Cd(NO3)2(2pica)2] in which 2pica chelates in a bidentate fashion through its picolyl and carbonyl groups. Magnetic susceptibility measurements on the cobalt(ii) complexes were performed and showed short-range antiferromagnetic coupling for the [Co(NCS)2(4pica)2]n 1D polymer.
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46

Bullock, R. Morris, e Geoffrey M. Chambers. "Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes". Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 375, n.º 2101 (24 de julho de 2017): 20170002. http://dx.doi.org/10.1098/rsta.2017.0002.

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This perspective examines frustrated Lewis pairs (FLPs) in the context of heterolytic cleavage of H 2 by transition metal complexes, with an emphasis on molecular complexes bearing an intramolecular Lewis base. FLPs have traditionally been associated with main group compounds, yet many reactions of transition metal complexes support a broader classification of FLPs that includes certain types of transition metal complexes with reactivity resembling main group-based FLPs. This article surveys transition metal complexes that heterolytically cleave H 2 , which vary in the degree that the Lewis pairs within these systems interact. Many of the examples include complexes bearing a pendant amine functioning as the base with the metal functioning as the hydride acceptor. Consideration of transition metal compounds in the context of FLPs can inspire new innovations and improvements in transition metal catalysis. This article is part of the themed issue ‘Frustrated Lewis pair chemistry’.
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47

Collman, James P., e Roman Boulatov. "Heterodinuclear Transition-Metal Complexes with Multiple Metal–Metal Bonds". Angewandte Chemie International Edition 41, n.º 21 (4 de novembro de 2002): 3948–61. http://dx.doi.org/10.1002/1521-3773(20021104)41:21<3948::aid-anie3948>3.0.co;2-k.

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48

Yu, Xianghua, Laurel A. Morton e Zi-Ling Xue. "Transition-Metal Silyl Complexes and Chemistry in the Reactions of Silanes with Transition-Metal Complexes". Organometallics 23, n.º 10 (maio de 2004): 2210–24. http://dx.doi.org/10.1021/om049862p.

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49

Akef Ibrahim Alhmaideen, Akef Ibrahim Alhmaideen, Hamzeh M. Abdel Halim Hamzeh M Abdel Halim e Assala A. Al Twal and Adnan S. Abu Surrah Assala A Al Twal and Adnan S Abu Surrah. "Synthesis of New Series of Transition Metal Complexes with Poly (Pyrazolyl) Borates". Journal of the chemical society of pakistan 45, n.º 4 (2023): 294. http://dx.doi.org/10.52568/001289/jcsp/45.04.2023.

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In structuring catalysis enzyme and chemistry, tridentate ligands and Scorpionate ligands are of significant worth. This study presents the synthesis of a tris(pyrazolyl)borate ligand to be utilized in transition metal complexes as possible redox shuttles. Complexes of general formula [AgTp], [MIIITp (Cl2)] (M = Fe, Co), Tp = tri (1-pyrazolyl) borohydride and [AgTp*], [FeIIITp*(Cl2)], Tp* = tris (3, 5-dimethyl-1-pyrazolyl) borohydride were synthesized and characterized in solid state. The Tp ligands were considered triply coordinated with the metal center with two bounded chloride atoms as per the information gathered from spectroscopic information. Entire preparations and operations were performed under argon using common Schlenk procedures. Elemental analysis was performed using (the EURO EA instrument). Thermolysis shows that the Tp ligand decomposes around 100oC and above 300oC for some complexes. The composites were simple to compose, yielded high yields, and were reasonably air sensitive. This study has examined the synthesis of a tris(pyrazolyl)borohydride ligand to develop an iron complex. Further studies conducting electrochemical tests should be carried out to demonstrate the effectiveness of this likely redox mediator.
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50

Chatterjee, Suranjana. "Mechanistic Aspects of Redox Reactions of Transition Metal Complexes in Aqueous Media". International Journal of Science and Research (IJSR) 13, n.º 4 (5 de abril de 2024): 644–50. http://dx.doi.org/10.21275/sr24408113730.

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