Literatura científica selecionada sobre o tema "Ruthenium-based optically pure complexes"

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Artigos de revistas sobre o assunto "Ruthenium-based optically pure complexes"

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Clavero, Pau, Arnald Grabulosa, Mercè Rocamora, Guillermo Muller, and Mercè Font-Bardia. "Ruthenium complexes of P-stereogenic phosphines with a heterocyclic substituent." Dalton Transactions 45, no. 20 (2016): 8513–31. http://dx.doi.org/10.1039/c6dt00995f.

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Optically pure P-stereogenic monophosphorus ligands containing a heterocyclic substituent have been prepared. They have been coordinated to Ru-η<sup>6</sup>-arene moieties in which the ligands act as mono- or bidentate. The complexes catalyse asymmetric transfer hydrogenation reactions with up to 70% ee.
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Genet, Jean Pierre. "Recent studies on asymmetric hydrogenation. New catalysts and synthetic applications in organic synthesis." Pure and Applied Chemistry 74, no. 1 (2002): 77–83. http://dx.doi.org/10.1351/pac200274010077.

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CODRu(h3methylallyl)2 is a versatile starting material for the preparation of a wide range of chiral bisphosphines ruthenium(II) complexes: (P*P)Ru(h3methylallyl)2 2, Ru[X4(P*P)2] 3, and cationic monohydride ruthenium complex 4. A facile synthesis of new C2 electron-rich chiral phosphines, bis(phosphetano)benzene 8 and 1,1¢bis(phosphetano)ferrocene 10 is presented. Dynamic kinetic resolution was used for efficient syntheses of key components of the hexahydroazepane core 16 of balanol and of optically pure Boc-(2S,3R,3S)-iso-dolaproïne 19. Catalyst 4 was used in asymmetric hydrogenation of 22 t
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Morvan, Jennifer, François Vermersch, Ziyun Zhang, et al. "Optically Pure C1-Symmetric Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Asymmetric Olefin Metathesis." Journal of the American Chemical Society 142, no. 47 (2020): 19895–901. http://dx.doi.org/10.1021/jacs.0c10705.

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Bhaduri, Debjani, John H. Nelson, Tieli Wang, and Robert A. Jacobson. "Syntheses and reactions of iron and ruthenium complexes of an optically pure fused cyclopentadienyl ligand." Organometallics 13, no. 6 (1994): 2291–98. http://dx.doi.org/10.1021/om00018a023.

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Ou-Yang, J. K., N. Saleh, G. Fernandez Garcia, et al. "Improved slow magnetic relaxation in optically pure helicene-based DyIII single molecule magnets." Chemical Communications 52, no. 100 (2016): 14474–77. http://dx.doi.org/10.1039/c6cc08638a.

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Caspar, Régis, Léna Musatkina, Alexander Tatosyan, et al. "Efficient DNA Binding by Optically Pure Ruthenium Tris(bipyridyl) Complexes Incorporating Carboxylic Functionalities. Solution and Structural Analysis." Inorganic Chemistry 43, no. 25 (2004): 7986–93. http://dx.doi.org/10.1021/ic0494657.

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Matsushima, Yuji, Nobuko Komatsuzaki, Yoshiki Ajioka та ін. "Synthesis and Properties of Planar-Chiral (η6-Benzene)(η5-cyclopentadienyl)ruthenium(II) Complexes in an Optically Pure Form". Bulletin of the Chemical Society of Japan 74, № 3 (2001): 527–37. http://dx.doi.org/10.1246/bcsj.74.527.

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Fei, Bao-Li, Shuangyan Tu, Zuzhuang Wei, et al. "Biological evaluation of optically pure chiral binuclear copper(ii) complexes based on a rosin derivative as highly potential anticancer agents." Dalton Transactions 48, no. 41 (2019): 15646–56. http://dx.doi.org/10.1039/c9dt01942a.

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Piehler, Torsten, and Arne Lützen. "Enantiomerically Pure C2-symmetric Dinuclear Silver(I) and Copper(I) Complexes from a Bis(2,2´-bipyridine)-substituted 9,9´-Spirobifluorene Ligand." Zeitschrift für Naturforschung B 65, no. 3 (2010): 329–36. http://dx.doi.org/10.1515/znb-2010-0316.

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We have prepared a new bis(bipyridyl) ligand 1 based on a chiral 9,9´-spirobifluorene core in both enantiomerically pure forms. This ligand was found to undergo diastereoselective self-assembly to optically pure dinuclear coordination compounds upon coordination to copper(I) and silver(I) ions. Surprisingly, however, the resulting diastereomer was not found to be D2-symmetric which is usually found for similar bis(bidentate) ligands, but rather C2-symmetric with differently configurated metal centers.
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Nasriddinov, Abulkosim, Sergey Tokarev, Olga Fedorova, Ivan Bozhev, and Marina Rumyantseva. "In2O3 Based Hybrid Materials: Interplay between Microstructure, Photoelectrical and Light Activated NO2 Sensor Properties." Chemosensors 10, no. 4 (2022): 135. http://dx.doi.org/10.3390/chemosensors10040135.

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In this work, organic–inorganic hybrids based on nanocrystalline indium oxide and ruthenium (II) heteroleptic complexes were used as sensitive materials for room temperature light-activated NO2 detection. In2O3 was obtained by chemical precipitation method and then annealed at three different temperatures (T = 300, 500, 700 °C) in order to investigate the influence of the microstructure of indium oxide on sensor characteristics of hybrid materials and on kinetics of the rise and fall of photoconductivity. The results of the X-ray phase analysis demonstrated that the obtained materials are sing
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Teses / dissertações sobre o assunto "Ruthenium-based optically pure complexes"

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Talcik, Jakub. "Conception de catalyseurs chiraux de ruthénium à base de carbènes alkyles amino cycliques (CAACs) pour la métathèse asymétrique des oléfines." Electronic Thesis or Diss., Université de Rennes (2023-....), 2024. http://www.theses.fr/2024URENC001.

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La métathèse des oléfines est une réaction emblématique de la chimie verte pour la formation de nouvelles doubles liaisons carbone-carbone. Permettant une grande économie d’atome et la réduction du nombre d’étapes de synthèse, cette réaction offre des atouts incontestables pour la production de molécules d’intérêts. Ainsi, une multitude de complexes de ruthénium ont été développés depuis les années 1990 avec pour objectif d’étendre les champs d’applications de la métathèse. Si des avancées majeures ont été accomplies au niveau de l’activité et de la stabilité de ces précatalyseurs, le contrôle
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Trabalhos de conferências sobre o assunto "Ruthenium-based optically pure complexes"

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Zhao, S. N., H. Chang, J. Wei, and Z. Wei. "Pseudo-Color Coded Optical System Based on the Spatial Light Modulator and Charge-Coupled Device." In ASME 2012 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2012. http://dx.doi.org/10.1115/imece2012-86642.

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A new pseudo-color coded optical system based on the liquid crystal spatial light modulator (LC-SLM) and a digital camera (CCD) is proposed. The SLM is used to replace the holographic grating with gray-scale image information, a gray-scale image in real-time modulation methods is proposed by synthesizing phase hologram and Ronchi grating, combined with the 4f coherent optical processing system and spatial filtering. For the high resolution gray image processed with existing digital pseudo-color method, the color sensitivity is low, algorithm is very complex. For traditional optical pseudo-colo
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Salmela, Juha, Sanna Haavisto, Antti Koponen, Ari Jäsberg, and Markku Kataja. "Rheological Characterization of Micro-Fibrillated Cellulose Fibre Suspensions Using Multi Scale Velocity Profile Measurements." In Advances in Pulp and Paper Research, Cambridge 2013, edited by S. J. I’ Anson. Fundamental Research Committee (FRC), Manchester, 2013. http://dx.doi.org/10.15376/frc.2013.1.495.

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A rheometric method based on velocity pro ling simultaneously by optical coherence tomography and the ultrasound velocity profilometry was introduced and used in a preliminary study of the rheological and boundary layer ow properties of micro fibrillated cellulose. The two velocity pro ling methods appear adequate and complementary for rheological characterization of opaque complex fluids. The ultrasound method is useful in measuring the velocity profile in the interior parts of the tube, while the optical technique is capable of high-resolution measurement of the boundary layer ow close to th
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Du, H., S. H. Ng, K. T. Neo, et al. "Inorganic-Polymer Nanocomposites for Optical Applications." In ASME 2006 Multifunctional Nanocomposites International Conference. ASMEDC, 2006. http://dx.doi.org/10.1115/mn2006-17088.

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The combination of organic and inorganic materials forms unique composites with properties that neither of the two components provides. Such functional materials are considered innovative advanced materials that enable applications in many fields, including optics, electronics, separation membranes, protective coatings, catalysis, sensors, biotechnology, and others. The challenge of incorporating inorganic particles into an organic matrix still remains today, especially for nanoparticles, due to the difficulties in their dispersion, de-agglomeration and surface modification. NanoGram has pione
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Zhang, Feng, Feng Yang, Dong Lin, and Chi Zhou. "Parameter Study on 3D-Printing Graphene Oxidize Based on Directional Freezing." In ASME 2016 11th International Manufacturing Science and Engineering Conference. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/msec2016-8846.

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Graphene is one of the most promising carbon nanomaterial due to its excellent electrical, thermal, optical and mechanical properties. However, it is still very challenging to unlock its exotic properties and widely adopt it in real-world applications. In this paper, we introduces a new 3D graphene structure printing approach with pure graphene oxide material, better inter-layer bonding, and complex architecture printing capability. Various parameters related to this novel process are discussed in detail in order to improve the printability, reliability and accuracy. We have shown that the pri
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Berten, Olivier, Patrick Hendrick, Alberto Villar, and David Seveno. "Using a Lubrication Test Bench for Testing New Oil Quality Sensors." In ASME Turbo Expo 2013: Turbine Technical Conference and Exposition. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/gt2013-94980.

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The Université Libre de Bruxelles/ Aero-Thermo-Mechanics Department (ULB/ATM) has developed a flow bench used to mimic the complete behaviour of an aircraft gas turbine engine lubrication system. This test bench has been improved to be fully instrumented and is really multi-purposes in order to test different lubrication devices in the supply circuit (pure oil) or in the scavenge part (two-phase flow) simulating real flight conditions (oil flow rate, oil temperature and pressure…). The paper will first present the characteristics of the lubrication test bench and its capabilities. In a second
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Gao, G., L. Pershin, and J. Mostaghimi. "Optical Emission Spectroscopic Diagnostics of Atmospheric Argon Radio Frequency Inductively Coupled Plasma." In ITSC2003, edited by Basil R. Marple and Christian Moreau. ASM International, 2003. http://dx.doi.org/10.31399/asm.cp.itsc2003p1337.

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Abstract An experimental study is conducted to determine the property fields of 40 MHz argon radio frequency inductively coupled plasma using optical emission spectroscopy. The pure argon plasma was operated at the input power of 0.3 kW and under atmospheric pressure. 29 atomic argon lines with upper level energies ranging from 12.9 to 15.5 eV, continuum emission and line width are used to evaluate plasma parameters such as temperature and electron number density. Since 40 MHz plasma is in almost complete nonequilibrium, the validaty and accuracy of most usual spectroscopic methods are questio
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Sergiienko, Ruslan, Roman Serhiiko, Volodymyr Shcheretskyi, et al. "Structure and physical-mechanical properties of cast heat-resistant FeNiCrCuAl high-entropy alloys." In IXth INTERNATIONAL SAMSONOV CONFERENCE “MATERIALS SCIENCE OF REFRACTORY COMPOUNDS”. Frantsevich Ukrainian Materials Research Society, 2024. http://dx.doi.org/10.62564/m4-rs1734.

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The crystal lattice of high-entropy alloys (HEAs) undergoes significant deformation, that is why HEAs have high strength, significant wear resistance and corrosion resistance in environments with high chemical activity [1]. This work was aimed at creating new heat-resistant high-entropy alloys, based on inexpensive elements and prepared from common master-alloys, studying their phase composition and structure, as well as determining their physical-mechanical properties. FeNiCrCuAl alloys do not contain such an expensive element as cobalt (Co), which is usually present in similar metallic syste
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