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1

Kemp, L., Elizabeth C. Jamieson e S. J. Gaskin. "Phosphorescent tracer particles for Lagrangian flow measurement and particle tracking velocimetry". Experiments in Fluids 48, n.º 5 (20 de janeiro de 2010): 927–31. http://dx.doi.org/10.1007/s00348-009-0818-z.

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2

Mahltig, Boris, Clara Heil, Sarah Kaub e Jaydip Nareshbhai Kapadiya. "The use of phosphorescence micromaterials for commercial textile products". Communications in Development and Assembling of Textile Products 5, n.º 1 (1 de janeiro de 2024): 1–10. http://dx.doi.org/10.25367/cdatp.2024.5.p1-10.

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Fluorescent textile products are manifold used. Compared to fluorescent textiles, phosphorescent textile products exhibit an afterglow effect even after the illumination is stopped. Phosphorescent textiles are less present as commercial products on the market. With this background the aim of the actual presentation is to investigate the properties of commercially available phosphorescent textile materials. Investigations are performed by illumination under different light arrangement. Microscopy is performed by scanning electronic microscopy (SEM) and advanced light microscopy using UV light. Light emission of the samples is recorded by fluorescence spectroscopy. The chemical composition is determined by using electron dispersive spectroscopy (EDS). Depending on the type of sample, an afterglow effect can be determined up to 5 to 30 minutes after stopping the illumination with UV light. By SEM and EDS methods it is observed that the phosphorescent effects are realized by application of phosphorescent pigments, which can be best described as phosphorescent micromaterials. Depending on the product category, two different types of phosphorescent materials are used – doped strontium aluminates (SrAl2O4) and zinc sulfide (ZnS). Products based on doped strontium aluminates exhibit longer afterglow effects compared to products with ZnS pigments. However, the use of doped strontium aluminate is quite surprising for a commercial textile product, because of cost reasons. Finally, it can be stated that phosphorescent micromaterials are established materials for realization of functional textile products. These micromaterials can be found in every day products and are examples for innovative particle technology used in commercial consumer products.
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3

Rojas-Hernandez, R. E., F. Rubio-Marcos, E. Enríquez, M. A. De La Rubia e J. F. Fernandez. "A low-energy milling approach to reduce particle size maintains the luminescence of strontium aluminates". RSC Advances 5, n.º 53 (2015): 42559–67. http://dx.doi.org/10.1039/c5ra04878h.

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4

Liu, Zhenping, Xianfeng Wang, Jingzhou Hou, Danqun Huo e Changjun Hou. "A Simple and Rapid Phosphorescence Probe Based on Mn-Doped ZnS Quantum Dots for Chloramphenicol Detection". Nano 14, n.º 11 (novembro de 2019): 1950144. http://dx.doi.org/10.1142/s1793292019501443.

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An innovative phosphorescence probe based on Mn-doped ZnS quantum dots (Mn:ZnS QDs) was developed for selective detection of chloramphenicol (CAP) via inner-filter effect (IFE). Mn:ZnS QDs were synthesized by water method and modified with L-Cysteine for better stability, and the average diameter of the nanometer particle was 3.8[Formula: see text]nm. With the excitation wavelength at 289[Formula: see text]nm, the strong phosphorescence of Mn:ZnS QDs can be emitted at 583[Formula: see text]nm. The excitation spectrum of Mn:ZnS QDs was substantially overlapped with the absorption spectrum of the target CAP. The excited light of Mn:ZnS QDs can be absorbed partially by CAP when they coexist, the phosphorescence intensity decreased with the increasing concentration of CAP, and it has a good linear relationship. Under optimal conditions, the linear relational concentration range achieved four orders of magnitude from 25 to [Formula: see text] ([Formula: see text]), with a detection limit (LOD; [Formula: see text]) down to 0.81[Formula: see text][Formula: see text]. The simple, rapid and low cost IFE phosphorescent probe exhibited satisfactory recoveries ranging from 88.9% to 98.5% for CAP analysis in spiked honey, which shows a potential for routine screening of CAP in ensuring the food safety.
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5

Shen, Yong, Yunfei Xia, Ping Li, Shuo Zhang, Linlin Li, Die Hu, Dongfang Shi e Kai Song. "Microwave-Assisted Synthesis of Room Temperature Long Persistent Luminescent Materials and Their Imaging Applications". Crystals 13, n.º 4 (20 de abril de 2023): 705. http://dx.doi.org/10.3390/cryst13040705.

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In this study, we utilized a simple and efficient microwave heating method with polyethyleneimine (PEI) and phosphate as raw materials to synthesize room temperature persistent luminescence (RTPL) materials that emit phosphorescent light for up to 10 s. Our investigation revealed that the optimal synthesis conditions were a microwave radiation power of 560 W and a heating time of 5 min. The synthesized RTPL materials had an average particle size of 2 nm and exhibited excellent RTPL performance, with optimal excitation and emission wavelengths of 360 nm and 544 nm, respectively. Additionally, these materials displayed good water solubility. We conducted mapping experiments and in situ phosphorescent imaging of plants to showcase the potential applications of RTPL materials in the fields of biological imaging and anti-counterfeiting. Overall, our findings demonstrate the promising potential of these RTPL materials as versatile tools for various practical applications.
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6

Karacaoglu, Erkul, Faruk Ozel, Sabriye Acikgoz, Adem Sarilmaz, Hasan Yungevis, Mert Gul e Ali Kemal Okyay. "Investigation of Atomic Layer Deposition Post-Coating Properties of Phosphorescent SrAl2O4: Eu2+, Dy3+ Fibers Produced By Electrospinning". ECS Meeting Abstracts MA2022-02, n.º 51 (9 de outubro de 2022): 1974. http://dx.doi.org/10.1149/ma2022-02511974mtgabs.

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In this research, phosphorescent SrAl2O4:Eu2+, Dy3+ fibers were produced by electrospinning and coated with atomic layer deposition (ALD) technique to enhance the photoluminescence (PL) properties, and water & thermal resistance. Particle form of Eu2+-activated strontium aluminate phosphors possess many remarkable features that have been reported over and over, for example, nontoxic, stable, efficient. PL enhancement and stability in water of these particles were provided by nano encapsulation process by ALD that has just been published in our previous paper. In this study, for the first time, SrAl2O4 based long persistence phosphor fibers were coated with the ALD method to both improve their PL and provide water & thermal resistance property. In this successfully carried out study, luminescence, optic, chemical and structural properties of phosphor in fiber form were investigated in detail. These improved submicron afterglow fibers which are SrAl2O4:Eu2+, Dy3+ based are promising materials for applications such as solar cells, luminescent labels for bioimaging, mechanoluminescence sensor, etc.
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7

Kaya, Selvin Yesilay, Bekir Karasu, Guray Kaya e Erkul Karacaoğlu. "Influences of Eu2+ and Dy3+ Contents on the Properties of Long Afterglow Strontium Aluminate Phosphors". Advances in Science and Technology 62 (outubro de 2010): 88–94. http://dx.doi.org/10.4028/www.scientific.net/ast.62.88.

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The detailed preparation process of Eu2+ and Dy3+ ion co-doped phosphor powders in Sr4Al14O25:Eu2+/Dy3+ phosphor system with bluish-green long afterglow produced by solid state reaction method under reducing atmosphere is here reported. X-ray diffraction (XRD), scanning electron microscopy (SEM), and particle size analysis were made to assign the effects of Eu and Dy ions on the luminescent properties of the synthesized phosphors, which were determined by measuring the photoluminescence spectra. The maximum emission intensity of these phosphors under excitation was investigated. As a result, the relevant values were obtained from the phosphorescent pigment with 0.21% and 0.05% molar percent of Eu2+ and Dy3+.
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8

Laskowska, Magdalena, Anna Nowak, Mateusz Dulski, Peter Weigl, Thomas Blochowicz e Łukasz Laskowski. "Spherical Silica Functionalized by 2-Naphthalene Methanol Luminophores as a Phosphorescence Sensor". International Journal of Molecular Sciences 22, n.º 24 (10 de dezembro de 2021): 13289. http://dx.doi.org/10.3390/ijms222413289.

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Photoluminescence is known to have huge potential for applications in studying biological systems. In that respect, phosphorescent dye molecules open the possibility to study the local slow solvent dynamics close to hard and soft surfaces and interfaces using the triplet state (TSD: triplet state solvation dynamics). However, for that purpose, probe molecules with efficient phosphorescence features are required with a fixed location on the surface. In this article, a potential TSD probe is presented in the form of a nanocomposite: we synthesize spherical silica particles with 2-naphthalene methanol molecules attached to the surface with a predefined surface density. The synthesis procedure is described in detail, and the obtained materials are characterized employing transmission electron microscopy imaging, Raman, and X-ray photoelectron spectroscopy. Finally, TSD experiments are carried out in order to confirm the phosphorescence properties of the obtained materials and the route to develop phosphorescent sensors at silica surfaces based on the presented results is discussed.
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9

Choong, H., N. Suardi e N. Ahmed. "Evaluation of strontium aluminate phosphorescent effect on blood as potential light source for phototherapy". Biomedical Photonics 9, n.º 3 (19 de outubro de 2020): 21–29. http://dx.doi.org/10.24931/2413-9432-2020-9-3-21-29.

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Phototherapy has shown its effect on cell stimulation and inhibition based on Arndt-Schulz model. Even though this therapeutic method has apparent effect, but it has limitations for epithelial application due to limitations on light penetration. Hence, with the ideology of fully overcoming this limitation, phosphorescent powder (strontium aluminate) is proposed as the potential light source that emitting photon from inside the body for phototherapy purposes. The strontium aluminate powder used in the experiment has the highest peak absorption at wavelength around 650 nm and lowest at around 350 nm. According to FESEM images, the powder has the particle size varies from 10 to 50 μm at cubic phase. The assessment is done by studying the effect on erythrocyte after blood plasma is irradiated by strontium aluminate powder’s photon. The powder luminesces with a maximum at 491.5 nm when pumped with 473 nm laser at 100 mW in fixed amount of 0.005±0.001 g. Later, it is mixed with centrifuged blood plasma for a predetermined time period (5, 10, 15, and 20 minutes). From this study, it shows that 5 minutes irradiation is the optimum period for erythrocyte in term of morphology enhancement and increase of UV-visible absorption spectrum with at least 21% in comparing with control blood. While the significant increment located at wavelengths 340 nm and 414 nm with both increased by 54% and 41%, respectively. However, for 10 minutes and beyond, the irradiation leads to morphology deterioration while the UV-visible spectrum decrement starts at 15 minutes and beyond. In conjunction, a comparison between blood plasma that either interacted with powder emitting photon or powder with no emission shows that photon emission plays a role in the phototherapy effect.
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10

Guerrier, M. P., P. A. Williams, A. R. Greig, M. Fry, A. J. Allnutt e J. N. Stewart. "Phosphorescent particle tracking, a novel optical technique with which to visualise the interaction of gas flowstreams within the cylinder of an IC engine". Optics & Laser Technology 31, n.º 1 (fevereiro de 1999): 41–51. http://dx.doi.org/10.1016/s0030-3992(99)00026-2.

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11

Diel, Waldemar, Dustin Büttner, Klaus Krüger e Beat Zobrist. "Digital Printing of Phosphorescent Particles". NIP & Digital Fabrication Conference 27, n.º 1 (1 de janeiro de 2011): 466–69. http://dx.doi.org/10.2352/issn.2169-4451.2011.27.1.art00013_2.

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12

KATOH, Akira, Tomomi HATANAKA, Eri TAKEUCHI, Masaki UCHIDA e Hideshi NATSUME. "Calibration of infrared video-oculography by using bioadhesive phosphorescent particles for accurate measurement of vestibulo-ocular reflex in mice". Journal of Advanced Science 27, n.º 3+4 (2015): 11–16. http://dx.doi.org/10.2978/jsas.27.11.

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13

Bradley, Melanie, Muthupandian Ashokkumar e Franz Grieser. "Sonochemical Production of Fluorescent and Phosphorescent Latex Particles". Journal of the American Chemical Society 125, n.º 2 (janeiro de 2003): 525–29. http://dx.doi.org/10.1021/ja0268581.

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14

Botev, I., e A. Marinova. "Light absorption formula for phosphorescing particles". Journal of Molecular Structure: THEOCHEM 314, n.º 3 (novembro de 1994): 329–30. http://dx.doi.org/10.1016/0166-1280(94)03715-w.

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15

Adadurov, A. F., P. N. Zhmurin, V. N. Lebedev e V. V. Kovalenko. "Plastic scintillator with phosphorescent dopants for α-particles registration". Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment 621, n.º 1-3 (setembro de 2010): 354–57. http://dx.doi.org/10.1016/j.nima.2010.04.055.

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16

Sperling, R. A., e W. J. Parak. "Surface modification, functionalization and bioconjugation of colloidal inorganic nanoparticles". Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 368, n.º 1915 (28 de março de 2010): 1333–83. http://dx.doi.org/10.1098/rsta.2009.0273.

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Inorganic colloidal nanoparticles are very small, nanoscale objects with inorganic cores that are dispersed in a solvent. Depending on the material they consist of, nanoparticles can possess a number of different properties such as high electron density and strong optical absorption (e.g. metal particles, in particular Au), photoluminescence in the form of fluorescence (semiconductor quantum dots, e.g. CdSe or CdTe) or phosphorescence (doped oxide materials, e.g. Y 2 O 3 ), or magnetic moment (e.g. iron oxide or cobalt nanoparticles). Prerequisite for every possible application is the proper surface functionalization of such nanoparticles, which determines their interaction with the environment. These interactions ultimately affect the colloidal stability of the particles, and may yield to a controlled assembly or to the delivery of nanoparticles to a target, e.g. by appropriate functional molecules on the particle surface. This work aims to review different strategies of surface modification and functionalization of inorganic colloidal nanoparticles with a special focus on the material systems gold and semiconductor nanoparticles, such as CdSe/ZnS. However, the discussed strategies are often of general nature and apply in the same way to nanoparticles of other materials.
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17

Winnik, Mitchell A., Onder Pekcan e M. D. Croucher. "Phosphorescence of naphthalene-labelled colloidal polymer particles. The α-methyl relaxation of one microphase in a multicomponent material". Canadian Journal of Chemistry 63, n.º 1 (1 de janeiro de 1985): 129–33. http://dx.doi.org/10.1139/v85-021.

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Nonaqueous dispersions of poly(methyl methacrylate) (PMMA) particles, sterically stabilized with polyisobutylene (PIB), were prepared with naphthalene (N) groups covalently incorporated into the PMMA chains. These materials have a complex morphology of phase-separated PMMA and PIB microdomains, with the N groups in the PMMA microphases. The phosphorescence intensity and decay times of the N groups were measured as a function of temperature over the range 77–295 K for dispersions in methylcyclohexane and for freeze-dried powder samples. An Arrhenius treatment of the radiationlcss decay rate showed a change in slope at −35 °C. The activation energy for the radiationless decay process is 3.8 kcal/mol in the −35 – +22 °C temperature region, identical to that found for pure PMMA by nmr for chain motion associated with the a-methyl relaxation process. We believe that the phosphorescence experiment is sensitive to the diffusion of oxygen and other impurities in the sample. These rates increase as the temperature is raised, enhancing the rate of phosphorescence quenching. These experiments indicate that phosphorescence measurements on labelled samples are suitable for studying relaxation processes within individual microphases of a polyphasic composite material.
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18

Kim, Hyungsoo, Eric S. Daniels, Shang Li, Vijaya K. Mokkapati e Keith Kardos. "Polymer encapsulation of yttrium oxysulfide phosphorescent particles via miniemulsion polymerization". Journal of Polymer Science Part A: Polymer Chemistry 45, n.º 6 (2007): 1038–54. http://dx.doi.org/10.1002/pola.21860.

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19

Lin, Meijuan, Caiping Luo, Guang Xing, Longjie Chen e Qidan Ling. "Influence of polyhedral oligomeric silsesquioxanes (POSS) on the luminescence properties of non-conjugated copolymers based on iridium complex and carbazole units". RSC Advances 7, n.º 63 (2017): 39512–22. http://dx.doi.org/10.1039/c7ra07316j.

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The non-conjugated copolymers with the carrier-transporting carbazole units, phosphorescence iridium complex units and nano-scale particles POSS were synthesized. The effects of POSS on the performance of copolymer hybrid materials were investigated.
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20

Duan, Xiaoxia, Lixin Yi, Xiqing Zhang e Shihua Huang. "Size-Dependent Optical Properties of Nanoscale and Bulk Long Persistent Phosphor SrAl2O4:Eu2+, Dy3+". Journal of Nanomaterials 2015 (2015): 1–7. http://dx.doi.org/10.1155/2015/298692.

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Nanoscale long persistent phosphor SrAl2O4:Eu2+, Dy3+was prepared by autocombustion of citrate gel. The energy level shift of activator Eu2+and coactivator Dy3+was analyzed according to the emission and the excitation spectra. The band gap change of SrAl2O4and the resulting trap depth change with particle size were discussed on the basis of analyzing the visible spectra, the vacuum ultraviolet (VUV) excitation spectra, and the thermoluminescence (TL) spectra. The fluorescence quenching and the shallow traps originating from surface adsorption or surface defects explain the weak initial persistent phosphorescence and the fast phosphorescence decay in nanometer SrAl2O4:Eu2+, Dy3+. It is confirmed that energy level, band gap, trap depth, defect, and surface adsorption are deeply related with each other in this nanoscale long persistent phosphor.
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21

Song, Xuedong, Lei Huang e Bin Wu. "Bright and Monodispersed Phosphorescent Particles and Their Applications for Biological Assays". Analytical Chemistry 80, n.º 14 (julho de 2008): 5501–7. http://dx.doi.org/10.1021/ac800483n.

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22

Louge, Michel Y., Subramanyam A. Iyer, Emmanuel P. Giannelis, D. Jeffrey Lischer e Hongder Chang. "Optical fiber measurements of particle velocity using laser-induced phosphorescence". Applied Optics 30, n.º 15 (20 de maio de 1991): 1976. http://dx.doi.org/10.1364/ao.30.001976.

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23

Deponte, H., W. Augustin e S. Scholl. "Development of a quantification method for fouling deposits using phosphorescence". Heat and Mass Transfer 57, n.º 10 (26 de março de 2021): 1661–70. http://dx.doi.org/10.1007/s00231-021-03053-6.

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AbstractParticulate fouling on structured surfaces is typically quantified using the integral thermal or mass-based fouling resistance. The observed geometries may be structures that can improve the heat transfer in heat exchangers (e.g., dimples), cavities in components, or more complex geometries. However, due to limited accessibility or the requirement for a locally resolved measurement, the existing quantification methods may not be applicable to structured surfaces. For this reason, a new method is needed for the quantification for fouling deposits. In this study, dimpled surfaces were evaluated by measuring the integral thermal and mass-based fouling resistance and comparing it with the local fouling resistance inside and around the dimple. This comparison was carried out online with the Phosphorescent Fouling Quantification method developed for this purpose, using phosphorescent particles to quantify the deposited mass. The mass-based fouling resistance can be calculated using computer-aided image analysis. The measurements for the evaluation were conducted on dimpled surfaces, which produced a characteristic fouling pattern. With the new method a reduced surface coverage from up to 33.3 % was observed, which led to lower fouling resistances downstream of the dimple compared to a plain surface. These results confirm earlier numerical and experimental findings, suggesting an advantage of dimpled surfaces over other surface structures with respect to thermo-hydraulic efficiency as well as reduced fouling. Thus, the Phosphorescent Fouling Quantification method provides the possibility of calculating values for local fouling resistances on structured surfaces, as well as the possibility of optimizing surface structures to minimize fouling propensity.
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24

Díaz-García, M. E., B. Noval Gutiérrez e R. Badía. "Tailoring room-temperature phosphorescent ormosil particles for oxygen recognition in organic solvents". Sensors and Actuators B: Chemical 110, n.º 1 (setembro de 2005): 66–72. http://dx.doi.org/10.1016/j.snb.2005.01.022.

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Sato, Hisako, Kenji Tamura, Tomoko Yajima, Fumi Sato e Akihiko Yamagishi. "Chiral phosphorescent probes for amino acids: hybrids of iridium(iii) complexes with synthetic saponite". New Journal of Chemistry 41, n.º 7 (2017): 2780–85. http://dx.doi.org/10.1039/c6nj03777a.

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The effects of amino acids on the emission of iridium(iii) complexes adsorbed by colloidal particles of synthetic saponite lead to the conclusion that the interplay between two intramolecular chiral centers achieved enantioselectivity.
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Bartwal, K. S., B. K. Singh e H. Ryu. "Preparation of CaAl2O4: Eu2+ Long Persistent Blue Phosphor". Advanced Materials Research 26-28 (outubro de 2007): 573–76. http://dx.doi.org/10.4028/www.scientific.net/amr.26-28.573.

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CaAl2O4:Eu2+ with high brightness and long persistent luminescence were prepared by solid state reaction method. The phosphor compositions with varying Eu2+ were investigated by powder X-ray diffractometer (XRD), SEM, TEM, photoluminescence excitation and emission spectra. Broad band UV excited luminescence of the CaAl2O4:Eu2+ was observed in the blue region (λmax = 440 nm) due to transitions from the 4f65d1 to the 4f7 configuration of the Eu2+ ion. The particle size also plays a role deciding the luminescence characteristics of these phosphors. The decay time of the persistence indicated that the persistent luminescence phosphor has bright phosphorescence and maintains a long duration.
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27

Murata, Junji, e Masaya Kagawa. "Photo-Assisted Chemical Mechanical Polishing of Si Wafer Using Phosphorescent Particles as a Luminescent Agent". ECS Journal of Solid State Science and Technology 8, n.º 11 (2019): P727—P733. http://dx.doi.org/10.1149/2.0161911jss.

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SOLAINI, Giancarlo, Alessandra BARACCA, Edi GABELLIERI e Giorgio LENAZ. "Modification of the mitochondrial F1-ATPase ∊ subunit, enhancement of the ATPase activity of the IF1–F1 complex and IF1-binding dependence of the conformation of the ∊ subunit". Biochemical Journal 327, n.º 2 (15 de outubro de 1997): 443–48. http://dx.doi.org/10.1042/bj3270443.

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Treatment of bovine heart submitochondrial particles with a low concentration of 2-hydroxy-5-nitrobenzyl bromide (HNB), a selective reagent for the Trp residue of the ε subunit [Baracca, Barogi, Lenaz and Solaini (1993) Int. J. Biochem. 25, 1269-1275], enhances the ATP hydrolytic activity of the particles exclusively when the natural inhibitor protein IF1 is present. Similarly, isolated F1 [the catalytic sector of the mitochondrial H+-ATPase complex (ATP synthase)] treated with the reagent has the ATPase activity enhanced exclusively if IF1 is bound to it. These experiments suggest that the modification of the ε subunit decreases the inhibitory activity of IF1, eliciting the search for a relationship between the ε subunit and the inhibitory protein. Certainly, a reverse relationship exists because HNB binds covalently to the isolated F1 exclusively when the inhibitory protein is present. This finding is consistent with the existence of the ε subunit in different conformational states depending on whether IF1 is bound to F1 or not. Support for this assertion is obtained by measurements of the intrinsic phosphorescence decay rate of F1, a probe of the Trp ε subunit conformation in situ [Solaini, Baracca, Parenti-Castelli and Strambini (1993) Eur. J. Biochem. 214, 729-734]. A significant difference in phosphorescence decay rate is detected when IF1 is added to preparations of F1 previously devoid of the inhibitory protein. These studies indicate that IF1 and the ε subunit of the mitochondrial F1-ATPase complex are related, suggesting a possible role of the ε subunit in the mechanism of regulation of the mitochondrial ATP synthase.
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Kaya, S. Yesilay, E. Karacaoglu e B. Karasu. "Particle size influence of starting batches on phosphorescence behaviour of Sr4Al14O25based bluish green phosphors". Advances in Applied Ceramics 111, n.º 7 (outubro de 2012): 393–97. http://dx.doi.org/10.1179/1743676112y.0000000005.

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Karacaoglu, Erkul, Bekir Karasu e Esra Öztürk. "The Investigations on Luminescence Characteristics and Influence of Doping and Co-Doping Different Rare Earth Ions in White Phosphorescence Materials Having Different Luminescent Centers". Advances in Science and Technology 90 (outubro de 2014): 133–40. http://dx.doi.org/10.4028/www.scientific.net/ast.90.133.

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The Akermanite type alkaline earth silicate Ca2MgSi2O7 activated by different types of rare earths was prepared by the conventional solid state reaction method under weak reductive atmosphere. The phase formation, particle size distribution, particle morphologies and photoluminescence properties of the samples have been investigated respectively. The comparative results of SEM and laser particle size analysis revealed that the relatively regular morphology, smaller particle size distribution could be achieved for the phosphors synthesized by the solid state reaction method including dry-ground after which powders were sieved below 170 meshes. The effects of rare earth oxides; Nd2O3, Pr6O11, Ce2O3 and Sm2O3 on the luminescence properties of the host material, Ca2MgSi2O7, were studied. Remarkable enhancement and novel color emitting including white in luminescence characteristics of host material were observed as a result of doping the mentioned rare-earths were doped.
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Thitithammawong, Anoma, Nattakamon Chuycherd, Sunisa Leekharee e Sitisaiyidah Saiwari. "Mechanical, morphological, and luminescent properties of strontium phosphorescent filler-filled NR/PP/PEC blends as affected by processing design". Journal of Elastomers & Plastics 52, n.º 5 (5 de junho de 2019): 383–96. http://dx.doi.org/10.1177/0095244319854149.

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Photoluminescent material was successfully prepared by blending europium-doped strontium aluminate phosphorescent filler (SrAl2O4:Eu2+) with terpolymer of natural rubber/polypropylene/propylene–ethylene copolymer (NR/PP/PEC). The influence of alternative processing design, that is, mixing method (simple blend (SB) or dynamic vulcanization (DV)) and mixing sequence (direct method or precompounding method) on mechanical, morphological, and photoluminescent properties of the SrAl2O4:Eu2+-filled NR/PP/PEC blends, was systematically studied. The results revealed that mechanical and photoluminescent properties can be improved by the control of rubber vulcanization and phase morphology. The dynamically vulcanized blends (DV1 and DV2), in which the NR phase was vulcanized during melt mixing under high shear and had vulcanized NR particles dispersed in the continuous PP and PEC matrices, showed superior mechanical and photoluminescent properties over the SB with co-continuous phase morphology. Controlled location of rubber additives in the NR phase by precompounding (DV2) gave the highest light emission intensity with the longest decay time.
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Dědic, R., A. Svoboda, J. Psŕenĕk, L. Lupínková, J. Komenda e J. Hála. "Time and spectral resolved phosphorescence of singlet oxygen and pigments in photosystem II particles". Journal of Luminescence 102-103 (maio de 2003): 313–17. http://dx.doi.org/10.1016/s0022-2313(02)00524-0.

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Ni, Zhongjin, Tianyu Fan, Shuyang Bai, Shiyu Zhou, Yan Lv, Yihua Ni e Bin Xu. "Effect of the Concentration of SrAl2O4: Eu2+and Dy3+ (SAO) on Characteristics and Properties of Environment-Friendly Long-Persistent Luminescence Composites from Polylactic Acid and SAO". Scanning 2021 (27 de setembro de 2021): 1–9. http://dx.doi.org/10.1155/2021/6337768.

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We report luminous polylactic acid (PLA) composite prepared via a solvent casting method using different amounts of phosphor strontium aluminate (SrAl2O4: Eu2+ and Dy3+) (SAO). The reason for doing this is that the changes of fluorescence and mechanical properties in the composites with different SAO contents can be directly evaluated. The SAO particles should have a variety of excellent characteristics in the PLA matrix, among which dispersibility and compatibility are particularly important; so, they can be modified by 3-aminopropyltriethoxysilane (APS) to achieve the target characteristics. The results showed that the fluorescence and mechanical properties were affected by SAO addition. The mechanical properties significantly improved with 5 wt% SAO; further, addition had no impact. And the emission band of fluorescence and phosphorescence is just at the peak of 524 nm. The composites with 15 wt% SAO have the best fluorescence properties. The fluorescence decreased with further doping. Fluorescence decay curves with various amounts of SAO particles show a similar tendency as pure SAO particles; the speed of decrease in afterglow intensity was higher for the first 30 min. In addition, the detailed morphological scanning and study by scanning electron microscope (SEM) showed that the particles had good adhesion to the matrix. In conclusion, the concentration of SAO into the PLA matrix impacts the fluorescence and mechanical properties of a SAO/PLA composite material.
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Atabaev, Timur Sh, Hong Ha Thi Vu, Mac Kim, Yong Suk Yang, Hyung-Kook Kim e Yoon-Hwae Hwang. "Effects of Li+ Codoping on the Optical Properties of SrAl2O4 Long Afterglow Ceramic Phosphors". Advances in Optics 2014 (4 de agosto de 2014): 1–4. http://dx.doi.org/10.1155/2014/459065.

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Rare-earths codoped long afterglow strontium aluminate phosphors with high brightness were synthesized via a facile combustion synthesis method using urea as a fuel. The resulted phosphor particles were analyzed by using X-ray diffraction and field emission scanning electron microscope, whereas their optical properties were monitored by photoluminescence spectroscopy. The prepared SrAl2O4:Eu2+, Dy3+, Li+ samples showed a broad green-yellowish emission, peaking at 512 nm when excited by 348 nm. Compared to traditional SrAl2O4:Eu2+, Dy3+ phosphor, the initial luminescence brightness of SrAl2O4:Eu2+, Dy3+, codoped with Li+ improved from 1.89 cd/m2 to 2.71 cd/m2 and the afterglow decay time was prolonged from 103 to 121 min. The possible mechanism of SrAl2O4:Eu2+, Dy3+, Li+ phosphorescence enhancement has been discussed.
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Julapong, Pongsiri, Apisit Numprasanthai, Ladda Tangwattananukul, Onchanok Juntarasakul, Palot Srichonphaisarn, Kosei Aikawa, Ilhwan Park, Mayumi Ito, Carlito Baltazar Tabelin e Theerayut Phengsaart. "Rare Earth Elements Recovery from Primary and Secondary Resources Using Flotation: A Systematic Review". Applied Sciences 13, n.º 14 (19 de julho de 2023): 8364. http://dx.doi.org/10.3390/app13148364.

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Rare earth minerals (REMs) contain rare earth elements (REEs) that are important in modern technologies due to their unique magnetic, phosphorescent, and catalytic properties. However, REMs are not only non-renewable resources but also non-uniformly distributed on the Earth’s crust, so the processing of REE-bearing secondary resources via recycling is one potential route to ensure the long-term sustainability of REE supply. Flotation—a method that separates materials based on differences in their surface wettability—is a process applied for both mineral processing and recycling of REEs, especially when the particles are fine and/or a high-purity product is required. In this review, studies about rare earth flotation from 2012 to 2021 were systematically reviewed using the PRISMA guideline. It was found that most REM flotation research works focused on finding better collectors and depressants while, for recycling, studies on advanced flotation techniques like froth flotation, ion flotation, solvent sublation, electroflotation, and adsorbing colloid flotation with an emphasis on the recovery of dissolved REEs from aqueous solutions dominated.
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36

Shin, Dae Yong, e Kyung Nam Kim. "Effects of Eu2+, Dy3+ Contents and Particle Sizes on the Luminescent Properties of SrAl2O4 Phosphor by the Sol-Gel Process". Materials Science Forum 620-622 (abril de 2009): 473–76. http://dx.doi.org/10.4028/www.scientific.net/msf.620-622.473.

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A green emitting SrAl2O4:Eu2+, Dy3+ phosphor with high brightness and long afterglow was synthesized by the sol-gel method. SrAl2O4: Eu2+, Dy3+ phosphor exhibited broad band extending from 450 to 650 nm and maximum emission spectra peaking at 520 nm. Three excited levels existed, two shoulders were observed at 270 and 330 nm in addition to the maximum at 360 nm on the excitation spectrum. After the removal of excitation light, the excellent after-glow characteristic of the phosphorescence was obtained as a result of low decay time, although the after-glow intensities of phosphor varied exponentially with the time.
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Shino, Naoki, Naoki Fujisawa, Takeshi Yokomori e Taro Hirasawa. "D124 Simultaneous Two-dimensional Temperature and Velocity Measurements in Gas Flow using the Phosphorescent Persistence of Thermographic Phosphor Particles". Proceedings of the Thermal Engineering Conference 2014 (2014): _D124–1_—_D124–2_. http://dx.doi.org/10.1299/jsmeted.2014._d124-1_.

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Hoshi, Mitsuki, Ryuhei Nishiyabu, Yuichiro Hayashi, Shigeyuki Yagi e Yuji Kubo. "Room‐Temperature Phosphorescence‐active Boronate Particles: Characterization and Ratiometric Afterglow‐sensing Behavior by Surface Grafting of Rhodamine B". Chemistry – An Asian Journal 15, n.º 6 (18 de fevereiro de 2020): 787–95. http://dx.doi.org/10.1002/asia.201901740.

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Cho, Min Young, Suman Timilsina, Jong Wook Roh, Walter Commerell, Ho Geun Shin, Yong-Nam Kwon e Ji Sik Kim. "Ultraviolet Light-Responsive Photorheological Fluid for Sensors and Actuators Realized by Phosphorescence Effects and LSTM RNN". Korean Journal of Metals and Materials 59, n.º 5 (5 de maio de 2021): 346–53. http://dx.doi.org/10.3365/kjmm.2021.59.5.346.

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A photo-rheological fluid (PRF) is a smart fluid which exhibits different viscosity under UV irradiation. A PRF is comprehensively presented in this work, with particular focus on its responses under UV off/on conditions. The isomeric conversion from SP to MC and vice versa under UV off and on, respectively, showed unequal rates of transformation. As a result, a complex non-linear hysteretic response was observed. To be used indifferent types of sensors and actuators which can exploit its rheological properties, it is essential the PRF have linearized hysteresis behavior. To minimize the asymmetric non-linear hysteresis characteristics under UV on and off conditions, the well-known long-lasting phosphor SAO (SrAl2O4:Eu2+, Dy3+) was incorporated. The incorporation of SAO in the PRF improved the linearity of the PRF response, although the conversion rate was not identical under UV off/on conditions. The SAO particles were observed to settle over time due to phase splitting, undermining the usefulness of the SAO-PRF composite. Instead of improving the PRF response by further adjusting the PRF composite, a software approach based on Long Short-Term Memory Recurrent Neural Networks (LSTM RNN) was employed to model and compensate the asymmetric non-linear hysteresis response, ensuring the realization of sensors and actuators that exploit PRF as hardware.
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40

Liu, Jia-ming, Shi-Rong Hu, Xiu-mei He, Xue-lin Li, Feng-ping Zhan, Li-qing Zeng, Long-Di Li, Guo-hui Zhu e Xiao-mei Huang. "Determination of traces of bismuth by quenching of solid-substrate room-temperature phosphorescence from morin-labeled silicon dioxide nano-particles". Analytical and Bioanalytical Chemistry 382, n.º 7 (13 de julho de 2005): 1507–12. http://dx.doi.org/10.1007/s00216-005-3293-2.

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41

Datta, Shubhashis, Andrej Hovan, Annamária Jutková, Sergei G. Kruglik, Daniel Jancura, Pavol Miskovsky e Gregor Bánó. "Phosphorescence Kinetics of Singlet Oxygen Produced by Photosensitization in Spherical Nanoparticles. Part II. The Case of Hypericin-Loaded Low-Density Lipoprotein Particles". Journal of Physical Chemistry B 122, n.º 20 (30 de abril de 2018): 5154–60. http://dx.doi.org/10.1021/acs.jpcb.8b00659.

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42

Papadopoulos, Nick, Angelos Efstathopoulos, Dimitrios Karangelos e Nick Petropoulos. "Determination of uranium isotope concentrations in precipitation in the vicinity of lignite-fired power plants". Nuclear Technology and Radiation Protection 26, n.º 1 (2011): 1–10. http://dx.doi.org/10.2298/ntrp1101001p.

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Coal- and lignite-fired power plants produce significant amounts of fly ash, which in many cases contains high concentrations of naturally occurring radionuclides such as 238U. This is of importance from the radio-environmental point of view since a small portion of the fly ash escapes from the power plant filtering system and disperses in the surrounding atmosphere. In addition, coal- and lignite-fired plants related activities such as fuel mining and ash deposition contribute to the suspended matter in the air with particles containing naturally occurring radionuclides. In this study, rainwater samples were collected in the Megalopolis lignite field basin of the Arcadia prefecture in Greece, where lignite-fired power plants are in operation and related activities are fully developed. The samples were preconcentrated and analyzed with alpha spectrometry and kinetic phosphorescence analysis in order to determine the levels of uranium isotope concentrations in precipitation in the Megalopolis basin. A control rainwater sample was also collected in the Athens area to account for reference purposes. Concentrations determined via the two techniques were found to be in statistical agreement. The concentration of 238U in the samples collected at the Megalopolis basin varies from 2.2 ? 0.6 to 90 ? 14 mBq/L, and is 5-40 times higher than the concentration of 238U in the sample collected in Athens. This could be attributed to the operation of the lignite-fired power plants, the fossil fuel mines, and the ash depositories.
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43

Qing, Xiang-Dong, Xiao-Hua Zhang, Rong An, Jin Zhang, Ling Xu e Ludovic Duponchel. "A Fast and Robust Third-Order Multivariate Calibration Approach Coupled with Excitation–Emission Matrix Phosphorescence for the Quantification and Oxidation Kinetic Study of Fluorene in Wastewater Samples". Chemosensors 11, n.º 1 (7 de janeiro de 2023): 53. http://dx.doi.org/10.3390/chemosensors11010053.

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Human activity today produces a large number of pollutants that end up in the environment, such as soil, water, and airborne particles. The first objective of this work is to introduce a new third-order multivariate calibration approach called self-weighted alternating quadrilinear decomposition (SWAQLD) for the analysis of organic pollutant of fluorene (FLU) in different water systems. One simulated and two real four-way data sets are used to study the potential of the proposed approach in comparison with two classical algorithms, namely alternating quadrilinear decomposition (AQLD) and parallel factor analysis (PARAFAC). The results of simulated data show that SWAQLD inherits the advantages of PARAFAC in terms of not only tolerance to experimental noise but also a fast convergence and a certain robustness to overestimation of the rank of the models from AQLD. The second objective of this work is to propose a new way of generating third-order data using excitation–emission matrix phosphorescence (EEMP) at room temperature for the study of the kinetic process of oxidation of FLU in complex chemical systems. The obtained rate constant and half-life of the FLU oxidation, on average, are 0.015 min−1 and 45.5 min for free-interference water and 0.017 min−1 and 40.0 min for wastewater, respectively. Research results show that SWAQLD coupled with EEMP allows the quantification and kinetic monitoring of FLU in analytical conditions of different complexities with excellent robustness to the choice of the number of model components.
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44

Hu, Shi‐Rong, Xiao‐Jie Cui, Lai‐Ming Li, Fei‐Ming Li, Xiao‐Jin Yang, Wen‐Yan Gao, Ai‐Fang Zheng, Long‐Di Li e Jia‐Ming Liu. "Determination of Trace Bismuth by a Solid Substrate Room Temperature Phosphorescence Quenching Method Based on Anionic Polymeric Acryclic Acid Lead Particles Containing Luminescent Eosine Molecules". Spectroscopy Letters 39, n.º 4 (1 de agosto de 2006): 387–97. http://dx.doi.org/10.1080/00387010600649000.

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LIU, J., A. WU, H. XU, Q. WANG, L. LI e G. ZHU. "Determination of trace mercury by solid substrate room temperature phosphorescence quenching method based on lead carboxymethyl cellulose (Pb(CMC)) particles containing luminescent salicyl fluorones molecules". Talanta 65, n.º 2 (30 de janeiro de 2005): 501–4. http://dx.doi.org/10.1016/j.talanta.2004.06.036.

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Liu, Jia‐Ming, Xuan Lin, Shan‐Shan Xu, Qiao‐Mei Lu, Li‐Qing Zeng e Shao‐Qin Lin. "Determination of Trace Copper by Solid Substrate–Room Temperature Phosphorescence Quenching Method Based on Lead Carboxymethyl Cellulose [Pb(CMC)2] Particles Containing Luminescent Salicyl Fluorones Molecules". Spectroscopy Letters 39, n.º 4 (1 de agosto de 2006): 311–20. http://dx.doi.org/10.1080/00387010600779179.

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47

Lin, Xuan, Ruo-Hong Wu, Xiao-Ju Li, Li Chen, Qing-Wei Lin, Wen-Yan GAO, Ai-Fang Zheng, Jia-Ming Liu, Guo-Hui Zhu e Xiao-Mei Huang. "Determination of trace lead by solid substrate room temperature phosphorescence enhancing method based on heavy atom effect and dissoluble manganese supramolecule containing rhodamine 6G luminescent particles". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 66, n.º 2 (fevereiro de 2007): 493–98. http://dx.doi.org/10.1016/j.saa.2006.03.027.

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48

Jiaming, Liu, Li Wenqi, Li Xuelin, Chen Hailing, Lu Qiaomei, Li Longdi, Li Zhimin, Zhu Guohui e Chen Cuilian. "Determination of trace silver by solid substrate room temperature phosphorescence quenching method based on lead carboxymethyl cellulose particles (Pb(CMC)2) containing luminescent salicyl fluorenes molecules". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 61, n.º 13-14 (outubro de 2005): 3077–81. http://dx.doi.org/10.1016/j.saa.2004.11.033.

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49

Mokrzyński, Krystian, Olga Krzysztyńska-Kuleta, Marcin Zawrotniak, Michał Sarna e Tadeusz Sarna. "Fine Particulate Matter-Induced Oxidative Stress Mediated by UVA-Visible Light Leads to Keratinocyte Damage". International Journal of Molecular Sciences 22, n.º 19 (30 de setembro de 2021): 10645. http://dx.doi.org/10.3390/ijms221910645.

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The human skin is exposed to various environmental factors including solar radiation and ambient air pollutants. Although, due to its physical and biological properties, the skin efficiently protects the body against the harm of environmental factors, their excessive levels and possible synergistic action may lead to harmful effects. Among particulate matter present in ambient air pollutants, PM2.5 is of particular importance for it can penetrate both disrupted and intact skin, causing adverse effects to skin tissue. Although certain components of PM2.5 can exhibit photochemical activity, only a limited amount of data regarding the interaction of PM2.5 with light and its effect on skin tissue are available. This study focused on light-induced toxicity in cultured human keratinocytes, which was mediated by PM2.5 obtained in different seasons. Dynamic Light Scattering (DLS) and Atomic Force Microscopy (AFM) were employed to determine sizes of the particles. The ability of PM2.5 to photogenerate free radicals and singlet oxygen was studied using EPR spin-trapping and time-resolved singlet oxygen phosphorescence, respectively. Solar simulator with selected filters was used as light source for cell treatment to model environmental lightning conditions. Cytotoxicity of photoexcited PM2.5 was analyzed using MTT assay, PI staining and flow cytometry, and the apoptotic pathway was further examined using Caspase-3/7 assay and RT-PCR. Iodometric assay and JC-10 assay were used to investigate damage to cell lipids and mitochondria. Light-excited PM2.5 were found to generate free radicals and singlet oxygen in season-dependent manner. HaCaT cells containing PM2.5 and irradiated with UV-Vis exhibited oxidative stress features–increased peroxidation of intracellular lipids, decrease of mitochondrial membrane potential, enhanced expression of oxidative stress related genes and apoptotic cell death. The data indicate that sunlight can significantly increase PM2.5-mediated toxicity in skin cells.
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Ha, Hyein, Jaeseung Kim, Young Jae Shim, Aqsa Irfan, Ajay Nimbalkar, Ramachandran Elumalai, Thi Na Le, Hyunjung Kim e Min Chul Suh. "Intrinsically Stretchable Emissive Layer for Green and Red Phosphorescent OLEDs: Small Molecules Blended with SEBS Elastomer". Advanced Materials Technologies, 3 de setembro de 2023. http://dx.doi.org/10.1002/admt.202300924.

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AbstractIn the field of stretchable electronics, intrinsically stretchable organic light‐emitting diodes (IS‐OLEDs) are considered to be essential units. However, research on stretchable electroluminescent layers for light‐emitting devices is limited. The most common method to obtain an effective stretchable emitting layer is blending a conjugated polymer with an elastomer. In this study, blending small molecules with a thermoplastic styrene‐ethylene‐butylene‐styrene (SEBS) elastomer to fabricate a stretchable emitting layer is proposed. The mechanical, electrical, and morphological properties of the blended films are studied. The results show that the blended films can be stretched up to 200% without any morphological change such as cracking or particle shedding. Additionally, an OLED is fabricated with a stretchable electroluminescent layer and demonstrated its functionality.
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